Abstract: The spent liquor (SL) of a thermomechanical pulping (TMP) process introduces a high load to the wastewater system of this process. To reduce this load, fly ash from a biomass boiler is used for removing lignin from the SL, and also for decreasing the chemical oxidation demand (COD) and turbidity of the SL.

Abstract: The method is for producing pulp. More particularly, a displacement batch cooking process comprises recovery of a first treatment liquid by draining of the digester, preferably not using a displacement liquid. The method may preferably be used in a prehydrolysis step, wherein the recovery of the by-products is improved. In the recovery step, after the target P-factor in the prehydrolysis stage is reached, the hydrolysate is withdrawn by draining in at least one phase obtaining a strong first liquid and thereafter any residual hydrolysate may be displaced.

Abstract: The method is for producing pulp in batch digesters. More particularly, the method is for ending a treatment phase of the digester content. In order to obtain a more uniform pulp quality from the process is the treatment phase ended by displacing a liquor volume (WLP) through the digester vessel with an imposed increasing temperature in the displacement liquor added to digester.

Abstract: A reactor vessel system including: a first reactor vessel having a hydrolysate and liquid extraction screen, a first region above the extraction screen that is maintained at conditions promoting a hydrolysis reaction in the cellulosic material, a second region below the extraction screen in which the hydrolysis is substantially suppressed and a wash liquid inlet below the extraction screen providing wash liquid at a temperature below a hydrolysis temperature; a transport pipe having an inlet coupled to the first reactor vessel and an outlet coupled to a second reactor vessel, and the second reactor vessel includes a liquid discharge that extracts a portion of liquid from the second reactor vessel and directs the portion of liquid to the first reactor vessel or to the transport pipe.

Abstract: A method for emptying a furnace floor from smelt in a black liquor recovery boiler when the black liquor recovery boiler is being shut down. The emptying can be started while smelt is still flowing in smelt spouts. The floor is emptied by sucking smelt from the furnace with a smelt eductor. A device for removing smelt and wash water from a furnace of a black liquor recovery boiler by means of suction. Negative pressure is generated in the device by conducting pressurized gas into a suction pipe of an eductor so that preheated pressurized gas is discharged in the discharge direction of smelt and wash water.

Abstract: It is described a process for thermal hydrolysis and team explosion of biomass, said method comprising the steps of: (i) leading the biomass approximately continuous to a first preheating step and preheat the biomass, (ii) leading the preheated biomass into at least two reactors sequentially, (iii) heating and pressurising the reactor by addition of steam, (iv) keeping the reactor(s) at a certain temperature and pressure for a certain time, (v) leading the heated and pressurized biomass from the reactor(s) to a first pressure relief tank without any substantial pressure reduction and quickly relief the pressure of the biomass by means of a nozzle, in order to disintegrate the biomass, (vi) leading the biomass from the first pressure relief tank to a second pressure relief tank having a lower pressure than the pressure of the first pressure relief tank, (vii) leading the so treated biomass to a downstream facility for subsequent treatment. The invention also comprises a device for thermal treatment of biomass.

Abstract: Provided is a lignocellulosic biomass saccharification pre-treatment device capable of producing a pretreated material for saccharification. The lignocellulosic biomass saccharification pre-treatment device comprises a separation unit 4 which separates ammonia gas by heating a pretreated material for saccharification obtained from a substrate mixture obtained by mixing lignocellulosic biomass and ammonia water; a first heat recovery unit 25 which recovers heat-of-dissolution generated when ammonia gas is dissolved in water, and the heat supply units 8, 9, 10 which generate heat by using heat-of-dissolution recovered by the frst heat recovery unit 25 and supply the heat to the separation unit 4.

Abstract: A method for heating a chip slurry in a pulping system including an impregnation vessel and a chemical digesting vessel, the method including: impregnating chips in the impregnation vessel with a liquor; transporting the chips from the impregnation vessel to an upper elevation of the digester vessel; extracting liquor from a lower elevation of the digester vessel, wherein the extracted liquor has a temperature substantially higher than a temperature of the chips being transported to the upper elevation of the digester vessel, and adding extracted liquor from the lower elevation of the digester vessel to the chips being transported from the impregnation vessel to the digester vessel.

Abstract: A method of treating and utilizing liquid flows at a chemical pulp mill including stages for: a) chemical pulp is produced in an alkaline cooking process, b) the brown stock generated in the cooking is treated, said treatment comprising washing of the stock and preferably oxygen delignification and subsequent washing of the stock, c) a bleaching process for the brown stock, the bleaching sequence comprising at least one stage using chlorine dioxide and additionally at least one oxidizing bleaching stage and having at least two washing stages for treating the stock with liquids and for producing filtrates, and d) filtrates from stage c) are purified at an effluent treatment plant of the chemical pulp mill, which comprises at least biological treatment, for obtaining purified effluent. The method further includes a stage e), where the purified effluent with a color of 200 mg/l (Pt color) or more and a COD value of over 150 mg/l is used as pulp treatment liquid in stage c).

Abstract: There is provided a process for improving the quality of lignosulfonate at least partly derived form a spent sulfite cooking liquor in at least two steps, comprising: one step in which a lignosulfonate-containing fraction at least partly derived from the spent sulfite cooking liquor is subjected to filtration using a membrane having a cut-off of 40-150 kD (high cut-off) at the pressure, flow rate and temperature of the step and the permeate is recovered; and another step in which a lignosulfonate-containing fraction at least partly derived from the spent sulfite cooking liquor is subjected to filtration using a membrane having a cut-off of 1-20 kD (low cut-off) at the pressure, flow rate and temperature of the step and the retentate is recovered. Products, uses thereof as well as a system are also provided.

Abstract: An apparatus for cleaning and cooling a liquor nozzle, the nozzle including at least a liquor tube for feeding liquor and chemicals into a furnace of a recovery boiler. The apparatus includes an outer casing tube, which defines a space whereto conduits are provided for introducing water and steam to generate an emulsion or a conduit for introducing emulsion generated by the water and steam and the surface of which is provided with openings, such as pores or holes, for discharging the emulsion formed by water and steam through the outer casing.

Abstract: Provided a lignocellulosic biomass saccharification pre-treatment device capable of producing a pretreated material for saccharification. The lignocellulosic biomass saccharification pre-treatment device comprises a separation unit 4 which separates ammonia gas by heating a pretreated material for saccharification obtained from a substrate mixture obtained by mixing lignocellulosic biomass and ammonia water; a first heat recovery unit 25 which recovers heat-of-dissolution generated when ammonia gas is dissolved in water, and the heat supply units 8, 9, 10 which generate heat by using heat-of-dissolution recovered by the first heat recovery unit 25 and supply the heat to the separation unit 4.

Abstract: The invention relates to a method and apparatus for processing the black liquor of a pulp mill to recover the chemicals and energy therein. In the invention, the black liquor is pyrolyzed in a pyrolysis reactor (4), formed gaseous components are lead for utilization, sand is returned to a fluidised-bed boiler, and solid matter is mixed with water, whereby a soda-water solution is returned to the pulping process and solid carbon to the fluidised-bed boiler (1).

Abstract: The invention relates to a method and equipment for treatment of black liquor at a pulp mill in order to recover chemicals and energy contained therein. In the invention, the black liquor is pyrolyzed in a pyrolysis reactor (4), the formed gaseous components are forwarded for utilization and the solids are mixed with water, whereby the formed solids are returned to a lime burning kiln (1) and the sodium-hydroxide-containing liquid is returned to the pulp cooking process.

Abstract: Methods and apparatus for maintaining sulfur concentration in the chemical recovery cycle of a Kraft pulping process. A portion of the recovery boiler ash is dissolved, treated to remove solids, and combined with an acid to provide a solution. The recovery boiler ash may be dissolved directly in the acid. The acid may be effluent from a chlorine dioxide generator. The resulting solution is maintained in a fully dissolved state and subjected to an acid separation step to provide a sodium sulfate enriched phase, which may be used to maintain sulfur concentration in the Kraft pulping process, and a sulfuric acid phase. Chlorine ions can be separated with the sulfuric acid phase. The sulfuric acid phase can be recycled to the chlorine dioxide generator.

Abstract: In a continuous digester system the digester system is greatly simplified by using a single vertical atmospheric vessel, replacing the conventional chip bin, steaming vessel, chip chute, high pressure pumping or sluice feeders, impregnation vessels and top separator. Chips are simply fed to the top of the atmospheric vessel, and a chip level is established in the vessel. Treatment liquids are added to the vessel such that a total liquid volume (Z1+Z2) with a liquid level (LIQ LEV) is established under the chip level (CH LEV). Impregnation stage and subsequent cooking stages are implemented in the atmospheric vessel at successively increasing temperature and depths into the total liquid volume, thus preventing boiling in the stages and preferably reducing steam blow trough of the chip surface in the top of the vessel.

Abstract: The invention proposes an installation (10) in which the impregnation and fractionation of the raw material (MP) are conducted at atmospheric pressure, characterized in that it comprises means (18, 20) for transferring the raw material (MP) successively to a first treatment station (PT1) and a second treatment station (PT2), each comprising means (G1, G2) for temporarily combining, at the first station (PT1), the raw material (MP) with a quantity of a first mixture of organic acids and, at the second station (PT2), for temporarily combining the raw material (MP) with a quantity of a second mixture; and means, after impregnation, for at least partially recovering the quantity of second mixture after impregnation and for recycling at least a portion of the second recovered mixture to form at least partially said first impregnation mixture used at the first station (PT1).

Abstract: The present invention relates to a method in connection with smelt removal form a recovery boiler, whereby the smelt is removed from the boiler via a smelt spout surrounded outside the boiler by a hood and a dispersion medium, preferably steam, is fed into the smelt flow falling from the smelt spout for shattering the smelt flow. An essential characteristic is that at least one wall of the hood is washed with liquid so that the liquid first flows downwards on the outer surface of the hood wall and is led into the interior of the hood via at least one trough-like member arranged on the outer surface of the wall and openings in the wall so that the liquid further flows downwards on the inner surface of the wall. The invention also relates to an arrangement for washing the hood and the feeding device for the dispersion medium.

Abstract: A method for heating a chip slurry in a pulping system including an impregnation vessel and a chemical digesting vessel, the method including: impregnating chips in the impregnation vessel with a liquor; transporting the chips from the impregnation vessel to an upper elevation of the digester vessel; extracting liquor from a lower elevation of the digester vessel, wherein the extracted liquor has a temperature substantially higher than a temperature of the chips being transported to the upper elevation of the digester vessel, and adding extracted liquor from the lower elevation of the digester vessel to the chips being transported from the impregnation vessel to the digester vessel.

Abstract: A method for adding cooking liquor into a vapor phase continuous digester for producing chemical cellulose pulp from cellulose chips including: introducing a slurry of the cellulose chips from a feed system to an inverted top separator in a top vapor phase section of the digester; distributing the slurry of the cellulose chips from the top separator into the vapor phase section of the digester; passing liquor through a conduit included with the drive shaft assembly of the top separator, and introducing the liquor from the conduit into the slurry as the slurry flows through the top separator or is distributed from the separator into the vapor phase section.

Abstract: The method and an arrangement are for improved impregnation of chips in association with the manufacture of chemical cellulose pulp. Un-steamed chips are fed into an impregnation vessel (30) in which a fluid level (LIQ_LEV) is established under the highest level (CH_LEV) of the chips. An improved impregnation arrangement for the chips is obtained by the addition of impregnation fluids (BL1/BL2/BL3) with increasing temperatures at different heights (P1, P2, P3), and by the establishment of a counter-flow zone (Z1) in the uppermost part of the impregnation vessel. The requirement for steaming may in this way be dramatically reduced while at the same time the amount of expelled waste gases may be minimized. A major part of the volatile compounds present in the wood are bound to the impregnation fluid (REC) that is withdrawn.

Abstract: A refiner steam separation system according to the present invention includes a blowline for transporting a mixture of fiber material from a refiner to an inlet of a steam separator. Waste steam is discharged from the separator through a waste steam outlet. Cleaned fiber material is discharged from the separator through an exit, which prevents a substantial portion of the waste steam from passing through the exit. A relay pipe communicates with the exit and a dryer duct, and transports cleaned fiber material therebetween. A resin input communicates with the relay pipe, and supplies resin therein. The resin is mixed with the cleaned fiber material prior to the cleaned fiber material being dried in the dryer duct. The present invention is also directed to a method of reducing VOC emissions generated during refining cellulosic fibrous material.

Abstract: The continuous digester is for producing chemical pulp to a process for operating this digester and to a feedback system for the cooking liquid. By means of implementing cooking zones 1st, 2nd, 3rd, 4th and 5th down through the digester, that have a successively decreasing liquid-to-wood ratio, it is possible to obtain a more uniform alkali profile during the cooking. The alkali is kept high at the beginning by means of a high liquid-to-wood ratio, typically over 6:1, which exceeds conventional liquid-to-wood ratios, which are normally around 3.5-5.0:1.

Abstract: The invention relates to a method and arrangement for alkaline oxygen delignification of cellulose pulp. By adding alkali in the final phase of the oxygen delignification one can ensure that an optimal predetermined end-pH is obtained. This provides advantages in the subsequent bleaching since the bleachability is substantially improved in the form of reduced need for bleaching chemicals.

Abstract: A continuous digester is disclosed for producing chemical cellulose pulp from cellulose chips, comprising: a continuous digester vessel having a lower section filled with the cellulose chips and an upper gas filled section; an inverted separator at least partially in said upper section which introduces chips and liquid into said digester vessel and separates some of the liquid from the chips, wherein said separator includes a drive shaft connected to a conveyor, and a liquid discharge port proximate to the drive shaft and arranged proximate to a chip discharge of the separator.

Abstract: The invention includes a treatment apparatus for treating fibrous cellulosic raw material suitable for use in a paper making plant comprising extracting means for extracting contrary material from the raw material, crushing means for crushing the raw material to remove nodes therefrom and splitting means for splitting the crushed raw material lengthways. A co-rotating twin screw conveyor is used to pulp the crushed material, the conveyor being divided up into a plurality of zones, means for inserting treatment materials into a least one zone and means for controlling the temperature and/or pressure of all of the zones. The black liquor effluent produced in the pulping process is treated in an apparatus comprising an evaporator for concentrating the liquor to 30-70% solids, a processing vessel for treating the concentrated liquor at a temperature of between 300-600° C., and a closed conveyor for transporting the concentrated liquor from the evaporator to the processing vessel in excess of 90° C.

Abstract: The invention relates to a continuous digester for producing chemical pulp, to a process for operating this digester and to a feedback system for the cooking liquid. By means of implementing cooking zones 1st, 2nd, 3rd, 4th and 5th down through the digester, having a successively decreasing liquid-to-wood ratio, it is possible to obtain a more uniform alkali profile during the cooking. The alkali which is totally available is kept high at the beginning by means of a high liquid-to-wood ratio, typically well over 6:1, which well exceeds conventional liquid-to-wood ratios, which are normally around 3.5-5.0:1. In combination with digester liquid from subsequent cooking zones being fed back to the top of the digester, the alkali concentration can be kept low at the beginning of the cooking, typically within 20-35 g/l when cooking softwood. This is achieved with essentially all the alkali, i.e. more than 80%, being added at the beginning of the cooking.

Abstract: A method is disclosed for extracting liquor from a cellulose slurry for a continuous digester comprising the steps of: providing the cellulose slurry of liquor and chips of cellulose fiber material to a separator; extracting a first stream of liquor from the separator; extracting a second stream of liquor from the separator, where the second stream has an effective alkali (EA) concentration greater than the EA concentration of the first steam; outputting the first stream from the separator and outputting the second stream from the separator separately from the second stream, and outputting a condensed slurry from the separator to a digester vessel.

Abstract: A continuous pulp digester having an elongate horizontally aligned pressure vessel through which the wood chips and digesting fluid flow in a forward direction. In a first and second embodiments within the pressure vessel there is an inner container defining an elongate chamber or passageway having a square cross sectional configuration. In a third embodiment the digesting chamber is cylindrical. At locations along the digester, there are several pair of liquid flow inlets and liquid flow outlets which enable filtrate from a pulp washer and a digesting agent to be moved into and across the digesting chamber to flow out the flow outlets. These are recirculated in a net upstream flow pattern toward the outlet end of the digester, and discharged as black liquor at different locations in the digester.

Abstract: A method is disclosed for extracting liquor from a cellulose slurry for a continuous digester comprising the steps of: providing the cellulose slurry of liquor and chips of cellulose fiber material to a separator; extracting a first stream of liquor from the separator; extracting a second stream of liquor from the separator, where the second stream has an effective alkali (EA) concentration greater than the EA concentration of the first steam; outputting the first stream from the separator and outputting the second stream from the separator separately from the second stream, and outputting a condensed slurry from the separator to a digester vessel.

Abstract: In the feeding of a slurry of comminuted cellulosic fibrous material to a digester (continuous or batch) in the production of chemical pulp, one of the tanks used in the feed system (which preferably includes a high pressure feeder) may be eliminated without consequent loss of its function by providing a single tank with the combined functions of controlling the level of liquid in a slurrying conduit which supplies slurry to a slurry pump, and storing and substantially continuously supplying liquid to a make-up liquid pump connected to the digester. The single tank preferably surrounds the slurrying conduit and is substantially concentric, and in liquid communication, with it. A gap of 3-48 inches may be provided between the bottom of the conduit and a connection to the slurry pump. A screen or strainer may be provided in the gap, which is substantially surrounded by the tank.

Abstract: In the feeding of a slurry of comminuted cellulosic fibrous material to a digester (continuous or batch) in the production of chemical pulp, one of the tanks used in the feed system (which preferably includes a high pressure feeder) may be eliminated without consequent loss of its function by providing a single tank with the combined functions of controlling the level of liquid in a slurrying conduit which supplies slurry to a slurry pump, and storing and substantially continuously supplying liquid to a make-up liquid pump connected to the digester. The single tank preferably surrounds the slurrying conduit and is substantially concentric, and in liquid communication, with it. A gap of 3-48 inches may be provided between the bottom of the conduit and a connection to the slurry pump. A screen or strainer may be provided in the gap, which is substantially surrounded by the tank.

Abstract: By the utilization of a jet ejector (such as a thermocompresser) in a cellulose chemical pulp mill, it is possible to effectively increase the utilization of steam. The volume of steam from a flash tank which flashes black liquor from a pulp digester may be increased (e.g. at least about 10%), while the volume and temperature of the liquor discharged from the flash tank are decreased and its concentration increased, by operatively connecting the jet ejector to the steam discharge from a flash tank. The jet ejector is supplied with higher pressure steam from another source which can result in a low pressure or partial vacuum condition in the flash tank. The flash tank may be a single flash tank or one of a series of flash tanks, and an ejector can be associated with at least another flash tank in the series.

Abstract: Method is disclosed for treating wood chips including a heater for preheating the wood chips in the presence of steam, a beater to mechanically process the wood chips into wood fibers, a cyclone for separating the wood fibers from steam and volatile organic substances produced in the beater, a blower line for transporting the wood fibers, steam and volatile organic substances from the beater to the inlet of the cyclone, a drying conduit connected to the lower outlet of the cyclone for carrying wood fibers therefrom, a sluice valve associated with the lower outlet of the cyclone for controlling the removal of the wood fibers from the cyclone, and a processing conduit connected to the upper outlet of the cyclone for the steam and the volatile organic substances whereby the volatile organic substances separated in the cyclone can be separated and heat associated with the steam separated in the cyclone can be recovered.

Abstract: A feed system for a cellulose pulp treating vessel (such as a continuous digester) is not limited by the required L/W ratio of the pump feeding a wood chip slurry to a high pressure transfer device, the feed system may be kept at a low temperature to minimize flashing of liquid into steam, and a return conduit from the treatment vessel to the transfer device high pressure inlet may be eliminated. Some of the liquid is removed from the slurry just before the low pressure inlet to the transfer device, and/or just after the high pressure outlet, to reduce the L/W ratio of the slurry by at least 0.25, e.g. from 3.0:1 to 2.25:1 just before the low pressure inlet, and from, 7.0:1 to 5.0:1 substantially immediately after the high pressure outlet.

Abstract: A continuous pulp digester having an elongate horizontally aligned pressure vessel through which the wood chips and digesting fluid flow in a forward direction. In a first and second embodiments within the pressure vessel there is an inner container defining an elongate chamber or passageway having a square cross sectional configuration. In a third embodiment the digesting chamber is cylindrical. At locations along the digester, there are several pair of liquid flow inlets and liquid flow outlets which enable filtrate from a pulp washer and a digesting agent to be moved into and across the digesting chamber to flow out the flow outlets. These are recirculated in a net upstream flow pattern toward the outlet end of the digester, and discharged as black liquor at different locations in the digester.

Abstract: A method in connection with continuous cooking of chips, comprising impregnation of the chips with impregnation liquid in an impregnation vessel (3) and cooking of the impregnated chips in a digester (4), the impregnation vessel and the digester being connected to each other by means of a transfer circulation, which partly, via a feed line (25), feeds the chips from an outlet end (27) of the impregnation vessel to the top of the digester for separation of free liquid in a separator (28), and partly, via a return line (26), feeds separated liquid from the top of the digester to the outlet end of the impregnation vessel for use as transfer liquid for the impregnated chips, besides which cooking liquid is added to the chips in the top of the digester. According to the invention, as a first part, less than 100%, preferably less than 95% and more preferred less than 90% of the liquid which is separated from the chips in the transfer circulation, is recirculated to be used as transfer liquid.

Abstract: Steam (preferably clean steam) having less noncondensible gases than steam produced by conventional black liquor flashing is produced from hot black liquor from a digester of a pulp mill. A heat exchanger is utilized and the hot black liquor is passed through the heat exchanger in heat exchange contact with an evaporable liquid, preferably clean water. After the water is heated in the heat exchanger it is flashed in at least one flash tank where the heat exchanger is a liquid-to-liquid heat exchanger. The heat exchanger may alternatively include an evaporator (such as a falling film evaporator) in which case the black liquor is passed through an inductor before it enters the evaporator. Alternatively, the heat exchanger may be one or more boilers, such as kettle boilers, in which case the black liquor preferably passes through a cooler after the boilers. Heat energy and turpentine recovery are also maximized.

Abstract: A continuous pulp digester having an elongate horizontally aligned pressure vessel through which the wood chips and digesting fluid flow in a forward direction. In a first and second embodiments within the pressure vessel there is an inner container defining an elongate chamber or passageway having a square cross sectional configuration. In a third embodiment the digesting chamber is cylindrical. At locations along the digester, there are several pair of liquid flow inlets and liquid flow outlets which enable filtrate from a pulp washer and a digesting agent to be moved into and across the digesting chamber to flow out the flow outlets. These are recirculated in a net upstream flow pattern toward the outlet end of the digester, and discharged as black liquor at different locations in the digester.

Abstract: The invention relates to a process system and a method for preliminary treatment of disintegrated cellulose-containing material, preferably wood chips, prior to pulp digestion. The process system and the method according to the invention make use of a process vessel intended to function both as a so-called chip bin and as a pre-impregnation vessel. The characteristics of the invention are that a sloping steaming vessel is arranged downstream of the process vessel for the purpose of separating an excess of pre-impregnation liquid from the pre-impregnated cellulose-containing material, that the sloping steaming vessel is arranged for supplying steaming vapor which preferably has been generated by flashing of extraction liquor from a pulp digester, and that the sloping steaming vessel is connected to a chip chute communicating with a condenser for connection to a system for managing foul-smelling process gases.

Abstract: An alkaline cellulose pulp pulping process treats soap and fiber-containing liquids to separate fibers from the liquids prior to further treatment of the liquids (e.g. by evaporation and combustion, or by cooking to produce tall oil). Black liquor containing soap, and/or washer filtrate containing soap, are fed to one or more soap separating tanks, and then the soap fraction from the top of the tanks is fed to a pressure screen where fiber separation takes place (preferably at a temperature of at least 70.degree. C.). Black liquor may be added to the soap fraction to dilute it, and preferably simultaneously raise its temperature. The pressure screen has a screen surface with holes of 0.4 mm diameter or less, or slots with a width of 0.2 mm or less.

Abstract: A method and arrangement for increasing evaporation capacity in a multi-stage evaporation plant of spent liquor of a pulp mill. The method includes increasing the pressure of vapor discharged from an evaporation stage by a separate booster, and supplying the vapor having increased pressure to the following evaporation stage. In the arrangement the booster (A-E) is provided in a conduit through which vapor is supplied from one evaporation stage onwards for increasing the pressure of the vapor conducted in the conduit.

Abstract: Sodium chloride is removed from pulping chemicals used in a Kraft pulping process by the use of a snake-cage polyelectrolyte ion exchange resin, coupled with removal of sulfide prior to treatment, or treatment of chemicals which are already low in sulfide. In one aspect of the invention, dust is collected from exhaust gases produced in the black liquor recovery cycle and is dissolved in water to produce a solution containing sodium chloride and sodium sulfate. The solution is filtered to yield a solid product and a filtrate solution. The filtrate solution is fed to an ion exchange unit which removes chloride and produces a purified sodium sulfate product. The sodium chloride is removed from the ion exchange resin by water elution, and useful recovered chemicals are recycled to the recovery cycle of the Kraft process.

Abstract: An oxygen delignification method and apparatus in which a charge of heated wood pulp is reacted with oxygen in the presence of a charge of caustic soda in a plurality of reaction stages located between mixing stages in which caustic is mixed with the wood pulp. The use of the plurality of mixing stages reduces peak pH exposure of the wood pulp that would otherwise occur if the charges of caustic and wood pulp were mixed all at once. Moreover, the caustic mixed in such manner replenishes neutralized caustic and ensures that the average pH level is increased above that in conventional oxygen delignification. The increase in average pH level favors an increase in the delignification. Filtrate from a washing stage is introduced into the mixing stages to prevent wood pulp degradation.

Abstract: Apparatus for a pulp and paper mill, and methods of acting on liquid effluents produced in the mill, which minimizes the discharge of polluting gaseous and liquid effluents to the environment. Liquid effluents from the bleach plant are concentrated (e.g. evaporated), incinerated (e.g. gasified), leached, crystallized (e.g. freeze crystallized) then washed, and then fed to the plant chemical recovery loop. White liquor produced from the recovery boiler melt is fully oxidized and used in place of caustic in the bleach plant. Essentially all sulfuric acid, sulfur dioxide, caustic, and chlorine dioxide necessary for the pulp mill is produced from mill liquid effluents and gas waste streams, on site at the pulp mill. Typical bleaching sequences that can be used are DE.sub.op D.sub.n D, or AZE.sub.o PZP.

Abstract: A method of producing oxidized white liquor from white liquor in which sodium sulfide is oxidized to sodium sulfate. In accordance with the method, an oxygen containing gas is contacted with the white liquor at a temperature of at least 110.degree. C. and such that the total pressure of oxygen and water vapor is no less than 9.2 atmospheres during the contacting.

Abstract: A spout for channeling smelt from a boiler through an opening in the walls of the boiler comprises a jacket having an inner wall and an outer wall. The outer wall is spaced a distance away from the inner wall and the jacket has one end insertable into the opening of the wall. The jacket defines a trough for carrying smelt from the boiler. An inlet communicates with the jacket for delivering a water flow to the jacket between the inner wall and the outer wall. An O-shaped tube communicates with the jacket at the inserted end of the jacket for receiving the water flow from between the inner wall and the outer wall of the jacket. An outlet communicates with the O-shaped tube near the inserted end for channeling the water flow from the O-shaped tube and out of the spout. A vacuum is used near the outlet for insuring a proper low pressure drop.

Abstract: A simplified method and apparatus for handling black liquor (or other spent liquor from the pulp industry) includes utilization of a mixing tank directly with a black liquor storage tank. The mixing tank has a side wall defined by a part of the side wall of the black liquor storage tank, and the mixing tank may either be disposed within the volume of the storage tank, or immediately exterior of it. Fly ash from a recovery boiler and make-up chemical are introduced into the mixing tank along with black liquor from evaporators, and the mixed liquid from mixing tank overflows into the interior volume of the black liquor storage tank. From the storage tank the black liquor is sent to a recovery boiler where it is burned. Also, some black liquor from the recovery boiler is recirculated to the storage tank, and introduced into the storage tank remote from the mixing tank.

Abstract: A method for white liquor oxidation in a kraft mill utilizes a two-stage selective oxidation system in which the first stage is operated to remove sulfide while the second stage is operated to oxidize a significant fraction of the remaining oxidizable sulfur compounds to sulfate. The resulting selectively oxidized white liquor products are used as alkali sources for various process steps in the mill. Optionally, white liquor can be oxidized in a single stage to convert a significant fraction of the oxidizable sulfur compounds to sulfate. Methods for controlling the selective oxidation process are disclosed.

Abstract: An apparatus is disclosed for treating lignocellulosic materials, comprising an enzymatic conversion zone adapted to enzymatically convert alcohol to aldehyde and hydrogen peroxide, a delignification zone, a device for transferring an effluent comprising aqueous hydrogen peroxide from the conversion zone to the delignification zone, a chopper for adding chopped lignocellulosic material to the delignification zone, a separator for separating solid delignified material in the delignification zone from a liquid, and a fermenter adapted to grow alcohol oxidase-producing yeast, and means for transferring alcohol oxidase from the fermenter into the conversion zone.