Abstract: A polyvinyl(tetrazole) is formed by a water-based method. A gas generating composition 12 containing the polyvinyl(tetrazole) is contained within an exemplary gas generator 10. An article or gas generating system 200 incorporates the polyvinyl(tetrazole) therein. A vehicle occupant protection system 180 incorporates the gas generating system 200. An article or substrate 300 containing a coating 302 formed from the product of the water-based method is also described.

Abstract: A method for manufacture and delivery of an emulsion explosive having a discontinuous oxidizer solution phase, a continuous fuel phase, and an emulsifier, the method comprising: (a) providing an emulsion manufacturing system; (b) conveying an oxidizer solution phase to the emulsion manufacturing system at a pre-determined pressure; (c) conveying a fuel phase to the emulsion manufacturing system at a pre-determined pressure; (d) forming an emulsion from the oxidizer solution and the fuel phases using only a portion of the pre-determined pressures so as to provide a usable residual pressure after the formation of the emulsion; and (e) utilizing the residual pressure to non-mechanically deliver the emulsion to a pre-determined location.

Abstract: Provided are energetic materials of low vapor pressure in the form of ionic liquids having fuel and oxidizer ions including, substituted pyridinium or imidazolium cations paired with nitrato-, perchlorato-, or nitramido-based anions, to form such ionic liquids or salts. The salts of the present invention are low melting and have essentially little or no vapor pressure over a wide temperature range. The salts of this invention are thus an important breakthrough since they can serve as high-performing monopropellants which are not complex mixtures and have no vapor toxicity. Such salts also find use as munitions, liquid explosives, reaction media for the synthesis of other high-energy materials, and as plasticizers.

Abstract: A blasting agent comprised of an ammonium nitrate component and an organic carbonaceous fuel component. The ammonium nitrate component includes ammonium nitrate crystals having a particle size of from about 1 to about 500 microns and further includes one or more crystal habit modifiers.

Abstract: A method of transporting a liquid product down a vertical conduit having an inlet provided at the top of the conduit and an outlet provided at the bottom of the conduit, which method comprises feeding the liquid product into the inlet of the conduit and contacting the liquid product with means for dissipating potential energy released by the liquid product as it is transported down the conduit so that turbulence in the liquid product at the outlet of the conduit is reduced.

Abstract: A gas generant for an inflatable restraint device (for example, an airbag system for a vehicle) is a monolithic compressed solid that has a linear burn rate of greater than or equal to about 1.6 inches per second at a pressure of about 3,000 pounds per square inch. The gas generant can be in the form of an annular disk having a plurality of apertures. The gas generant may be substantially free of binder and may have a low initial surface area which progressively increases during burning. The gas generant provides a gas generation profile that improves restraint of vehicle occupants, including those occupants that are out-of-position. Additionally, the shaped gas generant decreases occupant exposure to toxic effluent combustion products and solid respirable particulates.

Abstract: A fluorine gas generating material composition comprises a fluorine bearing material, the fluorine bearing material releasing fluorine gas at a first temperature, and a coruscative material, a reaction temperature of the coruscative material equal to or greater than the first temperature. In some embodiments, the fluorine bearing material is a nickel-based alloy and the coruscative material includes an element from Group IVB, VB or VIB of the periodic table or a transition metal and a carbon-based material. The fluorine gas generating material composition can be incorporated into a product such as a munition, a flare, a shape charge or an impulse device. The disclosed fluorine gas generating material composition can be used to produce work in applications and methods that include point delivery of fluorine gas, explosives related applications, aerospace applications, and applications in the fields of mining and drilling.

Abstract: Disclosed is a group of tertiary amine azides useful as hypergolic fuels for hypergolic bipropellant mixtures. The fuels provide higher density impulses than monomethyl hydrazine (MMH) but are less toxic and have lower vapor pressures that MMH. In addition, the fuels have shorter ignition delay times than dimethylaminoethylazide (DMAZ) and other potential reduced toxicity replacements for MMH.

Abstract: An explosive composition comprising a high density hydrocarbon compound selected from the group consisting of xylitol, sucrose, mannitol, and mixtures thereof and at least one energetic material. The high density hydrocarbon compound and the at least one energetic material form a substantially homogeneous explosive composition. A method of producing an explosive composition that is insensitive to impact is also disclosed.

Abstract: A pressable explosive composition is provided. The composition includes at least 40 weight percent of substantially uncoated fuel particles, a nitramine mechanically blended with the substantially uncoated fuel particles, and a binder coating the nitramine. The binder constitutes about 1 to about 6 weight percent of the pressable explosive composition. Also provided are a pressed thermobaric explosive, weapons containing the pressed thermobaric explosive, and methods for making the composition and thermobaric explosive.

Abstract: A particulate composite fuel of metal preferably of aluminum for a portable heater. The fuel reacts with oxygen in the air, producing heat. The composite fuel may also be flaked aluminum or iron nanopowder. A portable heater having a fuel mass, at least one thermal conductive member, and at least one insulating member. The heater transfers the heat of the oxidation of the metal particulate fuel to a desired mass to be heated, typically a food item. The multilayered heater also acts as a buffer absorbing released heat and releasing the heat to the desired mass at a rate slower than the absorbing.

Abstract: To provide a gas generating composition for air bag which is low in toxicity, large in burning rate, and low in combustion temperature. Gas generating compositions comprising (a) melamine cyanurate or a mixture of melamine cyanurate and nitrogen-containing organic compound and (b) oxygen-containing oxidant, and gas generating compositions comprising (c) binder and (d) additive are provided.

Abstract: An energy-producing material which comprises a chemically uniform polymer material whose monomer units contain an electron donor and an electron acceptor, wherein the stoichiometric ratio of electron donor to electron acceptor is ?1, is proposed.

Abstract: The invention relates to a fuel component for an explosive, in which case the fuel component contains a volume-expanded molecularly dispersed hydrocarbon, and a method for its production. Furthermore, the invention relates to an explosive formed of the fuel component and an oxidizer, an explosive body filled with the explosive as well as an explosion method.

Abstract: A method of manufacturing a pyrotechnic time delay composition includes admixing together a solid oxidizer, a solid fuel and water to form an aqueous slurry. The slurry is transformed into droplets. The droplets are gas-dried to form particles comprising the oxidizer and the fuel, with the particles thus constituting a pyrotechnic delay composition.

Abstract: A method for chemically neutralizing a nitroarene explosive uses a nitroarene hypergol having an ?,?-amine and an accelerant that is applied to the explosive composition to cause ignition of the explosive composition. The method may be used to neutralize active mines.

Abstract: A fluorine gas generating material composition comprises a fluorine bearing material, the fluorine bearing material releasing fluorine gas at a first temperature, and a coruscative material, a reaction temperature of the coruscative material equal to or greater than the first temperature. In some embodiments, the fluorine bearing material is a nickel-based alloy and the coruscative material includes an element from Group IVB, VB or VIB of the periodic table or a transition metal and a carbon-based material. The fluorine gas generating material composition can be incorporated into a product such as a munition, a flare, a shape charge or an impulse device. The disclosed fluorine gas generating material composition can be used to produce work in applications and methods that include point delivery of fluorine gas, explosives related applications, aerospace applications, and applications in the fields of mining and drilling.

Abstract: An energetic composite material is provided that includes inorganic particles and self-assembled monolayers (SAMs) formed on the inorganic particles. The SAMs include multifunctional linking molecules and optionally non-linking molecules. The multifunctional linking molecules have linking functional groups respectively chemically bonding to a corresponding pair of the inorganic particles so that the multifunctional linking molecules interconnect the inorganic particles to one another to form a network of inorganic particles. The optional non-linking molecules include a non-linking functional group chemically bonded to a corresponding one of the inorganic particles. Preferably, the multifunctional linking molecules and/or the optional non-linking molecules are fluorinated. Also preferably, bare aluminum particles are selected as the inorganic particles and are passivated with the SAMs.

Abstract: A powdered fuel includes a powder including a material consisting of particles having a particle size distribution median and other statistical characteristics such that less than about 5% of the particles by weight have a size larger than an explosibility size limit for the material. The particle size distribution median and other statistical characteristics are selected based on the use of the powder as a substantially explosible fuel. In one embodiment the material is biomass. In other embodiments, the material is a metal material, a metal alloy, a metal oxide, a plastic material, or a hydrocarbon-bearing solid. A powdered fuel dispersion includes an oxidizing gas and a powdered fuel dispersed in the oxidizing gas at a ratio such that the powdered fuel dispersion is explosible. Proper control of the moving dispersion produces a stationary deflagrating wave that substantially consumes the fuel to produce energy.

Abstract: The present invention provides a simulant material comprising a primary explosive and a carrier.

Abstract: A pyrotechnic charge for producing IR radiation is proposed, in which a deuterated compound is contained as fuel and/or as oxidizing agent or as fuel, as oxidizing agent and/or as binder. The use of such a pyrotechnic charge leads to a greater selective radiant emission in the ?-band and at the same time to a reduced selective radiant emission in the ?-band, so that the signature of a decoy is adapted to that of an aircraft.

Abstract: Disclosed is a gas generating polymer compound that when irradiated with light or other radiation sources makes a solid to gas phase transition due to chemically catylized degradation, irradiative degradation or both. This provides a low cost, stable and easily manufactured means of gas production. Also disclosed are possible uses for the gas generator such as a low cost micro thruster.

Abstract: The present invention relates to a composition based on 1,1,1,3,3-pentafluorobutane (HFC-365 mfc), that can be used in deposition, cleaning, degreasing and drying applications. Its object is also a fluid for cleaning internal heat-transfer systems. The object of the present invention is also a method for dissolving oil and for cleaning.

Abstract: A propellant charge, a priming cap including the propellant charge and a weapons training system including the priming cap are characterized in that the propellant charge contains a soft friction agent. The propellant charge can contain at least one impact-sensitive explosive substance as a heavy-metal-free priming compound, and the soft friction agent can be marble, calcite, dolomite, soft carbonates and/or mixtures thereof.

Abstract: There is provided a tubular molded article of a gas generating agent consisting of a non-azide-based composition. Both ends of the molded article are squashed. A gas-generating-agent producing process is to obtain a gas generating agent which is molded into the form of a tube both ends of which are squashed in such a way that the tubular molded article of the gas generating agent being in a wetted state is passed through a gap between a pair of molding gears that are rotatable so that each convex tooth of one of the molding gears can face that of the other molding gear, thereafter the molded article is squashed with the convex teeth at predetermined intervals, thereafter the molded article is cut off at the squashed concave parts in such a way as to be folded, and the resultant cut pieces are dried.

Abstract: Propellants and high energy materials compositions containing nano-sized oxidizer and other components. The propellant composition simulates a monopropellant formed by nano-sized propellant ingredients in the form of nano-scale reactors. When forming such monopropellant-like compositions, a protective coating is provided around the reactive ingredient. Coating the metal particles prevents formation of an oxidation layer.

Abstract: An emulsion explosive including a discontinuous phase dispersed in a liquid fuel continuous phase and is provided. The discontinuous phase contains a liquid oxidizer other than an inorganic oxidizer salt. Also provided are articles of manufacture containing the emulsion explosive.

Abstract: A novel compound, used for example, as a gas generating fuel, is defined as a compound having the structural formula of wherein: R4 is a triazine ring; R1 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles; R2 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles; R3 is selected from the group consisting of a tetrazolyl group, CH3, OCH3, —CN, —C2H, NCO, —NHNH2, NO, NO2, OH, Cl, —NHCONH2, —OCOR, NHNO2, substituted tetrazoles, and substituted triazoles.

Abstract: The method for producing a propellant powder (TLP) with a layered grain structure starts with a green powder, which is impregnated in a watery emulsion with an energetic plasticizer and a polymeric deterrent. Propellant powders (TLP) can be produced in industrial quantities by avoiding the dangerous direct introduction of a blasting oil. The propellant powders (TLP) produced in this way have similar characteristics and a similar structure as the known propellant powders (TLP).

Abstract: A compound including at least one copper II complex of a material selected from the group of imidazole and imidazole derivatives is provided for use in a gas generant composition. An associated burn rate enhanced gas generant composition, in addition to such copper complex-containing compound, also includes a nitrogen-containing non-azide fuel. Additionally provided are methods for improving the combustion performance of a non-azide gas generant composition in at least one aspect selected from the group consisting of ignitability, burn rate and burn rate pressure sensitivity, through the addition of such copper complex-containing compound to the non-azide gas generant composition.

Abstract: A solid pyrotechnic composition having a flame temperature and exhibiting ballistic performance comparable to that of black powder, but which does not contain charcoal or sulfur, is provided, as is a method for making such composition. A solid pyrotechnic composition, and method for making the same, which has a flame temperature and exhibits ballistic performance comparable to that of boron/potassium nitrate and that is preferably free of boron is also provided.

Abstract: The present invention relates to a new type of gas generant that may be used in airbag inflators. This new type of gas generant is designed to be flexible such that it may be used in side-curtain airbag applications and other situations where flexibility of the gas generant is required or desirable. The gas generant will generally include a flexible igniter, which in some instances, will be an electrical wire. The gas generant also includes one or more beads that are made from a gas-generating material. Each of the beads has a connector passage that is designed such that the flexible igniter may be strung through the connector passage in the beads. In some instances, the connector passage will be a hole in the bead through which the flexible igniter may be passed.

Abstract: A percussion primer composition including at least one explosive, at least fuel particle having a particle size of about 1500 nm or less, at least one oxidizer, optionally at least one sensitizer, optionally at least one buffer, and to methods of preparing the same.

Abstract: A gas generating composition containing a tetrazole amide as a fuel, 5-formamido-1H-tetrazole for example, and an oxidizer is provided. The gas generant is contained within a gas generator. The gas generator may be contained within a gas generating system such as an airbag inflator or seat belt assembly, or more broadly within a vehicle occupant protection system.

Abstract: The present invention provides a gas generating composition including a basic magnesium carbonate in addition to a fuel and an oxidizing agent, the content of the basic magnesium carbonate being less than 20 mass %.

Abstract: The present invention provides a hybrid inflator including: a pressurized gas and a solid gas generating agent that generates a combustion gas as a gas source, the solid gas generating agent including at least an oxidizing agent and a binder, the pressurized gas including 15 mol % or more of oxygen.

Abstract: The present invention relates to a gas generating composition including a fuel, an oxidizing agent, a binder and an additive, the additive being one or two or more selected from complex basic carbonates represented by Formula (I) or (II) below; M1+M23+CO3 (OH)2 ??(I) M32+M42+CO3(OH)2 ??(II) (In Formula (I), M1+stands for H+, Li+, Na+, K+, or NH4+; M23+ stands for Al3+, Fe3+, Cr3+, Co3+, In3+, Bi3+, Sb3+, B3+, Sc3+, or Ga3+; in Formula (II), M32+ and M42+ are mutually different, each standing for Cu2+, Zn2+, Co2+, Ni2+, Mg2+, Mn2+, Fe2+, or Be2+).

Abstract: A method of decomposing an organic azide is provided and comprises allowing an organic azide to contact a catalytic metal halide, main group halide, mixed metal-main group halide, or mixture thereof. Organic azide fuel sources comprising an organic azide/catalyst combination are also provided.

Abstract: An explosive and method of making comprising one or more fullerene compounds. The fullerenes may be buckyballs, carbon nanotubes, or buckypaper.

Abstract: A novel family of amine azides having a cyclic structure therein is disclosed. These compounds have attractive properties as rocket propellants.

Abstract: This invention comprises a new process for developing high regression rate propellants for application to hybrid rockets and solid fuel ramjets. The process involves the use of a criterion to identify propellants which form an unstable liquid layer on the melting surface of the propellant. Entrainment of droplets from the unstable liquid-gas interface can substantially increase propellant mass transfer leading to much higher surface regression rates over those that can be achieved with conventional hybrid propellants. The main reason is that entrainment is not limited by heat transfer to the propellant from the combustion zone. The process has been used to identify a new class of non-cryogenic hybrid fuels whose regression rate characteristics can be tailored for a given mission. The fuel can be used as the basis for a simpler hybrid rocket design with reduced cost, reduced complexity and increased performance.

Abstract: Methods and apparatuses for gas generation via a water-supplying compound and a water-reactive fuel precursor.

Abstract: This invention comprises a new process for developing high regression rate propellants for application to hybrid rockets and solid fuel ramjets. The process involves the use of a criterion to identify propellants which form an unstable liquid layer on the melting surface of the propellant. Entrainment of droplets from the unstable liquid-gas interface can substantially increase propellant mass transfer leading to much higher surface regression rates over those that can be achieved with conventional hybrid propellants. The main reason is that entrainment is not limited by heat transfer to the propellant from the combustion zone. The process has been used to identify a new class of non-cryogenic hybrid fuels whose regression rate characteristics can be tailored for a given mission. The fuel can be used as the basis for a simpler hybrid rocket design with reduced cost, reduced complexity and increased performance.

Abstract: The reduced toxicity hypergolic bipropellant fuels of the present invention contain a hypergolic fuel and rocket grade hydrogen peroxide oxidizer, preferably HTP. The hypergolic fuel may be a reactive fuel or a catalytic fuel. The rocket grade hydrogen peroxide oxidizer consists of about 90 weight % to about 99 weight % H2O2, more preferably about 94 weight % to 99 weight % H2O2. However, hypergolic ignition may be attained with a H2O2 content as low as 70 weight % for some reactive fuels. The reactive fuel comprises about 6 weight % to 10 weight % reducing agent in a solvent. The catalytic fuel comprises about 6 weight % to 10 weight % catalytic agent in a solvent. The reactive fuels contain ingredients that are intrinsically reactive with rocket grade hydrogen peroxide. Upon contact with rocket grade hydrogen peroxide oxidizer, reactive fuels react vigorously with the hydrogen peroxide resulting in ignition. The catalytic fuels are produced by dissolving a catalytic agent in a solvent.

Abstract: The present invention features methods for preparing stabilized &agr;-AlH3 and &agr;′-AlH3, compositions containing these alane polymorphs, e.g., energetic compositions such as rocket propellants, and methods for using the novel polymorphs as chemical reducing agents, polymerization catalysts, and as a hydrogen source in fuel cells and batteries. The method produces stabilized alane by treating &agr;-AlH3 with an acidic solution that optionally contains a stabilizing agent such as an electron donor, an electron acceptor, or a compound which coordinates the Al3+ ion.

Abstract: A warhead assembly includes a penetrating casing having a forward nose portion and an generally cylindrical aft portion opposite said nose portion. A closure ring is disposed in said aft portion, a vent also being provided in said aft portion. The warhead casing is filled with a predetermined level of explosive material. Preferably the explosive composition contain reduced amounts of explosive material and a strong oxidizer. The warhead assembly possesses superior penetration and blast performance, as well as superior Insensitive Munitions characteristics.

Abstract: Novel catalysts capable of rendering both polar and non-polar organic fuels hypergolic with rocket-grade hydrogen peroxide are disclosed. These catalysts are complexes formed by reacting alkyl-substituted diamines or triamines, with metal salts of an aliphatic carboxylic acid or metal 1, 3-dione chelates. In addition, the use of various acetylenic compounds as stability enhancing additives and/or promoters is described.

Abstract: Liquid monopropellants for passive vehicle restraint systems (e.g., air bags) include an aqueous solution of a water-soluble oxidizer and a water-soluble organic fuel miscible with the oxidizer. The oxidizer is most preferably ammonium nitrate, hydrogen peroxide or nitric acid, while the fuel is a lower alcohol such as methanol, ethanol, propanol or glycerol. The liquid monopropellants will advantageously have an oxidation ratio (OR) of greater than about 0.90.

Abstract: An anhydrous 5-aminotetrazole or “5-AT” based gas generating composition for use in passive restraint devices, such as air bags and a method of preparing the same that is devoid of metal oxides. The gas generating composition includes 5-AT with a blend of oxidizers such as potassium perchlorate and potassium nitrate. This gas generating composition is devoid of metal oxides, such as copper oxide or iron oxide, which form an insoluble slag when ignited. After ignition, the combustion products of the gas generating composition can be filtered with a filter assembly that includes a ceramic blanket. The ceramic blanket preferably includes an aluminum oxide and a silicon oxide.

Abstract: Liquid monopropellants for passive vehicle restraint systems (e.g., air bags) include an aqueous solution of a water-soluble oxidizer and a water-soluble organic fuel miscible with the oxidizer. The oxidizer is most preferably ammonium nitrate, hydrogen peroxide or nitric acid, while the fuel is a lower alcohol such as methanol, ethanol, propanol or glycerol. The liquid monopropellants will advantageously have an oxidation ratio (OR) of greater than about 0.90.