Abstract: The present disclosure provides methods and systems for mitigating finished product temperature transients caused by changes in product flow, raw product temperature, or other disturbances in an aseptic sterilization process. The methods and systems include applying an energy balance feedforward control scheme to the aseptic sterilization process to compensate for raw product temperature changes and changes in product flow. The methods and systems prevent damage to a finished product from occurring based on adverse transient temperature responses of heaters and coolers in an aseptic sterilization process.

Abstract: Described are methods for pretreating lignocellulosic biomass that comprise passing a hot aqueous biomass slurry through a heat exchange passage from an inlet to an outlet and locally regulating pressure in the passage by feed of a pressurized liquid medium to one or more intermediate locations of the passage. Also described are methods for producing ethanol from the pretreated biomass.

Abstract: A method and system for pulp manufacturing used in connection with a kraft process includes a vertical pressure vessel operated in batch mode, a single-vessel or multi-vessel continuous digester, and other equipment for further processing brown stock, such as for washing, oxygen delignification, bleaching, and drying. A feeder and conveyance system may include a high pressure feeder or direct pump system, and selectively provides fiber-containing material to the continuous digester when making lower grade pulp product and to the vertical pressure vessel when making higher grade pulp such as dissolving pulp. The vertical pressure vessel is used for pre-hydrolysis and neutralization, after which the resulting pulp is fed to the continuous digester for cooking. White liquor and black liquor from the same mill may be used for the neutralization fluids. The same continuous digester is selectively used for cooking in connection with making pulp products of different grades or quality.

Abstract: Properties of an end product, such as paper, paperboard or board, are important for the user of the end product. To be able to manufacture an end product of desired quality, it is important to know what kind of paper pulp used for manufacturing the end product results in a particular kind of property of the end product. Embodiments provide a method and an apparatus for generating a model, which model connects at least one property of the end product with at least one property of the paper pulp. On the basis of the model, also the manufacturing process can be controlled.

Abstract: A system and method for optimizing a process for refining lignocellulosic granular matter such as wood chips use a predictive model including a simulation model based on relations involving a plurality of matter properties characterizing the matter such as moisture content, density, light reflection or granular matter size, refining process operating parameters such as transfer screw speed, dilution flow, hydraulic pressure, plate gaps, or retention delays, at least one output controlled to a target such as primary motor load or pulp freeness, and at least one uncontrolled output such as specific energy consumption, energy split, long fibers, fines and shives. An adaptor is fed with measured values of matter properties and measured values of controlled and uncontrolled outputs, to adapt the simulation model accordingly. An optimizer generates a value of the target according to a predetermined condition on a predicted uncontrolled output parameter and to one or more process constraints.

Abstract: The present invention relates to a process for pretreatment of a feedstock in a pretreatment tank. Various parameters, such as oxidation-reduction potential, pH, and temperature, are monitored in the pretreatment tank to determine whether the oxidation-reduction potential, pH, and temperature are each within a predetermined range. The volume of feedstock inside the pretreatment tank is adjusted in response to a determination that one of the oxidation-reduction potential, pH, and temperature of the treated material are outside the corresponding predetermined ranges to maintain the oxidation-reduction potential, pH, and temperature of the treated material within operating conditions.

Abstract: The vessel in which the chips are pre-treated with steam (ST) is provided with a ventilation channel at the top of the vessel for the leading away of weak gases to a weak gas system (NCG). A simple safety system has been installed with the aim of guaranteeing that these weak gases do not reach a level of concentration at which these weak gases become explosive. The safety system has a control unit (CPU) that detects a process parameter that is indicative of the fraction of moisture in the weak gases and opens dilution lines that supply air for the dilution of the weak gases in the ventilation channel. It is appropriate that the dilution take place in stages, where the dilution lines are opened in stages with successively increasing temperature of the weak gases.

Abstract: An enhanced method of repulping paper and improving water quality by placing used paper product material in an aqueous solution of dipolar aprotic protophylic solvent, processing it, and recovering recycled pulp based on two physical reactions of the dipolar solvent: first with water from one part of the solvent, and second with cellulosic material from the other part of the solvent. The water reaction involves a rearrangement of hydrogen bonds within the water, improving its reactivity and solvent capacity, and the cellulosic reaction involves dissolution of hemicellulose in a manner which results in reduced fibre loss and improved pulp quality. The net result is more efficient pulping and reduced environmental impact.

Abstract: The vessel in which the chips are pre-treated with steam (ST) is provided with a ventilation channel at the top of the vessel for the leading away of weak gases to a weak gas system (NCG). A simple safety system has been installed with the aim of guaranteeing that these weak gases do not reach a level of concentration at which these weak gases become explosive. The safety system has a control unit (CPU) that detects a process parameter that is indicative of the fraction of moisture in the weak gases and opens dilution lines that supply air for the dilution of the weak gases in the ventilation channel. It is appropriate that the dilution take place in stages, where the dilution lines are opened in stages with successively increasing temperature of the weak gases.

Abstract: A method and apparatus for treating pulp in connection with a blow tank or a storage tank. The pulp is discharged from a batch digester and fed either to the upper or the lower part of a blow tank, depending on the consistency of the pulp being discharged from the digester.

Abstract: The method and an arrangement are for improved impregnation of chips in association with the manufacture of chemical cellulose pulp. Un-steamed chips are fed into an impregnation vessel (30) in which a fluid level (LIQ_LEV) is established under the highest level (CH_LEV) of the chips. An improved impregnation arrangement for the chips is obtained by the addition of impregnation fluids (BL1/BL2/BL3) with increasing temperatures at different heights (P1, P2, P3), and by the establishment of a counter-flow zone (Z1) in the uppermost part of the impregnation vessel. The requirement for steaming may in this way be dramatically reduced while at the same time the amount of expelled waste gases may be minimized. A major part of the volatile compounds present in the wood are bound to the impregnation fluid (REC) that is withdrawn.

Abstract: Thermomechanical pulp is an important process for producing fibrous mass used in papermaking. A two-level control strategy that stabilizes and optimizes the refining process has been developed. The Stabilization layer consists of a multivariable model predicative range controller that regulates the refiner line operations. The Quality Optimization layer provides the pulp quality control as measured by an online pulp quality (freeness, fibre length) sensor. This control startegy leverages the natural decoupling in the process. The modular design technique is able to handle multiple refiner lines that empty into a common latency chest. A global optimizer is also used to integrate and coordinate the two layers for enhanced constraint handling.

Abstract: A pulp pre-processor for the papermaking industry uses pulp fiber analyzers to determine the distribution of fiber parameters, such as length, curl or coarseness from a feed source, such as recycled pulp, and mixes metered portions of pulp from augmenting pulp sources on an as-needed basis to provide a uniform distribution of a particular fiber parameter while maximizing use of recycled pulp.

Abstract: Countercurrent extraction of lignocellulosic biomass such as trees, grasses, shrubs, and agricultural residues or waste involves the separation of cellulose fibers from other constituents, for subsequent use in the manufacture of paper, plastics, ethanol, and other industrial chemicals. Systems and methods involve continuous, multiple processing steps that may include chemical reactions with mixing at elevated temperature and/or pressure, efficient reagent or solvent utilization, filtration at elevated temperature and/or pressure, controlled discharge of liquid and solid products, and energy recuperation.

Abstract: A system for treating pulp comprises a dewatering device (2) for dewatering the pulp to a fiber concentration of at least 20%, a closed pulp-shredding vessel (16) for shredding the dewatered pulp, and an outlet pipe (22) from the pulp-shredding vessel. A transport screw (18) is arranged in the outlet pipe for transporting the shredded pulp from the pulp-shredding vessel through the outlet pipe through a reactor vessel (6) for bleaching the shredded pulp through reaction with ozone gas. The outlet pipe (22) is designed with a heightened roof portion (27), so that an upper gas space (29) free from pulp is formed in the outlet pipe between the roof portion and the transport screw. A flow-restraining member in the form of a partition wall (31) is arranged in the upper gas space in the outlet pipe for restraining the gas flow through the gas space, whereby the pumping action of the transport screw in the outlet pipe is decreased.

Abstract: A system for controlling a processor having at least one sampling port connected to a stage of the processor in order to sample a reactant product from the processor. The system includes a controller configured to control a processing parameter of the processor based on measurements of at least one property of the reactant product such that changes to the processing parameter maintain a target value for the at least one property of the reactant product. The system further includes a dead time compensator. The dead time compensator is configured, based upon a prescribed dead time related to a time before at least one effect of at least one change to the processing parameter is fully realized, to evaluate the reactant product to determine if the effect has been realized at a plurality of sequential times offset from the dead time.

Abstract: A computer based method for controlling an industrial process that includes at least two unit processes, including the steps of directly controlling the process by a control model including one or more algorithms, and automatic diagnosis of the validity of the process data retrieved from the process for the purpose of preventing irrelevant process data from being used as an input in the control model.

Abstract: A chip bin for a digester has an upper part through which chips fall freely from an inlet and a lower part within which the chips remain until they are fed to a digester. Steam orifices strike falling chips with steam and disperses the chips over the interior of the chip bin. Further steam heats the chips and drives out non-condensable gas. The lower part of the chip bin is conical. Steam jets aimed down the conical walls propel the chips to an outlet at the bottom and prevent bridging.

Abstract: A system (30) and method for determining stock consistency and for using consistency as a process variable to control some aspect of operation of a refiner (32) used to refine stock. The system includes at least one sensor (70 or 180) from which some refiner characteristic is obtained that is used by a processor (38) in determining consistency. The method uses the characteristic, such as temperature or pressure inside the refiner or in a refining zone (304) of the refiner, along with at least one other refiner parameter in determining consistency. A controller (274) uses the consistency determined in controlling some aspect of refiner operation. In one preferred controller, consistency is compared with a consistency setpoint and adjustments are made to try to converge consistency with the setpoint. The controller can be paused to accommodate other changes made to refiner operation and released when steady state refiner operation is achieved.

Abstract: A control system is provided for controlling a process for making paper or paper pulp. The process has a process product output at an end of the process. The controls include a process variable sensor input configured to receive a process variable related to the process. The controller is configured to provide a control signal to control the process. A process model has a model product output which is a model representation of the process product output. The model process output is a function of the sensed process variable and a product output setpoint representative of a desired process product output. The control signal is a function of the product output setpoint and the modeled product output.

Abstract: An apparatus and process for solvent pulping of cellulose-containing biomass utilizes at least one steaming vessel, a plug screw feeder or compression screw device, at least one super-atmospheric impregnation vessel, a solvent delignification reactor capable of operating at a pressure of 350 psig or more, and a solvent containing line for introducing solvent-containing liquor at the plug screw feeder outlet or compression screw device outlet. The process and system can also include at least one series connected pressure diffuser and optionally a retention tube downstream of each pressure diffuser to provide sufficient retention time to substantially preclude re-deposition of lignin on the cellulose fibers of the biomass, a blow tank connected to the last of the pressure diffusers and retention tubes, and vessels for multistage alcohol washing.

Abstract: The present invention includes a process for extracting bio-functional materials from biomass. The method comprises providing biomass and subjecting the biomass to substantially instantaneous pressurization and depressurization to separate bio-functional materials, such as cellulose, hemicellulose, and lignin from the biomass.

Abstract: A system and method for improved filtrate addition in a continuous digester is disclosed. The system comprises a blow dilution header/nozzle assembly located in the blow dilution zone of the digester. The header/nozzle assembly comprises (i) a plurality of nozzles for introducing and distributing filtrate into the blow dilution zone, and (ii) a plurality of measurement and control devices for monitoring and controlling filtrate flow through the plurality of nozzles. The method comprises (a) introducing and distributing filtrate through a plurality of nozzles of a blow dilution header/nozzle assembly in the blow dilution zone of the continuous digester; and (b) measuring and controlling the filtrate flow through each nozzle of the plurality of nozzles.

Abstract: A system and method for rapidly determining the pulp kappa number through direct measurement of the potassium permanganate concentration in a pulp-permanganate solution using spectrophotometry. Specifically, the present invention uses strong acidification to carry out the pulp-permanganate oxidation reaction in the pulp-permanganate solution to prevent the precipitation of manganese dioxide (MnO2). Consequently, spectral interference from the precipitated MnO2 is eliminated and the oxidation reaction becomes dominant. The spectral intensity of the oxidation reaction is then analyzed to determine the pulp kappa number.

Abstract: Bleaching device for pulp includes a container to which a supply of pulp and bleaching chemicals containing peroxide as well as discharge of bleached pulp are connected. The device comprises an oxygen measuring device a temperature measuring device and/or a carbon monoxide measuring device, which are arranged to measure oxygen concentration, temperature and/or carbon monoxide concentration, respectively, from the contents of the container such as from the gas volume of the same, or from a substance flow coming from the container, such as gas flow. The measuring device is connected to a data processing unit which is coupled to a controller for automatic control of the process. The process is especially a high consistency pulp bleaching of mechanical pulp, in which the consistency of pulp in the reaction area is at least 25%, advantageously at least 30%.

Abstract: In the feeding of a slurry of comminuted cellulosic fibrous material to a digester (continuous or batch) in the production of chemical pulp, one of the tanks used in the feed system (which preferably includes a high pressure feeder) may be eliminated without consequent loss of its function by providing a single tank with the combined functions of controlling the level of liquid in a slurrying conduit which supplies slurry to a slurry pump, and storing and substantially continuously supplying liquid to a make-up liquid pump connected to the digester. The single tank preferably surrounds the slurrying conduit and is substantially concentric, and in liquid communication, with it. A gap of 3-48 inches may be provided between the bottom of the conduit and a connection to the slurry pump. A screen or strainer may be provided in the gap, which is substantially surrounded by the tank.

Abstract: In the feeding of a slurry of comminuted cellulosic fibrous material to a digester (continuous or batch) in the production of chemical pulp, one of the tanks used in the feed system (which preferably includes a high pressure feeder) may be eliminated without consequent loss of its function by providing a single tank with the combined functions of controlling the level of liquid in a slurrying conduit which supplies slurry to a slurry pump, and storing and substantially continuously supplying liquid to a make-up liquid pump connected to the digester. The single tank preferably surrounds the slurrying conduit and is substantially concentric, and in liquid communication, with it. A gap of 3-48 inches may be provided between the bottom of the conduit and a connection to the slurry pump. A screen or strainer may be provided in the gap, which is substantially surrounded by the tank.

Abstract: This invention describes a new method to measure kappa number or lignin content of kraft pulps based on the voltammetric measurement of catalytic reactions involving lignin and redox mediators. This method comprises measuring the rate of regeneration of a lignin redox catalyst in the presence of pulp following its oxidation at a voltammetric electrode. The intensity of the catalytic current generated at the electrode surface is shown to be proportional to the amount of lignin present in a pulp. Within pulp types (softwood, hardwood or oxygen delignified) linear relationships can be obtained between the intensities of the generated current and a range of kappa numbers. The redox characteristics and concentration of the mediator, and the voltage sweep rate of the voltammetric procedure, are among parameters that can be tuned to obtained linear relationships with kappa number of various pulps.

Abstract: An on-line pulp digester control system. More particularly, this invention pertains to a control system which employs real time measurements from ion mobility spectrometry to automatically rapidly and continuously determine the physical and chemical characteristics of wood chip feedstock being fed into a pulp digester and thereby maximize process efficiencies, minimize chemical and energy consumption and improve product uniformity.

Abstract: In the feeding of a slurry of comminuted cellulosic fibrous material to a digester (continuous or batch) in the production of chemical pulp, one of the tanks used in the feed system (which preferably includes a high pressure feeder) may be eliminated without consequent loss of its function by providing a single tank with the combined functions of controlling the level of liquid in a slurrying conduit which supplies slurry to a slurry pump, and storing and substantially continuously supplying liquid to a make-up liquid pump connected to the digester. The single tank preferably surrounds the slurrying conduit and is substantially concentric, and in liquid communication, with it. A gap of 3-48 inches may be provided between the bottom of the conduit and a connection to the slurry pump. A screen or strainer may be provided in the gap, which is substantially surrounded by the tank.

Abstract: A rapid method is provided for the on-line spectroscopic determination of lignin content and/or kappa number in wood pulps. Unlike currently available commercial instrumentation, the method enables one to measure lignin content independently of species variations and pulp consistency.

Abstract: The present invention relates to a device and method for measuring the bleach requirement and bleachability of pulp in a pulp mill. The invention enables pulp mill operators to better control bleach plants. In one aspect, the invention comprises a system and method for rapid bleaching of the pulp, and measuring the rapid bleached brightness and lignin content of the pulp. In another aspect, the invention comprises an optical system for use in practicing embodiments of this invention.

Abstract: Methods of controlling oxygen delignification processes are disclosed including providing chemicals for a first oxygen delignification step, conducting the first oxygen delignification step with the chemicals, conducting a second oxygen delignification step at a predetermined temperature to produce a delignified pulp, measuring the final kappa number of the delignified pulp subsequent to the second oxygen delignification step, adjusting the chemicals provided for the first oxygen delignification step based upon the difference between the actual kappa number reduction and the desired kappa number reduction for the pulp, and adjusting the predetermined temperature based on the chemicals provided to the first oxygen delignification step in order to provide the delignified pulp at a final pH of from about 10.5 to about 11.5.

Abstract: A walled passageway, having openings therein only at opposite, inlet and outlet ends thereof, has a shaft journalled therein. The shaft carries a screw thereon for moving shredded pulp through the passageway. The screw is foreshortened, having a length less than that of the passageway, and causes inlet-admitted pulp to form into a continuously moving pulp plug. The plug, albeit having some porosity, comprises a gas seal within the passageway, and inhibits any migration of downstream gas from escaping to the atmosphere via the passageway and the inlet thereof. In addition, a source of oxygen or such gas as is inert to any downstream process is controllingly admitted into the inlet to maintain an upstream pressure equal to, or greater than any downstream process pressure to insure against release of downstream gas into the atmosphere.

Abstract: A method for controlling the addition of bleaching/delignifying reagents to obtain a substantially constant percentage of pulp delignification across the first bleaching stage. The present method allows substantial improvements in bleached pulp quality through proper addition of the bleaching/delignifying reagent flow rate. The efficiency of the bleaching/delignifying reagent is therefore greatly improved. Further, reduction of pulp off-grades, equipment corrosion and effluent loading are additional beneficial effects resulting from the present method.

Abstract: By establishing a relatively flat, for example, non-sharply conical, top profile of wood chips in a treatment vessel (such as a chip bin), the chips will be more uniformly steamed or otherwise treated (or have the treatment time of the chips extended) compared to if a conventional sharply conical top profile is established in the treatment vessel. The relatively flat top profile of the chips in the treatment vessel is established by utilizing a plurality (typically at least three, and preferably four or more) individually controlled gates (typically having a substantially polygon shape, such as triangular). The gates are mounted below the inlet of chips into a treatment vessel so to deflect, not significantly affect, or substantially preclude the flow of chips past them into the vessel depending upon the positions of each.

Abstract: A method of controlling the pressure of a vertical continuous comminuted cellulosic fibrous material (wood chip) digester is provided using a pressure-control extraction in a zone relatively insensitive to changes in the flow rate of liquid introduction or removal. The method comprises controlling the pressure in the digester primarily (or substantially exclusively) by varying the flow rate of liquor extracted from the pressure-control extraction to maintain the pressure in the digester at a desired superatmospheric level while avoiding non-uniform, unstable material movement in the counter-current washing zone; and introducing dilution liquid into the digester at the at least one recirculation-dilution loop. The pressure-control extraction is preferably substantially the upper extraction in the digester. Substantially except during excessive over pressure and under pressure conditions the extraction flow from the main extraction is maintained substantially constant.

Abstract: An automated tracer system and method for measuring the residence time of wood pulp as it moves through various stages of processing in a pulp mill. A tracer compound comprising a neutral salt of a halogen is introduced into a first location in the path of the pulp slurry; at a second location an automated detector detects the concentration of tracer compound over a time period; a controller relays a voltage signal from the detector to a processor which uses a calibration curve to integrate tracer concentration over time and thereby derive pulp residence, between the first and second locations.

Abstract: To enable extraction of one specific optical fiber from a plurality of optical fibers at remote sites. An environment variable apparatus is mounted to provide a temperature difference at a predetermined position of an optical fiber. An environment variable apparatus is mounted to detect scattered light of light incident on the optical fiber through one end thereof so as to extract a target optical fiber from a large member of optical fibers. Further, synchronous devices are mounted to transmit from the environment variable apparatus to the extracting apparatus a message in that the temperature difference is given to the optical fiber, and transmit from the extracting apparatus to the environment variable apparatus a decision signal as to whether or not the optical fiber is to be extracted.

Abstract: The sulfide ion concentration and sulfidity of kraft cooking liquor during kraft cooking of cellulose pulp is selectively increased. After treatment in a first treatment zone in which impregnation or kraft cooking takes place using a kraft cooking liquor having a first sulfide ion concentration and sulfidity, black liquor is extracted from the material, liquid is withdrawn from the material and dilution liquid is added to the withdrawn liquid and the withdrawn liquid with dilution liquid is reintroduced. In a second treatment zone after the first zone a second kraft cooking liquor is introduced having a second sulfide ion concentration and sulfidity greater than the first sulfide ion concentration and sulfidity (typically by about 20-50%), including by manipulating controlling the flow rate of extraction and the flow rates of withdrawal of liquid and addition of dilution liquid.

Abstract: An automated system and method for measuring the residence time of wood pulp as it moves through various stages of processing in a pulp mill. A tracer compound comprising a neutral salt of a halogen is introduced into a first location in the path of the pulp slurry; at a second location an automated detector detects the concentration of tracer compound over a time period; a controller relays a voltage signal from the detector to a processor which uses a calibration curve to integrate tracer concentration over time and thereby derive pulp residence, between the first and second locations.

Abstract: A process control method for adjusting chemical application in response to the pulp brightness and/or lignin content is realized by utilizing a coupled control feedforward, feedback or combination feedforward/feedback control system, wherein brightness measurements are made between successive lignin content measurements and adjustments made to the chemical application in response to a comparison value.

Abstract: A batch digester loading method is described wherein a flow stream of steam enters the digester near the bottom thereof as a flow stream of wood chips enters through the top filler neck. Steam flow begins in the bottom portion of the digester at an initial, reduced flow rate after a minimum chip mass is accumulated. Steam flow is thereafter increased at a rate proportional to the inflow rate of chips.

Abstract: A process control for adjusting bleaching agent application in response to the pulp brightness and/or K number is realized by utilizing a coupled control feedforward and/or feedback control system or combination thereof wherein brightness measurements are made between successive K number measurements and adjustments made to the bleaching agent application in response to a comparison value.

Abstract: In a continuous digester system the chip feed equipment is greatly simplified by substituting a single vertical vessel for the conventional chip bin, steaming vessel and chip chute. An outlet at the bottom of the single vessel is connected, through a low pressure pump, to the low pressure input of a high pressure transfer device which is connected to a digester (either directly or through an impregnation vessel). A metering device, preferably through a pressure isolation device for maintaining superatmospheric pressure in the vessel, feeds chips into the top of the vessel. A first level, of chips, is established in the vessel and a second, liquid, level below the first level is also established. Steam is supplied to a volume between the top of the vessel and the second level utilizing a conduit with an automatically controlled valve and a temperature controller for at least partially controlling the valve.

Abstract: A mill for the processing and production of wood pulp is contained substantially entirely within a single, integral structure that defines a unitarily-covered space substantially bounding and enclosing the mill. The mill includes a main control room or station for overall monitoring and control of pulp processing operations in the mill, the main control station being disposed substantially centrally within the covered space, and a plurality of processing stations at which various pulp processing operations take place in a generally sequential manner or order.

Abstract: A system for feeding wood chips entrained in cooking liquor to a high pressure feeder connected to a continuous digester includes a vertical treatment (e.g. steaming) vessel, a metering device connected to the discharge from the steaming vessel, a generally vertical chip chute extending downwardly from the metering device, and a slurry pump having an inlet. The slurry pump pumps the slurry from an outlet thereof to a high pressure feeder low pressure inlet. In order to minimize the effect of changes in liquid volume upon the operation of the system, and to provide separate control of liquor volume and chip volume, a substantially vertical liquor tank having a top and bottom the bottom including a discharge opening above the slurry pump inlet is provided. A conduit directly connects the liquor tank discharge opening with the slurry pump inlet. A pressure isolating device may be used in the system if it is to operate at superatmospheric pressure rather than atmospheric pressure.

Abstract: A rapid method is provided for the on-line determination of sodium sulfide concentration and/or percent sulfidity in green liquors or smelt solutions used for the production of either kraft or sulfite pulp. The method eliminates manual sampling, and the need for frequent equipment maintenance.

Abstract: The invention relates to a method of determining the concentration of sulfide and optionally also of polysulfide in liquors and solutions of smelt deriving from the sulfate process. According to the method, the concentrations are determined by measuring the light absorption of the liquor or the solution in the ultra-violet range. According to one preferred embodiment, the method is applied to determine the degree of reduction in sulfate liquor and smelt derived from burning liquor, wherein the concentrations of sulfate, thiosulfate and optionally sulfite and/or carbonate are determined by measuring the light absorption of the liquor or the solution in the infrared range, whereafter the degree of reduction is calculated from the measuring data obtained.

Abstract: A chip bin for wood chips in a continuous digester system includes internal steaming that is controlled in response to both the interior temperature across the level of chips in the bin, and the level of chips in the bin, so as to substantially prevent cool, non-condensible gas-laden chips from accumulating at the top of the chip column in the bin, and to substantially prevent steam blow-through. The temperature probe used in the chip bin has a temperature sensing portion with a length of about ten to twenty feet instead of the conventional five foot length, and extends across the level of the chips to a position about five feet below the level of chips. Control of steam added to the bin is provided utilizing a controller which controls the position of one or more valves in one or more steam conduits, each valve having multiple open positions and a closed position.