From Polyene Compound Patents (Class 162/169)
  • Patent number: 10669390
    Abstract: Provided is a unique class of foam materials characterized by regions of material unidirectionality. The foam materials are configured for a great variety of end-use applications as core materials or as materials in construction of multilayered structures. The novel and ingenious process for making the composite materials of the invention, permits modifying the foam materials to suite any specific end use.
    Type: Grant
    Filed: January 29, 2015
    Date of Patent: June 2, 2020
    Assignees: Yissum Research Development Company of the Hebrew University of Jerusalem Ltd., Melodea Ltd.
    Inventors: Shaul Lapidot, Sigal Roth Shalev, Rikard Slattegard, Oded Shoseyov, Clarite Azerraf, Ido Braslavsky, Victor Yashunsky
  • Patent number: 10563355
    Abstract: The present invention provides a treated fiber having reduced hydrogen bonding capabilities, which may be useful in the production of tissue products having improved bulk and softness. The treated fiber comprises a water-insoluble inorganic compound that is generated in situ by reacting at least one compound selected from the group consisting of a silicate, a silyl, a silane, and an alkaline metal and a precipitation agent in the presence of the fiber at or above the critical fiber consistency.
    Type: Grant
    Filed: October 16, 2019
    Date of Patent: February 18, 2020
    Assignee: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Jian Qin, Youquan Su, Liyi Shi
  • Patent number: 10487452
    Abstract: The present invention provides a treated fiber having reduced hydrogen bonding capabilities, which may be useful in the production of tissue products having improved bulk and softness. The treated fiber comprises a water-insoluble inorganic compound that is generated in situ by reacting at least one compound selected from the group consisting of a silicate, a silyl, a silane, and an alkaline metal and a precipitation agent in the presence of the fiber at or above the critical fiber consistency.
    Type: Grant
    Filed: January 16, 2018
    Date of Patent: November 26, 2019
    Assignee: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Jian Qin, Youquan Su, Liyi Shi
  • Patent number: 9951475
    Abstract: The disclosure provides methods and compositions for increasing the dry strength of paper. The invention utilizes a tailored strength agent whose size and shape is tailored to fit into the junction points between flocs of a paper sheet. The strength agents is in contact with the slurry for just enough time to collect at the junction points but not so much that it can migrate away from there.
    Type: Grant
    Filed: January 4, 2017
    Date of Patent: April 24, 2018
    Assignee: ECOLAB USA INC.
    Inventors: Weiguo Cheng, Mei Liu, Gary S. Furman, Jr., Robert M. Lowe
  • Patent number: 9458570
    Abstract: A modified filler composition for use in composites, such as paper and paper board, which is produced by reacting a filler material with a binder and a reactant material. Also, a method to produce composites, such as paper and paperboard, produced containing the modified filler composition is disclosed.
    Type: Grant
    Filed: October 11, 2011
    Date of Patent: October 4, 2016
    Assignees: Cerealus Holdings LLC, University of Maine System Board of Trustees
    Inventors: Anthony Jabar, Jr., Michael A. Bilodeau, Mark A. Paradis
  • Patent number: 9062170
    Abstract: The invention relates to thermally expandable thermoplastic microspheres comprising a polymer shell made from ethylenically unsaturated monomers encapsulating a propellant, said ethylenically unsaturated monomers comprising from 40 to 70 wt % of acrylonitrile, from 5 to 40 wt % of methacrylonitrile, from 10 to 50 wt % of monomers selected from the group consisting of esters of acrylic acid, esters of methacrylic acid and mixtures thereof, and said propellant comprising at least one of methane, ethane, propane, isobutane, n-butane and neo-pentane. The invention further relates to the production and use of the microspheres.
    Type: Grant
    Filed: May 3, 2011
    Date of Patent: June 23, 2015
    Assignee: AKZO NOBEL N.V.
    Inventors: Ove Nordin, Heléne Ström, Christina Nyholm, Claes Hammer
  • Patent number: 8894813
    Abstract: In general, the present disclosure is directed to creped tissue webs, and products produced therefrom. The creped webs and products are strong, soft, and have improved strike-through and absorbency properties. The improvement in both strike-through and absorbency is achieved in-part by increasing the basis weight of the web, while at the same time reducing the creping composition add-on levels.
    Type: Grant
    Filed: August 17, 2012
    Date of Patent: November 25, 2014
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Kenneth John Zwick, Peter Lee Carson, Gary Lee Shanklin, Michael William Smaby, Michael John Rekoske, Thomas Joseph Dyer, Mike Thomas Goulet
  • Publication number: 20140251563
    Abstract: The use in paper coatings is described of a mixture of an aqueous secondary dispersion of a polymer selected from polyalkylene carbonates, polyesters and polyethylene and an aqueous primary dispersion of an emulsion polymer having a glass transition temperature of below 50° C.
    Type: Application
    Filed: November 7, 2012
    Publication date: September 11, 2014
    Applicant: BASF SE
    Inventors: Dirk Lawrenz, Hubertus Kroener
  • Publication number: 20140216672
    Abstract: A modified filler composition used in papermaking is provided. The modified filler composition contains microfibrillated cellulose, filler, and latex having a glass transition temperature of less than 20° C. The dry weight of the microfibrillated cellulose is about 0.1% to about 10% that of the filler; the dry weight of the latex is about 0.1% to about 15% that of the filler.
    Type: Application
    Filed: December 12, 2013
    Publication date: August 7, 2014
    Applicant: Goldeast Paper (Jiangsu) Co., Ltd
    Inventors: YAN FENG, PENG ZHAO, XIANG-FEI LIU
  • Patent number: 8795471
    Abstract: A web-type composite intermediate is formed from fibers and plastic. The composite intermediate is formed by wet web formation from a substantially homogeneous liquid mixture which contains natural fibers, plastic particles having a diameter of less than approximately 1000 ?m, and an agent that improves compatibility between natural fibers and plastic particles. In addition, a method for forming a composite intermediate and the use of the composite intermediate are also described.
    Type: Grant
    Filed: April 20, 2010
    Date of Patent: August 5, 2014
    Assignee: Elastopoli Oy
    Inventors: Timo Ture, Eeva Hanni, Jouni Paltakari, Kari Luukko, Kaisa Herranen, Harri Kosonen, Markku Nikkila
  • Publication number: 20140178621
    Abstract: This invention relates to a paper substrate useful as a universal release liner, as well as methods of making and using the same.
    Type: Application
    Filed: February 28, 2014
    Publication date: June 26, 2014
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventors: STEVEN D. SCHULTZ, TIMOTHY J. BRADFORD, KOSARAJU KRISHNA MOHAN
  • Patent number: 8613834
    Abstract: A paper coating or binding formulation comprises an aqueous polymer dispersion comprising a copolymer obtained by polymerization of an unsaturated monomer and a carbohydrate derived compound and a tetrasulfonate-based fluorescent whitening agent. The carbohydrate derived compound can be selected from the group consisting of dextrins, maltodextrins, and mixtures thereof. Methods of preparing a paper coating or binding formulation and improving the whitening properties of paper are also provided. Furthermore, paper including a copolymer obtained by polymerization of an unsaturated monomer and a carbohydrate derived compound and a tetrasulfonate-based fluorescent whitening agent is also disclosed.
    Type: Grant
    Filed: April 3, 2008
    Date of Patent: December 24, 2013
    Assignee: BASF SE
    Inventors: Peter C. Hayes, Ralph Lewis De Jong
  • Patent number: 8568563
    Abstract: Methods of making the burnthrough resistant non-woven mat include forming the mat from glass fibers and at least two binders, a first binder having a vinyl component and a second binder having a strengthening component. The vinyl component may be, for example, ethylene vinyl chloride, and the strengthening component may be, for example, melamine formaldehyde. In one method, the vinyl component is added to the glass fibers by a beater addition process and the strengthening component is sprayed onto the glass fibers. The burnthrough resistant non-woven mat may be used in conjunction with an insulation blanket, and may be especially suited to use in insulating aircraft.
    Type: Grant
    Filed: January 14, 2013
    Date of Patent: October 29, 2013
    Assignee: Jonhs Manville
    Inventor: Glenda Beth Bennett
  • Publication number: 20130260072
    Abstract: This invention relates to a paper substrate useful as a universal release liner, as well as methods of making and using the same.
    Type: Application
    Filed: May 29, 2013
    Publication date: October 3, 2013
    Inventors: Steven D. Schultz, Timothy J. Bradford, Kosaraju Krishna Mohan
  • Patent number: 8529732
    Abstract: Process for the production of paper, board and cardboard having high dry strength by addition of a water-soluble cationic polymer and of an anionic polymer to a paper stock, draining of the paper stock and drying of the paper products, wherein an aqueous dispersion of at least one anionic latex and at least one degraded starch is used as the anionic polymer.
    Type: Grant
    Filed: February 4, 2010
    Date of Patent: September 10, 2013
    Assignee: BASF SE
    Inventors: Anton Esser, Joerg Nieberle
  • Patent number: 8518216
    Abstract: Methods for making a heterogeneous polymer blend comprising one or more anionic polymers, one or more cationic polymers, and one or more non-ionic polymers, which method comprises (a) adding to a non-neutral solution a first amount of polymerization initiator and one or more anionic or cationic monomers, wherein each monomer has the same charge; (b) a second amount of the polymerization initiator and one or more non-ionic monomers; (c) adding a third amount of the polymerization initiator and one or more ionic monomers that are oppositely charged from the monomers of (a); adding stepwise, a fourth amount of the polymerization initiator to react any residual monomer, and (e) neutralizing the resulting polymer blend. Also claimed are heterogeneous polymer blends containing polymers formed from one or more anionic, cationic, and non-ionic monomers, either polymerized in situ or separately and then combined.
    Type: Grant
    Filed: November 10, 2011
    Date of Patent: August 27, 2013
    Assignee: Hercules Incorporated
    Inventors: Frank J. Sutman, Joseph Mahoney
  • Patent number: 8506755
    Abstract: An absorbent composite material may be manufactured by applying a flexible absorbent binder polymer (FAB), also referred to herein as a flexible superabsorbent, during the creping step of conventional tissue manufacturing. As such, the costly process of applying FAB to a substrate by spraying or printing followed by drying may be eliminated. The creping step has the additional advantage of improving the flexibility and softness of the FAB treated fibrous web.
    Type: Grant
    Filed: December 28, 2010
    Date of Patent: August 13, 2013
    Assignee: Kimberly-Clark Worldwide, Inc
    Inventors: Dave Allen Soerens, Cathleen Mae Uttecht, Cynthia Suzanne Krueger
  • Patent number: 8475630
    Abstract: Compositions and methods of producing an optically-enhanced paper-based material are disclosed. The composition can include an optical brightening agent and an additive having an aromatic portion, where the aromatic portion is associated with an optical brightening agent. The paper-based material can exhibit a higher capacity for the optical brightening agent relative to a paper-based material that lacks the additive. Techniques for increasing optical brightening agent retention in a paper-based material are also disclosed. The techniques include using an additive having an aromatic portion, where the aromatic portion associates with an optical brightening agent so that the retention of the optical brightening agent is improved.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: July 2, 2013
    Assignee: NanoPaper, LLC
    Inventors: Lynn Reis, Gangadhar Jogikalmath, David S. Soane
  • Patent number: 8470219
    Abstract: Method for producing a fibrous web exclusively from cellulose fibers of natural origin, comprising the following procedural steps: forming an essentially uniformly thick, dry fiber layer from loose fibers having a low moisture content, pressing and embossing the fiber layer to obtain a fibrous web and forming an embossed pattern, moistening the fibrous web with a water-latex mixture having a high water concentration (75 to 99% by weight of water) and precipitating the latex in a drying process while the fibers are bonded inside and outside the fiber bond zones.
    Type: Grant
    Filed: February 16, 2005
    Date of Patent: June 25, 2013
    Inventor: Morton Rise Hansen
  • Patent number: 8460512
    Abstract: The invention provides a three layered reprographic paper having improved strength, stiffness and curl resistance properties, and a method for making same. The paper has a central core layer made largely of cellulose and bulked with a bulking agent such as a diamide salt. A starch-based metered size press coating is pressed on both sides of the core layer, wherein the starch has a high solid content. The coating forms a three layered paper having an I-beam arrangement with high strength outer layers surrounding a low density core.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: June 11, 2013
    Assignee: International Paper Company
    Inventors: Agne Swerin, Michael Herman, Jay C Song, Sen Yang, Peter F Lee, Ladislav Bednarik
  • Patent number: 8449721
    Abstract: Aqueous slurries of finely divided fillers which are at least partly covered by anionic latices, the slurries being obtainable by treating aqueous slurries of finely divided fillers with at least one anionic latex which comprises, incorporated in the form of polymerized units, at least one monomer comprising phosphonic and/or phosphoric acid groups, preparation of the aqueous slurries and their use as an additive to the paper stock in the production of filler-containing paper, filler-containing cardboard or filler-containing board by draining the paper stock.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: May 28, 2013
    Assignee: BASF SE
    Inventors: Juergen Schmidt-Thuemmes, Anton Esser, Joerg Nieberle
  • Patent number: 8444811
    Abstract: Sheet-like products are disclosed containing an additive composition. In accordance with the present disclosure, the additive composition is applied to a creping surface. A base sheet is then pressed against the creping surface for contact with the additive composition. The base sheet is then creped from the creping surface causing the additive composition to transfer to the base sheet. In particular, the additive composition is transferred to the base sheet in amounts greater than about 1% by weight, such as from about 2% to about 50% by weight. The additive composition can comprise, for instance, a thermoplastic polymer resin containing an aqueous dispersion, a lotion, a debonder, a softener, or mixtures thereof.
    Type: Grant
    Filed: June 14, 2007
    Date of Patent: May 21, 2013
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Thomas Joseph Dyer, Deborah Nickel, Kenneth J. Zwick, Mike T. Goulet, Jeffrey J. Timm, Perry H. Clough
  • Patent number: 8404084
    Abstract: A filler treatment process enhances the fixation of anionic latex on filler in a short time. Anionic polymer dispersions (latex) are added to papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. The anionic latexes applied by this process are totally and irreversibly fixed or bound onto the filler particles and the treated filler particle agglomerate to form an aggregated filler slurry which is stable over time. The latex-treated filler slurry can be added to papermaking furnishes at any point prior to the headbox of the paper machine or stored for later use. The latex-treated filler slurry improves filler retention, only slightly reduces sheet strength and improves sizing performance.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: March 26, 2013
    Assignee: FPInnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Publication number: 20130068409
    Abstract: A core paper comprising fiber material for producing a carrier material that can be laminated and that has at least one proportion of a reconstituted fiber material mixture and a wet sealer as a first additive, characterized in that the core paper comprises at least one active substance active on the boundary surface as a second additive for increasing capillarity at a weight proportion of 0.05% to 2% relative to the material.
    Type: Application
    Filed: May 5, 2011
    Publication date: March 21, 2013
    Applicant: PAPIERFABRIK JULIUS SCHULTE SOHNE GMBH & CO. KG.
    Inventor: Georg Pingen
  • Patent number: 8382950
    Abstract: The invention provides a method of recovering and recycling waste coating color from papermaking coating process for use as wet end filler. The inventive method overcomes many technical challenges inherent in using waste coating colors as wet end filler such as the coatings having fine pigments that hurts sheet strength more than regular filler, having strong anionic charge and tendency to disturb wet end chemistry, causing excessive foaming, and containing a large amount of hydrophobic binder particles that tend to agglomerate in the white water and deposit on papermaking equipment. The method involves mixing the coatings with fresh filler particles, adding de-foaming agent, adding cationic coagulant, then preflocculating the mixture. This process causes fresh filler particles, pigments and binders in waste coating color to agglomerate together and form stable flocs with defined particle size distribution.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: February 26, 2013
    Assignee: Nalco Company
    Inventor: Weiguo Cheng
  • Patent number: 8361278
    Abstract: A base sheet for food wrap products. The base sheet can include a pulp-derived papermaking fiber and a fibrillated regenerated cellulose microfiber having a CSF value of less than about 175 mL.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: January 29, 2013
    Assignee: Dixie Consumer Products LLC
    Inventors: Gregory M. Fike, Joseph R. Pounder, Daniel W. Sumnicht
  • Patent number: 8343312
    Abstract: Process for the production of filler-containing papers and filler-containing paper products by addition of an aqueous suspension of at least one finely divided polymer-pigment hybrid to a paper stock and drainage of the paper stock with sheet formation, the polymer-pigment hybrid being obtainable by milling an aqueous suspension of at least one inorganic pigment in the presence of at least one binder and, if appropriate, by drying the aqueous suspension thus obtainable and redispersing the dried polymer-pigment hybrid in water, and the use of the polymer-pigment hybrids thus obtainable as a filler for the production of filler-containing paper or filler-containing paper products.
    Type: Grant
    Filed: May 24, 2006
    Date of Patent: January 1, 2013
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Mahr, Dieter Meck, Rainer Blum, Ralf Hemel, Norbert Gispert, Juergen Schmidt-Thuemmes, Christoph Hamers
  • Publication number: 20120308790
    Abstract: The invention relates to a surface treatment composition for paper, board or other fibrous webs. The composition of the invention comprises particles which comprise an active material and a supporting material. The active material comprises a salt or a multivalent metal, such as a divalent or trivalent metal. In accordance with the invention, the supporting material is adapted to release the active material from the particles when subjected to heat and/or pressure and/or a change in pH. Consequently, the active material's adverse effects on the rheology of the composition are avoided while its desired effects on the surface characteristics are retained or enhanced.
    Type: Application
    Filed: February 11, 2011
    Publication date: December 6, 2012
    Applicant: STORA ENSO OYJ
    Inventors: Kaj Backfolk, Isto Heiskanen, Nina Miikki
  • Patent number: 8197641
    Abstract: Process for treating aqueous slurries of finely divided fillers, an aqueous dispersion of at least one latex and an aqueous slurry of at least one starch being metered separately from one another into an aqueous slurry of at least one finely divided filler.
    Type: Grant
    Filed: July 4, 2008
    Date of Patent: June 12, 2012
    Assignee: BASF SE
    Inventors: Anton Esser, Hans-Joachim Haehnle, Marc Schroeder
  • Patent number: 8192580
    Abstract: A process for treating aqueous slurries of finely divided fillers, wherein the treatment is carried out by heating an aqueous slurry of at least one finely divided filler and then by adding an aqueous dispersion of at least one latex.
    Type: Grant
    Filed: July 4, 2008
    Date of Patent: June 5, 2012
    Assignee: BASF SE
    Inventors: Anton Esser, Hans-Joachim Haehnle, Marc Schroeder
  • Publication number: 20120118520
    Abstract: The present invention provides a method for easily and efficiently manufacturing microfibrous cellulose composite sheets. The present invention is a method for manufacturing microfibrous cellulose composite sheets, including a preparation process in which a polymer emulsion is mixed with an aqueous suspension including microfibrous cellulose, thereby preparing a mixed fluid, a papermaking process in which the mixed fluid is dehydrated on a porous base material through filtration, and a sheet including moisture is formed, and a drying process in which the sheet including moisture is heated and dried. In addition, the present invention is a method for manufacturing a microfibrous cellulose composite sheet laminate, in which the microfibrous cellulose sheets are thermally compressed and thus laminated as they are or after being provided with a polymer layer on at least one surface thereof.
    Type: Application
    Filed: July 22, 2010
    Publication date: May 17, 2012
    Applicant: OJI PAPER CO., LTD.
    Inventors: Yasutomo Noishiki, Takashi Kawamukai, Mitsuru Tsunoda, Yoshiyuki Asayama
  • Patent number: 8133353
    Abstract: A creped paper product is provided according to the invention. The creped paper product comprises a result of creping a web of fibers comprising synthetic fibers to provide a creped paper product having a stretch of at least 3% in the machine direction according to TAPPI test T494. The web of fibers can include about 0.5 wt. % to 100 wt. % synthetic fibers based on the total weight of the fibers. In addition, the web of fibers can contain about 0.5 wt. % to about 10 wt. % of synthetic fibers and about 90 wt. % to about 99.5 wt. % of cellulosic fibers. When the web of fiber includes a mixture of synthetic fibers and cellulosic fibers, the creped paper product can be provided having a tear strength in the machine direction according to TAPPI test T494 at least 10% greater than an otherwise identical creped paper product that does not contain synthetic fibers. A method for forming a creped paper product is provided according to the invention.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: March 13, 2012
    Assignee: Wausau Paper Corp.
    Inventors: John James Blanz, Thomas Brod, Emerson S. Brooks
  • Publication number: 20120012264
    Abstract: Disclosed is a print medium for high speed, digital inkjet printing, which has high brightness and is resistant to yellowing. The print medium includes a base paper formed from a fiber furnish containing at least 30% by weight of mechanical pulp, and a coating layer formed on at least one surface of the base paper. The coating layer contains a metallic salt, a combination of two different binders at a predetermined ratio, and at least one inorganic pigment. A method of making the print medium is also disclosed.
    Type: Application
    Filed: July 17, 2009
    Publication date: January 19, 2012
    Inventors: Xiaoqi Zhou, Xulong Fu, Dave Edmondson
  • Patent number: 8066849
    Abstract: A wet-laid absorbent sheet includes a mixture of pulp-derived papermaking fibers and synthetic polymer fibers, a strength agent selected from carboxymethylcellulose and anionic starch as well as an epihalohydrin/amine functional wet strength resin. Also included is an anionic olefin copolymer resin effective to increase the wet/dry tensile ratio of the sheet.
    Type: Grant
    Filed: June 11, 2009
    Date of Patent: November 29, 2011
    Assignee: Georgia-Pacific Consumer Products LP
    Inventors: Bruce J. Kokko, Daniel W. Sumnicht
  • Patent number: 8025768
    Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: September 27, 2011
    Assignee: Fpinnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Patent number: 8007638
    Abstract: A method of manufacturing a cellulosic sheet having at least one of hydrophobic and oleophobic properties comprises the steps of depositing a stock of cellulosic fibers onto at least one forming fabric at an impingement zone and forming a web therefrom in a formation process; combining a water-based composition comprising an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon with the web at a preselected combination stage prior to a heating stage at which the web is subjected to a temperature exceeding 60° C.; and heat-curing the composition with the web during a drying process. A water-based composition for imparting at least one of hydrophobic and oleophobic properties to a cellulosic sheet during manufacture comprises an adhesion promoter, an organic nanoparticulate polymer and a fluorocarbon. A cellulosic sheet or layer thereof has at least one of hydrophobic and oleophobic properties. Improved resistance of cellulosic sheets to oil or water is obtained.
    Type: Grant
    Filed: July 4, 2006
    Date of Patent: August 30, 2011
    Assignee: AstenJohnson, Inc.
    Inventors: Samuel Baker, Jackson Graham, Dietmar Wirtz
  • Patent number: 7988826
    Abstract: The invention improves a sizing effect even on paper containing no internal sizing agent and improves productivity by making solution polymerization in a small amount of an organic solvent. The invention provides a cationic surface sizing agent composed of a copolymer obtained by solution polymerization of (a) 15 to 35% by weight of a tertiary amino group-containing monomer, (b) 30 to 85% by weight of C1 to C4 alkyl(meth)acrylate, and (c) 1 to 50% by weight of styrenes in an organic solvent in the presence of a chain transfer agent. The copolymer may be subjected to cationization treatment with a quaternization agent. As a constituent monomer of the copolymer, 0 to 20% by weight of another copolymerizable vinyl monomer (d) may be contained. The cationic surface sizing agent is applied to paper.
    Type: Grant
    Filed: March 30, 2006
    Date of Patent: August 2, 2011
    Assignee: Harima Chemicals, Inc.
    Inventors: Kazushige Inaoka, Tomohiko Nakata, Yoshiharu Hashiguchi
  • Publication number: 20110088861
    Abstract: The invention provides a method of recovering and recycling waste coating color from papermaking coating process for use as wet end filler. The inventive method overcomes many technical challenges inherent in using waste coating colors as wet end filler such as the coatings having fine pigments that hurts sheet strength more than regular filler, having strong anionic charge and tendency to disturb wet end chemistry, causing excessive foaming, and containing a large amount of hydrophobic binder particles that tend to agglomerate in the white water and deposit on papermaking equipment. The method involves mixing the coatings with fresh filler particles, adding de-foaming agent, adding cationic coagulant, then preflocculating the mixture. This process causes fresh filler particles, pigments and binders in waste coating color to agglomerate together and form stable flocs with defined particle size distribution.
    Type: Application
    Filed: December 22, 2010
    Publication date: April 21, 2011
    Inventor: Weiguo Cheng
  • Patent number: 7909962
    Abstract: The present invention refers in one embodiment to a method of manufacturing multilayer coated papers and paperboards, but excluding photographic papers and pressure sensitive copying papers, that are especially suitable for printing, packaging and labeling purposes, in which at least two curtain layers selected from aqueous emulsions or suspensions are formed into a composite, free-falling curtain and a continuous web of basepaper or baseboard is coated with the composite curtain, and paper or paperboard thereby obtainable.
    Type: Grant
    Filed: June 4, 2008
    Date of Patent: March 22, 2011
    Inventor: Robert Urscheler
  • Publication number: 20100263817
    Abstract: Tissue products are disclosed containing an additive composition. The additive composition, for instance, comprises an aqueous dispersion containing an alpha-olefin polymer, an ethylene-carboxylic acid copolymer, or mixtures thereof. The alpha-olefin polymer may comprise an interpolymer of ethylene and octene, while the ethylene-carboxylic acid copolymer may comprise ethylene-acrylic acid copolymer. The additive composition may also contain a dispersing agent, such as a fatty acid. The additive composition may be incorporated into the tissue web as the web is being formed. Alternatively, the additive composition may be topically applied to the web in a post processing operation. For instance, in one embodiment, the additive composition may be applied to the web as a creping adhesive during a creping operation.
    Type: Application
    Filed: July 1, 2010
    Publication date: October 21, 2010
    Applicant: KIMBERLY-CLARK WORLDWIDE, INC.
    Inventors: Michael Alan Hermans, Michael J. Rekoske, Thomas Joseph Dyer
  • Publication number: 20100186915
    Abstract: A process for treating aqueous slurries of finely divided fillers, wherein the treatment is carried out by heating an aqueous slurry of at least one finely divided filler and then by adding an aqueous dispersion of at least one latex.
    Type: Application
    Filed: July 4, 2008
    Publication date: July 29, 2010
    Applicant: BASF SE
    Inventors: Anton Esser, Hans-Joachim Haehnle, Marc Schroeder
  • Publication number: 20100181038
    Abstract: Process for treating aqueous slurries of finely divided fillers, an aqueous dispersion of at least one latex and an aqueous slurry of at least one starch being metered separately from one another into an aqueous slurry of at least one finely divided filler.
    Type: Application
    Filed: July 4, 2008
    Publication date: July 22, 2010
    Applicant: BASF SE
    Inventors: Anton Esser, Hans-Joachim Haehnle, Marc Schroeder
  • Publication number: 20100175845
    Abstract: The instant invention relates to storage stable aqueous optical brightener/PVOH solutions of low viscosity which may be used directly by the papermaker, in that they can be metered by pump directly into a coating composition, and which provide coated papers of a surprisingly high whiteness
    Type: Application
    Filed: July 24, 2007
    Publication date: July 15, 2010
    Applicant: Clariant Finance (BVI) Limited
    Inventors: Mariela Gauto, Andrew Clive Jackson, Alec Stewart Tindal
  • Patent number: 7740740
    Abstract: The invention provides a low density paperboard material and associated method for use in producing an insulated container, and is especially well-suited for making cups. The paperboard material comprises a paperboard web including wood fibers and expanded microspheres, and has a relatively low density ranging from about 6 to about 10 lb/3 MSF/mil, a relatively high caliper ranging from about 24 to about 35 mil, and an internal bond strength of at least about 80×10?3 ft-lbf., preferably at least 100×10?3 lft-lbf. For applications such as cups the material is also coated on one or both sides with a barrier coating, preferably low density polyethylene, to limit liquid penetration into the web. The low density paperboard material of the invention is convertible for manufacture of containers, particularly cups, and exhibits insulative properties comparable to higher cost materials conventionally used to make cups.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: June 22, 2010
    Assignee: International Paper Company
    Inventors: Kosaraju Krishna Mohan, Alexander A Koukoulas, Peter Matthew Froass, David Verd Reed
  • Patent number: 7682486
    Abstract: The invention provides a low density paperboard material and associated method for use in producing an insulated container, and is especially well-suited for making cups. The paperboard material comprises a paperboard web including wood fibers and expanded microspheres, and has a relatively low density ranging from about 6 to about 10 lb/3MSF/mil, a relatively high caliper ranging from about 24 to about 35 mil, and an internal bond strength of at least about 80×10?3 ft-lbf., preferably at least 100×10?3 lft-lbf. For applications such as cups the material is also coated on one or both sides with a barrier coating, preferably low density polyethylene, to limit liquid penetration into the web. The low density paperboard material of the invention is convertible for manufacture of containers, particularly cups, and exhibits insulative properties comparable to higher cost materials conventionally used to make cups.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: March 23, 2010
    Assignee: International Paper Company
    Inventors: Kosaraju Krishna Mohan, Alexander A Koukoulas, Peter Matthew Froass, David Verd Reed
  • Patent number: 7641765
    Abstract: Paper coated with a coating slip containing at least one optical brightener is produced by a process in which base paper or precoated paper is treated, before application of the coating slip containing optical brightener, with at least one substance which enhances the efficiency of optical brighteners.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: January 5, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Thierry Blum, Friedrich Linhart, Stephan Frenzel
  • Patent number: 7547375
    Abstract: Making mats using glass fibers having a diameter of about 13+/?3 microns, bound with a binder formed from a homopolymer or a copolymer of polyacrylic acid and a polyol produces fibrous nonwoven mats having high tensile strength and also an unexpected high flame resistance considering the amount of oxygen in the binder. Mats of the present invention pass the National Fire Protection Association's (NFPA) Flammability Test. Tabor stiffness of these mats is greater than about 40, preferably greater than about 50 and most preferably greater than about 55. Air permeability of the mats is preferably within the range of about 500 to about 800 CFM/sq. ft. Methods of making the mat are also disclosed.
    Type: Grant
    Filed: June 19, 2007
    Date of Patent: June 16, 2009
    Assignee: Johns Manville
    Inventors: Alan Michael Jaffee, Richard Emil Kajander
  • Patent number: 7491293
    Abstract: A multi-layered paperboard having a high brightness and exceptional uniformity. The white topped paperboard has a base layer(s) made from wood pulp and a top fibrous layer made of unbleached wood fiber, filler and a binder to create a top fibrous layer of sufficient uniformity at moderate brightness levels. The top fibrous layer optionally contains a coagulant and/or a retention aid. In a preferred embodiment, the top fibrous layer of the multi-layered paperboard product is coated with a coating of additional fillers and binders to produce the desired level of brightness and uniformity. The invention also includes a process for making a multi-layered paperboard.
    Type: Grant
    Filed: September 15, 2005
    Date of Patent: February 17, 2009
    Assignee: MeadWestvaco Corporation
    Inventors: Bruce W. Babcock, Tricia W. Thomas
  • Patent number: 7473333
    Abstract: The present invention refers to a method of producing a coated paper or paperboard, but excluding photographic papers, comprising the steps of: (a) forming a free flowing curtain comprising at least one layer, whereby the composition forming at least one layer of the free flowing curtain has a high shear viscosity of at least about 50 mPa·s, and (b) contacting the curtain with a continuous web substrate of basepaper and paperboard.
    Type: Grant
    Filed: October 16, 2003
    Date of Patent: January 6, 2009
    Assignee: Dow Global Technologies Inc.
    Inventors: Robert Urscheler, Pekka J. Salminen, Jamel F. Attai, John A. Roper, III
  • Publication number: 20080302494
    Abstract: The present disclosure includes a regenerated cotton board material comprised of dry cut cotton lint fiber, and wood fiber. The regenerated cotton board material may further include non-cellulosic fibers such as synthetic fibers or other natural fibers. In an alternate embodiment, a cotton board material may be manufactured from a mixture of dry cut cotton lint fiber and a binder material. A method for forming a regenerated cotton board material according to the present disclosure includes forming an aqueous slurry fiber furnish from a combination of dry cut cotton lint fiber, and wood fiber. The fiber furnish is then wet processed, calendared to remove the bulk of the water, and dried.
    Type: Application
    Filed: March 10, 2008
    Publication date: December 11, 2008
    Inventors: Kayren Joy Nunn, Marc Howard, Homan B. Kinsley