Silicon Containing Additive Other Than Clay Patents (Class 162/181.6)
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Patent number: 11480396Abstract: Total heat exchange element paper having excellent moisture resistance and gas barrier properties, comprising a substrate sheet and a moisture absorbent and colloidal silica both of which are adhered to the substrate sheet, wherein the substrate sheet contains natural pulp which has been beaten to a freeness specified in JIS P 8121-1:2012 of not lower than 80° SR and the colloidal silica is cationic colloidal silica.Type: GrantFiled: August 20, 2018Date of Patent: October 25, 2022Assignee: MITSUBISHI PAPER MILLS LIMITEDInventor: Kengo Yamane
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Patent number: 11131063Abstract: Embodiments of the invention a method for producing a composite paper by providing a particulate sorbent, providing a paper pulp, and mixing the particulate sorbent and the paper pulp to develop a mixture. The method includes producing an article from the mixture that includes the particulate sorbent at least partially distributed through at least a portion of the article. Further, the at least one article is configured and arranged to uptake and release carbon dioxide as a function of moisture content. Some embodiments of the invention include a composite paper-like assembly including at least a first and second layer including hydrophobic fibers, and sorbent particles and/or a sorbent loaded paper sandwiched between the first and second porous sheets. Some further embodiments include a method for producing a material that supports a moisture swing by providing a material including activated carbon, and infusing the activated carbon with ionic salt.Type: GrantFiled: July 13, 2020Date of Patent: September 28, 2021Assignee: Arizona Board of Regents on behalf of Arizona State UniversityInventors: Allen Wright, Klaus Lackner
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Patent number: 10759700Abstract: The present invention relates to a three component composition consisting of a polyol component (A) comprising at least two polyols, one with high and one with low molecular weight, and water, a polyisocyanate component (B) comprising a methylene diphenyl diisocyanate (MDI) product with an average NCO functionality of at least 2.5, or a methylene diphenyl diisocyanate (MDI) product with an average NCO functionality of at least 2 and at least one further polyol with an amount of between 1% and 30% based on the weight of said polyisocyanate component (B), wherein said MDI product and said polyol have reacted at least partially, and a powder component (C) comprising at least one hydraulic binder, preferably cement and/or calcined paper sludge, preferably a calcium compound selected from calcium hydroxide and/or calcium oxide, and optionally one or more aggregates.Type: GrantFiled: May 12, 2015Date of Patent: September 1, 2020Assignee: SIKA TECHNOLOGY AGInventors: Patricia Gimeno, Carola Kaddatz, Jochen Grötzinger, Hans Gantner
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Patent number: 10591063Abstract: Provided is a spiral wound gasket that has improved conformability and that is capable of exhibiting sufficient sealability for flanges provided at joints, irrespective of the state of a gap between the flanges. The present invention provides a spiral wound gasket in which a laminate of a hoop member made of metal and a filler member is wound and integrated so as to have an opening at the center, wherein the hoop member has a cross-sectional shape with a bent portion, and V expressed by an equation (I) below is 0.5 to 2.4: V = 1 r ? cos ? ( ? 2 ) , ( I ) where a bending angle constituting the bent portion is ? (°), and a radius of curvature of the bent portion is r (mm).Type: GrantFiled: June 29, 2018Date of Patent: March 17, 2020Assignee: NIPPON PILLAR PACKING CO., LTD.Inventors: Yuji Yanagitake, Naoyuki Sawamoto, Hiroki Tanabe, Yuta Sato, Kiyoshi Toyazaki
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Patent number: 10077363Abstract: A nano-composite structure. A synthetic nano-composite is described having a first component including a fibrous structured amorphous silica structure, and a second component including a precipitated calcium carbonate structure developed by pressure carbonation. The nano-composite may be useful for fillers in paints and coatings. Also, the nano-composite may be useful in coatings used in the manufacture of paper products.Type: GrantFiled: March 27, 2017Date of Patent: September 18, 2018Assignee: PACIFIC NANO PRODUCTS, INC.Inventor: Vijay K Mathur
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Patent number: 9908982Abstract: The present application relates to a natural fiber plastic composite product comprising thermoplastic polymer and dried deinking sludge containing cellulose fibers and minerals in foamed form. The present application also relates to a method for preparing the natural fiber plastic composite product.Type: GrantFiled: May 18, 2015Date of Patent: March 6, 2018Assignee: UPM-KYMMENE CORPORATIONInventor: Piia Peltola
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Patent number: 9487917Abstract: The invention relates to a sol containing silica-based particles having an axial ratio of at least about 10 and specific surface area of at least about 600 m2/g. The invention further relates to a sol containing silica-based particles having an axial ratio of at least about 10 and S-value up to about 25. The invention further relates to a sol containing silica-based particles having an axial ratio of at least about 10 and a specific surface area of at least about 400 m2/g, wherein the silica-based particles are surface-modified. The invention further relates to a sol containing silica-based particles having a viscosity of at least 50 cP and silica content of at least about 3% by weight, wherein the silica-based particles have a specific surface area of at least about 400 m2/g.Type: GrantFiled: September 24, 2014Date of Patent: November 8, 2016Assignee: AKZO NOBEL N.V.Inventors: Michael Persson, Freddie Hansson, Annika Viola Pal, Lars Lindahl, Joakim Carlén
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Patent number: 9067247Abstract: A process for treating a tailings stream comprises (a) contacting a deionized silicate solution with a tailings stream whereby the solids are entrapped within a gel produced from the silicate solution; and (b) allowing the gel to strengthen and solidify. The process may further comprise spreading the gel produced in step (a) over a surface. The present invention is particularly useful to treat tailings streams produced in processes to extract bitumen from oil sands ores.Type: GrantFiled: March 21, 2013Date of Patent: June 30, 2015Assignee: THE CHEMOURS COMPANY FC, LLCInventors: Robert Harvey Moffett, Sigridur Soley Kristjansdottir
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Patent number: 9051687Abstract: The present invention relates to a process for production of paper, card and board comprising draining a filler-containing paper stock comprising at least one water-soluble polymer with sheet formation in the wire section and then pressing the paper in the press section, wherein a paper stock having a fibrous concentration in the range from 20 to 40 g/l has the at least one water-soluble polymer added to it, then the paper stock is diluted to a fibrous concentration in the range from 5 to 15 g/l, the diluted paper stock is drained to form a sheet and the sheet is pressed in the press section to a solids content G(x) wt % or greater and G(x) computes according to G(x)=48+(x?15)·0.Type: GrantFiled: August 19, 2013Date of Patent: June 9, 2015Assignee: BASF SEInventors: Anton Esser, Hans-Joachim Haehnle
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Patent number: 8999112Abstract: A method for manufacturing a sheet of paper and/or board having improved retention and drainage properties is provided, according to which, before the formation of the sheet and/or board, at least two retention aids are added to the fibrous suspension. These two retention aids are a main retention aid corresponding to a (co)polymer having a cationic charge density above 2 meq/g, obtained by the Hofmann degradation reaction, and a secondary retention aid corresponding to a water-soluble or water-swellable polymer having an anionic charge density above 0.1 meq/g. The main retention aid is introduced into the fibrous suspension in a proportion of 100 to 800 g/t of dry pulp, and the secondary retention aid is introduced into the fibrous suspension in a proportion of 50 to 800 g/t of dry pulp and has an intrinsic viscosity IV above 3 dl/g.Type: GrantFiled: January 30, 2013Date of Patent: April 7, 2015Assignee: S.P.C.M. SAInventors: Gatien Faucher, Rene Hund
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Patent number: 8974637Abstract: The present invention relates to a process for the production of paper and board which comprises: (a) introducing one or more fillers, one or more anionic polysaccharides and one or more cationic agents into a mixing zone to form a filler composition; (b) introducing by means of a pump the filler composition into an aqueous suspension comprising cellulosic fibers; and (c) dewatering the obtained suspension. The present invention also relates to a process for the production of a filler composition which comprises: (a) introducing one or more fillers, one or more anionic polysaccharides and one or more cationic agents into a mixing zone to form a filler composition; (b) introducing by means of a pump the filler composition into a storage tank.Type: GrantFiled: June 5, 2012Date of Patent: March 10, 2015Assignee: Akzo Nobel Chemicals International B.V.Inventor: Patrik Simonson
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Patent number: 8932433Abstract: A method of improving retention and drainage in a papermaking process is disclosed. The addition of an associative polymer, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry to improve retention and drainage is disclosed. Additionally a method to improve retention and drainage comprising addition of an organic microparticle, a poly(vinylamine) and optionally a siliceous material to the papermaking slurry is disclosed. A composition comprising an associative polymer, and a poly(vinylamine) and optionally further comprising cellulose fiber is disclosed.Type: GrantFiled: July 17, 2012Date of Patent: January 13, 2015Assignee: Solenis Technologies, L.P.Inventors: Frank J. Sutman, John C. Harrington, Robert A Gelman
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Patent number: 8888957Abstract: The present invention relates to a process for producing paper which comprises: providing an aqueous suspension comprising cellulosic fibers, adding to the suspension, after all points of high shear, a cationic polysaccharide; an inorganic polymer P1 being a cationic polyaluminium compound; and a polymer P2 being an anionic polymer; and, dewatering the obtained suspension to form paper.Type: GrantFiled: September 6, 2012Date of Patent: November 18, 2014Assignee: Akzo Nobel N.V.Inventors: Fredrik Solhage, Joakim Carlén, Birgitta Johansson
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Patent number: 8888956Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.Type: GrantFiled: April 24, 2012Date of Patent: November 18, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Daniel C Kraiter, Michael Patrick Diebold, Timothy Allan Bell
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Patent number: 8871058Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.Type: GrantFiled: May 31, 2013Date of Patent: October 28, 2014Assignee: International Paper CompanyInventors: James E. Sealey, Brent A. Fields
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Patent number: 8840761Abstract: The present invention relates to a process for controlling deposits in a paper making process, more particularly to a process comprising the use of talc for controlling deposits in a paper making process with talc. One aspect of the invention is contacting talc with a white water stream at one or more locations within the paper making process after separating pulp from a pulp-containing stream and before introducing the re-circulating the white water stream to one or more of a pulper, a thick-stock, a thin-stock, a dilution process, a shower, a storage vessel, a blending process, and a digestor.Type: GrantFiled: June 8, 2011Date of Patent: September 23, 2014Assignee: Imerys Talc America, Inc.Inventor: Daniel Mark Woiceshyn
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Publication number: 20140251565Abstract: The invention provides a method for improving the effectiveness of colloidal silica. The method involves removing enough charged impurities from the colloid to prevent the charged particles from causing the colloid to become a viscous gel. The method however also involves not removing too many charged particles so the silica material doesn't gel by cross-linking with itself. This method is quite effective because it recognizes that materials that have accumulated during the formation of the colloid do perform an important function, but they can perform better at a lower concentration.Type: ApplicationFiled: March 8, 2013Publication date: September 11, 2014Inventors: Jane B. Wong Shing, Zhi Chen, Dennis MacDonald, Ronald S. Doles, Wen Bai
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Publication number: 20140241565Abstract: After beaten, pulp is mixed with a filler to obtain a mixture of the pulp and the filler. Additives are added to the mixture, which is made into pater and then hot-pressed. The filler content of the mixture is in the range of 20 wt % to 80 wt %. After the additives are added, a polymeric viscosity improver with high viscosity is added to produce a narrow diaphragm or a thin compact diaphragm with high aspect ratio. These diaphragms have high rigidity and a wide reproduction frequency range.Type: ApplicationFiled: May 1, 2014Publication date: August 28, 2014Applicant: PANASONIC CORPORATIONInventor: YOHEI JIN
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Patent number: 8790493Abstract: The present invention relates to a process for producing paper which comprises: (vii) providing an aqueous suspension comprising cellulosic fibers, (viii) adding to the suspension after all points of high shear a first polymer being a cationic polymer having a charge density above 2.5 meq/g; a second polymer, and a third polymer being an organic or inorganic anionic polymer; and (ix) dewatering the obtained suspension to form paper.Type: GrantFiled: October 10, 2012Date of Patent: July 29, 2014Assignee: Akzo Nobel N.V.Inventors: Fredrik Solhage, Joakim Carlén, Birgitta Johansson
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Patent number: 8778140Abstract: A method of preparing a stable dispersion of flocculated filler particles for use in papermaking processes comprises use of microparticle prior to, simultaneous to, and/or after addition of a first flocculating agent to an aqueous dispersion of filler particles, followed by addition of a second flocculating agent to the dispersion and further optional shearing of the resultant filler flocs to the desired particle size resulting in shear resistant filler flocs with a defined and controllable size distribution. In addition, a neutralizing coagulant can be added to the dispersion to partially or completely neutralize the charge of the filler before the microparticle and/or the first flocculating agent is added.Type: GrantFiled: November 1, 2012Date of Patent: July 15, 2014Assignee: Nalco CompanyInventors: Weiguo Cheng, Katherine M Broadus, Dorota Smoron, Shawnee M Wilson
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Patent number: 8663427Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.Type: GrantFiled: April 7, 2011Date of Patent: March 4, 2014Assignee: International Paper CompanyInventors: James E. Sealey, Brent A. Fields
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Publication number: 20140034259Abstract: The disclosure provides a paper slurry comprising a treated inorganic pigment, wherein the treated inorganic pigment comprises an inorganic pigment comprising a pigment surface area of about 30 to about 75 m2/g; wherein the pigment surface is treated with an organic treating agent comprising a polyalkanol alkane or a polyalkanol amine, present in the amount of at least about 1.5%, and wherein the treated inorganic pigment has a RHI (rat hole index) of about 7 to about 11.Type: ApplicationFiled: April 24, 2012Publication date: February 6, 2014Applicant: E I DU PONT DE NEMOURS AND COMPANYInventor: Daniel C. Kraiter
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Patent number: 8613832Abstract: The present invention relates to a drainage and retention aid composition which comprises: (d) a first anionic component which is a water-soluble anionic organic polymer; (e) a second anionic component which is a water-dispersible or branched anionic organic polymer; and (f) a third anionic component which is an anionic siliceous material; wherein the first, second and third anionic components are present in a dry matter content of from 0.01 to 50% by weight.Type: GrantFiled: February 15, 2012Date of Patent: December 24, 2013Assignee: Akzo Nobel N.V.Inventors: Johan Nyander, Fredrik Solhage
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Publication number: 20130306261Abstract: The invention provides a method of improving dewatering efficiency, increasing sheet wet web strength, increasing sheet wet strength and enhancing filler retention in a papermaking process. The method improves the efficiency of dewatering aid by coating at least some of the filler particles with a material that prevents the filler materials form adhering to dewatering aids. The dewatering aid holds the paper fibers together tightly and is not wasted on the filler particles.Type: ApplicationFiled: May 25, 2012Publication date: November 21, 2013Inventors: Yulin ZHAO, Jun LI, Qing Long RAO, Weiguo CHENG
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Patent number: 8568565Abstract: The present invention relates to a silica-based sol having a concentration of soluble silica of less than about 1000 mg SiO2/l, conductivity of at least about 2.0 mS/cm and S-value below about 50%. The invention further relates to a method of producing a silica-based sol comprising subjecting an aqueous alkali metal silicate solution to electrodialysis to form an electrodialyzed sol, and acidifying the electrodialyzed sol to form an acidified sol having a pH in the range of from about 5.0 to about 10. The invention further relates to silica-based sol obtainable by the process and to the use of the silica-based sol as a flocculating agent. The invention further relates to a process for producing paper which comprises providing an aqueous suspension comprising cellulosic fibers, adding to the suspension one or more drainage and retention aids comprising a silica-based sol according to the invention, and dewatering the obtained suspension to provide a sheet or web of paper.Type: GrantFiled: July 10, 2009Date of Patent: October 29, 2013Assignee: Akzo Nobel N.V.Inventors: Marek Tokarz, Hans-Åke Baltsen
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Publication number: 20130280545Abstract: Compositions such as filled and coated papers may include microfibrillated cellulose and inorganic particulate material.Type: ApplicationFiled: November 9, 2011Publication date: October 24, 2013Applicant: IMERYS MINERALS LIMITEDInventors: John Claude Husband, Per Svending, David Robert Skuse
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Publication number: 20130192781Abstract: A building material for use in forming exterior surface coverings. According to a preferred embodiment, the building material consists of the combination of a paper material, bonding agent, and water. The building material can either be formed directly upon a substrate, such as a wall or ceiling, or otherwise formed as a sheet of material or molding that can thereafter be affixed to a given surface or substrate. The building materials can be customized to have a specific type of color, shape and texture, and can further be utilized in a wide variety of building applications.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Applicant: TERRABOARD, INC.Inventor: Terraboard, Inc.
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Patent number: 8460512Abstract: The invention provides a three layered reprographic paper having improved strength, stiffness and curl resistance properties, and a method for making same. The paper has a central core layer made largely of cellulose and bulked with a bulking agent such as a diamide salt. A starch-based metered size press coating is pressed on both sides of the core layer, wherein the starch has a high solid content. The coating forms a three layered paper having an I-beam arrangement with high strength outer layers surrounding a low density core.Type: GrantFiled: June 27, 2008Date of Patent: June 11, 2013Assignee: International Paper CompanyInventors: Agne Swerin, Michael Herman, Jay C Song, Sen Yang, Peter F Lee, Ladislav Bednarik
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Patent number: 8460513Abstract: A process in which an at least partially delignified pulp fiber web having a Kappa number of less than about 130 is treated with an aqueous endothermic fire retardant solution having a pH of about 10 or less. The treated pulp fiber web has a near neutral pH of from about 5 to about 9, and is treated with at least about 20 lbs of endothermic fire retardants per ton of the pulp fiber web, with at least about 5% of the total amount of endothermic fire retardants being added at a point prior to when the pulp fiber web is formed. Also a fire resistant pulp fiber web having a near neutral pH.Type: GrantFiled: April 7, 2011Date of Patent: June 11, 2013Assignee: International Paper CompanyInventors: James E. Sealey, Brent A. Fields
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Publication number: 20130139987Abstract: The invention relates to a fiber web and a method for preparing it. The fiber web comprises a filler-containing base web, which is possibly coated with a pigment-containing coating layer. According to the invention, 5-100% of the filler in the base web is made up of cellulose fibrils or lignocellulose fibrils with light-scattering material particles deposited thereon. These coated cellulose fibrils or lignocellulose fibrils constitute at maximum approx. 70% of the weight of the base web. The base web according to the invention contains more than 20% less retention agents than does a web which has the same formation but in which more than 95% of the filler is made up of filler particles known per se.Type: ApplicationFiled: November 14, 2012Publication date: June 6, 2013Inventors: Petri SILENIUS, Jari MEURONEN, Markku LESKELA
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Patent number: 8398821Abstract: Fibrous structures comprising an additive, more particularly finished fibrous structures comprising a low surface energy solid additive, and/or sanitary tissue products comprising such finished fibrous structures, are provided.Type: GrantFiled: May 24, 2011Date of Patent: March 19, 2013Assignee: The Procter & Gamble CompanyInventors: Kenneth Douglas Vinson, Michael Scott Prodoehl
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Patent number: 8354003Abstract: The present invention relates to a porous fiber product, which contains chemical pulp or wood fibers, between which structural filler particles are attached, as well as to a method of manufacturing this product, wherein filler drops are produced in a spray dryer from the aqueous solution of the filler, the drops forming filler particles when the water evaporates, the particles being attached to the chemical pulp or wood fibers.Type: GrantFiled: February 20, 2009Date of Patent: January 15, 2013Assignee: Nordkalk Oy AbInventor: Pentti Virtanen
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Patent number: 8343311Abstract: A method for producing paper, cardboard or similar materials, comprising, separately or in a mixture, adding to a fibrous suspension: at least one main retention agent comprising a cationic (co)polymer, and at least one dual retention agent comprising a crosslinked cationic (co)polymer obtained in the form of a dispersion and placed in solution prior to its introduction into the fibrous suspension with gentle stirring. The crosslinked cationic (co)polymer having—a UL viscosity of between 1.3 and 2.7 cps, preferably between 1.5 and 2.4 cps, and—an apparent cationicity ratio of between 25 and 75%. Optionally, before or after the dual agent or the main retention agent are added, one or more tertiary retention agent(s) selected from the group comprising mineral particles and organic polymers carrying anionic charges, is added to the suspension.Type: GrantFiled: April 10, 2009Date of Patent: January 1, 2013Assignee: S.P.C.M. SAInventors: Rene Hund, Gatien Faucher
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Publication number: 20120318471Abstract: The invention relates to a process for the preparation of a pigment-cellulosic fibre composite, wherein the pigment comprises an inorganic pigment which comprises local cationic charges, said process comprises contacting an aqueous cellulosic fibre suspension and inorganic pigment particles such that crystals of said pigment are attached to the surface of the fibre, said crystals having a size of at most 5 ?m. The produced composite product can be used as a filler pigment or coating pigment in the production of paper.Type: ApplicationFiled: February 10, 2011Publication date: December 20, 2012Inventors: Tarja Turkki, Perttu Heiska
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Patent number: 8273216Abstract: The present invention relates to a process for producing paper which comprises: providing an aqueous suspension comprising cellulosic fibers, adding to the suspension, after all points of high shear, a cationic polysaccharide; and a polymer P2 being an anionic polymer; and, dewatering the obtained suspension to form paper.Type: GrantFiled: December 20, 2006Date of Patent: September 25, 2012Assignee: Akzo Nobel N.V.Inventors: Fredrik Solhage, Joakim Carlén, Birgitta Johansson
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Patent number: 8197642Abstract: An object of the present invention is to provide an inorganic board lighter in weight and excellent in strength and rigidity, and a method of producing the inorganic board. An inorganic board described in claim 1 for accomplishing the object comprises a hydraulic inorganic material, an inorganic lightweight material, a woody reinforcing material and a calcium silicate hydrate, wherein a ratio of the calcium silicate hydrate to the hydraulic inorganic material is 3-54 parts by mass: 100 parts by mass. Thus, by making an inorganic board, made of a hydraulic inorganic material, an inorganic lightweight material and a woody reinforcing material as main components, further contain a calcium silicate hydrate, an inorganic board which is lightweight and excellent in strength and rigidity can be obtained.Type: GrantFiled: July 26, 2007Date of Patent: June 12, 2012Assignee: Nichiha CorporationInventor: Hideo Aizawa
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Patent number: 8133352Abstract: A method of manufacturing high purity fiber cement grades of cellulose fibers is described. Additional washing steps, coupled with an elevated temperature, are used in the process to extensively wash the pulps and remove substantially all COD components remaining in the pulps. The pulps are counter-currently washed by diffusion and dewatering at elevated temperatures following the brown stock washer systems. During the additional washing steps, the pulps are soaked in counter-current heated water for a pre-determined time and some chemicals may be introduced to chemically break down the COD components in the pulps and to make them more soluble in the aqueous solution. The additional washing steps can be performed using existing equipment at conventional pulp mills. A formulation and a process of making fiber reinforced cement composite materials are also described using the low COD and high purity cellulose fibers.Type: GrantFiled: October 2, 2001Date of Patent: March 13, 2012Assignee: James Hardie Technology LimitedInventors: Donald J. Merkley, Caidian Luo
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Patent number: 8118976Abstract: The present invention concerns a process for the production of a cellulosic product comprising providing a fiber-containing suspension, wherein at least about 60% by weight of the fibers are cellulosic fibers, and dewatering the suspension on a wire to form a cellulosic fiber web, the process further comprising adding silica-based particles to the formed web and a wet strength agent to the suspension and/or to the formed web. The invention also concerns a product obtainable by the process. The invention further concerns a dispersion comprising silica-based particles and a substantially aldehyde-free wet strength agent. A further aspect of the invention concerns a dispersion comprising silica-based particles having a specific surface area ranging from about 1000 to about 1700 m2/g and a wet strength agent. Still another aspect of the invention concerns the use of the dispersion as an additive in a papermaking process.Type: GrantFiled: April 28, 2008Date of Patent: February 21, 2012Assignee: Akzo Nobel N.V.Inventors: Hans Johansson-Vestin, Arne Andersson, Fredrik Solhage
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Patent number: 8097127Abstract: An aqueous polysilicate composition comprising a polysilicate microgel based component in association with particles derived from colloidal polysilicate. The invention also concerns a process for preparing an aqueous polysilicate composition comprising mixing an aqueous colloidal polysilicate with an aqueous phase of a polysilicate microgel. The aqueous polysilicate composition is more effective than colloidal silica and is more stable than a conventional polysilicate microgel.Type: GrantFiled: September 13, 2007Date of Patent: January 17, 2012Assignee: BASF SEInventors: Sakari Saastamoinen, Tero Seppala, David Robert Cordier, Christian Bruce Edmonds
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Patent number: 8092587Abstract: The invention relates to stabilized dispersions of precipitated silicon dioxide, to a process for production thereof and to the use thereof, especially for production of paper coatings for glossy photo paper for inkjet printing.Type: GrantFiled: January 21, 2011Date of Patent: January 10, 2012Assignee: Evonik Degussa GmbHInventors: Florian Zschunke, Burkhard Standke, Stefan Scharfe, Christoph Batz-Sohn, Heinz Lach, Andrea Heuschen, Juergen Behnisch, Markus Ruf, Guenter Stein, Tobias Banert
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Publication number: 20110303377Abstract: A method of manufacturing a newsprint paper for offset printing, includes: selecting a filler or fillers having an average grain size of 0.5 to 5 ?m and a zeta potential of 0 mV or above; providing a pulp slurry for making a base paper; adding the filler or fillers to the pulp slurry in an amount of more than 15 percent by weight but less than 40 percent by weight as ash relative to the dry weight of the base paper; and subjecting the resultant slurry to a papermaking machine to obtain the base paper.Type: ApplicationFiled: August 18, 2011Publication date: December 15, 2011Applicant: NIPPON PAPER INDUSTRIES CO., LTD.Inventors: Fuminari NONOMURA, Tomohiro HIGATA, Yasunori NANRI
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Publication number: 20110263784Abstract: The invention relates to a novel method of preparing silicas and to highly-structured silicas having the following characteristics: a specific surface area CTAB (SCTAB) of between 40 and 525 m2g/g; a specific surface area BET (SBET) of between 45 and 550 m2g; an object size distribution width Ld ((d84?D16)/d50), which is measured by XDC particle size analysis after deagglomeration with ultrasound, of at least 0.91; and a pore-size distribution such that ratio V(d5?d50)/V(d5?d100) is at least 0.66. The invention also relates to the use of said silicas as polymer reinforcing fillers.Type: ApplicationFiled: June 22, 2011Publication date: October 27, 2011Applicant: RHODIA CHIMIEInventors: Rémi VALERO, Julien Hernandez
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Patent number: 8038846Abstract: According to the present invention, a process is provided for making paper or board comprising forming a cellulosic suspension that may or may not comprise a filler, flocculating the cellulosic suspension, draining the cellulosic suspension on a screen to form a sheet, wherein the cellulosic suspension is flocculated using a flocculation system comprising the sequential or simultaneous addition of a siliceous material and an organic, cationic or anionic, water-in-water or dispersion micropolymer in a salt solution.Type: GrantFiled: September 14, 2007Date of Patent: October 18, 2011Assignee: Kemira OyjInventors: Marco Savio Polverari, Christopher Michael Lewis, Matthew Gerard Fabian
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Publication number: 20110247774Abstract: The present invention relates to a silica-based sol having a concentration of soluble silica of less than about 1000 mg SiO2/l, conductivity of at least about 2.0 mS/cm and S-value below about 50%. The invention further relates to a method of producing a silica-based sol comprising subjecting an aqueous alkali metal silicate solution to electrodialysis to form an electrodialyzed sol, and acidifying the electrodialyzed sol to form an acidified sol having a pH in the range of from about 5.0 to about 10. The invention further relates to silica-based sol obtainable by the process and to the use of the silica-based sol as a flocculating agent. The invention further relates to a process for producing paper which comprises providing an aqueous suspension comprising cellulosic fibers, adding to the suspension one or more drainage and retention aids comprising a silica-based sol according to the invention, and dewatering the obtained suspension to provide a sheet or web of paper.Type: ApplicationFiled: July 10, 2009Publication date: October 13, 2011Applicant: AKZO NOBEL N.V.Inventors: Marek Tokarz, Hans-Ake Baltsen
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Publication number: 20110240240Abstract: The invention relates to an aqueous polysilicate composition comprising i) particles of polysilicate seeds, ii) polymerised silicate in intimate association with the polysilicate seeds, iii) cross linkages within the polymerised polysilicate formed from aluminium atoms, aluminium compounds or aluminium ions, iv) cross linkages within the polymerised polysilicate formed from atoms, compounds or ions of a multi-valent metal other than aluminium. Preferably the aqueous polysilicate composition further comprises component v) a water-soluble branched anionic polymer that has been formed from ethylenically unsaturated monomers. The invention also incorporates a method for preparing an aqueous polysilicate composition and also to the use of the aqueous polysilicate composition as a retention/drainage aid in a process of making paper or paperboard.Type: ApplicationFiled: November 12, 2009Publication date: October 6, 2011Applicant: BASF SEInventors: Sakari Saastamoinen, Neil Sidney Harris
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Patent number: 8025768Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.Type: GrantFiled: June 5, 2008Date of Patent: September 27, 2011Assignee: FpinnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Publication number: 20110226432Abstract: A method of mixing at least two chemicals or additives into a process liquid flow flowing in a process liquid flow duct including: feeding a liquid jet to the process liquid flow in the process liquid flow duct, wherein the liquid jet is formed in a feeding device and the liquid jet flows in a transverse direction to a flow direction of the process liquid flow through the process liquid flow duct; mixing the at least two chemicals or additives together to form a mixture; feeding the mixture of the at least two chemicals or additives into the process liquid flow duct with the feeding liquid jet, and mixing the at least two chemicals or additives with the feeding liquid jet in the process liquid flow duct.Type: ApplicationFiled: May 16, 2011Publication date: September 22, 2011Applicant: WETEND TECHNOLOGIES OYInventor: Jouni MATULA
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Publication number: 20110226433Abstract: The invention provides a method of producing paper with a higher proportion of mineral filler particles than is otherwise be possible without the expected loss in paper strength by preflocculating the filler particles. The method allows for the use of the greater amount of filler particles by coating at least some of the filler particles with a material that prevents the filler materials form adhering to a strength additive. The strength additive holds the paper fibers together tightly and is not wasted on the filler particles.Type: ApplicationFiled: March 19, 2010Publication date: September 22, 2011Inventors: Weiguo Cheng, Ross T. Gray
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Patent number: 8016979Abstract: A chemical solution-containing thin paper wherein a chemical solution is contained in an amount of 5 to 40% by weight with respect to base paper, powders are included in an amount of 0.1 to 30% by weight with respect to the chemical solution, the powders are formed by blending first powders each having an average particle size of 3 to 15 ?m and second powders each having an average particle size of 15 to 40 ?m with a weight ratio of the first powders with respect to the second powders of 0.1:1.9 to 1.9:0.1, and the chemical solution does not include an adhesive ingredient.Type: GrantFiled: January 12, 2007Date of Patent: September 13, 2011Assignee: Daio Paper CorporationInventor: Atsushi Konuma
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Patent number: RE44519Abstract: Starch compositions, including cationic crosslinked starches, and methods of using those starches in papermaking are disclosed. In particular, a cationized crosslinked starch and use of the starch in the wet end system of a paper machine is disclosed. The starch compositions of the disclosure are particularly adapted for customization for specific wet end systems, and allow for modification to correspond to variations in the wet end of the papermaking machine.Type: GrantFiled: February 24, 2005Date of Patent: October 8, 2013Assignee: Cargill, IncorporatedInventors: Kevin Ray Anderson, David Edward Garlie