With Addition Of Chemicals To Recirculating Fluid Patents (Class 162/45)
  • Patent number: 8940131
    Abstract: The invention describes a process for the conversion of aqueous suspensions of lignocellulosic solids comprising a solids content of between 1 and 20% of dry material, said process comprising a step a) for compression of said suspension so as to separate the liquid phase present in and between the solids from the compressed solid phase and a step b) for extraction of at least the liquid phase, said liquid phase then being homogenized by heat and/or chemical treatments and reinjected on to the compressed solid phase.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: January 27, 2015
    Assignee: IFP Energies Nouvelles
    Inventor: Matthieu Rolland
  • Publication number: 20150007951
    Abstract: In a delignification of pulp with hydrogen peroxide catalyzed by molybdate, molybdate can be recovered by contacting the molybdate-containing aqueous solution at a pH in the range from 2 to 7 with a carrier material comprising a sheet silicate been ion-exchanged with a quaternary ammonium salt and subsequent flotation without a surfactant having to be added for flotation.
    Type: Application
    Filed: December 19, 2012
    Publication date: January 8, 2015
    Applicant: Evonik Industries AG
    Inventors: Thomas Dietz, Bernd Hopf, Ralf Grimmer
  • Publication number: 20140106412
    Abstract: The invention describes a process for the conversion of aqueous suspensions of lignocellulosic solids comprising a solids content of between 1 and 20% of dry material, said process comprising a step a) for compression of said suspension so as to separate the liquid phase present in and between the solids from the compressed solid phase and a step b) for extraction of at least the liquid phase, said liquid phase then being homogenised by heat and/or chemical treatments and reinjected on to the compressed solid phase.
    Type: Application
    Filed: October 30, 2013
    Publication date: April 17, 2014
    Applicant: IFP Energies Nouvelles
    Inventor: Matthieu ROLLAND
  • Publication number: 20110203755
    Abstract: The method is for influencing the flow from a strainer construction in a continuous digester. In order to avoid clogging of the withdrawal compartment in the strainer construction, an additive that counteracts precipitation processes is added directly to the withdrawal compartment while the cooking fluid is withdrawn from the withdrawal compartment. The addition of chemicals can take place at the same time as the withdrawn cooking fluid is withdrawn from the digester and the strainer construction, or while the withdrawn cooking fluid is fully or partially re-circulated back to the withdrawal compartment.
    Type: Application
    Filed: October 12, 2009
    Publication date: August 25, 2011
    Inventor: Jonas Saetherasen
  • Patent number: 7871491
    Abstract: The continuous digester system has an inlet defined therein for the feed of a chips suspension and an outlet for the output of a cooked suspension of pulp. The suspension of chips is fed in to the inlet through a line at the beginning of the cook, where the chips suspension has a volume of starting cooking fluid that establishes a fluid/wood ratio that is greater than 3.5. A final cooking fluid is present during the cook for the major part of the cock and is withdrawn through a withdrawal strainer only during the final 15 minutes of the cook. The final cooking fluid ensures a fluid/wood ratio that is greater than 3.5 in association with the withdrawal. The withdrawn final cooking fluid during the final 15 minutes of the cook consists of spent black liquor that maintains a residual alkali level that lies under 15 g/l.
    Type: Grant
    Filed: January 29, 2010
    Date of Patent: January 18, 2011
    Assignee: Metso Fiber Karlstad AB
    Inventors: Vidar Snekkenes, Mikael Lindstrom
  • Patent number: 7854847
    Abstract: Systems and methods for purifying wood pulp by caustic-borate extraction. The systems and method include a method for recovering both the caustic and borate compounds from the resultant hemicaustic effluent, so that they may be recycled and re-used. Efficient recovery of these components is enabled by a nanofiltration system that has one or more alkali-resistant nanofiltration membranes.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: December 21, 2010
    Assignee: Rayonier TRS Holdings Inc.
    Inventor: Jian Li
  • Patent number: 7686919
    Abstract: The continuous digester system has an inlet defined therein for the feed of a chips suspension and an outlet for the output of a cooked suspension of pulp. The suspension or chips is fed in to the inlet through a line at the beginning of the cook, where the chips suspension has a volume of starting cooking fluid that establishes a fluid/wood ratio that is greater than 3.5. A final cooking fluid is present during the cook for the major part of the cook and is withdrawn through a withdrawal strainer only during the final 15 minutes of the cook. The final cooking fluid ensures a fluid/wood ratio that is greater than 3.5 in association with the withdrawal. The withdrawn final cooking fluid during the final 15 minutes of the cook consists of spent black liquor that maintains a residual alkali level that lies under 15 g/l.
    Type: Grant
    Filed: November 24, 2006
    Date of Patent: March 30, 2010
    Assignee: Metso Fiber Karlstad AB
    Inventors: Vidar Snekkenes, Mikael Lindstrom
  • Patent number: 7029553
    Abstract: The present invention relates to the use of urea sulfate or urea hydrochloride, or both, in process streams in the paper and pulping industries to control pH, to bring about flocculation or precipitation of various materials, and to replace all or part of the sulfuric acid, hydrochloric acid, and/or papermaking alum used in the paper and pulping industries.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: April 18, 2006
    Assignee: Peach State Labs, Inc.
    Inventors: Michael S. Williams, R. Richard Sargent
  • Patent number: 6866748
    Abstract: The present invention provides a process for preparing polysulfide. More particularly, the process of the present invention allows one to prepare the amount of polysulfide needed using clarified white liquor, and to be used when and where it is needed during the cooking process. The process comprises reacting alkaline digesting liquor after clarification with a catalytic amount of a transition metal oxide catalyst, most preferably manganese dioxide. The reaction is conducted at a temperature of 98° C. or less, and is conducted for a short period of time, e.g., less than five minutes, with no oxygen gas or air being introduced with the catalyst and the main flow of clarified liquor.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: March 15, 2005
    Assignee: American Air Liquide, Inc.
    Inventors: Meenakshi V. Sundaram, Sebastien Corbeil, Michel Epiney
  • Patent number: 6824646
    Abstract: Lignocellulose pulp is bleached by bleaching a pulp in aqueous alkali solution with oxygen and treating the pulp with a hemicellulase, while a liquid fraction delivered from the enzyme treatment step is separated from the hemicellulase treated reaction mixture, and subjected to a penetration treatment through a separation membrane, for example, reverse osmosis membrane, to separate a permeated fraction from a non-permeated fraction; the permeated fraction is fed to the alkali-oxygen bleaching (oxygen delignification) step and is used as a liquid medium of the bleaching system.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: November 30, 2004
    Assignee: OJI Paper Co., Ltd.
    Inventors: Yoshiya Izumi, Jun Sugiura, Hitoshi Kagawa, Naoya Azumi
  • Patent number: 6746568
    Abstract: A method in bleaching of pulp is described, in which the pulp is subjected to a peroxide bleaching step, whereupon the pulp is washed and the washing liquid from the washing is separated from the pulp in the form of a filtrate. The method is characterised in that the filtrate is treated with an aluminium compound, such as aluminium sulphate or polyaluminium sulphate, for precipitation of interfering substances, such as oxygen-demanding organic material and metals, that the precipitated material is removed from the filtrate, that the aluminium content of the filtrate after precipitation of interfering substances is adjusted to at most 20 ppm, and that the filtrate is then recirculated to the peroxide bleaching step. By the method, a reduced consumption of hydrogen peroxide in the peroxide bleaching step is achieved.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: June 8, 2004
    Assignee: Kemira Kemi AB
    Inventors: Hans Terelius, Anette Olsson, Margareta Nilsson, Jessica Svensson, Christos Rampotas
  • Publication number: 20040089431
    Abstract: An alkaline batch process for the production of pulp from wood chips, wherein the preheated chips are subjected to an extended impregnation step outside the digester for at least 60 min, preferably longer, at a temperature not exceeding the impregnation liquor boiling point at atmos-pheric conditions, and a rapid heating and cooking period in the digester of less than about 90 min, preferably shorter, followed by cooling to below reaction tempera-ture. Fresh alkali is added both during impregnation and the heating/cooking period.
    Type: Application
    Filed: December 29, 2003
    Publication date: May 13, 2004
    Inventors: Thomas Fant, Mikael Svedman, Lari Lammi
  • Publication number: 20020079071
    Abstract: The invention relates to a process for continuous cooking of wood chips at elevated pressure and temperature in a vertical digester (1) for production of chemically dissolved pulp.
    Type: Application
    Filed: September 28, 2001
    Publication date: June 27, 2002
    Applicant: Kvaerner Pulping AB;
    Inventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
  • Publication number: 20020079070
    Abstract: The invention relates to a process for continuous cooking of wood chips at elevated pressure and temperature in a vertical digester (1) for production of chemically dissolved pulp.
    Type: Application
    Filed: September 28, 2001
    Publication date: June 27, 2002
    Applicant: Kvaerner Pulping AB
    Inventors: Vidar Snekkenes, Lennart Gustavsson, Sven-Erik Olsson
  • Patent number: 6280568
    Abstract: Kraft pulp of increased strength and bleachability may be produced with decreased consumption of effective alkali, and at a lower H factor, by keeping the dissolved organic material (DOM) concentration low substantially through the entire kraft cook, including by extracting high DOM liquid from at least one part of a continuous digester and replacing it with much lower level DOM liquid. Existing pulp mills having two-vessel hydraulic, one-vessel hydraulic, or other systems may be retrofit to provide for extractions and additions of low DOM dilution liquor (including substantially DOM-free white liquor). Also, commercial size batch digesters (8 tons per day of pulp or more) can be operated with low DOM liquor to produce increased strength pulp. Using dilution with low DOM liquor also results in reduced H factor and effective alkali consumption, and increased bleachability.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: August 28, 2001
    Assignee: Andritz-Ahlstrom Inc.
    Inventors: Bruno S. Marcoccia, J. Robert Prough, Richard O. Laakso, Joseph R. Phillips, Rolf C. Ryham, Jan T. Richardsen, R. Fred Chasse
  • Patent number: 6261413
    Abstract: The present invention relates to a process for continuously guiding a liquid when digesting pulp in a digester, wherein liquid used in a process step can circulate between containers or tanks arranged at the inflow and outflow side of the digester and when this particular process step has been reached, the digester is connected into the circulation between the containers or tanks associated with the process step.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: July 17, 2001
    Assignee: Impco-Voest-Alpine Pulping Technologies GmbH
    Inventor: Manfred Dietmar Hepp
  • Patent number: 6254723
    Abstract: In a single-vessel system for continuous cooking of kraft pulp, chips and liquor are conveyed from a high pressure feeder in a transfer line to a first end of a digester. A part of the liquor is separated from the chips that are withdrawn from an outlet defined in an upper part of the digester and conveyed in a return line to the high pressure feeder. A constituent flow of liquor is led from the return line and heated and fed via one or more inlets into the digester at a location that is downstream of the outlet for the return line.
    Type: Grant
    Filed: December 13, 1999
    Date of Patent: July 3, 2001
    Assignee: Kvaerner Pulping AB
    Inventors: Vidar Snekkenes, Lennart Gustavsson
  • Patent number: 6143130
    Abstract: A method for impregnation and chemical digestion of lignocellulosic material and recovery of pulping liquors. A spent impregnating or cooking liquor is withdrawn and sulphurous compounds are recovered therefrom in a partial oxidation reactor. These sulphurous compounds are converted into hot liquid elemental sulphur which thereafter is mixed with a hot sulphide containing liquor to provide a polysulphide liquor with a concentration greater than 10 g/l and which is essentially free from thiosulphate. This polysulphide liquor is used for carbohydrate stabilising impregnation and/or for cooking at a relatively low temperature.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: November 7, 2000
    Assignee: Kvaerner Pulping AB
    Inventors: Lars Stigsson, Mikael Linstrom
  • Patent number: 6063238
    Abstract: The present invention relates to a digester and a method for continuously cooking kraft pulp in a single-vessel system (1), preferably a single-vessel hydraulic digester, with chips (2) being fed in at a first end (3) of the digester (1), white liquor (4) being added at at least one position at or near the said first end (3), the chips being impregnated in a cocurrent impregnation zone (5), the chips being cooked in a cooking zone (6) downstream of the impregnation zone, hot black liquor (7) being extracted from at least one extraction strainer section (8), and cooked pulp being discharged (9) at the other end of the digester, and hot black liquor (7) being added (11), (12) to the said impregnation zone (5), and the extract (13) from the first strainer section (14), which is arranged downstream of the position of addition (11a) of the said hot black liquor (7), being largely removed from the digester.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: May 16, 2000
    Assignee: Kvaerner Pulping AB
    Inventors: Anders Bergqvist, Johan Engstrom
  • Patent number: 6054019
    Abstract: A method for cooking chips which are impregnated, in a vessel (3), with liquid in first and second concurrent impregnation zones (A, B), impregnation liquid being supplied, in a mixture with steamed chips, through a feeding system to the first impregnation zone, and liquid for recovery being extracted at a first point (41) at the end of the first impregnation zone, and further liquid being supplied to the second impregnation zone (B). According to the invention, liquid is extracted at a second point (43) at the start of the second impregnation zone (B) and is circulated in an impregnation circulation (44, 45) which empties out at the center of the vessel at a point between the first and second points (41, 43) for extraction of liquid so that a flow of liquid is established from the center of the vessel in a radial direction. The further liquid is supplied to the impregnation circulation for continued impregnation of the chips in the second impregnation zone.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: April 25, 2000
    Assignee: Kvaerner Pulping AB
    Inventors: Johan Engstrom, Olav Hoglund
  • Patent number: 5885414
    Abstract: A method and device for cooking pulp by increasing the effective alkali concentration in the residual phase of the cooking process to substantially improve the residual delignification rate and thus improving the pulp properties such as the pulp strength and pulp yield at a given lignin content.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: March 23, 1999
    Assignee: Kvaerner Pulping AB
    Inventors: Mikael Lindstrom, Christofer Lindgren
  • Patent number: 5788813
    Abstract: A method and apparatus for treating green liquor from a sulphate pulp mill enhances the clarification of the green liquor and may easily be integrated into existing pulp mills. A first portion of the green liquor from the sulphate pulp mill is clarified in a clarifier to produce a clarified green liquor and a dregs-containing green liquor. The dregs-containing green liquor is filtered in a green liquor filter to produce filtrate and dregs. The filtrate is combined) with the clarified green liquor to produce a first combined stream; and the dregs are filtered in a dregs filter. A second portion of green liquor from the sulphate pulp mill is combined with the dregs-containing green liquor to produce a second combined stream, and the second combined stream is introduced into the green liquor filter. The dregs from step (b) are washed prior to filtering the dregs, the green liquor filter and washer comprising a single structure.
    Type: Grant
    Filed: September 11, 1996
    Date of Patent: August 4, 1998
    Assignee: Ahlstrom Machinery Oy
    Inventors: Holger Engdahl, Martti Pokkinen, Pekka Tormikoski
  • Patent number: 5779856
    Abstract: Chemical (typically kraft) pulp having enhanced intrinsic fiber strength and bleachability compared to pulp produced using conventional or modified kraft cooking is produced by using high alkali and/or pH cooking, preferably by adding the vast majority of cooking liquor (such as kraft white liquor) after the first removal of liquid from the digester so that the effective alkali concentration is high near the end of the cook. That is during at least the last minute (preferably at least the last 15 minutes and most preferably at least the last 30 minutes) before the cook is terminated the effective alkali concentration is between 15-50 g/l, more preferably between about 18-40 g/l, and most preferably between about 20-35 g/l.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: July 14, 1998
    Assignee: Ahlstrom Machinery Inc.
    Inventor: Auvo K. Kettunen
  • Patent number: 5672279
    Abstract: A method to remove the build-up of water-insoluble metal salts on surfaces, and a method to lower the solids content of industrial liquids that contain water-insoluble metal salts using urea hydrochloride or its equivalent. Also disclosed is a method to use urea hydrochloride or an equivalent strong acid/weak base salt as acid replacements for a variety of purposes.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: September 30, 1997
    Assignee: Peach State Labs, Inc.
    Inventors: R. Richard Sargent, Jeffrey Randolph Alender, Thomas Hudson Moss, III
  • Patent number: 5662775
    Abstract: Digester systems for producing paper pulp from comminuted cellulosic fibrous material take into account the level of dissolved organic materials (DOM), such as lignin, hemi-cellulose, and cellulose, maintaining the DOM level at about 100 g/l throughout the cook (particularly kraft cook). In order to make sure there is sufficient liquid to slurry the material in the feed system of a two vessel system, some liquid is withdrawn from the circulation conduits between the digester and impregnation vessel, cooled, and fed to the feed system. In a vapor phase digester, the level of liquid at the top of the digester is more precisely controlled by circulating some of the withdrawn liquid from a circulatory loop of the digester to the level tank associated with the feed system. An in-line drainer may be provided in the feed system between a make-up liquor pump and a liquid inlet conduit leading to the top of an impregnation vessel.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 2, 1997
    Assignee: Ahlstrom Machinery Inc.
    Inventors: Bruno S. Marcoccia, J. Robert Prough, Richard O. Laakso, R. Fred Chasse
  • Patent number: 5658428
    Abstract: The present invention relates to a method for continuous cooking of kraft pulp in a single-vessel system (1), preferably a single-vessel hydraulic digester, with chips being conveyed from a high-pressure feeder (2) in a transfer line (2A, 4A) to a first end (3) of the digester (1), the chips being impregnated, in a liquid containing black liquor, in a concurrent impregnation zone (5), the chips being cooked in a cooking zone (6) subsequent to the impregnation zone, hot black liquor (7) being extracted from at least one extraction screen section (8), and cooked pulp being discharged (9) at the other end of the digester. The chips are, when they leave the high-pressure feeder (2), included in a first liquid, which first liquid is in the main separated from the chips in a liquid exchanger (4) installed in the transfer line (2A, 4A) and is replaced by a second liquid which contains black liquor.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: August 19, 1997
    Assignee: Kvaerner Pulping Technologies AB
    Inventor: Finn Oulie
  • Patent number: 5620562
    Abstract: Kraft pulp of increased strength and bleachability may be produced with decreased consumption of effective alkali, and at a lower H factor, by keeping the dissolved organic material (DOM) concentration low substantially through the entire kraft cook, including by extracting high DOM liquid from at least one part of a continuous digester and replacing it with much lower level DOM liquid. Existing pulp mills having two-vessel hydraulic, one-vessel hydraulic, or other systems may be retrofit to provide for extractions and additions of low DOM dilution liquor (including substantially DOM-free white liquor). Also, commercial size batch digesters (8 tons per day of pulp or more) can be operated with low DOM liquor to produce increased strength pulp. Using dilution with low DOM liquor also results in reduced H factor and effective alkali consumption, and increased bleachability.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: April 15, 1997
    Assignee: Ahlstrom Machinery Inc.
    Inventors: Bruno S. Marcoccia, J. Robert Prough, Richard O. Laakso, Joseph R. Phillips, Rolf C. Ryham, Jan T. Richardsen, R. Fred Chasse
  • Patent number: 5575890
    Abstract: The sulfide ion concentration and sulfidity of kraft cooking liquor during kraft cooking of cellulose pulp is selectively increased. After treatment in a first treatment zone in which impregnation or kraft cooking takes place using a kraft cooking liquor having a first sulfide ion concentration and sulfidity, black liquor is extracted from the material, liquid is withdrawn from the material and dilution liquid is added to the withdrawn liquid and the withdrawn liquid with dilution liquid is reintroduced. In a second treatment zone after the first zone a second kraft cooking liquor is introduced having a second sulfide ion concentration and sulfidity greater than the first sulfide ion concentration and sulfidity (typically by about 20-50%), including by manipulating controlling the flow rate of extraction and the flow rates of withdrawal of liquid and addition of dilution liquid.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: November 19, 1996
    Assignee: Kamyr, Inc.
    Inventors: J. Robert Prough, Bruno S. Marcoccia, Richard O. Laakso, Carl L. Luhrmann
  • Patent number: 5547012
    Abstract: Kraft pulp of increased strength and bleachability may be produced with decreased consumption of effective alkali, and at a lower H factor, by keeping the dissolved organic material (DOM) concentration low substantially through the entire kraft cook, including by extracting high DOM liquid from at least one part of a continuous digester and replacing it with much lower level DOM liquid. Existing pulp mills having two-vessel hydraulic, one-vessel hydraulic, or other systems may be retrofit to provide for extractions and additions of low DOM dilution liquor (including substantially DOM-free white liquor). Also, commercial size batch digesters (8 tons per day of pulp or more) can be operated with low DOM liquor to produce increased strength pulp. Using dilution with low DOM liquor also results in reduced H factor and effective alkali consumption, and increased bleachability.
    Type: Grant
    Filed: September 28, 1993
    Date of Patent: August 20, 1996
    Assignee: Kamyr, Inc.
    Inventors: Bruno S. Marcoccia, J. Robert Prough, Richard O. Laakso, Joseph R. Phillips, Rolf C. Ryham, Jan T. Richardsen, R. Fred Chasse
  • Patent number: 5536366
    Abstract: Digester systems for producing paper pulp from comminuted cellulosic fibrous material take into account the level of dissolved organic materials (DOM), such as lignin, hemi-cellulose, and cellulose, maintaining the DOM level at about 100 g/l throughout the cook (particularly kraft cook). In order to make sure there is sufficient liquid to slurry the material in the feed system of a two vessel system, some liquid is withdrawn from the circulation conduits between the digester and impregnation vessel, cooled, and fed to the feed system. In a vapor phase digester, the level of liquid at the top of the digester is more precisely controlled by circulating some of the withdrawn liquid from a circulatory loop of the digester to the level tank associated with the feed system. An in-line drainer may be provided in the feed system between a make-up liquor pump and a liquid inlet conduit leading to the top of an impregnation vessel.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: July 16, 1996
    Assignee: Ahlstrom Machinery Inc.
    Inventors: Bruno S. Marcoccia, J. Robert Prough, Richard O. Laakso, R. Fred Chasse
  • Patent number: 5527427
    Abstract: A high solids black liquor which has solids content of at least 65% by weight of liquor is mixed with a viscosity reducing additive prior to firing in a chemical recovery furnace. The additive is an admixed compound consisting of monoethylene glycol, diethylene glycol and triethylene glycol.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: June 18, 1996
    Assignee: Optima Specialty Chemicals & Technology Inc.
    Inventors: Mualla Berksoy, Yaman Boluk
  • Patent number: 5522958
    Abstract: A method for the production of kraft pulps in a digester, by modifying the cooking chemical concentration, and lignin concentration profiles during the cook, has provided extended delignification and improved selectivity in a simpler way than has previously been possible. The cooking is performed at an elevated temperature in two stages. The first stage liquor is a mixture of 1) the spent liquor of the second stage and 2) a portion of the conventional charge of fresh cooking chemicals needed for the complete cook. The second stage liquor is made up by adding an aqueous diluent, for example, fresh water or washing filtrate to the remaining portion of the fresh cooking chemicals.
    Type: Grant
    Filed: July 18, 1994
    Date of Patent: June 4, 1996
    Assignee: Pulp and Paper Research Institute of Canada
    Inventor: Jian Li
  • Patent number: 5468393
    Abstract: A method of inhibiting scale formation in acidic aqueous systems where metal ions such as Al.sup.+3 and Fe.sup.+3 are present by employing a polyepoxysuccinic acid in combination with a metal ion binding material.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: November 21, 1995
    Assignee: Betz PaperChem, Inc.
    Inventors: Davor F. Zidovec, Alexander D. Fisher, deceased
  • Patent number: 5437791
    Abstract: Process water from pulp manufacture is purified in a separator device by mechanical or a combination of mechanical and chemical methods and is thereafter evaporated, at least part of the concentrate resulting from the evaporation being recycled and mixed with the process water fed into the separator device. In a preferred embodiment, a precipitant is added to the mixed water comprising the process water and the concentrate. The part of the concentrate not recycled and mixed with the process water is supplied, optionally after further evaporation, with an acid to a pH of 1-5, whereupon resulting flocs and precipitates are removed in a separator device.
    Type: Grant
    Filed: February 2, 1994
    Date of Patent: August 1, 1995
    Assignee: Eka Nobel AB
    Inventors: Gunnar Goransson, Birgitta Sundblad, Johan Landfors, Hans A. Baltsen
  • Patent number: 5368740
    Abstract: A method of inhibiting scale formation in acidic aqueous systems where metal ions such as A1.sup.+3 or Fe.sup.+3 are present by employing a polyepoxysuccinic acid in combination with a metal ion binding material.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: November 29, 1994
    Assignee: Betz PaperChem, Inc.
    Inventors: Davor F. Zidovec, Alexander D. Fisher
  • Patent number: 5213663
    Abstract: A method for regulating the sodium carbonate concentration of a green liquor in the dissolving tank of the Kraft recovery process by measuring the conductivity of the green liquor from the dissolving tank, measuring the conductivity and flow rate of a weak wash solution being added to the green liquor in the dissolving tank, using these measurements to determine the sodium carbonate concentration of the green liquor in the dissolving tank, and adjusting the volume of the weak wash solution being added to the dissolving tank in response to changes in the concentration of sodium carbonate in the green liquor so as to maintain the concentration of sodium carbonate in the green liquor at a predetermined, preferably constant, level.
    Type: Grant
    Filed: July 22, 1991
    Date of Patent: May 25, 1993
    Assignee: The Foxboro Company
    Inventor: Wolf Musow
  • Patent number: 5145556
    Abstract: A one-step slaking/causticizing method for producing white liquor from unslaked lime and clarified green liquor comprising introducing a feed slurry of unslaked lime and clarified green liquor into a pressurized slaker/causticizer reaction zone and maintaining the mixture in the zone at a temperature, under sufficient pressure and for a time sufficient, in one step to slake the lime and to convert the slaked lime to a white liquor containing product slurry.
    Type: Grant
    Filed: July 31, 1991
    Date of Patent: September 8, 1992
    Assignee: International Paper Company
    Inventors: J. Lennart Westerberg, Alex K. Bonsu, Fred J. Perrett
  • Patent number: 5108655
    Abstract: This invention relates to a system for monitoring and controlling foam in a liquid tank utilizing a foam level sensing device positioned at a downstream location from a defoaming agent delivery arrangement. The foam level sensing device comprises a float having a plurality of foam sensors positioned at various levels above the float and provides signals to a control device regarding the level of foam in the tank. The control device provides instructions to the defoaming agent delivery arrangement so to provide a proper amount of defoaming agent to the tank. The defoaming agent delivery arrangement may be operated continuously and includes a backup delivery device for times when the delivery means runs out of defoaming agent or at times when foam is generated at an exceptional rate.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: April 28, 1992
    Assignees: Electro-System, Incorporated, Ross Chem, Incorporated
    Inventors: Joseph W. Johns, Jr., Joseph G. Katzel
  • Patent number: 5096540
    Abstract: Combined acidification and evaporative concentration of sulfite based chemical and sulfite based semichemical spent liquors expel massive amounts of gaseous sulfur dioxide and water vapor from the spent liquor.The concentration of the expelled sulfur dioxide is sufficiently high so that the sulfur dioxide and water vapor can be recycled directly, without further separation, to produce fresh sulfite pulping liquor.
    Type: Grant
    Filed: April 6, 1990
    Date of Patent: March 17, 1992
    Inventors: Nancy J. Sell, Jack C. Norman
  • Patent number: 4853082
    Abstract: A process is provided for the activation and delignification of cellulose pulp, which comprises:(1) subjecting chemical cellulose pulp to activation by reaction with nitrogen dioxide in the presence of water at a temperature within the range from about 20.degree. to 120.degree. C., while(a) separating gas containing at least 1.2 mml nitrogen oxides, including NO, per liter of gas determined at 25.degree. C. and calculated as nitrogen, reacting nitrogen oxides in said withdrawn gas with oxygen gas in an amount within the range from about 10 to about 200 mole percent, calculated on the amount of NO present, and recycling the reacted gas to the activation; and(b) separating gas containing less than 0.4 mml nitrogen oxides, including NO, per liter of gas determined at 25.degree. C. and calculated as nitrogen from the cellulose pulp and removing said gas from the process; and(2) delignifying the activated cellulose pulp.
    Type: Grant
    Filed: June 9, 1987
    Date of Patent: August 1, 1989
    Assignee: Mooch Domsjo Aktiebolag
    Inventor: Hans O. Samuelson
  • Patent number: 4849052
    Abstract: A multi-stage wood chip cooking process performed in a single digester in a batch type operation. The wood chips to be cooked are introduced into the digester and soaked with a warm black liquor to remove most of the air from the digester and the chips. This warm black liquor is thereafter displaced from the digester with a mixture of a first stage hot black liquor and hot white liquor, the proportionate amount of hot white liquor being relatively high. The temperature of the digester contents is then raised to a cooking temperature for a predetermined amount of time. The original cooking liquor is then displaced with a mixture of a second hot black liquor and hot white liquor, the proportiionate amount of hot white liquor in this second cooking liquor being less than in the first. Again, the temperature of the digester is raised to a cooking temperature and the cooking is carried out for a shorter period of time than in the first cooking stage.
    Type: Grant
    Filed: August 21, 1985
    Date of Patent: July 18, 1989
    Assignee: Beloit Corporation
    Inventor: Ralph S. Grant
  • Patent number: 4838995
    Abstract: For bleaching cellulose pulp or a fraction thereof, e.g. reject pulp, the cellulose pulp or fraction, having a concentration of 0.5-10%, preferably 3-6%, is introduced into a screw press comprising at least a first (47) and a second (48) dewatering zone, is dewatered in the first zone to a concentration of 20-40%, whereupon a liquor of bleach chemicals is introduced centrally into the pulp which, during continued treatment, is dewatered in the second zone to a discharge pulp concentration of 15-50, preferably 15-30%, the liquid pressed out of the second zone, together with fresh bleach chemicals, being returned to the pulp in the screw press as liquor of bleach chemicals.
    Type: Grant
    Filed: January 28, 1987
    Date of Patent: June 13, 1989
    Assignee: Thune-Eureka A/S
    Inventor: Arne I. Klausen
  • Patent number: 4761238
    Abstract: A method for removing dissolved and colloidal material from the circulation water of a paper mill with chemical pulp fibers wherein fiber sludge which has been recovered from the paper manufacturing process and acidified to a pH of 1.5-2.5, is mixed with the circulation water of a paper mill whereby the dissolved and colloidal substances are precipitated.
    Type: Grant
    Filed: July 1, 1987
    Date of Patent: August 2, 1988
    Assignee: Kamyr AB
    Inventor: Pertti K. Hynninen
  • Patent number: 4690731
    Abstract: A modified batch cooking technique for making sulfate pulp with a high degree of delignification or with a normal degree of delignification but with increased pulp viscosity. This is effected by one or several displacements of the liquor in the digester with liquor of the same temperature as the cooking liquor but with a lower lignin content.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: September 1, 1987
    Assignee: Sunds Defibrator Aktiebolag
    Inventors: Nils J. C. Hartler, Karl-Erik Lekander, Lars T. Sjodin, Per J. Mjoberg
  • Patent number: 4601787
    Abstract: A method for bringing a digester up to cooking temperature efficiently and rapidly wherein wood chips are packed in the digester, covered with a hot spent liquor, and then a hot liquor displacing liquid is used to displace the hot spent liquor from the digester and send it to an alkali adjustment zone in an accumulator. After the hot spent liquor has been displaced, the hot liquor displacing liquid is passed through the digester and into a lower portion of the alkali adjustment zone. Hot liquor is constantly passed from a constant volume heating zone into the alkali adjustment zone by overflow or otherwise. Hot liquor at the cooking temperature is passed from the top of the heating zone into the bottom of the digester and relatively cool liquor after passage through the digester passes from the top of the digester to the bottom of the heating zone.
    Type: Grant
    Filed: April 11, 1984
    Date of Patent: July 22, 1986
    Assignee: Beloit Corporation
    Inventor: Bertil K. E. Fagerlund
  • Patent number: 4561936
    Abstract: A two-stage process is provided for the conversion of lignocellulosic material, for instance, wood, to cellulose pulp, first oxidizing the lignocellulosic material to form aldonic acid end groups, preferably bound with 1,4-glycosidic bonds, in the polysaccharides, in an alkaline medium in the presence of the oxidized form of a redox additive which is converted into a reduced form in reaction with the wood and/or products formed from the wood, withdrawing the alkaline medium and then reoxidizing the reduced form of the redox additive in the absence of the lignocellulosic material at a rate to maintain the oxidized form of the redox additive in a major proportion in the alkaline medium during oxidation of the lignocellulosic material by contacting the withdrawn alkaline medium with oxygen-containing gas, and then continuing the digestion in an alkaline medium at a temperature within the range from about 160.degree. to about 200.degree. C.
    Type: Grant
    Filed: August 24, 1981
    Date of Patent: December 31, 1985
    Assignee: Mo och Domsjo Aktiebolag
    Inventor: Hans O. Samuelson
  • Patent number: 4537656
    Abstract: A method for delignifying and/or bleaching cellulose pulp adds to the cellulose pulp a liquid which contains chlorine dioxide, causes the pulp to react with the chlorine dioxide over a selected period of time, and then reduces the amount of available active chlorine, optionally to a negligible amount, either by reducing the amount of liquid accompanying the cellulose pulp and/or by displacing such liquid with a newly supplied liquid containing no active chlorine or at most only a small amount of active chlorine; the displaced liquor can be replenished with chlorine and optionally with chlorine dioxide, and then added mainly to fresh cellulose pulp in the same bleaching stage, and/or to cellulose pulp in another bleaching stage.
    Type: Grant
    Filed: December 1, 1983
    Date of Patent: August 27, 1985
    Assignee: Mo och Domsjo Aktiebolag
    Inventors: Jonas A. I. Lindahl, John R. Bergstrom
  • Patent number: 4466861
    Abstract: A process is provided for inhibiting the formation of deposits in the course of pulping lignocellulosic material and in the treating of cellulose pulp, by addition to the cellulose pulping or treating process of compounds of polyvalent metals other than aluminum and manganese capable of complexing deposit-forming anions, thereby maintaining the deposit-forming anions in solution in the form of a liquor-soluble complex.
    Type: Grant
    Filed: October 14, 1981
    Date of Patent: August 21, 1984
    Assignee: Mo och Domsjo Aktiebolag
    Inventors: Bengt G. Hultman, Rolf C. Nilsson
  • Patent number: 4456750
    Abstract: A method for controlling the pH of the liquid circulation in a continuous prehydrolysis apparatus where a mineral acid or some other acid stronger than sulfurous acid is used as a hydrolysis agent and the material to be hydrolyzed is transferred, entrained in the liquids of a first and a second liquid circulation separated by a liquid exchanger, from a steaming vessel to a hydrolysis vessel by means of a transfer valve. Such an amount of alkaline sulfite or ammonium sulfite is added into the liquid of the first liquid circulation as is necessary to make the liquid alkaline or at least neutral.
    Type: Grant
    Filed: February 2, 1983
    Date of Patent: June 26, 1984
    Assignee: A.Ahlstrom Osakeyhtio
    Inventors: Tapani Marttala, Kari Saramaki
  • Patent number: 4218284
    Abstract: A process is provided for inhibiting the formation of deposits in the course of pulping lignocellulosic material and in the treating of cellulose pulp, by addition to the cellulose pulping or treating process of compounds of polyvalent metals capable of complexing deposit-forming anions, thereby maintaining the deposit-forming anions in the form of a liquor-soluble complex.
    Type: Grant
    Filed: May 3, 1978
    Date of Patent: August 19, 1980
    Assignee: Mo och Domsjo Aktiebolag
    Inventors: Bengt G. Hultman, Rolf C. Nilsson