With Additional Chemical Treatment Before Start Of Defibration Patents (Class 162/25)
  • Publication number: 20020069981
    Abstract: A chemical wood pulping process having reduced volatile organic compound emissions includes extracting wood particulates with solvent at a pressure less than 50 psi to reduce naturally-occurring particulate pitch and volatile organic compound content without significant dissolution of lignin and wood cellulosic components. The solvent used is methanol, ethanol, or acetone. This is followed by comingling the extracted wood particulates with a liquor having chemical reactants, not including the solvent used to extract the wood particulates, for solubilizing lignin. Then, allowing the chemical reactants of the liquor to react with lignin contained in the extracted wood particulates under controlled conditions of temperature and pressure for a sufficient time to solubilize and remove lignin. This is followed by producing a wood pulp having individual cellulosic fibers while releasing a reduced amount of VOCs in the wood pulping process.
    Type: Application
    Filed: November 6, 2001
    Publication date: June 13, 2002
    Applicant: Weyerhaeuser Company
    Inventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
  • Publication number: 20020069982
    Abstract: A process for producing paper and absorbent products of increased strength includes extracting wood particulates with a solvent selected from methanol, ethanol, and acetone at a pressure less than 50 psi to reduce the pitch and volatile organic compounds of the particulates without significant dissolution of lignin and cellulosic components. The wood particulates are pulped to produce a pulp with reduced pitch content. A slurry is prepared from the pulp and used to form paper products.
    Type: Application
    Filed: November 6, 2001
    Publication date: June 13, 2002
    Applicant: Weyerhaeuser Company
    Inventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
  • Patent number: 6402887
    Abstract: A method using biological processes in the production of pulp from industrial wood waste is described. The process makes use of various species of white-rot fungi which selectively degrade lignin. The industrial wood waste must be cleaned and hydrated prior to inoculation with the fungus. Paper produced by this process has excellent strength characteristics as compared to both non-treated industrial wood waste and pulp produced from virgin wood chips. Substantial energy savings are also realized when the biopulped industrial wood waste chips are further refined by conventional mechanical pulping procedures. Kraft pulping of wood waste resulted in strength properties comparable to those of virgin wood. Fungal pretreatment subsequently enhanced the resulting kraft pulp properties.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: June 11, 2002
    Assignees: Biopulping International, Inc., The United States of America as represented by the Secretary of Agriculture
    Inventors: Masood Akhtar, Gary M. Scott, Aziz Ahmed, Michael J. Lentz, Eric G. Horn
  • Publication number: 20020062935
    Abstract: A paper product having a mass of cellulosic fibers produced from wood, where the fibers have a pitch content reduced by at least about 40% as compared to an expected pitch content based on naturally-occurring levels of pitch in the wood is disclosed.
    Type: Application
    Filed: November 6, 2001
    Publication date: May 30, 2002
    Applicant: Weyerhaeuser Company
    Inventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
  • Patent number: 6364999
    Abstract: Paper and absorbent products having reduced pitch content and enhanced properties, including increased tensile index, tear index, burst index, Scott Bond, smoothness, and stiffness. Further, pulps of the invention, although having slightly reduced brightness, are more responsive to bleach chemicals thereby permitting the use of less chemicals to achieve a specific brightness. The products are produced by a process that includes extracting wood particulates with a solvent for naturally-occurring volatile organic compounds and pitch. The extracted wood particulates are then pulped and formed into paper and absorbent products with enhanced properties. Due to the extraction of volatile organic compounds, the pulping and paperforming stages of the process are substantially free of emissions of volatile organic compounds that occur naturally in wood. Moreover, the extraction of pitch reduces or eliminates pitch fouling of equipment and permits the production of paper products of enhanced qualities.
    Type: Grant
    Filed: February 24, 1999
    Date of Patent: April 2, 2002
    Assignee: Weyerhaeuser Company
    Inventors: Jerry R. Speaks, Roger O. Campbell, Michael A. Veal
  • Patent number: 6344108
    Abstract: A process for producing fibrous materials for the manufacture of cellulose, paper or wood materials by using at least one dicarboxylic acid dialkyl ester and/or a copolymer of polyester-polyether and/or fatty acid polyol monopolyester, dipolyester, tripolyester and or higher polyester. Fibrous materials with an improved quality and higher yield are thus produced.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: February 5, 2002
    Assignee: Stockhausen GmbH & Co. KG
    Inventors: Ingo Von Medvey, Thomas Rajcsanyi, Peter Hänssle, Joachim Werres
  • Patent number: 6340408
    Abstract: A method for the preparation of cellulosic pulp capable of being defibrated (fluffed) for the manufacture of an absorbent material intended to be incorporated as a component in absorbent products. A stock of cellulosic fibres in aqueous suspension is pH-adjusted to 4<pH<8, that at least any water-soluble, non-polymeric aluminium salt is added to the stock, said salt in aqueous solutions at said pH forming at least any hydrocomplex with aluminium of the type Al(OH)nx, where n is a number between 1 and 3, and x is o, + or 2+, that said salt in aqueous solution is caused to act on the cellulosic fibres in said suspension at said pH during a period of time of at least 2 min, and that the fibre pulp thereafter is formed to a web, which is dewatered and dried. The invention also relates to the prepared cellulose pulp as such and to its use in absorbent products.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: January 22, 2002
    Assignee: Stora Kopparbergs Bergslags Aktiebolag (Publ)
    Inventor: Leif Norlander
  • Publication number: 20010045264
    Abstract: A device treats a fiber stock suspension with at least one additive, the fiber stock suspension being used for production of at least one of paper and cardboard. The fiber stock suspension includes a suspension medium and a fiber material. The fiber material has fiber surfaces, the fiber surfaces being moistened by the suspension medium. The device includes a fluffer having an inlet for receiving at least one of the fiber stock suspension and the at least one additive. The fluffer is coupled to the inlet, the fluffer being configured for separating the fiber material and enlarging a specific surface of the fiber surfaces.
    Type: Application
    Filed: May 23, 2001
    Publication date: November 29, 2001
    Inventors: Jorg Rheims, Klaus Doelle, Oliver Heise, Werner Witek, Shawn Flanigan, Robert J. Matz
  • Publication number: 20010042605
    Abstract: The present invention is generally directed to a process for recycling paper containing wet strength additives. The process generally includes the step of mechanically fiberizing the paper in order to reduce the paper into substantially discreet fibers. The paper can be fiberized in various devices, including mills and pulverizers. Once the paper has been converted into substantially discreet fibers, the fibers can then be used in forming various paper products, including wipers and tissues. Of particular advantage, it has been discovered that fibers produced according to the process of the present invention produce paper webs having high bulk, high brightness, high porosity, and high opacity.
    Type: Application
    Filed: December 17, 1999
    Publication date: November 22, 2001
    Inventors: MIKE T. GOULET, ROBERT J. MAKOLIN
  • Publication number: 20010020522
    Abstract: A low energy process for the manufacture of high yield pulp that involves the processing of chemically-treated chips or wood fiber at high stresses or intensity.
    Type: Application
    Filed: April 25, 2001
    Publication date: September 13, 2001
    Inventors: Alcibiadis Karnis, Cyril Heitner, J. David McDonald, Keith B. Miles, Oleg V. Chagaev, Mustafa I. Stationwala, Thomas C. Browne
  • Patent number: 6277240
    Abstract: In the production of chemical pulp, such as kraft pulp, it is possible to reduce the amount of ancillary equipment, and/or the size of the continuous digester vessel, while achieving enhanced uniformity of treatment by avoiding “hang ups”. Instead of providing vertical counter-current flow of liquid and comminuted cellulosic fibrous material being treated in the lower half of the digester, the counter-current flow may be a cross flow, that is substantially horizontal (e.g. radial) while the flow of the chip column is vertical. Regardless of the configuration of the digester vessel, a single pump may be utilized for all of the recirculations, or only a few pumps for all of the recirculations.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: August 21, 2001
    Assignee: Andritz-Ahlstrom Inc.
    Inventors: Bruno S. Marcoccia, C. Bertil Stromberg, Brian F. Greenwood
  • Patent number: 6267841
    Abstract: A low energy thermomechanical pulping process which employs an enzyme treatment stage between two low energy thermomechanical stages.
    Type: Grant
    Filed: February 27, 1995
    Date of Patent: July 31, 2001
    Inventor: Steven W. Burton
  • Patent number: 6214164
    Abstract: The invention relates to a process and apparatus for pretreating pulp raw material, to be subsequently prepared in a chemical pulping process, and for preparing cellulose pulp from a fibrous starting material. According to the process the starting material is delignified to yield a chemical cellulose pulp, and the obtained pulp is bleached when desirable. According to the invention the starting material is crushed in cooking liquor prior to delignification in order to open its fiber structure. The apparatus of the invention comprises a frame (21), to which to adjacent first rolls (12; 22, 23) have been fitted, which form a first pair of rolls with the rolls arranged to distance from each other in such a manner that a gap clearance is formed between their outer mantles. The rolls are caused to rotate by a means of power transmission, which causes the raw material to be crushed inside the gap between the rolls where a liquid pocket is formed, from which liquid is absorbed into the fiber material being treated.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: April 10, 2001
    Assignee: Sunds Defibrator Woodhandling Oy
    Inventor: Pekka Rantala
  • Patent number: 5879510
    Abstract: A chemimechanical pulp for use in the manufacture of paper or paperboard products where a high drainability, bulky pulp is desired. The pulp has a long fiber content of between 60 and 75%, a fine-material content of at most 14%, a shive content of less than 0.5%, is refined to a freeness of 600 ml CSF at the lowest, and has a tensile index of at least 10 kNm/kg. A method for producing such a pulp comprises: a) impregnating chips with a lignin softening chemical; b) preheating the chips; c) refining the chips to papermaking pulp; wherein the chips are impregnated and heated over a total time period of at most 4 minutes; a) using a hot impregnating liquid having a temperature of at least 130.degree. C.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: March 9, 1999
    Assignee: SCA Hygiene Products AB
    Inventors: Tjell-Ake Hagglund, Ingela Ekebro, Hans Hoglund, Roland Back
  • Patent number: 5718802
    Abstract: Novel fiber bundles may be produced as a by-product of sugar cane or other plants. These fiber bundles may be spun into a yarn, or formed into a non-woven mat. The non-woven mat is useful, for example, as a biodegradable geotextile for inhibiting erosion while allowing plants to become established on roadsides, or in other applications. Sugar cane fiber bundles were extracted from the Tilby-separated rind of cane stalks using alkaline treatments. The amount of lignin removed was dependent on alkaline concentration and time, pressure of treatment, and steam explosion conditions if employed. Agitation and vigorous boiling affected the lignin removal. Alkali concentration significantly affected the mechanical properties of the fiber bundles. Tenacity, toughness, and linear density were higher for the fibers extracted at lower alkali concentration. Bending rigidity and hysteresis of these fibers were also higher. This process is also expected to work with other plant stalks having a high lignin content.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: February 17, 1998
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventors: John R. Collier, Billie J. Collier
  • Patent number: 5628830
    Abstract: A method of producing sugars and converting the sugars to ethanol in which particulate biomass resulting from hydrolysis of the hemicellulosic content of the biomass is subjected to enzymatic hydrolysis of the cellulosic content to glucose and fermentation of the glucose to ethanol. The particulate biomass resulting from hydrolysis of the hemicellulosic content of the feed stock is reduced to very fine particle size before enzymatic hydrolysis. The hydrolysis of cellulose and the fermentation of the resulting glucose may be carried out separately or they may be carried out simultaneously. The pentoses and hexoses resulting from hydrolysis of the hemicellulose may be subjected to fermentation separately to produce ethanol or they may be fermented simultaneously with the fermentation of the glucose derived from the cellulose.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 13, 1997
    Assignee: The Regents of the University of California
    Inventor: David L. Brink
  • Patent number: 5622597
    Abstract: A process for deinking recycled paper using a pressurized deinking module to separate ink from paper pulp stock. The addition of salts of imidazolinium based compounds with alkyl, alkenyl and amidoethyl side chains to the pulp slurry at the beginning of the pressurized deinking module cycle removes ink more effectively and results in a brighter recycled paper and an increase in yield of final paper stock.
    Type: Grant
    Filed: January 24, 1995
    Date of Patent: April 22, 1997
    Assignee: Callaway Corporation
    Inventors: John W. Callen, Alicia Anderson-Norris
  • Patent number: 5607546
    Abstract: An absorbent, chemithermomechanical pulp produced from lignocellulosic material with a wood yield above 88%, a low resin content <0.15%, a long fiber content above 70%, a short fiber content below 10% and a shive content below 3%. The method for producing the pulp comprises the steps of impregnating, preheating, defibering, and washing the material. The impregnation and preheating of the chips are effected in one and the same vessel over a combined time period of at most 2 minutes, particularly at most 1 minute, preferably at most 0.5 minutes; using a warm impregnating liquid having a temperature of at least 100.degree. C., suitably at least 130.degree. C. and preferably having essentially the same temperature as in the preheating process; and preheating the chips at a temperature of 150.degree.-175.degree. C., preferably 160.degree.-170.degree. C.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: March 4, 1997
    Assignee: Molnlycke AB
    Inventors: Hans H oglund, Roland B ack, Ove Danielsson, Bo Falk
  • Patent number: 5536325
    Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: July 16, 1996
    Inventor: David L. Brink
  • Patent number: 5366558
    Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: November 22, 1994
    Inventor: David L. Brink
  • Patent number: 5338405
    Abstract: In a process for manufacturing chemo-mechanical and/or chemothermal-mechanical wood pulps, raw materials containing lignocellulose, such as wood shavings, wood chips, pre-ground wood or sawdust, are first impregnated with an aqueous alcoholic SO.sub.2 solution and then heated to a temperature between 50.degree. and 170.degree. C. for a period of 1 to 300 minutes. The wood shavings are then ground to the desired degree of fineness in a defibrinating device. The process makes it possible to achieve up to 50% reduction in grinding energy in comparison with known chemothermal-mechanical processes.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: August 16, 1994
    Assignee: Stora Feldmuhle Aktiengesellschaft
    Inventors: Rudolf Patt, Georg Rachor
  • Patent number: 5338402
    Abstract: A process for preparing chemithermomechanical pulp comprising subjecting a lignocellulosic substance from which said pulp is to be formed to the simultaneous action of a sulfite and a reducing agent that is more electronegative than the sulfite ion during a nondestructive cooking operation at a temperature of about 100.degree. C. or above under saturated steam pressure; said simultaneous action taking place at an initial pH of between 7 and 12.5.
    Type: Grant
    Filed: October 6, 1992
    Date of Patent: August 16, 1994
    Assignee: Societe Atochem
    Inventors: Michel Devic, Robert Angelier
  • Patent number: 5314583
    Abstract: A process for the comminution, in particular defibrillation, and reaction of fibrous materials having a high dry solids content with the addition of a circulating medium, preferably a carrier gas and/or reaction agent, as well as optionally of chemicals. The invention is mainly characterized in that the circulating medium is recycled after leaving the comminuting device, by changing its temperature, and is then recycled to the comminuting device. Another embodiment of the invention is characterized in that the fibrous materials and liquid reaction agent are separated from the carrier gas and reaction agent vapors, which are then recycled back to comminuting device. A plant for carrying out this process is mainly characterized in that the comminuting device and route for recycling and treatment of the circulating medium form a closed system.
    Type: Grant
    Filed: August 16, 1990
    Date of Patent: May 24, 1994
    Assignee: Maschinenfabrik Andritz Actiengesellschaft
    Inventor: Johannes Kappel
  • Patent number: 5267655
    Abstract: Method and apparatus for treating a gas containing aqueous fiber suspension in a fiber line process of a pulp mill including at least one of pulp screening, washing and bleaching includes (a) transferring the gas containing fiber suspension at a consistency to a treatment station; (b) treating said fiber suspension at the same level by removing a portion of the water from the fiber suspension so as to generate aqueous filtrate and treated fiber suspension having a relatively higher consistency; (c) simultaneously pumping and degassing the filtrate at the same level; and (d) pumping the treated fiber suspension having the relatively higher consistency away from the treatment station at the same level by imparting to the treated fiber suspension sufficient shear force so as to render the fiber suspension pumpable.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: December 7, 1993
    Assignee: A. Ahlstrom Corporation
    Inventors: Jukka Heino, Kaj Henricson, Pasi Immonen, Raimo Kohonen, Erikki Savolainen, Pentti Vikio
  • Patent number: 5227021
    Abstract: A method of defiberizing fibrous cellulosic material bound by chemical bonds and physical force comprising treating the fibrous cellulosic material in a treatment apparatus so as to loosen the chemical bonds between the fibers but to leave the bonds caused by physical force essentiall undisburbed to generate treated fiber accumulations and removing a stream of the treated fiber accumulations from said treatment apparatus and defiberting the treated fiber accumulations by subjecting the material to shear forces in the stream, the shear forces being of sufficient strenth to substantiallyl break the physical forces keeping the fibers together and to separate the fibers.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: July 13, 1993
    Assignees: A. Ahlstrom Corporation, Wisaforest Oy Ab
    Inventors: Lasse Hernesniemi, Pikka Olavi, Ronkonharju
  • Patent number: 5221357
    Abstract: Two stage hydrolysis of lignocellulosic material, conditions during the first stage being such as to hydrolyze or depolymerize the hemicellulosic component without substantial degradation of resulting monosaccharides, conditions during the second stage being such as to hydrolyze the cellulose to glucose without substantial degradation of the glucose. The solids left after first stage hydrolysis are disintegrated mechanically thereby greatly facilitating second stage hydrolysis. Hydrolysis in both stages is preferably accomplished by the use of nitric acid. The pH, retention time and temperature in both stages are selected to maximize production of the desired monosaccharide or monosaccharides.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: June 22, 1993
    Inventor: David L. Brink
  • Patent number: 5164042
    Abstract: In a method of producing high-yield pulp from pulp chip material containing lignocellulose the material is treated with steam in a steam treating station (1) for driving air out of the material and heating the latter. Heat treated material is mixed in a mixing station (8) with a liquid containing chemicals. The mixture of steam treated material and said liquid is transferred from the mixing station to an impregnation station (25) for impregnating the material by means of said chemicals. Impregnated material is supplied to a refining station (36) for refining the material. According to the invention the steam treated material is mixed with said liquid in proportions, such that the created mixture of material and liquid leaving the mixing station (8) assumes a flowing pumpable consistency. Further, said flowing mixture is pumped from the mixing station (8) to the impregnation station (25).
    Type: Grant
    Filed: October 29, 1991
    Date of Patent: November 17, 1992
    Assignee: Celleco AB
    Inventors: Hans Larsen, Leif Klinga
  • Patent number: 5129987
    Abstract: A paper pulp refining and bleaching process wherein the pulp is treated in one or more refiners with a sodium hydrosulfite bleach liquor in the presence of a strong alkali such as NaOH, whereby the bleaching solution has an alkaline pH, preferably 10 to 12, and the pulp is discharged from the refiner at a pH of from about 5 to 6. The bleaching produces a brightness gain of at least 8 to 13 ISO points in the refiners. The process is preferably carried out by passing the pulp successively through a primary refiner at elevated pressure, a secondary refiner at atmospheric pressure and a bleaching tower, an alkaline hydrosulfite solution being fed to each.
    Type: Grant
    Filed: April 9, 1990
    Date of Patent: July 14, 1992
    Assignee: Morton Thiokol, Inc.
    Inventors: Thomas Joachimides, Stephen H. Levis, Bert A. Edstrom, Hans B. S. Moldenius
  • Patent number: 4983256
    Abstract: In the method for the manufacture of a paper pulp for currency use from a stock comprising textile fibers, the operations of boiling, bleaching, chopping, breaking, cutting and washing of the textile fibers are performed in at least one treatment machine (10, 40) of the type having two co-rotating screws, in a plurality of phases taking place successively and continuously. The operations include a phase of feeding and mixing the stock with water, at least oen compression phase, at least one phase of shearing of the textile fibers, at least one phase of treatment of introduction of boiling and bleaching reagents, at least one phase of washing of the bleached pulp by introduction of washing water, and a phase of transferring and evacuating the bleached and washed pulp.
    Type: Grant
    Filed: April 6, 1989
    Date of Patent: January 8, 1991
    Assignees: Clextral, Centre Technique de l'Industries des Papiers Cartons et Cellulose, Banque de Frane
    Inventors: Ph. Combette, Robar Angelier, Christian Vieu
  • Patent number: 4968385
    Abstract: A method of preparing a pulp for digestion in a continuous process from a fiber-containing cellulose material is described.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: November 6, 1990
    Assignee: Kamyr AB
    Inventors: Julio Amador, Eurico de Faria Amaro, Hans T. Haukerud, Ake Backlund
  • Patent number: 4966651
    Abstract: An improved paper for printing and other uses can be made from a paper pulp that contains pulp derived from hardwoods if the pulp is refined in a refiner that has at least one abrasive surface disk. The pulp can be refined to give a vessel picks count of 2/cm.sup.2 or less and have a Freeness of less than that which can be achieved using a refiner having conventional barred disks.
    Type: Grant
    Filed: January 12, 1989
    Date of Patent: October 30, 1990
    Assignee: P.H. Glatfelter Company
    Inventors: Robert A. Olson, Lewin R. Lutz, III
  • Patent number: 4941943
    Abstract: The invention relates to a method and an equipment for preparing NaCMC, in which (a) cellulose is slushed in the reaction medium until a consistency of c. 5-15%, preferably 5-10%, (b) the fibre suspension obtained in step (a) is thickened to a consistency of c. 20-35% and (c) the pulp containing reaction medium obtained in the second step is homogenized by means of a screw conveyor having a screw pitch which decreases from an inlet opening thereof towards an outlet opening thereof, in order to increase the reactivity, whereby a mercerization activating the cellulose is carried out after step (b) and/or (c), and the cellulose thus pretreated is etherified in a manner known per se.
    Type: Grant
    Filed: January 27, 1988
    Date of Patent: July 17, 1990
    Assignee: Metsa-Serla Oy
    Inventors: Kari Edelman, Torsten Lindroos
  • Patent number: 4812206
    Abstract: A process for bleaching a lignocellulosic matter in the form of a mechanical, thermomechanical, chemicomechanical or chemicothermomechanical papermaking pulp, or of wood chips while being converted into one of these pulp types by processing in a machine consisting essentially of two interpenetrating spiral surfaces wound around parallel shafts driven in synchronous rotation in the same direction inside a barrel which encloses them, and determining between upstream and downstream in the direction of forward travel of the matter a series of zones for drawing and braking the matter, which comprises combining a bleaching treatment using a reducing agent and a bleaching treatment using an oxidizing agent, characterized in that, after pretreatment using at least one metal-complexing or sequestering agent, the lignocellulosic matter undergoes a washing operation with an efficiency greater than 96% before undergoing in succession a bleaching treatment using a reducing agent at a pH of between about 8 and 12, a washin
    Type: Grant
    Filed: September 22, 1987
    Date of Patent: March 14, 1989
    Assignee: Atochem
    Inventors: Michel Devic, Robert Angelier
  • Patent number: 4787959
    Abstract: A process of preparing new chemical paper pulps wherein a first cooking stage is effected in the presence of sodium hydroxide and advantageously adjuvants, after which an intermediate grinding is effected and followed by a second cooking stage characterized in that the second cooking stage is performed in the presence of a peroxide alkaline solution containing a peroxide stabilizing agent.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: November 29, 1988
    Assignee: Atochem
    Inventors: Dominique Lachenal, Christian de Choudens, Pierre Monzie
  • Patent number: 4767499
    Abstract: A method for the production of fiber pulp from lignocellulosic material containing at least 70% spruce or spruce-like material. The method comprises the steps of lignin softening and defibration/refining, the step of lignin softening being performed prior to the step of defibration/refining and comprising impregnating the starting material with a dilute aqueous solution of a lignin softening agent, namely a solution of sulfurous acid, metal bisulfite salts and/or metal sulfite salts in an amount sufficient to provide a defibrated/refined pulp containing an absorbed and bonded amount of sulfonate groups within the range of from 0.06 to 0.75 wt.-%, calculated as Na.sub.2 SO.sub.3 and based on the dry pulp weight. The absorbed and bonded amount of sulfonate groups is balanced to the composition of the starting material and the temperature-pressure conditions in the defibration step to provide a pulp of maximum tensile strength such as to represent a point within the polygon ABGH in FIG. 1.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: August 30, 1988
    Inventors: Rune G. W. Simonson, Per O. Axelson
  • Patent number: 4756799
    Abstract: In accordance with the invention a chemimechanical pulp is produced from lignocellulosic material, for example wood chips, by subjecting the material to a process in which it is steamed, impregnated with alkali and peroxide, drained, pre-heated, refined and bleached. The material is impregnated in a single stage with a solution containing alkali and peroxide. Subsequent to passing an intermediate drainage and reaction stage, the material is pre-heated to a temperature of from about 50.degree. C., but not above 100.degree. C. The material is then refined in one or two stages. The material can be impregnated by immersing the same in the impregnating solution for a period of up to 20 minutes at a temperature of 15.degree.-60.degree. C., or by compressing the material in a screw press and permitting the compressed material to expand in the impregnating solution.
    Type: Grant
    Filed: March 12, 1986
    Date of Patent: July 12, 1988
    Assignees: Eka AB, Goran Bengtsson, Rune Simonson
    Inventors: Goran Bengtsson, Rune Simonson, Roland Agnemo
  • Patent number: 4743338
    Abstract: Air is removed from wood chips, and they are impregnated by treatment liquid, in a process that is an alternative to presteaming and is particularly applicable to environments where presteaming is undesirable, such as in the sulphite treatment of chips during the production of mechanical pulp. The chips are passed in a continuous manner in a generally serpentine, vertically oriented path so that the chips are subjected to a pressure build-up pulsation as they move downwardly, and a pressure release pulsation as they move upwardly. The diameters or cross-sectional areas of the conduit portions defining the upward and downward portions of the path are controlled so that there is about twice the residence time during pressure build-up than there is during pressure release. A high pressure feeder and pump with a fly wheel are operatively connected to one end of the serpentine path, while an in-line drainer and other apparatus are connected to the other end.
    Type: Grant
    Filed: May 19, 1986
    Date of Patent: May 10, 1988
    Assignee: Kamyr, Inc.
    Inventor: Robert J. Prough
  • Patent number: 4689117
    Abstract: The brightness of a thermomechanical pulp can be improved if a serial multiple blowdown technique is used and a bleachant is present at an effective concentration throughout the thermomechanical pulping process.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: August 25, 1987
    Assignee: Process Evaluation and Development Corporation
    Inventor: Eduardo J. Villavicencio
  • Patent number: 4634498
    Abstract: High strength and high density wood fiberboard is formed by treating the wood fiber source material with a highly alkaline solution, such as sodium hydroxide solution, before interfelting the fibers into a loose mat. The wood source material may be treated after refining the material into fibers, but preferably, the wood source material is treated before fibrillation. Further, wood fiber source material may be partially neutralized before felting without substantial change in the resulting densities and strengths.
    Type: Grant
    Filed: December 31, 1984
    Date of Patent: January 6, 1987
    Assignee: United States Gypsum Company
    Inventors: Dennis L. Hardesty, Timothy D. Hanna, Frank J. Wendt, Kendall D. White, Jr.
  • Patent number: 4599138
    Abstract: A process is provided for pretreating particulate lignocellulosic material to remove heavy metals and resin without any delignification or defibration, which comprises washing particulate lignocellulosic material; compressing the washed material to a solids content of at least 40% to remove absorbed and excess liquid; impregnating the compressed material with an alkaline aqueous solution comprising alkali and at least one of a heavy metal ion complexing agent and a heavy metal ion reducing agent; heating the impregnated material at a temperature within the range from abut 50.degree. to 100.degree. C. for up to approximately 0.75 hour; compressing the pretreated material to a solids content of at least 40%; and separating undiluted liquor squeezed out during the compression, while maintaining conditions during the pretreating such that the pH of the squeezed-out liquor is within the range from about 4 to about 9.
    Type: Grant
    Filed: October 30, 1981
    Date of Patent: July 8, 1986
    Assignee: Mooch Domsjo Aktiebolag
    Inventor: Jonas A. I. Lindahl
  • Patent number: 4486267
    Abstract: A high yield chemithermomechanical (CTMP) process for obtaining high strength hardwood pulps is disclosed wherein hardwood chips are subjected to a two-stage chemical treatment prior to defibration, the first consisting of chip impregnation and reaction with an alkaline liquor followed by a second stage treatment with sulfite and/or bisulfite; in one embodiment peroxide is added to the alkaline liquor to enhance brightness.
    Type: Grant
    Filed: November 14, 1983
    Date of Patent: December 4, 1984
    Assignee: Mead Corporation
    Inventor: Zenon C. Prusas
  • Patent number: 4435249
    Abstract: Rejects such as knots, shives, slivers, chops, and uncooked and partially cooked wood chips are separated from a pulp slurry and treated to produce a bleachable grade pulp. The rejects are dewatered to a 10-15% consistency, mechanically fiberized, and then delignified at the same 10-15% consistency in the presence of oxygen and alkaline pulping chemicals. The delignification is carried out at 80.degree.-140.degree. C. for 5-120 minutes. The process has low external power requirements, requires no expensive dewatering machinery, and proceeds at a rapid rate to yield a bleachable grade pulp which can be used alone or mixed with other pulp.
    Type: Grant
    Filed: November 25, 1981
    Date of Patent: March 6, 1984
    Assignees: The Black Clawson Co., Air Products & Chemicals, Inc.
    Inventors: Larry D. Markham, Andrew C. Martin, Edward F. Elton, Vincent L. Magnotta, Scott A. Wallick
  • Patent number: 4406734
    Abstract: A method and a device for the manufacture of mechanical pulp from lignocellulosic material by forcing the said material into contact with a grindstone (1) which revolves about an axle (2). The material is supplied in bulk, particulate form, preferably as wood chips, a large number of particles simultaneously being retained, compressed and, in the presence of water, forced into contact with one or more grinding areas on the circumferential surface of the grindstone (1). The grindstone (1) is enclosed in a sealed, pressurized housing (5).
    Type: Grant
    Filed: October 9, 1980
    Date of Patent: September 27, 1983
    Assignee: Sunds Defibrator AB
    Inventor: Hjalmar S. I. Bystedt
  • Patent number: 4372810
    Abstract: A method and a device for the manufacture of mechanical pulp from lignocellulosic material by forcing the said material into contact with a grinding disc (1) which revolves about a central axle (2) perpendicular to the two end faces of the disc.. The material is supplied in bulk, particulate form, preferably as wood chips, a large number of particles simultaneously being retained, compressed and, in the presence of water, forced into contact with one or more grinding areas (5) on one or both end faces of the grinding disc. The disc is enclosed in a sealed, pressurized housing (6).
    Type: Grant
    Filed: October 9, 1980
    Date of Patent: February 8, 1983
    Assignee: Sunds Defibrator AB
    Inventor: Hjalmar S. I. Bystedt
  • Patent number: 4357208
    Abstract: Lignocellulose material is pretreated with steam, heat, lignin softening chemicals or combinations thereof. The pretreated material is then refined in a disc refiner. Water is added to the material in the refining zone of the disc refiner to form a suspension at concentration of 8-15% at the point of discharge from the gap between the discs of the refiner. Steam development and steam backflow from the gap is reduced.
    Type: Grant
    Filed: October 17, 1979
    Date of Patent: November 2, 1982
    Assignee: SCA Development Aktiebolag
    Inventors: Per V. Peterson, Hans E. Hoglund
  • Patent number: 4347101
    Abstract: A high quality newsprint pulp can be produced from wood or vegetable fibers by thermomechanically pulping one portion of these fibers and thermochemically pulping the remaining portion. After combining these pulps the result is a pulp which has a GE brightness of 55 to 60, an opacity of 93 to 96 percent, and a relatively high tear strength. A pulp useful for making low strength papers can be produced by solely thermomechanically pulping fiber and directly using this pulp to make such products.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: August 31, 1982
    Assignee: W. R. Grace & Co.
    Inventor: Eduardo J. Villavicencio
  • Patent number: 4294653
    Abstract: A process is provided for the manufacture of bleached chemimechanical cellulose pulp in high yield of between 65 and 95% from particulate and preferably washed lignocellulosic material, such as wood chips, featuring the use of spent or waste bleaching liquid, preferably from a lignin-preserving bleaching process, in at least one stage of the process where a cooling and diluting liquid is required, such as during mechanical defibration of the material.
    Type: Grant
    Filed: April 11, 1978
    Date of Patent: October 13, 1981
    Assignee: Mo och Domsjo Aktiebolag
    Inventors: Jonas A. I. Lindahl, Lars G. Rudstrom
  • Patent number: 4260452
    Abstract: Paper pulp is produced by a process in which raw sugar mill bagasse is moist depithed, wet bulk stored in the presence of an inorganic and organic preservative, wet depithed by hydraulic shearing in the presence of an inorganic color remover, pulped, washed, cleaned and dewatered.
    Type: Grant
    Filed: November 24, 1978
    Date of Patent: April 7, 1981
    Inventors: Horst Kruger, Wilhelm Berndt, Ursula Schwartzkopff, Franz J. Reitter, Theodor Hopner, Hans-Joachim Muhlig
  • Patent number: 4248662
    Abstract: Fibrous material is pre-steamed, impregnated with alkali liquor, refined, and then oxygen pulped at a low consistency (about 3 to 8 percent solids) using an alkali liquor which contains boron compounds. The pulping step of the process is carried out in stages with recycle of liquor to preceding stages after it has been reoxygenated. By recycling a major portion of the pulping liquor, the actual liquor to fibrous material ratio at each stage of the pulping step is maintained at a relatively high level (12/1 to 30/1) while the effective liquor to fibrous material ratio for the overall process is much lower (4/1 to 8/1). This results in a bright pulp of acceptable strength as well as a high solids content spent liquor which is economically recoverable.
    Type: Grant
    Filed: January 22, 1979
    Date of Patent: February 3, 1981
    Assignee: The Black Clawson Company
    Inventor: Scott A. Wallick
  • Patent number: 4230524
    Abstract: Knots separated from sulphite cellulose produced by a sulphite cellulose cooking process are converted to unbleached sulphite cellulose by first separating and defibrating the sulphite knots and then treating the defibrated sulphite knots with oxygen under pressure in an alkaline milieu at an elevated temperature. The resultant cellulose may be bleached by itself, or mixed with sulphite cellulose produced from knot-free cellulose pulp for bleaching therewith.
    Type: Grant
    Filed: June 28, 1979
    Date of Patent: October 28, 1980
    Assignee: Borregaard A/S
    Inventor: Ketil Hasvold