With Additional Organic Reactant Patents (Class 162/167)
-
Patent number: 10556978Abstract: A magnesium suppressant/flocculant for use in separating dolomite from calcium phosphate. The magnesium suppressant/flocculant may be applied at a mine site prior to subjecting ore fractions to phosphate flotation or at a chemical plant after grinding.Type: GrantFiled: May 8, 2019Date of Patent: February 11, 2020Assignee: Arr-Maz Products, L.P.Inventors: Lucas R. Moore, Todd Parker, Leon Willis
-
Patent number: 9816233Abstract: The present invention relates to a containerboard packaging material comprising at least one non-wood alternative pulp material wherein said non-wood alternative pulp material is present in an amount of from about 5% to about 100% and wherein said material replaces at least a portion of conventional fiber materials.Type: GrantFiled: September 28, 2012Date of Patent: November 14, 2017Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Bo Shi, Mark M. Mleziva, Brent M. Thompson, Robert J. Zelenak
-
Patent number: 9562326Abstract: One or more embodiments include paper, methods of making paper, compositions, and the like, are provided. In various exemplary embodiments described herein, a paper material may be formed by treating a cellulosic fiber or an aqueous pulp slurry, with a strength including a polyamine resin.Type: GrantFiled: March 13, 2014Date of Patent: February 7, 2017Assignee: KEMIRA OYJInventors: Chen Lu, Scott Rosencrance, Vladimir Grigoriev
-
Patent number: 9506196Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.Type: GrantFiled: April 6, 2015Date of Patent: November 29, 2016Assignee: Georgia-Pacific Chemicals LLCInventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
-
Patent number: 9353483Abstract: Resin systems and methods for making and using same are provided. The method for making a paper product can include contacting a plurality of pulp fibers with a resin system. The resin system can include a first polyamidoamine-epihalohydrin resin and a second resin that can include a second polyamidoamine-epihalohydrin resin, a urea-formaldehyde resin, or a mixture thereof to produce a paper product. The first resin and the second resin can be sequentially or simultaneously contacted with the plurality of pulp fibers. The period for sequential addition between the first resin and the second resin is about 1 second to about 1 hour.Type: GrantFiled: April 6, 2015Date of Patent: May 31, 2016Assignee: Georgia-Pacific Chemicals LLCInventors: Cornel Hagiopol, David F. Townsend, Clay E. Ringold, James W. Johnston, Robert McDonald, Metric M. Simpson, Frederick S. Potter
-
Patent number: 8932433Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.Type: GrantFiled: July 17, 2012Date of Patent: January 13, 2015Assignee: Solenis Technologies, L.P.Inventors: Frank J. Sutman, John C. Harrington, Robert A Gelman
-
Patent number: 8916024Abstract: Methods and systems are provided for producing market pulp which include treatment of pulp with diverse ionic compounds before pulp drying. Cationically and anionically charged compounds can be used to treat pulp before pulp drying to improve pulp dewatering performance and efficiency in the production of market pulp. Market pulp products containing the treatment compounds are also described.Type: GrantFiled: November 26, 2012Date of Patent: December 23, 2014Assignee: Buckman Laboratories International, Inc.Inventors: Weiping Ban, Philip M. Hoekstra, Michael R. Elsey
-
Patent number: 7858141Abstract: A method of imparting sustained antimicrobial properties throughout a material or substrate using an antimicrobial polymerizable silicon-containing quaternary ammonium salt monomer in a solvent to form a quaternary ammonium salt solution; and mixing the silicon-containing quaternary ammonium salt solution with at least a second monomer or a polymer or coating a solid polymer. Depending on the nature of the second monomer or polymer and the reaction conditions; a copolymer with the first monomer or a homopolymer will form, such that a polymeric material, substrate or formed plastic product comprising the copolymer or homopolymer or blended with the coated concentrate will have sustained antimicrobial properties. This method can be used to make formed plastic products, thin layer films and other products having sustained antimicrobial properties.Type: GrantFiled: March 22, 2006Date of Patent: December 28, 2010Assignee: Biosafe Inc.Inventors: Gerry D. Getman, Matt Bootman, Donald Wagner, Jr., Thomas Ward
-
Patent number: 7323083Abstract: Resinous coatings can be applied to glass, exhibiting improved adhesion thereto, by including in the coating composition a sulfonic acid derived compound such as 2-acrylamido-2-methylpropanesulfonic acid or a salt thereof. Alternatively, the glass can be first coated with the sulfonic acid derived compound and thereafter the film-forming resin applied.Type: GrantFiled: October 28, 2003Date of Patent: January 29, 2008Assignee: The Lubrizol CorporationInventors: John S. Manka, Todd K. Yonker
-
Patent number: 7178140Abstract: Less data to transmit from a server to a virtual machine on a client is achieved by transmitting only those methods of classes that the executed application actually requires. This is accomplished by taking the classes of the targeted application and statically determining which methods of these classes, as well as of the library classes, can actually be used by the application. A method usage map of usable methods for each class is saved in a file. When the request to download is received from the client, the server consults this map and selectively transmits only those methods that are in it. This saves download time and memory space in the virtual machine and speeds up execution.Type: GrantFiled: May 31, 2002Date of Patent: February 13, 2007Assignee: Sun Microsystems, Inc.Inventor: Mikhail Dmitriev
-
Patent number: 7041197Abstract: A method for making paper to enhance its wet strength includes adding separately to a cellulosic paper pulp furnish the following additives to form a treated pulp: a cationic wet strength resin whose cationic sites bond to anionic sites of cellulose fibers contained in the paper pulp furnish, and a hydrophobically modified anionic polyelectrolyte whose anionic sites bond with cationic sites of the cationic wet strength resin.Type: GrantFiled: April 15, 2003Date of Patent: May 9, 2006Assignee: Fort James CorporationInventors: Bruce J. Kokko, David W. White
-
Patent number: 6770169Abstract: A method for improving the balance of tensile strength and tear strength of cured urea formaldehyde (UF) resin-bound glass fiber nonwoven mats; the glass fiber nonwoven mats produced by the method, and a phosphate-containing binder composition useful in the method. The mats are useful in, for example, the manufacture of roofing shingles.Type: GrantFiled: March 8, 2001Date of Patent: August 3, 2004Assignee: Dow Reichhold Specialty Latex LLCInventor: Karen L. Wallace
-
Patent number: 6699359Abstract: Disclosed are adhesive formulations as creping process aids for producing an absorbent creped cellulosic sheet having a high level of surface-perceived softness that comprises continuously forming a web of cellulosic papermaking fibers, adhering said web to a thermal drying means by means of adhesive compositions comprising polymers having at least one primary or secondary amine group in the backbone such as chitosan, plolyvinylamine, polyvinyl alcohol-vinyl amine and polyaminoamide in combination with crosslinking agents such as zirconium compounds having a valence of plus four including ammonium zirconium carbonate, zirconium acetylacetonate, zirconium acetate, zirconium carbonate, zirconium sulfate, zirconium phosphate, potassium zirconium carbonate, zirconium sodium phosphate and sodium zirconium tartrate and creping said treated web from said thermal drying means.Type: GrantFiled: February 2, 2000Date of Patent: March 2, 2004Assignee: Fort James CorporationInventors: Phuong Van Luu, Cristian M. Neculescu, Dawn M. Mews
-
Patent number: 6667384Abstract: The present invention contemplates poly(aminoamide) pre-polymers, polyamide polymers, a multi-step process for the synthesis of these pre-polymers and polymers using acrylates and at least one monomer containing at least two primary amines, and the resins resulting from the reaction of the polymers with an epihalohydrin. These resins may be used as wet strength resins and creping aids in the papermaking industry as well as surface additives for wool.Type: GrantFiled: December 27, 2001Date of Patent: December 23, 2003Assignee: Hercules IncorporatedInventors: Qu-Ming Gu, Armin Michel, Huai Nan Cheng, William W. Maslanka, Ronald R. Staib
-
Patent number: 6576086Abstract: Paper, board and cardboard are produced by draining paper stock containing interfering substances in the presence of fixing agents by a process in which the fixing agents used are reaction products which are obtainable by reacting amino- and/or ammonium-containing polymers selected from the group consisting of the polymers containing vinylamine units polyalkylene polyamines polyamidoamines ethyleneimine-grafted polyamidoamines which may be crosslinked, polydiallyldimethylammonium chlorides polymers containing dialkylaminoalkylacrylamide units or dialkylaminoalkylmethacrylamide units and polyallylamines and dicyandiamide and formaldehyde condensates with reactive sizes for paper in a weight ratio of polymer to reactive size of from 15,000:1 to 1:1, and the reaction products thus obtainable are used as fixing agents for water-soluble and for water-insoluble interfering substances in the production of paper, board and cardboard from paper stocks containing interfering substances.Type: GrantFiled: November 2, 1999Date of Patent: June 10, 2003Assignee: BASF AktiengesellschaftInventors: Roland Ettl, Hubert Meixner, Anton Esser, Rainer Scholz, Norbert Mahr, Ulrich Steuerle, Matthias Höne, Klaus Lorenz
-
Patent number: 6500303Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: May 18, 2000Date of Patent: December 31, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
-
Patent number: 6485555Abstract: The present invention relates to sizing of paper and more specifically to a substantially water-free and aqueous composition of a sizing agent where the composition contains a cellulose reactive sizing agent, a cationic compound with a molecular weight up to 10000 and a non-ionic compound. Additionally, the invention relates to the preparation and use of above-mentioned compositions.Type: GrantFiled: December 21, 2001Date of Patent: November 26, 2002Assignee: Akzo Nobel N.V.Inventors: Erik Lindgren, Sten Frölich, Rein Sikkar
-
Patent number: 6447644Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethylpiperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: October 10, 2001Date of Patent: September 10, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
-
Publication number: 20020112836Abstract: This invention concerns a method of increasing retention and drainage in a papermaking furnish comprising adding to the furnish an effective amount of a structurally rigid polymeric coagulant and an effective flocculating amount of a flocculant and a microparticle.Type: ApplicationFiled: December 20, 2000Publication date: August 22, 2002Inventors: William J. Ward, Andrew J. Dunham
-
Patent number: 6254724Abstract: Pulps or papers, especially chemimechanical or thermomechanical pulps or papers, which still contain lignin, have enhanced resistance to yellowing when they contain an effective stabilizing amount of a hindered amine compound which preferably is a nitroxide, a hydroxylamine or an ammonium salt thereof. This performance is often further enhanced by the presence of one or more coadditives selected from the group consisting of the UV absorbers, the polymeric inhibitors, the nitrones, the fluorescent whitening agents, metal chelating agents, sulfur containing stabilizers, metal salts and diene compounds. Combinations of nitroxides, hydroxylamines or their salts, benzotriazole or benzophenone UV absorbers and a metal chelating agent are particularly effective. Selected derivatives of 1-oxyl-2,2,6,6-tetramethyl-piperidin-4-ol and selected hydroxylamine salts are novel compounds and are surprisingly effective for this purpose.Type: GrantFiled: July 20, 1998Date of Patent: July 3, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Raymond R. Seltzer, Jean-Pierre Wolf, Cyril Heitner, John A. Schmidt, Peter F. McGarry, Glen T. Cunkle, Randall B. Nelson
-
Patent number: 6245874Abstract: A process for making paper with increased wet and dry strength by incorporating into the pulp suspension an ionic thermosettable resin which is the reaction product of dialdehyde and epihalohydrin, or epihalohydrin equivalent, with a copolymer containing monomer units derived by polymerization of monomers comprising acrylamide or alkyl-substituted acrylamide and diallylamine or an acid salt thereof. The paper has wet and dry strength greater than that of paper not containing the resin and has a higher repulpability index than wet strength paper that is essentially the same but contains conventional polyazetidinium ion containing wet strength resin instead of the ionic thermosettable resin.Type: GrantFiled: March 1, 2000Date of Patent: June 12, 2001Assignee: Hercules IncorporatedInventors: Ronald Richard Staib, Joseph Raymond Fanning, William Walter Maslanka
-
Patent number: 6228223Abstract: The present invention generally relates to an aqueous softening and antistatic agent composition comprising a quaternary ammounium compound and a biodegradable nonionic surfactant, which composition comprises a quaternary ammounium compound having the formula wherein R1 is a C6-C22 hydrocarbyl group; and X is halogen or SO42−, in a concentration of at least about 15% by weight. The surfactant is a linear alkoxylated fatty acid or a linear alkoxylated unsaturated alcohol. Furthermore a method for providing cellulosic materials with a reduced tendency to retain an electrostatic charge as well as providing said material with improved softness, wherein the cellulosic material is treated with said composition, and fluff obtainable from fluff pulp treated with the composition.Type: GrantFiled: July 30, 1998Date of Patent: May 8, 2001Assignee: Akzo Nobel NVInventors: Ingemar Thebrin, Lisbeth Ankarbratt
-
Patent number: 6114471Abstract: The strength of lignocellulosic materials is improved by treating them with water-soluble strengthening agents containing sulfonic units, and rendering these agents water-insoluble by reacting them with compounds containing azetidinium rings. Thus, a substantial reduction or elimination of the bleeding of said strengthening agents from the lignocellulosic materials when touched with wet hands or contacted under humid conditions is achieved.Type: GrantFiled: November 12, 1998Date of Patent: September 5, 2000Assignee: The Proctor & Gamble CompanyInventors: Blair Alex Owens, Dimitris Ioannis Collias, Andrew Julian Wnuk
-
Patent number: 5954921Abstract: The present invention relates to agents for the pulp and/or surface sizing of paper, which comprise aqueous, solventless dispersions of cationic polymers, and to a process for sizing paper by using said agent. The sizing agents according to the present invention which can be used both in pulp and surface sizing obtain as active substance copolymers ofa) 30-70 mole-% of a monomer Iwithb) 70-30 mole-% of a monomer II,and optionallyc) 0-20 mole-% of C.sub.8 -C.sub.30 monoolefins,andd) 0-10 mole-% of further monomers copolymerizable with a), b), and optionally c), the sum of monomers a), b), c), and d) amounting to 100 mole-%.Type: GrantFiled: February 25, 1997Date of Patent: September 21, 1999Assignee: Stockhausen GmbH & Co. KGInventors: Kurt Dahmen, Richard Mertens, Thomas Muller, Johann Schulte
-
Patent number: 5935384Abstract: A water-disintegrable paper which can be used in the same way as the ordinary toilet paper and shows excellent water disintegrability, wiping out property, feel, and moisture retaining property is provided, the water-disintegrable paper comprising: a water-disintegrable body paper; one or more components selected from glycerol, diglycerol, polyethylene glycol having an average molecular weight in a desired range, sorbitol, propylene glycol, 1,3-butylene glycol, glycine betaine, pyrrolidone carboxylic acid, pyrrolidone carboxylic acid salt, maltitol, and sodium lactate, as a humectant; and one or more components selected from sodium carboxymethylcellulose, a starch, a denatured starch, guar gum polyvinyl alcohol, and polyacrylamide, as a dry paper strength additive.Type: GrantFiled: July 21, 1997Date of Patent: August 10, 1999Assignee: Kawano Paper Co. LtdInventor: Kenji Taniguchi
-
Patent number: 5830320Abstract: The invention is a method of enhancing the strength of paper products, particularly the dry strength, without adversely affecting repulpability. It is also directed to the resulting products. It is particularly applicable but not limited to products with significant amounts of secondary fiber in the furnish. Preferably, about 10-30% of the fiber is separated from the furnish at some point prior to sheeting. This is treated with a cationic wet strength resin which is allowed to bond to the fiber. Cationic polyamide-epichlorohydrin resins are particularly useful. The treated fiber is them mixed with the untreated balance of the fiber at some point before the paper machine. Screnning fines on repulping do not normally exceed 2-3%.Type: GrantFiled: September 18, 1996Date of Patent: November 3, 1998Assignee: Weyerhaeuser CompanyInventors: David W. Park, Frank R. Hunter
-
Patent number: 5824192Abstract: Disclosed is a method for the production of paper and an adjuvant composition comprising the following ingredients: 30 to 80% by weight of phenolic resin or modified phenolic resin; 10 to 50% by weight of melamine resin; and 5 to 35% by weight of at least one naphthalene sulphonate salt. The ingredients are under granulated form or dissolved in an aqueous solution. The method comprises the step of admixing the adjuvant composition with a solution of one or several polyethylene oxide having a molecular weight varying from 1.times.10.sup.6 to 13.times.10.sup.6 and with an aqueous mixture comprising lignocellulosic particles and an aqueous medium to significantly improve the retention of particles such as fines and fibers, on a wire screen and the drainage of the aqueous medium.Type: GrantFiled: May 24, 1996Date of Patent: October 20, 1998Assignee: E. QU. I. P. International Inc.Inventor: Georges Radu
-
Patent number: 5626720Abstract: A method for the control of pitch in an aqueous system used in pulp or paper making is disclosed which comprises adding to the system, or to the pulp making or paper making machinery, a water soluble polymer derived from (a) an epihalohydrin, a diepoxide or a precursor of an epihalohydrin or diepoxide, (b) an alkyl amine having a functionality with respect to an epihalohydrin of 2 and (c) an amine which has a functionality with respect to an epihalohydrin greater than 2 and which does not possess any carbonyl groups.Type: GrantFiled: May 19, 1995Date of Patent: May 6, 1997Assignee: W.R. Grace & Co.-Conn.Inventor: Thord Gustav G. Hassler
-
Patent number: 5622786Abstract: An improved-strength, polymer-reinforced paper which includes fibers, of which at least about 30 percent on a dry weight basis are eucalyptus fibers; and from about 15 to about 60 percent by weight, based on the dry weight of the fibers, of a latex binder.Type: GrantFiled: November 30, 1994Date of Patent: April 22, 1997Assignee: Kimberly-Clark CorporationInventors: Robert E. Weber, Linda G. Harris, Amy B. Reed
-
Patent number: 5595828Abstract: An improved-strength, polymer-reinforced paper which includes fibers, of which at least about 30 percent on a dry weight basis are eucalyptus fibers; and from about 15 to about 60 percent by weight, based on the dry weight of the fibers, of a latex binder.Type: GrantFiled: May 26, 1995Date of Patent: January 21, 1997Assignee: Kimberly-Clark CorporationInventors: Robert E. Weber, Linda G. Harris, Amy B. Reed
-
Patent number: 5585456Abstract: A composition of matter (resin) useful for imparting wet strength to paper products is prepared from a polyamine, a polycarboxylic acid or ester, a dialdehyde and epichlorohydrin. Wet strengthened paper products made using the resin are more easily repulped than paper products made with conventional wet strength agents.Type: GrantFiled: September 8, 1995Date of Patent: December 17, 1996Assignee: Georgia-Pacific Resins, Inc.Inventors: Margaret A. Dulany, Chad E. Garvey, Clay E. Ringold, Ramji Srinivasan
-
Patent number: 5536370Abstract: Condensates of polyalkylenepolyamines which are obtainable by(a) partial amidation of polyalkylenepolyamines and(b) condensation of the partially amidated polyalkylenepolyamines with bifunctional or polyfunctional crosslinking agentsto give crosslinked polyalkylenepolyamines which, in 20% strength aqueous solution at 20.degree. C., have a viscosity of at least 100 mPa.s, processes for the preparation of the condensates of polyalkylenepolyamines by partial amidation of polyalkylenepolyamines with carboxylic acids, carboxylic esters, carboxylic anhydrides or carbonyl halides and crosslinking of the partially amidated polyalkylenepolyamines with bifunctional or polyfunctional crosslinking agents, from 0.001 to 10 parts by weight of a crosslinking agent being used per part by weight of the partially amidated polyalkylenepolyamines, and the use of the resulting condensates as drainage aids, flocculants, retention aids and fixing agents in papermaking.Type: GrantFiled: May 26, 1995Date of Patent: July 16, 1996Assignee: BASF AktiengesellschaftInventors: Guenter Scherr, Wolfgang Reuther, Primoz Lorencak, Dietmar Moench, Friedrich Linhart, Juergen Weiser
-
Patent number: 5518586Abstract: A urea-formaldehyde resin modified with a water-insoluble anionic phosphate ester is used as binder in the preparation of glass fiber mats using a hydroxyethyl cellulose white water system. High tear strength glass fiber mats can be produced in a hydroxyethyl cellulose white water system using such a binder.Type: GrantFiled: May 26, 1995Date of Patent: May 21, 1996Assignee: Georgia-Pacific Resins, Inc.Inventor: George E. Mirous
-
Patent number: 5498315Abstract: A method of enhancing the opacity of paper and paper of enhanced opaqueness is provided wherein a reaction product of dimerized acid and alkanol diamine an further including a surfactant, is added to a slurry of cellulose fibers in a papermaking process. A viscosity controlling gent may be added to the reaction product.Type: GrantFiled: May 12, 1995Date of Patent: March 12, 1996Assignee: Sequa Chemicals, Inc.Inventors: Louis R. Dragner, Bernard F. North
-
Patent number: 5494555Abstract: A method of enhancing the opacity of paper and paper of enhanced opaqueness is provided wherein a reaction product of fatty acid, diamine and a glyoxal product an further including a surfactant, is added to a slurry of cellulose fibers in a papermaking process.Type: GrantFiled: May 12, 1995Date of Patent: February 27, 1996Assignee: Sequa Chemicals, Inc.Inventors: Louis R. Dragner, Bernard F. North
-
Patent number: 5445878Abstract: A urea-formaldehyde resin modified with a water-insoluble anionic phosphate ester is used as binder in the preparation of glass fiber mats using a hydroxyethyl cellulose white water system. High tear strength glass fiber mats can be produced in a hydroxyethyl cellulose white water system using such a binder.Type: GrantFiled: September 20, 1993Date of Patent: August 29, 1995Assignee: Georgia-Pacific Resins, Inc.Inventor: George E. Mirous
-
Patent number: 5391225Abstract: An alkenylsuccinic acid emulsion sizing agent, wherein said alkenylsuccinic acid emulsion sizing agent has a solid concentration of at least 25% by weight, and comprises active components comprising an alkenylsuccinic acid present in an amount of at least 50 parts by weight, per 100 parts by weight of the total active components in the alkenylsuccinic acid emulsion sizing agent; and, wherein said alkenylsuccinic acid is obtained by dispersing a product prepared by reacting a branched inner olefin having from 9 to 18 carbon atoms with maleic anhydride in water using an amphoteric acrylamide-series polymer.Type: GrantFiled: October 13, 1993Date of Patent: February 21, 1995Assignee: Mitsubishi Oil. Co., Ltd.Inventors: Hatanaka Shigeto, Hideto Umekawa
-
Patent number: 5385754Abstract: This invention relates to a process for modifying lignocellulosic materials by a chemical treatment comprising treating the material sequentially or simultaneously with phthalic anhydride and a thermosetting resin at elevated temperature, and finally heat lignocellulosic material so produced can be formed into shapes or molds having excellent dimensional stability.Type: GrantFiled: September 17, 1993Date of Patent: January 31, 1995Assignee: BP Chemicals LimitedInventors: Harold A. Earl, Richard J. Salisbury
-
Patent number: 5232553Abstract: Polyvinylaminals, optionally as the formed copolymer with polyvinyl hemiaminals, and polyvinyl acetals are added to a papermaking pulp slurry to improve the retention of fines in the final paper product. This polymer is provided by reacting a poly(vinylamine) which can be a homopolymer or a copolymer containing vinyl alcohol and vinyl amine units with a monoaldehyde. The aldehyde, such as butyraldehyde, modifies the structure of the polymer and increases its hydrophobicity. The use of these polymers in papermaking involving the recycle of waste papers provides notable advantages in fines retention because of the high level of fines which normally accompany such recycle paper waste.Type: GrantFiled: January 24, 1992Date of Patent: August 3, 1993Assignee: Air Products and Chemicals, Inc.Inventors: John G. Smigo, Robert K. Pinschmidt, Andrew F. Nordquist, Timothy L. Pickering
-
Patent number: 5223097Abstract: A method for the control of pitch in an aqueous system used in pulp or paper making is disclosed which comprises adding to the system, or to the pulp making or paper making machinery, a water soluble polymer derived from (a) an epihalohydrin, a diepoxide or a precursor of an epihalohydrin or diepoxide, (b) an alkyl amine having a functionality with respect to an epihalohydrin of 2 and (c) an amine which has a functionality with respect to an epihalohydrin greater than 2 and which does not possess any carbonyl groups.Type: GrantFiled: June 20, 1989Date of Patent: June 29, 1993Assignee: W. R. Grace ABInventor: Thord G. G. Hassler
-
Patent number: 5026457Abstract: The present invention provides a process for sizing in the production of paper, cardboard, paperboard and other cellulose-containing materials with and without filling materials and/or pigments by natural or synthetic sizing agents under neutral to weakly basic pH conditions without the use of aluminum salts, wherein sizing is carried out with a combination of natural or synthetic sizing agents with a cationic dicyandiamide resin.Type: GrantFiled: February 28, 1989Date of Patent: June 25, 1991Assignee: SKW Trostberg AktiengesellschaftInventors: Rudolf Eichinger, Horst Michaud, Josef Seeholzer
-
Patent number: 4847143Abstract: A binder composition is disclosed, which comprises:(A) a copolymer emulsion which contains as its essential ingredients vinyl acetate, ethylene, and a monomer represented by the formula (1): ##STR1## wherein R.sub.1 is H or CH.sub.3 ; and R.sub.2 is H or an alkyl group having not more than 5 carbon atoms, the proportions of the respective ingredients being within the range of 55-96.5/3-40/0.5-5 on a weight basis;(B) a formaldehyde-free nitrogen-containing glyoxal resin;(C) a metal salt catalyst; and optionally(D) a higher alcohol sulfuric acid ester-based surfactant.Nonwoven fabrics and impregnated papers using the binder composition are also disclosed. The binder composition exhibits not only high resistance to water and solvents but also low residual free formaldehyde level, with an improvement in foamability being optionally attainable.Type: GrantFiled: June 4, 1986Date of Patent: July 11, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Katsuyoshi Watanabe, Takashi Miyaoka, Takeo Oyamada
-
Patent number: 4797176Abstract: A thermosetting size applyable to paper in a size press and curable at a temperature not in excess of about 280.degree. F. for 10 seconds is disclosed. This size comprises an aqueous emulsion comprising water having suspended therein aqueous emulsion copolymer particles of monoethylenically unsaturated monomers comprising hydroxy-functional monomer having an hydroxy number of at least about 20, and the balance of the monomers provides a water insoluble polymer having a glass transition temperature of from about -20.degree. C. to about 50.degree. C. The emulsion has a pH greater than about 2.5, preferably from 4.0 to 7.0, and a stoichiometric deficiency of an aminoplast cross-linking agent is used for cure. An acid curing catalyst is uniformly distributed in the size to speed the cure.Type: GrantFiled: August 10, 1987Date of Patent: January 10, 1989Assignee: DeSoto, Inc.Inventors: John E. Katchko, Charles W. Strobel, Thomas H. Plaisance
-
Patent number: 4783240Abstract: A lightweight paper having a superior opacity and printing opacity is provided, which lightweight paper comprises dry pulp, 0.015 to 1.2% by weight based on the pulp of an alumina polymer and 0.5 to 30% by weight based on the pulp of a coaggregate formed from agglomerated particles of urea-formal-dehyde polymer (A) and agglomerated particles of hydrated silicic acid (B) in a ratio of (A):(B) of 5:95 to 95:5.Type: GrantFiled: October 16, 1986Date of Patent: November 8, 1988Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Akio Kurokawa, Naoyuki Ifuku, Kenzo Seita, Youzi Nagata
-
Patent number: 4774272Abstract: There is provided a composite sheet material for fabrication of storage envelopes for magnetic recording media, e.g., floppy diskettes. The material has a low debris count, and a fast rate of static decay as well as high stiffness and strength.Type: GrantFiled: August 8, 1986Date of Patent: September 27, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Craig F. Lamphere, Jeffry S. Shaw, Leonard R. Swanson
-
Patent number: 4737239Abstract: Sizing agents devoid of anhydride groups, some of which are known and others are novel compounds, and which carry a single N,N-C.sub.6 -C.sub.22 alkyl(or alkenyl)amide group as hydrophobic substituent and at least one anionic group, in particular N,N-C.sub.6 -C.sub.22 dialkyl or N,N-C.sub.6 -C.sub.22 dialkenyl partial amides of a dicarboxylic acid, tricarboxylic acid or sulfocarboxylic acid, or the salts thereof, are particularly suitable, together with commercially available retention aids, for use in a process for pulp-sizing paper or cardboard at a pH of at least 6.5 of the fibre suspension, in the absence of e.g. aluminium sulfate, or in a process for surface-sizing paper.Type: GrantFiled: September 9, 1985Date of Patent: April 12, 1988Assignee: Ciba-Geigy CorporationInventors: Michael Bernheim, Hubert Meindl, Peter Rohringer
-
Patent number: 4735685Abstract: Anionic sizing agents containing anhydride groups, which are novel compounds and which contain a single N,N-C.sub.6 -C.sub.22 di(alkyl- or alkenyl)amido group, a N-C.sub.6 -C.sub.22 (alkyl- or alkenyl)amido group or a C.sub.6 -C.sub.22 -(alkyl or alkenyl) ester group as hydrophobic substituent, and at least one anionic group in acid or salt form, in particular the anhydride of a N,N-C.sub.6 -C.sub.22 dialkylamido- or N,N-C.sub.6 -C.sub.22 dialkenylamidocarboxylic acid, the anhydride of a N-C.sub.6 -C.sub.22 alkylamido- or N,N-C.sub.6 -C.sub.22 alkenylamidocarboxylic acid, or the C.sub.6 -C.sub.22 alkyl ester or C.sub.6 -C.sub.22 alkenyl ester of an aromatic tetracarboxylic acid anhydride or a salt thereof, are particularly suitable, together with commerically available retention aids, for use in a process for pulp-sizing or surface-sizing paper or cardboard.Type: GrantFiled: September 9, 1985Date of Patent: April 5, 1988Assignee: Ciba-Geigy CorporationInventors: Michael Bernheim, Hubert Meindl, Peter Rohringer
-
Patent number: 4431481Abstract: Cellulosic fibers, characterized by a lack of swellability and incapable of natural fiber-to-fiber bonding, are produced by a process which comprises treating an aqueous slurry of the fibers with a formaldehyde-free polymeric compound, heating the treated fibers to cause the polymeric compound to react with the fibers, and refiberizing to separate individual, treated fibers. The fibers are useful in the preparation of improved cellulosic webs characterized primarily by their increased bulk and improved softness.Type: GrantFiled: March 29, 1982Date of Patent: February 14, 1984Assignee: Scott Paper Co.Inventors: John E. Drach, Cleveland O'Neal, Jr.
-
Patent number: 4430158Abstract: What is described herein is a method of improving the wet tensile strength of sized glass fiber mats characterized by forming the mat from a plurality of glass fibers and a binder composition therefor which consists essentially of a urea-formaldehyde resin and about 0.01 to 5% by weight of a surfactant which is both highly water soluble and which wets the surfaces of sized glass fibers. The preferred surfactant is an anionic surfactant such as a sodium dodecylbenzene sulfonate. The glass mats thus made retained up to 79% of their tensile strength upon being subjected to severe wet conditions.Type: GrantFiled: September 14, 1981Date of Patent: February 7, 1984Assignee: GAF CorporationInventors: Philip A. Jackey, V. Robert Canfield
-
Patent number: 4416728Abstract: Self-extinguishing paper materials essentially consisting of paper pulps obtained from virgin chemical or reclaimed cellulose fibers and from red phosphorus powder encapsulated by a modified melaminic resin. These materials find practical industrial appliances especially as paperboard and in papers of various types requiring flame-retarding self-extinguishing characteristics.Type: GrantFiled: July 16, 1982Date of Patent: November 22, 1983Assignee: Saffa S.p.A.Inventors: Giancarlo Albanesi, Gianfranco Rinaldi