Liquor From Digestion Using Organic Compound Or Including Element Other Than Na, Ca, Mg, O, C, H Or S Patents (Class 162/32)
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Patent number: 10596720Abstract: The present invention relates to a method for producing wood materials from lignocellulose-containing crushed products, in particular for producing wooden insulating panels or OSB boards, wherein in order to decrease or reduce the emission of volatile organic compounds (VOC) and, if relevant, very volatile organic compounds (VVOC), including terpenes, acids and aldehydes, said wood materials are treated with a combination of additives during production. According to the invention, the treatment is carried out with a first component made of porous carbon and a second component, a hydrogen sulphite salt. The invention further relates to wood materials that can be obtained using the method according to the invention, having reduced emissions of VOCs, including terpenes, acids and aldehydes.Type: GrantFiled: September 23, 2016Date of Patent: March 24, 2020Assignee: SWISS KRONO TEC AGInventors: Norbert Kalwa, Dirk Müller, Gunnar Thielecke
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Patent number: 8657996Abstract: A method is provided for controlling deposit-forming contaminants that comprise pitch or other fiber components which can interfere with the processing of the fibers, reduce paper quality, or both in papermaking systems. The method includes contacting fibers with a lipase and at least one peroxide source-free oxidant, and optionally nonionic surfactant, to liberate the organic contaminants from the fibers. Paper products of the method are also provided.Type: GrantFiled: April 19, 2013Date of Patent: February 25, 2014Assignee: Buckman Laboratories International, Inc.Inventors: Xiangdong Zhou, Percy Jaquess
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Patent number: 8617354Abstract: Provided is a process for manufacturing shaped cellulose materials from lignocellulose where a dissolving grade pulp is manufactured and dissolved in an aqueous alkaline or acidic solvent system forming a solution suitable for shaping new cellulose structures including fibers, films and cellulose derivatives. At least a part of the spent cellulose dissolving or cellulose shaping chemicals are recovered in one or more unit operations in a pulp mill chemical recovery cycle.Type: GrantFiled: March 8, 2010Date of Patent: December 31, 2013Assignee: Kiram ABInventor: Lars Stigsson
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Patent number: 7468176Abstract: Feeding device for feeding burned lime to a reaction vessel for causticizing soda liquor to caustic soda. The feeding device, in its upper part, has an inlet for receiving slurry of the burned lime and the soda liquor for formation of said slurry inside said feeding device. The system further comprises a tall and slender feed vessel having a lower part having an outlet defined therein for the slurry. The outlet, via a pump, is operatively connected to the reaction vessel. The process and the feeding system utilize the feeding device, in which process the slurry is created of the burned lime and a first part of the soda liquor, a second part being preheated before addition to the slurry, whereafter slaking and causticizing reactions are completed under elevated temperature and pressure.Type: GrantFiled: February 3, 2006Date of Patent: December 23, 2008Inventors: Lennart Westerberg, George W. Bearry, Patrik Lownertz, Don Parker
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Patent number: 7097738Abstract: The invention relates to a process for producing pulp from a fibre-based raw material using, as the cooking reagent, a solvent mixture which is based on organic acids and also contains furfural. The method is applicable to herbaceous plants, in particular.Type: GrantFiled: July 11, 2002Date of Patent: August 29, 2006Assignee: Chempolis OyInventors: Esa Rousu, Pasi Rousu, Juha Anttila, Päivi Rousu
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Patent number: 6923888Abstract: The invention relates to a process for treating bleaching liquors from pulping processes based on organic acids. The process is characterized in that inorganic acid, such as nitric acid, phosphoric acid and/or sulphuric acid, is added into a bleaching liquor obtained from the bleaching or a stage closely associated with bleaching, whereby organic acids contained in the bleaching liquor are released into the bleaching liquor. The organic acids are then separated from the bleaching liquor and recycled to the cooking stage to be used as cooking chemicals. The nitrogen-, phosphor- and/or sulphur-containing product thereby produced, from which organic acids have been separated, is recovered to be used as a fertilizer or as raw material for a fertilizer.Type: GrantFiled: February 27, 2001Date of Patent: August 2, 2005Assignee: Chempolis OyInventors: Pasi Rousu, Päivi Rousu, Esa Rousu, Juha Anttila
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Publication number: 20040000381Abstract: Polynuclear compounds dissolved and contained within an organic solvent are separated from the organic solvent by rendering the organic compounds insoluble within the organic solvent. Accordingly this invention removes polynuclear compounds from a saturated organic solvent. The polynuclear compounds are derived from black liquor obtained from kraft digestion. Whereby polynuclear compounds, substantially free of an organic solvent, are obtained from the organic solvent.Type: ApplicationFiled: July 1, 2002Publication date: January 1, 2004Inventor: Gene E. Lightner
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Patent number: 6663749Abstract: A method is provided for the use of borates in the recausticization of alkali-containing liquors such as those produced in the chemical and semi-chemical pulping of wood and in the oxidation and bleaching of wood pulp. Sodium hydroxide is regenerated from sodium carbonate-containing smelts in such pulp processes by autocausticization through the addition of limited amounts of borate. Autocausticization may be carried out at boron to carbonate molar ratios below 2:1 and at sodium to boron molar ratios exceeding 3:1, resulting in high reaction efficiency. Partial autocausticization using borate may also be combined with conventional lime recausticization for the regeneration of sodium hydroxide from sodium carbonate-containing smelts.Type: GrantFiled: September 25, 2001Date of Patent: December 16, 2003Assignee: U.S. Borax Inc.Inventors: Charles M. Bair, Robert B. McBroom, Honghi N. Tran
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Publication number: 20030145961Abstract: The invention relates to a process for treating bleaching liquors from pulping processes based on organic acids. The process is characterized in that inorganic acid such as nitric acid, phosphoric acid and/or sulphuric acid, is added into a bleaching liquor obtained from the bleaching or a stage closely associated with bleaching, whereby organic acids contained in the bleaching liquor are released into the bleaching liquor. The organic acids are then separated from the bleaching liquor and recycled to the cooking stage to be used as cooking chemicals. The nitrogen-, phosphor- and/or sulphur-containing product thereby produced, from which organic acids have been separated, is recovered to be used as a fertilizer or as raw material for a fertilizer.Type: ApplicationFiled: November 15, 2002Publication date: August 7, 2003Inventors: Pasi Rousu, Paivi Rousu, Esa Rousu, Juha Anttila
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Patent number: 6348128Abstract: A method is provided for improving causticizing efficiency in the conventional lime recausticization portion of an alkaline pulping process. Such processes are commonly used in the pulping and bleaching of wood and non-wood cellulose fiber materials. The method of this invention comprises reacting an aqueous solution of sodium carbonate with lime to produce sodium hydroxide (causticization) in the presence of borate in order to improve the causticization reaction efficiency. Borate is added in an amount sufficient to provide a boron to sodium (B/Na) molar ratio in the range of between about 0.001:1 and 0.4:1, and preferably in the range of between about 0.01:1 and 0.3:1, which results in an increased causticization efficiency of up to 8% over the reaction efficiency obtained in the absence of borate.Type: GrantFiled: March 24, 1999Date of Patent: February 19, 2002Assignee: U.S. Borax Inc.Inventors: Honghi N. Tran, Charles M. Bair, Robert B. McBroom
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Patent number: 6024833Abstract: Provided is a process for removing metals from a bleaching plant spent liquor and recovering a chelating agent which includes the steps of: heating a spent liquor containing a chelate comprising metals bound in a chelating agent to a temperature of at least about 140.degree. C.Type: GrantFiled: May 2, 1997Date of Patent: February 15, 2000Assignee: Kvaerner Pulping AbInventor: Olle Wennberg
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Patent number: 5635027Abstract: A method of recycling sodium-based salts used for digesting wood in a digester during the manufacture of pulp and paper. The method comprises collecting a black liquor from the digester, concentrating the black liquor, and adding a salt to the black liquor in an amount sufficient to reduce the viscosity thereof. Preferred salts are thiocyanate salts. The black liquor is then oxidized to produce a green liquor and a causticizer added to the green liquor to produce a white liquor containing the sodium-based salts to be recycled. The white liquor is then returned to the digester.Type: GrantFiled: April 3, 1995Date of Patent: June 3, 1997Assignee: North Carolina State UniversityInventors: Richard J. Spontak, Joanna E. Roberts, Victoria A. Prevysh, Saad A. Khan
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Patent number: 4778813Abstract: Novel capped polymeric quaternary ammonium compositions formed by reacting ionene type polymers with tertiary amines are useful as microbicides, corrosion inhibitors, debonding agents, flocculants, softeners, and demulsifiers.Type: GrantFiled: January 30, 1985Date of Patent: October 18, 1988Assignee: Buckman Laboratories International, Inc.Inventors: Joseph G. Fenyes, John D. Pera
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Patent number: 4767500Abstract: A sulphite cooking process is described for the production of pulp from materials containing lignocelluloses, with recovery of the cooking chemicals, in which the cooking, the blowing, the washing and the bleaching are performed sucessively. The waste liquor is subjected to several thermal treatments for the recovery of the cooking chemicals. For the cooking of the lignocellulosic materials, alkaline sulphite solutions are used, to which one or, in mixture, several low-boiling solvents are added, as well as at least one compound suitable as a redox catalyst.Type: GrantFiled: August 27, 1987Date of Patent: August 30, 1988Assignee: Kraftanlagen AktiengesellschaftInventors: Rudolf Patt, Othar Kordsachia
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Patent number: 4735683Abstract: Described herein is a process for producing potassium salts from potassium-based liquors for pulping of lignocellulosic material. The process comprises the steps of(a) digesting lignocellulosic material with a potassium-base aqueous cooling liquor to obtain an aqueous slurry of partially delignified pulp of the lignocellulosic material;(b) separating the pulp from the spent potassium-base aqueous cooling liquor;(c) concentrating the spent pulping liquor; and(d) recovering potassium salts including potassium carbonate, potassium sulphate and potassium lignosulphonate from the concentrated spent pulping liquor. The recovered potassium salts find numerous uses, an example being use in fertilizers.Type: GrantFiled: May 28, 1986Date of Patent: April 5, 1988Assignee: Potash Corporation of SaskatchewanInventors: Alfred Wong, Gary D. Derdall
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Patent number: 4597830Abstract: A pulping liquor for the delignification of lignocellulosic materials is disclosed which avoids the use of sodium hydroxide and so avoids degradation of substantial portions of the cellulose component, and simultaneously avoids the use of sulphide or other environmental pollutants. The cooking process employing this liquor can advantageously include recycling of the liquor to provide sustained delignification from the same original liquor provided, and distillation of spent liquor to recover the essential components thereof.The liquor is comprised of alcohol, an amine and water, each present in amount of 1-12 parts by volume. The liquor is further used in the presence of a quinone and/or azine catalyst.Type: GrantFiled: June 20, 1983Date of Patent: July 1, 1986Assignee: The University of AlabamaInventors: Gary C. April, Ramkrishna G. Nayak
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Patent number: 4504356Abstract: A continuous process of removing silica from spent pulping liquors (black liquors) which have been obtained by the alkaline digestion of annual plants. The spent liquor is preconcentrated and contacted with a CO.sub.2 -containing gas. The CO.sub.2 -containing gas is supplied at a rate of 30 to 40 m.sup.3 s.t.p. per m.sup.3 of spent liquor. The precipitated silica is removed from the treated liquor. The silica-containing precipitate which has been separated is diluted and washed with water and causticized by an addition of lime or milk of lime. Solid and liquid phases are separated from each other and the resulting residue is combusted.Type: GrantFiled: February 28, 1983Date of Patent: March 12, 1985Assignee: Metallgesellschaft AktiengesellschaftInventors: Jurgen Mulder, Pedro Gutmann
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Patent number: 4486394Abstract: The invention relates to an improvement in a method of regenerating alkaline or alkaline earth metal oxides or hydroxides from solution particularly in delignification processes wherein a suitable transition metal such as ferric oxide is burnt with the solution to produce a mixed oxide that is subsequently treated in hot water to regenerate the alkaline or alkaline earth metal oxide or hydroxide and precipitate the transition metal oxide. The improvement controls the presence of fines in the transition metal oxide to maintain these at an acceptable level in the fluidized bed combustion zone. This is achieved by contacting the fines with spent liquor from a delignification process. The invention also provides for the pelletization of the fine material of the transition metal oxide and spent delignification liquor can be used as a binder in the formation of such pellets.Type: GrantFiled: November 1, 1983Date of Patent: December 4, 1984Assignee: Australian Paper Manufacturers LimitedInventors: Kien L. Nguyen, Andrew J. Keogh, Geoffrey H. Covey
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Patent number: 4248662Abstract: Fibrous material is pre-steamed, impregnated with alkali liquor, refined, and then oxygen pulped at a low consistency (about 3 to 8 percent solids) using an alkali liquor which contains boron compounds. The pulping step of the process is carried out in stages with recycle of liquor to preceding stages after it has been reoxygenated. By recycling a major portion of the pulping liquor, the actual liquor to fibrous material ratio at each stage of the pulping step is maintained at a relatively high level (12/1 to 30/1) while the effective liquor to fibrous material ratio for the overall process is much lower (4/1 to 8/1). This results in a bright pulp of acceptable strength as well as a high solids content spent liquor which is economically recoverable.Type: GrantFiled: January 22, 1979Date of Patent: February 3, 1981Assignee: The Black Clawson CompanyInventor: Scott A. Wallick
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Patent number: 4116759Abstract: A method for the regeneration of pulping or bleaching chemicals from spent liquor containing salts of polybasic organic acids. The liquor is evaporated and then burned so that organic matter will be discharged as carbon dioxide and water, and a carbonate residue is formed. Carbon dioxide is expelled from the carbonate with an acid by autocaustization to regenerate the cooking chemicals.Type: GrantFiled: August 31, 1976Date of Patent: September 26, 1978Inventor: Jan Janson
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Patent number: 4070233Abstract: A pulping process which includes the steps of oxidizing vegetable materials with an oxidizing chemical selected from the group comprising Cl.sub.2, Cl.sub.2 O,ClO.sub. 2, Mg(ClO).sub.2, Mg(ClO.sub.2).sub.2 Mg.(ClO.sub. 3).sub.2 and mixtures thereof, extracting the oxidized materials with Mg(OH).sub.2 thereby to delignify and bleach the materials and treating the waste liquor from the oxidation, extraction and washing steps by combustion or thermal decomposition thereby to regenerate the chemicals necessary for the oxidation and extraction steps. The process of the invention produces semi-bleached or completely bleached pulp of high strength with high yield while eliminating the problem relating to environmental pollution.Type: GrantFiled: June 14, 1972Date of Patent: January 24, 1978Assignee: Japan Pulp & Paper Research Instutute Inc.Inventor: Hiroshi Matsuura