Without Treatment Or Modification Patents (Class 162/40)
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Patent number: 10570542Abstract: An apparatus and method for pre-shrinking a wet fabric prior to drying. The apparatus includes, among other components, a balloon extractor station and a hydro-sizer compression station. The balloon extractor station removes some water from the wet fabric. The hydro-sizer compression station is operatively connected to, and disposed downstream of, the balloon extractor station, and compresses the wet fabric in a lengthwise direction, and in so doing, pre-shrinks the wet fabric prior to drying. The method includes, among other steps, extracting some water from the wet fabric so as to faun a hydro-extracted and wet fabric, compressing lengthwise the hydro-extracted and wet fabric so as to form a compacted and wet fabric that is now pre-shrunk prior to drying, and drying the compacted and wet fabric so as to form a compacted and dry fabric.Type: GrantFiled: January 13, 2016Date of Patent: February 25, 2020Inventor: Teresa Catallo
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Publication number: 20140246158Abstract: A reactor vessel system including: a first reactor vessel having a hydrolysate and liquid extraction screen, a first region above the extraction screen that is maintained at conditions promoting a hydrolysis reaction in the cellulosic material, a second region below the extraction screen in which the hydrolysis is substantially suppressed and a wash liquid inlet below the extraction screen providing wash liquid at a temperature below a hydrolysis temperature; a transport pipe having an inlet coupled to the first reactor vessel and an outlet coupled to a second reactor vessel, and the second reactor vessel includes a liquid discharge that extracts a portion of liquid from the second reactor vessel and directs the portion of liquid to the first reactor vessel or to the transport pipe.Type: ApplicationFiled: May 15, 2014Publication date: September 4, 2014Applicant: Andritz Inc.Inventors: Namhee Shin, Bertil Stromberg, Ventzislav H. Kirov, William J. Cann
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Publication number: 20140174679Abstract: A process for making bleached pulp comprises contacting an unbleached pulp mixture with a first recycled filtrate obtained from a first location (3) of a first recycled filtrate loop, to obtain a first pulp mixture having a first consistency; bleaching the first pulp mixture, to obtain a first bleached pulp mixture; pressing or dewatering the first bleached pulp mixture, to obtain a first pressed bleached pulp mixture and a second filtrate; sending at least a portion of the second filtrate to a second location (5) of the first recycled filtrate loop, wherein the second location (5) is downstream of and in fluid communication with the first location (3); contacting the first pressed bleached pulp mixture with a second recycled filtrate obtained from a third location (6) of the first recycled filtrate loop, to obtain a second pulp mixture having a second consistency, wherein the second consistency is greater than the first consistency, and wherein the third location (6) is downstream of and in fluid communicatiType: ApplicationFiled: February 28, 2014Publication date: June 26, 2014Applicant: INTERNATIONAL PAPER COMPANYInventor: CAIFANG F. YIN
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Publication number: 20140166221Abstract: A method of hydrothermal hydrocatalytic treating biomass is provided. Lignocellulosic biomass solids is provided to a hydrothermal digestion unit in the presence of a digestive solvent, at least one of ammonia or a source of ammonia, and a supported hydrogenolysis catalyst containing (a) sulfur, (b) Mo or W, and (c) Co, Ni or mixture thereof, incorporated into a suitable support. The lignocellulosic biomass solids and digestive solvent are heated in the presence of hydrogen, supported hydrogenolysis catalyst and the at least one of ammonia or a source of ammonia forming a product solution containing plurality of oxygenated hydrocarbons and ammonia. At least a portion of ammonia is separated and recycled to the hydrothermal digestion unit.Type: ApplicationFiled: December 19, 2013Publication date: June 19, 2014Applicant: Shell Oil CompanyInventors: Joseph Broun POWELL, Glenn Charles KOMPLIN, John Anthony SMEGAL, Kimberly Ann JOHNSON
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Publication number: 20130299104Abstract: A screen structure which is unusually effective at removing stickies from recyclable fiber but is tolerant of substantial swings in throughput which result in variations in the flow velocity through the screen—slot velocity. One example of the screen structure is created by forming a very large number of similarly shaped vanes then locking them into a ring structure to form a cylindrical screen basket but equivalent surface configurations can also be formed into sheet stock.Type: ApplicationFiled: July 17, 2013Publication date: November 14, 2013Inventors: Wayne F. Winkler, Bradley E. Lucas
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Patent number: 8545673Abstract: Process for recovering molybdate or tungstate from an aqueous solution, in which molybdate or tungstate is bound to a water-insoluble, cationized inorganic carrier material from the aqueous solution at a pH in the range from 2 to 6, the laden carrier material is separated off and the bound molybdate or tungstate is liberated once again into aqueous solution at a pH in the range from 6 to 14. The process is suitable for recovering molybdate or tungstate in the delignification of pulp with hydrogen peroxide in the presence of molybdate or tungstate as catalyst. The recovered molybdate or tungstate can be recycled to the delignification.Type: GrantFiled: August 14, 2012Date of Patent: October 1, 2013Assignee: Evonik Degussa GmbHInventors: Thomas Dietz, Hans Ulrich Süss
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Publication number: 20120305208Abstract: Process for recovering molybdate or tungstate from an aqueous solution, in which molybdate or tungstate is bound to a water-insoluble, cationized inorganic carrier material from the aqueous solution at a pH in the range from 2 to 6, the laden carrier material is separated off and the bound molybdate or tungstate is liberated once again into aqueous solution at a pH in the range from 6 to 14. The process is suitable for recovering molybdate or tungstate in the delignification of pulp with hydrogen peroxide in the presence of molybdate or tungstate as catalyst. The recovered molybdate or tungstate can be recycled to the delignification.Type: ApplicationFiled: August 14, 2012Publication date: December 6, 2012Applicant: Evonik Degussa GmbHInventors: Thomas Dietz, Hans Ulrich Süss
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Publication number: 20120237989Abstract: A method for the production water insoluble reactive lignin having low sulfur content and lignosulfonates from lignocellulosic material in a batch or continuous process. Lignocellulosic material is fractionated to produce water insoluble native lignin and lignosulfonates in various ratios, while preserving the cellulose and hydrolyzed hemicelluloses using water, ethanol and sulfur dioxide.Type: ApplicationFiled: September 19, 2008Publication date: September 20, 2012Applicant: API Intellectual Property Holdings, LLCInventors: Theodora Retsina, Vesa Pylkkanen
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Publication number: 20120097350Abstract: A processes producing mechanical pulps utilizing refiners for improving the quality of screen rejects, and most particularly to a mechanical pulp mill integrated with a neutral-alkaline papermaking process producing mechanical printing paper grades is disclosed. The rejects are treated with hydrogen peroxide, an alkali and an organic stabilizing agent just prior to or during refining to provide improved optical and physical properties of the refined rejects and more efficiently utilize electrical energy to reach target fiber quality after bleaching for cost-effectively producing a wide array of coated and uncoated mechanical printing papers.Type: ApplicationFiled: June 9, 2010Publication date: April 26, 2012Applicant: Arkema Inc.Inventors: Stanley A. Heimburger, Melford R. Lougheed
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Publication number: 20110232853Abstract: A process for making bleached pulp comprises contacting an unbleached pulp mixture with a first recycled filtrate obtained from a first location (3) of a first recycled filtrate loop, to obtain a first pulp mixture having a first consistency; bleaching the first pulp mixture, to obtain a first bleached pulp mixture; pressing or dewatering the first bleached pulp mixture, to obtain a first pressed bleached pulp mixture and a second filtrate; sending at least a portion of the second filtrate to a second location (5) of the first recycled filtrate loop, wherein the second location (5) is downstream of and in fluid communication with the first location (3); contacting the first pressed bleached pulp mixture with a second recycled filtrate obtained from a third location (6) of the first recycled filtrate loop, to obtain a second pulp mixture having a second consistency, wherein the second consistency is greater than the first consistency, and wherein the third location (6) is downstream of and in fluid communicatiType: ApplicationFiled: March 18, 2011Publication date: September 29, 2011Applicant: INTERNATIONAL PAPER COMPANYInventor: CAIFANG F. YIN
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Patent number: 7604711Abstract: Method and apparatus for batch displacement digester systems to increase tank farm vessel temperatures for more efficient delignification rates by mitigating the formation of flow channels in the chip bed, minimizing the vertical temperature gradient in the digester and segregation of returning liquors to the tank farm from the digester.Type: GrantFiled: March 7, 2006Date of Patent: October 20, 2009Inventor: Craig A. Bianchini
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Publication number: 20090020245Abstract: It consists in performing a security paper or special paper incorporating pigments within the paste of the synthetic element itself during its manufacture, providing pigment properties to said synthetic element, the pigments being protected from the attack of physical and chemical agents by the synthetic element itself.Type: ApplicationFiled: April 6, 2005Publication date: January 22, 2009Inventors: Vicente Garcia Juez, Javier Baraja Carracedo
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Patent number: 7241363Abstract: One aspect of this invention relates to a method and digester for reducing the deposition of calcium-based scale in a wood chip digester including extraction from the digester of first and second quantities of cooking liquor having respective first and second calcium concentrations, treating the extracted cooking liquors to produce a cooking liquor having a calcium concentration less that the calcium concentration of the either of the first and second extracted cooking liquors, and, reintroducing the treated cooking liquor to the digester. Another aspect of this invention relates to a method and digester in which through put through the digester is increased by the continuous addition of process liquor into the digester preferably at an upper region of the digester.Type: GrantFiled: June 26, 2004Date of Patent: July 10, 2007Assignee: International Paper CompanyInventors: Jianer Jiang, Gerald Wayne Hill
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Patent number: 7112256Abstract: A method for the continuous cooking of chemical pulp with the aim of achieving improved heat economy in a digester system having a vessel (1) for impregnation and a vessel (2) for cooking the impregnated cellulose chips. A part of the black liquor (14) withdrawn from the digester (2) is added at the beginning of a transfer system (4) to increase the temperature of the chips mixture in the transfer system (4). A fraction of the transport fluid (10) from the transfer system (4) that is continuously withdrawn from the impregnated chips fed into the top of the digester is returned to the impregnation vessel (1) at essentially the maintained transfer temperature.Type: GrantFiled: January 22, 2003Date of Patent: September 26, 2006Assignee: Kvaerner Pulping ABInventors: Vidar Snekkenes, Lennart Gustavsson
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Patent number: 6939439Abstract: Methods for producing chemical pulp from lignocellulose-containing material in processes for kraft pulp production are disclosed including charging the lignocellulose-containing material to a digester, initially treating the lignocellulose-containing material with an impregnation liquor, and then treating the impregnated lignocellulose-containing material with hot liquor and displacing calcium-containing spent liquor from the digester during that treatment, heating and cooking the heated lignocellulose-containing material to produce cooked lignocellulose-containing material and cooking liquor and displacing the cooking liquor from the digester using at least a portion of the displaced calcium-containing spent liquor.Type: GrantFiled: October 4, 2000Date of Patent: September 6, 2005Assignee: Metso Chemical Pulping OyInventors: Asko Paakki, Päivi Uusitalo, Mikael Svedman
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Publication number: 20040099386Abstract: Separation of dissolved and colloidal high molecular weight organic by-products from liquors or filtrates in a cellulosic pulping process to improve the overall efficiency of the process.Type: ApplicationFiled: November 20, 2003Publication date: May 27, 2004Inventor: Craig A. Bianchini
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Publication number: 20040060672Abstract: A method for the continuous cooling of chemical pulp with the aim of achieving improved heat economy in a digester system comprising a vessel (1) for impregnation and a vessel (2) for cooking the impregnated cellulose chips. A part of the black liquor (14) withdrawn from the digester (2) is added at the beginning of a transfer system (4) having maintained essentially the withdrawl temperature, increasing the temperature of the chips mixture in the transfer system (4). A fraction of the transport fluid (10) from the transfer system (4) that is continuously withdrawn from the impregnated chips fed into the top of the digester is returned to the impregnation vessel (1) at essentially maintained transfer temperature, at a location before the said transfer system (4), seen from the point of view of the direction of flow of the chips.Type: ApplicationFiled: October 22, 2003Publication date: April 1, 2004Inventors: Vidar Snekkenes, Lennart Gustavsson
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Patent number: 6699357Abstract: The invention relates to a process for continuous cooking of wood chips at elevated pressure and temperature in a vertical digester (1) for production of chemically dissolved pulp. Fiber material and cooking liquor are introduced at the top of the digester and pulp is discharged from the bottom of the digester (1), via a line (8) in which the pulp is maintained at substantially the same pressure level, to a pressurized wash (7). More than 50% of the used cooking liquor (black liquor) which is extracted from the system in total is extracted from the wash filtrate of the pressurized wash. The pressurized wash is regulated so that a high temperature is maintained in the wash filtrate. The extraction is regulated so that a net co-current flow is established at the bottom of the digester.Type: GrantFiled: September 28, 2001Date of Patent: March 2, 2004Assignee: Kvaerner Pulping ABInventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
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Publication number: 20030209335Abstract: A method is disclosed for extracting liquor from a cellulose slurry for a continuous digester comprising the steps of: providing the cellulose slurry of liquor and chips of cellulose fiber material to a separator; extracting a first stream of liquor from the separator; extracting a second stream of liquor from the separator, where the second stream has an effective alkali (EA) concentration greater than the EA concentration of the first steam; outputting the first stream from the separator and outputting the second stream from the separator separately from the second stream, and outputting a condensed slurry from the separator to a digester vessel.Type: ApplicationFiled: May 21, 2003Publication date: November 13, 2003Applicant: Andritz Inc.Inventors: Kaj O. Henricson, C. Bertil Stromberg, Richard Laakso, John F. Bolles, Keith P. Vogel, Patrick J. Sullivan
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Publication number: 20030205343Abstract: A continuous pulp digester having an elongate horizontally aligned pressure vessel through which the wood chips and digesting fluid flow in a forward direction. In a first and second embodiments within the pressure vessel there is an inner container defining an elongate chamber or passageway having a square cross sectional configuration. In a third embodiment the digesting chamber is cylindrical. At locations along the digester, there are several pair of liquid flow inlets and liquid flow outlets which enable filtrate from a pulp washer and a digesting agent to be moved into and across the digesting chamber to flow out the flow outlets. These are recirculated in a net upstream flow pattern toward the outlet end of the digester, and discharged as black liquor at different locations in the digester.Type: ApplicationFiled: April 18, 2003Publication date: November 6, 2003Inventor: Reijo K. Salminen
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Publication number: 20030178163Abstract: A method of bleaching chemical pulp, comprising two bleaching stages (D0 and, respectively, D1) with chlorine dioxide as dominating bleaching chemical and at least one intermediate alkaline bleaching stage (E). The ingoing pulp is dewatered to a concentration of 25-40% before the first chlorine dioxide stage (D0) and to 10-40% after the second chlorine dioxide stage (D1). Filtrate from the dewatering after the second chlorine dioxide stage (D1) is re-cycled and utilized for controlling the pulp concentration to 8-15% of the dewatered pulp to the first chlorine dioxide stage (D0).Type: ApplicationFiled: February 12, 2003Publication date: September 25, 2003Inventors: Lars-Ake Lindstrom, Solveig Norden, Gunnar Carre
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Patent number: 6605180Abstract: Fiber material and cooking liquor are introduced at the top of the digester and pulp is discharged from the bottom of the digester, via a line in which the pulp is maintained at substantially the same pressure level, to a pressurized wash. More than 50% of the used cooking liquor (black liquor) which is extracted from the system in total is extracted from the wash filtrate of the pressurized wash. At the same time a small portion of the wash filtrate is also to be recirculated to the bottom of the digester as dilution liquid. The pressurized wash is regulated so that a high temperature is maintained in the wash filtrate. The extraction is regulated so that a net co-current flow is established at the bottom of the digester.Type: GrantFiled: September 28, 2001Date of Patent: August 12, 2003Inventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
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Patent number: 6468390Abstract: A method for continuous cooking of lignocellulosic fiber material, comprising the steps of sequentially (a) in a first stage, impregnating the fiber material in an impregnation liquid comprising alkali metal hydroxide, and thereafter withdrawing (14, 514) a spent impregnation liquid; (b) in a second stage, cooking the fiber material in a cooking liquor comprising alkali metal hydroxide; and (c) in a third stage, adding (A), to said fiber material, a liquid which is rich in hemicellulose, said liquid preferably comprising at least a part (14a, 514a) of said withdrawn spent impregnation liquid. In a fourth stage (d), the fiber material is cooked in a cooking liquor comprising the liquid added in the third stage, whereby the fiber material is subjected to a retention time of at least 1 hour in said fourth stage.Type: GrantFiled: August 24, 1998Date of Patent: October 22, 2002Assignee: Kvaerner Pulping ABInventors: Vidar Martin Snekkenes, Krister Karl Erik Olsson, Bror Lennart Gustavsson, Ernst Mikael Lindström
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Patent number: 6458242Abstract: Processes are disclosed for bleaching pulp with ozone in an environmentally friendly bleaching plant. The processes include removing a first filtrate from the pulp, bleaching the treated pulp with ozone, washing the bleached pulp with a washing liquid to provide a washed bleached pulp and a second filtrate including oxalic acid, recycling the second filtrate to the pulp prior to the bleaching step, and transferring the first filtrate to the bleached pulp.Type: GrantFiled: March 8, 2001Date of Patent: October 1, 2002Assignee: Valmet Fibertech AktiebolagInventor: Monica Bokström
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Publication number: 20020026990Abstract: Chemical cellulose pulp is made from sawdust utilizing a static down-flow retention vessel. By adding steam and cooking liquor to a flow of sawdust a heated slurry, at a cooking temperature of about 250-350° F., is produced. The heated slurry is, at superatmospheric pressure, moved downwardly in the static down-flow retention vessel while cooking temperature is maintained, for a time period of about 0.5-6 (preferably 1 to 3) hours, the slurry having a consistency of about 5-30%. At superatmospheric pressure, without significant reduction in pressure from the retention vessel, the slurry is cooled to well below cooking temperature by diffusing cooling liquid through it, as in a conventional pressure diffuser. The discharge from the retention vessel is preferably substantially solely gravity action (e.g. using a discharge with single convergence and side relief).Type: ApplicationFiled: October 19, 2001Publication date: March 7, 2002Applicant: ANDRITZ-AHLSTROM INC.Inventors: Jay J. Miele, Marco Marois, R. Fred Chasse, J. Wayne Chamblee, John D. Weston, J. Robert Prough
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Patent number: 6315862Abstract: A process for bleaching pulp, in which, after fiber liberation, a first filtrate containing metals, principally in ionic form, is separated off from the pulp, and supplied downstream to the pulp flow after a bleaching stage.Type: GrantFiled: March 15, 1995Date of Patent: November 13, 2001Assignee: Kvaerner Pulping TechnologiesInventors: Anders Bergovist, Hakan Dahllof
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Patent number: 6315863Abstract: Collection of a post-chlorination washer filtrate and recycle thereof to acidify a wood pulp stream entering the initial chlorine dioxide bleaching stage is provided in order to reduce the formation of barium scale.Type: GrantFiled: June 18, 1998Date of Patent: November 13, 2001Assignee: Weyerhaeuser CompanyInventor: David B. Jack
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Patent number: 6210527Abstract: A method for producing bleached wood pulp in which wood chips are digested in polysulfide liquor to produce brown stock pulp. The brown stock pulp is washed to produce washed brown stock wood pulp and weak black liquor and the washed wood pulp is then delignified in an oxygen delignification stage to produce oxygen delignified wood pulp. The delignified wood pulp is then ozone bleached in an ozone bleaching stage in which a waste stream principally containing ozone, carbon dioxide and oxygen is produced. The ozone-bleached pulp is introduced into an extractive oxidation stage which can include peroxide to further bleach the pulp and the product of the extractive oxidation stage is then either introduced into either a peroxide or chlorine dioxide bleaching stage.Type: GrantFiled: March 14, 1994Date of Patent: April 3, 2001Assignee: The BOC Group, Inc.Inventors: Mark J. Kirschner, Rustam H. Sethna
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Patent number: 6103058Abstract: This invention relates to a new and improved way of continuously cooking fiber material in an over loaded digester, wherein temperatures and alkaline levels are controlled to be maintained within specific levels in different zones of the digesting process in order to optimize chemical consumption and heat economy and, at the same time, to achieve very good pulp properties.Type: GrantFiled: April 16, 1998Date of Patent: August 15, 2000Assignee: Kvaerner Pulping ABInventor: Johan Engstrom
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Patent number: 5980689Abstract: Methods for separating metal ions from pulp material are disclosed including treating the pulp with a chelating agent to produce a pulp flow with dissolved metal ions, washing that pulp flow prior to bleaching with hydrogen peroxide or ozone and mixing the washed liquid containing metal ions with another flow of lignocellulose-containing material in order to bind the metal ions to that flow, washing that flow, and subsequently washing that flow at a reduced pH to produce a wash flow containing metal ions.Type: GrantFiled: April 11, 1996Date of Patent: November 9, 1999Assignee: Sunds Defibrator Industries ABInventor: Ulf Germg.ang.rd
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Patent number: 5688367Abstract: A method and installation for bleaching a lignocellulosic pulp with ozone, while recovering an oxygen-rich gas which may be recycled or re-used. Bleaching of the pulp with ozone is preferably carried out under conditions in which ingress of air is prevented. In a multi-step bleaching process, an oxygen-rich vent gas typically containing at least 90%, by weight, of oxygen may be recovered from a second contactor for potential use in different oxygen-consuming operations in a pulp mill.Type: GrantFiled: December 11, 1995Date of Patent: November 18, 1997Assignee: Canadian Liquid Air/Air Liquide Canada LTEEInventors: Derek Hornsey, Gordon H. Homer, John R. Ayton
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Patent number: 5643410Abstract: Methods for discharging spent cooking liquors from a batch digester containing cooked lignocellulose-containing material in spent cooking liquor are disclosed, including supplying a first portion of washing liquid to the digester to displace a first portion of the spent cooking liquor at a temperature and dry solids content which substantially corresponds to the temperature and dry solids content of the spent cooking liquor at the end of the batch digestion, supplying a second portion of washing liquid to the digester to displace a second portion of the spent cooking liquor having a temperature and dry solids content substantially lower than that of the spent cooking liquor in the digester, and maintaining the first and second portions of spent cooking liquor separate from each other. Methods of producing kraft pulp in batch digesting processes using this method are also disclosed.Type: GrantFiled: December 28, 1992Date of Patent: July 1, 1997Assignee: Sunds Defibrator Rauma OyInventors: Seppo T. Hiljanen, Panu O. Tikka
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Patent number: 5587049Abstract: A process for delignifying raw cellulose which comprises a preliminary treatment for impregnating raw cellulose with a monopersulphuric acid solution, a successive filtration without washing with recycle of the filtered liquid to the first step, and a treatment, at low temperature and in alkaline solution at a pH higher than 9, of the previously impregnated raw cellulose in order to permit the reaction of the monopersulphuric acid with the lignin contained in the raw cellulose.Type: GrantFiled: April 8, 1994Date of Patent: December 24, 1996Assignee: Ausimont S.p.A.Inventors: Fausto Marzolini, Giulio Calmanti, Gianpiero Sacchi
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Patent number: 5525195Abstract: Unbleached pulp is washed with an aqueous alkaline solution in a wash press to substantially uniformly distribute a first amount of alkaline material throughout the pulp. The consistency of the pulp exiting the wash press is above about 18%, preferably between 25 to 35 percent by weight, and the high consistency alkali containing pulp is then treated with oxygen to effect delignification. The use of a wash press reduces the overall amounts of alkaline material utilized in the process compared to processes which add alkaline material to the pulp at low consistency. Additional alkali may be applied, if desired, onto the high consistency pulp prior to oxygen delignification to provide a total amount of between 0.8 and 7 percent by weight of oven dry pulp. High strength, low lignin pulps are formed after oxygen delignification which may be further bleached to high brightness with reduced amounts of bleaching chemicals.Type: GrantFiled: September 7, 1993Date of Patent: June 11, 1996Assignee: Union Camp Patent Holding, Inc.Inventors: William H. Friend, Stuart T. Terrett, Spencer W. Eachus, Bruce F. Griggs
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Patent number: 5462641Abstract: A process for bleaching pulp, in which, after fiber liberation, a first filtrate containing metals, principally in ionic form, is separated off from the pulp, and supplied downstream to the pulp flow after a bleaching stage.Type: GrantFiled: July 7, 1993Date of Patent: October 31, 1995Assignee: Kamyr AtkiebolagInventors: Anders Bergvist, Hakan Dahllof
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Patent number: 5460696Abstract: An oxygen delignification method and apparatus in which a charge of heated wood pulp is reacted with oxygen in the presence of a charge of caustic soda in a plurality of reaction stages located between mixing stages in which caustic is mixed with the wood pulp. The use of the plurality of mixing stages reduces peak pH exposure of the wood pulp that would otherwise occur if the charges of caustic and wood pulp were mixed all at once. Moreover, the caustic mixed in such manner replenishes neutralized caustic and ensures that the average pH level is increased above that in conventional oxygen delignification. The increase in average pH level favors an increase in the delignification. Filtrate from a washing stage is introduced into the mixing stages to prevent wood pulp degradation.Type: GrantFiled: August 12, 1993Date of Patent: October 24, 1995Assignee: The BOC Group, Inc.Inventors: Mark J. Kirschner, Rustam H. Sethna
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Patent number: 5415734Abstract: A process is disclosed for bleaching pulp without chlorine containing chemicals and for greatly reducing total washing filtrate discharge, comprising the steps of: 1) sending pulp that has been subjected to continuous digestion, oxygen-delignification and then washing, through a washing press; 2) treating, with agitation, the delignified washed pulp with sulfuric acid and a chelating agent; 3) washing the pulp in a washing apparatus; 4) bleaching with hydrogen peroxide in a reaction vessel; 5) washing the hydrogen peroxide bleached pulp; 6) adding sulfuric acid and ozone with mixing of the pulp; 7) reacting the pulp with ozone in a reaction vessel; and 8) washing the ozone reacted pulp, wherein the majority of liquid filtrate from the bleaching process that is waste not to be recycled is drawn off from the washing apparatus of step 3, the washings in step 3 and 5 have at least 85% efficiency, filtrate from washing step 5 is recirculated to the washing apparatus of step 3, and filtrate from the washing apparatType: GrantFiled: May 11, 1993Date of Patent: May 16, 1995Assignee: Kvaerner Pulping Technologies ABInventors: Ake Backlund, Stig Andtbacka, Bjorn Dillner
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Patent number: 5409570Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine or chlorine-containing compounds by oxygen delignifying the pulp to a K No. of about 14 or less and a viscosity of greater than about 10 cps and thereafter further delignifying the partially delignified pulp by lifting, displacing and tossing the pulp in a radial direction while advancing it in an axial direction in a plug flow-like manner with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 6 or less, a viscosity of at least about 7 cps and a GE brightness of at least about 35. The substantially delignified pulp may then be brightened to a final product having a GE brightness of at least about 75, or alternately up to about 83 or more by contacting the ozonated pulp with chlorine dioxide or a peroxide compound.Type: GrantFiled: November 25, 1992Date of Patent: April 25, 1995Assignee: Union Camp Patent Holding, Inc.Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen, Stuart T. Terrett, Spencer W. Eachus, David E. White, William H. Friend, Omar F. Ali
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Patent number: 5296097Abstract: A process for conditioning an ozone gas recycle stream in an ozone pulp bleaching process, wherein the level of carbon dioxide in the recycle stream is controlled to allow full capacity operation of the ozone generator. Carbon dioxide concentration is identified over the relevant operational ranges and maximum concentration is identified for full capacity/optimum efficiency operation. Specific methods are described for controlling carbon dioxide concentration including purging a portion of the recycle stream, counter-current scrubbing of the recycle stream with an alkaline solution and passing the recycle stream through an adsorbent material. Contaminants entering the system also may be reduced by directing the purged recycle stream, which is relatively oxygen rich, into the dewatering press where pulp consistency is increased. In this manner nitrogen surrounding the pulp is displaced by oxygen and thus, does not enter the bleaching/ozone system with the pulp.Type: GrantFiled: September 14, 1992Date of Patent: March 22, 1994Assignee: Union Camp Holding, Inc.Inventor: William H. Friend
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Patent number: 5277760Abstract: Process for producing pulp suitable as raw material for paper, board or fiberboards and similar products. A pumpable alkaline slurry of fibrous raw material is conducted through a pressurized tube system by the use of pulp pumps, the pressure increasing in steps from the beginning of the process to the end of the process. On its way the slurry is repeatedly dewatered and rediluted with process liquid. An apparatus suitable for being used in carrying out the process comprises a dewatering tube (64) and a dewatering and venting tube (67) arranged centrally and axially within the tube (64) which may be provided with a perforated part (66). The tube (67) is provided with perforations (68) through which gas and liquid from fiber-containing slurry introduced into the outer tube (64) can escape. At the opposite end from the inlet end of the outer tube (64) there is an outlet (72, 65) for thickened fiber-containing slurry.Type: GrantFiled: December 21, 1990Date of Patent: January 11, 1994Inventor: Sigurd Fongen
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Patent number: 5236553Abstract: In the continuous cooking of comminuted cellulosic fibrous material (e.g. wood chips) to produce paper pulp, the material passes upwardly in an impregnation vessel which is within and concentric with a continuous digester and open at the top to digester pressure. At the top of the impregnation vessel, a solids/liquid separator (a screw within a screen cylinder) is provided. Separated liquid is returned in a conduit adjacent the exterior of the impregnation vessel, and open at the top to digester pressure, and passes out the bottom of the digester. The impregnation vessel is welded to the bottom of the digester, and the bottom of the digester is generally hemi-spherical, and substantially devoid of packings.Type: GrantFiled: October 9, 1991Date of Patent: August 17, 1993Assignee: Kamyr ABInventor: Johan C. F. C. Richter
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Patent number: 5217574Abstract: Unbleached pulp is combined with an aqueous alkaline solution while in a state of low consistency to distribute a first amount of alkaline material substantially uniformly throughout the pulp. The consistency of the pulp is then increased to above about 18%, and the high consistency alkali containing pulp is then treated with oxygen to effect delignification. The total amount of alkaline material applied to the pulp is between 0.8 and 7% by weight of oven dry pulp. High strength, low lignin pulps are subsequently formed which may be further bleached to high brightness with reduced amounts of chemicals.Type: GrantFiled: April 16, 1991Date of Patent: June 8, 1993Assignee: Union Camp Patent Holdings Inc.Inventor: Bruce F. Griggs
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Patent number: 5211811Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine by partially delignifying the pulp to a K No. of about 10 or less and a viscosity of greater than about 13 cps; and further delignifying the partially delignified pulp with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 5 or less, a viscosity of greater than about 10, and a GE brightness of at least about 50%. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65%, preferably above 70% to as high as 90%. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.Type: GrantFiled: August 26, 1991Date of Patent: May 18, 1993Assignee: Union Camp Patent Holding, Inc.Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen
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Patent number: 5188708Abstract: A process for delignifying and bleaching a lignocellulosic pulp without the use of elemental chlorine by partially delignifying the pulp to a K No. of about 10 or less and a viscosity of greater than about 13 cps; and further delignifying the partially delignified pulp with an effective amount of ozone for a sufficient time to obtain a substantially delignified pulp having a K No. of about 5 or less, a viscosity of greater than about 10, and a GE brightness of at least about 50%. The substantially delignified pulp may be brightened by the addition of a bleaching agent such as chlorine dioxide or a peroxide to obtain a final product having a GE brightness of at least about 65%, preferably above 70% to as high as 90%. Because of the absence of elemental chlorine in this sequence, filtrate from all stages but the chlorine dioxide stage (if used) can be recovered without sewering. Major environmental improvements are thus achieved.Type: GrantFiled: August 26, 1991Date of Patent: February 23, 1993Assignee: Union Camp Patent Holding, Inc.Inventors: Bruce F. Griggs, Thomas P. Gandek, Michael A. Pikulin, Allen Rosen
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Patent number: 5183535Abstract: Processes for prepariing kraft pulp are disclosed. The processes include pretreating cellulosic material or chips with spent cooking liquor at the temperature of about 20.degree. to 100.degree. C., followed by heating the impregnated chips at the temperature of from about 120.degree. to 180.degree. C., followed by digestion of the lignin with white liquor, which is facilitated by using this pretreatment process.Type: GrantFiled: November 19, 1991Date of Patent: February 2, 1993Assignee: Sunds Defibrator Rauma OyInventor: Panu Tikka
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Patent number: 5173153Abstract: Unbleached pulp is combined with an aqueous alkaline solution while in a state of low consistency to distribute a first amount of alkaline material substantially uniformly throughout the pulp. The consistency of the pulp is then increased to above about 20%. Additional alkali is applied onto the high consistency pulp to provide a total amount of between 0.8 and 7% by weight of oven dry pulp. The high consistency alkali containing pulp is then treated with oxygen to effect delignification. High strength, low lignin pulps are formed which may be further bleached to high brightness with reduced amounts of chemicals by following the methods of the invention.Type: GrantFiled: January 3, 1991Date of Patent: December 22, 1992Assignee: Union Camp Patent Holding, Inc.Inventors: Stuart T. Terrett, Spencer W. Eachus, Bruce F. Griggs
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Patent number: 5145557Abstract: A three-stage bleaching process for dissolving grade pulp utilizes the sequence OP(alkaline)-Z-P and the off gas from the Z-stage is delivered to the alkaline (OP)-stage whose parameters are controlled to fully react all of the oxygen of the off gas. The filtrate or waste water from the Z-stage, at a pH below 3, serves to dilute the alkaline OP-stage pulp before Z-stage bleaching and/or for de-ashing of the P pulp following the P-stage.Type: GrantFiled: February 7, 1991Date of Patent: September 8, 1992Assignee: Lenzing AktiengesellschaftInventors: Walter Peter, Anton Hruschka, Oskar Hoglinger
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Patent number: 5143580Abstract: A process for delignification and bleaching of chemically digested lignocellulose-containing pulp for reduced formation and discharge of halogenated organic compounds, while preserving the pulp quality, where the prebleaching with halogen-containing bleaching agent is replaced by a treatment, in a first step, with the addition of a complexing agent at elevated temperature and at a pH from 3.1 to 9.0, and in a second step, by using a peroxide-containing compound under alkaline conditions, whereupon spent liquor from the final bleaching with halogen-containing compounds is recycled to the first or second step of the halogen-free prebleaching.Type: GrantFiled: April 23, 1991Date of Patent: September 1, 1992Assignee: Eka Nobel ABInventors: Jiri J. Basta, Lillemor K. Holtinger, Marie R. Samuelsson, Per G. Lundgren
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Patent number: 5118389Abstract: A continuous two-stage peroxide bleaching process operated in a single bleach plant for producing a bleached pulp of high brightness, having a second stage bleaching step using a high charge of peroxide followed by a washing stage to recover the residual liquor containing a substantial amount of the applied peroxide. The residual liquor is recycled and used for bleaching in the first stage. Only a portion of the pulp bleached in the first stage is treated in the second stage. Two or more bleached pulp products can be produced simultaneously. The bleached pulp products can be used to form different layers of a multi-layer paper products.Type: GrantFiled: July 6, 1990Date of Patent: June 2, 1992Assignee: ICI Canada Inc.Inventors: Paul Dubelsten, Christopher J. Kanters, John R. Du Manoir
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Patent number: 5089086Abstract: The invention relates to a process for continuous cooking of cellulose. In the process, wood chips (11) are impregnated (1) with cooking lye (10), after which the wood chips impregnated with cooking lye is mixed (27) with spent liquor (18) in order to transfer (12) it into the upper portion of a pressurized digester (2). The transfer liquor used for the transfer of the wood chips in the preceding step is separated (26) from the impregnated wood chips in the upper portion of the digester (2) and is recycled (13,14) to the preceding step. After this, the chips are conducted from the digester (2) downwards into the cooking zone (24) and from there on to the washing zone (24), whereby a mixture of spent lye and wash lye, i.e. spent liquor (18) is removed from between the cooking and washing zones (19) and a portion (21) of the liquor removed from the digester (2) is expansion evaporized (5,6) in order to recover heat in the form of steam (22,23).Type: GrantFiled: April 25, 1990Date of Patent: February 18, 1992Assignee: Jaakko Poyry OyInventor: Risto Silander