Sulfur Dioxide Patents (Class 162/64)
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Patent number: 11965220Abstract: The present invention relates to methods of processing lignocellulosic material to obtain hemicellulose sugars, cellulose sugars, lignin, cellulose and other high-value products. Also provided are hemicellulose sugars, cellulose sugars, lignin, cellulose, and other high-value products.Type: GrantFiled: June 4, 2021Date of Patent: April 23, 2024Assignee: VIRDIA, LLCInventors: Robert Jansen, Philip Travisano, Lee Madsen, Neta Matis, James Alan Lawson, Noa Lapidot, Aharon Eyal, Timothy Allen Bauer, Ziv-Vladimir Belman, Bassem Hallac, Michael Zviely
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Patent number: 8578625Abstract: A process for removing water and solutes from the lumens of green wood, while leaving the cell walls throughout the wood uniformly fully swollen, comprises subjecting the green wood to supercritical carbon dioxide.Type: GrantFiled: October 29, 2007Date of Patent: November 12, 2013Assignee: New Zealand Forest Research Institute LimitedInventors: Robert Arthur Franich, Sheryl Suzanne Gallagher, Hendricus Wilhelmus Kroese
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Publication number: 20120305207Abstract: A method for the fractionation of lignocellulosic materials into cellulose, hemicelluloses and lignin in a batch or continuous process in a treatment with vaporous mixture of aliphatic alcohol, sulfur dioxide and water. Cooking conditions are varied to get different proportions of cellulose, hemicelluloses and lignin. Chemical recovery through pressure release is described.Type: ApplicationFiled: August 14, 2012Publication date: December 6, 2012Applicant: API INTELLECTUAL PROPERTY HOLDINGS, LLCInventors: Theodora RETSINA, Vesa PYLKKANEN, Adriaan Reinhard P. VAN HEININGEN
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Publication number: 20120237989Abstract: A method for the production water insoluble reactive lignin having low sulfur content and lignosulfonates from lignocellulosic material in a batch or continuous process. Lignocellulosic material is fractionated to produce water insoluble native lignin and lignosulfonates in various ratios, while preserving the cellulose and hydrolyzed hemicelluloses using water, ethanol and sulfur dioxide.Type: ApplicationFiled: September 19, 2008Publication date: September 20, 2012Applicant: API Intellectual Property Holdings, LLCInventors: Theodora Retsina, Vesa Pylkkanen
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Publication number: 20110192560Abstract: The present invention relates to a process for the production of xylose and dissolving pulp from xylan-containing biomass, such as hardwood. The invention is based on prehydrolysis of the xylan-containing biomass with SO2 in specified conditions, followed by chromatographic fractionation, nanofiltration or precipitation crystallization of the xylose-containing prehydrolyzate to obtain a xylose product having a xylose content of at least 55% on DS. The dissolving pulp obtained from the process can be used for example for the production of viscose.Type: ApplicationFiled: October 20, 2009Publication date: August 11, 2011Applicant: DANISCO A/SInventors: Heikki Heikkila, Jari Lewandowski, Mirja Lindroos, Pia Saari
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Publication number: 20110165643Abstract: A method for the production water insoluble reactive lignin having low sulfur content and lignosulfonates from lignocellulosic material in a batch or continuous process. Lignocellulosic material is fractionated to produce water insoluble native lignin and lignosulfonates in various ratios, while preserving the cellulose and hydrolyzed hemicelluloses using water, ethanol and sulfur dioxide.Type: ApplicationFiled: January 11, 2011Publication date: July 7, 2011Inventors: THEODORA RETSINA, VESA PYLKKANEN
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Publication number: 20090236060Abstract: A method for the fractionation of lignocellulosic materials into cellulose, hemicelluloses and lignin in a batch or continuous process in a treatment with vaporous mixture of aliphatic alcohol, sulfur dioxide and water. Cooking conditions are varied to get different proportions of cellulose, hemicelluloses and lignin. Chemical recovery through pressure release is described.Type: ApplicationFiled: March 23, 2009Publication date: September 24, 2009Inventors: Theodora Retsina, Vesa Pylkkanen, Adriaan van Heiningen
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Patent number: 5041192Abstract: An improved wood pulping process for the delignification of wood in a solvent wherein the solvent is a supercritical fluid under supercritical conditons and contains a delignification agent such as sodium hydroxide, sodium sulfide and/or sodium bisulfate.Type: GrantFiled: September 16, 1988Date of Patent: August 20, 1991Assignee: University of South FloridaInventors: Aydin K. Sunol, Shan L. Chen
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Patent number: 4756800Abstract: A method of producing salts of monoperoxysulfuric acid comprising reacting together, in the presence of a catalyst consisting of cupric ions in a concentration of at least 0.01 part per milion, (a) a solution of aerated water having a pH of from about 8 to about 14, and (b) a sulfur-containing reactant, wherein said reactant comprises sulfur dioxide or a sulfite. If a pulp is added to the reaction mixture and the cupric ion concentration is increased, the monoperoxysulfuric acid salts that are genrated in situ in the reaction mixture will simultaneously bleach the pulp.Type: GrantFiled: September 3, 1986Date of Patent: July 12, 1988Assignee: The United States of America as represented by the Secretary of AgricultureInventors: Edward L. Springer, James D. McSweeny
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Patent number: 4259147Abstract: A versatile process and apparatus is presented for producing, in high yields, many different grades of pulp from a single wood specie or for pulping any specie or type of woody material, and for storage and recycling of the by-product liquid and gaseous materials. The process of this invention is virtually pollution free, and the reactant chemicals are recoverable from the by-products. In the alternative, the by-products themselves have a commercial value which may forestall recovery of the reactants. The lignin constituent extracted from the pulp is usable as a resin binder, a wood rehardening agent, or a glue.Type: GrantFiled: October 11, 1979Date of Patent: March 31, 1981Assignee: New Fibers InternationalInventor: John Gordy
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Patent number: 4211605Abstract: An improved, three-stage process for producing high yield chemimechanical pulps from wood or other lignocellulosic materials, such as chips, whereby, in the first stage, the wood or other lignocellulosic material is treated with sulfur dioxide gas or aqueous solution of sulfur dioxide, whereby sufficient sulfur dioxide is present to provide an amount of at least about 1 percent by weight based on weight of wood or other lignocellulosic material; in the second stage, said wood is sulfonated in an aqueous solution of sodium sulfite at a temperature of between about 100.degree. C. and 150.degree. C. for between about 10 and 90 minutes, said aqueous solution having a pH of between about 6 and 8.5 at the end of said sulfonating, without reducing the pulp yield to below about 90 percent; and, in the third stage, subjecting the resulting sulfonated wood to mechanical defibration.Type: GrantFiled: August 3, 1978Date of Patent: July 8, 1980Assignee: Canadian International Paper CompanyInventors: William R. Saxton, William H. Lawford