Organic Additive Patents (Class 162/127)
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Patent number: 6200418Abstract: The invention relates to hydrophilic, humectant, soft, pliant, single-ply or multi-ply absorbent papers in the form of a napkin. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and a softener which has a melting range of about 0°-40° C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.01 to 15 percent: wet pressing said nascent web, creping said web from said Yankee, and recovering the paper products.Type: GrantFiled: May 24, 2000Date of Patent: March 13, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
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Patent number: 6193838Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: July 1, 1999Date of Patent: February 27, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 6190499Abstract: Wet pressed absorbent papers having temporary or permanent wet strength properties are disclosed. These are useful as bathroom tissue and napkins. In many applications, these products need not be creped, and in that case they do not have the serpentine configuration.Type: GrantFiled: March 8, 1999Date of Patent: February 20, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
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Patent number: 6187140Abstract: A method of increasing the wet strength of a creped sheet, which method involves providing a sheet which includes cellulosic fibers, which sheet has a first side and a second side; applying a low temperature-curing latex adhesive binder composition to the first side of the sheet in a fine, spaced-apart pattern occupying from about 20 to about 50 percent of the surface area of the sheet; adhering the first side of the sheet to a creping surface; and creping the sheet from the creping surface. The binder composition is adapted to adhere the sheet to the creping surface and includes a functional group-containing latex, a functional group-reactive crosslinking agent, and a volatile base. In addition, the creping surface is heated at a temperature no greater than about 100° C.Type: GrantFiled: December 7, 1998Date of Patent: February 13, 2001Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ralph Anderson, Christopher Lee Davidson, Kenneth Curtis Larson, Thomas C. Saffel, Robert Emil Weber, Duane K. Zacharias
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Patent number: 6187141Abstract: A water-disintegratable fibrous sheet having a layered structure comprising: (a) at least one first fiber web comprising pulp of conifer and pulp of hardwood; (b) at least one second fiber web comprising pulp of conifer, having a content of pulp of hardwood less than that in said first fiber web or containing no pulp of hardwood, said first and second fiber webs forming said layered structure; and (c) a water-insoluble or water-swellable binder being added to at least one of said first and second fiber webs. The fibrous sheet excellent in water-disintegratability and strength can be obtained.Type: GrantFiled: September 16, 1998Date of Patent: February 13, 2001Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Daisuke Yamada
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Patent number: 6179961Abstract: Strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. At least one surface of the tissue papers has uniform discrete surface deposits of a substantively affixed chemical softening mixture comprising a mixture of a quartenary ammonium compound, an emollient, and a sorbitan ester.Type: GrantFiled: October 8, 1997Date of Patent: January 30, 2001Assignee: The Procter & Gamble CompanyInventors: Jonathan Andrew Ficke, Kenneth Douglas Vinson
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Patent number: 6176972Abstract: The present invention relates to the manufacture of a hydrophilic, humectant, soft, pliant single-ply or multi-ply absorbent papers to which an organic permanent or temporary wet strength agent has been added. Novel absorbent papers having temporary or permanent wet strength properties are shown. These are useful as bathroom tissue and napkins. These products are suitably also prepared using through air drying methods with or without the use of a Yankee dryer, and the products exhibit a unique combination of properties designed to appeal to consumer preferences. In many applications, these products need not be creped, and in that case they do not have the serpentine configuration.Type: GrantFiled: May 24, 2000Date of Patent: January 23, 2001Assignee: Fort James CorporationInventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
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Patent number: 6165319Abstract: The present invention relates to a soft, thick, single-ply, printed, absorbent paper product having a Yankee side and an air side wherein the absorbent paper is printed on before or after embossing on the Yankee side, air side, or both sides, said absorbent paper exhibiting a serpentine configuration. This inventions also relates to a process for the manufacture of such absorbent paper product having a basis weight of at least about 12.5 lbs. per 3000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 200 grams per 3 inches per pound per 3000 square foot ream, a cross direction specific wet tensile strength of between 2.75 and 20.0 grams per 3 inches per pound per 3000 square foot ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 3.2 grams per inch per percent strain per pound per 3000 square foot ream, a friction deviation of less than 0.Type: GrantFiled: May 11, 1998Date of Patent: December 26, 2000Assignee: Fort James CorporationInventors: Michael S. Heath, T. Philips Oriaran, Mark S. Siegel, Frank D. Harper, John H. Dwiggins
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Patent number: 6149769Abstract: Disclosed is a soft, low density paper product made using papermaking fibers and a cationic temporary wet strength resin. Such paper products have a density less than about 0.6 grams per cubic centimeter, a basis weight is between about 10 and about 65 grams per square meter, a dry strength less than about 500 grams per inch (197 grams per centimeter), a ratio of an initial wet strength to the dry strength greater than about 0.15:1, and a ratio of a thirty minute wet strength to the initial wet strength less than about 0.4. Methods for producing such paper products are also disclosed. The paper products may be produced either as homogeneous structures or as multi-layered structures and may be either creped or uncreped.Type: GrantFiled: June 3, 1998Date of Patent: November 21, 2000Assignee: The Procter & Gamble CompanyInventors: Khosrow Parviz Mohammadi, Larry Odell Seward, David Mark Rasch
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Patent number: 6117525Abstract: A chemically enhanced paper structure having a discrete pattern of a chemical composition is disclosed. The paper structure comprises a cellulose substrate, such as tissue paper. The substrate has a topography comprising at least two different elevations. The chemical composition may include a chemical softener composition or a surface-active composition and is selectively disposed in register with one of the elevations of the cellulose substrate, preferably the higher elevation regions. The paper structure is suitable for use as bath tissue or facial tissue.Type: GrantFiled: October 8, 1998Date of Patent: September 12, 2000Assignee: The Procter & Gamble CompanyInventors: Paul Dennis Trokhan, Dean Van Phan, Joe Brian Melvin
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Patent number: 6113740Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: July 1, 1999Date of Patent: September 5, 2000Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 6103063Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: July 1, 1999Date of Patent: August 15, 2000Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Christian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 6054020Abstract: Amine-modified polysiloxanes are applied to the opposite outer surfaces of a tissue product, such as the two outer surfaces of a 3-ply facial tissue, providing improved softness to the surfaces and a degree of hydrophobicity to prevent wet through of liquids during use. However, the degree of hydrophobicity is controlled by the chemical structure of the amine-modified polysiloxane and/or by blending the amine-modified polysiloxane with a more hydrophilic modified polysiloxane such that liquid is still allowed to enter the tissue structure in a reasonably short time to be absorbed by the center ply, but the absorption in combination with the hydrophobicity of the other outer surface substantially delays the liquid from passing completely through the tissue product.Type: GrantFiled: January 23, 1998Date of Patent: April 25, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Mike Thomas Goulet, Dale Alan Burghardt, Duane Gerard Krzysik
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Patent number: 6051104Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: August 13, 1997Date of Patent: April 18, 2000Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 6033761Abstract: The present invention relates to a soft, thick, single-ply tissue and to a process for the manufacture of such tissue product having a basis weight of at least about 15 lbs./3,000 square foot ream and having low sidedness, said tissue exhibiting:a specific total tensile strength of between 40 and 75 grams per 3 inches per pound per 3000 square feet ream, a cross direction specific wet tensile strength of between 2.75 and 7.5 grams per 3 inches per pound per 3000 square feet ream, the ratio of MD tensile to CD tensile of between 1.25 and 2.75, a specific geometric mean tensile stiffness of between 0.5 and 1.2 grams per inch per percent strain per pound per 3000 square feet ream, a friction deviation of less than 0.225, and a sidedness parameter of less than 0.275.Type: GrantFiled: December 23, 1996Date of Patent: March 7, 2000Assignee: Fort James CorporationInventors: John H. Dwiggins, Ranga Ramesh, Frank D. Harper, Anthony O. Awofeso, T. Philips Oriaran, Galyn A. Schulz, Dinesh M. Bhat
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Patent number: 6030675Abstract: The invention relates to tissue products having improved softness properties and methods of making them. Specifically, improved softness is achieved by incorporating a cationic silicone amidoamine ester or phosphate and, optionally, one or more softeners/debonders into the fiber furnish at the wet end of the tissue machine prior to formation, followed by an optional topical treatment with a cationic silicone amidoamine ester or phosphate and/or one or more softeners/debonders after the tissue web is formed. The result is a tissue product with added bulk and a smooth surface feel, both properties contributing to improved softness characteristics.Type: GrantFiled: June 30, 1998Date of Patent: February 29, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Wen Zyo Schroeder, Gary Lee Shanklin
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Patent number: 6027611Abstract: Facial tissue is rendered resistant to water penetration while retaining softness by treating the fibers with a sizing agent prior to forming the sheet, or topically after the sheet is formed. The resulting tissue prevents the user's hands from becoming wetted during nose care.Type: GrantFiled: April 26, 1996Date of Patent: February 22, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Timothy Maurice McFarland, Michael Francis Drymalski, James Martin Kaun, Marvin Edsel Swails, Eric Francis Sweeney
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Patent number: 6019871Abstract: The foam process is used to make non-woven webs from cellulose or synthetic fibers, which webs have as a component super absorbent polymer (SAP). In order to minimize water absorbency by the SAP, it may have a protective coating that dissolves only after in contact with water a few seconds; the SAP may be frozen (e.g. to about -18.degree. C.); and/or the SAP may be transported by highly chilled (e.g. about 1.degree. C.) water. The SAP, and liquid or foam carrier, is fed as a small volume flow into a conduit carrying a high volume flow of a fiber containing foam slurry, just before a foraminous element. A mechanical mixer may be provided in the conduit for mixing the SAP with the fiber-foam slurry. The addition of the SAP to the carrier fluid takes place no more than ten seconds (preferably no more than five seconds) before the fiber-foam slurry mixed with SAP is brought into operative association with one or more foraminous elements.Type: GrantFiled: April 30, 1998Date of Patent: February 1, 2000Assignee: Ahlstrom Paper Group OyInventors: Kay Rokman, Juhani Jansson, Eino Laine
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Patent number: 6017417Abstract: Throughdried tissue products such as facial tissue, bath tissue, and paper towels are made using a throughdrying fabric having from about 5 to about 300 machine direction impression knuckles per square inch (per 6.45 square centimeters) which are raised above the plane of the fabric. These impression knuckles create corresponding protrusions in the throughdried sheet which impart a significant amount of cross-machine direction stretch to the sheet. In addition, other properties such as bulk, absorbent capacity, absorbent rate and flexibility are also improved.Type: GrantFiled: October 7, 1997Date of Patent: January 25, 2000Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Greg Arthur Wendt, Kai F. Chiu, Mark Alan Burazin, Theodore Edwin Farrington, Jr., David Alan Heaton
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Patent number: 6017418Abstract: Hydrophilic, humectant, soft, pliant, single-ply or multiply absorbent papers in the form of napkin, towel, bathroom tissue or facial tissue are disclosed. These humectant paper products are formed by supplying a furnish to headbox comprising: Cellulosic papermaking fiber consisting essentially of recycle fiber, hardwood fiber, softwood fiber, and mixtures thereof; and optionally up to 50% synthetic fibers and ad a softener which has a melting range of about 0.degree.-40.degree. C. wherein the softener comprises an imidazoline moiety formulated in organic compounds selected from the group consisting of alkoxylated aliphatic polyols, alkoxylated aliphatic diols, aliphatic polyols, aliphatic diols and a mixture of these compounds, wherein the process of adding the softener is controlled to retain a ratio of the average particle size of dispersed softener to the average fiber diameter in the range of about 0.Type: GrantFiled: May 6, 1997Date of Patent: January 25, 2000Assignee: Fort James CorporationInventors: T. Philips Oriaran, Byron E. Burrier, Henry S. Ostrowski, Elroy W. Post, Jacob H. Propp
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Patent number: 5989389Abstract: The invention relates to a method of producing visible, preferably transparent or translucent, continuous streaks and/or delimited fields in paper in conjunction with forming a paper web in a paper machine. The method is characterized by essentially preventing dewatering of paper stock/paper fibres on one or more surfaces of a wire in the forming unit of a paper machine in conjunction with forming a paper web in the machine, and by applying a special stock that contains fibres which differ from the other fibre material deposited on the wire, optionally together with an arbitrary filler and/or binder. The invention also relates to a valuable document, such as a banknote, produced from the aforedescribed paper.Type: GrantFiled: June 9, 1995Date of Patent: November 23, 1999Assignee: AB Tumba BrukInventor: Tore Sundberg
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Patent number: 5981044Abstract: Multi-layered tissue paper webs comprising biodegradable chemical softener compositions and binder materials are disclosed. The multi-layered tissue webs are useful in the manufacture of soft, absorbent paper products such as facial tissues and/or toilet tissues. The multi-layered tissue paper products contain a biodegradable chemical softening composition, preferably comprising a mixture of an ester-functional quaternary ammonium compound and a polyhydroxy compound. The multi-layered tissue paper webs also contain an effective amount of binder materials to control linting and/or to offset the loss in tensile strength, if any, resulting from the use of the chemical softening compositions. Preferably, the majority of the biodegradable chemical softening compositions will be disposed on the outer layers of the multi-layered tissue paper products where they are most effective at enhancing softness.Type: GrantFiled: September 12, 1996Date of Patent: November 9, 1999Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul Dennis Trokhan, Bart Steven Hersko
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Patent number: 5958185Abstract: Soft, strong, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. The tissue papers comprise fibers such as wood pulp and a non-cellulosic, water insoluble particulate filler such as kaolin clay and possess biased surface properties.Type: GrantFiled: November 7, 1995Date of Patent: September 28, 1999Inventors: Kenneth Douglas Vinson, Robert Michael Bourbon, Howard Thomas Deason, David Jochen Lorenz, Charles William Neal, Paul Thomas Weisman
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Patent number: 5958187Abstract: A paper product and a method of making a paper product with a glabrous surface and adapted for use either dry or use in a manually pre-moistened condition. The paper product has temporary wet strength exhibiting an initial normalized CD wet tensile strength of at least about 25 g/1" strip, preferably 35 g/1" strip as measured by the Finch Cup Test 5 seconds after immersion and a subsequent CD wet tensile strength of less than about 2/3 the initial value as measured 30 minutes after immersion. A temporary wet strength agent comprising aldehydic units in the range of from about 2 pounds per ton to about 30 pounds per ton is added to the furnish. A cationic nitrogenous softener/debonder is preferably added to the furnish, in an amount of from about 1 pound per ton to about 6 pounds per ton. The CD dry tensile strength of the paper product is from at least about 133 g/1" up to about 267 g/1", and the tensile modulus is from about 10 to about 32 g/% strain while the GM MMD friction is from about 0.26 to about 0.Type: GrantFiled: July 11, 1997Date of Patent: September 28, 1999Assignee: Fort James CorporationInventors: Dinesh M. Bhat, Robert J. Marinack, Henry S. Ostrowski, Scott D. Moesch
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Patent number: 5885697Abstract: A soft tissue product is disclosed having uniformly distributed surface deposits of a solidified composition having a melting point of from about 30.degree. C. to about 70.degree. C. The solidified composition is applied to the outer surfaces of the tissue product in melted form, preferably by rotogravure printing. The solidified composition contains an oil, a wax, and preferably a fatty alcohol.Type: GrantFiled: December 12, 1997Date of Patent: March 23, 1999Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Duane Gerard Krzysik, Lee Patrick Garvey, Cynthia Watts Henderson, Michael Chauncey Tuck
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Patent number: 5882479Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: August 13, 1997Date of Patent: March 16, 1999Assignee: Fort James CorporationInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 5851352Abstract: Strong and soft multi-ply tissue paper products useful as absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. At least one internal surface of the tissue paper product has a surface deposited strengthening agent.Type: GrantFiled: May 12, 1997Date of Patent: December 22, 1998Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Jonathan Andrew Ficke, Howard Thomas Deason
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Patent number: 5846380Abstract: A soft absorbent, creped tissue paper having an ATP factor of less than about 0.036, a slip/stick coefficient of less than about 0.024, and a lint level of less than about 6. The tissue paper preferably has a density of less than about 0.15 gram/cm.sup.3. Preferably, the creped tissue paper is a single- or multi-layer, single-ply tissue. More preferably, the creped tissue paper is made by a through air drying technique. Tissue paper having unique combinations of these above attributes is highly desirable by the consumers.Type: GrantFiled: April 23, 1997Date of Patent: December 8, 1998Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul Dennis Trokhan
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Patent number: 5840403Abstract: A chemically enhanced paper structure having a discrete pattern of a chemical composition is disclosed. The paper structure comprises a cellulose substrate, such as tissue paper. The substrate has a topography comprising at least two different elevations. The chemical composition may include a chemical softener composition or a surface-active composition and is selectively disposed in register with one of the elevations of the cellulose substrate, preferably the higher elevation regions. The paper structure is suitable for use as bath tissue or facial tissue.Type: GrantFiled: June 14, 1996Date of Patent: November 24, 1998Assignee: The Procter & Gamble CompanyInventors: Paul Dennis Trokhan, Dean Van Phan, Joe Brian Melvin
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Patent number: 5830317Abstract: Soft, strong, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. The tissue papers comprise fibers such as wood pulp and a non-cellulosic, water insoluble particulate filler such as kaolin clay and possess biased surface properties.Type: GrantFiled: December 20, 1996Date of Patent: November 3, 1998Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Jonathan Andrew Ficke, Bart Steven Hersko
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Patent number: 5814188Abstract: Strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels are disclosed. At least one surface of the tissue papers has uniform discrete surface deposits of a substantively affixed chemical softening agent.Type: GrantFiled: December 31, 1996Date of Patent: September 29, 1998Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Paul Thomas Weisman, Jonathan Andrew Ficke, Thomas James Klofta
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Patent number: 5770013Abstract: A method for manufacturing paper having given physical characteristics is described, and which includes, providing a paper stock slurry of a given composition; removing water from the paper stock slurry to form a continuous sheet of paper; and without the use of a sizing press, providing and applying an aqueous solution of a substantially amylose free starch to the resulting paper in a predetermined amount effective to provide the resulting paper with the given physical characteristics, the paper manufactured at a production rate which is at least 10% faster than the production rate which can be achieved for substantially identical paper having the same given physical characteristics, but which is manufactured using a sizing press.Type: GrantFiled: June 21, 1996Date of Patent: June 23, 1998Assignee: Potlatch CorporationInventors: Nicholas R. Chance, Christopher J. Elskamp, Timothy H. Switzer
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Patent number: 5759346Abstract: A method for producing uncreped, strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels is disclosed. The tissue papers comprise fibers such as wood pulp and a non-cellulosic, water insoluble particulate filler such as kaolin clay.Type: GrantFiled: September 27, 1996Date of Patent: June 2, 1998Assignee: The Procter & Gamble CompanyInventor: Kenneth Douglas Vinson
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Patent number: 5746887Abstract: Throughdried tissue products such as facial tissue, bath tissue, and paper towels are made using a throughdrying fabric having from about 5 to about 300 machine direction impression knuckles per square inch (per 6.45 square centimeters) which are raised above the plane of the fabric. These impression knuckles create corresponding protrusions in the throughdried sheet which impart a significant amount of cross-machine direction stretch to the sheet. In addition, other properties such as bulk, absorbent capacity, absorbent rate and flexibility are also improved.Type: GrantFiled: April 24, 1996Date of Patent: May 5, 1998Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Greg Arthur Wendt, Kai F. Chiu, Mark Alan Burazin, Theodore Edwin Farrington, Jr., David Alan Heaton
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Patent number: 5731034Abstract: A method of coating paper with a paper coating composition having a solids concentration of at least 45% by weight, consisting essentially of an aqueous cationic dispersion of a particulate calcium carbonate pigment and a nonionic or cationic adhesive, wherein the pigment has a particle size distribution such that no more than 1% by weight of the particles have an equivalent spherical diameter larger than 10 microns, at least 65% by weight of the particles have an equivalent spherical diameter smaller than 2 microns and not more than 10% by weight of the particles have an equivalent spherical diameter smaller than 0.25 micron, and wherein said pigment is dispersed with a combination of a cationic polyelectrolyte and an anionic polyelectrolyte, with the amount of cationic polyelectrolyte being in the range of about 0.01% to about 1.5% by weight, based on the weight of the dry pigment, and with the amount of anionic polyelectrolyte being in the range of about 0.01% to about 0.5% by weight.Type: GrantFiled: December 2, 1996Date of Patent: March 24, 1998Assignee: ECC International LimitedInventor: John Claude Husband
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Patent number: 5700352Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.Type: GrantFiled: April 3, 1996Date of Patent: December 23, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Howard Thomas Deason
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Patent number: 5695607Abstract: A one-ply paper tissue product and a method of making a one-ply paper product combining high strength and softness along with low sidedness. The paper tissue product exhibits a sidedness parameter of less than 0.3 preferably, less than 0.225, a tensile modulus of no more than 32 grams/percent strain, a GM MMD of no more than about 0.225, and a cross directional strength of at least 200 grams per 3 inches. In stratification tissues, these properties are obtained by control of stratification, particularly, chemical stratification and stratification of furnish when appropriate. The tissue has a sidedness parameter value of less than 0.3, preferably, about 0.15 to about less than 0.225. In homogenous tissue, these properties are obtained by adding a strength enhancing agent to separate furnish sources prior to the funish sources being combined, and further, optionally adding the softener to the nascent web.Type: GrantFiled: April 1, 1994Date of Patent: December 9, 1997Assignee: James River Corporation of VirginiaInventors: T. Philips Oriaran, Frank D. Harper, Anthony O. Awofeso, Cristian M. Neculescu, Phuong Van Luu, Thomas N. Kershaw, Galyn A. Schulz
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Patent number: 5679218Abstract: Tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and napkins are provided. The composite average coarseness of the tissue papers is between about 11 mg/100 m and about 18 mg/100 m. The tissue paper comprise closed cell wall, chemically softened cellulose fibers further comprising coarse cellulose fibers such as those derived from CTMP or recycled sources. The cellulose fibers have enhanced lubricity such that they possess a depressed coefficient of friction (DCOF, in percentage points) related to the composite average coarseness, C, in mg/100 m, by the equation:DCOF>4.27*C-44.23.Type: GrantFiled: March 13, 1996Date of Patent: October 21, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Howard Thomas Deason
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Patent number: 5672248Abstract: Throughdried tissue products such as facial tissue, bath tissue, and paper towels are made using a throughdrying fabric having from about 5 to about 300 machine direction impression knuckles per square inch (per 6.45 square centimeters) which are raised above the plane of the fabric. These impression knuckles create corresponding protrusions in the throughdried sheet which impart a significant amount of cross-machine direction stretch to the sheet. In addition, other properties such as bulk, absorbent capacity, absorbent rate and flexibility are also improved.Type: GrantFiled: February 6, 1995Date of Patent: September 30, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Greg Arthur Wendt, Kai F. Chiu, Mark Alan Burazin, Theodore Edwin Farrington, Jr., David Alan Heaton
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Patent number: 5672249Abstract: A process for incorporating a fine particulate filler such as kaolin clay into tissue paper is disclosed. The process results in strong, soft, and low dusting tissue paper webs useful in the manufacture of soft, absorbent sanitary products such as bath tissue, facial tissue, and absorbent towels.Type: GrantFiled: April 3, 1996Date of Patent: September 30, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, John Paul Erspamer, Charles William Neal, Jonathan Andrew Ficke, Jeffress Paul Halter
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Patent number: 5651862Abstract: Described is a wet-formed composite. The wet-formed composite is formed from a combination of fibers and absorbent material. Specifically, the wet-formed composite is formed from absorbent material and a fiber slurry wherein the absorbent material is swellable in the dispersion medium of the slurry. Also disclosed is a method of forming the wet-formed composite. The method involves forming a fiber slurry, combining an absorbent material with the fiber slurry prior to forming the composite and then forming and drying the composite. The absorbent material is swellable in the dispersion medium of the fiber slurry.Type: GrantFiled: August 13, 1991Date of Patent: July 29, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Richard Allen Anderson, Richard John Schmidt
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Patent number: 5647951Abstract: An agricultural growth control device (2) includes an organic, biodegradable, layer (6) and an impermeable sheet (4) affixed to the underside of the organic layer to form a unitary ground collar (8). The ground collar defines at least one hole (10) to allow growth of a plant (P) therethrough while suppressing the growth of weeds or grass around the plant. The impermeable sheet is preferably formed from a slurry of cellulosic fiber and water and the organic layer is preferably formed from a slurry of fiber, water and finely chopped organic material, such as straw, manure, leaves or almond wood chips. The fiber and chopped organic material provide a semi-rigid mulch cover for suppressing weeds around the plant. The mulch cover is easily positioned around the plant and, once it is so disposed, will be relatively impervious to severe weather, such as heavy rainfall and winds. The chopped organic material, particularly almond wood chips, enhance the appearance of the mulch cover.Type: GrantFiled: May 7, 1996Date of Patent: July 15, 1997Inventor: John Bayer
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Patent number: 5643413Abstract: A method of producing a multi-ply paperboard product. A single aqueous recycled pulp stock which contains both heavy contaminants and lightweight contaminants is separated into three fractions, including a first fraction which contains the heavy contaminants, a second middle density fraction that contains the most desirable fibers, and a third low density fraction that contains the lightweight contaminants. The three fractions are discharged from a multi-channel head box onto a forming fabric, with the middle density fraction constituting the base ply in contact with the forming fabric, the low density fraction being the central ply and the high density fraction being the outer ply, thus forming a multiple-ply paperboard product.Type: GrantFiled: June 13, 1996Date of Patent: July 1, 1997Assignee: Hoffman Environmental Systems, Inc.Inventor: Roger P. Hoffman
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Patent number: 5635028Abstract: Soft creped tissue paper products comprising papermaking fibers and a crepe facilitating composition are disclosed. The crepe facilitating composition comprises a bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the bonding inhibitor is a quaternary ammonium compound. The use of a bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped papermaking process comprising the addition of the crepe facilitating composition is also disclosed. The crepe facilitating composition offers the potential to improve production capacity.Type: GrantFiled: April 19, 1995Date of Patent: June 3, 1997Assignee: The Procter & Gamble CompanyInventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan
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Patent number: 5591306Abstract: The addition of a relatively small amount of a cationic silicone to the aqueous suspension of papermaking fibers in the wet end of the tissue making process provides improved tactile properties (softness) to the resulting tissue.Type: GrantFiled: March 18, 1996Date of Patent: January 7, 1997Assignee: Kimberly-Clark CorporationInventor: James M. Kaun
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Patent number: 5573637Abstract: Tissue paper products comprising a two component chemical softener composition and binder materials, either permanent or temporary wet strength binders, and/or dry strength binders are disclosed. The two component chemical softening composition comprises a quaternary ammonium compound and a polysiloxane compound. Preferred quaternary ammonium compounds include dialkyl dimethyl ammonium salts such as di(hydrogenated)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium methyl sulfate. Preferred polysiloxanes include amino-functional polydimethyl polysiloxanes wherein less than about 10 mole percent of the side chains on the polymer contain an amino-functional group.Type: GrantFiled: December 19, 1994Date of Patent: November 12, 1996Assignee: The Procter & Gamble CompanyInventors: Robert S. Ampulski, Joel K. Monteith, Ward W. Ostendorf, Dean Van Phan, Paul D. Trokhan
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Patent number: 5538595Abstract: Tissue paper products comprising a two component chemical softener composition and binder materials, either permanent or temporary wet strength binders, and/or dry strength binders are disclosed. The two component chemical softening composition comprises an ester-functional ammonium compound and a polysiloxane compound. Preferred ester-functional ammonium compounds include diester dialkyl dimethyl ammonium salts such as diester di(touch hardened)tallow dimethyl ammonium chloride and/or di(hydrogenated)tallow dimethyl ammonium chloride. Preferred polysiloxanes include amino-functional polydimethyl polysiloxanes wherein less than about 10 mole percent of the side chains on the polymer contain an amino-functional group.Type: GrantFiled: May 17, 1995Date of Patent: July 23, 1996Assignee: The Proctor & Gamble CompanyInventors: Paul D. Trokhan, Dean V. Phan, Ward W. Ostendorf, Joel K. Monteith, Bart S. Hersko, Robert S. Ampulski
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Patent number: 5529665Abstract: The addition of a relatively small amount of a cationic silicone to the aqueous suspension of papermaking fibers in the wet end of the tissue making process provides improved tactile properties (softness) to the resulting tissue.Type: GrantFiled: August 8, 1994Date of Patent: June 25, 1996Assignee: Kimberly-Clark CorporationInventor: James M. Kaun
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Patent number: 5514429Abstract: A cylindrical composite paperboard cushion core for winding a sheet material therearound without forming undesirable stepwise marks thereon, comprises a cylindrical paperboard substrate and a cushion layer formed on the cylindrical paperboard substrate from an expanded paper sheet having a density of 0.1 to 0.4 g/cm.sup.3, the expanded paper sheet being formed by forming an unexpended paper sheet containing therein a plurality of expansible microcapsules each having a volatile liquid core contained in a thermoplastic resin shell and capable of starting an expansion at a temperature of 80.degree. C. to 200.degree. C., and heating the unexpanded paper sheet at the expansion-starting temperature of the microcapsules or higher, to cause the paper sheet to be expanded.Type: GrantFiled: November 15, 1993Date of Patent: May 7, 1996Assignee: New Oji Paper Co., Ltd.Inventors: Hiromi Kamihgaraguchi, Tsunehisa Shigetani
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Patent number: 5487813Abstract: Soft creped tissue paper products comprising papermaking fibers and a biodegradable crepe facilitating composition is disclosed. The crepe facilitating composition is a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose. Preferably, the biodegradable bonding inhibitor is a biodegradable quaternary ammonium compound. The use of a biodegradable bonding inhibitor, a cationic starch and a carboxymethyl cellulose results in a creped tissue paper that is both strong and soft. A creped paper process comprising the addition of the crepe facilitating composition is also disclosed. The composition offers the potential to improve production capacity.Type: GrantFiled: December 2, 1994Date of Patent: January 30, 1996Assignee: The Procter & Gamble CompanyInventors: Kenneth D. Vinson, Paul T. Weisman, Dean V. Phan