Synthetic (including Chemically Modified Cellulose) Patents (Class 162/146)
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Patent number: 5928777Abstract: A high pressure laminate is made of several layers of paper, including from bottom to top core sheets, a decor sheet and an overlay sheet. The core sheets are either composed of cellulose fibers or composed of 30 to 90 weight percent cellulose acetate fibers and 70 to 10 weight percent cellulose fibers. The core sheets are respectively coated with either a lamination polymer or a plasticizer. The decor sheet is composed of a mixture and a conventional amount of paper making dye. The mixture comprises 30 to about 90 weight percent cellulose acetate fibers, 10 to 70 weight percent cellulose fibers and 0 to 20 weight percent fillers. The decor sheet is coated with a plasticizer. The overlay sheet is composed of cellulose fibers and is coated with a lamination polymer. Upon application of heat and pressure to the several layers a laminate is formed having thermoplastic properties, improved postformability and a significant reduction in the release of volatile organics during formation.Type: GrantFiled: March 23, 1998Date of Patent: July 27, 1999Assignee: Eastman Chemical CompanyInventors: Stephen Todd Cox, Melvin Glenn Mitchell, Paul Jay Kennedy, Guy Fostine Massie, Jr., Freddie Wayne Williams
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Patent number: 5916670Abstract: An absorbent material that can be used as an absorbent core in absorbent articles such as disposable diapers, feminine hygiene products and incontinence devices is provided. An absorbent material of this invention contains cellulosic fibers at least a portion of which cellulosic fibers are treated with caustic at a low temperature. The absorbent material has superior absorptive, strength, and suppleness properties when compared to existing core materials. The material can be air-laid in one or more layers.Type: GrantFiled: October 10, 1997Date of Patent: June 29, 1999Assignee: Rayonier Inc.Inventors: Erol Tan, Peter R. Abitz, Kays Chinai
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Patent number: 5910231Abstract: A process for increasing the solvent resistance of calendered paper consisting of poly(p-phenylene terephthalamide) short fibers and poly(m-phenylene isophthalamide) fibrids and the dimensional stability of laminates made therefrom.Type: GrantFiled: July 22, 1997Date of Patent: June 8, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Birol Kirayoglu, David Jeffrey Powell
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Patent number: 5906712Abstract: The present invention provides a process for producing a fiber reinforced composite which contains the reinforcing fibers uniformly dispersed therein and therefore has uniformity of strength. The process comprises;preparing an aqueous slurry which comprises reinforcing fibers, water-soluble organic polymers A charged in water and particulate organic polymers,adding thereto water-soluble organic polymers B charged opposite to said organic polymers A in water to flocculate the solid components in said aqueous slurry, andthen removing aqueous medium and molding.Type: GrantFiled: June 20, 1994Date of Patent: May 25, 1999Assignee: Unitika Ltd.Inventors: Keiichi Asami, Kiyotaka Nakanishi, Hideki Takahashi, Ritsuko Shidei, Azusa Yamagata, Yoshiaki Echigo
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Patent number: 5885418Abstract: The improved creped non-laminar singular web structure comprising long fibers and short fibers demonstrated by high TWA and Z peeling. Creping causes a certain portion of long synthetic fibers and short fibers to substantially be oriented in a predetermined vertical or Z direction across the thickness of the web structure. In particular, when a stratified preparation containing wet stiff CTMP fibers is used, the vertically oriented CTMP fibers increase the total water absorption (TWA) of the web structure without collapsing. The high TWA print/double-creped paper products manufactured from the above web structure are suitable for heavy wipe and dry uses.Type: GrantFiled: May 19, 1997Date of Patent: March 23, 1999Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ralph L. Anderson, Kenneth C. Larson
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Patent number: 5876643Abstract: A foamed aqueous dispersion of a mixture of particulate plastics material is formed when the fibers are between 5% and 35% of the volume of the mixture, where no more than about 7% of the volume of the mixture is conductive fibers between about 7 and 20 mm long, and where any other fibers are reinforcing fibers with a high modulus of elasticity and between about 7 and about 50 mm long. A web is formed from the foamed dispersion using a wet laying process. The web is dried and compacted under heat and pressure. The compacted web is cooled to form a consolidated element in which the conductive fibers extend as a conductive lattice. The resulting element can be formed or molded into shielding to provide attenuation of electrical or magnetic fields.Type: GrantFiled: November 15, 1996Date of Patent: March 2, 1999Assignee: The Wiggins Teape Group LimitedInventors: Ian Stedman Biggs, Bronislaw Radvan
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Patent number: 5854149Abstract: As a paper-made stampable sheet having a high rigidity and, if necessary, improved adhesiveness and non-permeability and a light weight stampable sheet shaped body made from this sheet and a method of producing the same, there are proposed a paper-made stampable sheet obtained by paper-making a mixture of thermoplastic resin and reinforcing fibers to obtain a sheet-like web, piling a thermoplastic resin film of a single layer or multi layer or an organic fiber nonwoven fabric having at least one excellent property selected from rigidity, non-permeability and adhesiveness on at least one-side surface of the sheet-like web in accordance with use purpose, compressing them under heating above a melting point of the thermoplastic resin constituting the web, cooling and solidifying at a compressed state as well as a light weight stampable sheet shaped body made from this sheet and a method of producing the same.Type: GrantFiled: November 15, 1996Date of Patent: December 29, 1998Assignees: Kawasaki Steel Corporation Sumitomo Chemical Co., Ltd., K-Plasheet CorporationInventors: Katsuhiro Nagayama, Masami Fujimaki, Shigeru Takano, Taiji Matsumoto, Tomoshige Ono, Yukio Nagashima, Syohei Masui, Satoru Funakoshi, Yuji Kobayashi, Hiroyuki Yoshitake, Mitsuaki Sunada
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Patent number: 5851355Abstract: A nonwoven composite web is formed by a wet process on a papermaking machine. The web coming off the papermaking machine is dried and thermally bonded using heated calendar rolls. The nonwoven composite material is made from a furnish of polymeric staple fibers, a first binder fiber consisting, at least in part, of a first thermoplastic binder material which melts at a first melting temperature less than and a second binder fiber consisting, at least in part, of a second polymeric material which has second melting temperature which is higher than the first melting temperature. The first polymeric material is selected to have a first melting temperature less than the temperature to which the first material will be subjected in the papermaking machine. The melted first polymeric material gives the web strength on the papermaking machine. The second polymeric material is selected to have a second melting temperature less than the temperature to which the second material will be subjected in the calendar rolls.Type: GrantFiled: November 27, 1996Date of Patent: December 22, 1998Assignee: BBA Nonwovens Simpsonville, Inc.Inventor: James A. Goettmann
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Patent number: 5849447Abstract: Recording paper, at least one of opposite surface portions contains a mixture of hydrophilic fibers and hydrophobic fiber as main raw material. In addition, recording paper having a double-layer structure, in which a first layer 31 contains a mixture of hydrophilic fibers and hydrophobic fibers as main raw material, and a second layer 32 is a layer different from the first layer. The recording paper may have three or more layers including the first layer. Recording is performed by using such recording paper.Type: GrantFiled: October 16, 1996Date of Patent: December 15, 1998Assignee: Fuji Xerox Co., Ltd.Inventor: Tsukasa Matsuda
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Patent number: 5849153Abstract: A water-dispersible sheet and a cigarette using the sheet are disclosed. The sheet comprises a water-resolvable base paper made from fibrous raw materials and a water-dispersible coating layer containing water-soluble polymer and an alkaline compound. The sheet is also produced through an impregnation treatment for a water-resolvable base paper with a coating mixture containing water-soluble polymer and an alkaline compound, wherein said water-resolvable base paper is made from a mixture of water-dispersible fibers and fibrous carboxymethyl cellulose acid or fibrous carboxyethyl cellulose acid. The gas-permeability of the water-dispersible sheet is controlled by the water-dispersible coating layer or the impregnation treatment.Type: GrantFiled: July 30, 1996Date of Patent: December 15, 1998Assignees: Mishima Paper Co., Ltd., Japan Tobaco Inc.Inventors: Yoshiaki Ishino, Masato Shishikura, Toru Tsujimoto, Susumu Minamisawa
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Patent number: 5843278Abstract: A method of producing a soft paper product incudes, a) providing a pulp sheet at a moisture content of no greater than about 10%, the pulp of said sheet not having been previously subjected to dry milling and not being predominately anfractuous; b) treating the pulp sheet at moisture content of no greater than about 10% with liquid ammonia of a concentration of at least 90% for a period of time less than or equal to about 60 seconds effective to increase degree of softness in the sheet of pulp from that existing prior to the treating, the pulp in the treated sheet remaining not predominately anfractuous after said treating; c) forming the treated pulp sheet into a papermaking slurry; and d) feeding the papermaking slurry into the headbox of a paper machine and producing a tissue paper product therefrom which has greater softness than a tissue paper product made from the same pulp which has not been so treated with said ammonia.Type: GrantFiled: February 14, 1997Date of Patent: December 1, 1998Assignee: Potlatch CorporationInventors: Gopal C. Goyal, Robert E. Packwood, Jr., Mary L. Minton
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Patent number: 5837627Abstract: A web of fibers is bound together by a bonding medium that has been activated by partially solubilizing the bonding medium with a solvent therefor. The fibers are insoluble in the bonding medium. As the bonding medium is partially solubilized, it becomes tacky and flows into contact with the fibers and with itself Thereafter, the solvent is absorbed by the bonding medium, allowing the bonding medium to resolidify and bond the fibers in a matrix, increasing the web strength.Type: GrantFiled: January 13, 1997Date of Patent: November 17, 1998Assignee: Weyerhaeuser CompanyInventors: Donald D. Halabisky, Hugh West, Andre S. Hajnal, Terry M. Grant
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Patent number: 5824191Abstract: The present invention provides a process for making a paper based product which comprises a paper sheet, an aqueous latex binder and a release agent comprised of an emulsion of lecithin and a fatty acid or derivative thereof. In one embodiment, the process comprises first preparing a slurry of a cellulosic pulp and a polymeric latex binder, and then breaking the stability of the latex so that the polymer particles of the latex are able to be deposited on the fibers of the cellulosic pulp. An emulsion comprised of lecithin and a fatty acid or derivative thereof is added during the process. The addition can be to the slurry, or to the web which is formed when the slurry is drained of liquid. The web is then dried to provide the paper based product. In a preferred embodiment, a slurry of cellulosic pulp is first drained of liquid to form a web, with the polymeric latex binder and emulsion being applied to the web prior to drying.Type: GrantFiled: March 28, 1997Date of Patent: October 20, 1998Assignee: FiberMark Filter & Technical Products, Inc.Inventor: Homan B. Kinsley, Jr.
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Patent number: 5814256Abstract: A method and apparatus of producing and using composite fibers in a liquid molding process. The composite fibers are formed from a base material and filler particles which are lighter or less expensive than the base material. A preform screen is placed at the bottom of a tank. The tank is filled with liquid, the composite fibers and a mass of reinforcing fibers creating a slurry above the screen. The screen is raised up through the slurry causing the composite fibers and the reinforcing fibers to be deposited on the screen creating a fiber preform. The preform is then removed from the screen and is placed in a mold for use in a liquid molding process.Type: GrantFiled: March 20, 1997Date of Patent: September 29, 1998Assignee: The Budd CompanyInventors: Bruce Norman Greve, Richard Freeman
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Patent number: 5795439Abstract: The instant invention is directed to a process for making a non-woven, wet-laid, superabsorbent polymer-impregnated structure. The process generally comprises the steps of: mixing; deliquifying; and drying. Specifically, fibers, superabsorbent polymers, and a liquid are mixed to form a furnish. The liquid is treated with a means for inhibiting the swelling of the superabsorbent polymer. Then, the furnish is deliquified to form a preformed structure. The preformed structure is dried to form the non-woven, wet-laid, superabsorbent polymer-impregnated structure.Type: GrantFiled: January 31, 1997Date of Patent: August 18, 1998Assignee: Celanese Acetate LLCInventors: Joanne M. Euripides, Lessie C. Phillips, Steven F. Nielsen
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Patent number: 5783039Abstract: A wholly aromatic polyamide staple fiber fabric having excellent insulation and superior dimensional stability at a high temperature and/or a high humidity, includes 70 to 96 parts by weight of a staple fiber web made from a blend of 5 to 30% by weight of m-type wholly aromatic polyamide staple fibers and 70 to 95% by weight of p-type wholly aromatic polyamide staple fibers, and 4 to 30 parts by weight of an organic resin binder incorporated into the staple fiber web.Type: GrantFiled: February 14, 1997Date of Patent: July 21, 1998Assignee: Teijin LimitedInventor: Sadamitsu Murayama
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Patent number: 5779736Abstract: The present invention discloses a process for producing a fibrillated cellulose acetate fiber comprising contacting cellulose acetate fiber with a strong base solution at conditions sufficient to remove greater than about 5% of bulk acetyl groups from said cellulose acetate fiber. Modified cellulose acetate staple fiber comprising an outer layer of regenerated cellulose in which at least about 5% of the acetyl groups are removed on an overall fiber basis are also disclosed. Paper products incorporating said fibers are also disclosed.Type: GrantFiled: January 19, 1995Date of Patent: July 14, 1998Assignee: Eastman Chemical CompanyInventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin, Alan K. Wilson, Richard D. Neal
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Patent number: 5772846Abstract: A new thermoformable nonwoven fibrous mat having properties particularly suited for a facer on insulating gypsum board and the method of making the mat is disclosed. The mat can also be pleated or thermoformed to produce filter elements and preforms for producing a wide range of fiber reinforced composites and laminates. The mat preferably contains a major portion of glass fibers and a minor portion of polyester fibers bound together with up to 35 wt. percent of a cross linked vinyl chloride acrylate copolymer binder having a glass transition temperature as high as about 113 degrees F., preferably about 97 degrees F. The binder also optionally contains about 3-10 wt. percent stearylated melamine.Type: GrantFiled: January 9, 1997Date of Patent: June 30, 1998Assignee: Johns Manville International, Inc.Inventor: Alan Michael Jaffee
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Patent number: 5766752Abstract: A high pressure laminate is made of several layers of paper, including from bottom to top core sheets, a decor sheet and an overlay sheet. The core sheets are either composed of cellulose fibers or composed of 30 to 90 weight percent cellulose acetate fibers and 70 to 10 weight percent cellulose fibers. The core sheets are respectively coated with either a lamination polymer or a plasticizer. The decor sheet is composed of a mixture and a conventional amount of paper making dye. The mixture comprises 30 to about 90 weight percent cellulose acetate fibers, 10 to 70 weight percent cellulose fibers and 0 to 20 weight percent fillers. The decor sheet is coated with a plasticizer. The overlay sheet is composed of cellulose fibers and is coated with a lamination polymer. Upon application of heat and pressure to the several layers a laminate is formed having thermoplastic properties, improved postformability and a significant reduction in the release of volatile organics during formation.Type: GrantFiled: December 7, 1995Date of Patent: June 16, 1998Assignee: Eastman Chemical CompanyInventors: Stephen Todd Cox, Melvin Glenn Mitchell, Paul Jay Kennedy, Guy Fostine Massie, Jr., Freddie Wayne Williams
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Patent number: 5755828Abstract: Crosslinked cellulose fibers having free pendant carboxylic acid groups are disclosed. The fibers include a polycarboxylic acid covalently coupled to the fibers, and are crosslinked with a crosslinking agent having a cure temperature lower than the cure temperature of the polycarboxylic acid. Methods for producing the fibers and for producing a fibrous sheet incorporating the fibers are also disclosed.Type: GrantFiled: December 18, 1996Date of Patent: May 26, 1998Assignee: Weyerhaeuser CompanyInventor: John A. Westland
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Patent number: 5736009Abstract: A packing paper, superior in antibacterial activity, deodorization and electroconductivity, which is prepared by a method having the steps of making a pulp-dispersed mixture comprising 80 to 94% by weight of an aqueous pulp, 1 to 5% by weight of carbon staple 20 microns or less in diameter, and 5 to 15% by weight of acrylic staple 15 microns or less in diameter and dispersing a rosin and a mineral filler at an amount of 0.5 to 1 g and 15 to 20 g per liter of the pulp-dispersed mixture, respectively. The method further includes the step of forming the resulting mixture into a paper material. The method also includes the step of passing the paper material through several calendars maintained at a temperature of 120.degree. to 150.degree. C.Type: GrantFiled: February 16, 1996Date of Patent: April 7, 1998Inventor: Kim Soon-Jai
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Patent number: 5736008Abstract: A process for forming a highly filled, fibrous-reinforced sheet in which the sheet is formed from an aqueous dispersion of solids which include fibers, filler, and binder and cationic flocculating agent by continuously feeding a stream of such aqueous dispersion onto a moving porous support surface, wherein the filler comprises at least about 50 wt. % of the solids portion of the dispersion, the improvement comprising the use in the aqueous dispersion of a filler consisting essentially of calcium carbonate and a cationic polymeric flocculant having a charge-density of at least about 2 equivalents of cationic nitrogen per kilogram of polymer, and a highly-filled calcium carbonate-containing sheet, and the use of carbon black to impart opacity to paper or sheet that has a white appearance.Type: GrantFiled: April 8, 1993Date of Patent: April 7, 1998Assignee: Congoleum CorporationInventors: William D. Barrows, George H. Crouse, John F. Morton
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Patent number: 5731080Abstract: The present invention relates to a novel composite product which is composed of a fibrocrystalline heterogeneous structure consisting of:on the one hand a plurality of fibers of expanded specific surface area and of hydrophilic character, having a substantial quantity of microfibrils on their surface, andon the other hand crystals of precipitated calcium carbonate (PCC), organized essentially in clusters of granules, the majority of which trap the microfibrils and are joined directly thereto by mechanical bonding.Type: GrantFiled: November 21, 1994Date of Patent: March 24, 1998Assignee: International Paper CompanyInventors: Laurent Cousin, Fernand Mora
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Patent number: 5725601Abstract: A water absorbent cross-linked, carboxyalkylated cellulose-containing material is produced by impregnating a cellulose-containing material with an aqueous reaction solution including a carboxyalkylating agent, an alkali metal hydroxide, and a cross-linking agent dissolved in water in an initial content of 50 to 90% by weight, the molar ratio of the carboxylating agent to glucose groups of cellulose being 0.7 to 2.0; adjusting the water content of the aqueous reaction solution impregnated in the cellulose-containing material to 20 to 60% by weight and of at least 5% by weight below the initial water content by evaporating a portion of water; and subjecting the water content-adjusted cellulose-containing material to a simultaneous cross-linking and carboxylating reaction procedure at 50.degree. to 110.degree. C., while maintaining the water content at 20 to 60% and of at least 5% by weight below the initial water content.Type: GrantFiled: August 1, 1996Date of Patent: March 10, 1998Assignee: New Oji Paper Co., Ltd.Inventors: Kozo Tajiri, Masayo Maeda, Haruo Tsukamoto
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Patent number: 5688370Abstract: A sheet article for solid phase extraction or solid phase reaction has at least one sorptive polymer pulp at least one of sorptive and reactive particulate. The article can be used in a method of separating an analyte from a fluid by passing a fluid containing an analyte through a sheet article containing poly(p- or m-phenylenephthalamide) pulp and solid phase particles.Type: GrantFiled: April 25, 1995Date of Patent: November 18, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Donald F. Hagen, Simon S. Fung, Paul E. Hansen
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Patent number: 5681428Abstract: An inorganic board consisting of a cured base mat and a cured surface mat is manufactured by forming a surface mat by the dry method on a base mat formed by a paper making method, embossing the composite mat, and curing the embossed composite mat. Ridges each having an enlarged top are formed on the surface of the base mat when a plural number of single mats formed by the paper making method are rolled and laminated around a making roll having a surface on which a plural number of ring grooves are formed. The ridges of the base mat engage the surface mat since each ridge has an enlarged top to improve the interlaminate strength between a cured base mat and a cured surface mat of the resulting inorganic board.Type: GrantFiled: February 7, 1996Date of Patent: October 28, 1997Assignee: Nichiha CorporationInventors: Shiro Nakajima, Masaki Kanai
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Patent number: 5667637Abstract: The invention relates to paper and similar products made with at least a portion of the papermaking furnish being essentially water insoluble carboxyethyl cellulose fibers. A cationic additive material, such as a polyamide epichlorohydrin wet strength resin or cationic starch, is also required. From 2-100% of the modified fiber is used in conjunction with a usual papermaking fiber. The D.S. of the carboxyethylated fiber is in the range of about 0.01-0.3, preferably about 0.025-0.10. A notable feature of paper products made with the fiber/cationic additive system is an improved ratio of wet to dry tensile and burst strengths compared with sheets made from unmodified fiber.Type: GrantFiled: November 3, 1995Date of Patent: September 16, 1997Assignee: Weyerhaeuser CompanyInventors: Richard A. Jewell, David W. Park
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Patent number: 5662773Abstract: The present invention discloses a process for treating filter rods comprising cellulose acetate tow waste comprising the steps of:a. cutting said filter rods so that fiber of said cellulose acetate have a fiber length of less than about 4 inches; andb. treating said cut filter rods with an aqueous base until at least 5% of acetyl groups on said cellulose acetate has been hydrolyzed.Filter rods treated in this manner are suitable for use in various paper products. The process of the present invention may further include a step for repulping the cut filter rods to repulp any included plugwrap.Modified fiber comprising cellulose acetate wherein at least 5% of acetyl groups on said cellulose acetate have been hydrolyzed, said fiber having a length of less than about 4 inches, are also disclosed.Paper products comprising between about 5 and about 90% of the fiber of claim 21 and paper pulp are also disclosed.Type: GrantFiled: January 19, 1995Date of Patent: September 2, 1997Assignee: Eastman Chemical CompanyInventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin
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Patent number: 5651862Abstract: Described is a wet-formed composite. The wet-formed composite is formed from a combination of fibers and absorbent material. Specifically, the wet-formed composite is formed from absorbent material and a fiber slurry wherein the absorbent material is swellable in the dispersion medium of the slurry. Also disclosed is a method of forming the wet-formed composite. The method involves forming a fiber slurry, combining an absorbent material with the fiber slurry prior to forming the composite and then forming and drying the composite. The absorbent material is swellable in the dispersion medium of the fiber slurry.Type: GrantFiled: August 13, 1991Date of Patent: July 29, 1997Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Richard Allen Anderson, Richard John Schmidt
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Patent number: 5622775Abstract: A multi-layered smooth-calendered surface aramid paper with high break strength and tear resistance comprises a substrate layer and at least one surface layer intimately bonded to the substrate layer, wherein the surface layer(s) consists essentially of 65 to 90% by weight aramid fibrids and 10 to 35% by weight aramid floc and comprises 10 to 67% of the total basis weight of the paper.Type: GrantFiled: June 29, 1995Date of Patent: April 22, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Philip P. Burks, Jr., Lee J. Hesler
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Patent number: 5607550Abstract: A wet-laid nonwoven fabric comprises a blend of 1 to 50% by weight of fibres of a water-swellable water-insoluble superabsorbent polymer and 99 to 50% by weight of less absorbent fibres, for example fibres having an absorbency of less than 10 g/g measured by retention to centrifuging of a 0.9% by weight saline solution.Type: GrantFiled: February 7, 1995Date of Patent: March 4, 1997Assignee: Courtaulds Fibres (Holdings) LimitedInventor: Paul J. Akers
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Patent number: 5580459Abstract: A filtration structure comprising a thermally bonded, wet laid, fibrous web and support is provided. The web is formed from bicomponent fiber comprising a structure-forming component and a heat-bondable component. Also provided is a filtration method using the filtration structure. Beneficially, the filtration structure may include microfiber.Type: GrantFiled: December 31, 1992Date of Patent: December 3, 1996Assignee: Hoechst Celanese CorporationInventors: Edward J. Powers, Steve F. Nielsen, Jeanne E. Smith, Theodore S. Thornburg
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Patent number: 5573640Abstract: A composition of paper comprising 99 to 10 weight percent cellulose fibers and 1 to 90 weight percent cored cellulose fibers that are uniformly dispersed within the paper. The cored cellulose fibers are composed of a cellulose sheath that is 4 to 15 weight percent of the weight of the fiber and a cellulose acetate core. The cored cellulose fibers contain no substantial crimp and have an average length of 1 to 7 mm, a density of 1.20 to about 1.35 gm/cc, a denier 1 to 30 grams per 9,000 meters and a uniform dispersion index of less than 0.15.Type: GrantFiled: July 28, 1995Date of Patent: November 12, 1996Assignee: Eastman Chemical CompanyInventors: Tim J. Frederick, Melvin G. Mitchell, Lee R. Partin
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Patent number: 5545467Abstract: Inorganic or organic particles have been used in the past as paper additives for hot-pressed forms to impart the pattern of granite thereto, but when these are boiled in hot water, for example, an uncountable number of small blisters result, lowering the commercial value of the product; however, according to the present invention it is possible to obtain an additive for forming patterns by grinding to desired particle sizes colored paper which has undergone water-resistance treatment with a thermosetting resin, and by selecting the color of the colored paper, a pattern may be selected as desired having spots of any desired color or size. With patterned paper manufactured by adding these paper additives during the paper manufacturing process, there is no occurrence of the above mentioned blisters and a clear pattern may be formed, and therefore hot-pressed forms utilizing have a natural granite image.Type: GrantFiled: December 23, 1994Date of Patent: August 13, 1996Assignee: Kohjin Co., Ltd.Inventors: Isao Suzuki, Sunao Matsushima, Yoshikazu Kubota, Masayasu Kamijyou
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Patent number: 5539028Abstract: A water-resistant, fiberboard for use in making panels and tiles for building construction is disclosed. The fiberboard contains primary components which include mineral fiber, low density, nonfibrous inorganic filler and organic fiber. The fiberboard includes about 0.1-2 wt % of silicone fluid, preferably polymethylhydrogensiloxane, which improves water resistance without adversely affecting other physical properties.Type: GrantFiled: June 7, 1995Date of Patent: July 23, 1996Assignee: The Celotex CorporationInventors: Allan F. Bednar, Kenneth W. Espeut
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Patent number: 5522967Abstract: Disclosed is a method for the surface modification of cellulose fiber and the resulting product, sulfonated cellulose. Cellulose is first oxidized, preferably with sodium metaperiodate (NaIO.sub.4), to form dialdehyde oxycellulose, which is then reacted with sodium bisulfite (NaHSO.sub.3) to produce sulfonated cellulose. Sulfonation of the cellulose fiber significantly increases the dry and wet tensile strength as well as the wet strength:dry strength ratio, making this modified cellulose fiber extremely useful in a wide variety of paper products requiring a combination of good strength in both wet and dry applications.Type: GrantFiled: May 27, 1994Date of Patent: June 4, 1996Assignee: Kimberly-Clark CorporationInventor: Ramakant T. Shet
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Patent number: 5498314Abstract: Provided is a process for making a paper based product which comprises first preparing a slurry of a cellulosic pulp, a particulate binder, and an emulsion comprised of lecithin and a fatty acid or derivative thereof. This slurry is then drained of liquid to form a web, with the web being dried to provide the paper based product. The preferred polymeric binder is a hydrolyzed polyvinyl alcohol powder, which binder can be present in the final dried product in amounts of up to about 20 weight percent or more. The use of the emulsion comprised of lecithin and a fatty acid or derivative thereof permits a web containing such a high amount of sticky polymeric binder to be dried at high temperatures, without the web sticking to the drying cans generally used in commercial processes. The process of the present invention thereby permits one to efficiently prepare such a paper based product using conventional, commercial papermaking machinery.Type: GrantFiled: August 9, 1993Date of Patent: March 12, 1996Assignee: CPG Holdings Inc.Inventor: Homan B. Kinsley, Jr.
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Patent number: 5491020Abstract: A board of calcium silicate crystals, characterized in that the board is composed of a plurality of layers of laminated thin sheets, each of the thin sheets having a thickness of 2 mm or less, each layer comprising secondary particles of calcium silicate crystals, a fibrous material, a coagulant and preferably additionally a polymer adsorbed on the surface of the secondary particles of calcium silicate; wherein each layer contains secondary calcium silicate particles interconnected with one another, and wherein the superposed thin sheets are firmly united with one another into an integral body by the interlayer interconnection of secondary particles of calcium silicate crystals present on the surface of the sheets.Type: GrantFiled: November 10, 1994Date of Patent: February 13, 1996Assignee: Kabushiki Kaisha Osaka Packing SeizoshoInventors: Tsutomu Ide, Suguru Hamada
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Patent number: 5470409Abstract: A process for the production of structural and semi-structural composites formed by compressing planar layers of nonwoven preform materials formed from aqueous blends of reinforcing fibers and thin thermoplastic fluoropolymer flake. The flakes have an irregular periphery with microfibrils extending therefrom, having a Canadian Standard Freeness of from 800 to 883. The planar layers which are unconstrained in the in-plane direction are preconsolidated by heating the layer to above the melting point of the fluoropolymer, the applying pressure normal to the plane of the layer causing the fluoropolymer to flow thus orienting the fibers in the plane of the layer. The composites are useful in applications which require higher strength and/or modulus, and where chemical and/or heat resistance is needed, as in chemical processing.Type: GrantFiled: July 25, 1994Date of Patent: November 28, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Clifford K. Deakyne, Gregory P. Weeks
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Patent number: 5466336Abstract: The present invention provides a process for making a paper based product which comprises a paper sheet, an aqueous latex binder and a release agent comprised of an emulsion of lecithin and a fatty acid or derivative thereof. In one embodiment, the process comprises first preparing a slurry of a cellulosic pulp and a polymeric latex binder, and then breaking the stability of the latex so that the polymer particles of the latex are able to be deposited on the fibers of the cellulosic pulp. An emulsion comprised of lecithin and a fatty acid or derivative thereof is added during the process. The addition can be to the slurry, or to the web which is formed when the slurry is drained of liquid. The web is then dried to provide the paper based product. In a preferred embodiment, a slurry of cellulosic pulp is first drained of liquid to form a web, with the polymeric latex binder and emulsion being applied to the web prior to drying.Type: GrantFiled: August 9, 1993Date of Patent: November 14, 1995Assignee: CPG Holdings Inc.Inventor: Homan B. Kinsley, Jr.
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Patent number: 5454910Abstract: Pulp-like short fibers prepared from liquid crystal polyesters capable of forming an anisotropic melt phase at a temperature of 200.degree. C. to 400.degree. C. and having a molecular weight of 2,000 to 100,000 are provided. These fibers consist of microfibrils and have the following highly-oriented fiber characteristics and properties:(a) Tensile strength: 5-30 g/den.;(b) Modulus of elasticity: 200-1,500 g/den.;(c) Orientation angle as determined by an X-ray diffraction: below 20.degree.;(d) Thickness distribution: 0.1-50 .mu.m;(e) Length distribution: 0.1-50 mm; and(f) Specific surface area as determined by a nitrogen adsorption method: 3-30 m.sup.2 /g.Type: GrantFiled: September 9, 1994Date of Patent: October 3, 1995Assignee: Korea Institute of Science and TechnologyInventors: Han S. Yoon, Tae W. Son, Chul J. Lee, Byung G. Min, Jae W. Cho
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Patent number: 5451456Abstract: A latex comprises a colloidal suspension in water of essentially non-crystalline particles of a polymer or copolymer or .beta.-hydroxyalkanoates, for example .beta.-hydroxybutyrate and .beta.-hydroxyvalerate; the latex may be employed to produce self-supporting filfms or papers which are biodegradable and also readily recyclable.Type: GrantFiled: August 18, 1992Date of Patent: September 19, 1995Assignee: Pulp and Paper Research Institute of CanadaInventors: Robert H. Marchessault, Pierre F. LePoutre, Peter E. Wrist
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Patent number: 5443899Abstract: Disclosed is a fiber comprising, chemically bonded together, (a) a conventional cellulosic fiber, such as a Kraft fiber or a chemithermomechanical pulp fiber; (b) poly(acrylate-co-itaconate) copolymer, such as the acid form of a poly(acrylate-co-itaconate) copolymer comprising 90-95 mole % acrylate and 5-10 mole % itaconate having weight average molecular weight of about 600,000-900,000; and (c) a polyol, such as polyethylene glycol; also disclosed are methods for making such fibers, especially evaporatively depositing an intimate mixture of the copolymer and polyol on the fiber followed by thermally crosslinking at specific temperatures for limited periods; absorbent paper which can be made by wet-laying the fiber, especially in admixture with conventional fiber; and derivative paper structures, such as multi-ply disposable absorbent towels.Type: GrantFiled: June 2, 1992Date of Patent: August 22, 1995Assignee: The Procter & Gamble CompanyInventors: Robert L. Barcus, David W. Bjorkquist
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Patent number: 5437767Abstract: A wet laying process for making fluid-sealing gasket sheet materials is described. The gasket materials seal particularly well against polar liquids. These gasketing sheets have from about 5 to about 20% fiber, and at least about 62% filler, and a reduced binder concentration, containing about 18% by weight of binder or less, allowing the binder to be reduced even to zero. The sheet must include at least about 3% by total dry weight of a gel-forming mineral filler. In addition to giving from good to very excellent seals against polar liquids, this gasketing also has good torque retention and creep resistance.Type: GrantFiled: July 22, 1992Date of Patent: August 1, 1995Assignee: Armstrong World Industries, Inc.Inventors: Nowaf Halout, Alexandra M. Kavoulakis, Ellen R. Romano
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Patent number: 5436094Abstract: A bulky synthetic pulp sheet which does not lose its shape even after having absorbed a liquid and has excellent resistance against to chemicals such as acids and alkalis, and a process for preparing the same, which pulp sheet contains 5 to 95% by weight of a synthetic pulp having a drainage factor over a range of from 0.1 to 2.0 sec/g, and 5 to 50% by weight of a polymer binder having a melting point lower than a melting point or a decomposition temperature of said synthetic pulp, the sheet being obtained by subjecting a mixture of the synthetic pulp and fibrous binder to wet laid sheet-making followed by a heat treatment, and having an apparent density of 0.15 g/cm.sup.3 or smaller under the load of 200 g/cm.sup.2.Type: GrantFiled: March 18, 1994Date of Patent: July 25, 1995Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Koji Horimoto, Makoto Nakamaru, Yukio Kohno
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Patent number: 5431782Abstract: The present invention relates to a reactivable paper and to a process for obtaining it.The paper consists of fibres with a heat resistance .gtoreq.180.degree. C., bonded together by means of a fibrous binder composed of polyamide or aromatic polyester pulp and of a chemical binder consisting of a polyether-imide of an aromatic polyester or of a resin of polyimide type, with a particle size smaller than 100 .mu.m, a softening point of between 50.degree. and 200.degree. C., and a degree of crosslinking of between 0.025 and 0.25. The weight proportion of fibres in the finished paper is generally preferably between 45 and 85%, that of the fibrous binder between 5 and 20%, that of the chemical binder between 10 and 50%.The papers are obtained by a wet route and find wide applications as a function of the degree of conversion of the resin, for example as a dielectric.Type: GrantFiled: December 14, 1993Date of Patent: July 11, 1995Assignee: Rhone Poulenc FibresInventor: Robert Cassat
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Patent number: 5416960Abstract: A method for the production of a fibrous product containing curled fibers includes applying rectilinear bi-component fibers (17) to the upper side of a raw material sheet (2) before it is introduced into a defibrator (1). Immediately before the introduction a heating is effected. When the rectininear bi-component fibers (17) are introduced into defibrator (1), the beater bars (9) effect a curling effect to provide a raw material including curled bi-component fibers. Hereby it is possible to substantially reduce the manufacturing costs, however, having the effect of curled bi-component fibers in the final fibrous product. Moreover, a good bonding of the fibers is obtained in the final product.Type: GrantFiled: October 28, 1993Date of Patent: May 23, 1995Inventor: Karl K. K. Kroyer
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Patent number: 5415738Abstract: Non-woven fabrics and methods and apparatus for their manufacture are disclosed. The fabrics have excellent mechanical strength and hand, and have a substantial uniformity of constituent fibers even at low basis weights. The fabric comprises chopped fibers of a synthetic polymeric thermoplastic material, which serve as binder fibers, and chopped fibers of a synthetic polymeric material which need not be a thermoplastic, which serve as bonded fibers. No extraneous binder materials need be present in the fabric. During manufacture, the binder fibers are uniformly dispersed in an aqueous liquid with the bonded fibers. The fibers are wet laid to form a web which is subsequently dried. During drying, the web is physically supported to prevent fracture. Also, during drying, the web is heated sufficiently to cause the binder fibers to bond to the bonded fibers, thereby forming the finished fabric.Type: GrantFiled: March 22, 1993Date of Patent: May 16, 1995Assignee: Evanite Fiber CorporationInventors: Haresh R. Mehta, Tejendra M. Singh, Joseph E. Meyer
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Patent number: 5412052Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.Type: GrantFiled: May 11, 1994Date of Patent: May 2, 1995Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh
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Patent number: 5411793Abstract: A board of calcium silicate crystals, characterized in that the board is composed of a plurality of layers of laminated thin sheets, each of the thin sheets having a thickness of 2 mm or less, each layer comprising secondary particles of calcium silicate crystals, a fibrous material, a coagulant and preferably additionally a polymer adsorbed on the surface of the secondary particles of calcium silicate; wherein each layer contains secondary calcium silicate particles interconnected with one another, and wherein the superposed thin sheets are firmly united with one another into an integral body by the interlayer interconnection of secondary particles of calcium silicate crystals present on the surface of the sheets.Type: GrantFiled: February 1, 1993Date of Patent: May 2, 1995Assignee: Kabushiki Kaisha Osaka Packing SeizoshoInventors: Tsutomu Ide, Suguru Hamada, Masahiro Kawai