With Carbon And Sulfur Patents (Class 149/72)
  • Patent number: 7981225
    Abstract: A lead-free primer energetic composition including Cyanuric Triazide (60%), Tetracene (5%), Barium Nitrate (20%) and Antimony Trisulfide (15%) is produced. The lead-free primer energetic composition is used to construct a primary detonator including a transfer charge of Cyanuric Triazide, which produces a further initiation train that may subsequently detonate a secondary explosive, i.e., HDX, RDX, or a pyrotechnic device.
    Type: Grant
    Filed: October 19, 2006
    Date of Patent: July 19, 2011
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Neha Mehta, Gartumg Cheng, Emily A. Cordaro, Neelam Mehta, Carl Hu, Robert Lateer, Daniel Stec, III, Raja G. Duddu, Paritosh R. Dave, Kathy Yang
  • Patent number: 6334961
    Abstract: Solid gas generant compositions produce low particulates (e.g., condensed ash) when ignited. The solid gas generant compositions most preferably include a nitramine, at least one oxidizer selected from nitrates of strontium or cerium, in admixture with or without potassium perchlorate, and a binder. Graphite may optionally be employed. The gas generant compositions are usefully employed in inflatable vehicle occupant passive restraint systems (e.g., air bag systems).
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: January 1, 2002
    Assignee: Atlantic Research Corporation
    Inventors: Brian K. Wheatley, Norman H. Lundstrom, Robert D. Lynch, R. Stephen Scheffee, James D. Martin
  • Patent number: 5670098
    Abstract: A continuous process of manufacturing black powder and black powder substitute using a twin screw extruder is disclosed. Guar gum mixed with the composition at a concentration in the range from 0.05% to 0.5%, by weight, dramatically reduced the friction in the dies and permitted extrusion of the powder at much lower water levels. Different size dies used in combination with face cutting of the extruded strands produce various sized granules. The process can be operated remotely and automatically. The process reduces the number of buildings, equipment and personnel required to manufacture black powder or black powder substitute. The process produces more uniform and reproducible particle sizes.
    Type: Grant
    Filed: August 20, 1996
    Date of Patent: September 23, 1997
    Assignee: Thiokol Corporation
    Inventors: David R. Dillehay, David W. Turner, Jim Blackwell
  • Patent number: 5051143
    Abstract: A gas generating grain has a water-based particulate booster coating thereon. The coating comprises an alkali metal azide, a water-soluble inorganic oxidizer in approximately a stoichiometric ratio of oxidizer to azide, and a nucleating amount of a small particle size metal oxide. The inorganic oxidizer is potassium perchlorate. A preferred metal oxide is selected from the group consisting of iron oxide, nickel oxide and aluminum oxide. The coating is applied to the grain from a water slurry and dried.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: September 24, 1991
    Assignee: TRW Vehicle Safety Systems Inc.
    Inventor: George W. Goetz
  • Patent number: 4933029
    Abstract: A free-flowing granular explosive comprising of an oxidizing salt, fuel, a hydrophilic thickener and a hydrophobic compound. Upon water impingement the hydrophobic compound repels water from the surface of the oxidizing salt while the hydrophilic thickener simultaneously forms a water-resistant barrier.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: June 12, 1990
    Inventor: John P. Sheeran
  • Patent number: 4780156
    Abstract: A dry non-explosive additive for ammonium nitrate-fuel oil (ANFO) blasting agents which provides water resistance and wet sensitivity to allow use of the explosive in wet drill holes. The additive contains gelling agents that rapidly hydrate and swell upon water impingement, and thereafter cross-link to rapidly form a peripheral water-blocking barrier to prevent further water intrusion into a loaded blasting agent mass. The additive additionally contains hydrophobic sensitizers and optional fuels to provide points of adiabatic compression and physically hinder water incursion. When the additive is mixed with ANFO, the resulting blasting agent retains its dry and free pouring characteristics and has enhanced explosive properties over untreated ANFO. While ANFO may not detonate in wet conditions unless protected from water, when admixed with our additive it retains its explosive characteristics and detonation potential after placement in wet environs, to function well either wet or dry.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: October 25, 1988
    Inventors: Harold W. Sheeran, John P. Sheeran
  • Patent number: 4728375
    Abstract: A pyrotechnic composition for producing a screen for blocking the passage of infra-red radiation and of light, comprises phosphorus, preferably red amorphous phosphorus, dispersed in a binding agent, for example rubber. The composition is produced by forming the binding agent into a gel with solvent, dispersing the phosphorus into the gel, evaporating off solvent, and comminuting the resulting solid material.
    Type: Grant
    Filed: April 4, 1984
    Date of Patent: March 1, 1988
    Assignee: Haley & Weller Limited
    Inventor: Geoffrey M. Simpson
  • Patent number: 4719856
    Abstract: The pyrotechnic device comprises a projectile, a ground mounted device or a floating device whose casing contains a charge of titanium or other suitable combustible metal-containing material, charcoal, or other reducing agent and gunpowder such that, following ignition, infra-red emitting particles are emitted to form an infra-red radiating screen. The carbon reduces oxidation of the combustible material prior to emission.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: January 19, 1988
    Assignee: Pains-Wessex Limited
    Inventor: Nigel F. Joslin
  • Patent number: 4719857
    Abstract: The pyrotechnic device comprises a projectile, a ground mounted device or a floating device whose casing contains a charge of particulate material, for example a combustible silicon-containing material in particular mixed with titanium or other suitable combustible metal-containing material and gunpowder such that, following ignition, infra-red emitting particles are emitted for forming an infra-red radiating screen.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: January 19, 1988
    Assignee: Pains-Wessex Limited
    Inventor: David J. Spring
  • Patent number: 4681643
    Abstract: A solid or semisolid propellant comprising grains of propellant or propellant components bonded together so as to create voids within the propellant volume, said grains bonded together with sufficient strength to substantially delay the fluidization of the propellant by the onset of Taylor unstable burning, said propellant having a rapid burn rate below that associated with Taylor unstable burn. In another embodiment, the grains are held within and the voids are filled with viscous fluid binder such as a petroleum oil, said binder functioning to hinder Taylor unsatable burning and yet permit very rapid burning within the propellant volume.
    Type: Grant
    Filed: October 3, 1983
    Date of Patent: July 21, 1987
    Inventors: Stirling A. Colgate, George E. Roos
  • Patent number: 4637849
    Abstract: Waterproof explosive compositions are made from blends of inorganic oxidizing salts, fuel oil and polygalactomannans plus crosslinkers. When exposed to water, the polygalactomannans and crosslinkers form gels which protect the explosive composition from penetration of water and the dissolution of the inorganic oxidizing salt.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: January 20, 1987
    Assignee: Celanese Corporation
    Inventor: William F. Harris, Jr.
  • Patent number: 4547235
    Abstract: In accordance with the present invention there are provided gas generating compositions comprising sodium azide, silicon dioxide, potassium nitrate, molybdenum disulfide and sulfur.
    Type: Grant
    Filed: June 14, 1984
    Date of Patent: October 15, 1985
    Assignee: Morton Thiokol, Inc.
    Inventors: Fred E. Schneiter, Allan J. McDonald
  • Patent number: 4543137
    Abstract: A gas-retaining agent consisting of bubble assemblies, each bubble assembly being one particle consisting of a large number of bubbles agglomerated into the particle, is effective for improving the safety of water-in-oil emulsion explosive compositions against methane and coal dust, for improving the sympathetic detonability of the explosive compositions and for lowering their detonation velocity without deteriorating their strength.
    Type: Grant
    Filed: October 2, 1984
    Date of Patent: September 24, 1985
    Assignee: Nippon Oil and Fats Co. Ltd.
    Inventors: Koji Edamura, Akio Torii, Kazuyuki Sato, Hiroshi Sakai
  • Patent number: 4507161
    Abstract: This invention concerns a dynamite type explosive composition which comprises at least one liquid explosive nitric ester and an emulsion composition comprising an oxygen-releasing salt phase, an organic phase and an emulsifier. The invention provides dynamite type compositions in which the amount of liquid explosive nitric ester can be significantly reduced without adversely affecting the performance and physical properties of the composition.
    Type: Grant
    Filed: February 2, 1984
    Date of Patent: March 26, 1985
    Assignee: ICI Australia Limited
    Inventors: Vladimir Sujansky, Sergio Tribuzio, Jolanta Paull
  • Patent number: 4500370
    Abstract: A method for making a water-in-oil emulsion type explosive composition is disclosed. The method comprises combining a liquid carbonaceous fuel and an aqueous solution of at least one inorganic oxidizing salt, with agitation, in the presence of ingredients A and B and incorporating dispersed gas bubbles into the resulting emulsion. One of the ingredients A or B is added before or during agitation and the remaining ingredient is added during agitation. Ingredient A is oleic acid and/or linoleic acid. Ingredient B is an ammonium or alkali metal phosphate or carbonate.
    Type: Grant
    Filed: December 27, 1983
    Date of Patent: February 19, 1985
    Assignee: Du Pont Canada Inc.
    Inventor: Ernest A. Hajto
  • Patent number: 4455150
    Abstract: A method of enhancing the combustion of solid fuel/water slurries by the addition of about 100 to 5,000 ppm of a stable water-soluble explosive, which will detonate early in the combustion process, thereby producing a secondary dispersion of fuel particles, and an 80-65% coal/20-35% water composition suitable for secondary dispersion during combustion containing about 100-5,000 ppm of a water-soluble explosive, preferably selected from at least one member of a group consisting of picric acid; alkali picrates, such as ammonium picrate, sodium picrate, potassium picrate, calcium picrate, etc., and heavy metal picrates, such as iron picrate, lead picrate, zinc picrate, etc.; guanidine and nitroguanidine. The addition of the explosive may be made to the water of make up of the slurry or may be added to the formed slurry.
    Type: Grant
    Filed: August 18, 1983
    Date of Patent: June 19, 1984
    Inventor: Kenneth R. Olen
  • Patent number: 4341573
    Abstract: Pyrotechnic compositions in which sulfur is utilized to regulate or control the ignition or detonation of potassium nitrate and aluminum in compositions which may be used as emergency, signal or display type flares and which are characterized by exhibiting a predetermined or timed pulsating illuminary effect.
    Type: Grant
    Filed: September 5, 1980
    Date of Patent: July 27, 1982
    Assignee: Pulsar Laboratories, Inc.
    Inventor: David W. Donoho
  • Patent number: 4244701
    Abstract: A fuel in the form of a powder which is used for combustion engines, and including a process whereby the fuel is made; the fuel including charcoal, hard coal, grain chaff, gun powder, alcohol and water, while the process confines the temperatures at which the process is conducted.
    Type: Grant
    Filed: May 23, 1979
    Date of Patent: January 13, 1981
    Assignee: Yasui Yamashita
    Inventor: Yasui Yamashita
  • Patent number: 3980741
    Abstract: A method of continuously processing meal black powder in order to make it suitable for use in fuses, wherein a conventionally produced meal black powder is blended with about 20 % of water; said moist black powder is compressed to a coherent body in the form of sheets; said sheets are rubbed through a sieve; said sieved powder is agglomerated into spherical grains; said grains are dried to a moisture content of about 1 % and are sieved in order to provide a fraction having a grain size in the range of 0.3 and 1.0 mm.
    Type: Grant
    Filed: April 21, 1975
    Date of Patent: September 14, 1976
    Assignee: Dyno Industrier A.S.
    Inventor: Kjell Lovold
  • Patent number: 3937770
    Abstract: A method for the production of mealy crude black powder from components consisting essentially of potassium nitrate, sulfur and carbon, all in particle form, comprises the steps of placing each component in a storage container, continuously withdrawing said components individually from said storage containers in the determined proportions, continuously feeding said separate components as particles into a circular oscillating cylindrical grinding zone consisting of at least two grinding zones rigidly interconnected and containing grinding elements, whereby said component particles are ground and mixed with each other with agglomeration of the individual component particles, and continuously withdrawing said mealy crude black powder. This mealy crude black powder is then compressed and granulated, followed optionally by further treatment such as polishing and graphitizing or grinding.
    Type: Grant
    Filed: October 3, 1973
    Date of Patent: February 10, 1976
    Assignee: Wasagchemie GmbH
    Inventors: Wolfgang Wiedemann, Friedrich Platte