Gum Patents (Class 162/178)
  • Patent number: 6296696
    Abstract: A one-pass, non-tolerance dependent method for preparing paper size emulsions comprising an aqueous emulsion of a substituted cyclic dicarboxylic anhydride, a colloidal stabilizer, and a surfactant wherein the emulsion after one-pass through a dispersion system has an average particle size of less than 2 microns.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: October 2, 2001
    Assignee: National Starch & Chemical Investment Holding Corporation
    Inventors: Michel D. Létourneau, Walter Maliczyszyn
  • Patent number: 6290814
    Abstract: The present invention provides an improved method for sizing paper which comprises the step of coating paper with a composition comprising gellan gum and a derivatized starch wherein the derivatized starch and the gellan gum are present at a weight ratio of from 300:1 to 1000:1. Also provided by the invention are improved papers adapted for ink jet printing characterized by an ash content of from 5% to 30% by weight, permeability characterized by an HST score in the range of over 200 seconds and treated with a surface size comprising gellan gum and a derivatized starch wherein the derivatized starch and the gellan gum are present at a weight ratio of from 100:1 to 1000.
    Type: Grant
    Filed: March 29, 2000
    Date of Patent: September 18, 2001
    Assignees: Penford Corporation, Pharmacia Corporation
    Inventors: LuAnn E. Rooff, Catherine Bennett, Frank J. Miskiel
  • Patent number: 6270626
    Abstract: The invention concerns a novel method for making paper based on sheet cellulose fibre, wherein a novel retention system comprising a suspension of bentonite and a cationic galactomannan is used to improve in particular the retention of the incorporated mineral fillers. The invention also concerns a method for making paper using a retention system which substantially improves draining.
    Type: Grant
    Filed: February 9, 2001
    Date of Patent: August 7, 2001
    Assignee: Rhodia Chimie
    Inventor: Herbert Hruschka
  • Patent number: 6270627
    Abstract: The invention comprises a borosilicate retention aid composition and a method for improving the production of paper by addition of the borosilicate. The borosilicate may be utilized in conjunction with a high molecular weight synthetic flocculant and/or starch, with or without the addition of a cationic coagulant. The borosilicate material is preferably a colloidal borosilicate. Methods for the preparation of the borosilicate material are disclosed.
    Type: Grant
    Filed: November 22, 1999
    Date of Patent: August 7, 2001
    Assignee: Nalco Chemical Company
    Inventors: Bruce A. Keiser, James E. Whitten
  • Patent number: 6251223
    Abstract: A process for improving gravure and offset printability of coated and uncoated printing papers by increasing filler share in the paper on the top and bottom sides or in the outer layers of the paper web by using a retention agent, and providing the outerlayers of the fiber bearing liquid forming the paper web with additional retention agent before or during sheet formation on or between the wires of the paper making machine.
    Type: Grant
    Filed: January 11, 1999
    Date of Patent: June 26, 2001
    Assignee: Stora Publication Paper AG
    Inventors: Hansjörg Kessler, Dieter Horand, Wolfram Friesen
  • Patent number: 6241853
    Abstract: A soft, flexible yet strong paper product is provided from the unique configuration of particular pulp types, cationic wet strength resins, and anionic processing aids.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: June 5, 2001
    Assignee: Kimberly Clark Worldwide, Inc.
    Inventors: Michael John Smith, Gary L. Bushman
  • Patent number: 6217709
    Abstract: A composition comprising cationic starch, cationic galactomannan gum (such as cationic guar, locust bean and fenugreek gum) and acid suitable as drainage aid and strength additive in papermaking.
    Type: Grant
    Filed: November 23, 1998
    Date of Patent: April 17, 2001
    Assignee: Hercules Incorporated
    Inventor: Keith Edward Burnfield
  • Patent number: 6179962
    Abstract: Process for making paper having improved strength characteristics by adding to the pulp water-soluble and/or water-dispersible cationic polymer and oxidized galactose type of alcohol configuration containing polymer.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: January 30, 2001
    Assignee: Hercules Incorporated
    Inventors: Richard Lee Brady, Raymond Thomas Leibfried, Sr., Tuyen Thanh Nguyen
  • Patent number: 6051160
    Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) styrene maleic anhydride copolymer. The invention also relates to a process for inhibiting pitch deposition in pulp and papermaking systems and on papermaking equipment.
    Type: Grant
    Filed: April 15, 1998
    Date of Patent: April 18, 2000
    Assignee: Ashland Inc.
    Inventors: Linda M. Hlivka, George K. Wai
  • Patent number: 6030443
    Abstract: A paper coating composition has therein an optical brightening agent (OBA) and a water-soluble non-ionic polysaccharide derivative, exhibiting a solution viscosity in water of less than 1500 cps when dissolved at 5% polymer concentration, wherein the paper coating provides improved optical brightness as compared to the same formulation without said non-ionic, polysaccharide derivative. A paper coated with this composition has an optical brightness value of greater than 70.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: February 29, 2000
    Assignee: Hercules Incorporated
    Inventors: Eric F. Bock, Charles L. Burdick, L. Drake Walsh
  • Patent number: 5993530
    Abstract: A thermally-decomposable, biodegradable resin composition is dispersed and stabilized in water optionally along with additives to give an aqueous dispersion of the resin composition. In the dispersion, the base polymer consists substantially of a water-insoluble starch-type, biodegradable resin. The dispersion is usable in various fields of papermaking, non-woven fabric production, film and sheet production and woven fabric production, in those of dispersed adhesive production, and in those of metal processing, plastic processing, wood processing and stone processing.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: November 30, 1999
    Assignee: Japan Corn Starch Co., Ltd.
    Inventors: Hideyuki Tanaka, Nobuhiro Hosokawa, Nobuyuki Sugtura, Masato Takahara
  • Patent number: 5989391
    Abstract: A product obtained by reacting a sulfonated amino resin and an amino group-containing substance in a weight ratio of from 1:0.05 to 1:3.
    Type: Grant
    Filed: October 27, 1997
    Date of Patent: November 23, 1999
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yoshitane Watanabe, Kiyomi Ema, Takaichi Sugiyama, Hisanobu Urahata, Michie Kaneko
  • Patent number: 5876562
    Abstract: An aqueous anionic sizing dispersion which comprises an anionic dispersion of a cellulose-reactive sizing agent and colloidal anionic aluminum modified silica-based particles. The dispersion is used in the production of paper, board or cardboard whereby the dispersion is either added to the stock or applied as a surface size.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: March 2, 1999
    Assignee: Eka Chemicals AB
    Inventor: Hans Johansson
  • Patent number: 5873978
    Abstract: Provided is a recording paper having a feeling of plain paper suitable for ink jet recording with water-base ink, with the recording paper having in both machine and cross directions an irreversible shrinkage factor of from -0.10% to +0.10% when it is put under an environment that the relative humidity thereof is changed from 35% to 90% and further changed to 35%.
    Type: Grant
    Filed: February 28, 1997
    Date of Patent: February 23, 1999
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yoshihiro Kuroyama, Yoichi Yamazaki, Yasunori Nanri
  • Patent number: 5871616
    Abstract: Enzymatic dehalogenation of undesirable nitrogen-free organohalogen compounds is carried out by adding a dehalogenase to an aqueous composition comprising a nitrogen-free organohalogen compound and a nitrogen-containing cationic polymer. The enzymatic dehalogenation of the nitrogen-free organohalogen compound is achieved without any substantial effect upon the nitrogen-free organohalogen compound. The dehalogenation method may be carried out via continuous, batch, or semi-continuous processes.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 16, 1999
    Assignee: Hercules Incorporated
    Inventors: Alan Bull, David J. Hardman, Brian M. Stubbs, Paul J. Sallis
  • Patent number: 5853539
    Abstract: Dry strength additives used to enhance the properties of creped tissues are applied to the surface of the Yankee dryer along with the creping adhesive formulation and thereafter transferred to the tissue web as the tissue web is being adhered to the Yankee. When dry strength agents are applied in this manner, less dust and lint are accumulated resulting in improved productivity and product quality.
    Type: Grant
    Filed: July 21, 1997
    Date of Patent: December 29, 1998
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Michael John Smith, Stephen John McCullough
  • Patent number: 5849155
    Abstract: The invention describes a method for dispersion of cellulose based fibers in water. The raw material, which particularly may be recycled paper, is first wetted with water. By a combination of addition of hydrocolloid which binds water, and strong kneading at high solid content, the mixture is transformed into a modulable paste. The high viscosity of the paste effectively conveys the shear forces of the kneading machine to make the fibers flexible and tear them apart. When the kneading is terminated, the hydrocolloid prevents the fibers from reassociation into fiber bundles.
    Type: Grant
    Filed: November 6, 1995
    Date of Patent: December 15, 1998
    Assignee: E. Khashoggi Industries, LLC
    Inventor: Stein Gasland
  • Patent number: 5785813
    Abstract: An efficient and effective method for treating tissue making stock to make soft tissues involves adding a softening agent to a first papermaking furnish of short fibers, such as eucalyptus fibers. A second papermaking furnish of long fibers, such as softwood fibers, is blended with the short fiber furnish. Thereafter, wet strength agents and/or dry strength agents are added to the blended furnish. The treated furnish is then fed to a headbox and processed into soft tissue in any suitable manner.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: July 28, 1998
    Assignee: Kimberly-Clark Worldwide Inc.
    Inventors: Michael John Smith, Vinay Kumar Rao, Gary Lee Shanklin
  • Patent number: 5744003
    Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) styrene maleic anhydride copolymer.
    Type: Grant
    Filed: July 30, 1996
    Date of Patent: April 28, 1998
    Assignee: Ashland Inc.
    Inventors: Linda M. Hlivka, George K. Wai
  • Patent number: 5707493
    Abstract: A temperature-activated polysilicic acid is prepared by heating an acidified aqueous alkali metal silicate. The temperature-activated polysilicic acid is used in the production of paper for improvement of retention and water removal.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: January 13, 1998
    Assignee: J.M. Huber Corporation
    Inventor: Sakari Saastamoinen
  • Patent number: 5633300
    Abstract: A process for making paper to enhance the dry strength of the paper produced without substantially reducing its softness comprising adding to a bleached pulp furnish, separately or together, (1) an anionic polymer selected from the group consisting of carboxymethyl guar, carboxymethyl bean gum, carboxymethyl hydroxyethyl guar, and a carboxymethyl hydroxypropyl guar, with (2) a cationic polymer selected from the group consisting of a cationic guar, a cationic acrylamide copolymer, a cationic bean gum, a cationic amineepichlorohydrin wet strength resin, and both a cationic wet strength resin and at least one of the other said cationic polymers, a composition for adding to a paper-making pulp slurry comprising the said polymers, a method for making the said composition, and a paper product containing the said composition, are disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: May 27, 1997
    Assignee: Hercules Incorporated
    Inventor: Sunil P. Dasgupta
  • Patent number: 5618861
    Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) a nonionic polymer.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: April 8, 1997
    Assignee: Ashland Inc.
    Inventors: Linda M. Hlivka, George K. Wai
  • Patent number: 5595630
    Abstract: A process for producing paper, utilizing a combination of anionic and cationic aluminum compound additives and providing superior freeness and diminished turbidity, is provided.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: January 21, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert H. Moffett
  • Patent number: 5584966
    Abstract: An improved method of paper formation, utilizing a combination of polysilicate microgel, anionic and cationic polymers with the optional utilization of an aluminum salt, is provided.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: December 17, 1996
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Robert H. Moffett
  • Patent number: 5567234
    Abstract: Addition of xanthan gum to aqueous dispersions of colloidal silica containing non-skid compositions for improved spraying.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: October 22, 1996
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: Robert A. LaBrash, Stephen M. Willging
  • Patent number: 5543459
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free moneothylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule,in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: March 9, 1995
    Date of Patent: August 6, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5502091
    Abstract: A process for making paper to enhance the dry strength of the paper produced without substantially reducing its softness comprising adding to a bleached pulp furnish, separately or together, (1) an anionic polymer selected from the group consisting of carboxymethyl guar, carboxymethyl bean gum, carboxymethyl hydroxyethyl guar, and a carboxymethyl hydroxypropyl guar, with (2) a cationic polymer selected from the group consisting of a cationic guar, a cationic acrylamide copolymer, a cationic bean gum, a cationic amine-epichlorohydrin wet strength resin, and both a cationic wet strength resin and at least one of the other said cationic polymers, a composition for adding to a paper-making pulp slurry comprising the said polymers, a method for making the said composition, and a paper product containing the said composition, are disclosed.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: March 26, 1996
    Assignee: Hercules Incorporated
    Inventor: Sunil P. Dasgupta
  • Patent number: 5489638
    Abstract: At least 20% of poly(vinyl alcohol) (PVA) is dispersed in an aqueous solution of at least one salt dissolved therein selected from the group of sodium or potassium formate, sodium, potassium, or magnesium sulfate, sodium or potassium citrate, sodium or potassium polyacrylate, or mixtures thereof. This aqueous suspension of PVA is useful in systems in which PVA is dissolved in order to reduce the time of dissolution.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: February 6, 1996
    Assignee: Aqualon Company
    Inventor: Charles L. Burdick
  • Patent number: 5487419
    Abstract: A process for the production of and a composition of redispersible mechanically disassembled cellulose and the resultant product, referred to as microdenominated cellulose (MDC). The process is characterized by drying the MDC in the presence of a dispersion agent. The product is characterized by a settled volume of greater than 50%, as determined on the basis of a 1% by weight suspension in water after twenty-four hours, and a water retention value of over 350%. MDC is useful as an ingredient in foods, pharmaceutical and cosmetic products.
    Type: Grant
    Filed: July 9, 1993
    Date of Patent: January 30, 1996
    Assignee: Microcell, Inc.
    Inventor: Michael K. Weibel
  • Patent number: 5470435
    Abstract: An improved method for the production of water soluble polyaluminosilicate microgels, formed by the reaction of solutions of alkali metal silicates with solutions of acids containing dissolved aluminum compounds, is provided.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: November 28, 1995
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: John D. Rushmere, Robert H. Moffett
  • Patent number: 5464472
    Abstract: The present invention relates to a fine aqueous dispersion of an organophilic sheet silicate, consisting essentially of a sheet silicate capable of cation exchange and a quaternary organic onium salt reacted therewith, which dispersion comprises from 3 to 30% by weight, based on the organophilic sheet silicate, of a water-soluble, natural polymer and/or a derivative thereof.
    Type: Grant
    Filed: June 24, 1994
    Date of Patent: November 7, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ute Horn, Guido Dessauer
  • Patent number: 5415736
    Abstract: A sheet material, typically paper or cardboard, contains a natural, chemically untreated fibrous material and a secondary long-staple fiber material in a weight ratio comprised between (50-90):(10-50). It further contains fiber fines, at least one retention agent for these fines and at least one sheet strength improving agent. The sheet may be manufactured on paper making machines after preparing a mash from the components listed above and refining. The sheet material is intended to replace paper or cardboard normally made from chemically treated, expensive raw materials.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: May 16, 1995
    Inventor: Till Grether
  • Patent number: 5338406
    Abstract: A polyelectrolyte complex comprising at least one water-soluble, linear, high molecular weight, low charge density cationic polymer having a reduced specific viscosity greater than 2 deciliters/gram (at 0.05 weight % in a 2M NaCl solution at 30.degree. C.) and a charge density of 0.2 to 4 milliequivalents/gram (meq/g), and at least one water-soluble, anionic polymer having a charge density less than 5 meq/g, an aqueous system comprising the polyelectrolyte complex, a composition comprising the polymers which form the polyelectrolyte complex, and paper comprising the polyelectrolyte complex. It is also directed to a process comprising (1) forming an aqueous suspension of cellulosic fibers; (2) adding a strengthening additive so that the aforementioned polyelectrolyte complex is incorporated into the aqueous suspension of cellulosic fibers; and (3) sheeting and drying the fibers to form the desired cellulosic web.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: August 16, 1994
    Assignee: Hercules Incorporated
    Inventor: Douglas C. Smith
  • Patent number: 5338407
    Abstract: A process for making paper to enhance the dry strength of the paper produced without reducing its softness, that comprises adding to a bleached pulp furnish a mixture of an anionic carboxymethyl guar or a carboxymethyl hydroxyethyl guar with a cationic guar that may be prepared by reacting a natural guar with caustic and subsequently with quaternary ammonium chloride.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: August 16, 1994
    Assignee: Hercules Incorporated
    Inventor: Sunil P. Dasgupta
  • Patent number: 5334287
    Abstract: Graft polymers are obtainable by free radical polymerization of(A) monomers or monomer mixtures of(a) from 10 to 100% by weight of open-chain N-vinylcarboxamides(b) from 0 to 90% by weight of other, carboxyl-free monoethylenically unsaturated monomers which are copolymerizable with the monomers (a) and(c) from 0 to 5% by weight of monomers containing two or more ethylenically unsaturated, non-conjugated double bonds in the molecule, in the presence of(B) natural substances containing saccharide structures, such as mono-, oligo- and polysaccharides,in a weight ratio (A):(B) of from 95:5 to 20:80 and, if required, subsequent hydrolysis of the amido groups of the polymerized monomers (a) of the graft polymer with formation of amino groups, and said polymers are used as dry and wet strength agents for paper, board and cardboard.
    Type: Grant
    Filed: July 17, 1992
    Date of Patent: August 2, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinrich Hartmann, Walter Denzinger, Michael Kroener, Claudia Nilz, Friedrich Linhart, Andreas Stange
  • Patent number: 5326631
    Abstract: An unsintered metal fiber burner is produced by mixing ceramic fibers with the metal fibers and binding the mixed metal-ceramic fibers together as a porous layer adherent to a foraminous support. By mixing ceramic fibers with metal fibers, the cost of a sintered metal fiber burner is reduced while the novel burner, because of the metal fiber therein, exhibits improved properties such as greater radiant efficiency, lower NO.sub.x emissions and increased durability.
    Type: Grant
    Filed: June 7, 1993
    Date of Patent: July 5, 1994
    Assignee: Alzeta Corporation
    Inventors: Martin G. Carswell, Robert M. Kendall, John D. Sullivan
  • Patent number: 5318669
    Abstract: A process for making paper to enhance the dry strength of the paper produced without substantially reducing its softness comprising adding to a bleached pulp furnish, separately or together, (1) an anionic polymer selected from the group consisting of carboxymethyl guar, carboxymethyl bean gum, carboxymethyl hydroxyethyl guar, and a carboxymethyl hydroxypropyl guar, with (2) a cationic polymer selected from the group consisting of a cationic guar, a cationic acrylamide copolymer, a cationic bean gum, a cationic amineepichlorohydrin wet strength resin, and both a cationic wet strength resin and at least one of the other said cationic polymers, a composition for adding to a paper-making pulp slurry comprising the said polymers, a method for making the said composition, and a paper product containing the said composition, are disclosed.
    Type: Grant
    Filed: August 14, 1992
    Date of Patent: June 7, 1994
    Assignee: Hercules Incorporated
    Inventor: Sunil P. Dasgupta
  • Patent number: 5316623
    Abstract: A method for imparting wet strength to paper with improved water absorbency, that comprises adding to an aqueous suspension of cellulosic paper stock a neutral or alkaline-curing thermosetting wet-strength resin, a water-soluble polymer containing carboxyl groups or carboxylate ions as their alkali metal or ammonium salts, and a substantially non-thermosetting tertiary-amino polyamide-epichlorohydrin resin.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: May 31, 1994
    Assignee: Hercules Incorporated
    Inventor: Herbert H. Espy
  • Patent number: 5292403
    Abstract: A method of inhibiting the deposition of organic contaminants in a pulp and papermaking system comprising adding to the system an effective amount of a detackifying composition comprising a charged polymer and an oppositely charged surfactant, with the proviso that at least the polymer or the surfactant be surface active.
    Type: Grant
    Filed: March 10, 1993
    Date of Patent: March 8, 1994
    Assignee: Betz PaperChem, Inc.
    Inventors: David D. Dreisbach, Mark E. Laurint
  • Patent number: 5281306
    Abstract: A water-disintegrable cleaning sheet comprising a web of water-dispersible fibers having incorporated thereinto a water-soluble binder having a carboxyl group; at least one metallic ion selected from the group consisting of ions of alkaline earth metals, manganese, zinc, cobalt, and nickel; and an aqueous cleaning agent containing an organic solvent, is disclosed. The sheet satisfies both water disintegrability and strength even when cotained a cleaning agent of high water content.
    Type: Grant
    Filed: April 2, 1992
    Date of Patent: January 25, 1994
    Assignee: Kao Corporation
    Inventors: Shusuke Kakiuchi, Makoto Ishii, Atsuo Nakae, Seiko Ikoma
  • Patent number: 5277764
    Abstract: Cellulose fibre containing products in sheet or web form, such as paper and pulp sheets, are produced from a suspension of cellulose containing fibres, and optional fillers, to which is added anionic inorganic particles, such as bentonite and silica based particles, and a cationic carbohydrate polymer containing aluminum. The cationic carbohydrate polymers are cationic galactomannans or cationic starch. High cationized starch with a degree of substitution of at least 0.07 are especially suitable.
    Type: Grant
    Filed: December 9, 1991
    Date of Patent: January 11, 1994
    Assignee: Eka Nobel AB
    Inventors: Kjell Johansson, Hans E. Johansson, Stefan Klofver
  • Patent number: 5250153
    Abstract: The manufacture of sag-resistant, lightweight structural mineral panels on a foraminous support wire is accomplished by forming a dilute aqueous dispersion of mineral fiber and/or aggregate and an anionically stabilized latex binder, coupling the binder solids onto the mineral fiber materials by adding a small amount of a flocculant such as a cationic polyacrylamide, and passing the slurry onto a first flooded section of the support wire to form an open, entangled, structural mass having water in interstitial spaces of the entangled mass. Water is stripped from the mass and the mass dried without collapse of the open structure by passing heated dry air through the open entangled structure.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: October 5, 1993
    Assignee: USG Interiors, Inc.
    Inventors: David G. Izard, Mark H. Englert
  • Patent number: 5153317
    Abstract: A composition and its method of use are disclosed for controlling rheology of an aqueous dye, which composition comprises 1-30 parts of a gum selected from the group consisting of xanthan gum, rhamsan gum, welan gum and mixtures thereof and 70-99 parts of a water soluble polysaccharide having aliginate equivalent rheology, preferably an alginate. Also disclosed is a color imparting composition for fabric or carpet printing which comprises 99-99% of an aqueous dye component and 1-10% of the rheology control component. The polysaccharide is preferably an alginate, starch, cellulosic polymer or guar gum or mixtures thereof.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: October 6, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Theresa M. Ortega, Philip E. Winston, Jr., Kenneth Clare
  • Patent number: 5112445
    Abstract: Surface sizes comprising 1) gellan gum and 2) one or more film-forming polymers such as chemically modified starch, cellulose derivatives, and polyvinyl alcohol are described. The compositions exhibit enhanced film-forming properties.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: May 12, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Philip E. Winston, Jr., Harold D. Dial, Kenneth Clare, Theresa M. Ortega
  • Patent number: 5104487
    Abstract: The present invention is directed to a paper having improved properties, a process of producing the paper, and compositions used in the process of producing the paper. The invention generally comprises using a cationic starch in combination with a naturally anionic polysaccharide gum.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: April 14, 1992
    Assignee: Betz Paper Chem., Inc.
    Inventors: Thomas E. Taggart, Michael A. Schuster, Alan J. Schellhamer
  • Patent number: 5082528
    Abstract: Iron salts hydrolyzable to ferric hydroxide are provided as retention agents for size in the production of paper and paperboard to aid in water repellence, reduce pollutants, and create other beneficial effects.
    Type: Grant
    Filed: December 7, 1990
    Date of Patent: January 21, 1992
    Assignee: Eaglebrook, Inc.
    Inventor: Neil A. Hartman
  • Patent number: 5079348
    Abstract: A film forming composition useful as a paper size is described which includes 1-20 parts, preferably 2-15 parts, by weight of a gum selected from the group consisting of xanthan gum, rhamsan gum, welan gum and mixtures thereof; 3-20 parts, preferably 5-17 parts, by weight of a water soluble alginate; and 60-100 parts, preferably 70-90 parts, by weight of starch, polyvinyl alcohol or carboxymethylcellulose, with the gum:alginate ratio being not greater than 1:1, preferably not greater than 1:2. The balance of the composition will primarily be water. Additives such as sodium hexametaphosphate may also be present.
    Type: Grant
    Filed: May 24, 1989
    Date of Patent: January 7, 1992
    Assignee: Merck & Co., Inc.
    Inventors: Kenneth Clare, Philip E. Winston, Jr., Harold D. Dial, Theresa M. Ortega
  • Patent number: 5004791
    Abstract: Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch--O--(G).sub.m --(M)--.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.
    Type: Grant
    Filed: September 10, 1990
    Date of Patent: April 2, 1991
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Robert L. Billmers
  • Patent number: 4973680
    Abstract: Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch-O-(G).sub.m -(M)-.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.
    Type: Grant
    Filed: March 3, 1989
    Date of Patent: November 27, 1990
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Robert L. Billmers
  • Patent number: 4961825
    Abstract: In the production of paper or pulp sheets from a paper stock, a binder is added which comprises cationic and anionic components to improve the paper characteristics and the stock characteristics, such that increased retention and a more readily dewatered stock are obtained.The anionic component consists of colloidal anionic particles having at least one surface layer of aluminum silicate or aluminum-modified silicic acid, such that the surface groups of the particles contain silicium and aluminum atoms in a ratio of from 9.5:0.5 to 7.5:2.5.The cationic component consists of cationic carbohydrate having a degree of substitution of 0.01-1.0.
    Type: Grant
    Filed: September 22, 1989
    Date of Patent: October 9, 1990
    Assignee: Eka Nobel AB
    Inventors: Kjell R. Andersson, Bernt Larsson, Hans-Olof Thoresson, Bo V. Larsson