Layer Or Zone Contains An Inorganic Explosive Or Inorganic Thermic Component Patents (Class 149/15)
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Patent number: 12203337Abstract: This invention relates to a thermite reaction charge comprising bismuth oxide and aluminium adapted to react with a reaction rate giving a reaction time of 8 to 15 seconds for a thermite reaction charge of 30 to 100 kg from initialisation of the thermite reaction charge to at least 90% of the thermite reaction charge is reacted, a method for forming a three-phased rock-to-rock barrier by applying the thermite reaction charge and a well barrier formed thereof.Type: GrantFiled: July 1, 2021Date of Patent: January 21, 2025Assignee: INTERWELL P&A ASInventors: Stian Tøndel, Darren James Wilkinson, Torgeir Rusten
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Patent number: 10257924Abstract: Tamper-proof electronic packages and fabrication methods are provided which include a glass enclosure enclosing, at least in part, at least one electronic component within a secure volume, and a tamper-respondent detector. The glass enclosure includes stressed glass with a compressively-stressed surface layer, and the tamper-respondent detector monitors, at least in part, the stressed glass to facilitate defining the secure volume. The stressed glass fragments with an attempted intrusion event through the stressed glass, and the tamper-respondent detector detects the fragmenting of the stressed glass. In certain embodiments, the stressed glass may be a machined glass enclosure that has undergone ion-exchange processing, and the compressively-stressed surface layer of the stressed glass may be compressively-stressed to ensure that the stressed glass fragments into glass particles of fragmentation size less than 1000 ?m with the intrusion event.Type: GrantFiled: December 5, 2017Date of Patent: April 9, 2019Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: James A. Busby, Silvio Dragone, Michael J. Fisher, Michael A. Gaynes, David C. Long, Kenneth P. Rodbell, William Santiago-Fernandez, Thomas Weiss
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Publication number: 20140216288Abstract: Embodiments of energetic devices are provided herein. In some embodiments, an energetic device may include a substrate having a plurality of pores formed in a portion of the substrate; a plurality of carbon nanotubes disposed proximate the plurality of pores such that a reaction within one of the plurality of pores or the plurality of carbon nanotubes initiates a reaction within the other of the plurality of pores or the plurality of carbon nanotubes; a solid oxidizer disposed in the plurality of pores and the carbon nanotubes; and an initiator to initiate a reaction within one of the plurality of pores or the plurality of carbon nanotubes.Type: ApplicationFiled: February 6, 2013Publication date: August 7, 2014Applicant: U.S. Army Research Laboratory ATTN: RDRL-LOC-IInventors: Luke Currano, Madan Dubey, Ronald G. Polcawich
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Publication number: 20140102605Abstract: An energetic composite having a plurality of reactive particles each having a reactive multilayer construction formed by successively depositing reactive layers on a rod-shaped substrate having a longitudinal axis, dividing the reactive-layer-deposited rod-shaped substrate into a plurality of substantially uniform longitudinal segments, and removing the rod-shaped substrate from the longitudinal segments, so that the reactive particles have a controlled, substantially uniform, cylindrically curved or otherwise rod-contoured geometry which facilitates handling and improves its packing fraction, while the reactant multilayer construction controls the stability, reactivity and energy density of the energetic composite.Type: ApplicationFiled: March 25, 2013Publication date: April 17, 2014Applicant: The Johns Hopkins UniversityInventor: The Johns Hopkins University
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Patent number: 8657974Abstract: A gas generator 10 includes an auto-ignition/booster composition 212 that contains a metal chlorate such as potassium chlorate as an oxidizer, a carboxylic acid such as DL-tartaric acid as a primary fuel, a secondary oxidizer such as strontium nitrate, and if desired, a secondary fuel such as 5-aminotetrazole. The auto-ignition/booster composition 212 and a separate provision of ammonium nitrate or phase stabilized ammonium nitrate 228 are provided within a single combustion/decomposition chamber 222 for the production of gas, upon actuation of the gas generator 10. Vehicle occupant protection systems 180, containing the gas generator 10, are also provided.Type: GrantFiled: August 31, 2010Date of Patent: February 25, 2014Assignee: TK Holdings, Inc.Inventors: Brian A. Mayville, Deborah L. Hordos, Graylon K. Williams
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Patent number: 8608878Abstract: A heat generating structure includes a substrate, a coating and a polymeric material. The substrate comprises a first material. The coating comprises a second material, different from the first material that covers at least a portion of the substrate. The coating and substrate, upon being thermally energized to their minimum alloying temperature, react in a first exothermic reaction that is an alloying reaction. The relative quantities of the substrate and coating are such that the first exothermic reaction yields a first amount of exothermic energy that is insufficient to cause self-sustained propagation of the first exothermic reaction. The polymeric material covers substantially all of the substrate and coating, and is different from the first and second materials. The polymeric layer, upon being thermally energized, reacts with at least one of the substrate and coating in a second exothermic reaction.Type: GrantFiled: September 8, 2010Date of Patent: December 17, 2013Assignee: Ensign-Bickford Aerospace & Defense CompanyInventors: Richard M. Kellett, David F. Irwin
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Patent number: 8591676Abstract: A thermite composition includes at least one composite particle having a convoluted lamellar structure having alternating metal oxide layers including a metal oxide and metal layers including a metal capable of reducing the metal oxide. The metal oxide layers and metal layers both have an average thickness of between 10 nm and 1 ?m. Molar proportions of the metal oxide and metal is within 30% of being stoichiometric for a thermite reaction.Type: GrantFiled: November 15, 2012Date of Patent: November 26, 2013Assignees: University of Central Florida Research Foundation, Inc., Lockheed Martin CorporationInventors: Kevin R. Coffey, Edward Dein, Dickson Hugus, Edward Sheridan
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Patent number: 8585839Abstract: A large-scale synthetic method that enables the preparation of nanoenergetic composites in kilogram scales which forms superior materials as compared to the ultra-sonicated nanoenergetic composites and at a lower cost for use in explosive, pyrotechnic, agent defeat, ammunition primers, and propellant applications.Type: GrantFiled: June 27, 2012Date of Patent: November 19, 2013Assignee: The United States of America as Represented by the Secretary of the NavyInventor: Kelvin T. Higa
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Patent number: 8540829Abstract: An electrically initiated security device includes a first energetic sheet, a second energetic sheet, and a corrugated energetic sheet disposed between the first energetic sheet and the second energetic sheet. A first surface of the corrugated energetic sheet defines at least one channel and a second surface of the corrugated energetic sheet defines at least one channel. The electrically initiated security device further includes a first constituent portion disposed in the at least one channel defined by the first surface and a second constituent portion disposed in the at least one channel defined by the second surface. The first constituent portion and the second constituent portion, when mixed, comprise an energetic material.Type: GrantFiled: July 31, 2012Date of Patent: September 24, 2013Assignee: Lockheed Martin CorporationInventors: Toby D. Thomas, James Horning
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Patent number: 8496765Abstract: A system and method correct crystal pulling motor speed deviations in a crystal pulling mechanism. In a first embodiment, a processor implements a tracking filter by estimating new filter state based on previous state and the since-then-travelled nominal distance, and then updating the filter state based on estimation error and filter gains which are also functions of the travelled nominal distance. In a second embodiment, a harmonic tracking filter suppresses residual harmonic modulation and allows a short time constant. Rapid variations of pulling speed may thus be corrected.Type: GrantFiled: September 10, 2009Date of Patent: July 30, 2013Assignees: Sumco Phoenix Corporation, Sumco CorporationInventors: Benno Orschel, Keiichi Takanashi
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Patent number: 8465608Abstract: A method for forming a metastable intermolecular composite (MIC) includes providing a vacuum level of <10?8 torr base pressure in a deposition chamber. A first layer of a first material of a metal that is reactive with water vapor is deposited, followed by depositing a second layer of a second material of a metal oxide on the first layer. The first and second material are capable of an exothermic chemical reaction to form at least one product, and the first and second layer are in sufficiently close physical proximity so that upon initiation of the exothermic reaction the reaction develops into a self initiating chemical reaction. An interfacial region averaging <1 nm thick is formed between the first layer and second layer from a reaction of the first material with water vapor. In one embodiment, the first material is Al and the second material is CuOx.Type: GrantFiled: September 28, 2012Date of Patent: June 18, 2013Assignee: University of Central Florida Research Foundation, Inc.Inventors: Kevin R. Coffey, Edward Alan Dein, Bo Yao
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Patent number: 8409377Abstract: Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.Type: GrantFiled: July 28, 2011Date of Patent: April 2, 2013Assignee: Battelle Energy Alliance, LLCInventors: Michael A. Daniels, Ronald J. Heaps, Eric D. Steffler, W. David Swank
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Publication number: 20130068353Abstract: A thermite composition includes at least one composite particle having a convoluted lamellar structure having alternating metal oxide layers including a metal oxide and metal layers including a metal capable of reducing the metal oxide. The metal oxide layers and metal layers both have an average thickness of between 10 nm and 1 ?m. Molar proportions of the metal oxide and metal is within 30% of being stoichiometric for a thermite reaction.Type: ApplicationFiled: November 15, 2012Publication date: March 21, 2013Applicants: Lockheed Martin Corporation, University of Central Florida Research Foundation, Inc.Inventors: University of Central Florida Research Foundation, Lockheed Martin Corporation
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Patent number: 8336457Abstract: Applicants have discovered that electrostatic discharge (ESD) may, in some circumstances, result in current densities sufficient to ignite unprotected reactive composite materials. They have further discovered that a reactive composite material (RCM) can be protected from ESD ignition without adversely affecting the desirable properties of the RCM by the application of conducting and/or insulating materials at appropriate locations on the RCM. Thus ESD-protected RCM structures can be designed for such sensitive applications as ignition of propellants, generation of light bursts, and structural materials for equipment that may require controlled self-destruction.Type: GrantFiled: June 15, 2006Date of Patent: December 25, 2012Assignee: Nanofoil CorporationInventors: Timothy P. Weihs, Etienne Besnoin, Ramzi Vincent, Somasundaram Valliappan, Ellen Heian, David Van Heerden, Timothy Ryan Rude, Omar Knio, Ronald Spraker, Yuping Lin
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Patent number: 8333854Abstract: A process for the preparation of composite thermite particles, and thermite particles and consolidated objects formed from a plurality of pressed composite particles. The process includes providing one or more metal oxides and one or more complementary metals capable of reducing the metal oxide, and milling the metal oxide and the metal at a temperature below ?50° C., such as cryomilling, to form a convoluted lamellar structure. The average layer thickness is generally between 10 nm and 1 ?m. The molar proportions of the metal oxide and metal are generally within 30% of being stoichiometric for a thermite reaction.Type: GrantFiled: April 18, 2008Date of Patent: December 18, 2012Assignees: University of Central Florida Research Foundation, Inc., Lockheed Martin CorporationInventors: Kevin Coffey, Edward Dein, Dickson Hugus, Edward Sheridan
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Patent number: 8328967Abstract: Sol-gel chemistry is used to prepare igniters comprising energetic multilayer structures coated with energetic materials. These igniters can be tailored to be stable to environmental aging, i.e., where the igniters are exposed to extremes of both hot and cold temperatures (?30 C to 150 C) and both low (0%) and high relative humidity (100%).Type: GrantFiled: May 3, 2011Date of Patent: December 11, 2012Assignee: Lawrence Livermore National Security, LLCInventors: Troy W. Barbee, Jr., Randall L. Simpson, Alexander E. Gash, Joe H. Satcher, Jr.
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Patent number: 8298358Abstract: A metastable intermolecular composite (MIC) and methods for forming the same includes a first material and a second material having an interfacial region therebetween. The first and second material are capable of an exothermic chemical reaction with one another to form at least one product and are in sufficiently close physical proximity to one another so that upon initiation the exothermic reaction develops into a self initiating reaction. At least one of said first and second materials include a metal that is reactive with water vapor at room temperature. The interfacial region averages <2 nm thick, such as <1 nm thick. In one embodiment, the first material is Al and the second material is CuOx.Type: GrantFiled: March 5, 2009Date of Patent: October 30, 2012Assignee: University of Central Florida Research Foundation, Inc.Inventors: Kevin R. Coffey, Edward Dein, Bo Yao
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Patent number: 8007607Abstract: Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.Type: GrantFiled: September 19, 2008Date of Patent: August 30, 2011Assignee: Battelle Energy Alliance, LLCInventors: Michael A. Daniels, Ronald J. Heaps, Eric D Steffler, William D. Swank
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Patent number: 7972453Abstract: A thermobaric munition including a composite explosive material, the composite explosive material having a high-explosive composition, and a detonable energetic material dispersed within the high-explosive composition, the detonable energetic material in the form of a thin film, the thin film having at least one layer composed at least in part by a reducing metal and at least one layer composed at least in part by a metal oxide. A related method includes tailoring the blast characteristics of high explosive composition to match a predetermined time-pressure impulse, the method including disbursing a detonable energetic material having a preselected reaction rate within the high-explosive composition, the detonable energetic material in the form of a thin film, the thin film having at least one layer composed at least in part by a reducing metal and at least one layer composed at least in part by a metal oxide.Type: GrantFiled: June 13, 2006Date of Patent: July 5, 2011Assignee: Lockheed Martin CorporationInventors: Edward W. Sheridan, George D. Hugus, George W. Brooks
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Publication number: 20110132222Abstract: A thermobaric munition including a composite explosive material, the composite explosive material having a high-explosive composition, and a detonable energetic material dispersed within the high-explosive composition, the detonable energetic material in the form of a thin film, the thin film having at least one layer composed at least in part by a reducing metal and at least one layer composed at least in part by a metal oxide.Type: ApplicationFiled: June 13, 2006Publication date: June 9, 2011Applicant: LOCKHEED MARTIN CORPORATIONInventors: Edward W. Sheridan, George D. Hugus, George W. Brooks
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Patent number: 7955451Abstract: A munition is described including a reactive fragment having an energetic material having a least one layer of a reducing metal or metal hydride and at least one layer of a metal oxide dispersed in a binder material. A method is also described including forming a energetic material; including combining the energetic material having a least one layer of a reducing metal or metal hydride and at least one layer of a metal oxide with a polymeric binder material to form a mixture; and shaping the mixture to form a reactive fragment. The munition may be in the form of a warhead, and the reactive fragment may be contained within a casing of the warhead.Type: GrantFiled: February 22, 2007Date of Patent: June 7, 2011Assignee: Lockheed Martin CorporationInventors: George D. Hugus, Edward W. Sheridan
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Patent number: 7951247Abstract: Sol-gel chemistry is used to prepare igniters comprising energetic multilayer structures coated with energetic booster materials. These igniters can be tailored to be stable to environmental aging, i.e., where the igniters are exposed to extremes of both hot and cold temperatures (?30 C to 150 C) and both low (0%) and high relative humidity (100%).Type: GrantFiled: September 30, 2002Date of Patent: May 31, 2011Assignee: Lawrence Livermore National Security, LLCInventors: Troy W. Barbee, Jr., Randall L. Simpson, Alexander E. Gash, Joe H. Satcher, Jr.
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Patent number: 7896988Abstract: A charge system for destroying chips on a circuit board is provided. The charge system has a first substrate having a number of recesses formed therein with each of the recesses having a housing disposed therein. A high density charge is disposed within the housing. A number of recesses are formed within the high density charge. A number of low density charges are disposed within each of the recesses formed within the high density charge. A second substrate is located proximate to the first substrate. The low density charge and the high density charge are structured to destroy the second substrate after ignition. A method of destroying chips is also provided.Type: GrantFiled: June 15, 2007Date of Patent: March 1, 2011Assignee: Spectre Enterprises, Inc.Inventor: Jonathan Mohler
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Publication number: 20100193093Abstract: A process for the preparation of composite thermite particles, and thermite particles and consolidated objects formed from a plurality of pressed composite particles. The process includes providing one or more metal oxides and one or more complementary metals capable of reducing the metal oxide, and milling the metal oxide and the metal at a temperature below ?50° C., such as cryomilling, to form a convoluted lamellar structure. The average layer thickness is generally between 10 nm and 1 ?m. The molar proportions of the metal oxide and metal are generally within 30% of being stoichiometric for a thermite reaction.Type: ApplicationFiled: April 18, 2008Publication date: August 5, 2010Applicant: LOCKHEED MARTIN CORPORATIONInventors: Kevin R. Coffey, Edward Dein, Dickson Hugus, Edward Sheridan
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Patent number: 7749345Abstract: A fluorine gas generating material composition comprises a fluorine bearing material, the fluorine bearing material releasing fluorine gas at a first temperature, and a coruscative material, a reaction temperature of the coruscative material equal to or greater than the first temperature. In some embodiments, the fluorine bearing material is a nickel-based alloy and the coruscative material includes an element from Group IVB, VB or VIB of the periodic table or a transition metal and a carbon-based material. The fluorine gas generating material composition can be incorporated into a product such as a munition, a flare, a shape charge or an impulse device. The disclosed fluorine gas generating material composition can be used to produce work in applications and methods that include point delivery of fluorine gas, explosives related applications, aerospace applications, and applications in the fields of mining and drilling.Type: GrantFiled: August 21, 2008Date of Patent: July 6, 2010Assignee: Lockheed Martin CorporationInventor: James R. Wood
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Publication number: 20100071813Abstract: Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.Type: ApplicationFiled: September 19, 2008Publication date: March 25, 2010Applicant: BATTELLE ENERGY ALLIANCE, LLCInventors: MICHAEL A. DANIELS, RONALD J. HEAPS, ERIC D. STEFFLER, W. DAVID SWANK
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Publication number: 20090178741Abstract: Novel reactive composite materials and associated methods for making the same which are pertinent to numerous new or improved applications. The method for making the reactive composite materials utilizes mechanical deformation to manufacture such materials with controlled, predictable characteristics. In the first deformation step, an assembly of reactive layers and/or particles is plastically deformed to reduce its cross sectional area by one-half or more. Portions of the deformed sheets are stacked or bent into a new assembly, and the new assembly is then deformed. The steps of assembly and deformation are repeated a sufficient number of times that the resulting materials are only locally layered but have relatively uniform reaction velocity and heat generating characteristics predictable by stochastic models derived herein.Type: ApplicationFiled: January 12, 2009Publication date: July 16, 2009Applicant: Reactive Nanotechnologies, Inc.Inventors: Yuwei Xun, David Lunking, Etienne Besnoin, David Van Heerden, Timothy P. Weihs, Omar M. Knio
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Patent number: 6881284Abstract: A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.Type: GrantFiled: October 19, 2001Date of Patent: April 19, 2005Assignee: The Regents of the University of CaliforniaInventors: Daniel M. Makowiecki, Robert S. Rosen
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Publication number: 20040060625Abstract: Sol-gel chemistry is used to prepare igniters comprising energetic multilayer structures coated with energetic booster materials. These igniters can be tailored to be stable to environmental aging, i.e., where the igniters are exposed to extremes of both hot and cold temperatures (−30 C to 150C) and both low (0%) and high relative humidity (100%).Type: ApplicationFiled: October 1, 2002Publication date: April 1, 2004Applicant: The Regents of the University of California.Inventors: Troy W. Barbee, Randall L. Simpson, Alexander E. Gash, Joe H. Satcher
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Patent number: 6276276Abstract: A thin-film optical initiator having an inert, transparent substrate, a reactive thin film, which can be either an explosive or a pyrotechnic, and a reflective thin film. The resultant thin-film optical initiator system also comprises a fiber-optic cable connected to a low-energy laser source, an output charge, and an initiator housing. The reactive thin film, which may contain very thin embedded layers or be a co-deposit of a light-absorbing material such as carbon, absorbs the incident laser light, is volumetrically heated, and explodes against the output charge, imparting about 5 to 20 times more energy than in the incident laser pulse.Type: GrantFiled: August 19, 1999Date of Patent: August 21, 2001Assignee: The United States of America as represented by the United States Department of EnergyInventor: Kenneth L. Erickson
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Patent number: 6165307Abstract: A multi-component three dimensional energetic device and the method of maacturing it. The method includes the steps of forming a quantity of an energetic material into a plurality of sheets having relatively no appreciable thickness, and then cutting at least one required shape from the surface of a portion of each of the plurality of sheets to define an opening for at least one inlay of a different material. An inlay of the different material is placed in the openings to form a plurality of stackable shapes that are then bonded together to form the multi-component three dimensional energetic device. The preferred embodiment includes forming the inlay from an energetic material that is different from the sheet energetic material. Optionally a bonding agent may be admixed with at least one of the materials to facilitate bonding to form the device. The bonding agent may or may not be an energetic material, as desired.Type: GrantFiled: March 5, 1998Date of Patent: December 26, 2000Assignee: The United States of America as represented by the Secretary of the ArmyInventors: David Fair, Eileen Heider, Mark J. Mezger
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Patent number: 6053108Abstract: A caseless propellant charge structure and sensitizer structure for safe ignition and cleaner gas generation. The sensitizer structure is comprised of a sensitizer material which is encapsulated in a protective binder material. The protective binder layer is broken during desired ignition in the combustion chamber. Meanwhile the propellant structure comprises an oxidizer rich layer which also contains fuel and a propellant layer. The oxidizer rich layer is adjacent the sensitizer structure in the strip assembly. The oxidizer rich layer allows ignition while foregoing the need for high concentration of oxidizer throughout the propellant structure thus reducing the mass of solids generated from the oxidizer combustion.Type: GrantFiled: January 13, 1998Date of Patent: April 25, 2000Assignee: Senco Products, Inc.Inventor: David L. Remerowski
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Patent number: 5970877Abstract: A coating for a gun propellant powder wherein the graphite commonly used to coat a gun propellant powder is totally or partially replaced with molybdenum disulfide in an amount equal to or less than five tenths percent by weight of the propellant powder.Type: GrantFiled: March 2, 1998Date of Patent: October 26, 1999Inventor: Jerry Hensler
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Patent number: 5773748Abstract: A cartridge primer which utilizes an explosive that can be designed to become inactive in a predetermined period of time: a limited-life primer. The explosive or combustible material of the primer is an inorganic reactive multilayer (RML). The reaction products of the RML are sub-micron grains of non-corrosive inorganic compounds that would have no harmful effects on firearms or cartridge cases. Unlike use of primers containing lead components, primers utilizing RML's would not present a hazard to the environment. The sensitivity of an RML is determined by the physical structure and the stored interfacial energy. The sensitivity lowers with time due to a decrease in interfacial energy resulting from interdiffusion of the elemental layers. Time-dependent interdiffusion is predictable, thereby enabling the functional lifetime of an RML primer to be predetermined by the initial thickness and materials selection of the reacting layers.Type: GrantFiled: June 14, 1995Date of Patent: June 30, 1998Assignee: Regents of the University of CaliforniaInventors: Daniel M. Makowiecki, Robert S. Rosen
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Patent number: 5670740Abstract: A gas generant charge comprises a heterogeneous mixture of between about 80 and about 95 wt % of a first gas generant composition 1) and between about 5 and about 20 wt % of a second gas generant composition 2), based on the total weight of 1) plus 2). The first gas generant composition 1) comprises between about 20 and about 40 wt % fuel A) and between about 20 and about 60 wt % oxidizer B). Between about 50 and about 85 wt % of the fuel A) is a triazole or tetrazole compound A.sup.1), and between about 15 and about 50 wt % of the fuel is, a water-soluble fuel A.sup.2). At least about 20 wt % of the oxidizer B), up to 100%, a transition metal oxide B.sup.1); balance of the oxidizer is selected from the group B.sup.2) consisting of alkali and/or alkaline earth metal nitrates, chlorates or perchlorates.Type: GrantFiled: October 6, 1995Date of Patent: September 23, 1997Assignee: Morton International, Inc.Inventors: Michael W. Barnes, Robert D. Taylor, Christopher Hock, Michael P. Jordan, Matthew A. Cox, Alan J. Ward
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Patent number: 5606146Abstract: A method for providing chemical energy and energetic compositions of matter consisting of thin layers of substances which will exothermically react with one another. The layers of reactive substances are separated by thin layers of a buffer material which prevents the reactions from taking place until the desired time. The reactions are triggered by an external agent, such as mechanical stress or an electric spark. The compositions are known as metastable interstitial composites (MICs). This class of compositions includes materials which have not previously been capable of use as energetic materials. The speed and products of the reactions can be varied to suit the application.Type: GrantFiled: July 1, 1993Date of Patent: February 25, 1997Assignee: The United States of America as represented by the United States Department of EnergyInventors: Wayne C. Danen, Joe A. Martin
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Patent number: 5534090Abstract: A novel dosimeter capsule for indicating the condition of the solid propellant contained within a rocket motor to provide a measure of the remaining service life of the motor is described, which comprises a sealed expandable container and a portion of the solid propellant sealed therein and sized to fill the available volume within the container, the propellant portion containing a smaller concentration of chemical stabilizer than that which characterizes the solid propellant contained in the rocket motor, so that the propellant portion will deteriorate at a predictably faster rate than the rocket motor propellant, resulting in an increase of pressure within the expandable container of evolved gaseous products of the decomposition of the propellant portion and an accompanying bulge or protrusion of the container from its receptacle on the rocket motor casing corresponding to the increased internal pressure.Type: GrantFiled: December 20, 1984Date of Patent: July 9, 1996Assignee: The United States of America as represented by the Secretary of the Air ForceInventor: Richard B. Leining
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Patent number: 5507890Abstract: The present invention resides in a body of material which is ignitable to generate a gas for inflating an air bag. The body of material comprises at least two layers of ignitable gas generating material which are pressed together. One of the layers comprises a nitrogen generating composition which is easily ignited and burns rapidly. The other of the layers comprises a nitrogen generating composition which is less easily ignited and burns less rapidly than the one layer.Type: GrantFiled: May 17, 1994Date of Patent: April 16, 1996Assignee: TRW Inc.Inventors: Timothy A. Swann, Eldron L. Boehmer
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Patent number: 5505799Abstract: A complex modulated structure of reactive elements that have the capability of considerably more heat than organic explosives while generating a working fluid or gas. The explosive and method of fabricating same involves a plurality of very thin, stacked, multilayer structures, each composed of reactive components, such as aluminum, separated from a less reactive element, such as copper oxide, by a separator material, such as carbon. The separator material not only separates the reactive materials, but it reacts therewith when detonated to generate higher temperatures. The various layers of material, thickness of 10 to 10,000 angstroms, can be deposited by magnetron sputter deposition. The explosive detonates and combusts a high velocity generating a gas, such as CO, and high temperatures.Type: GrantFiled: September 19, 1993Date of Patent: April 9, 1996Assignee: Regents of the University of CaliforniaInventor: Daniel M. Makowiecki
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Patent number: 5501751Abstract: The present invention is directed to the encapsulation of pyrophoric materials in a high temperature resistant membrane having at least one perforation which allows air to contact the pyrophoric material. By controlling the accessibility of the pyrophoric material to the surrounding air, it is possible to reduce the kinetics of the oxidation reaction without affecting the thermodynamics of the reaction. This results in a product that demonstrates a lower peak temperature, longer dwell time at the lower temperature and, in most cases, an increase in the total heat energy output in comparison to an identical pyrophoric material that is not so encapsulated.Type: GrantFiled: December 8, 1994Date of Patent: March 26, 1996Assignee: Alloy Surfaces Co. Inc.Inventors: Alfonso L. Baldi, Frank J. Clark
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Patent number: 5467714Abstract: High reaction temperature explosive compositions which provide enhanced air blast and extended reaction times are disclosed. The explosive compositions include a separate acceptor phase and a separate explosive phase. The acceptor phase contains a halogenated polymer and a reactive metal which are capable of reacting at high temperature and pressure. The explosive phase includes a nonmetallized explosive. Suitable explosives produce a detonation pressure in excess of 200 kilobars at the Chapman-Jouget (C-J) condition.In the explosive compositions disclosed herein, at least a portion of the explosive phase surrounds the acceptor phase. In this configuration, detonation of the explosive phase exposes the acceptor phase to high temperatures and pressures which permit the metal and halogenated polymer to efficiently react and produce even greater temperatures and pressures.Type: GrantFiled: December 16, 1993Date of Patent: November 21, 1995Assignee: Thiokol CorporationInventors: Gary K. Lund, Paul C. Braithwaite
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Patent number: 5464699Abstract: A pyrophoric coating formed by leaching aluminum from an aluminide coated web in which the aluminide coating was formed on or into the web by an exothermic and diffusion reaction of a powder containing aluminum and chromium with or without a transition metal selected from the group consisting of iron, nickel or cobalt and in which the weight ratio of chromium to aluminum is at least 1:50 but no more than about 1:4.Type: GrantFiled: November 15, 1993Date of Patent: November 7, 1995Assignee: Alloy Surfaces Co. Inc.Inventor: Alfonso L. Baldi
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Patent number: 5458912Abstract: Disclosed is a method of forming tamper-proof coatings on electronic devices. The method comprises applying a coating of a silica precursor resin and a filler onto the electronic device, wherein the filler is one which reacts in an oxidizing atmosphere to liberate enough heat to damage the electronic device. The coated electronic device is then heated at a temperature sufficient to convert the silica precursor resin to a silica containing ceramic matrix.Type: GrantFiled: August 9, 1993Date of Patent: October 17, 1995Assignee: Dow Corning CorporationInventors: Robert C. Camilletti, Loren A. Haluska, Keith W. Michael
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Patent number: 5454363Abstract: Proposed is a compact high-temperature exothermic device by utilizing the heat of reaction of a reactive metal powder, e.g., titanium and zirconium, and a powder of boron and/or carbon mixed together in about the stoichiometric proportion forming a calorific mixture. The exothermic device is constructed by filling a hermetically sealable container of a metallic or ceramic material with the calorific mixture which is contacted at one end portion with an ignition means to cause ignition of the calorific mixture by supplying, for example, electric energy. The ignition means can be hermetically sealed in the container and the electric circuit of the ignition means comprises a switching means with a coil spring consolidated with a solder alloy in a constricted state in such a fashion that, when the solder alloy is melted down by heating from outside, the coil spring is released to close the electric circuit by bringing a contact point held thereon into contact with a couterpart contact point.Type: GrantFiled: October 14, 1994Date of Patent: October 3, 1995Assignee: Japan as represented by Director General of Agency of Industrial Science and TechnologyInventor: Nobuhiro Sata
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Patent number: 5403035Abstract: The present invention provides a cellulose-based propellant for generating gas to inflate an air bag in a vehicle occupant restraint system. In one embodiment, the propellant includes cellulose in combination with an alkali nitrate oxidizer, such a potassium nitrate, and Kaolinite clay for increasing the viscosity of the residue resulting from combustion of the propellant. Also included in the present invention is a method for producing the propellant and incorporating the propellant into an air bag restraint system. In one embodiment of the method, cellulose fiber in the form of pulp board or wood pulp is soaked in a solution that includes an oxidizing agent to produce a slurry, the slurry is then formed into a sheet of a desired density, the sheet is then at least partially dried, if required, and then formed into a desired shape for incorporation into a vehicle restraint system that employs an air bag.Type: GrantFiled: June 1, 1992Date of Patent: April 4, 1995Assignee: OEA, Inc.Inventor: Brian K. Hamilton
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Patent number: 5266132Abstract: A method for providing chemical energy and energetic compositions of matter consisting of thin layers of substances which will exothermically react with one another. The layers of reactive substances are separated by thin layers of a buffer material which prevents the reactions from taking place until the desired time. The reactions are triggered by an external agent, such as mechanical stress or an electric spark. The compositions are known as metastable interstitial composites (MICs). This class of compositions includes materials which have not previously been capable of use as energetic materials. The speed and products of the reactions can be varied to suit the application.Type: GrantFiled: October 8, 1991Date of Patent: November 30, 1993Assignee: The United States of America as represented by the United States Department of EnergyInventors: Wayne C. Danen, Joe A. Martin
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Patent number: 5090322Abstract: A micro pyrotechnic train is formed from a reactive laminate comprised by a plurality of thin films of an electron acceptor material (9) and an electron donor material (10) alternately layered upon a substrate layer by vacuum deposition. The thus deposited films are then removed from selected areas by etching, using standard printed circuit board techniques, to leave a desired network of reaction progression paths (2). The thickness of the films is of substantially molecular order to maximize molecular intermingling between them, and the number of films is selected to ensure a reliable burning characteristic. Ignition of the conjoint films at any selected location initiates a self-sustaining exothermic reaction which progresses laterally along the film interfaces.In further aspects the reactive laminate is applicable as an infra-red emitting coating and as a flash transmitter.Type: GrantFiled: June 22, 1987Date of Patent: February 25, 1992Assignee: The Secretary of State of Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britian and Northern IrelandInventor: Frederick G. Allford
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Patent number: 5049212Abstract: The invention consists of a class of high energy explosive yield enhancers reated through the use of microencapsulation techniques. The microcapsules consist of combinations of highly reactive oxidizers that are encapsulated in either passivated inorganic fuels or inert materials and inorganic fuels. Depending on the application, the availability of the various oxidizers and fuels within the microcapsules can be customized to increase the explosive yield or modify other characteristics of high explosives. The microcapsules prevent premature reaction of the component oxidizers and inorganic fuel to allow their use in munitions and propellant applications. The physical stability of the microcapsules, in combination with epoxies, plastics, and composites, also permits microcapsules to be included in warhead structural components.Type: GrantFiled: March 27, 1991Date of Patent: September 17, 1991Assignee: The United States of America as represented by the Secretary of the NavyInventor: Joseph F. Colick
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Patent number: 5043030Abstract: The invention is directed to a primer/detonator acceptable for use in an automobile air bag system.Type: GrantFiled: October 5, 1990Date of Patent: August 27, 1991Assignee: Breed Automotive Technology, Inc.Inventor: Coodly P. Ramaswamy
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Patent number: 4895609Abstract: Metals are made pyrophoric by diffusing aluminum or zinc into them and then leaching it out, or by reacting with aluminum and then leaching aluminum out. Powdered aluminum and powdered nickel, iron or cobalt, can thus be carried on an elongated support web and reacted by heating for a few seconds to a few minutes, after which leaching will provide elongated pyrophoric foil suitable for decoying heat-seeking missile.Type: GrantFiled: June 10, 1988Date of Patent: January 23, 1990Assignee: Alloy Surfaces Company, Inc.Inventor: Alfonso L. Baldi