Metal Salt Other Than Silicate Patents (Class 162/181.2)
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Publication number: 20030121624Abstract: For a process and an apparatus for loading fibers contained in a pulp suspension with calcium carbonate, a calcium oxide and/or a medium containing calcium hydroxide is fed to the pulp suspension, and the so treated pulp suspension is further charged in several reactors with pure carbon dioxide or a medium containing carbon dioxide. The reactors can be connected in series and/or in parallel.Type: ApplicationFiled: February 19, 2003Publication date: July 3, 2003Applicant: Voith Paper Patent GmbHInventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek
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Publication number: 20030121633Abstract: A process for manufacturing a cellulosic paper product is provided. The process comprises forming an aqueous suspension of papermaking fibers; introducing sodium bicarbonate into the aqueous suspension; depositing the aqueous suspension onto a sheet-forming fabric to form a wet web; and dewatering and drying the wet web. The process of the present invention provides cellulosic paper products exhibiting a reduced malodor upon re-wetting.Type: ApplicationFiled: December 31, 2001Publication date: July 3, 2003Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Tameka Spence, Ralph Anderson
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Patent number: 6579410Abstract: A new composite material which is useful as a pigment in paper making or paper coating is produced by precipitating a white insoluble pigment compound, eg calcium carbonate, in an aqueous suspension containing a mixture of fine particulate material eg titanium dioxide particles and fibers, eg cellulosic fibers. These suspended solids in the mixture are derived from separate stocks and added together to produce the composite pigment material. The new material is a bonded matrix of the fibers and the white pigment compound having particles of the fine particulate material, eg TiO2, dispersed and bonded within the matrix. The new material may exist in the form of particles in dry or wet form which may be further treated in a known way prior to use in paper making or paper coating.Type: GrantFiled: October 24, 1997Date of Patent: June 17, 2003Assignee: Imerys Minerals LimitedInventors: Ian Stuart Bleakley, Jonathan Stuart Phipps, Paul A Rey, Jose M Rodriguez, Hannu Olavi Ensio Toivonen
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Publication number: 20030106658Abstract: The invention relates to a process for producing a coated paper web. According to the process, a paper web is formed from a fibrous raw material in a paper machine, the paper web is coated with a pigment-containing coating mix, and the coated paper web is calendered. According to the invention, the paper web is coated with a coating composition that contains as the mineral pigment mainly a mixture of gypsum and calcium carbonate, the amount of gypsum being at minimum 10% by weight of the total amount of gypsum and calcium carbonate. With mixtures of calcium carbonate and gypsum, such as mixtures of PCC and gypsum and mixtures of PCC, ground carbonate and gypsum, there are obtained simultaneously a sufficient gloss and smoothness as well as a brightness and opacity better than with PCC-kaolin pastes.Type: ApplicationFiled: July 18, 2002Publication date: June 12, 2003Inventors: Teuvo Ilmonen, Soili Hietanen, Markku Leskela
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Publication number: 20030094252Abstract: Cellulosic products comprising cellulosic fibers and precipitated calcium carbonate prepared in-situ during papermaking are described. The precipitated calcium carbonate is deposited on the cellulosic fibers and is present in a variety of sizes, shapes and morphologies, and is present in the cellulosic products on all physical features of the cellulosic fibers. At least a portion of the precipitated calcium carbonate is present with the fiber based on interaction with one or more chemicals used in papermaking.Type: ApplicationFiled: October 17, 2001Publication date: May 22, 2003Applicant: American Air Liquide, Inc.Inventors: Meenakshi V. Sundar, Steven A. Fisher
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Publication number: 20030079846Abstract: A multi-purpose paper, a manufacturing method thereof, and an application thereof are provided. The method of manufacturing the multi-purpose paper comprises steps of (a) providing a papermaking material and obtaining a clean paper pulp by treating the papermaking material, (b) adding at least one functional additive into the clean paper pulp to form the multi-purpose paper, and (c) processing the multi-purpose paper to form thereon an uneven surface structure. The cultivating paper has the combined functions of weed control, pest control, supplying the required nutrients to plants to help develop the root system, maintaining moisture and breath for the root system. The multi-purpose paper can be carriers of agricultural antagonistic microorganisms and serve as the basic functional substrate for weed control, pest control, sowing, growing seedlings, fertilization, fertilizer saving, manpower saving and organic cultivating.Type: ApplicationFiled: October 26, 2001Publication date: May 1, 2003Applicant: Yuen Foong Yu Paper MFG Co., LTDInventor: Ching-Chung Huang
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Patent number: 6551457Abstract: A process for the production of paper from an aqueous suspension containing cellulosic fibers, and optional fillers, which comprises draining the suspension to obtain a paper web and subjecting the obtained paper web to impulse pressing by passage through at least one press nip having at least one heated roll which is in contact with the web and heated to a temperature above 100° C., wherein a chemical system comprising a polymer component and micro- or nanoparticles are added to the suspension or the paper web before the paper web passes the press nip of the impulse unit.Type: GrantFiled: September 20, 2001Date of Patent: April 22, 2003Assignee: Akzo Nobel N.V.Inventors: Caroline Westman, Tom Lindstrom, Janne Laine, Maria Norell
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Patent number: 6547927Abstract: There is disclosed a water-decomposable fibrous sheet including water-dispersible fibers and water-insoluble carboxymethyl cellulose. The water-insoluble carboxymethyl cellulose has a degree of substitution for etherification (DE) falling between 0.3 and 0.6. In the water-insoluble carboxymethyl cellulose, the hydrogen of the carboxyl group in at least 95% of the carboxymethyl groups is substituted with a metal.Type: GrantFiled: September 18, 2000Date of Patent: April 15, 2003Assignee: Uni-Charm CorporationInventors: Naohito Takeuchi, Takayoshi Konishi, Jyoji Shimizu
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Patent number: 6547928Abstract: Disclosed is a composition for softening an absorbent tissue and tissue structures softened using the composition. The composition includes an effective amount of a softening active ingredient; a vehicle in which the softening active ingredient is dispersed; an electrolyte dissolved in the vehicle; a bilayer disrupter and a high polymer. The electrolyte and the bilayer disrupter cooperate to cause the viscosity of the composition to be less than the viscosity of a dispersion of the softening active ingredient in the vehicle alone. The high polymer adds “stringiness” to the composition opening the air pressure operating window for spray application of the softening composition.Type: GrantFiled: November 30, 2001Date of Patent: April 15, 2003Assignee: The Procter & Gamble CompanyInventors: Steven Lee Barnholtz, Kenneth Douglas Vinson, Paul Joseph Coffaro, Larry Neil Mackey, Amy Jo Hamilton, Errol Hoffman Wahl, Gayle Marie Frankenbach, Yenchun Wu
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Patent number: 6540870Abstract: The invention relates to papermaking processes wherein calcium carbonate is included in a pulp suspension. The dissolution of the calcium carbonate in the papermaking system is prevented or substantially retarded by the introduction of carbon dioxide to said pulp suspension in connection with subjecting said calcium carbonate in said papermaking system to pH conditions of about 8 or lower. The invention also provides processes for the production of paper or board in papermaking systems wherein solid calcium carbonate is present as a filler and/or pigment.Type: GrantFiled: January 3, 2000Date of Patent: April 1, 2003Assignees: AGA Aktiebolag, UPM-Kymmene Corp.Inventors: Auli Laurila-Lumme, Heikki Pakarinen, Hannu Juhani Leino
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Patent number: 6540878Abstract: The present invention relates to a stabilized calcium carbonate filler, a process for stabilizing calcium carbonate, the use of the stabilized filler in a paper making system, and an improved paper making process wherein calcium carbonate is used as a filler. Specifically, the invention relates to a process wherein the rate of dissolution of calcium carbonate filler is retarded as compared to the rate found in conventional paper making processes. The rate of dissolution is retarded by addition of carbon dioxide to a slurry containing the calcium carbonate filler.Type: GrantFiled: December 18, 2000Date of Patent: April 1, 2003Assignee: AGA AktiebolagInventor: Hannu Juhani Leino
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Patent number: 6533895Abstract: A fiber loading apparatus continuously loads fibers in a fiber suspension with a chemical compound. A pulper has an inner chamber, a shear imparting device within the inner chamber, an inlet and an outlet. The pulper inlet receives a fiber suspension at a consistency of between 20 and 30%. The shear imparting device, which may be configured as a rotor, imparts high shear forces to the fiber suspension. A fluffer includes an inner chamber, an inlet and an outlet. The fluffer inlet is connected with the pulper outlet. A reactor includes an inner chamber, an inlet and an outlet. The reactor inlet is connected with the fluffer outlet. A gas supply is connected with the fluffer inner chamber and/or reactor inner chamber. The gas supply supplies and pressurizes the fluffer inner chamber and/or reactor inner chamber with a gas, such as carbon dioxide or ozone, acting as a reactant for the chemical compound to be loaded into fibers of the fiber suspension.Type: GrantFiled: February 24, 2000Date of Patent: March 18, 2003Assignee: Voith Sulzer Paper Technology North America, Inc.Inventors: Klaus Doelle, Oliver U. Heise
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Publication number: 20030037893Abstract: Electrophotographic paper and a method for its production, according to which method a cellulose pulp is slushed, a filler is mixed with the slush, and the slush is formed in the paper machine into a web, which is dried. According to the invention, bivalent or trivalent cations in an amount of at least 0.1% of the dry weight of the pulp are attached to the acid groups of the cellulose pulp before the forming of the web. Thereby a paper web is obtained the surface charge of which is at least approximately 600 V when relative humidity is 40%. The surface charge of the paper according to the invention remains stable within a wide humidity range. For this reason, when the paper according to the invention is used, the need for drying the paper in the printing press is significantly reduced.Type: ApplicationFiled: September 17, 2002Publication date: February 27, 2003Inventors: Sami Simula, Tarja Tamminen, Kaarlo Niskanen
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Publication number: 20030037896Abstract: Chemical additives can be adsorbed on cellulosic papermaking fibers at high levels with a minimal amount of unadsorbed chemical additives present in the papermaking process water. A method includes treating a fiber slurry with an excess of the chemical additive, allowing sufficient residence time for adsorption to occur, filtering the slurry to remove unadsorbed chemical additives, and redispersing the filtered pulp with fresh water. Filtrate from the thickening process contains unadsorbed chemical additive and it is not sent forward in the process with the chemically treated fibers. The method can be employed to make improved paper products.Type: ApplicationFiled: May 29, 2002Publication date: February 27, 2003Inventors: Mike Thomas Goulet, Jill A. Georger, Denise Alice Polderman, Maurice Alan Wyatt, Victor Michael Gentile
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Publication number: 20030037897Abstract: The present invention discloses a nanometer-scale particle recycled slurry paper. The shares in weight of its ingredients are: papermaking wastewater slurry 20-80, pulp 20-80, nanometer-scale calcium carbonate 2-20, and chemical auxiliary agent performing the function of coacervation 1-5. The production technology process of the present invention is: slurry→pressing and squeezing the slurry→washing and filtering→putting into a pool→adding nanometer-scale calcium carbonate→mixing the paper pulp with the chemical auxiliary agent performing coacervation function→stirring and mixing→transferring onto a mesh→pressing and squeezing→drying→forming into paper→winding into reels.Type: ApplicationFiled: January 31, 2002Publication date: February 27, 2003Inventor: Jianhu Yu
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Publication number: 20030029590Abstract: Silica-calcium carbonate composition particles having the characteristics of both synthetic silica and calcium carbonate without a lowering thereof are described along with paper internally filling the particles and a method for making the particles.Type: ApplicationFiled: August 20, 2002Publication date: February 13, 2003Inventors: Katsuyuki Tanabe, Kouhei Mitsuhashi
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Publication number: 20020195218Abstract: A process for making paper comprising forming a cellulosic suspension, flocculating the suspension, draining the suspension on a screen to form a sheet and then drying the sheet, wherein the cellulosic suspension is flocculated by addition of a water soluble polymer which is selected fromType: ApplicationFiled: August 2, 2002Publication date: December 26, 2002Inventor: Gordon Cheng I Chen
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Patent number: 6485609Abstract: This invention relates to an improvement in coatings particularly suited for the preparation of paper products having an ink jet coating applied thereto and to the resulting paper products. The improvement in ink jet coatings resides in the incorporation of a primary amine functional polyvinyl alcohol (PVOH/PVNH2) as a polymeric binder. One form of an amine functional polyvinyl alcohol is produced by the hydrolysis of a copolymer of vinyl acetate and N-vinylformamide or vinyl acetate and allyl amine. Another is the polyvinyl butyral derivative of polyvinyl alcohol which typically is formed by the reaction of a 4-amino alkyl aldehyde dialkyl acetal, such as 4-aminobutyraldehyde dimethyl acetal with polyvinyl alcohol.Type: GrantFiled: March 8, 2001Date of Patent: November 26, 2002Assignee: Celanese International CorporationInventor: John Richard Boylan
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Publication number: 20020162638Abstract: In a procedure for loading fibers contained in a pulp suspension with an additive by means of a chemical precipitation reaction, which is initiated through adding carbon dioxide, the carbon dioxide is produced with a degree of purity of ≦99%, preferably of ≦85%, and this carbon dioxide is then added to the pulp suspension.Type: ApplicationFiled: April 23, 2002Publication date: November 7, 2002Inventor: Klaus Doelle
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Patent number: 6475340Abstract: A wet-laid, porous solid phase extraction sheet material that contains both active particles and binder and that possesses excellent wet strength is described. The binder is present in a relatively small amount while the particles are present in a relatively large amount. The sheet material is sufficiently strong and flexible so as to be pleatable so that, for example, it can be used in a cartridge device.Type: GrantFiled: March 15, 1999Date of Patent: November 5, 2002Assignee: 3M Innovative Properties CompanyInventors: Kurt C. Carlson, Roger L. Langer
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Patent number: 6475341Abstract: Paper is made by mixing anionic starch, carboxyl methyl cellulose or other polymeric binder into a cellulosic thin stock together with a cationic inorganic or polymeric coagulant and then flocculating the suspension by means of an anionic swelling clay or other anionic retention aid.Type: GrantFiled: February 9, 2000Date of Patent: November 5, 2002Assignee: Ciba Specialty Chemicals Water Treatments Ltd.Inventors: Howard Johnston, Lesley Collett
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Method for deflocculating and chemically loading fibers in a fiber suspension with calcium carbonate
Patent number: 6471825Abstract: An apparatus for continuously loading fibers in a fiber suspension with a chemical compound includes a deflocculating vessel having an interior chamber, a fluid inlet connected with the interior chamber, a fluid outlet connected with the interior chamber, and a high shear imparting device disposed within the interior chamber for imparting high shear forces to and thereby deflocculating the fiber suspension. A mixing container has an interior compartment, a fluid inlet connected with both the interior compartment and the fluid outlet of the deflocculating vessel, a fluid outlet connected with the interior compartment, and a low shear imparting device within the interior compartment for imparting low shear forces to the fiber suspension. A gas supply is connected with the interior chamber of the deflocculating vessel and/or the interior compartment of the mixing container. The gas supply is configured for supplying a gas to and pressurizing each of the deflocculating vessel and the mixing container.Type: GrantFiled: June 28, 2000Date of Patent: October 29, 2002Assignee: Voith Sulzer Paper Technology North Amrica, Inc.Inventors: Klaus Doelle, Kurt William Lorenz, Oliver U. Heise, Werner Witek, Robert J. Matz -
Publication number: 20020148582Abstract: The present invention relates to an acid-stabilized calcium carbonate slurry having a pH of less than 7, preferably between about 6 and about 7, containing water, calcium carbonate, preferably precipitated calcium carbonate, and an acid-stabilizer of a water soluble calcium salt, a weak acid, a chelating agent, a weak acid capable of chelating calcium ion, or a mixture thereof. The acid-stabilizer is present in an amount sufficient to provide an aqueous calcium carbonate slurry having an increased calcium ion concentration and an acidic pH. In a typical acid-stabilized calcium carbonate slurry of the invention, the acid-stabilizer is present in an amount sufficient to provide a calcium ion concentration of about 1 millimolar to about 5 molar, preferably from about 1 to about 120 millimolar.Type: ApplicationFiled: April 4, 2001Publication date: October 17, 2002Applicant: Minerals Technologies Inc.Inventor: Donald Kendall Drummond
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Publication number: 20020144797Abstract: A method of dispersing a solid particulate material in an aqueous medium by addition to the aqueous medium of a dispersing agent wherein the solid particulate material is to be used as a filler or pigment in a sheet material which is required to come into contact with foodstuffs, wherein the dispersing agent is a composition comprising:Type: ApplicationFiled: November 13, 2001Publication date: October 10, 2002Applicant: ECC INTERNATIONAL, LTD.Inventors: David Robert Skuse, Shih-Ruey Thomas Chen, William Leonard Garforth, Gary F. Matz
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Patent number: 6458241Abstract: An apparatus for loading fibers in a fiber suspension with calcium carbonate includes a housing with a fiber source inlet, and inlet chamber and an accept outlet. A stator is carried by the housing. A rotor is positioned in opposing relation with the stator. Each of the rotor and the stator are positioned downstream from the inlet chamber. A reactant gas supply is positioned in fluid communication with the inlet chamber.Type: GrantFiled: January 8, 2001Date of Patent: October 1, 2002Assignee: Voith Paper, Inc.Inventors: Klaus Doelle, Oliver Heise
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Patent number: 6440269Abstract: A paper-based sheet for wallcoverings that is made in a single pass on a standard paper making machine is described. The sheet has a print side and a barrier side and is made from softwood pulp in an amount of about 15% to about 40% by dry weight; hardwood pulp in an amount of about 30% to about 55% by dry weight; and, mineral filler in an amount of about 15% to about 30% by dry weight. A first coating is applied to the print side of the sheet in an amount of about 5 to about 20 gm/m2 dry weight. A second coating is applied to the barrier side of the sheet in an amount of about 2.5 to about 10 gm/m2 dry weight. The advantage is a strong, durable, alkaline wallcovering that is less expensive to produce, and provides a smooth print surface.Type: GrantFiled: December 6, 1999Date of Patent: August 27, 2002Assignee: Domtar, Inc.Inventor: Harold Freeburn
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Patent number: 6436232Abstract: The invention relates to a procedure for adding a filler into a pulp based on cellulose fibers, in which the pulp is fluidized and the filler is added into it. Preferably the pulp is stirred in the fluidized state while the filler is being added. The pulp is preferably at a medium consistency when the filler is being added. Preferably the filler added into the pulp is calcium hydroxide and the calcium carbonate is precipitated with carbon dioxide.Type: GrantFiled: February 20, 1997Date of Patent: August 20, 2002Assignee: M-Real Oyj.Inventors: Petri Silenius, Markku Leskelä, Johan Gullichsen, Esa Halinen
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Patent number: 6423183Abstract: Chemical additives can be adsorbed on cellulosic papermaking fibers at high levels with a minimal amount of unadsorbed chemical additives present in the papermaking process water. A method includes treating a fiber slurry with an excess of the chemical additive, allowing sufficient residence time for adsorption to occur, filtering the slurry to remove unadsorbed chemical additives, and redispersing the filtered pulp with fresh water. Filtrate from the thickening process contains unadsorbed chemical additive and it is not sent forward in the process with the chemically treated fibers. The method can be employed to make improved paper products.Type: GrantFiled: April 30, 1999Date of Patent: July 23, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Mike Thomas Goulet, Jill A. Georger, Denise Alice Polderman, Maurice Alan Wyatt, Victor Michael Gentile
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Publication number: 20020092636Abstract: For a process and an apparatus for loading fibers contained in a pulp suspension with calcium carbonate, a calcium oxide and/or a medium containing calcium hydroxide is fed to the pulp suspension, and the so treated pulp suspension is further charged in several reactors with pure carbon dioxide or a medium containing carbon dioxide. The reactors can be connected in series and/or in parallel.Type: ApplicationFiled: March 14, 2002Publication date: July 18, 2002Applicant: Voith Paper Patent GmbHInventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek
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Publication number: 20020088566Abstract: A method of continuously loading fibers in a fiber suspension with calcium carbonate. The fibers include a fiber wall surrounding a lumen. A reactant solid in the form of calcium oxide and/or calcium hydroxide is mixed into the fiber suspension with a resultant initial process pH of between 11 and 12. The fiber suspension is transported at a consistency of between approximately 15 and 30% into an inner chamber of a closed reactor. A reactant gas is injected into the reactor, whereby the reactor is pressurized to a pressure between 5 and 150 psi. A temperature of the fiber suspension within the reactor is controlled at a range between −10° C. and 80° C. The fibers within the fiber suspension are loaded with calcium carbonate as a result of a chemical reaction between the reactant solid and the reactant gas in the reactor over a predetermined reaction time.Type: ApplicationFiled: March 11, 2002Publication date: July 11, 2002Applicant: Voith Sulzer Paper Technology North America, Inc.Inventor: Klaus Doelle
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Publication number: 20020088586Abstract: An inkjet printing paper of noncoated type, in which the feathering is prevented and the conveyability is improved. This inkjet printing paper comprises calcium carbonate as its filler wherein the filler contains ash of 10 to 30 weight % as defined in JIS P 8128 and wherein the paper has Stockigt sizing degree of 0.001 to 0.05 sec/g/m2 according to JIS P 8122. Further, in this paper, X-ray image obtained from area-analysis with an energy-distributed X-ray microanalyzer for the surface of the inkjet printing paper, the area of white part, which indicates the presence of calcium, is 3 to 40% related to the total area of the X-ray image.Type: ApplicationFiled: October 5, 2001Publication date: July 11, 2002Inventors: Katsuhiko Haga, Noboru Yamada, Hiroyuki Osumi, Hiroyuki Ando
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Publication number: 20020084050Abstract: The invention relates to a filler used in paper manufacture and mainly consisting of calcium carbonate, and to a procedure for producing the filler. The filler consists of porous aggregates formed by precipitated calcium carbonate particles. In the procedure, calcium carbonate is precipitated.Type: ApplicationFiled: December 27, 2001Publication date: July 4, 2002Applicant: M-real CorporationInventors: Petri Silenius, Markku Leskela
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Patent number: 6413370Abstract: A coated roll printing paper for printing with the cold-set offset-printing process is described, which gives a printing result comparable with that of low-weight coated matte grades. The paper is characterized by a high proportion of a fine calcium carbonate in the coating pigment, and a relatively low proportion of highly active binders.Type: GrantFiled: August 7, 2000Date of Patent: July 2, 2002Assignee: Haindl Papier GmbHInventors: Hartmut Wurster, Hans-Peter Hofmann
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Patent number: 6413365Abstract: A method of loading fibers in a fiber suspension with calcium carbonate includes the step of transporting a fiber suspension to an inlet of a housing. The fiber suspension includes calcium oxide and/or calcium hydroxide. The fiber suspension is distributed from the inlet using a rotatable distribution member. The fiber suspension is passed through a toothed ring interposed between the distribution member and a rotor and stator assembly. A reactant gas is supplied to a gas ring defined between a toothed ring and the rotor and stator assembly. Calcium carbonate crystals are formed in the fiber suspension as the fiber suspension passes through the gas ring. The calcium carbonate crystals are distributed in the fiber suspension using the rotor and stator assembly.Type: GrantFiled: July 11, 2001Date of Patent: July 2, 2002Assignee: Voith Paper Patent GmbHInventors: Klaus Doelle, Oliver Heise
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Patent number: 6409881Abstract: The present invention relates to crosslinked cellulose-containing fibrous material, wherein hydroxy groups are oxidized at the C(6) of glucose units of the cellulose into aldehyde and/or carboxy groups crosslinked with a metal-containing crosslinking agent selected from transition metals of groups of IVa (preferably Zr), Va, VIa, VIIa and VIIIa, aluminum and zinc; and a paper or nonwoven (product), e.g. tissue (product), which comprises this fibrous material. These paper or nonwoven (products) are distinguished by high wet and dry strength.Type: GrantFiled: November 7, 2000Date of Patent: June 25, 2002Assignee: SCA Hygiene Products GmbHInventor: Thomas Jaschinski
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Patent number: 6406594Abstract: Composite products having mineral networks polymerized about cellulosic material and a method for making such products are described. One embodiment of the composite product comprises a paper product having a polymerized mineral network, such as a silica/silicate network around, throughout and/or about the cellulosic material instead of having isolated particles of filler material deposited onto, or purposefully bonded to, the cellulosic material. One embodiment of the method comprises providing a mixture comprising cellulosic material, a Group I metal silicate and a Group II metal base or salt. The mixture is then carbonated to produce a product comprising precipitated carbonate filler material and a polymerized mineral network about the cellulosic material. This product is then formed into paper products wherein the ash content can be substantially greater than conventional paper products while maintaining suitable strength properties.Type: GrantFiled: July 17, 1998Date of Patent: June 18, 2002Assignee: Boise Cascade CorporationInventors: Richard F. Palmer, Mike S. D. Juang, James S. Johnson, Barbara R. Atha, David T. Lee, Larry L. Malcom
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Publication number: 20020059999Abstract: A method is disclosed for reducing or inhibiting alkaline darkening of mechanical pulp caused by the presence of calcium carbonate filler during production; the method comprises adding a sulfite, or sulfur-containing reducing agent, especially a sulfite to the mechanical pulp and the filler; the method is usefully applied in the production of mechanical pulp and paper in which calcium carbonate is used as a filler and also in the production of paper at neutral or mildly alkaline conditions.Type: ApplicationFiled: November 27, 2001Publication date: May 23, 2002Inventors: Xujun Hua, Makhlouf Laleg
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Patent number: 6387212Abstract: The invention relates to a process for obtaining fibers integral with calcium carbonate particles, in which the fibers to be treated are contacted with carbon dioxide generator means and at least one composition comprising Ca++ ions capable of reacting with the carbon dioxide so as to give “in fine” a precipitation of calcium carbonate “in situ” on the fibers. Preferably, the carbon dioxide generator used is calcium bicarbonate.Type: GrantFiled: August 9, 2000Date of Patent: May 14, 2002Assignee: L'Air Liquide Societe Anonyme a Directoire et Conseil de Surveillance pour l'Etude et l'Exploitation des procedes Georges ClaudeInventor: Richard Christian
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Patent number: 6383337Abstract: A papermaking machine and a method for applying an application medium to a moving web of material in a papermaking machine. The papermaking machine has a wet end section, a press section, a drying section and an applying device for applying a medium to a moving web of material. The wet end section includes a twin wire area having a first wire and a second wire wherein the web of material is formed and positioned between the two wires and separated from the two wires before moving to the press section. At least one wet end section applying device is positioned on one side of at least one of the first wire or the second wire within the twin wire area and facing away from the web of material positioned on the wires. The press section of the papermaking machine has a first press element and at least one press section applying device facing directly toward the web of material.Type: GrantFiled: June 22, 1999Date of Patent: May 7, 2002Assignee: Voith Sulzer Papiertechnik Patent GmbHInventors: Albrecht Meinecke, Volker Schmidt-Rohr, Ingolf Cedra
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Patent number: 6379499Abstract: The strength properties of paper are improved by treating the paper with a hydroxy-containing polymer, a multifunctional aldehyde and a catalyst. The multifunctional aldehyde is present at a concentration of about 50% to about 800% weight percent of the polymer, the catalyst is present at a weight ratio of between about 1:0.1 to about 1:2 multifunctional aldehyde:catalyst and the total weight of the polymer, aldehyde and catalyst is between about 0.1% to about 10% based on the dry weight of the paper.Type: GrantFiled: September 28, 2000Date of Patent: April 30, 2002Assignee: University of Georgia Research Foundation, Inc.Inventors: Charles Q. Yang, Guozhong Xu
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Patent number: 6379501Abstract: Processes for preparing cellulose products, such as paper products which include substantially simultaneously or sequentially adding at least one aluminum compound and at least one silicate to a cellulose slurry, to a cellulose slurry such as a paper slurry. In particular, the present invention is directed to processes for preparing the cellulose products, such as paper products which include substantially simultaneously or sequentially adding at least one aluminum compound and at least one monovalent silicate or water-soluble metal silicate complex to a cellulose slurry, such as a paper slurry. Compositions containing at least one aluminum compound and at least one water-soluble metal silicate, and cellulose products, such as paper products containing at least one water-soluble metal silicate complex.Type: GrantFiled: December 14, 1999Date of Patent: April 30, 2002Assignee: Hercules IncorporatedInventors: Fushan Zhang, Jimei Tong
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Patent number: 6375794Abstract: The invention relates to a filler used in paper manufacture and mainly consisting of calcium carbonate, and to a procedure for producing the filler. The filler consists of porous aggregates formed by precipitated calcium carbonate particles. In the procedure, calcium carbonate is precipitated.Type: GrantFiled: November 30, 2000Date of Patent: April 23, 2002Assignee: Metsa-SerlaInventors: Petri Silenius, Markku Leskela
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Patent number: 6372089Abstract: Disclosed are stable, aqueous colloidal silicas having surface area of greater than 700 m2/g and S-values of from 20-50. These colloidal silicas do not require treatment with surface treatment agents such as aluminum to achieve stability. These colloidal silica aquasols can be produced and stored at concentrations of greater than 7 percent by weight SiO2 solids, and even as high as 15 percent by weight solids or higher, and remain stable at room temperature for at least 30 days compared to art-known silica aquasols. These colloidal silica sols demonstrate advantageously improved performance over art-known colloidal silica sols in applications such as in drainage and retention in papermaking processes. Also disclosed are processes for making aqueous colloidal silicas of the invention and the use of such colloidal silicas in papermaking processes.Type: GrantFiled: February 14, 2000Date of Patent: April 16, 2002Assignee: Nalco Chemical CompanyInventors: Bruce A. Keiser, Maureen B. Nunn, Cheng-Sung Huang, Dennis I. MacDonald
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Patent number: 6358365Abstract: Aqueous composition, including a water-soluble metal silicate complex which includes at least one divalent metal. A process for preparing an aqueous composition including water-soluble metal silicate complex includes combining monovalent cation silicate and divalent metal ions in an aqueous environment to form the water-soluble metal silicate complex. A process of modifying cellulose slurry includes adding an aqueous composition having water-soluble metal silicate complex which includes divalent metal to cellulose slurry. A process for preparing cellulose slurry includes adding monovalent cation silicate to cellulose slurry comprising a sufficient amount of divalent metal ions to combine with the monovalent cation silicate to form water-soluble metal silicate complex. A process of making cellulose product includes: adding an aqueous composition having water-soluble metal silicate complex including divalent metal to cellulose slurry; and forming cellulose product from the cellulose slurry.Type: GrantFiled: December 14, 1999Date of Patent: March 19, 2002Assignee: Hercules IncorporatedInventors: Fushan Zhang, Jimei Tong, Tom E. Taggart
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Patent number: 6355138Abstract: A method of continuously loading fibers in a fiber suspension with calcium carbonate. The fibers include a fiber wall surrounding a lumen. A reactant solid in the form of calcium oxide and/or calcium hydroxide is mixed into the fiber suspension with a resultant initial process pH of between 11 and 12. The fiber suspension is transported at a consistency of between approximately 15 and 30% into an inner chamber of a closed reactor. A reactant gas is injected into the reactor, whereby the reactor is pressurized to a pressure between 5 and 150 psi. A temperature of the fiber suspension within the reactor is controlled at a range between −10° C. and 80° C. The fibers within the fiber suspension are loaded with calcium carbonate as a result of a chemical reaction between the reactant solid and the reactant gas in the reactor over a predetermined reaction time.Type: GrantFiled: February 24, 2000Date of Patent: March 12, 2002Assignee: Voith Sulzer Paper Technology North America, Inc.Inventor: Klaus Doelle
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Publication number: 20020026989Abstract: During the chemical process of loading with calcium carbonate fibers contained in a pulp suspension, a medium containing calcium oxide or calcium hydroxide is added to the pulp suspension. This treated pulp suspension is charged in at least one reactor with pure carbon dioxide (or a medium containing carbon dioxide), which, during the progression of the reaction, converts at least a significant portion of the starting materials (calcium oxide and/or calcium hydroxide and carbon dioxide) into the reaction products, calcium carbonate and water. This reaction is accomplished by properly controlling the pulp suspension's pH.Type: ApplicationFiled: July 11, 2001Publication date: March 7, 2002Inventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek
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Publication number: 20020007925Abstract: For a process and an apparatus for loading fibers contained in a pulp suspension with calcium carbonate, a calcium oxide and/or a medium containing calcium hydroxide is fed to the pulp suspension, and the so treated pulp suspension is further charged in several reactors with pure carbon dioxide or a medium containing carbon dioxide. The reactors can be connected in series and/or in parallel.Type: ApplicationFiled: July 12, 2001Publication date: January 24, 2002Inventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek
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Publication number: 20010054491Abstract: The present invention relates to a method of manufacturing a paper of multi-colour ink-jet printable grade. A proper hydrophicity for the paper is secured by using an 2-oxetanone size in the appropriate sizing steps. The size is made from non-branched and branched-chain fatty acids having main chain comprising 6-22 carbons linked with each other by saturated bonds.Type: ApplicationFiled: July 2, 2001Publication date: December 27, 2001Inventors: Olof Malmstrom, Markku Nurminen, Raija Savolainen, Ari Teijo, Claes Zetter
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Patent number: 6328850Abstract: A multi-layered paper product. The paper product has individual layers for providing a soft tactile sensation to the user, for providing strength, and for providing bulk. Suitable fibers for increasing bulk may be synthetic fibers, debonded fibers, weakly bonded fibers, curled fibers, and fibers combined with particulate fillers. An exemplary embodiment having five layers is disclosed.Type: GrantFiled: April 16, 1998Date of Patent: December 11, 2001Assignee: The Procter & Gamble CompanyInventors: Dean Van Phan, Paul Dennis Trokhan
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Publication number: 20010045264Abstract: A device treats a fiber stock suspension with at least one additive, the fiber stock suspension being used for production of at least one of paper and cardboard. The fiber stock suspension includes a suspension medium and a fiber material. The fiber material has fiber surfaces, the fiber surfaces being moistened by the suspension medium. The device includes a fluffer having an inlet for receiving at least one of the fiber stock suspension and the at least one additive. The fluffer is coupled to the inlet, the fluffer being configured for separating the fiber material and enlarging a specific surface of the fiber surfaces.Type: ApplicationFiled: May 23, 2001Publication date: November 29, 2001Inventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek, Shawn Flanigan, Robert J. Matz