Over 50 Percent Metal, But No Base Patents (Class 148/707)
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Patent number: 11035028Abstract: The present disclosure relates to a powder of an austenitic alloy and a HIP:ed object manufactured thereof and a process for the manufacturing the HIP:ed object and its use in corrosive environments.Type: GrantFiled: March 21, 2018Date of Patent: June 15, 2021Assignee: Sandvik Intellectual Property ABInventors: Hans Söderberg, Thomas Blomfeldt, Ulf Kivisäkk, Lars-Olov Nordberg, Zhiliang Zhou
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Patent number: 10209208Abstract: Provided in one embodiment is a method of identifying a stable phase of an ordering binary alloy system comprising a solute element and a solvent element, the method comprising: determining at least three thermodynamic parameters associated with grain boundary segregation, phase separation, and intermetallic compound formation of the ordering binary alloy system; and identifying the stable phase of the ordering binary alloy system based on the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter by comparing the first thermodynamic parameter, the second thermodynamic parameter and the third thermodynamic parameter with a predetermined set of respective thermodynamic parameters to identify the stable phase; wherein the stable phase is one of a stable nanocrystalline phase, a metastable nanocrystalline phase, and a non-nanocrystalline phase.Type: GrantFiled: July 25, 2017Date of Patent: February 19, 2019Assignee: Massachusetts Institute of TechnologyInventors: Heather A. Murdoch, Christopher A. Schuh
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Patent number: 9034247Abstract: A cobalt-nickel base alloy is disclosed. The alloy includes, in weight percent: greater than about 4 % of Al, about 10 to about 20 % of W, about 10 to about 40 % Ni, about 5 to 20 % Cr and the balance Co and incidental impurities. The alloy has a microstructure that is substantially free of a CoAl phase having a B2 crystal structure and configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment. A method of making an article of the alloy includes: selecting the alloy; forming an article from the alloy; solution-treating the alloy; and aging the alloy to form an alloy microstructure that is substantially free of a CoAl phase having a B2 crystal structure, wherein the alloy is configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment.Type: GrantFiled: June 9, 2011Date of Patent: May 19, 2015Assignee: General Electric CompanyInventors: Akane Suzuki, Andrew John Elliott, Michael Francis Xavier Gigliotti, Jr., Kathleen Blanche Morey, Jon Conrad Schaeffer, Pazhayannur Subramanian
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Patent number: 9017602Abstract: A method of forming a wrought material having a refined grain structure is provided. The method comprises providing a metal alloy material having a depressed solidus temperature and a low temperature eutectic phase transformation. The metal alloy material is molded and rapidly solidified to form a fine grain precursor that has fine grains surrounded by a eutectic phase with fine dendritic arm spacing. The fine grain precursor is plastic deformed at a high strain rate to cause recrystallization without substantial shear banding to form a fine grain structural wrought form. The wrought form is then thermally treated to precipitate the eutectic phase into nanometer sized dispersoids within the fine grains and grain boundaries and to define a thermally treated fine grain structure wrought form having grains finer than the fine grains and the fine dendritic arm spacing of the fine grain precursor.Type: GrantFiled: February 4, 2011Date of Patent: April 28, 2015Assignee: Thixomat, Inc.Inventors: Raymond F. Decker, Jack Huang, Sanjay G. Kulkarni, Stephen E. Lebeau, Ralph E. Vining
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Patent number: 9017490Abstract: A high strength, corrosion resistant alloy suitable for use in oil and gas environments includes, in weight %: 0-12% Fe, 18-24% Cr, 3-6.2% Mo, 0.05-3.0% Cu, 4.0-6.5% Nb, 1.1-2.2% Ti, 0.05-0.4% 0.05-0.2% Al, 0.005-0.040% C, balance Ni plus incidental impurities and deoxidizers. A ratio of Nb/(Ti+Al) is equal to 2.5-7.5 to provide a desired volume fraction of ?? and ?? phases. The alloy has a minimum yield strength of 145 ksi.Type: GrantFiled: November 18, 2008Date of Patent: April 28, 2015Assignee: Huntington Alloys CorporationInventor: Sarwan Kumar Mannan
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Patent number: 8906174Abstract: Disclosed are a high-strength Ni-base alloy, a method of producing the Ni-base alloy, and a method of recovering a member made of a degraded Ni-base alloy. It contains not more than 0.1 wt % C, not more than 50 wt % Fe, not more than 30 wt % Cr, Ti, and at least one of Nb and Al. It has been strengthened by precipitates of a ?? phase (Ni3Al) and/or a ?? phase (Ni3Nb). It contains also a ? phase (Ni3Ti) which is thermodynamically stable in a temperature range of 800° C. to 900° C. When observed a cross-section of the Ni-base alloy, a plurality of nodes exist along each segment connecting two meeting points each of which point is defined by adjacent three crystal grains, and precipitates of the ?? phase and/or the ?? phase in each of crystal grains of the Ni-base alloy have an average particle size of not more than 100 nm.Type: GrantFiled: February 18, 2010Date of Patent: December 9, 2014Assignee: Mitsubishi Hitachi Power Systems, Ltd.Inventors: Shinya Imano, Jun Sato
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Publication number: 20140283953Abstract: Method for producing a soft magnetic alloy strip suited to be mechanically cut, having a chemical composition comprising, by weight: 18% ?? Co ? 55%? 0% ? V + W ? 3% 0% ? Cr ? 3% 0% ? Si ? 3% 0% ? Nb ? 0.5%? 0% ? B ? 0.05%?? 0% ? C ? 0.1%? 0% ? Zr + Ta ? 0.5%? 0% ? Ni ? 5% 0% ? Mn ? 2% the rest being iron and impurities from production, according to which a strip obtained by hot rolling a semi-finished product consisting of the alloy is cold-rolled to obtain a cold-rolled strip with a thickness less than 0.6 mm, After the cold rolling, the strip is running annealed by passing it through a continuous furnace at a temperature between the order/disorder transition temperature of the alloy and the ferritic/austenitic transformation point of the alloy, followed by rapid cooling to a temperature below 200° C.Type: ApplicationFiled: December 16, 2011Publication date: September 25, 2014Applicant: APERAMInventors: Thierry Waeckerle, Remy Batonnet
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Publication number: 20140255246Abstract: Guide wire devices and other intra-corporal medical devices fabricated from a Ni—Ti—Nb alloy and methods for their manufacture. The Ni—Ti alloy includes nickel, titanium, and niobium either up to its solubility limit in Ni—Ti, or in amounts over 15 atomic percent so as to provide a dual phase alloy. In either case, the Ni—Ti—Nb alloy provides increased stiffness to provide better torque response, steerability, stent scaffolding strength, and similar properties associated with increased stiffness, while still providing super-elastic or linear pseudo-elastic properties.Type: ApplicationFiled: March 8, 2013Publication date: September 11, 2014Applicant: ABBOTT LABORATORIESInventors: John A. Simpson, John F. Boylan
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Patent number: 8801877Abstract: An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si?2%, Mn?3%, P?0.03%, S?0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co?20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N?0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P?3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr?Ni+Co?1.85×Cr . . . (2), Al?1.5×Zr . . . (3).Type: GrantFiled: June 3, 2013Date of Patent: August 12, 2014Assignee: Nippon Steel & Sumitomo Metal CorporationInventors: Hiroyuki Semba, Hirokazu Okada, Masaaki Igarashi
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Publication number: 20140137994Abstract: Austenitic stainless steel having high temperature strength and excellent nitric acid corrosion resistance is provided. The austenitic stainless steel according to the present embodiment including, in mass percent, C: at most 0.050%, Si: 0.01 to 1.00%, Mn: 1.75 to 2.50%, P: at most 0.050%, S: at most 0.0100%, Ni: 20.00 to 24.00%, Cr: 23.00 to 27.00%, Mo: 1.80 to 3.20%, and N: 0.110 to 0.180%, the balance being Fe and impurities, a grain size number of crystal grains based on JIS G0551 (2005) is at least 6.0, and an area fraction of a ? phase is at most 0.1%.Type: ApplicationFiled: June 20, 2012Publication date: May 22, 2014Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventor: Masaki Ueyama
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Publication number: 20140083576Abstract: There is provided an austenitic alloy pipe that is durable even if a stress distribution different according to usage environment is applied. The austenitic alloy pipe in accordance with the present invention has a tensile yield strength YSLT of at least 689.1 MPa. The tensile yield strength YSLT, a compressive yield strength YSLC in a pipe axial direction, a tensile yield strength YSCT in a pipe circumferential direction of the alloy pipe, and a compressive yield strength YSCC in the pipe circumferential direction satisfy Formulas (1) to (4). 0.90?YSLC/YSLT?1.11??(1) 0.90?YSCC/YSCT?1.11??(2) 0.90?YSCC/YSLT?1.11??(3) 0.90?YSCT/YSLT?1.Type: ApplicationFiled: March 19, 2012Publication date: March 27, 2014Applicant: Nippon Steel & Sumitomo Medtal CorporationInventors: Naoki Sawawatari, Kouichi Kuroda, Hitoshi Suwabe, Masaki Ueyama
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Publication number: 20130341184Abstract: Provided is a Co—Cr—Pt—B-based alloy sputtering target having no more than 10 cracks of 0.1 to 20 ?m in a B-rich phase in a 100 ?m×100 ?m area (field of view). Additionally provided is a method for producing this Co—Cr—Pt—B-based alloy sputtering target including the steps of hot forging or hot rolling a Co—Cr—Pt—B-based alloy cast ingot, thereafter performing cold rolling or cold forging thereto at an elongation rate of 4% or less, and machining the ingot to prepare a target having no more than 10 cracks of 0.1 to 20 ?m in a B-rich phase in a 100 ?m×100 ?m area (field of view), or, hot forging or hot rolling the ingot, thereafter quenching the ingot to ?196° C. to 100° C., and machining the ingot to prepare a target. The target of the present invention has high magnetic flux density and few microcracks in a B-rich layer, and thus stabilizes discharge and minimizes arcing.Type: ApplicationFiled: May 22, 2012Publication date: December 26, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventors: Yuto Morishita, Shin-ichi Ogino, Yuichiro Nakamura
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Patent number: 8608877Abstract: Articles that include a material that has L12-structured gamma-prime phase precipitates within a matrix phase at a concentration of at least 20% by volume are disclosed. The gamma-prime phase precipitates are less than 1 micrometer in size. The material also has A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The articles may be formed by mechanically working a workpiece that has at least about 40% nickel, about 1.5% to about 8% titanium, and about 1.5% to about 4.5% aluminum. The workpiece may be worked at a temperature below a solvus temperature of the eta phase; and then heat treated at a temperature sufficient to dissolve any gamma prime phase present in the workpiece but below the solvus temperature of the eta phase.Type: GrantFiled: July 27, 2010Date of Patent: December 17, 2013Assignee: General Electric CompanyInventors: Richard DiDomizio, Judson Sloan Marte, Pazhayannur Ramanathan Subramanian
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Patent number: 8557015Abstract: In a Cr—Cu alloy that is formed by powder metallurgy and contains a Cu matrix and flattened Cr phases, the Cr content in the Cr—Cu alloy is more than 30% to 80% or less by mass, and the average aspect ratio of the flattened Cr phases is more than 1.0 and less than 100. The Cr—Cu alloy has a small thermal expansion coefficient in in-plane directions, a high thermal conductivity, and excellent processibility. A method for producing the Cr—Cu alloy is also provided. A heat-release plate for semiconductors and a heat-release component for semiconductors, each utilizing the Cr—Cu alloy, are also provided.Type: GrantFiled: February 14, 2007Date of Patent: October 15, 2013Assignees: JFE Precision Corporation, JFE Steel CorporationInventors: Hoshiaki Terao, Hiroki Ota, Hideaki Kobiki, Aya Uenosono
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Publication number: 20130248061Abstract: Methods of processing compositions containing titanium and aluminum, especially titanium aluminide intermetallic compositions (TiAl intermetallics) based on the TiAl (gamma) intermetallic compound. The methods entail processing steps that include a hot isostatic pressing (HIP) cycle and a heat treatment cycle that can be performed in a single vessel. TiAl intermetallic compositions processed in this manner preferably exhibit a duplex microstructure containing equiaxed and lamellar morphologies.Type: ApplicationFiled: April 30, 2012Publication date: September 26, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Thomas Joseph Kelly, Bernard Patrick Bewlay, Michael James Weimer, Richard Kenneth Whitacre
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Publication number: 20130216421Abstract: A method and process for at least partially forming a medical device that is at least partially formed of a metal alloy which improves the physical properties of the medical device.Type: ApplicationFiled: February 25, 2013Publication date: August 22, 2013Applicant: Rich Products CorporationInventors: Raymond W. Buckman, JR., Udayan Patel, Joseph Furst
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Publication number: 20130133793Abstract: A method for heat treating a 718-type nickel-base comprises heating a 718-type nickel-base alloy to a heat treating temperature, and holding the alloy at the heat treating temperature for a heat treating time sufficient to form an equilibrium or near-equilibrium concentration of ?-phase grain boundary precipitates within the nickel-base alloy and up to 25 percent by weight of total ??-phase and ??-phase. The 718-type nickel-base alloy is air cooled. The present disclosure also includes a 718-type nickel-base alloy comprising a near-equilibrium concentration of ?-phase grain boundary precipitates and up to 25 percent by weight of total ??-phase and ??-phase precipitates. Alloys according to the disclosure may be included in articles of manufacture such as, for example, face sheet, honeycomb core elements, and honeycomb panels for thermal protection systems for hypersonic flight vehicles and space vehicles.Type: ApplicationFiled: November 30, 2011Publication date: May 30, 2013Applicant: ATI Properties, Inc.Inventor: Erin T. McDevitt
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CAST NICKEL-IRON-BASE ALLOY COMPONENT AND PROCESS OF FORMING A CAST NICKEL-IRON-BASE ALLOY COMPONENT
Publication number: 20130126056Abstract: A cast nickel-iron-base alloy component having by weight about 12.0% to about 16.5% Cr, about 1.0% to about 2.0% Al, about 2.0% to about 3.0% Ti, about 2.0% to about 3.0% W, about 3.0 to about 5.0% Mo, up to about 0.1% Nb, up to about 0.2% Mn, up to about 0.1% Si, about 0.05% to about 0.10% C, about 0.003 to about 0.010% B, about 35% to about 37% Fe, and balance essentially Ni and inevitable impurities. The nickel-iron-base alloy component has a creep rupture life greater than about 1000 hours at about 25 ksi to about 30 ksi at about 1400° F. A method for forming the cast nickel-iron-base alloy component is also disclosed.Type: ApplicationFiled: November 18, 2011Publication date: May 23, 2013Applicant: GENERAL ELECTRIC COMPANYInventors: Ganjiang FENG, George Albert GOLLER, Joseph C. RAZUM, Matthew LAYLOCK -
Publication number: 20130014862Abstract: The present invention provides an Ni-base dual multi-phase intermetallic compound alloy which has a dual multi-phase microstructure including: a primary precipitate L12 phase and an (L12+D022) eutectoid microstructure, and which comprises more than 5 atomic % and up to 13 atomic % of Al; at least 9.5 atomic % and less than 17.5 atomic % of V; between 0 atomic % and 5.0 atomic % inclusive of Nb; more than 0 atomic % and up to 12.5 atomic % of Ti; more than 0 atomic % and up to 12.5 atomic % of C; and a remainder comprising Ni.Type: ApplicationFiled: March 25, 2011Publication date: January 17, 2013Applicant: OSAKA PREFECTURE UNIVERSITY PUBLIC CORPORATIONInventors: Takayuki Takasugi, Yasuyuki Kaneno
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Publication number: 20130000797Abstract: A soft magnetic alloy is provided that consists essentially of 47 weight percent?Co?50 weight percent, 1 weight percent?V?3 weight percent, 0 weight percent?Ni?0.25 weight percent, 0 weight percent?C?0.007 weight percent, 0 weight percent?Mn?0.1 weight percent, 0 weight percent?Si?0.1 weight percent, at least one of niobium and tantalum in amounts of x weight percent of niobium, y weight percent of tantalum, remainder Fe. The alloy includes 0 weight percent?x<0.15 weight percent, 0 weight percent?y?0.3 weight percent and 0.14 weight percent?(y+2x)?0.3 weight percent. The soft magnetic alloy has been annealed at a temperature in the range of 730° C. to 880° C. for a time of 1 to 6 hours and comprises a yield strength in the range of 200 MPa to 450 MPa and a coercive field strength of 0.3 A/cm to 1.5 A/cm.Type: ApplicationFiled: June 29, 2012Publication date: January 3, 2013Applicant: Vacuumschmelze GmbH & Co. KGInventors: Witold PIEPER, Niklas VOLBERS, Joachim GERSTER
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Publication number: 20120312434Abstract: A high-temperature, high-strength, oxidation-resistant cobalt-nickel base alloy is disclosed. The alloy includes, in weight percent: about 3.5 to about 4.9% of Al, about 12.2 to about 16.0% of W, about 24.5 to about 32.0% Ni, about 6.5% to about 10.0% Cr, about 5.9% to about 11.0% Ta, and the balance Co and incidental impurities. A method of making an article having high-temperature strength, cyclic oxidation resistance and corrosion resistance is disclosed. The method includes forming a high-temperature, high-strength, oxidation-resistant cobalt-nickel base alloy as described herein; forming an article from the alloy; solution-treating the alloy by a solution heat treatment; and aging the alloy by providing at least one aging heat treatment at an aging temperature that is less than the gamma-prime solvus temperature, wherein the alloy is configured to form a continuous, protective, adherent oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment.Type: ApplicationFiled: June 9, 2011Publication date: December 13, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Akane Suzuki, Andrew John Elliott, Michael Francis Xavier Gigliotti, JR., Kathleen Blanche Morey, Pazhayannur Subramanian
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Publication number: 20120312426Abstract: A cobalt-nickel base alloy is disclosed. The alloy includes, in weight percent: greater than about 4% of Al, about 10 to about 20% of W, about 10 to about 40% Ni, about 5 to 20% Cr and the balance Co and incidental impurities. The alloy has a microstructure that is substantially free of a CoAl phase having a B2 crystal structure and configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment. A method of making an article of the alloy includes: selecting the alloy; forming an article from the alloy; solution-treating the alloy; and aging the alloy to form an alloy microstructure that is substantially free of a CoAl phase having a B2 crystal structure, wherein the alloy is configured to form a continuous, adherent aluminum oxide layer on an alloy surface upon exposure to a high-temperature oxidizing environment.Type: ApplicationFiled: June 9, 2011Publication date: December 13, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Akane Suzuki, Andrew John Elliott, Michael Francis Xavier Gigliotti, JR., Kathleen Blanche Morey, Jon Conrad Schaeffer, Pazhayannur Subramanian
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Publication number: 20120190321Abstract: A nonmagnetic stainless steel which has a higher electrical resistivity than existing nonmagnetic alloys, a production process for producing the stainless steel, and a radio wave receiver. The receiver has a main case and rear cover constituted of a nonmagnetic stainless steel having an electrical resistivity as high as more than 100 ??·cm and consisting of C: not more than 0.1%, Si: 4.0-7.5%, Mn: not more than 2.0%, Ni: 25.5-30.0%, Cr: 15.0-20.0%, Mo: 0.1-3.0%, Cu: 0-2.0%, in mass % and the balance Fe and impurities. Even if some variable magnetic flux generated by a coil of an antenna runs through the main case and the rear cover, the receiving efficiency of the antenna can be prevented from being reduced by eddy current loss and a sufficient radio receiving sensitivity can be obtained. This nonmagnetic stainless steel is produced by hot and/or cold plastic working and subsequent solution treating conducted at 1,000-1,180° C.Type: ApplicationFiled: July 29, 2010Publication date: July 26, 2012Applicants: HITACHI METALS, LTD., CASIO COMPUTER CO., LTD.Inventors: Junichi Sato, Toshihiro Uehara, Kenji Yokoyama
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Patent number: 8147751Abstract: To provide a silver-white copper alloy which represents a silver-white color equivalent to that of nickel silver and is excellent in hot workability and the like. The silver-white copper alloy includes 47.5 to 50.5 mass % of Cu, 7.8 to 9.8 mass % of Ni, 4.7 to 6.3 mass % of Mn, and the remainder including Zn, and the silver-white copper alloy has an alloy composition satisfying relationships of f1=[Cu]+1.4×[Ni]+0.3×[Mn]=62.0 to 64.0, f2=[Mn]/[Ni]=0.49 to 0.68, and f3=[Ni]+[Mn]=13.0 to 15.5 among a content [Cu] mass % of Cu, a content [Ni] mass % of Ni, and a content [Mn] mass % of Mn, and has a metal structure in which ? phases at an area ratio of 2 to 17% are dispersed in an ?-phase matrix. The copper alloy is provided as a hot processing material or continuous casting material formed by performing one or more heat treatments and cold processes on a hot processing raw material formed by performing a hot process on an ingot or a casting raw material obtained by continuous casting.Type: GrantFiled: March 9, 2009Date of Patent: April 3, 2012Assignee: Mitsubishi Shindoh Co., Ltd.Inventor: Keiichiro Oishi
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Patent number: 8119063Abstract: High-alloy austenitic stainless steels that are extra resistant to pitting and crevice corrosion in aggressive, chloride-containing solutions have a tendency for macro-segregation of Mo, at solidification of the melt. This problem is solved by a super austenite stainless steel having the following composition, in % by weight: max 0.03 C, max 0.5 Si, max 6 Mn, 28-30 Cr, 21-24 Ni, 4-6% (Mo+W/2), the content of W being max 0.7, 0.5-1.1 N, max 1.0 Cu, balance iron and impurities at normal contents originating from the production of the steel.Type: GrantFiled: December 28, 2005Date of Patent: February 21, 2012Assignee: Outokumpu OyjInventors: Hachemi Loucif, Mats Liljas
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Publication number: 20120031534Abstract: A method for producing a high-strength Cr—Ni alloy seamless pipe comprising preparing an alloy billet with a chemical composition consisting, by mass %, of C: 0.05% or less, Si: 1.0% or less, Mn: less than 3.0%, P: 0.005% or less, S: 0.005% or less, Cu: 0.01 to 4.0%, Ni: 25% or more and less than 35%, Cr: 20 to 30%, Mo: 0.01% or more and less than 4.0%, N: 0.10 to 0.30%, Al: 0.03 to 0.30%, O (oxygen): 0.01% or less, REM (rare earth metal): 0.01 to 0.20%, and the balance being Fe and impurities, and satisfying the formula N×P/REM?0.10, wherein P, N and REM represent the contents (mass %) of P, N and REM, respectively. The pipe is hot worked using cross roll piercing, solution heat treated, and cold worked. The pipe is excellent in hot workability, stress corrosion cracking and does not laminate during cross piercing.Type: ApplicationFiled: September 26, 2011Publication date: February 9, 2012Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Yohei OTOME, Masaaki Igarashi, Hirokazu Okada, Kunio Kondo, Masayuki Sagara, Kazuhiro Shimoda
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Publication number: 20120027607Abstract: Articles suitable for use in high temperature applications, such as turbomachinery components, and methods for making such articles, are provided. One embodiment is an article. The article comprises a material comprising a plurality of L12-structured gamma-prime phase precipitates distributed within a matrix phase at a concentration of at least 20% by volume, wherein the gamma-prime phase precipitates are less than 1 micrometer in size, and a plurality of A3-structured eta phase precipitates distributed within the matrix phase at a concentration in the range from about 1% to about 25% by volume. The solvus temperature of the eta phase is higher than the solvus temperature of the gamma-prime phase. Moreover, the material has a median grain size less than 10 micrometers. The method comprises providing a workpiece, the workpiece comprising at least about 40% nickel, from about 1.5% to about 8% titanium, and from about 1.5% to about 4.5% aluminum.Type: ApplicationFiled: July 27, 2010Publication date: February 2, 2012Applicant: GENERAL ELECTRIC COMPANYInventors: Richard DiDomizio, Judson Sloan Marte, Pazhayannur Ramanathan Subramanian
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Publication number: 20110307014Abstract: A spinal fixation titanium alloy rod fixes a plurality of spinal-fixing screws embedded and fixed in vertebrae of a human body. The rod is cylindrically shaped, has a sufficient length for coupling with the spinal-fixing screws, and has a diameter adjusted to 4 to 7 mm. In the titanium alloy constituting the rod, Nb content is 25 to 35 percent by weight, Ta content is such that the Nb content+0.8×Ta content ranges from 36 to 45 percent by weight, Zr content is 3 to 6 percent by weight, and the remainder is Ti and unavoidable impurities, excluding vanadium. The titanium alloy is manufactured by swaging processing at a cross-sectional reduction rate of at least 90%, and aging the swaged titanium alloy by heating at a temperature of 600 to 800K, preferably 700 to 800K, for 43.2 ks to 604.8 ks.Type: ApplicationFiled: December 10, 2010Publication date: December 15, 2011Applicants: NATIONAL UNIVERSITY CORPORATION TOHOKU UNIVERSITY, SHOWA-IKA KOGYO CO. LTD.Inventors: Mitsuo Niinomi, Masaaki Nakai, Kengo Narita
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Publication number: 20110286312Abstract: [Task] A constant-modulus alloy, which has a low saturation magnetic flux density to provide weakly magnetic properties, a high Young's modulus, a low temperature coefficient of Young's modulus, and high hardness, is provided. A hairspring, a mechanical driving apparatus and a watch and clock, in which the alloy is used, are provided. [Means for Solution] The alloy consists essentially of, by atomic weight ratio, 20 to 40% Co and 7 to 22% Ni, with the total of Co and Ni being 42.0 to 49.5%, 5 to 13% Cr and 1 to 6% Mo, with the total of Cr and Mo being 13.5 to 16.0%, and with the balance being essentially Fe (with the proviso that Fe is present in an amount of 37% or more) and inevitable impurities. The alloy is heated to a temperature of 1100 degrees C. or higher and lower than the melting point, followed by cooling. The alloy is subsequently subjected to repeated wiredrawing and intermediate annealing at 800 to 950 degrees C., thereby forming a wire at a working ratio of 90% or more.Type: ApplicationFiled: November 16, 2009Publication date: November 24, 2011Applicants: SEIKO INSTRUMENTS INC., FOUNDATION: THE RESEARCH INSTITUTE FOR ELECTRIC AND MAGNETIC MATERIALSInventors: Yuetsu Murakami, Koichiro Jujo, Osamu Takahashi, Jun Tsuneyoshi, Ryo Sugawara, Takeshi Takano
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Publication number: 20110272070Abstract: A nickel chromium alloy with 0.4 to 0.6% carbon, 28 to 33% chromium, 15 to 25% iron, 2 to 6% aluminum, up to 2% silicon, up to 2% manganese, up to 1.5% niobium, up to 1.5% tantalum, up to 1.0% tungsten, up to 1.0% titanium, up to 1.0% zirconium, up to 0.5% yttrium, up to 1.0% cerium, up to 0.5% molybdenum, up to 0.1% nitrogen, remainder nickel, has a high oxidation and carburization stability, long-term rupture strength and creep resistance. This alloy is particularly suited as a material for components of petrochemical plants and for parts, for example tube coils of cracker and reformer furnaces, pre-heaters, and reformer tubes, as well as for use for parts of iron ore direct reduction plants.Type: ApplicationFiled: October 13, 2009Publication date: November 10, 2011Applicant: Schmidt + Clemens GmbH + Co. KGInventors: Dietlinde Jakobi, Peter Karduck, Alexander Freiherr Von Richthofen
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Publication number: 20110203707Abstract: A gamma prime nickel-base superalloy and components formed therefrom that exhibit improved high-temperature dwell capabilities, including creep and dwell fatigue crack growth behavior. The superalloy contains, by weight, 10.00 to 22.0% cobalt, 10.0 to 14.0% chromium, 4.0 to 6.0% tantalum, 2.0 to 4.0% aluminum, 2.0 to 6.0% titanium, 1.5 to 5.0% tungsten, 1.5 to 5.0% molybdenum, 1.0 to 3.5% niobium, 0.05 to 0.6% hafnium, 0.02 to 0.10% carbon, 0.01 to 0.40% boron, 0.02 to 0.10% zirconium, the balance essentially nickel and impurities, wherein the titanium:aluminum weight ratio is 0.7 to 1.5. The superalloy is hot worked and heat treated to contain cellular gamma prime precipitates that distort grain boundaries, creating tortuous grain boundary fracture paths that are believed to promote the fatigue crack growth resistance of the superalloy.Type: ApplicationFiled: May 3, 2011Publication date: August 25, 2011Applicant: GENERAL ELECTRIC COMPANYInventors: David Paul Mourer, Kenneth Rees Bain
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Patent number: 7947136Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: GrantFiled: March 16, 2010Date of Patent: May 24, 2011Assignees: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Publication number: 20110097238Abstract: To provide a silver-white copper alloy which represents a silver-white color equivalent to that of nickel silver and is excellent in hot workability and the like. The silver-white copper alloy includes 47.5 to 50.5 mass % of Cu, 7.8 to 9.8 mass % of Ni, 4.7 to 6.3 mass % of Mn, and the remainder including Zn, and the silver-white copper alloy has an alloy composition satisfying relationships of f1=[Cu]+1.4×[Ni]+0.3×[Mn]=62.0 to 64.0, f2=[Mn]/[Ni]=0.49 to 0.68, and f3=[Ni]+[Mn]=13.0 to 15.5 among a content [Cu] mass % of Cu, a content [Ni] mass % of Ni, and a content [Mn] mass % of Mn, and has a metal structure in which ? phases at an area ratio of 2 to 17% are dispersed in an ?-phase matrix. The copper alloy is provided as a hot processing material or continuous casting material formed by performing one or more heat treatments and cold processes on a hot processing raw material formed by performing a hot process on an ingot or a casting raw material obtained by continuous casting.Type: ApplicationFiled: March 9, 2009Publication date: April 28, 2011Applicant: MITSUBISHI SHINDOH CO., LTD.Inventor: Keiichiro Oishi
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Publication number: 20110088819Abstract: An austenitic heat resistant alloy, which comprises by mass percent, C: over 0.02 to 0.15%, Si?2%, Mn?3%, P?0.03%, S?0.01%, Cr: 28 to 38%, Ni: over 40 to 60%, Co?20% (including 0%), W over 3 to 15%, Ti: 0.05 to 1.0%, Zr: 0.005 to 0.2%, Al: 0.01 to 0.3%, N?0.02%, and Mo<0.5%, with the balance being Fe and impurities, in which the following formulas (1) to (3) are satisfied has high creep rupture strength and high toughness after a long period of use at a high temperature, and further it is excellent in hot workability. This austenitic heat resistant alloy may contain a specific amount of one or more elements selected from Nb, V, Hf, B, Mg, Ca, Y, La, Ce, Nd, Sc, Ta, Re, Ir, Pd, Pt and Ag. P?3/{200(Ti+8.5×Zr)} . . . (1), 1.35×Cr?Ni+Co?1.85×Cr . . . (2), Al?1.5×Zr . . . (3).Type: ApplicationFiled: December 13, 2010Publication date: April 21, 2011Applicant: SUMITOMO METAL INDUSTRIES, LTD.Inventors: Hiroyuki SEMBA, Hirokazu OKADA, Masaaki IGARASHI
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Publication number: 20110041967Abstract: Alloys, formed by a eutectic transformation of the type Fe25-35 Ni15-25 Mn30-40 Al10-20 MO-5, are disclosed. M is selected from chromium, molybdenum, carbon and combinations thereof. The alloys have high strength and ductility. The alloys are prepared from readily available transition metals, and can be used in applications where properties similar to steel are necessary or advantageous.Type: ApplicationFiled: February 13, 2009Publication date: February 24, 2011Applicant: THE TRUSTEES OF DARTMOUTH COLLEGEInventors: Ian Baker, Yifeng Liao
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Publication number: 20110011500Abstract: A Ni—Fe—Cr—Mo alloy containing a small amount of Cu and correlated percentages of Nb, Ti and Al to develop a unique microstructure to produce 145 ksi minimum yield strength. The unique microstructure is obtained by special annealing and age hardening conditions, by virtue of which the alloy has an attractive combination of yield strength, impact strength, ductility, corrosion resistance, thermal stability and formability, and is especially suited for corrosive oil well applications that contain gaseous mixtures of carbon dioxide and hydrogen sulfide. The alloy comprises in weight percent the following: 0-15% Fe, 18-24% Cr, 3-9% Mo, 0.05 3.0% Cu, 3.6-6.5% Nb, 0.5-2.2% Ti, 0.05-1.0% Al, 0.005-0.040% C, balance Ni plus incidental impurities and a ratio of Nb/(Al+Ti) in the range of 2.5-7.5. To facilitate formability, the composition range of the alloy is balanced to be Laves phase free.Type: ApplicationFiled: November 18, 2008Publication date: January 20, 2011Applicant: HUNTINGTON ALLOYS CORPORATIONInventor: Sarwan Kumar Mannan
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Publication number: 20100329883Abstract: A gamma prime precipitation-strengthened nickel-base superalloy and method of forging an article from the superalloy to promote a low cycle fatigue resistance and high temperature dwell behavior of the article. The superalloy has a composition of, by weight, 16.0-22.4% cobalt, 6.6-14.3% chromium, 2.6-4.8% aluminum, 2.4-4.6% titanium, 1.4-3.5% tantalum, 0.9-3.0% niobium, 1.9-4.0% tungsten, 1.9-3.9% molybdenum, 0.0-2.5% rhenium, greater than 0.05% carbon, at least 0.1% hafnium, 0.02-0.10% boron, 0.03-0.10% zirconium, the balance nickel and incidental impurities. A billet is formed of the superalloy and worked at a temperature below the gamma prime solvus temperature of the superalloy so as to form a worked article, which is then heat treated above the gamma prime solvus temperature of the superalloy to uniformly coarsen the grains of the article, after which the article is cooled to reprecipitate gamma prime.Type: ApplicationFiled: June 30, 2009Publication date: December 30, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: David Paul Mourer, Kenneth Rees Bain
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Publication number: 20100276041Abstract: Disclosed herein is a method of treating a component comprising solution treating the component for a period of about 4 to about 10 hours at a temperature of about 1750 to about 1850° F.; cooling the component to a temperature of about 1490 to about 1520° F. at an average rate of 1° F./min to about 25° F./min; stabilizing the component at about 1450 to about 1520° F. for a period of from about 1 to about 10 hours; cooling the component to room temperature; precipitation aging the component by heating the component to a first precipitation aging temperature of about 1275 to about 1375° F. for about 3 to about 15 hours; cooling the component at an average rate of 50 to about 150° F./hour to a second precipitation aging temperature of about 1100 to about 1200° F. for a time period of about 2 to about 15 hours; and cooling the component.Type: ApplicationFiled: January 8, 2007Publication date: November 4, 2010Inventors: Ling Yang, Jeffrey Allen Hawk, Robin Carl Schwant
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Publication number: 20100269958Abstract: The present disclosure describes methods of heat treating Ti-based alloys and various improvements that can be realized using such heat treatments. In one exemplary implementation, the invention provides a method of forming a metal member that involves forming an alloy into a utile shape and cooling the alloy from a first temperature above a beta transus temperature of the alloy to a second temperature below the beta transus temperature at a cooling rate of no more than about 30° F./minute. If so desired, the alloy my be treated for a period of about 1-12 hours at about 700-1100° F. Titanium alloys treated according to aspects of the invention may have higher tensile strengths and higher fracture toughness than conventional wrought, mill-annealed Ti 64 alloy.Type: ApplicationFiled: July 6, 2010Publication date: October 28, 2010Applicant: The Boeing CompanyInventor: Robert D. Briggs
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Publication number: 20100265028Abstract: The invention discloses a soft magnetic amorphous alloy and a soft magnetic nanocomposite alloy formed from the amorphous alloy. Both alloys comprise a composition expressed by the following formula: (Fe1-x-yCoxMy)100-a-b-cTaBbNc where, M is at least one element selected from the group consisting of Ni and Mn; T is at least one element selected from the group consisting of Nb, W, Ta, Zr, Hf, Ti, Cr, Cu, Mo, V and combinations thereof, and the content of Cu when present is less than or equal to 2 atomic %; N is at least one element selected from the group consisting of Si, Ge, C, P and Al; and 0.01?x+y<0.5; Q?y?0.4; 1<a<5 atomic %; 10<b<30 atomic %; and 0<c<10 atomic %. A core, which may be used in transformers and wire coils, is made by charging a furnace with elements necessary to form the amorphous alloy, rapidly quenching the alloy, forming a core from the alloy; and heating the core in the presence of a magnetic field to form the nanocomposite alloy.Type: ApplicationFiled: February 21, 2007Publication date: October 21, 2010Applicant: CARNEGIE MELLON UNIVESITYInventors: Michael E. McHenry, Jianguo Long, Vladimir Keylin, David Laughlin, Joseph Huth, Edward Conley
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Publication number: 20100243111Abstract: Disclosed are a high-strength Ni-base alloy, a method of producing the Ni-base alloy, and a method of recovering a member made of a degraded Ni-base alloy. It contains not more than 0.1 wt % C, not more than 50 wt % Fe, not more than 30 wt % Cr, Ti, and at least one of Nb and Al. It has been strengthened by precipitates of a ?? phase (Ni3Al) and/or a ?? phase (Ni3Nb). It contains also a ? phase (Ni3Ti) which is thermodynamically stable in a temperature range of 800° C. to 900° C. When observed a cross-section of the Ni-base alloy, a plurality of nodes exist along each segment connecting two meeting points each of which point is defined by adjacent three crystal grains, and precipitates of the ?? phase and/or the ?? phase in each of crystal grains of the Ni-base alloy have an average particle size of not more than 100 nm.Type: ApplicationFiled: February 18, 2010Publication date: September 30, 2010Applicant: HITACHI, LTD.Inventors: Shinya IMANO, Jun SATO
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Publication number: 20100230017Abstract: A method of making steel wire is described that includes the step of forming a length of wire from a high strength, corrosion resistant alloy. The alloy preferably has the following composition in weight percent. Carbon 0.03 max. Manganese 0.15 max. Silicon 0.15 max. Phosphorus 0.015 max. Sulfur 0.010 max. Chromium 19.00-21.00 Nickel 33.00-37.00 Molybdenum ?9.00-10.50 Titanium 1.00 max. Boron 0.010 max. Iron 1.00 max. The balance of the alloy is cobalt and usual impurities. The wire is annealed at a combination of temperature and time effective to provide a grain size of about ASTM 6 or finer. The annealed wire is then drawn such that the cross-sectional area of the wire is reduced by about 50 to 80%.Type: ApplicationFiled: March 11, 2010Publication date: September 16, 2010Inventors: Richard B. Frank, Lyndon W. Burleson
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Publication number: 20100193083Abstract: A hydrogen-resistant high strength material made of a Ni-based alloy or an Fe—Ni-based alloy includes an aged portion and a hydrogen embrittlement suppressing layer that is to be exposed to hydrogen. The hydrogen embrittlement suppressing layer has a hydrogen embrittlement index of not less than 0.9, wherein the hydrogen embrittlement index is defined as a ratio of an elongation after hydrogen charging in relation to an elongation before hydrogen charging. The aged portion has a tensile strength exceeding 1000 MPa.Type: ApplicationFiled: February 1, 2010Publication date: August 5, 2010Applicant: HITACHI, LTD.Inventors: Hironori KAMOSHIDA, Shinya IMANO
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Publication number: 20100196799Abstract: The present invention relates to the use of the A286 alloy grade for the manufacture of a sheet, optionally surfaced, making it possible to obtain a conducting plate of mono polar or bipolar type for a fuel cell element. The invention also relates to this optional surface treatment process, which comprises a cold-rolling step followed by a continuous annealing step in an oxidizing atmosphere and by an acid pickling step.Type: ApplicationFiled: June 19, 2007Publication date: August 5, 2010Applicants: L'Air Liquide Societe Anonyme Pour L'Etude et L'Exploration DesProcedes George Claude, Arcelormittal-Stainless & Nickel Alloys, Alfa Laval Corporate ABInventors: Eric Claude, Richard Bousquet, Gilles Platen, Claude Roussel
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Publication number: 20100170597Abstract: A metal gasket formed from a suitable iron-nickel chromium alloy includes at least one embossment that exhibits essentially full functional recovery at temperatures exceeding 1000° F. and including in the range of 1100° F. to 1600° F. or more and which is made from sheet material that is work hardened and strengthened by cold rolling, or a combination of cold rolling and precipitation hardening, without any post embossment heat treating that would act to further harden the material. Suitable iron-nickel-chromium alloys include those comprising, by weight, greater than 18% nickel; greater than 14% chrome and 0.1-10% of at least one element selected from the group consisting of Mo, Ti, V, Al, Co, Nb, Ta and Cu, with the balance being substantially Fe, wherein the gasket sheet alloy has a deformed microstructure.Type: ApplicationFiled: March 18, 2010Publication date: July 8, 2010Inventor: Thomas Zurfluh
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Publication number: 20100170596Abstract: An austenitic, substantially ferrite-free steel alloy and a process for producing components therefrom. This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: March 16, 2010Publication date: July 8, 2010Applicants: Boehler Edelstahl GmbH & Co KG, Schoeller-Bleckmann Oilfield Technology GmbHInventors: Gabriele Saller, Herbert Aigner, Josef Bernauer, Raimund Huber
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Publication number: 20100116383Abstract: A heat treatment method for desensitizing a nickel-based alloy with respect to environmentally-assisted cracking, the alloy having the following composition in percentages by weight: C?0.10%; Mn?0.5%; Si?0.5%; P?0.015%; S?0.015%; Ni?40%; Cr=12%-40%; Co?10%; Al?5%; Mo=0.1%-15%; Ti?5%; B?0.01%; Cu?5%; W=0.1%-15%; Nb=0-10%; Ta?10%; the balance being Fe, and inevitable impurities that result from processing, characterized in that the alloy is held at 950° C.-1160° C. in an atmosphere of pure hydrogen or containing at least 100 ppm of hydrogen mixed with an inert gas. A part made of a nickel-based alloy having the composition and that has been subjected to the heat treatment.Type: ApplicationFiled: December 6, 2007Publication date: May 13, 2010Applicant: AREVA NPInventors: Jean-Marc Cloue, Veronique Garat, Rric Andrieu, Julien Deleume
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Publication number: 20100116382Abstract: An austenitic stainless steel excellent in intergranular corrosion resistance and stress corrosion cracking resistance, comprising: C: 0.005 wt % or less; Si: 0.5 wt % or less; Mn: 0.5 wt % or less; P: 0.005 wt % or less; S: 0.005 wt % or less; Ni: 15.0 to 40.0 wt %, Cr: 20.0 to 30.0 wt %, N: 0.01 wt % or less; O: 0.01 wt % or less; and the balance of Fe and inevitable impurities, wherein the content of B included in the inevitable impurities is 3 wt ppm or less.Type: ApplicationFiled: April 24, 2008Publication date: May 13, 2010Applicants: Japan Atomic Energy Agency, Kobelco Research Institute, Inc., Kabushiki Kaisha Kobe Seiko ShoInventors: Kiyoshi Kiuchi, Ikuo Ioka, Chiaki Kato, Nobutoshi Maruyama, Ichiro Tsukatani, Makoto Tanabe, Jumpei Nakayama
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Patent number: 7713364Abstract: A manganese alloy sputtering target characterized in that oxygen is 1000 ppm or less, sulfur is 200 ppm or less and a forged texture is provided, and a method for producing a forged manganese alloy target stably by eliminating the drawbacks of manganese alloy that it is susceptible to cracking and has a low rupture strength. A manganese alloy sputtering target which can form a thin film exhibiting high characteristics and high corrosion resistance while suppressing generation of nodules or particles is thereby obtained.Type: GrantFiled: March 19, 2007Date of Patent: May 11, 2010Assignee: Nippon Mining & Metals Co., Ltd.Inventor: Yuichiro Nakamura
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Publication number: 20100073624Abstract: Disclosed are: a structural member for use in an eyeglass which has a super elastic property and shape memory property while retaining an excellent biocompatibility in addition to the fact that it is N-free, and which also has an excellent cold workability; an eyeglass frame comprising the structural member; and a process for producing the structural member or eyeglass frame. A structural member for an eyeglass comprising a Ti—Nb—Zr alloy which comprises (A) 40 to 75% by weight of Ti, (B) 18 to 30% by weight of Nb, (C) 10 to 30% by weight of Zr and (D) 0.2 to 3.7% by weight of at least one additive metal element selected from the group consisting of Al, In and Ga.Type: ApplicationFiled: June 12, 2006Publication date: March 25, 2010Inventors: Xin Min WANG, Hiroyuki TADA