Gp Ii-iv-vi Compounds Patents (Class 148/DIG63)
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Patent number: 5523241Abstract: Channel stops for MIS infrared photodetector devices in Hg.sub.1-x Cd.sub.x Te by lattice damage (454) between and automatically aligned to MIS gates (408). Also, field plates and guard rings are automatically aligned to MIS gates.Type: GrantFiled: December 21, 1994Date of Patent: June 4, 1996Assignee: Texas Instruments IncorporatedInventors: Chang-Feng Wan, Joseph D. Luttmer, Julie S. England, David E. Fleming
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Patent number: 5454885Abstract: A typical source of cadmium and tellurium is as a by-product of copper mining. Although attempts are made to remove impurities such as copper prior to commercially supplying them for forming material like cadmium telluride, cadmium zinc telluride and cadmium telluride selenide for use as a substrate to support electronic circuitry, processing during formation of the circuitry causes the impurities from the substrate to segregate into the circuitry, resulting in unacceptable electrical performance of the circuitry. A method for purifying the substrate prior to circuitry formation includes forming a sacrificial layer of mercury telluride or mercury cadmium telluride on the substrate, annealing the combination at elevated temperature with an overpressure of mercury and removing the sacrificial layer along with a contiguous portion of the substrate, if desired. The sacrificial layer may be formed by vapor phase type processes or even by liquid phase epitaxy.Type: GrantFiled: December 21, 1993Date of Patent: October 3, 1995Assignee: Martin Marietta CorporationInventors: Gregory K. Dudoff, Karl A. Harris, Lee M. Mohnkern, Richard J. Williams, Robert W. Yanka, Thomas H. Meyers, III
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Patent number: 5028563Abstract: A PbTe/PbEuSeTe buried heterostructure tunable diode laser and array and the method for making the same. The active region layer is buried between two lead salt semiconductor layers containing europium and selenium that are mutually of opposite conductivity type and have substantially the same lattice constant as the active region layer. In addition, the europium and selenium containing lead chalcogenide layers have an energy band gap greater than the active buried layer and an index of refraction less than the active layer. The buried structure enhances electrical and optical confinement, reduces threshold currents, and provides a stable single mode laser. Strontium, calcium or tin may be used in place of the europium. The buried laser and array are produced using a two-step molecular beam epitaxy method.Type: GrantFiled: January 23, 1990Date of Patent: July 2, 1991Assignee: Laser Photonics, Inc.Inventors: Zeev Feit, Douglas Kostyk, Robert J. Woods
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Patent number: 4870027Abstract: In a process for preparing an infrared sentitive photodiode comprising the teps of:(1) forming by vacuum deposition an epitaxial layer of a semiconductor alloy material selected from the group consissting of PbSe, PbTe, PbSe.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y Se, Pb.sub.y Sn.sub.1-y Te, Pb.sub.y Sn.sub.1-y Se.sub.x Te.sub.1-x, Pb.sub.z Cd.sub.1-z Se, Pb.sub.z Cd.sub.1-z Te, and Pb.sub.z Cd.sub.1-x Se.sub.x Te.sub.1-x, wherein 0<x<1, 0<y<1, and 0<z-1, to cover at least a portion of the surface of a substrate composed of an infrared transparent single crystal material selected from the group consisting of(a) alkali metal halides and(b) alkaline earth halides;(2) coating the epitaxial layer of semiconductor alloy material with a thin layer of a lead halide selected from the group consisting of PbCl.sub.2, PbBr.sub.2, PbF.sub.Type: GrantFiled: July 27, 1988Date of Patent: September 26, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: Tak-Kin Chu, Francisco Santiago
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Patent number: 4853339Abstract: In a process of preparing an infrared sensitive photodiode comprising the eps of(1) forming by vacuum deposition an epitaxial layer of a semiconductor alloy material selected from the group consisting of PbS, PbSe, PbTe, PbS.sub.x Se.sub.1-x, PbS.sub.x Te.sub.1-x, PbSe.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y S, Pb.sub.y Sn.sub.1-y Se, Pb.sub.y Sn.sub.1-y Te, Pb.sub.y Sn.sub.1-y S.sub.x, Pb.sub.y Sn.sub.1-y S.sub.x Te.sub.1-x, Pb.sub.y Sn.sub.1-y Se.sub.x Te.sub.1-x, Pb.sub.z Cd.sub.1-z S, Pb.sub.z Cd.sub.1-z Se, Pb.sub.z Cd.sub.1-z Te, Pb.sub.z Cd.sub.1-z S.sub.x Se.sub.1-x, Pb.sub.z Cd.sub.1-z S.sub.x Te.sub.1-x, and Pb.sub.z Cd.sub.1-z Se.sub.x Te.sub.Type: GrantFiled: July 27, 1988Date of Patent: August 1, 1989Assignee: The United States of America as represented by the Secretary of the NavyInventors: Tak-Kin Chu, Francisco Santiago
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Patent number: 4632711Abstract: A zinc selenide or zinc selenide-sulphide epitaxial crystal is grown at a growth temperature of about 180.degree.-320.degree. C. by organometallic chemical vapor deposition by using zinc alkyl and hydrogen selenide and/or hydrogen sulphide. An as-grown crystal presented an n conductivity type low resistivity and exhibited a narrow near-band gap emission peak. Besides a crystal of the same material as the epitaxial layer, crystals of group III-V, group IV, and so forth having the same or similar crystal structure as the epitaxial layer can be used as an underlayer for the growth.Type: GrantFiled: March 1, 1985Date of Patent: December 30, 1986Assignee: Sumitomo Chemical Company, LimitedInventors: Shigeo Fujita, Yoshinobu Matsuda, Akio Sasaki
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Patent number: 4568397Abstract: A method for growing a Group II-VI epitaxial layer on a substrate, said epitaxial layer having an electron mobility greater than 1.5.times.10.sup.5 cm.sup.2 /V-sec at 77.degree. K. and a carrier concentration less than 4.times.10.sup.15 (cm.sup.-3) is described. The method includes the steps of directing a plurality of vapor flows towards the substrate including a Group II metalorganic vapor having a mole fraction in the range of 3.0.times.10.sup.-4 to 4.5.times.10.sup.-4, a Group VI metalorganic vapor having a mole fraction in the range of 2.9.times.10.sup.-3 to 3.5.times.10.sup.-3 and a Group II elemental metal vapor having a mole fraction in the range of 2.6.times.10.sup.-2 to 3.2.times.10.sup.-2. The source of Group II metal is heated to at least 240.degree. C. while radiant energy is directed toward the reactor vessel to warm the zone of the reactor vessel between the Group II metal source and the substrate to at least 240.degree. C.Type: GrantFiled: September 12, 1984Date of Patent: February 4, 1986Assignee: Raytheon CompanyInventors: William E. Hoke, Richard Traczewski, Peter J. Lemonias
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Patent number: 4566918Abstract: A layer of Cd.sub.x Hg.sub.1-x Te is grown on a substrate by growing layers of HgTe t.sub.1 thick, and CdTe t.sub.2 thick alternately. The thicknesses t.sub.1 and t.sub.2 combined are less than 0.5 .mu.m so that interdiffusion occurs during growth to give a single layer of Cd.sub.x Hg.sub.1-x Te. The HgTe layers are grown by flowing a Te alkyl into a vessel containing the substrate and filled with an Hg atmosphere by an Hg bath. The CdTe layers are grown by flowing of Cd alkyl into the vessel where it combines preferentially with the Te on the substrate. Varying the ratio of t.sub.1 to t.sub.2 varies the value of x. Dopants such as alkyls or hydrides of Al, Ga, As and P, or Si, Ge, As and P respectively may be introduced to dope the growing layer.Type: GrantFiled: August 16, 1984Date of Patent: January 28, 1986Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern IrelandInventors: Stuart J. C. Irvine, John B. Mullin, Jean Giess