Abstract: 1. A method for the preparation of difluoraminoalkyl acrylates and methacrylates in which there are at least two difluoramino groups present and the alkyl contains two to eighteen carbon atoms which comprises reacting in the temperature range of about 0.degree. C. up to the reflux temperature of the reaction mixture a member from the class consisting of a difluoraminoalkyl .alpha.,.beta.-dibromopropionate and difluoraminoalkyl .alpha.,.beta.-dibromoisobutyrate in the presence of a compound having the formula ##EQU1## wherein R is a member from the group consisting of alkoxy one to four carbon atoms, alkyl one to eight carbon atoms, phenyl, alkylphenyl in which the alkyl portion contains from one to eight carbon atoms, phenoxy and alkylphenoxy in which the alkyl portion contains from one to eight carbon atoms.

Abstract: Particulate high explosives containing ammonium nitrate and organic or inorganic ammonium nitrate sensitizers are disclosed along with methods of producing the same. The sensitizers, comprising sulfur, metals, carbonaceous material and combinations of these, are dispersed throughout each particle in intimate association with the ammonium nitrate by suspension in a layer of ammonium nitrate-calcium sulfate reaction product.

Abstract: Disclosed is a solid propellant composition in the form of a munition which comprises an inorganic acid salt in intimate combination with the reaction product of a carboxyl bearing polymer and a glycidyl thioether. The composition is prepared by mixing the oxidizer, carboxyl containing polymer, and glycidyl thioether and curing the resulting mixture to a coherent grain. Unexpectedly, an excellent cure is achieved in the presence of the oxidizer.

Abstract: A flame-explosion couple is disclosed which upon ignition burns for a period of time in a relatively stable manner and thereafter explodes to produce fragments which continue to burn for a further period of time. The composition may comprise from 40 to 89 percent by weight of a volatile liquid fuel, from 10 to 50 percent by weight of a secondary explosive or strong metal salt oxidizer and from 0.5 to 5 percent by weight of an explosive primer. It is usually desirable to incorporate a gellant in the composition to give it a jellylike consistency of a desired viscosity. The composition may optionally contain combustible metal powders and combustible polymers.

Abstract: A propellant formulation employing an energetic plasticizer, a solid oxidr, a crosslinking agent, a curing catalyst, a ballistic modifier, and an acrylate - acrylic acid prepolymer binder comprised of about 95 parts of an acrylate selected from petrin acrylate and 2,2' dinitropropyl acrylate and of about 5 parts of acrylic acid has a low signature (i.e., propellants whose exhaust does not cause serious attenuation of visible, infrared, or radar radiation) while retaining the preferred specific impulse, mechanical properties, processing properties, and other properties of importance in solid propellants.

Abstract: A blue-burning pyrotechnic tracer mix which provides a smoke trail even ar the blue flame is no longer visible to thus extend the visible range of the projectile in which the mixture is employed, the pyrotechnic mixture comprising by weight percent: 6-10% potassium perchlorate, 11-18% magnesium, 10-20% cupric chloride anhydrous, 35-45% barium nitrate, 12-18% hexachlorobenzene, 5-10% sulfur.

Abstract: 1. An explosive slurry composition comprising a substantially saturated solution of ammonium nitrate, and suspended solids in said solution to form said slurry, said solids being comprised of at least 50 parts by weight of ammonium nitrate, and not more than 50 parts by weight of finely divided metallic aluminum of character such as to increase the sensitivity of said composition to detonation, the total nitrate comprising at least 50% of the total composition, said composition including water comprising at least 3 percent by weight of the total composition. 2. An ammonium nitrate explosive composition consisting essentially of particulate ammonium nitrate in admixture with an aqueous solution saturated with respect to ammonium nitrate, and with up to 35 per cent by weight of an inorganic sensitizer which taken alone is a stable solid at a temperature of at least 100.degree.C., the amount of water being from 3 to 25 per cent by weight of the total composition. 3.

Abstract: This invention relates to a method of charging drill holes for blasting, according to which method solid and liquid components of an explosive substantially each of them separately but simultaneously are blown or pumped, respectively, through its individual hose channel into the drill hole within which the components are intermixed as a result of the simultaneous pumping and blowing operations. The invention relates also to various recipes for preparation of explosives possessing properties especially fitted for the method in consideration. The invention also comprises an apparatus suited for carrying out the method.

Abstract: A friction igniter assembly for high altitude operation having a pull wire oated with a scratch sensitive composition which is moved through a chlorate composition. The scratch sensitive composition containing red phosphorus reacts with the chlorate to provide a flash which transfers ignition to an adjacent boron-lead dioxide composition. The boron-lead dioxide composition is the main igniting charge and provides an intense output of heat in a very short time for igniting a pyrotechnic composition.

Abstract: A stable, gelled, water-bearing explosive composition and a process for making same. The composition comprises at least one water-soluble inorganic oxygen releasing salt; at least one fuel; water; and at least one gum selected from the group consisting of galactomannans and xanthans crosslinked in situ with a crosslinking agent comprising a redox system which system comprises at least one arsenious compound.

Abstract: A gas-generating composition comprising an oxidizer, a non-metal, preferably organic, fuel component, and a metal fuel staple component of a particular size.

Abstract: Slurry blasting compositions of low water content and high density, including substantial proportions of calcium nitrate as an oxidizer component, can be sensitized in various ways to produce economical explosive compositions. Sensitizers may include aluminum powder, granular explosives such as smokeless powder, TNT, etc.; a particularly preferred sensitizer or fuel is ethylene glycol. Solid carbonaceous fuels and conventional thickeners may be added. The calcium nitrate may be produced directly from burned lime with nitric acid and/or other nitrates.