Abstract: The present invention relates to a new process for improving dewatering when manufacturing a film comprising high amounts of microfibrillated cellulose (MFC) without negatively impacting the film properties. According to the present invention a high amount of nanoparticles is used as an additive, optionally together with a polymer.

Abstract: An anti-static agent containing a polyether compound having a cationic group is provided. According to the present invention, an anti-static agent can be provided which has excellent compatibility with a resin material and a rubber material as well as excellent anti-static properties.

Abstract: The present invention concerns a process for the preparation of flocculated filler particles, wherein at least two aqueous suspensions of at least one filler material and at least one flocculating additive are combined.

Abstract: Papermaking additives that include various polymers and/or micropolymers are disclosed. The micropolymers may have a network structure that can be created by crosslinking or other means. The micropolymer may be an acrylamide based polymer having a boronic acid moiety. The weight average molecular weight of the micropolymer may be greater than 1,000,000.

Abstract: In various exemplary embodiments described herein, an absorbent structure (e.g., a paper material) having an applied absorbent material (e.g., an absorbent film) may be formed by treating a fiber (e.g., a cellulosic fiber) with an applied absorbent material forming system (also referred to as a “film forming system”), absorbent materials, compositions, methods of making absorbent materials, and the like.

Abstract: Water dispersible polyamides having carboxylic acid groups are disclosed. These are made by reacting polycarboxyl is acids or anhydrides thereof with amine containing monomer or an amide terminated polyamide under reaction conditions such that a few of the carboxylic acid groups are residual and can promote dispersion in water. These polyamides after dispersion can be chain extended to higher molecular weight polymers or can be terminally functionalized with reactive groups such as isocyanate, epoxy, vinyl, acetoacetonate, or silanol groups. Composites and hybrids of these polyamides with vinyl polymers are also disclosed and claimed.

Abstract: Paper strength systems including polyamine-polyamidoamine-epihalohydrin (PPAE) resin are disclosed. Also disclosed are methods of forming a paper including applying a strength system comprising PPAE to cellulosic fiber, as well as the resultant paper.

Abstract: Resin compositions, products made therewith, and methods for making such resin compositions and products. The resin composition can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound. The product can include a fiber web and an at least partially cured resin composition. The resin composition, prior to curing, can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound.

Abstract: A method of additively manufacturing a composite part is disclosed. The method comprises depositing, via a delivery guide, a segment of a continuous flexible line along a print path. The continuous flexible line comprises a non-resin component and a thermosetting-epoxy-resin component that is partially cured. The method also comprises maintaining the thermosetting-epoxy-resin component of at least the continuous flexible line being advanced toward the print path via the delivery guide below a threshold temperature. The method further comprises delivering a predetermined or actively determined amount of curing energy to the segment of the continuous flexible line at a controlled rate while advancing the continuous flexible line toward the print path to at least partially cure the segment of the continuous flexible line.

Abstract: A décor paper is prepared from a dispersion having improved optical performance, wherein the dispersion contains a TiO2 particle slurry; paper pulp; and a cationic polymer. The TiO2 particle slurry has a treated TiO2 particle with a surface area of at least about 30 m2/g and a cationic polymer; the treatment is an oxide of silicon, aluminum, phosphorus or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle. Comparable dispersions not using the TiO2 particle slurry described would require about 10% more treated TiO2 particle than a dispersion made with the described TiO2 particle slurry, paper pulp, and cationic polymer to achieve equivalent optical performance. These décor papers are useful in preparing paper laminates.

Abstract: The invention relates to a method for producing a core card (20) with at least the steps of a) providing a reprocessed fibrous mixture having at least the following properties: the Brecht-Holl fine fraction is at most 50% by weight; the Brecht-Holl long fiber fraction is at least 10% by weight; the Brecht-Holl short fiber fraction is at most 60% by weight; and the ISO 1762 ash fraction is at most 20% by weight, b) preparing at least one fibrous suspension, c) processing the at least one fibrous suspension by carrying out at least one de-ashing of the fibrous suspension until the ash fraction of the dry component of the fibrous suspension is at most 15% by weight, and by adding at least one additive to the at least one fibrous suspension d) producing the laminar system from the at least one fibrous suspension.

Abstract: The purpose of the present invention is to provide a silicone-modified epoxy resin which produces a cured product having excellent low gas permeability and strength; a composition of the resin; and an epoxy resin cured product obtainable by curing the composition. Disclosed is an epoxy resin represented by the following Formula (1): wherein R1 independently represents a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms; R2 independently represents a monovalent aliphatic hydrocarbon group having 1 to 12 carbon atoms; R3 independently represents a monovalent aliphatic hydrocarbon group having 1 to 12 carbon atoms or a monovalent aromatic hydrocarbon group having 6 to 12 carbon atoms; R4 represents an oxygen atom or a divalent hydrocarbon group having an aliphatic cyclic structure; R5 represents silicone chain having a norbornane epoxy structure at either end; and X represents an organic group having a norbornane epoxy group.

Abstract: The invention is related to poly(2-oxazoline-co-ethyleneimine)-epichlorohydrin copolymers and chemically-modified derivatives thereof as well as their uses in formation of non-silicone hydrogel coatings on silicone hydrogel contact lenses.

Abstract: The disclosure provides methods and compositions for increasing the strength of a paper sheet. The method involves adding to the paper sheet an amine-containing polymer. The amine-containing polymer interacts with materials such as glyoxalated polyacrylamide or starch to make the paper stronger in terms including tensile strength, surface strength and bulk strength.

Abstract: Methods for removing particulates from an aqueous suspension are provided. In at least one specific embodiment, the method can include mixing a polyamidoamine-epihalohydrin resin with an aqueous suspension comprising one or more first particulates to produce a treated mixture. An amount of the polyamidoamine-epihalohydrin resin in the treated mixture can be less than 500 g/tonne of the one or more first particulates. The method can also include recovering from the treated mixture a purified water having a reduced concentration of the one or more first particulates relative to the aqueous suspension, a purified first particulate product having a reduced concentration of water relative to the aqueous suspension, or both.

Abstract: The invention is related to poly(2-oxazoline-co-ethyleneimine)-epichlorohydrin copolymers and chemically-modified derivatives thereof as well as their uses in formation of non-silicone hydrogel coatings on silicone hydrogel contact lenses.

Abstract: The invention provides methods and compositions for increasing the strength of a paper sheet. The method involves adding to the paper sheet an amine containing polymer. The amine containing polymer interacts with materials such as GPAM or starch to make the paper stronger in terms including tensile strength, surface strength and bulk strength.

Abstract: Resin compositions, products made therewith, and methods for making such resin compositions and products. The resin composition can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound. The product can include a fiber web and an at least partially cured resin composition. The resin composition, prior to curing, can include a polyamide-epihalohydrin resin, a cationic styrene maleimide resin, and a urea-formaldehyde resin. The polyamide-epihalohydrin resin can include a reaction product of a polyamidoamine and an epihalohydrin. The cationic styrene maleimide resin can include a reaction product of a styrene maleic anhydride copolymer and an amine compound.

Abstract: The hydration of clays and shale in drilling operations may be inhibited by employing an aqueous based drilling fluid comprising a shale hydration inhibition agent comprising a polyaminopolyamide-epichlorohydrin resin, preferably the polyamino polyamide-epichlorohydrin resin is a reaction product of an aliphatic polyamine, an aliphatic polycarboxylic acid, and epichlorohydrin. The shale hydration inhibition agent should be present in the aqueous based drilling fluid in sufficient concentration to reduce the reactivity, such as swelling, of clays and shale when exposed to water-based drilling fluids.

Abstract: Disclosed is a décor paper with a self-dispersing pigment having an isoelectric point of at least about 8, where the inorganic particle is treated sequentially by (a) hydrolyzing an aluminum compound or basic aluminate to deposit a hydrous alumina surface and (b) adding a dual-functional compound. The dual functional compound has an anchoring group that attaches to the pigment surface and a basic amine group. Typically, the inorganic particle is titanium dioxide, TiO2. These décor papers are useful in making paper laminates.

Abstract: Disclosed is a paper laminate made from a décor paper, wherein the décor paper has a self-dispersing pigment with an isoelectric point of at least about 8. The inorganic particle is treated sequentially by (a) hydrolyzing an aluminum compound or basic aluminate to deposit a hydrous alumina surface; and (b) adding a dual-functional compound with an anchoring group that attaches the dual-functional compound to the pigment surface, and a basic amine group having a primary, secondary or tertiary amine.

Abstract: The present invention relates to a process of making paper or paperboard in which a cellulosic thin stock is provided and subjected to one or more shear stages and then drained and a moving screen to form a sheet which is dried, wherein the process employs a retention system which is applied to the thin stock, said retention system comprising as components i) a blend of different cationic polymers and ii) a microparticulate material, in which the blend of cationic polymers comprises, a) a cationic polymer having a charge density of at least 3 mEq per gram and a molar mass of greater than 700,000 Da, b) a cationic polymer having a charge density of below 3 mEq per gram and an intrinsic viscosity of at least 3 dl/g, wherein one of the components of the retention system is dosed into the thin stock after the final shearing stage and the other is dosed into the thin stock before the final shearing stage.

Abstract: Improvements to absorbent sheet manufacture include spraying a softener onto the web and providing a creping adhesive to a surface of a heated drying cylinder of a Yankee dryer such that a creping adhesive coating is formed, the creping adhesive comprising a poly(aminoamide)epihalohydrin (PAE) resin and a polyvinyl alcohol copolymer, wherein the polyvinyl alcohol copolymer includes functional repeat units selected from carboxylate repeat units, sulfonate repeat units as well as combinations of the comonomers. A preferred PAE resin is fully crosslinked PAE resin.

Abstract: Graft polymers whose grafting base is selected from the group consisting of polymers having vinylamine units, polyamines, polyamidoamines and polymers of ethylenically unsaturated acids and which comprise exclusively oligoalkylenimine side chains as side chains, process for the preparation of graft polymers having oligoalkylenimine side chains, at least one oligoalkylenimine which comprises a terminal aziridine group being grafted onto one of said grafting bases, and the use of the graft polymers thus obtainable as process chemicals in the production of paper, as antimicrobial coating materials, as builders in detergents and for the treatment of metal surfaces.

Abstract: Exemplary embodiments of the present disclosure include paper, methods of making paper, and the like.

Abstract: The disclosure provides a dispersion for making décor paper having improved optical performance without negatively impacting mechanical strength comprising a TiO2 particle slurry comprising a treated TiO2 particle having a surface area of at least about 30 m2/g, and a cationic polymer; wherein the treatment comprises an oxide of silicon, aluminum, phosphorus or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; paper pulp; and a cationic polymer; wherein the cationic polymer in the slurry and the cationic polymer in the dispersion are compatible; wherein for equal optical performance, the amount of treated TiO2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO2 particle of (a). These dispersions are useful in making décor paper that may be used in paper laminates.

Abstract: A method of cleaning residue from a surface includes providing a disposable cellulosic wiper including a percentage by weight of pulp-derived papermaking fibers. The pulp-derived papermaking fibers have a characteristic scattering coefficient of less than 50 m2/kg. The wiper also includes a percentage by weight of fibrillated regenerated independent cellulosic microfibers having a number average diameter of less than about 2 microns, and a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml. The microfibers are selected and present in amounts such that the wiper exhibits a scattering coefficient of greater than 50 m2/kg. The wiper is applied, with a predetermined amount of pressure, to a residue-bearing surface, and the surface is wiped, while applying the predetermined amount of pressure, to remove residue from the surface, such that the surface has less than 1 g/m2 of residue after being wiped under the predetermined amount of pressure.

Abstract: A disposable cellulosic wiper includes (a) a percentage by weight of pulp-derived papermaking fibers, and (b) a percentage by weight of fibrillated regenerated independent cellulosic microfibers having a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml and having a weight average diameter of less than 2 microns. The microfibers are further characterized in that 40% by weight thereof is finer than 14 mesh.

Abstract: A dry strength additive composition generally includes an anionic and/or amphoteric polyacrylamide having a molecular weight of less than 1,000,000 Daltons, wherein the amphoteric polyacrylamide has a net negative charge; a cationic and/or amphoteric starch; and a cationic non-starch polymer having a charge density greater than 1 milliequivalent per gram (meq/g) at a pH of 3. The components defining the composition can be added to a pulp suspension sequentially or as a pre-blended mixture.

Abstract: The invention relates to a method for dissolving cationic starch. In the method is obtained an aqueous polyelectrolyte solution comprising a synthetic cationic polymer, which has a charge density value of at least 0.1 meq/g, determined at pH3, the concentration of the cationic polymer in the polyelectrolyte solution being >2.5 weight-%, and the aqueous polyelectrolyte solution is brought together with cationic starch having a degree of substitution, DS, >0.1. The cationic starch is dissolved to the polyelectrolyte solution by heating and/or mixing. The invention relates also to a papermaking agent comprising 2-40 weight-% of synthetic cationic polymer which has a charge density value of at least 0.1 meq/g, determined at p H 3, and 2.5-25 weight-% cationic starch having degree of substitution, DS, >0.1. The papermaking agent is in slurry form and has a viscosity of 50-20 000 m Pas, measured at 25° C. with Brookfield DVI+ viscometer.

Abstract: A method of treating a cellulosic slurry to improve drainage is disclosed the method comprises adding a PEO to a cellulosic furnish in an amount of from 0.1 to 10 lbs per ton and adding a synthetic polymer to the furnish in an amount of from 0.1 to 10 lbs per ton, allowing the furnish to drain and forming a paper product.

Abstract: The present invention relates to a fixative composition and process for reducing hydrophobic and/or anionic substances in fiber-containing stock for making of paper, board or the like. The composition comprises a synthetic cationic polymer, which has a charge density of 3.0-24 meq/g, and a cationic non-degraded starch, which has charge density of 0.5-3.0 meq/g. The invention relates also to thick stock composition comprising fibers and a fixative composition according to the invention.

Abstract: The following steps are provided for producing a sheet cellulose material, for instance a handkerchief, comprising at least one adjuvant substance for the treatment of allergic rhinitis: generating an aqueous nano- or micro-emulsion containing nano- or micro-droplet of said at least one substance encapsulated in a protective layer comprising a non-ionic surface-active agent; applying the nano- or micro-emulsion to the cellulose material; evaporating water, leading to the formation of nano- or micro-capsules anchored to the cellulose fibers.

Abstract: The disclosure provides a dispersion for making décor paper having improved optical performance without negatively impacting mechanical strength comprising a TiO2 particle slurry comprising a treated TiO2 particle having a surface area of at least about 30 m2/g, and a cationic polymer; wherein the treatment comprises an oxide of silicon, aluminum, phosphorus or mixtures thereof; and the treatment is present in the amount of at least 15% based on the total weight of the treated titanium dioxide particle; paper pulp; and a cationic polymer; wherein the cationic 1.5 polymer in the slurry and the cationic polymer in the dispersion are compatible; wherein for equal optical performance, the amount of treated TiO2 particle in the dispersion is reduced by about 10% when compared to a dispersion not comprising the treated TiO2 particle of (a). These dispersions are useful in making décor paper that may be used in paper laminates.

Abstract: A dispersion having a cationic zeta potential for use as a base coating on a sheet of paper or paperboard as a primer for a functional barrier top coating, wherein the composition comprises an anionic pigment containing mixture comprising one or more anionic pigments in an amount of at least about 20% dry weight of the mixture, and one or more polyamine-epihalohydrin cationic wet strength resin.

Abstract: Debonding compositions and methods are disclosed for use in fibrous compositions such as paper-based products. In some instances, debonding agents can be combined with fibers (e.g., cellulose-based fibers) to produce a material having substantial wicking properties while decreasing fiber-fiber interactions that can require substantial energy to overcome in materials processing. In some instances, the debonding agent can act to create a paper-based product exhibiting a transition temperature in which the agent has a higher affinity for the fibers at temperatures above the transition temperature, and the product exhibiting enhaced wicking properties at temperatures below the transition temperature. As an example, a debonding agents can include polymers or other material exhibiting a lower critical solution temperature. The disclosed debonding agents can provide benefits over existing debonding agent formulations such as ammonium salts.

Abstract: The present invention provides tissue products having an MD/CD Tensile Ratio less than about 0.95, yet relatively high geometric tensile strength, such as geometric mean tensile strengths greater than about 1500 g/3? and more preferably greater than about 2000 g/3?. The combination of a tough, yet relatively supple sheet is preferably achieved by subjecting the embryonic web to a speed differential as it is passed from one fabric in the papermaking process to another, commonly referred to as rush transfer.

Abstract: The present invention provides tissue products having an MD/CD Tensile Ratio less than about 0.95, yet relatively high geometric tensile strength, such as geometric mean tensile strengths greater than about 1500 g/3? and more preferably greater than about 2000 g/3?. The combination of a tough, yet relatively supple sheet is preferably achieved by subjecting the embryonic web to a speed differential as it is passed from one fabric in the papermaking process to another, commonly referred to as rush transfer.

Abstract: A method of cleaning residue from a surface using a disposable cellulosic wiper that includes from about 25% or more by weight of pulp-derived papermaking fibers. The pulp-derived papermaking fibers have a characteristic scattering coefficient of less than 50 m2/kg. The wiper also has from about 25% to about 75% by weight of fibrillated regenerated independent cellulosic microfibers. The fibers are finer than 14 mesh, have a characteristic Canadian Standard Freeness (CSF) value of less than 175 ml, have a number average diameter of less than about 2 microns, and are present in amounts such that the wiper exhibits a scattering coefficient of greater than 50 m2/kg. The wiper is applied, with a predetermined amount of pressure, to a residue-bearing surface. The surface is wiped with the applied wiper to remove residue from the surface, such that the surface has less than 1 g/m2 of residue after being wiped.

Abstract: A process for producing paper, board and cardboard in the presence of an aqueous slurry of components comprising finely divided fillers coated at least partly with water-soluble amphoteric copolymers, which involves adding, further to the aqueous slurry of components comprising finely divided fillers, at least one cationic and/or amphoteric polymer comprising as structural element no esters of unsaturated carboxylic acids with quaternized amino alcohols to the fiber suspension prior to sheet forming.

Abstract: A composition comprising one or more high molecular weight resins and one or more low molecular weight resins in a ratio of about 1:99 to about 99:1 based on polymer actives, wherein said high molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of about 100,000 to about 5,000,000 Dalton and the low molecular weight resins are selected from the group consisting of glyoxylated polyacrylamide, crosslinked polyaminoamide and polyaminoamide-epihalohydrin resins having a molecular weight of less than about 100,000 Dalton and wherein the mole ratio of epihalohydrin to secondary nitrogen atoms in the high and low molecular weight polyaminoamide-epihalohydrin resins is less than about 0.5. and use of the composition for creping paper webs.

Abstract: Compositions that can be used in a paper material, which may include an anionic polymer, a polyamidoamine epihalohydrin resin, and a stabilizer, are disclosed. Methods for adding the compositions to a paper material are also disclosed.

Abstract: The invention is directed towards methods and compositions for improving the sizing of paper using PAE. Proper sizing of paper requires that a sizing agent adequately disperse so as to evenly distribute on the paper. Proper sizing also requires that the agent not cause runnability or chemical problems with other materials or equipment used in the papermaking process. PAE displays unexpected attributes that allow it to disperse sizing agents. Best of all it is not subject to the same overdose effect of typical emulsifiers such as cationic starch. As a result PAE is an excellent option for use in sizing paper.

Abstract: Although a microfibrillated cellulose has been conventionally added to a resin molded article for the purpose of improving the properties of resin such as strength, it is only possible to achieve the same level of strength as that of the resin itself. The object is to provide a resin molded article of greater strength. A molded article can be produced by blending resin with a microfibrillated cellulose having a type-II crystalline structure produced by treating a microfibrillated cellulose with an alkali solution. The molded article can be largely increased in tensile strength or flexural strength, tensile strain at break or flexural strain at break, and fracture toughness (work-of-fracture) compared to a molded article produced with resin containing a conventional microfibrillated cellulose.

Abstract: Methods of making paper or paperboard having enhanced dry strength are provided. An enzyme and a polymer including at least one of a cationic water-soluble polymer and an amphoteric water-soluble polymer can be added to a papermaking pulp to yield a treated pulp. The treated pulp can then be formed into paper or paperboard having a dry strength greater than paper or paperboard formed from papermaking pulp without the addition of the enzyme and polymer. Any suitable enzyme can be used, for example, a laccase or a cellulase. Any suitable polymer can be used. For example, at least one of a glyoxylated polyacrylamide (gPAM), a polyvinylamine, a decarboxylated polyacrylamide, and a dimethylamine-epichlorohydrin (epi-DMA).

Abstract: The present invention relates to a fixative composition and process for reducing hydrophobic and/or anionic substances in fibre-containing stock for making of paper, board or the like. The composition comprises a synthetic cationic polymer, which has a charge density of 3.0-24 meq/g, and a cationic non-degraded starch, which has charge density of 0.5-3.0 meq/g. The invention relates also to thick stock composition comprising fibres and a fixative composition according to the invention.

Abstract: A sheet of vegetable wool fiber is impregnated with a reactive mix made up of a partially or completely epoxidized vegetable oil and a hardener. The sheet can also be included in a panel. The method for manufacturing the sheet includes mixing an epoxidized vegetable oil and a hardener at a temperature higher than each one of the melting temperatures thereof and lower than each one of the breakdown temperatures thereof; and depositing the obtained mix on an assembly of vegetable wool fibers at a temperature higher than each one of the melting temperatures thereof and lower than each one of the breakdown temperatures thereof.

Abstract: The present invention relates to a process for production of paper, card and board comprising draining a filler-containing paper stock comprising at least one water-soluble polymer with sheet formation in the wire section and then pressing the paper in the press section, wherein a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble polymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) computes according to G(x)=48 +(x?15)·0.

Abstract: The invention provides methods and compositions for softening paper. An inventive composition and method of its use softens paper products (like tissue paper) by de-bonding its cellulose fibers and by improving the smoothness of the resulting paper. The invention forms a surfactant-polymer complex that attaches de-bonding non-ionic surfactants to cellulose fibers that would otherwise not be retained by the cellulose fibers. This complex prevents the fibers from bonding with each other and makes the paper product smoother. Best of all, the composition is environmentally superior and is a non-toxic.

Abstract: Methods and compositions for softening paper. An inventive composition and method of its use softens paper products (like tissue paper) by de-bonding its cellulose fibers and by improving the smoothness of the resulting paper. The invention forms a surfactant-polymer complex that attaches de-bonding non-ionic surfactants to cellulose fibers that would otherwise not be retained by the cellulose fibers. This complex prevents the fibers from bonding with each other and makes the paper product smoother. Best of all, the composition is environmentally superior and is a non-toxic.