With Additional Chemical Treatment Before Start Of Defibration Patents (Class 162/25)
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Publication number: 20020069981Abstract: A chemical wood pulping process having reduced volatile organic compound emissions includes extracting wood particulates with solvent at a pressure less than 50 psi to reduce naturally-occurring particulate pitch and volatile organic compound content without significant dissolution of lignin and wood cellulosic components. The solvent used is methanol, ethanol, or acetone. This is followed by comingling the extracted wood particulates with a liquor having chemical reactants, not including the solvent used to extract the wood particulates, for solubilizing lignin. Then, allowing the chemical reactants of the liquor to react with lignin contained in the extracted wood particulates under controlled conditions of temperature and pressure for a sufficient time to solubilize and remove lignin. This is followed by producing a wood pulp having individual cellulosic fibers while releasing a reduced amount of VOCs in the wood pulping process.Type: ApplicationFiled: November 6, 2001Publication date: June 13, 2002Applicant: Weyerhaeuser CompanyInventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
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Publication number: 20020069982Abstract: A process for producing paper and absorbent products of increased strength includes extracting wood particulates with a solvent selected from methanol, ethanol, and acetone at a pressure less than 50 psi to reduce the pitch and volatile organic compounds of the particulates without significant dissolution of lignin and cellulosic components. The wood particulates are pulped to produce a pulp with reduced pitch content. A slurry is prepared from the pulp and used to form paper products.Type: ApplicationFiled: November 6, 2001Publication date: June 13, 2002Applicant: Weyerhaeuser CompanyInventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
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Patent number: 6402887Abstract: A method using biological processes in the production of pulp from industrial wood waste is described. The process makes use of various species of white-rot fungi which selectively degrade lignin. The industrial wood waste must be cleaned and hydrated prior to inoculation with the fungus. Paper produced by this process has excellent strength characteristics as compared to both non-treated industrial wood waste and pulp produced from virgin wood chips. Substantial energy savings are also realized when the biopulped industrial wood waste chips are further refined by conventional mechanical pulping procedures. Kraft pulping of wood waste resulted in strength properties comparable to those of virgin wood. Fungal pretreatment subsequently enhanced the resulting kraft pulp properties.Type: GrantFiled: November 30, 1998Date of Patent: June 11, 2002Assignees: Biopulping International, Inc., The United States of America as represented by the Secretary of AgricultureInventors: Masood Akhtar, Gary M. Scott, Aziz Ahmed, Michael J. Lentz, Eric G. Horn
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Publication number: 20020062935Abstract: A paper product having a mass of cellulosic fibers produced from wood, where the fibers have a pitch content reduced by at least about 40% as compared to an expected pitch content based on naturally-occurring levels of pitch in the wood is disclosed.Type: ApplicationFiled: November 6, 2001Publication date: May 30, 2002Applicant: Weyerhaeuser CompanyInventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
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Process for producing a wood pulp having reduced pitch content and process and reduced VOC-emissions
Patent number: 6364999Abstract: Paper and absorbent products having reduced pitch content and enhanced properties, including increased tensile index, tear index, burst index, Scott Bond, smoothness, and stiffness. Further, pulps of the invention, although having slightly reduced brightness, are more responsive to bleach chemicals thereby permitting the use of less chemicals to achieve a specific brightness. The products are produced by a process that includes extracting wood particulates with a solvent for naturally-occurring volatile organic compounds and pitch. The extracted wood particulates are then pulped and formed into paper and absorbent products with enhanced properties. Due to the extraction of volatile organic compounds, the pulping and paperforming stages of the process are substantially free of emissions of volatile organic compounds that occur naturally in wood. Moreover, the extraction of pitch reduces or eliminates pitch fouling of equipment and permits the production of paper products of enhanced qualities.Type: GrantFiled: February 24, 1999Date of Patent: April 2, 2002Assignee: Weyerhaeuser CompanyInventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal -
Patent number: 6344108Abstract: A process for producing fibrous materials for the manufacture of cellulose, paper or wood materials by using at least one dicarboxylic acid dialkyl ester and/or a copolymer of polyester-polyether and/or fatty acid polyol monopolyester, dipolyester, tripolyester and or higher polyester. Fibrous materials with an improved quality and higher yield are thus produced.Type: GrantFiled: August 30, 1999Date of Patent: February 5, 2002Assignee: Stockhausen GmbH & Co. KGInventors: Ingo Von Medvey, Thomas Rajcsanyi, Peter Hänssle, Joachim Werres
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Patent number: 6340408Abstract: A method for the preparation of cellulosic pulp capable of being defibrated (fluffed) for the manufacture of an absorbent material intended to be incorporated as a component in absorbent products. A stock of cellulosic fibres in aqueous suspension is pH-adjusted to 4<pH<8, that at least any water-soluble, non-polymeric aluminium salt is added to the stock, said salt in aqueous solutions at said pH forming at least any hydrocomplex with aluminium of the type Al(OH)nx, where n is a number between 1 and 3, and x is o, + or 2+, that said salt in aqueous solution is caused to act on the cellulosic fibres in said suspension at said pH during a period of time of at least 2 min, and that the fibre pulp thereafter is formed to a web, which is dewatered and dried. The invention also relates to the prepared cellulose pulp as such and to its use in absorbent products.Type: GrantFiled: September 24, 1998Date of Patent: January 22, 2002Assignee: Stora Kopparbergs Bergslags Aktiebolag (Publ)Inventor: Leif Norlander
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Publication number: 20010045264Abstract: A device treats a fiber stock suspension with at least one additive, the fiber stock suspension being used for production of at least one of paper and cardboard. The fiber stock suspension includes a suspension medium and a fiber material. The fiber material has fiber surfaces, the fiber surfaces being moistened by the suspension medium. The device includes a fluffer having an inlet for receiving at least one of the fiber stock suspension and the at least one additive. The fluffer is coupled to the inlet, the fluffer being configured for separating the fiber material and enlarging a specific surface of the fiber surfaces.Type: ApplicationFiled: May 23, 2001Publication date: November 29, 2001Inventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek, Shawn Flanigan, Robert J. Matz
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Publication number: 20010042605Abstract: The present invention is generally directed to a process for recycling paper containing wet strength additives. The process generally includes the step of mechanically fiberizing the paper in order to reduce the paper into substantially discreet fibers. The paper can be fiberized in various devices, including mills and pulverizers. Once the paper has been converted into substantially discreet fibers, the fibers can then be used in forming various paper products, including wipers and tissues. Of particular advantage, it has been discovered that fibers produced according to the process of the present invention produce paper webs having high bulk, high brightness, high porosity, and high opacity.Type: ApplicationFiled: December 17, 1999Publication date: November 22, 2001Inventors: MIKE T. GOULET, ROBERT J. MAKOLIN
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Publication number: 20010020522Abstract: A low energy process for the manufacture of high yield pulp that involves the processing of chemically-treated chips or wood fiber at high stresses or intensity.Type: ApplicationFiled: April 25, 2001Publication date: September 13, 2001Inventors: Alcibiadis Karnis, Cyril Heitner, J. David McDonald, Keith B. Miles, Oleg V. Chagaev, Mustafa I. Stationwala, Thomas C. Browne
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Patent number: 6277240Abstract: In the production of chemical pulp, such as kraft pulp, it is possible to reduce the amount of ancillary equipment, and/or the size of the continuous digester vessel, while achieving enhanced uniformity of treatment by avoiding “hang ups”. Instead of providing vertical counter-current flow of liquid and comminuted cellulosic fibrous material being treated in the lower half of the digester, the counter-current flow may be a cross flow, that is substantially horizontal (e.g. radial) while the flow of the chip column is vertical. Regardless of the configuration of the digester vessel, a single pump may be utilized for all of the recirculations, or only a few pumps for all of the recirculations.Type: GrantFiled: October 2, 1998Date of Patent: August 21, 2001Assignee: Andritz-Ahlstrom Inc.Inventors: Bruno S. Marcoccia, C. Bertil Stromberg, Brian F. Greenwood
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Patent number: 6267841Abstract: A low energy thermomechanical pulping process which employs an enzyme treatment stage between two low energy thermomechanical stages.Type: GrantFiled: February 27, 1995Date of Patent: July 31, 2001Inventor: Steven W. Burton
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Patent number: 6214164Abstract: The invention relates to a process and apparatus for pretreating pulp raw material, to be subsequently prepared in a chemical pulping process, and for preparing cellulose pulp from a fibrous starting material. According to the process the starting material is delignified to yield a chemical cellulose pulp, and the obtained pulp is bleached when desirable. According to the invention the starting material is crushed in cooking liquor prior to delignification in order to open its fiber structure. The apparatus of the invention comprises a frame (21), to which to adjacent first rolls (12; 22, 23) have been fitted, which form a first pair of rolls with the rolls arranged to distance from each other in such a manner that a gap clearance is formed between their outer mantles. The rolls are caused to rotate by a means of power transmission, which causes the raw material to be crushed inside the gap between the rolls where a liquid pocket is formed, from which liquid is absorbed into the fiber material being treated.Type: GrantFiled: August 7, 1998Date of Patent: April 10, 2001Assignee: Sunds Defibrator Woodhandling OyInventor: Pekka Rantala
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Patent number: 5879510Abstract: A chemimechanical pulp for use in the manufacture of paper or paperboard products where a high drainability, bulky pulp is desired. The pulp has a long fiber content of between 60 and 75%, a fine-material content of at most 14%, a shive content of less than 0.5%, is refined to a freeness of 600 ml CSF at the lowest, and has a tensile index of at least 10 kNm/kg. A method for producing such a pulp comprises: a) impregnating chips with a lignin softening chemical; b) preheating the chips; c) refining the chips to papermaking pulp; wherein the chips are impregnated and heated over a total time period of at most 4 minutes; a) using a hot impregnating liquid having a temperature of at least 130.degree. C.Type: GrantFiled: December 13, 1996Date of Patent: March 9, 1999Assignee: SCA Hygiene Products ABInventors: Tjell-Ake Hagglund, Ingela Ekebro, Hans Hoglund, Roland Back
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Patent number: 5718802Abstract: Novel fiber bundles may be produced as a by-product of sugar cane or other plants. These fiber bundles may be spun into a yarn, or formed into a non-woven mat. The non-woven mat is useful, for example, as a biodegradable geotextile for inhibiting erosion while allowing plants to become established on roadsides, or in other applications. Sugar cane fiber bundles were extracted from the Tilby-separated rind of cane stalks using alkaline treatments. The amount of lignin removed was dependent on alkaline concentration and time, pressure of treatment, and steam explosion conditions if employed. Agitation and vigorous boiling affected the lignin removal. Alkali concentration significantly affected the mechanical properties of the fiber bundles. Tenacity, toughness, and linear density were higher for the fibers extracted at lower alkali concentration. Bending rigidity and hysteresis of these fibers were also higher. This process is also expected to work with other plant stalks having a high lignin content.Type: GrantFiled: January 9, 1995Date of Patent: February 17, 1998Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical CollegeInventors: John R. Collier, Billie J. Collier
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Patent number: 5628830Abstract: A method of producing sugars and converting the sugars to ethanol in which particulate biomass resulting from hydrolysis of the hemicellulosic content of the biomass is subjected to enzymatic hydrolysis of the cellulosic content to glucose and fermentation of the glucose to ethanol. The particulate biomass resulting from hydrolysis of the hemicellulosic content of the feed stock is reduced to very fine particle size before enzymatic hydrolysis. The hydrolysis of cellulose and the fermentation of the resulting glucose may be carried out separately or they may be carried out simultaneously. The pentoses and hexoses resulting from hydrolysis of the hemicellulose may be subjected to fermentation separately to produce ethanol or they may be fermented simultaneously with the fermentation of the glucose derived from the cellulose.Type: GrantFiled: June 6, 1995Date of Patent: May 13, 1997Assignee: The Regents of the University of CaliforniaInventor: David L. Brink
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Patent number: 5622597Abstract: A process for deinking recycled paper using a pressurized deinking module to separate ink from paper pulp stock. The addition of salts of imidazolinium based compounds with alkyl, alkenyl and amidoethyl side chains to the pulp slurry at the beginning of the pressurized deinking module cycle removes ink more effectively and results in a brighter recycled paper and an increase in yield of final paper stock.Type: GrantFiled: January 24, 1995Date of Patent: April 22, 1997Assignee: Callaway CorporationInventors: John W. Callen, Alicia Anderson-Norris
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Patent number: 5607546Abstract: An absorbent, chemithermomechanical pulp produced from lignocellulosic material with a wood yield above 88%, a low resin content <0.15%, a long fiber content above 70%, a short fiber content below 10% and a shive content below 3%. The method for producing the pulp comprises the steps of impregnating, preheating, defibering, and washing the material. The impregnation and preheating of the chips are effected in one and the same vessel over a combined time period of at most 2 minutes, particularly at most 1 minute, preferably at most 0.5 minutes; using a warm impregnating liquid having a temperature of at least 100.degree. C., suitably at least 130.degree. C. and preferably having essentially the same temperature as in the preheating process; and preheating the chips at a temperature of 150.degree.-175.degree. C., preferably 160.degree.-170.degree. C.Type: GrantFiled: November 7, 1994Date of Patent: March 4, 1997Assignee: Molnlycke ABInventors: Hans H oglund, Roland B ack, Ove Danielsson, Bo Falk
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Patent number: 5536325Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.Type: GrantFiled: June 6, 1994Date of Patent: July 16, 1996Inventor: David L. Brink
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Patent number: 5366558Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.Type: GrantFiled: June 8, 1993Date of Patent: November 22, 1994Inventor: David L. Brink
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Patent number: 5338405Abstract: In a process for manufacturing chemo-mechanical and/or chemothermal-mechanical wood pulps, raw materials containing lignocellulose, such as wood shavings, wood chips, pre-ground wood or sawdust, are first impregnated with an aqueous alcoholic SO.sub.2 solution and then heated to a temperature between 50.degree. and 170.degree. C. for a period of 1 to 300 minutes. The wood shavings are then ground to the desired degree of fineness in a defibrinating device. The process makes it possible to achieve up to 50% reduction in grinding energy in comparison with known chemothermal-mechanical processes.Type: GrantFiled: May 18, 1992Date of Patent: August 16, 1994Assignee: Stora Feldmuhle AktiengesellschaftInventors: Rudolf Patt, Georg Rachor
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Patent number: 5338402Abstract: A process for preparing chemithermomechanical pulp comprising subjecting a lignocellulosic substance from which said pulp is to be formed to the simultaneous action of a sulfite and a reducing agent that is more electronegative than the sulfite ion during a nondestructive cooking operation at a temperature of about 100.degree. C. or above under saturated steam pressure; said simultaneous action taking place at an initial pH of between 7 and 12.5.Type: GrantFiled: October 6, 1992Date of Patent: August 16, 1994Assignee: Societe AtochemInventors: Michel Devic, Robert Angelier
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Patent number: 5314583Abstract: A process for the comminution, in particular defibrillation, and reaction of fibrous materials having a high dry solids content with the addition of a circulating medium, preferably a carrier gas and/or reaction agent, as well as optionally of chemicals. The invention is mainly characterized in that the circulating medium is recycled after leaving the comminuting device, by changing its temperature, and is then recycled to the comminuting device. Another embodiment of the invention is characterized in that the fibrous materials and liquid reaction agent are separated from the carrier gas and reaction agent vapors, which are then recycled back to comminuting device. A plant for carrying out this process is mainly characterized in that the comminuting device and route for recycling and treatment of the circulating medium form a closed system.Type: GrantFiled: August 16, 1990Date of Patent: May 24, 1994Assignee: Maschinenfabrik Andritz ActiengesellschaftInventor: Johannes Kappel
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Patent number: 5267655Abstract: Method and apparatus for treating a gas containing aqueous fiber suspension in a fiber line process of a pulp mill including at least one of pulp screening, washing and bleaching includes (a) transferring the gas containing fiber suspension at a consistency to a treatment station; (b) treating said fiber suspension at the same level by removing a portion of the water from the fiber suspension so as to generate aqueous filtrate and treated fiber suspension having a relatively higher consistency; (c) simultaneously pumping and degassing the filtrate at the same level; and (d) pumping the treated fiber suspension having the relatively higher consistency away from the treatment station at the same level by imparting to the treated fiber suspension sufficient shear force so as to render the fiber suspension pumpable.Type: GrantFiled: July 29, 1991Date of Patent: December 7, 1993Assignee: A. Ahlstrom CorporationInventors: Jukka Heino, Kaj Henricson, Pasi Immonen, Raimo Kohonen, Erikki Savolainen, Pentti Vikio
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Patent number: 5227021Abstract: A method of defiberizing fibrous cellulosic material bound by chemical bonds and physical force comprising treating the fibrous cellulosic material in a treatment apparatus so as to loosen the chemical bonds between the fibers but to leave the bonds caused by physical force essentiall undisburbed to generate treated fiber accumulations and removing a stream of the treated fiber accumulations from said treatment apparatus and defiberting the treated fiber accumulations by subjecting the material to shear forces in the stream, the shear forces being of sufficient strenth to substantiallyl break the physical forces keeping the fibers together and to separate the fibers.Type: GrantFiled: April 21, 1992Date of Patent: July 13, 1993Assignees: A. Ahlstrom Corporation, Wisaforest Oy AbInventors: Lasse Hernesniemi, Pikka Olavi, Ronkonharju
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Patent number: 5221357Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH, retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.Type: GrantFiled: March 28, 1991Date of Patent: June 22, 1993Inventor: David L. Brink
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Patent number: 5164042Abstract: In a method of producing high-yield pulp from pulp chip material containing lignocellulose the material is treated with steam in a steam treating station (1) for driving air out of the material and heating the latter. Heat treated material is mixed in a mixing station (8) with a liquid containing chemicals. The mixture of steam treated material and said liquid is transferred from the mixing station to an impregnation station (25) for impregnating the material by means of said chemicals. Impregnated material is supplied to a refining station (36) for refining the material. According to the invention the steam treated material is mixed with said liquid in proportions, such that the created mixture of material and liquid leaving the mixing station (8) assumes a flowing pumpable consistency. Further, said flowing mixture is pumped from the mixing station (8) to the impregnation station (25).Type: GrantFiled: October 29, 1991Date of Patent: November 17, 1992Assignee: Celleco ABInventors: Hans Larsen, Leif Klinga
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Patent number: 5129987Abstract: A paper pulp refining and bleaching process wherein the pulp is treated in one or more refiners with a sodium hydrosulfite bleach liquor in the presence of a strong alkali such as NaOH, whereby the bleaching solution has an alkaline pH, preferably 10 to 12, and the pulp is discharged from the refiner at a pH of from about 5 to 6. The bleaching produces a brightness gain of at least 8 to 13 ISO points in the refiners. The process is preferably carried out by passing the pulp successively through a primary refiner at elevated pressure, a secondary refiner at atmospheric pressure and a bleaching tower, an alkaline hydrosulfite solution being fed to each.Type: GrantFiled: April 9, 1990Date of Patent: July 14, 1992Assignee: Morton Thiokol, Inc.Inventors: Thomas Joachimides, Stephen H. Levis, Bert A. Edstrom, Hans B. S. Moldenius
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Patent number: 4983256Abstract: In the method for the manufacture of a paper pulp for currency use from a stock comprising textile fibers, the operations of boiling, bleaching, chopping, breaking, cutting and washing of the textile fibers are performed in at least one treatment machine (10, 40) of the type having two co-rotating screws, in a plurality of phases taking place successively and continuously. The operations include a phase of feeding and mixing the stock with water, at least oen compression phase, at least one phase of shearing of the textile fibers, at least one phase of treatment of introduction of boiling and bleaching reagents, at least one phase of washing of the bleached pulp by introduction of washing water, and a phase of transferring and evacuating the bleached and washed pulp.Type: GrantFiled: April 6, 1989Date of Patent: January 8, 1991Assignees: Clextral, Centre Technique de l'Industries des Papiers Cartons et Cellulose, Banque de FraneInventors: Ph. Combette, Robar Angelier, Christian Vieu
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Patent number: 4968385Abstract: A method of preparing a pulp for digestion in a continuous process from a fiber-containing cellulose material is described.Type: GrantFiled: May 25, 1989Date of Patent: November 6, 1990Assignee: Kamyr ABInventors: Julio Amador, Eurico de Faria Amaro, Hans T. Haukerud, Ake Backlund
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Patent number: 4966651Abstract: An improved paper for printing and other uses can be made from a paper pulp that contains pulp derived from hardwoods if the pulp is refined in a refiner that has at least one abrasive surface disk. The pulp can be refined to give a vessel picks count of 2/cm.sup.2 or less and have a Freeness of less than that which can be achieved using a refiner having conventional barred disks.Type: GrantFiled: January 12, 1989Date of Patent: October 30, 1990Assignee: P.H. Glatfelter CompanyInventors: Robert A. Olson, Lewin R. Lutz, III
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Patent number: 4941943Abstract: The invention relates to a method and an equipment for preparing NaCMC, in which (a) cellulose is slushed in the reaction medium until a consistency of c. 5-15%, preferably 5-10%, (b) the fibre suspension obtained in step (a) is thickened to a consistency of c. 20-35% and (c) the pulp containing reaction medium obtained in the second step is homogenized by means of a screw conveyor having a screw pitch which decreases from an inlet opening thereof towards an outlet opening thereof, in order to increase the reactivity, whereby a mercerization activating the cellulose is carried out after step (b) and/or (c), and the cellulose thus pretreated is etherified in a manner known per se.Type: GrantFiled: January 27, 1988Date of Patent: July 17, 1990Assignee: Metsa-Serla OyInventors: Kari Edelman, Torsten Lindroos
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Patent number: 4812206Abstract: A process for bleaching a lignocellulosic matter in the form of a mechanical, thermomechanical, chemicomechanical or chemicothermomechanical papermaking pulp, or of wood chips while being converted into one of these pulp types by processing in a machine consisting essentially of two interpenetrating spiral surfaces wound around parallel shafts driven in synchronous rotation in the same direction inside a barrel which encloses them, and determining between upstream and downstream in the direction of forward travel of the matter a series of zones for drawing and braking the matter, which comprises combining a bleaching treatment using a reducing agent and a bleaching treatment using an oxidizing agent, characterized in that, after pretreatment using at least one metal-complexing or sequestering agent, the lignocellulosic matter undergoes a washing operation with an efficiency greater than 96% before undergoing in succession a bleaching treatment using a reducing agent at a pH of between about 8 and 12, a washinType: GrantFiled: September 22, 1987Date of Patent: March 14, 1989Assignee: AtochemInventors: Michel Devic, Robert Angelier
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Patent number: 4787959Abstract: A process of preparing new chemical paper pulps wherein a first cooking stage is effected in the presence of sodium hydroxide and advantageously adjuvants, after which an intermediate grinding is effected and followed by a second cooking stage characterized in that the second cooking stage is performed in the presence of a peroxide alkaline solution containing a peroxide stabilizing agent.Type: GrantFiled: November 18, 1987Date of Patent: November 29, 1988Assignee: AtochemInventors: Dominique Lachenal, Christian de Choudens, Pierre Monzie
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Patent number: 4767499Abstract: A method for the production of fiber pulp from lignocellulosic material containing at least 70% spruce or spruce-like material. The method comprises the steps of lignin softening and defibration/refining, the step of lignin softening being performed prior to the step of defibration/refining and comprising impregnating the starting material with a dilute aqueous solution of a lignin softening agent, namely a solution of sulfurous acid, metal bisulfite salts and/or metal sulfite salts in an amount sufficient to provide a defibrated/refined pulp containing an absorbed and bonded amount of sulfonate groups within the range of from 0.06 to 0.75 wt.-%, calculated as Na.sub.2 SO.sub.3 and based on the dry pulp weight. The absorbed and bonded amount of sulfonate groups is balanced to the composition of the starting material and the temperature-pressure conditions in the defibration step to provide a pulp of maximum tensile strength such as to represent a point within the polygon ABGH in FIG. 1.Type: GrantFiled: August 13, 1987Date of Patent: August 30, 1988Inventors: Rune G. W. Simonson, Per O. Axelson
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Patent number: 4756799Abstract: In accordance with the invention a chemimechanical pulp is produced from lignocellulosic material, for example wood chips, by subjecting the material to a process in which it is steamed, impregnated with alkali and peroxide, drained, pre-heated, refined and bleached. The material is impregnated in a single stage with a solution containing alkali and peroxide. Subsequent to passing an intermediate drainage and reaction stage, the material is pre-heated to a temperature of from about 50.degree. C., but not above 100.degree. C. The material is then refined in one or two stages. The material can be impregnated by immersing the same in the impregnating solution for a period of up to 20 minutes at a temperature of 15.degree.-60.degree. C., or by compressing the material in a screw press and permitting the compressed material to expand in the impregnating solution.Type: GrantFiled: March 12, 1986Date of Patent: July 12, 1988Assignees: Eka AB, Goran Bengtsson, Rune SimonsonInventors: Goran Bengtsson, Rune Simonson, Roland Agnemo
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Patent number: 4743338Abstract: Air is removed from wood chips, and they are impregnated by treatment liquid, in a process that is an alternative to presteaming and is particularly applicable to environments where presteaming is undesirable, such as in the sulphite treatment of chips during the production of mechanical pulp. The chips are passed in a continuous manner in a generally serpentine, vertically oriented path so that the chips are subjected to a pressure build-up pulsation as they move downwardly, and a pressure release pulsation as they move upwardly. The diameters or cross-sectional areas of the conduit portions defining the upward and downward portions of the path are controlled so that there is about twice the residence time during pressure build-up than there is during pressure release. A high pressure feeder and pump with a fly wheel are operatively connected to one end of the serpentine path, while an in-line drainer and other apparatus are connected to the other end.Type: GrantFiled: May 19, 1986Date of Patent: May 10, 1988Assignee: Kamyr, Inc.Inventor: Robert J. Prough
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Patent number: 4689117Abstract: The brightness of a thermomechanical pulp can be improved if a serial multiple blowdown technique is used and a bleachant is present at an effective concentration throughout the thermomechanical pulping process.Type: GrantFiled: September 4, 1985Date of Patent: August 25, 1987Assignee: Process Evaluation and Development CorporationInventor: Eduardo J. Villavicencio
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Patent number: 4634498Abstract: High strength and high density wood fiberboard is formed by treating the wood fiber source material with a highly alkaline solution, such as sodium hydroxide solution, before interfelting the fibers into a loose mat. The wood source material may be treated after refining the material into fibers, but preferably, the wood source material is treated before fibrillation. Further, wood fiber source material may be partially neutralized before felting without substantial change in the resulting densities and strengths.Type: GrantFiled: December 31, 1984Date of Patent: January 6, 1987Assignee: United States Gypsum CompanyInventors: Dennis L. Hardesty, Timothy D. Hanna, Frank J. Wendt, Kendall D. White, Jr.
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Patent number: 4599138Abstract: A process is provided for pretreating particulate lignocellulosic material to remove heavy metals and resin without any delignification or defibration, which comprises washing particulate lignocellulosic material; compressing the washed material to a solids content of at least 40% to remove absorbed and excess liquid; impregnating the compressed material with an alkaline aqueous solution comprising alkali and at least one of a heavy metal ion complexing agent and a heavy metal ion reducing agent; heating the impregnated material at a temperature within the range from abut 50.degree. to 100.degree. C. for up to approximately 0.75 hour; compressing the pretreated material to a solids content of at least 40%; and separating undiluted liquor squeezed out during the compression, while maintaining conditions during the pretreating such that the pH of the squeezed-out liquor is within the range from about 4 to about 9.Type: GrantFiled: October 30, 1981Date of Patent: July 8, 1986Assignee: Mooch Domsjo AktiebolagInventor: Jonas A. I. Lindahl
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Patent number: 4486267Abstract: A high yield chemithermomechanical (CTMP) process for obtaining high strength hardwood pulps is disclosed wherein hardwood chips are subjected to a two-stage chemical treatment prior to defibration, the first consisting of chip impregnation and reaction with an alkaline liquor followed by a second stage treatment with sulfite and/or bisulfite; in one embodiment peroxide is added to the alkaline liquor to enhance brightness.Type: GrantFiled: November 14, 1983Date of Patent: December 4, 1984Assignee: Mead CorporationInventor: Zenon C. Prusas
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Patent number: 4435249Abstract: Rejects such as knots, shives, slivers, chops, and uncooked and partially cooked wood chips are separated from a pulp slurry and treated to produce a bleachable grade pulp. The rejects are dewatered to a 10-15% consistency, mechanically fiberized, and then delignified at the same 10-15% consistency in the presence of oxygen and alkaline pulping chemicals. The delignification is carried out at 80.degree.-140.degree. C. for 5-120 minutes. The process has low external power requirements, requires no expensive dewatering machinery, and proceeds at a rapid rate to yield a bleachable grade pulp which can be used alone or mixed with other pulp.Type: GrantFiled: November 25, 1981Date of Patent: March 6, 1984Assignees: The Black Clawson Co., Air Products & Chemicals, Inc.Inventors: Larry D. Markham, Andrew C. Martin, Edward F. Elton, Vincent L. Magnotta, Scott A. Wallick
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Patent number: 4406734Abstract: A method and a device for the manufacture of mechanical pulp from lignocellulosic material by forcing the said material into contact with a grindstone (1) which revolves about an axle (2). The material is supplied in bulk, particulate form, preferably as wood chips, a large number of particles simultaneously being retained, compressed and, in the presence of water, forced into contact with one or more grinding areas on the circumferential surface of the grindstone (1). The grindstone (1) is enclosed in a sealed, pressurized housing (5).Type: GrantFiled: October 9, 1980Date of Patent: September 27, 1983Assignee: Sunds Defibrator ABInventor: Hjalmar S. I. Bystedt
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Patent number: 4372810Abstract: A method and a device for the manufacture of mechanical pulp from lignocellulosic material by forcing the said material into contact with a grinding disc (1) which revolves about a central axle (2) perpendicular to the two end faces of the disc.. The material is supplied in bulk, particulate form, preferably as wood chips, a large number of particles simultaneously being retained, compressed and, in the presence of water, forced into contact with one or more grinding areas (5) on one or both end faces of the grinding disc. The disc is enclosed in a sealed, pressurized housing (6).Type: GrantFiled: October 9, 1980Date of Patent: February 8, 1983Assignee: Sunds Defibrator ABInventor: Hjalmar S. I. Bystedt
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Patent number: 4357208Abstract: Lignocellulose material is pretreated with steam, heat, lignin softening chemicals or combinations thereof. The pretreated material is then refined in a disc refiner. Water is added to the material in the refining zone of the disc refiner to form a suspension at concentration of 8-15% at the point of discharge from the gap between the discs of the refiner. Steam development and steam backflow from the gap is reduced.Type: GrantFiled: October 17, 1979Date of Patent: November 2, 1982Assignee: SCA Development AktiebolagInventors: Per V. Peterson, Hans E. Hoglund
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Patent number: 4347101Abstract: A high quality newsprint pulp can be produced from wood or vegetable fibers by thermomechanically pulping one portion of these fibers and thermochemically pulping the remaining portion. After combining these pulps the result is a pulp which has a GE brightness of 55 to 60, an opacity of 93 to 96 percent, and a relatively high tear strength. A pulp useful for making low strength papers can be produced by solely thermomechanically pulping fiber and directly using this pulp to make such products.Type: GrantFiled: November 24, 1980Date of Patent: August 31, 1982Assignee: W. R. Grace & Co.Inventor: Eduardo J. Villavicencio
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Patent number: 4294653Abstract: A process is provided for the manufacture of bleached chemimechanical cellulose pulp in high yield of between 65 and 95% from particulate and preferably washed lignocellulosic material, such as wood chips, featuring the use of spent or waste bleaching liquid, preferably from a lignin-preserving bleaching process, in at least one stage of the process where a cooling and diluting liquid is required, such as during mechanical defibration of the material.Type: GrantFiled: April 11, 1978Date of Patent: October 13, 1981Assignee: Mo och Domsjo AktiebolagInventors: Jonas A. I. Lindahl, Lars G. Rudstrom
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Patent number: 4260452Abstract: Paper pulp is produced by a process in which raw sugar mill bagasse is moist depithed, wet bulk stored in the presence of an inorganic and organic preservative, wet depithed by hydraulic shearing in the presence of an inorganic color remover, pulped, washed, cleaned and dewatered.Type: GrantFiled: November 24, 1978Date of Patent: April 7, 1981Inventors: Horst Kruger, Wilhelm Berndt, Ursula Schwartzkopff, Franz J. Reitter, Theodor Hopner, Hans-Joachim Muhlig
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Patent number: 4248662Abstract: Fibrous material is pre-steamed, impregnated with alkali liquor, refined, and then oxygen pulped at a low consistency (about 3 to 8 percent solids) using an alkali liquor which contains boron compounds. The pulping step of the process is carried out in stages with recycle of liquor to preceding stages after it has been reoxygenated. By recycling a major portion of the pulping liquor, the actual liquor to fibrous material ratio at each stage of the pulping step is maintained at a relatively high level (12/1 to 30/1) while the effective liquor to fibrous material ratio for the overall process is much lower (4/1 to 8/1). This results in a bright pulp of acceptable strength as well as a high solids content spent liquor which is economically recoverable.Type: GrantFiled: January 22, 1979Date of Patent: February 3, 1981Assignee: The Black Clawson CompanyInventor: Scott A. Wallick
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Patent number: 4230524Abstract: Knots separated from sulphite cellulose produced by a sulphite cellulose cooking process are converted to unbleached sulphite cellulose by first separating and defibrating the sulphite knots and then treating the defibrated sulphite knots with oxygen under pressure in an alkaline milieu at an elevated temperature. The resultant cellulose may be bleached by itself, or mixed with sulphite cellulose produced from knot-free cellulose pulp for bleaching therewith.Type: GrantFiled: June 28, 1979Date of Patent: October 28, 1980Assignee: Borregaard A/SInventor: Ketil Hasvold