Cellulosic Patents (Class 162/157.6)
  • Patent number: 11920305
    Abstract: A preparation method and an application method of a multifunctional intelligent cellulose-based visual label are provided. The multifunctional intelligent cellulose-based visual label solved a problem that an existing freshness indicator film is narrowed in an indication range. The preparation method includes the following steps: step 1 of carboxylation modification; step 2 of cationic grafting; step 3 of preparation of a composite dye solution; step 4 of preparation of responsive fibers; and step 5 of performing vacuum filtration to prepare paper, thereby obtaining the multifunctional intelligent cellulose-based visual label. The food freshness is indicated with the obtained intelligent visual label. An indicated pH value range is 4-8, color variation can be completed within 30 seconds, and the food freshness can be accurately indicated. The multifunctional intelligent cellulose-based visual label is low-carbon, efficient, green, safe, and wide in the indication range, and can be used in food monitoring.
    Type: Grant
    Filed: September 23, 2023
    Date of Patent: March 5, 2024
    Assignee: Northeast Forestry University
    Inventors: Lijuan Wang, Ruoting Liu
  • Patent number: 11795619
    Abstract: A tissue sheet includes softwood fibers and treated non-wood fibers from plants in the Poaceae family, wherein the treated non-wood fibers have less than 15 percent hemicellulose. Also, a tissue sheet consists essentially of softwood fibers and treated non-wood fibers, wherein the treated non-wood fibers have less than 15 percent hemicellulose. Customizing the tensile index and Canadian standard freeness (CSF) of fibers in a tissue sheet includes treating non-wood fibers by removing a portion of hemicellulose from the non-wood fibers; forming a tissue sheet comprising softwood fibers and the treated non-wood fibers; and adjusting the portion of hemicellulose removed from the non-wood fibers to achieve a desired the tensile index and Canadian standard freeness (CSF) of the treated non-wood fibers.
    Type: Grant
    Filed: February 1, 2022
    Date of Patent: October 24, 2023
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ning Wei, Thomas G. Shannon
  • Patent number: 11739477
    Abstract: A method for producing a modified lignocellulosic pulp having improved wet-strength properties and a modified lignocellulosic pulp obtainable by the method.
    Type: Grant
    Filed: October 29, 2019
    Date of Patent: August 29, 2023
    Assignee: SCA FOREST PRODUCTS AB
    Inventors: Kent Malmgren, Thomas Nordqvist
  • Patent number: 11634863
    Abstract: An improved market pulp and process for making the same by adding a composite material are described. The composite material includes cellulose nanocrystals, cellulose nanofibers, or another high aspect ratio, high surface area cellulose material (or a starch, or both) and a crosslinking compound that crosslinks a portion of the surface hydroxyl groups to form a 3-D matrix. Adding the composite material to market pulp has been shown to improve the strength of twice-dried paper products, made from such an enhanced market pulp. By crosslinking a portion of the surface hydroxyl groups in the market pulp to form a 3-D matrix, a first drying step may be accomplished without loss of benefits afforded when the market pulp is later re-pulped to make a paper product.
    Type: Grant
    Filed: October 11, 2018
    Date of Patent: April 25, 2023
    Assignee: University of Maine System Board of Trustees
    Inventors: Michael A. Bilodeau, Mark A. Paradis
  • Patent number: 11473242
    Abstract: Treated pulp sheets comprising cellulose pulp fibers treated with a densifying agent and having a relatively low moisture content. In certain embodiments, the treated pulp sheets are used to produce fiberized pulp having low knot content, while maintaining density and softness properties usually associated with similarly treated pulp that is fiberized at higher moisture content. Methods of making fiberized pulp from the treated pulp sheets, as well as products comprising the treated pulp sheets or fiberized pulp from the treated pulp sheets, are also provided.
    Type: Grant
    Filed: April 1, 2019
    Date of Patent: October 18, 2022
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventor: Andre Stephan Hajnal
  • Patent number: 11453728
    Abstract: Provided is a carboxymethylated microfibrillated cellulose fiber having a Canada standard freeness of less than 200 mL and an average fiber diameter of not less than 500 nm. Said fiber provides a composition having excellent water retention ability.
    Type: Grant
    Filed: March 28, 2019
    Date of Patent: September 27, 2022
    Assignee: NIPPON PAPER INDUSTRIES CO., LTD.
    Inventors: Masato Takayama, Yoshihiro Aoki, Takanori Otsuhata, Takeo Izumiya, Hiroyuki Okumura, Tomonori Kawamata, Ryo Sotooka
  • Patent number: 11390991
    Abstract: The present invention provides compositions comprising cellulose fibers and cellulose ester fibers and wet laid articles made from the compositions, as well as wet laid processes to produce these compositions. More specifically, the present invention provided compositions comprising cellulose fibers and cellulose acetate fibers and wet laid articles made from these compositions as well as wet laid processes to produce these compositions. The present invention also relates to developing a composition, process, wet laid product, or articles exhibiting any one of many the desired benefits. This invention also relates to a process to produce a wet laid article in a paper mill, said process comprising adding cellulose ester staple fiber to a hydropulper zone, and/or to a refining zone, and/or after the refining zone wherein said paper mill process is not substantially modified to allow for said adding of said cellulose ester.
    Type: Grant
    Filed: July 26, 2019
    Date of Patent: July 19, 2022
    Assignee: Eastman Chemical Company
    Inventors: Kenny Randolph Parker, Charles Stuart Everett, Melvin Glenn Mitchell, Koushik Ghosh, Mounir Izallalen
  • Patent number: 11352748
    Abstract: Pulps, cellulose ether products, and methods of making pulps are described.
    Type: Grant
    Filed: August 16, 2018
    Date of Patent: June 7, 2022
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventors: Mengkui Luo, Michael Rea, Angela Dodd, Andrew Dodd, Amy Anderson-Gaber, Kris Lindenauer, Hugh West, Charles Miller
  • Patent number: 11339532
    Abstract: Methods of forming crosslinked cellulose include mixing a crosslinking agent with cellulose mat fiber fragments composed of hydrogen-bonded cellulose fibers and having a solids content of about 45-95% to form a substantially homogenous mixture of non-crosslinked, individualized cellulose fibers, drying the resulting mixture to 85-100% solids, then curing the dried mixture under conditions effective to crosslink the cellulose fibers. Some of such methods may include fragmenting a cellulose fiber mat to form the mat fragments. Systems include a mixing unit (such as a high-consistency mixer) configured to form, from the mat fragments and a crosslinking agent, a substantially homogenous mixture of non-crosslinked, individualized cellulose fibers and crosslinking agent, at ambient conditions, a drying unit to dry the substantially homogenous mixture to a consistency of 85-100%, and a curing unit and to cure the crosslinking agent to form dried and cured crosslinked cellulose fibers.
    Type: Grant
    Filed: November 15, 2018
    Date of Patent: May 24, 2022
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventors: Charles E. Miller, Alan D. Lovas
  • Patent number: 11313075
    Abstract: The present invention relates to a modified cellulosic fiber that comprises anionic moieties in an amount of more than 0.25 mol/kg of dry fiber and has applied thereon a polymeric modifying agent in an amount of from 0.5 wt. % to 5.0 wt. %, based on dry fiber, the polymeric modifying agent comprising cationic moieties with a charge of at least 1.5 meq per gram of polymer and the molar ratio of anionic moieties to cationic moieties contained in the fiber is in the range of from 1:1 to 25:1. The fiber according to the present invention is characterized in that the anionic moieties are incorporated in the fiber and are from carboxymethylcellulose, and that the polymeric modifying agent comprising cationic moieties is selected from the group consisting of polydiallyldimethylammonium chloride (poly-DADMAC), poly(acrylamide-co-diallyldimethylammonium chloride) (PAM-DADMAC) and mixtures thereof. The invention furthermore relates to a nonwoven product or fabric comprising the modified cellulosic fiber.
    Type: Grant
    Filed: October 27, 2017
    Date of Patent: April 26, 2022
    Assignees: KELHEIM FIBRES GMBH, GLATFELTER GERNSBACH GMBH
    Inventors: Jörg Kühn, Ingo Bernt, Walter Roggenstein, Bernd Seger
  • Patent number: 11220787
    Abstract: A fine cellulose fiber-containing substance that has excellent dispersibility in water and can be manufactured easily. A method is for manufacturing the fine cellulose fiber-containing substance, and a method is for manufacturing a fine cellulose fiber dispersion. A fine cellulose fiber-containing substance contains fine cellulose fibers into which a phosphite containing a cation of an inorganic substance is introduced. The ratio of the cation of the inorganic substance with respect to 1 g of the fine cellulose fibers is 0.14 mmol or more. In manufacturing the fine cellulose fiber-containing substance, a phosphite is introduced into cellulose fibers, and then the cellulose fibers are defibrated to obtain a dispersion containing fine cellulose fibers, during which an alkali metal ion-containing substance is added to the cellulose fibers, and the dispersion is concentrated. In manufacturing a fine cellulose fiber dispersion, the fine cellulose fiber-containing substance is mixed with water.
    Type: Grant
    Filed: May 30, 2018
    Date of Patent: January 11, 2022
    Assignee: Daio Paper Corporation
    Inventor: Ikko Matsusue
  • Patent number: 11111631
    Abstract: It is an object of the present invention to provide a method for producing ultrafine fibrous cellulose, which is capable of efficiently obtaining ultrafine fibrous cellulose having phosphoric acid groups with a high yield. The present invention relates to a method for producing fibrous cellulose having a fiber width of 1000 nm or less, comprising: a (A) of introducing phosphoric acid groups into cellulose fibers to form crosslinked structures via the phosphoric acid groups, thereby obtaining crosslinked phosphorylated cellulose fibers, a (B) of breaking some or all of the crosslinked structures to obtain crosslink-broken phosphorylated cellulose fibers, and a (C) of performing a mechanical treatment on the crosslink-broken phosphorylated cellulose fibers to obtain fibrous cellulose having a fiber width of 1000 nm or less, wherein, in the (A), crosslinked structures in an amount of 0.05 mmol/g or more and 2.
    Type: Grant
    Filed: March 10, 2020
    Date of Patent: September 7, 2021
    Assignee: OJI HOLDINGS CORPORATION
    Inventors: Yuichi Noguchi, Ikue Homma, Yusuke Matsubara
  • Patent number: 11066535
    Abstract: An environmentally friendly, formaldehyde-free, aqueous binder composition that includes a carbohydrate, a crosslinking agent, and a pre-reacted product of an alcohol or polyol and monomeric or polymeric polycarboxylic acid or polyglycerol is provided. The pre-reacted product may include glycerol and esters of citric acid such a monoglyceryl citrate, diglyceryl citrate, and triglyceryl citrate as well as other higher molecular weight citric acid-based esters. The inclusion of the pre-reacted product in the binder composition helps to speed the crosslinking reaction, induces faster water evaporation, decreases the viscosity of the binder, helps to reduce the amount of water needed for application of the binder, decreases tackiness, and helps to achieve a maximum vertical expansion of the insulation pack in the transfer zone. The binder composition may be used in the formation of insulation materials and non-woven chopped strand mats.
    Type: Grant
    Filed: July 3, 2018
    Date of Patent: July 20, 2021
    Assignee: Owens Corning Intellectual Capital, LLC
    Inventors: Jesus Hernandez-Torres, Larry Todd Banner
  • Patent number: 11053324
    Abstract: Objects of the present invention are to provide a phosphoric acid-esterified fine cellulose fiber of which slurry shows superior transparency, and to provide a method for producing a phosphorylated fine cellulose fiber showing superior transparency with good efficiency and high yield. According to the present invention, there is provided a phosphoric acid-esterified fine cellulose fiber, of which 0.2 mass % aqueous dispersion shows a solution haze of 15% or lower.
    Type: Grant
    Filed: May 16, 2014
    Date of Patent: July 6, 2021
    Assignee: OJI HOLDINGS CORPORATION
    Inventors: Yuichi Noguchi, Yasutomo Noishiki, Ikue Homma
  • Patent number: 10875973
    Abstract: The present invention provides an ionic liquid represented by the following chemical formula (I): [(CH3)3N(CH2)2OH]+[NH2-L-COO]???(I) where L is —(CH2)2— or —(CH2)3—. The present invention also provides an ionic liquid composition containing an ionic liquid; and water. The ionic liquid is represented by the above chemical formula (I). A molar ratio of [(CH3)3N(CH2)2OH]+ to [NH2-L-COO]? is not less than 0.86 and not more than 1.12. A weight ratio of the water to the ionic liquid composition is not more than 4.7%. The present invention provides an ionic liquid capable of dissolving cellulose without an cellulose-degrading enzyme (namely, an enzyme capable of hydrolyzing cellulose).
    Type: Grant
    Filed: February 20, 2020
    Date of Patent: December 29, 2020
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Takahiro Aoki, Tomoko Kawashima, Haruka Kusukame, Yuko Taniike
  • Patent number: 10570563
    Abstract: In some embodiments, the present invention provides methods including the steps of providing cellulosic material, associating the cellulosic material with an organic acid (e.g., lactic acid) to form a mixture, and heating the mixture to a temperature between 100° C. and 120° C. for at least ten minutes to form a treated cellulosic material, wherein the water retention value of the treated cellulosic material is decreased by at least 10% as compared to untreated cellulosic material.
    Type: Grant
    Filed: May 13, 2016
    Date of Patent: February 25, 2020
    Assignee: University of Maine System Board of Trustees
    Inventors: Michael A. Bilodeau, Jonathan Spender
  • Patent number: 10458067
    Abstract: The present application relates to a cross-linked fiber and more specifically to fibers that have been subjected to cold caustic extraction (at less than 60° C.) to reduce the hemicellulose content of the fibers by at least 50% and then cross-linked with a cross-linking agent that is curable at a modest temperature, such as less than 160° C. The treated cross-linked fibers preferably have a hemicellulose content that is less than 5% by weight of the fiber. Preferable cross-linking agents are polyamide-epichlorohydrin (PAE) resins, polyamide-polyamine-epichlorohydrin (PPE) resins, and polydiallylamine-epichlorohydrin resins. The cross-linked fibers are readily dispersible in water even without fiberization and generally form webs and products having relatively few knits or knots. As such, the cross-linked fibers of the present invention are well suited for use in the manufacture of tissue webs and products, particularly wet-laid tissue webs and products.
    Type: Grant
    Filed: January 25, 2018
    Date of Patent: October 29, 2019
    Assignee: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Michael Andrew Zawadzki, Mike Thomas Goulet, Donald Eugene Waldroup, Cathleen Mae Uttecht, Stephen Michael Lindsay
  • Patent number: 10344430
    Abstract: A method for making a specialty fiber by activating pulp in an alkaline aqueous medium, then reacting it a water-soluble, multi-functional reagent able to bridge neighboring cellulose chain within a single fiber. The resultant specialty cellulose fibers have high intrinsic viscosity and may be used to make cellulose ethers, cellulose acetate, and viscose.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: July 9, 2019
    Assignee: RAYONIER PERFORMANCE FIBERS, LLC
    Inventors: Othman A. Hamed, Romuald Krzywanski
  • Patent number: 10156042
    Abstract: Methods of forming crosslinked cellulose include mixing a crosslinking agent with cellulose mat fiber fragments composed of hydrogen-bonded cellulose fibers and having a solids content of about 45-95% to form a substantially homogenous mixture of non-crosslinked, individualized cellulose fibers, drying the resulting mixture to 85-100% solids, then curing the dried mixture under conditions effective to crosslink the cellulose fibers. Some of such methods may include fragmenting a cellulose fiber mat to form the mat fragments. Systems include a mixing unit (such as a high-consistency mixer) configured to form, from the mat fragments and a crosslinking agent, a substantially homogenous mixture of non-crosslinked, individualized cellulose fibers and crosslinking agent, at ambient conditions, a drying unit to dry the substantially homogenous mixture to a consistency of 85-100%, and a curing unit and to cure the crosslinking agent to form dried and cured crosslinked cellulose fibers.
    Type: Grant
    Filed: December 29, 2015
    Date of Patent: December 18, 2018
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventors: Charles E. Miller, Alan D. Lovas
  • Patent number: 9995000
    Abstract: Methods of forming crosslinked cellulose include mixing a crosslinking agent with an aqueous mixture of cellulose fibers containing little to no excess water (e.g., solids content of 25-55%), drying the resulting mixture to 85-100% solids, then curing the dried mixture to crosslink the cellulose fibers. Systems include a mixing unit to form, from an aqueous mixture of unbonded cellulose fibers having a solids content of about 25-55% and a crosslinking agent, a substantially homogenous mixture of non-crosslinked, unbonded cellulose fibers and crosslinking agent; a drying unit to dry the substantially homogenous mixture to a consistency of 85-100%; and a curing unit and to cure the crosslinking agent to form dried and cured crosslinked cellulose fibers. Intrafiber crosslinked cellulose pulp fibers produced by such methods and/or systems have a chemical on pulp level of about 2-14% and an AFAQ capacity of at least 12.0 g/g.
    Type: Grant
    Filed: August 31, 2016
    Date of Patent: June 12, 2018
    Assignee: INTERNATIONAL PAPER COMPANY
    Inventor: Charles E. Miller
  • Patent number: 9695552
    Abstract: Wet strengthened fiber products, wet strengthening resins, and methods for making such wet strengthened fiber products and wet strengthening resins. The wet strengthened fiber product can include a fiber web and an at least partially cured wet strengthening resin, which prior to at least partially curing, the wet strengthening resin can include a polyamide-epihalohydrin (PAE) resin and a cationic styrene maleimide (SMI) resin. The PAE resin can include a reaction product of a polyamidoamine and an epihalohydrin and the cationic SMI resin can include a reaction product of a styrene maleic anhydride (SMA) copolymer and an amine. The wet strengthened fiber product can include the wet strengthening resin in an amount of about 0.05 wt % to about 5 wt %, based on a dried weight of the wet strengthened fiber product.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: July 4, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston
  • Patent number: 9611590
    Abstract: Creping adhesives and methods for making and using same are provided. The creping adhesive can include a first thermosetting polyamidoamine-epihalohydrin resin that includes a reaction product of a first epihalohydrin and a first polyamidoamine containing one or more secondary amine groups, a first thermoplastic polyamidoamine-epihalohydrin resin that includes a reaction product of a second epihalohydrin and a second polyamidoamine containing one or more secondary amine groups, and one or more re-wetting agents. The first thermosetting polyamidoamine-epihalohydrin resin can have a weight average molecular weight of about 800,000 to about 1,200,000 and a molar ratio of the first epihalohydrin to the secondary amine groups of about 0.002:1 to about 0.1:1. The first thermoplastic polyamidoamine-epihalohydrin resin can have a weight average molecular weight of about 40,000 to about 200,000 and a molar ratio of the second epihalohydrin to the secondary amine groups of about 0.001:1 to about 0.1:1.
    Type: Grant
    Filed: November 7, 2014
    Date of Patent: April 4, 2017
    Assignee: Georgia-Pacific Chemicals LLC
    Inventors: Clay E. Ringold, David F. Townsend, Cornel Hagiopol, Karla D. Favors, Thomas L. Wright
  • Patent number: 9034145
    Abstract: The invention provides methods and compositions for improving the characteristics of paper substrates. The method involves adding to a paper substrate an NCC-polymer. NCC-polymers have unique chemical properties which result in improvements in wet strength, dry strength and drainage retention properties of the paper substrates.
    Type: Grant
    Filed: October 1, 2013
    Date of Patent: May 19, 2015
    Assignee: Ecolab USA Inc.
    Inventors: David J. Castro, Rangarani Karnati, Shawnee M. Wilson, Weiguo Cheng, Mei Liu, Zhiyi Zhang
  • Publication number: 20150119838
    Abstract: A method of producing a modified pulp for use in paper or paper web products, the method comprising treating wood chips in an extraction process to remove hemicellose to form treated wood chips; and subjecting said treated wood chips to chemical or semichemical pulping to form a modified Kraft pulp wherein the amount of hemicellulose contained in the modified Kraft pulp is from about 5 to about 10% by dry weight of the modified pulp.
    Type: Application
    Filed: January 6, 2015
    Publication date: April 30, 2015
    Inventors: ZHENG TAN, GOPAL GOYAL, ALEXANDER A. KOUKOULAS
  • Patent number: 8992728
    Abstract: The cellulose nanofiber production method of the present invention comprises an oxidation treatment step for oxidizing native cellulose in a neutral or acidic reaction solution containing an N-oxyl compound and an oxidizing agent that oxidizes aldehyde groups, and a dispersion step for dispersing the native cellulose in a medium following the oxidation treatment step. According to the production method of the present invention, a cellulose nanofiber is provided that has long fibers and demonstrates high strength.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: March 31, 2015
    Assignee: The University of Tokyo
    Inventors: Akira Isogai, Tsuguyuki Saito
  • Patent number: 8980054
    Abstract: The present invention provides a modified cellulosic fiber having reduced hydrogen bonding capabilities. The modified fiber formed in accordance with the present invention may be useful in the production of tissue products having improved bulk and softness. More importantly, the modified fiber is adaptable to current tissue making processes and may be incorporated into a tissue product to improve bulk and softness without an unsatisfactory reduction in tensile.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: March 17, 2015
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: SeungRim Yang, JeongKyung Kim, Jian Qin
  • Patent number: 8981080
    Abstract: A process for producing a silane-modified cationized polymeric compound, the process including the steps of: (1) cationizing a water-soluble polymeric compound in a mixed solvent of a water-miscible organic solvent and water in the presence of an alkali to produce a slurry containing a cationized polymeric compound, (2) adding an aminosilane compound to the slurry or a cake produced therefrom, thereby treating the cationized polymeric compound with the aminosilane compound, (3) optionally adding an acid to the slurry obtained in step (1) or a product obtained in step (2), and (4) drying a product obtained in step (2) or a product obtained by performing step (3) after step (2), wherein the drying step (4) includes a primary drying treatment step of performing drying at a temperature of 50 to 140° C. under a degree of vacuum of 4.0 to 53.3 kPa, and a secondary drying treatment step of drying the product obtained following the primary drying treatment at a temperature of 90 to 155° C.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: March 17, 2015
    Assignee: LION Corporation
    Inventors: Takeshi Yamada, Youichirou Kohno, Yoko Osako, Yoshifumi Yamagata
  • Patent number: 8968518
    Abstract: A papermaking process includes, firstly, providing carboxylated cellulosic fibers with a carboxyl group content being in the range from 0.06 to 1.5 mmol/g. Then the carboxylated cellulosic fibers are employed to prepare mixing pulp including filler particles, wherein the content of the carboxylated cellulosic fibers in the mixing pulp is in the range from 40% to 100% by dry fiber weight of the mixing pulp. After that, paper is made employing the mixing pulp.
    Type: Grant
    Filed: August 28, 2013
    Date of Patent: March 3, 2015
    Assignee: Goldeast Paper (Jiangsu) Co., Ltd.
    Inventors: Yungchang F. Chin, Cui-Xia Wang, Ke-Cheng Fu, Pu Ma, Ren-Rong Wang
  • Publication number: 20150041089
    Abstract: The invention provides methods and compositions for improving the characteristics of paper substrates. The method involves adding to a paper substrate an NCC-polymer. NCC polymers have unique chemical properties which result in improvements in wet strength, dry strength and drainage retention properties of the paper substrates.
    Type: Application
    Filed: August 8, 2013
    Publication date: February 12, 2015
    Applicant: Ecolab USA Inc.
    Inventors: David A. Castro, Rangarani Karnati, Shawnee M. Wilson, Weiguo Cheng, Mei Liu, Zhiyi Zhang
  • Publication number: 20150034263
    Abstract: A method for fibrillation of cellulose includes the following steps: introducing fibre pulp of anionic cellulose at a consistency of 1 to 4% into a homogenizer, and homogenizing fibre pulp in the homogenizer at a pressure of 200 to 1000 bar, advantageously 300 to 650 bar, and by using 2 to 4 passes through for the same fibre pulp under these conditions, and after passes through, taking pulp from the homogenizer, which pulp has been fibrillated by homogenization to a degree than can be expressed as Brookfield viscosity exceeding 10,000 mPa.s (consistency 0.8%, 10 rpm).
    Type: Application
    Filed: February 13, 2013
    Publication date: February 5, 2015
    Inventor: Markus Nuopponen
  • Publication number: 20150020985
    Abstract: A process for improving the wet strength of paper or paperboard is disclosed, and compositions, methods, and products related to improved wet strength paper or paperboard are provided. The process includes, for example, contacting at least one side of the paper or paperboard with water or an aqueous composition to wet the paper or paperboard, contacting the wet paper or paperboard with a wet strength resin composition followed by drying the paper or paperboard. The resulted treated or coated paper or paperboard has comparable wet strength properties to that of paper or paperboard containing wet strength resin from a conventional wet end application.
    Type: Application
    Filed: July 9, 2014
    Publication date: January 22, 2015
    Inventors: Gregg A. Reed, William J. Haskins, Lakeisha D. Talbert
  • Publication number: 20140338851
    Abstract: A water dispersion paper made of wood pulp and/or non-wood pulp is characterized in that purified pulp containing ?-cellulose by 88 percent by weight or more accounts for 15 to 95 percent by weight of all pulp. The water dispersion paper has quick water dispersion property and high strength (printability) and its paper surface pH is 6 to 8 (neutral range).
    Type: Application
    Filed: August 4, 2014
    Publication date: November 20, 2014
    Inventors: Munenaka KOYAMA, Masaki KISHIMOTO, Yoshiaki ISHINO
  • Patent number: 8864945
    Abstract: A method of making a multi-ply wiper/towel product with cellulosic microfibers. The method includes compactively dewatering a nascent web that includes at least about 10% fibrillated cellulosic microfibers and has an apparently random distribution of fibers. The dewatered web having the apparently random distribution of fibers is applied to a transfer surface. The web is belt-creped from the transfer surface utilizing a generally planar polymeric creping belt provided with a plurality of perforations through the belt. The belt-creping step occurs under pressure in a belt creping nip defined between the transfer surface and the creping belt. The web is dried to form a dried web that includes a plurality of fiber-enriched hollow domed regions protruding from an upper side of the dried web. The hollow domed regions have a sidewall of a relatively high local basis weight formed along at least a leading edge thereof.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: October 21, 2014
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Joseph H. Miller, Daniel W. Sumnicht, Ayanna M. Bernard, Sanjay Wahal
  • Patent number: 8864944
    Abstract: A method of making a multi-ply wiper/towel product with cellulosic microfibers. The method includes compactively dewatering a nascent web that includes at least about 10% fibrillated cellulosic microfibers and has an apparently random distribution of fibers. The dewatered web having the apparently random distribution of fibers is applied to a transfer surface. The web is belt-creped from the transfer surface utilizing a creping belt. The belt-creping step occurs under pressure in a belt creping nip defined between the transfer surface and the creping belt. The web is dried to form a dried web having a plurality of fiber-enriched hollow domed regions protruding from an upper side of the dried web. The hollow domed regions have a sidewall of a relatively high local basis weight formed along at least a leading edge thereof.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: October 21, 2014
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Joseph H. Miller, Daniel W. Sumnicht, Ayanna M. Bernard, Sanjay Wahal
  • Publication number: 20140305605
    Abstract: A papermaking process includes, firstly, providing carboxylated cellulosic fibers with a carboxyl group content being in the range from 0.06 to 1.5 mmol/g. Then the carboxylated cellulosic fibers are employed to prepare mixing pulp including filler particles, wherein the content of the carboxylated cellulosic fibers in the mixing pulp is in the range from 40% to 100% by dry fiber weight of the mixing pulp. After that, paper is made employing the mixing pulp.
    Type: Application
    Filed: August 28, 2013
    Publication date: October 16, 2014
    Applicant: Goldeast Paper (Jiangsu) Co., Ltd
    Inventors: YUNGCHANG F. CHIN, CUI-XIA WANG, KE-CHENG FU, PU MA, REN-RONG WANG
  • Publication number: 20140302336
    Abstract: The present invention relates to a process for producing a dispersion comprising microfibrillated cellulose and nanoparticles wherein the process comprises the steps; providing a slurry comprising pre-treated cellulose fibers, adding nanoparticles to the slurry and treating the slurry by mechanical disintegration so that a dispersion comprising microfibrillated cellulose is formed in which the nanoparticles are being absorbed to the surface of the microfibrillated cellulose and/or being absorbed into the microfibrillated cellulose. The invention further relates to a dispersion produced according to the process, a paper or board product being coated with a coating comprising said dispersion and a paper or board product being produced from said dispersion as well as a composite comprising said dispersion.
    Type: Application
    Filed: October 25, 2012
    Publication date: October 9, 2014
    Inventors: Isto Heiskanen, Lars Axrup, Mari-Ann Norborg, Isabel Knöös
  • Publication number: 20140290882
    Abstract: Carboxylated, mercerized cellulose fiber having at least 12 meq/100 g of carboxyl substitution at the C-6 position of the anhydroglucose units, which includes at least 20% cellulose II, may be produced by catalytically carboxylating mercerized cellulose fiber in at least two catalytic carboxylation stages in a continuous series in which the pH is adjusted, and a primary oxoammonium salt catalyst (or precursor thereof) and secondary oxidant is added, at the beginning of each stage. Optionally, the carboxylated, mercerized cellulose may be made substantially free of aldehyde groups by means of a stabilizing step following the final carboxylation stage, in which aldehyde groups present in the fibers are converted to carboxyl groups.
    Type: Application
    Filed: March 29, 2013
    Publication date: October 2, 2014
    Applicant: WEYERHAEUSER NR COMPANY
    Inventor: S. Ananda Weerawarna
  • Patent number: 8785623
    Abstract: The present invention relates to ferromagnetic materials based on nano-sized bacterial cellulose templates. More specifically, the present invention provides an agglomerate free magnetic nanoparticle cellulose material and a method of forming such magnetic nanoparticle cellulose material. Further, the magnetic nonoparticles are physically attached on the cellulose material and evenly distribute.
    Type: Grant
    Filed: March 31, 2008
    Date of Patent: July 22, 2014
    Assignee: Cellutech AB
    Inventors: Richard T. Olsson, My Ahmed Said Samir Azizi, Lars Berglund, Ulf W. Gedde
  • Patent number: 8784611
    Abstract: The invention relates to a process for the production of paper or board comprising: adding a retention system to a stream of stock entering a paper machine head box, directing the stream of stock to a wire, de watering the stream of stock on the wire to form a paper web, and drying the paper web, wherein the retention system comprises a water-soluble cationic polymer, and nanocellulose acting like a micro particle, wherein the nanocellulose is added in an amount of less than 1% as active substance based on dry solids weight of the stock.
    Type: Grant
    Filed: November 3, 2010
    Date of Patent: July 22, 2014
    Assignee: Kemira OYJ
    Inventors: Ari Juppo, Ulf Stenbacka
  • Publication number: 20140186576
    Abstract: A nonwoven web of unmodified or cyanoethylated nanocellulose was found to have greater strength than kraft paper after immersion in oil at high temperature, making it useful as an insulation material for transformers. A mixture of nanocellulose and polymetaphenylene isophthalamide has further improved properties for use as an insulating material.
    Type: Application
    Filed: December 28, 2012
    Publication date: July 3, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: MARK ANDREW HARMER, Ann Y. Liauw, Byoung Sam Kang, Mark A. Scialdone
  • Publication number: 20140166222
    Abstract: A composition for use as a strengthening agent in the wet-end of papermaking which comprises a surface modified non-wood plant fiber and a starch component.
    Type: Application
    Filed: July 25, 2012
    Publication date: June 19, 2014
    Applicant: CARGILL, INCORPORATED
    Inventors: Rita Delrue, Peter Leonhardt, Dogan Sivasligil
  • Patent number: 8728273
    Abstract: The present invention relates to a process for the production of a composition wherein the process comprises pre-treating cellulosic fibers by mechanical, chemical and/or enzymatic treatment, mixing the pre-treated cellulosic fibers with pigments forming a dispersion and dispersing the dispersion of pre-treated cellulosic fibers and pigments whereby a composition comprising microfibrillated cellulose is formed. The invention further relates to a composition produced according to the process.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: May 20, 2014
    Assignee: Stora Enso OYJ
    Inventors: Isto Heiskanen, Kaj Backfolk
  • Patent number: 8728272
    Abstract: Although a microfibrillated cellulose has been conventionally added to a resin molded article for the purpose of improving the properties of resin such as strength, it is only possible to achieve the same level of strength as that of the resin itself. The object is to provide a resin molded article of greater strength. A molded article can be produced by blending resin with a microfibrillated cellulose having a type-II crystalline structure produced by treating a microfibrillated cellulose with an alkali solution. The molded article can be largely increased in tensile strength or flexural strength, tensile strain at break or flexural strain at break, and fracture toughness (work-of-fracture) compared to a molded article produced with resin containing a conventional microfibrillated cellulose.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: May 20, 2014
    Assignee: Kyoto University
    Inventors: Hiroyuki Yano, Antonio Norio Nakagaito
  • Patent number: 8679292
    Abstract: A method is conceived for producing hydrophobic lignocellulosics based on the graft copolymerisation of vinyl-type monomers onto the lignocellulosic backbone initiated by a redox couple initiator in aqueous medium. The green modification process can be carried out on any lignocellulosic material, for example, chemical, chemi-thermomechanical or thermo-mechanical pulps, bleached or unbleached. The technology disclosed in this invention yields individual lignocellulosic entities, for instance, hydrophobic pulp fibers, that can be used in combination with other fibers or polymers to produce nonwoven fibrous materials or composites. A significant aspect of the invention is that the modified lignocellulosic material possesses an efficient hydrophobic barrier and minimum interfacial energy to generate optimum adhesion when introduced to polymer resins.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: March 25, 2014
    Assignee: Fpinnovations
    Inventors: Wadood Y. Hamad, Ali Hayek
  • Patent number: 8663425
    Abstract: The present invention provides a method for easily and efficiently manufacturing microfibrous cellulose composite sheets. The present invention is a method for manufacturing microfibrous cellulose composite sheets, including a preparation process in which a polymer emulsion is mixed with an aqueous suspension including microfibrous cellulose, thereby preparing a mixed fluid, a papermaking process in which the mixed fluid is dehydrated on a porous base material through filtration, and a sheet including moisture is formed, and a drying process in which the sheet including moisture is heated and dried. In addition, the present invention is a method for manufacturing a microfibrous cellulose composite sheet laminate, in which the microfibrous cellulose sheets are thermally compressed and thus laminated as they are or after being provided with a polymer layer on at least one surface thereof.
    Type: Grant
    Filed: July 22, 2010
    Date of Patent: March 4, 2014
    Assignee: Oji Holdings Corporation
    Inventors: Yasutomo Noishiki, Takashi Kawamukai, Mitsuru Tsunoda, Yoshiyuki Asayama
  • Patent number: 8662316
    Abstract: A filter medium for liquid filtration of fine texture exhibiting high strength when wetted with water, which filter medium is comprised of a wet-laid nonwoven fabric. There is provided a filter medium for liquid filtration comprised of a wet-laid nonwoven fabric, characterized in that through blending of 0.5 to 40 wt. % of unbeaten natural fibers, it exhibits a very fine texture, a lowering ratio, calculated from bursting strength in ordinary state and bursting strength when wetted with water, of 30% or below, and a bursting strength, had when wetted with water, of 300 kPa or greater.
    Type: Grant
    Filed: July 21, 2004
    Date of Patent: March 4, 2014
    Assignee: Hokuetsu Paper Mills, Ltd.
    Inventors: Nobuyuki Sakadume, Eiko Meguro, Toshihiko Soyama
  • Publication number: 20140053995
    Abstract: The present invention is directed towards a method for spinning anionically modified cellulose comprising the steps of: (a) preparing a suspension of the anionically modified cellulose in a continuous phase; (b) subjecting the suspension to high shear rate; (c) performing spinning by extruding the cellulose suspension through a spinneret into a spinbath comprising a cationic complexing agent, and (d) isolating the sun fibres from the spin bath; as well as fibres obtained based on the method of the invention and paper or board products derived from such fibres.
    Type: Application
    Filed: March 8, 2012
    Publication date: February 27, 2014
    Applicant: Sappi Netherlands Services B.V.
    Inventor: Ian Graveson
  • Publication number: 20140041821
    Abstract: The present invention is directed towards a method for spinning neutral or anionically modified cellulose comprising the steps of: (a) preparing a suspension of the neutral or anionically modified cellulose in a continuous phase; (b) subjecting the suspension to high shear rate; (c) performing spinning by extruding the cellulose suspension into an airgap region comprising at least one heated zone to obtain spun fibres, (d) subjecting the spun fibres to at least one washing stages and (e) isolating the spun fibres from the at least one washing stages; as well as fibres obtained based on the method of the invention and paper or board products derived from such fibres.
    Type: Application
    Filed: March 8, 2012
    Publication date: February 13, 2014
    Applicant: SAPPI NETHERLANDS SERVICES B.V.
    Inventors: Ian Graveson, Philip Turner
  • Patent number: 8647470
    Abstract: Process for the production of paper, board and cardboard having high dry strength by addition of an aqueous composition comprising a nanocellulose and at least one polymer selected from the group consisting of the anionic polymers and water-soluble cationic polymers, draining of the paper stock and drying of the paper products.
    Type: Grant
    Filed: October 14, 2010
    Date of Patent: February 11, 2014
    Assignee: BASF SE
    Inventor: Anton Esser
  • Patent number: 8641869
    Abstract: A method for making particles containing carboxyalkyl cellulose, comprising blending a carboxyalkyl cellulose and a starch in water to provide an aqueous gel; treating the aqueous gel with a crosslinking agent to provide a crosslinked gel; drying the crosslinked gel to provide a solid; comminuting the solid to provide a plurality of particles.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: February 4, 2014
    Assignee: Weyerhaeuser NR Company
    Inventor: S Ananda Weerawarna