Without Treatment Or Modification Patents (Class 162/40)
  • Patent number: 10570542
    Abstract: An apparatus and method for pre-shrinking a wet fabric prior to drying. The apparatus includes, among other components, a balloon extractor station and a hydro-sizer compression station. The balloon extractor station removes some water from the wet fabric. The hydro-sizer compression station is operatively connected to, and disposed downstream of, the balloon extractor station, and compresses the wet fabric in a lengthwise direction, and in so doing, pre-shrinks the wet fabric prior to drying. The method includes, among other steps, extracting some water from the wet fabric so as to faun a hydro-extracted and wet fabric, compressing lengthwise the hydro-extracted and wet fabric so as to form a compacted and wet fabric that is now pre-shrunk prior to drying, and drying the compacted and wet fabric so as to form a compacted and dry fabric.
    Type: Grant
    Filed: January 13, 2016
    Date of Patent: February 25, 2020
    Inventor: Teresa Catallo
  • Publication number: 20140246158
    Abstract: A reactor vessel system including: a first reactor vessel having a hydrolysate and liquid extraction screen, a first region above the extraction screen that is maintained at conditions promoting a hydrolysis reaction in the cellulosic material, a second region below the extraction screen in which the hydrolysis is substantially suppressed and a wash liquid inlet below the extraction screen providing wash liquid at a temperature below a hydrolysis temperature; a transport pipe having an inlet coupled to the first reactor vessel and an outlet coupled to a second reactor vessel, and the second reactor vessel includes a liquid discharge that extracts a portion of liquid from the second reactor vessel and directs the portion of liquid to the first reactor vessel or to the transport pipe.
    Type: Application
    Filed: May 15, 2014
    Publication date: September 4, 2014
    Applicant: Andritz Inc.
    Inventors: Namhee Shin, Bertil Stromberg, Ventzislav H. Kirov, William J. Cann
  • Publication number: 20140174679
    Abstract: A process for making bleached pulp comprises contacting an unbleached pulp mixture with a first recycled filtrate obtained from a first location (3) of a first recycled filtrate loop, to obtain a first pulp mixture having a first consistency; bleaching the first pulp mixture, to obtain a first bleached pulp mixture; pressing or dewatering the first bleached pulp mixture, to obtain a first pressed bleached pulp mixture and a second filtrate; sending at least a portion of the second filtrate to a second location (5) of the first recycled filtrate loop, wherein the second location (5) is downstream of and in fluid communication with the first location (3); contacting the first pressed bleached pulp mixture with a second recycled filtrate obtained from a third location (6) of the first recycled filtrate loop, to obtain a second pulp mixture having a second consistency, wherein the second consistency is greater than the first consistency, and wherein the third location (6) is downstream of and in fluid communicati
    Type: Application
    Filed: February 28, 2014
    Publication date: June 26, 2014
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventor: CAIFANG F. YIN
  • Publication number: 20140166221
    Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, at least one of ammonia or a source of ammonia, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a suitable support. The lignocellulosic biomass solids and digestive solvent are heated in the presence of hydrogen, supported hydrogenolysis catalyst and the at least one of ammonia or a source of ammonia forming a product solution containing plurality of oxygenated hydrocarbons and ammonia. At least a portion of ammonia is separated and recycled to the hydrothermal digestion unit.
    Type: Application
    Filed: December 19, 2013
    Publication date: June 19, 2014
    Applicant: Shell Oil Company
    Inventors: Joseph Broun POWELL, Glenn Charles KOMPLIN, John Anthony SMEGAL, Kimberly Ann JOHNSON
  • Publication number: 20130299104
    Abstract: A screen structure which is unusually effective at removing stickies from recyclable fiber but is tolerant of substantial swings in throughput which result in variations in the flow velocity through the screen—slot velocity. One example of the screen structure is created by forming a very large number of similarly shaped vanes then locking them into a ring structure to form a cylindrical screen basket but equivalent surface configurations can also be formed into sheet stock.
    Type: Application
    Filed: July 17, 2013
    Publication date: November 14, 2013
    Inventors: Wayne F. Winkler, Bradley E. Lucas
  • Patent number: 8545673
    Abstract: Process for recovering molybdate or tungstate from an aqueous solution, in which molybdate or tungstate is bound to a water-insoluble, cationized inorganic carrier material from the aqueous solution at a pH in the range from 2 to 6, the laden carrier material is separated off and the bound molybdate or tungstate is liberated once again into aqueous solution at a pH in the range from 6 to 14. The process is suitable for recovering molybdate or tungstate in the delignification of pulp with hydrogen peroxide in the presence of molybdate or tungstate as catalyst. The recovered molybdate or tungstate can be recycled to the delignification.
    Type: Grant
    Filed: August 14, 2012
    Date of Patent: October 1, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Thomas Dietz, Hans Ulrich Süss
  • Publication number: 20120305208
    Abstract: Process for recovering molybdate or tungstate from an aqueous solution, in which molybdate or tungstate is bound to a water-insoluble, cationized inorganic carrier material from the aqueous solution at a pH in the range from 2 to 6, the laden carrier material is separated off and the bound molybdate or tungstate is liberated once again into aqueous solution at a pH in the range from 6 to 14. The process is suitable for recovering molybdate or tungstate in the delignification of pulp with hydrogen peroxide in the presence of molybdate or tungstate as catalyst. The recovered molybdate or tungstate can be recycled to the delignification.
    Type: Application
    Filed: August 14, 2012
    Publication date: December 6, 2012
    Applicant: Evonik Degussa GmbH
    Inventors: Thomas Dietz, Hans Ulrich Süss
  • Publication number: 20120237989
    Abstract: A method for the production water insoluble reactive lignin having low sulfur content and lignosulfonates from lignocellulosic material in a batch or continuous process. Lignocellulosic material is fractionated to produce water insoluble native lignin and lignosulfonates in various ratios, while preserving the cellulose and hydrolyzed hemicelluloses using water, ethanol and sulfur dioxide.
    Type: Application
    Filed: September 19, 2008
    Publication date: September 20, 2012
    Applicant: API Intellectual Property Holdings, LLC
    Inventors: Theodora Retsina, Vesa Pylkkanen
  • Publication number: 20120097350
    Abstract: A processes producing mechanical pulps utilizing refiners for improving the quality of screen rejects, and most particularly to a mechanical pulp mill integrated with a neutral-alkaline papermaking process producing mechanical printing paper grades is disclosed. The rejects are treated with hydrogen peroxide, an alkali and an organic stabilizing agent just prior to or during refining to provide improved optical and physical properties of the refined rejects and more efficiently utilize electrical energy to reach target fiber quality after bleaching for cost-effectively producing a wide array of coated and uncoated mechanical printing papers.
    Type: Application
    Filed: June 9, 2010
    Publication date: April 26, 2012
    Applicant: Arkema Inc.
    Inventors: Stanley A. Heimburger, Melford R. Lougheed
  • Publication number: 20110232853
    Abstract: A process for making bleached pulp comprises contacting an unbleached pulp mixture with a first recycled filtrate obtained from a first location (3) of a first recycled filtrate loop, to obtain a first pulp mixture having a first consistency; bleaching the first pulp mixture, to obtain a first bleached pulp mixture; pressing or dewatering the first bleached pulp mixture, to obtain a first pressed bleached pulp mixture and a second filtrate; sending at least a portion of the second filtrate to a second location (5) of the first recycled filtrate loop, wherein the second location (5) is downstream of and in fluid communication with the first location (3); contacting the first pressed bleached pulp mixture with a second recycled filtrate obtained from a third location (6) of the first recycled filtrate loop, to obtain a second pulp mixture having a second consistency, wherein the second consistency is greater than the first consistency, and wherein the third location (6) is downstream of and in fluid communicati
    Type: Application
    Filed: March 18, 2011
    Publication date: September 29, 2011
    Applicant: INTERNATIONAL PAPER COMPANY
    Inventor: CAIFANG F. YIN
  • Patent number: 7604711
    Abstract: Method and apparatus for batch displacement digester systems to increase tank farm vessel temperatures for more efficient delignification rates by mitigating the formation of flow channels in the chip bed, minimizing the vertical temperature gradient in the digester and segregation of returning liquors to the tank farm from the digester.
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: October 20, 2009
    Inventor: Craig A. Bianchini
  • Publication number: 20090020245
    Abstract: It consists in performing a security paper or special paper incorporating pigments within the paste of the synthetic element itself during its manufacture, providing pigment properties to said synthetic element, the pigments being protected from the attack of physical and chemical agents by the synthetic element itself.
    Type: Application
    Filed: April 6, 2005
    Publication date: January 22, 2009
    Inventors: Vicente Garcia Juez, Javier Baraja Carracedo
  • Patent number: 7241363
    Abstract: One aspect of this invention relates to a method and digester for reducing the deposition of calcium-based scale in a wood chip digester including extraction from the digester of first and second quantities of cooking liquor having respective first and second calcium concentrations, treating the extracted cooking liquors to produce a cooking liquor having a calcium concentration less that the calcium concentration of the either of the first and second extracted cooking liquors, and, reintroducing the treated cooking liquor to the digester. Another aspect of this invention relates to a method and digester in which through put through the digester is increased by the continuous addition of process liquor into the digester preferably at an upper region of the digester.
    Type: Grant
    Filed: June 26, 2004
    Date of Patent: July 10, 2007
    Assignee: International Paper Company
    Inventors: Jianer Jiang, Gerald Wayne Hill
  • Patent number: 7112256
    Abstract: A method for the continuous cooking of chemical pulp with the aim of achieving improved heat economy in a digester system having a vessel (1) for impregnation and a vessel (2) for cooking the impregnated cellulose chips. A part of the black liquor (14) withdrawn from the digester (2) is added at the beginning of a transfer system (4) to increase the temperature of the chips mixture in the transfer system (4). A fraction of the transport fluid (10) from the transfer system (4) that is continuously withdrawn from the impregnated chips fed into the top of the digester is returned to the impregnation vessel (1) at essentially the maintained transfer temperature.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: September 26, 2006
    Assignee: Kvaerner Pulping AB
    Inventors: Vidar Snekkenes, Lennart Gustavsson
  • Patent number: 6939439
    Abstract: Methods for producing chemical pulp from lignocellulose-containing material in processes for kraft pulp production are disclosed including charging the lignocellulose-containing material to a digester, initially treating the lignocellulose-containing material with an impregnation liquor, and then treating the impregnated lignocellulose-containing material with hot liquor and displacing calcium-containing spent liquor from the digester during that treatment, heating and cooking the heated lignocellulose-containing material to produce cooked lignocellulose-containing material and cooking liquor and displacing the cooking liquor from the digester using at least a portion of the displaced calcium-containing spent liquor.
    Type: Grant
    Filed: October 4, 2000
    Date of Patent: September 6, 2005
    Assignee: Metso Chemical Pulping Oy
    Inventors: Asko Paakki, Päivi Uusitalo, Mikael Svedman
  • Publication number: 20040099386
    Abstract: Separation of dissolved and colloidal high molecular weight organic by-products from liquors or filtrates in a cellulosic pulping process to improve the overall efficiency of the process.
    Type: Application
    Filed: November 20, 2003
    Publication date: May 27, 2004
    Inventor: Craig A. Bianchini
  • Publication number: 20040060672
    Abstract: A method for the continuous cooling of chemical pulp with the aim of achieving improved heat economy in a digester system comprising a vessel (1) for impregnation and a vessel (2) for cooking the impregnated cellulose chips. A part of the black liquor (14) withdrawn from the digester (2) is added at the beginning of a transfer system (4) having maintained essentially the withdrawl temperature, increasing the temperature of the chips mixture in the transfer system (4). A fraction of the transport fluid (10) from the transfer system (4) that is continuously withdrawn from the impregnated chips fed into the top of the digester is returned to the impregnation vessel (1) at essentially maintained transfer temperature, at a location before the said transfer system (4), seen from the point of view of the direction of flow of the chips.
    Type: Application
    Filed: October 22, 2003
    Publication date: April 1, 2004
    Inventors: Vidar Snekkenes, Lennart Gustavsson
  • Patent number: 6699357
    Abstract: The invention relates to a process for continuous cooking of wood chips at elevated pressure and temperature in a vertical digester (1) for production of chemically dissolved pulp. Fiber material and cooking liquor are introduced at the top of the digester and pulp is discharged from the bottom of the digester (1), via a line (8) in which the pulp is maintained at substantially the same pressure level, to a pressurized wash (7). More than 50% of the used cooking liquor (black liquor) which is extracted from the system in total is extracted from the wash filtrate of the pressurized wash. The pressurized wash is regulated so that a high temperature is maintained in the wash filtrate. The extraction is regulated so that a net co-current flow is established at the bottom of the digester.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: March 2, 2004
    Assignee: Kvaerner Pulping AB
    Inventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
  • Publication number: 20030209335
    Abstract: A method is disclosed for extracting liquor from a cellulose slurry for a continuous digester comprising the steps of: providing the cellulose slurry of liquor and chips of cellulose fiber material to a separator; extracting a first stream of liquor from the separator; extracting a second stream of liquor from the separator, where the second stream has an effective alkali (EA) concentration greater than the EA concentration of the first steam; outputting the first stream from the separator and outputting the second stream from the separator separately from the second stream, and outputting a condensed slurry from the separator to a digester vessel.
    Type: Application
    Filed: May 21, 2003
    Publication date: November 13, 2003
    Applicant: Andritz Inc.
    Inventors: Kaj O. Henricson, C. Bertil Stromberg, Richard Laakso, John F. Bolles, Keith P. Vogel, Patrick J. Sullivan
  • Publication number: 20030205343
    Abstract: A continuous pulp digester having an elongate horizontally aligned pressure vessel through which the wood chips and digesting fluid flow in a forward direction. In a first and second embodiments within the pressure vessel there is an inner container defining an elongate chamber or passageway having a square cross sectional configuration. In a third embodiment the digesting chamber is cylindrical. At locations along the digester, there are several pair of liquid flow inlets and liquid flow outlets which enable filtrate from a pulp washer and a digesting agent to be moved into and across the digesting chamber to flow out the flow outlets. These are recirculated in a net upstream flow pattern toward the outlet end of the digester, and discharged as black liquor at different locations in the digester.
    Type: Application
    Filed: April 18, 2003
    Publication date: November 6, 2003
    Inventor: Reijo K. Salminen
  • Publication number: 20030178163
    Abstract: A method of bleaching chemical pulp, comprising two bleaching stages (D0 and, respectively, D1) with chlorine dioxide as dominating bleaching chemical and at least one intermediate alkaline bleaching stage (E). The ingoing pulp is dewatered to a concentration of 25-40% before the first chlorine dioxide stage (D0) and to 10-40% after the second chlorine dioxide stage (D1). Filtrate from the dewatering after the second chlorine dioxide stage (D1) is re-cycled and utilized for controlling the pulp concentration to 8-15% of the dewatered pulp to the first chlorine dioxide stage (D0).
    Type: Application
    Filed: February 12, 2003
    Publication date: September 25, 2003
    Inventors: Lars-Ake Lindstrom, Solveig Norden, Gunnar Carre
  • Patent number: 6605180
    Abstract: Fiber material and cooking liquor are introduced at the top of the digester and pulp is discharged from the bottom of the digester, via a line in which the pulp is maintained at substantially the same pressure level, to a pressurized wash. More than 50% of the used cooking liquor (black liquor) which is extracted from the system in total is extracted from the wash filtrate of the pressurized wash. At the same time a small portion of the wash filtrate is also to be recirculated to the bottom of the digester as dilution liquid. The pressurized wash is regulated so that a high temperature is maintained in the wash filtrate. The extraction is regulated so that a net co-current flow is established at the bottom of the digester.
    Type: Grant
    Filed: September 28, 2001
    Date of Patent: August 12, 2003
    Inventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
  • Patent number: 6468390
    Abstract: A method for continuous cooking of lignocellulosic fiber material, comprising the steps of sequentially (a) in a first stage, impregnating the fiber material in an impregnation liquid comprising alkali metal hydroxide, and thereafter withdrawing (14, 514) a spent impregnation liquid; (b) in a second stage, cooking the fiber material in a cooking liquor comprising alkali metal hydroxide; and (c) in a third stage, adding (A), to said fiber material, a liquid which is rich in hemicellulose, said liquid preferably comprising at least a part (14a, 514a) of said withdrawn spent impregnation liquid. In a fourth stage (d), the fiber material is cooked in a cooking liquor comprising the liquid added in the third stage, whereby the fiber material is subjected to a retention time of at least 1 hour in said fourth stage.
    Type: Grant
    Filed: August 24, 1998
    Date of Patent: October 22, 2002
    Assignee: Kvaerner Pulping AB
    Inventors: Vidar Martin Snekkenes, Krister Karl Erik Olsson, Bror Lennart Gustavsson, Ernst Mikael Lindström
  • Patent number: 6458242
    Abstract: Processes are disclosed for bleaching pulp with ozone in an environmentally friendly bleaching plant. The processes include removing a first filtrate from the pulp, bleaching the treated pulp with ozone, washing the bleached pulp with a washing liquid to provide a washed bleached pulp and a second filtrate including oxalic acid, recycling the second filtrate to the pulp prior to the bleaching step, and transferring the first filtrate to the bleached pulp.
    Type: Grant
    Filed: March 8, 2001
    Date of Patent: October 1, 2002
    Assignee: Valmet Fibertech Aktiebolag
    Inventor: Monica Bokström
  • Publication number: 20020026990
    Abstract: Chemical cellulose pulp is made from sawdust utilizing a static down-flow retention vessel. By adding steam and cooking liquor to a flow of sawdust a heated slurry, at a cooking temperature of about 250-350° F., is produced. The heated slurry is, at superatmospheric pressure, moved downwardly in the static down-flow retention vessel while cooking temperature is maintained, for a time period of about 0.5-6 (preferably 1 to 3) hours, the slurry having a consistency of about 5-30%. At superatmospheric pressure, without significant reduction in pressure from the retention vessel, the slurry is cooled to well below cooking temperature by diffusing cooling liquid through it, as in a conventional pressure diffuser. The discharge from the retention vessel is preferably substantially solely gravity action (e.g. using a discharge with single convergence and side relief).
    Type: Application
    Filed: October 19, 2001
    Publication date: March 7, 2002
    Applicant: ANDRITZ-AHLSTROM INC.
    Inventors: Jay J. Miele, Marco Marois, R. Fred Chasse, J. Wayne Chamblee, John D. Weston, J. Robert Prough
  • Patent number: 6315862
    Abstract: A process for bleaching pulp, in which, after fiber liberation, a first filtrate containing metals, principally in ionic form, is separated off from the pulp, and supplied downstream to the pulp flow after a bleaching stage.
    Type: Grant
    Filed: March 15, 1995
    Date of Patent: November 13, 2001
    Assignee: Kvaerner Pulping Technologies
    Inventors: Anders Bergovist, Hakan Dahllof
  • Patent number: 6315863
    Abstract: Collection of a post-chlorination washer filtrate and recycle thereof to acidify a wood pulp stream entering the initial chlorine dioxide bleaching stage is provided in order to reduce the formation of barium scale.
    Type: Grant
    Filed: June 18, 1998
    Date of Patent: November 13, 2001
    Assignee: Weyerhaeuser Company
    Inventor: David B. Jack
  • Patent number: 6210527
    Abstract: A method for producing bleached wood pulp in which wood chips are digested in polysulfide liquor to produce brown stock pulp. The brown stock pulp is washed to produce washed brown stock wood pulp and weak black liquor and the washed wood pulp is then delignified in an oxygen delignification stage to produce oxygen delignified wood pulp. The delignified wood pulp is then ozone bleached in an ozone bleaching stage in which a waste stream principally containing ozone, carbon dioxide and oxygen is produced. The ozone-bleached pulp is introduced into an extractive oxidation stage which can include peroxide to further bleach the pulp and the product of the extractive oxidation stage is then either introduced into either a peroxide or chlorine dioxide bleaching stage.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: April 3, 2001
    Assignee: The BOC Group, Inc.
    Inventors: Mark J. Kirschner, Rustam H. Sethna
  • Patent number: 6103058
    Abstract: This invention relates to a new and improved way of continuously cooking fiber material in an over loaded digester, wherein temperatures and alkaline levels are controlled to be maintained within specific levels in different zones of the digesting process in order to optimize chemical consumption and heat economy and, at the same time, to achieve very good pulp properties.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: August 15, 2000
    Assignee: Kvaerner Pulping AB
    Inventor: Johan Engstrom
  • Patent number: 5980689
    Abstract: Methods for separating metal ions from pulp material are disclosed including treating the pulp with a chelating agent to produce a pulp flow with dissolved metal ions, washing that pulp flow prior to bleaching with hydrogen peroxide or ozone and mixing the washed liquid containing metal ions with another flow of lignocellulose-containing material in order to bind the metal ions to that flow, washing that flow, and subsequently washing that flow at a reduced pH to produce a wash flow containing metal ions.
    Type: Grant
    Filed: April 11, 1996
    Date of Patent: November 9, 1999
    Assignee: Sunds Defibrator Industries AB
    Inventor: Ulf Germg.ang.rd
  • Patent number: 5688367
    Abstract: A method and installation for bleaching a lignocellulosic pulp with ozone, while recovering an oxygen-rich gas which may be recycled or re-used. Bleaching of the pulp with ozone is preferably carried out under conditions in which ingress of air is prevented. In a multi-step bleaching process, an oxygen-rich vent gas typically containing at least 90%, by weight, of oxygen may be recovered from a second contactor for potential use in different oxygen-consuming operations in a pulp mill.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: November 18, 1997
    Assignee: Canadian Liquid Air/Air Liquide Canada LTEE
    Inventors: Derek Hornsey, Gordon H. Homer, John R. Ayton
  • Patent number: 5643410
    Abstract: Methods for discharging spent cooking liquors from a batch digester containing cooked lignocellulose-containing material in spent cooking liquor are disclosed, including supplying a first portion of washing liquid to the digester to displace a first portion of the spent cooking liquor at a temperature and dry solids content which substantially corresponds to the temperature and dry solids content of the spent cooking liquor at the end of the batch digestion, supplying a second portion of washing liquid to the digester to displace a second portion of the spent cooking liquor having a temperature and dry solids content substantially lower than that of the spent cooking liquor in the digester, and maintaining the first and second portions of spent cooking liquor separate from each other. Methods of producing kraft pulp in batch digesting processes using this method are also disclosed.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: July 1, 1997
    Assignee: Sunds Defibrator Rauma Oy
    Inventors: Seppo T. Hiljanen, Panu O. Tikka
  • Patent number: 5587049
    Abstract: A process for delignifying raw cellulose which comprises a preliminary treatment for impregnating raw cellulose with a monopersulphuric acid solution, a successive filtration without washing with recycle of the filtered liquid to the first step, and a treatment, at low temperature and in alkaline solution at a pH higher than 9, of the previously impregnated raw cellulose in order to permit the reaction of the monopersulphuric acid with the lignin contained in the raw cellulose.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: December 24, 1996
    Assignee: Ausimont S.p.A.
    Inventors: Fausto Marzolini, Giulio Calmanti, Gianpiero Sacchi
  • Patent number: 5525195
    Abstract: Unbleached pulp is washed with an aqueous alkaline solution in a wash press to substantially uniformly distribute a first amount of alkaline material throughout the pulp. The consistency of the pulp exiting the wash press is above about 18%, preferably between 25 to 35 percent by weight, and the high consistency alkali containing pulp is then treated with oxygen to effect delignification. The use of a wash press reduces the overall amounts of alkaline material utilized in the process compared to processes which add alkaline material to the pulp at low consistency. Additional alkali may be applied, if desired, onto the high consistency pulp prior to oxygen delignification to provide a total amount of between 0.8 and 7 percent by weight of oven dry pulp. High strength, low lignin pulps are formed after oxygen delignification which may be further bleached to high brightness with reduced amounts of bleaching chemicals.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: June 11, 1996
    Assignee: Union Camp Patent Holding, Inc.
    Inventors: William H. Friend, Stuart T. Terrett, Spencer W. Eachus, Bruce F. Griggs
  • Patent number: 5462641
    Abstract: A process for bleaching pulp, in which, after fiber liberation, a first filtrate containing metals, principally in ionic form, is separated off from the pulp, and supplied downstream to the pulp flow after a bleaching stage.
    Type: Grant
    Filed: July 7, 1993
    Date of Patent: October 31, 1995
    Assignee: Kamyr Atkiebolag
    Inventors: Anders Bergvist, Hakan Dahllof
  • Patent number: 5460696
    Abstract: An oxygen delignification method and apparatus in which a charge of heated wood pulp is reacted with oxygen in the presence of a charge of caustic soda in a plurality of reaction stages located between mixing stages in which caustic is mixed with the wood pulp. The use of the plurality of mixing stages reduces peak pH exposure of the wood pulp that would otherwise occur if the charges of caustic and wood pulp were mixed all at once. Moreover, the caustic mixed in such manner replenishes neutralized caustic and ensures that the average pH level is increased above that in conventional oxygen delignification. The increase in average pH level favors an increase in the delignification. Filtrate from a washing stage is introduced into the mixing stages to prevent wood pulp degradation.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: October 24, 1995
    Assignee: The BOC Group, Inc.
    Inventors: Mark J. Kirschner, Rustam H. Sethna
  • Patent number: 5415734
    Abstract: A process is disclosed for bleaching pulp without chlorine containing chemicals and for greatly reducing total washing filtrate discharge, comprising the steps of: 1) sending pulp that has been subjected to continuous digestion, oxygen-delignification and then washing, through a washing press; 2) treating, with agitation, the delignified washed pulp with sulfuric acid and a chelating agent; 3) washing the pulp in a washing apparatus; 4) bleaching with hydrogen peroxide in a reaction vessel; 5) washing the hydrogen peroxide bleached pulp; 6) adding sulfuric acid and ozone with mixing of the pulp; 7) reacting the pulp with ozone in a reaction vessel; and 8) washing the ozone reacted pulp, wherein the majority of liquid filtrate from the bleaching process that is waste not to be recycled is drawn off from the washing apparatus of step 3, the washings in step 3 and 5 have at least 85% efficiency, filtrate from washing step 5 is recirculated to the washing apparatus of step 3, and filtrate from the washing apparat
    Type: Grant
    Filed: May 11, 1993
    Date of Patent: May 16, 1995
    Assignee: Kvaerner Pulping Technologies AB
    Inventors: Ake Backlund, Stig Andtbacka, Bjorn Dillner
  • Patent number: 5409570
    Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine or chlorine-containing compounds by oxygen delignifying the pulp to a K No. of about 14 or less and a viscosity of greater than about 10 cps and thereafter further delignifying the partially delignified pulp by lifting, displacing and tossing the pulp in a radial direction while advancing it in an axial direction in a plug flow-like manner with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 6 or less, a viscosity of at least about 7 cps and a GE brightness of at least about 35. The substantially delignified pulp may then be brightened to a final product having a GE brightness of at least about 75, or alternately up to about 83 or more by contacting the ozonated pulp with chlorine dioxide or a peroxide compound.
    Type: Grant
    Filed: November 25, 1992
    Date of Patent: April 25, 1995
    Assignee: Union Camp Patent Holding, Inc.
    Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen, Stuart T. Terrett, Spencer W. Eachus, David E. White, William H. Friend, Omar F. Ali
  • Patent number: 5296097
    Abstract: A process for conditioning an ozone gas recycle stream in an ozone pulp bleaching process, wherein the level of carbon dioxide in the recycle stream is controlled to allow full capacity operation of the ozone generator. Carbon dioxide concentration is identified over the relevant operational ranges and maximum concentration is identified for full capacity/optimum efficiency operation. Specific methods are described for controlling carbon dioxide concentration including purging a portion of the recycle stream, counter-current scrubbing of the recycle stream with an alkaline solution and passing the recycle stream through an adsorbent material. Contaminants entering the system also may be reduced by directing the purged recycle stream, which is relatively oxygen rich, into the dewatering press where pulp consistency is increased. In this manner nitrogen surrounding the pulp is displaced by oxygen and thus, does not enter the bleaching/ozone system with the pulp.
    Type: Grant
    Filed: September 14, 1992
    Date of Patent: March 22, 1994
    Assignee: Union Camp Holding, Inc.
    Inventor: William H. Friend
  • Patent number: 5277760
    Abstract: Process for producing pulp suitable as raw material for paper, board or fiberboards and similar products. A pumpable alkaline slurry of fibrous raw material is conducted through a pressurized tube system by the use of pulp pumps, the pressure increasing in steps from the beginning of the process to the end of the process. On its way the slurry is repeatedly dewatered and rediluted with process liquid. An apparatus suitable for being used in carrying out the process comprises a dewatering tube (64) and a dewatering and venting tube (67) arranged centrally and axially within the tube (64) which may be provided with a perforated part (66). The tube (67) is provided with perforations (68) through which gas and liquid from fiber-containing slurry introduced into the outer tube (64) can escape. At the opposite end from the inlet end of the outer tube (64) there is an outlet (72, 65) for thickened fiber-containing slurry.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: January 11, 1994
    Inventor: Sigurd Fongen
  • Patent number: 5236553
    Abstract: In the continuous cooking of comminuted cellulosic fibrous material (e.g. wood chips) to produce paper pulp, the material passes upwardly in an impregnation vessel which is within and concentric with a continuous digester and open at the top to digester pressure. At the top of the impregnation vessel, a solids/liquid separator (a screw within a screen cylinder) is provided. Separated liquid is returned in a conduit adjacent the exterior of the impregnation vessel, and open at the top to digester pressure, and passes out the bottom of the digester. The impregnation vessel is welded to the bottom of the digester, and the bottom of the digester is generally hemi-spherical, and substantially devoid of packings.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: August 17, 1993
    Assignee: Kamyr AB
    Inventor: Johan C. F. C. Richter
  • Patent number: 5217574
    Abstract: Unbleached pulp is combined with an aqueous alkaline solution while in a state of low consistency to distribute a first amount of alkaline material substantially uniformly throughout the pulp. The consistency of the pulp is then increased to above about 18%, and the high consistency alkali containing pulp is then treated with oxygen to effect delignification. The total amount of alkaline material applied to the pulp is between 0.8 and 7% by weight of oven dry pulp. High strength, low lignin pulps are subsequently formed which may be further bleached to high brightness with reduced amounts of chemicals.
    Type: Grant
    Filed: April 16, 1991
    Date of Patent: June 8, 1993
    Assignee: Union Camp Patent Holdings Inc.
    Inventor: Bruce F. Griggs
  • Patent number: 5211811
    Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine by partially delignifying the pulp to a K No. of about 10 or less and a viscosity of greater than about 13 cps; and further delignifying the partially delignified pulp with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 5 or less, a viscosity of greater than about 10, and a GE brightness of at least about 50%. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65%, preferably above 70% to as high as 90%. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: May 18, 1993
    Assignee: Union Camp Patent Holding, Inc.
    Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen
  • Patent number: 5188708
    Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine by partially delignifying the pulp to a K No. of about 10 or less and a viscosity of greater than about 13 cps; and further delignifying the partially delignified pulp with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 5 or less, a viscosity of greater than about 10, and a GE brightness of at least about 50%. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65%, preferably above 70% to as high as 90%. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: February 23, 1993
    Assignee: Union Camp Patent Holding, Inc.
    Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen
  • Patent number: 5183535
    Abstract: Processes for prepariing kraft pulp are disclosed. The processes include pretreating cellulosic material or chips with spent cooking liquor at the temperature of about 20.degree. to 100.degree. C., followed by heating the impregnated chips at the temperature of from about 120.degree. to 180.degree. C., followed by digestion of the lignin with white liquor, which is facilitated by using this pretreatment process.
    Type: Grant
    Filed: November 19, 1991
    Date of Patent: February 2, 1993
    Assignee: Sunds Defibrator Rauma Oy
    Inventor: Panu Tikka
  • Patent number: 5173153
    Abstract: Unbleached pulp is combined with an aqueous alkaline solution while in a state of low consistency to distribute a first amount of alkaline material substantially uniformly throughout the pulp. The consistency of the pulp is then increased to above about 20%. Additional alkali is applied onto the high consistency pulp to provide a total amount of between 0.8 and 7% by weight of oven dry pulp. The high consistency alkali containing pulp is then treated with oxygen to effect delignification. High strength, low lignin pulps are formed which may be further bleached to high brightness with reduced amounts of chemicals by following the methods of the invention.
    Type: Grant
    Filed: January 3, 1991
    Date of Patent: December 22, 1992
    Assignee: Union Camp Patent Holding, Inc.
    Inventors: Stuart T. Terrett, Spencer W. Eachus, Bruce F. Griggs
  • Patent number: 5145557
    Abstract: A three-stage bleaching process for dissolving grade pulp utilizes the sequence OP(alkaline)-Z-P and the off gas from the Z-stage is delivered to the alkaline (OP)-stage whose parameters are controlled to fully react all of the oxygen of the off gas. The filtrate or waste water from the Z-stage, at a pH below 3, serves to dilute the alkaline OP-stage pulp before Z-stage bleaching and/or for de-ashing of the P pulp following the P-stage.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: September 8, 1992
    Assignee: Lenzing Aktiengesellschaft
    Inventors: Walter Peter, Anton Hruschka, Oskar Hoglinger
  • Patent number: 5143580
    Abstract: A process for delignification and bleaching of chemically digested lignocellulose-containing pulp for reduced formation and discharge of halogenated organic compounds, while preserving the pulp quality, where the prebleaching with halogen-containing bleaching agent is replaced by a treatment, in a first step, with the addition of a complexing agent at elevated temperature and at a pH from 3.1 to 9.0, and in a second step, by using a peroxide-containing compound under alkaline conditions, whereupon spent liquor from the final bleaching with halogen-containing compounds is recycled to the first or second step of the halogen-free prebleaching.
    Type: Grant
    Filed: April 23, 1991
    Date of Patent: September 1, 1992
    Assignee: Eka Nobel AB
    Inventors: Jiri J. Basta, Lillemor K. Holtinger, Marie R. Samuelsson, Per G. Lundgren
  • Patent number: 5118389
    Abstract: A continuous two-stage peroxide bleaching process operated in a single bleach plant for producing a bleached pulp of high brightness, having a second stage bleaching step using a high charge of peroxide followed by a washing stage to recover the residual liquor containing a substantial amount of the applied peroxide. The residual liquor is recycled and used for bleaching in the first stage. Only a portion of the pulp bleached in the first stage is treated in the second stage. Two or more bleached pulp products can be produced simultaneously. The bleached pulp products can be used to form different layers of a multi-layer paper products.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: June 2, 1992
    Assignee: ICI Canada Inc.
    Inventors: Paul Dubelsten, Christopher J. Kanters, John R. Du Manoir
  • Patent number: 5089086
    Abstract: The invention relates to a process for continuous cooking of cellulose. In the process, wood chips (11) are impregnated (1) with cooking lye (10), after which the wood chips impregnated with cooking lye is mixed (27) with spent liquor (18) in order to transfer (12) it into the upper portion of a pressurized digester (2). The transfer liquor used for the transfer of the wood chips in the preceding step is separated (26) from the impregnated wood chips in the upper portion of the digester (2) and is recycled (13,14) to the preceding step. After this, the chips are conducted from the digester (2) downwards into the cooking zone (24) and from there on to the washing zone (24), whereby a mixture of spent lye and wash lye, i.e. spent liquor (18) is removed from between the cooking and washing zones (19) and a portion (21) of the liquor removed from the digester (2) is expansion evaporized (5,6) in order to recover heat in the form of steam (22,23).
    Type: Grant
    Filed: April 25, 1990
    Date of Patent: February 18, 1992
    Assignee: Jaakko Poyry Oy
    Inventor: Risto Silander