Abstract: A three-stage bleaching process for dissolving grade pulp utilizes the sequence OP(alkaline)-Z-P and the off gas from the Z-stage is delivered to the alkaline (OP)-stage whose parameters are controlled to fully react all of the oxygen of the off gas. The filtrate or waste water from the Z-stage, at a pH below 3, serves to dilute the alkaline OP-stage pulp before Z-stage bleaching and/or for de-ashing of the P pulp following the P-stage.

Abstract: Delignification and bleaching of lignocellulosic material is enhanced after the pulp has been treated with peroxomonosulfuric acid. The starting pH of the reaction with peroxomonosulfuric acid is between 7 and 11, and the reaction is continued until a final pH of 3 to 5 obtained. Subsequently the pulp is delignified and bleached with peroxide and/or oxygen.

Abstract: A method for the production of delignified wood pulp is provided which result in said pulp's having improved delignification ratios. In accordance with preferred embodiments, brownstocks are substantially uniformly treated with aqueous alkaline solution while in a state of low consistency. The consistency is then increased to values preferably in excess of about 20% and the brownstock treated with oxygen to effect delignification. The processes of the invention provide surprising improvements over prior methods in the high strength, low lignin containing pulps may be formed thereby. These pulps can be further bleached to high brightness with less subsequent bleach chemical.

Abstract: Lignin contained in a cellulosic or lignocellulosic pulp product is removed by contacting the product with a gaseous medium containing ozone in the presence of a liquid agent which is a lower fatty acid, such a formic, acetic or propionic acid, having only a low solvent capacity for lignin; as a consequence of this treatment, lignin which is present in the product will be converted into a lignin derivative that has an increased solubility in the fatty acid and can be removed quantitatively by extraction from the lignocellulosic material. Purified pulp can thus be obtained with increased processing efficiency and without most pollution problems of prior art processing methods because the fatty acid used as the main constituent of the processing liquid in all stages of pulp production can be circulated counter-currently through the stages of the process with purification of the acid for recirculation only after its use in the digestion step where the normal starting materials of pulp production, i.e.

Abstract: A process is described in which, by the addition of formamidinesulfinic acid in association with an ozone or ozone/oxygen treatment, the viscosity and strength of wood pulps are stabilized at the level that is obtained with use of conventional, chlorine-containing bleaching processes.

Abstract: A process for preparing an explosive comprising contacting a ketone with a compound capable of producing a product, or compound, containing nitro groups for a time sufficient to obtain a product having a high-energy content and the product resulting therefrom.

Abstract: A cellulose pulp slurry is delignified in an apparatus comprising a vertical cylindrical barrel chamber, a cone-shaped bottom chamber connected to the barrel chamber and having a circular inlet formed in a lower end portion thereof, and a cone-shaped top chamber connected to the barrel chamber and having a circular outlet formed in a top end portion thereof, in which apparatus the cone-shaped top and bottom chambers converge at a convergence angle of 60 degrees or less respectively, by feeding a cellulose pulp slurry containing an alkali and oxygen and having a pulp consistency of 8 to 15% into the apparatus through the circular inlet of the bottom chamber at 70.degree. C. to 140.degree. C., and discharging the pulp slurry through the circular outlet of the top chamber, while controlling the flow speed of the pulp slurry in the barrel chamber to a level of 0.4 m/min or more.

Abstract: The present invention provides a process for bleaching and delignifying cellulose-containing products with peroxides and/or oxygen and/or ozone, wherein there is additionally used 0.01 to 2.5% by weight of cyanamide and/or cyanamide salts, referred to the dry weight of the cellulose.

Abstract: An improved process for bleaching cellulosic pulp in a first chlorination stage of a multi-stage bleaching process is provided, which involves an improved process for bleaching cellulosic pulp in a first chlorination stage of a multi-stage bleaching process, comprising: (a) admixing cellulosic pulp with a first chlorine dioxide charge and reacting the cellulosic pulp and said chlorine dioxide for a period of time ranging from about 1 second to about 10 minutes; (b) admixing the cellulosic pulp effluent obtained after step (a) wtih chlorine and chlorine dioxide and reacting the thus-obtained cellulosic pulp for a period of time ranging from 1 second to about 10 minutes; and then (c) admixing the cellulosic pulp effluent obtained after step (b) with a second chlorine dioxide charge and reacting the thus-obtained cellulosic pulp effluent for a period of time ranging from about 1 second to about 10 minutes, wherein the pH of the reaction mixture is maintained throughout the bleaching process at from about 5.

Abstract: A process is provided for a two-stage oxygen delignification of chemical pulp in which 0.01% to 1% hydrogen peroxide is incorporated into the first and, optionally the second stage. The invention is particularly suitable when the pulp is subsequently bleached with at least one chlorine dioxide stage and at least one hydrogen peroxide stage.

Abstract: Pulp of improved refinability for the production of high strength linerboard is obtained by digesting wood chips in alkaline cooking liquor, defibering, treating with oxygen and alkali in the absence of a cellulose protector, and refining. Linerboard pulp produced by this method results in improved paper strength properties. The treatment is conducted in its best mode at temperatures below 100.degree. C. to minimize pulp yield losses.

Abstract: A method of enhancing the quality of a pulp which has been subjected to a chlorine-based bleaching agent, by subjecting the chlorinated pulp to ozonation prior to an extraction stage in the bleaching sequence. The improved pulp of the present invention includes reduction of total organically bound chlorine residues in the wood pulp and adsorbed organic halides (AOX) in the effluent, and has good brightness and viscosity. The advantages of the present invention may be accomplished by means of a bleaching sequence that employs as few as four stages, namely DZED with attendant relatively lower capital investment than heretofore possible.

Abstract: The viscosity of paper pulp is maximized, while chlorine bleaching is minimized or eliminated, by subjecting the pulp suspension to multiple consecutive oxygen bleaching stages, with a countercurrent wash between O.sub.2 stages. A chelating agent--such as EDTA--may be added to the countercurrent wash liquid, and/or another chelating agent--such as DTPA--may be used to pretreat the pulp.

Abstract: An inert gas such as helium is employed as a tracer gas in a pulp and paper mill to determine the utilization of oxygen by an aqueous cellulosic pulp particularly, as well as other parameters, in an oxygen delignification or extraction in which oxygen is dissolved in the pulp and reacted to solubilize lignins and reduce the requirement for chlorine-based bleaching chemicals.

Abstract: Disclosed are modified cellulosic fibers comprising the reaction product of linear, water-wettable polysaccharides with N,N'-methylenebisacrylamide and methods of making same. The materials are useful in the preparation of products characterized by their increased bulk and absorbency.

Abstract: Ozone and chlorine are used to bleach cellulosic fibrous material pulp in the production of kraft pulp for paper and paper products, being applied together in a mixture. When the ozone and chlorine are applied simultaneously it is possible to achieve delignification to a greater extent than is possible utilizing chlorine at any level. The total chlorinated ring compounds in the bleach plant effluent are remarkably reduced utilizing the ozone-chlorine mixture, compared to all chlorine, with resulting decrease in the fish toxicity of the bleach plant effluent. Utilizing an O.sub.3 /Cl.sub.2 E.sub.o D bleaching sequence (only three stages) it is possible to obtain pulp with 90 TAPPI Absolute, or greater, brightness.

Abstract: A process is provided for activating cellulose pulp using NO and/or NO.sub.2 plus oxygen gas in the presence of nitric acid, added in an amount within the range from about 0.1 to about 1.0 gmole per kg of water accompanying the cellulose pulp at a temperature within the range from about 40.degree. to about 120.degree. C. for a time at an activating temperature of 40.degree. to 50.degree. C. of from 15 to 180 minutes, at from 50.degree. to 90.degree. C. of from 5 to 120 minutes, and at higher temperatures of from 1 to 10 minutes, followed by washing, and delignifying bleaching in an alkaline medium with or without oxygen gas and/or peroxide.

Abstract: A method of delignification of cellulosic fiber material is described. The pulp containing said cellulosic fiber material is fed in a main line containing a main reactor in which the pulp is treated with oxygen. The pulp is screened at at lest one point in the main line, and the screen reject obtained is fed in a branch line containing at least one secondary reactor for separate treatment with oxygen. According to the invention the separate treatment with oxygen is carried out without previous refining, and the screen reject thus separately treated in said branch line is returned to the main line at a point upstream of said main reactor.

Abstract: Oxygen delignification of paper pulp (comminuted cellulosic material in a slurry) at medium consistency (i.e., about 6-18%) is practiced without the necessity of a separate mixer. The pulp is drawn into the inlet of a fluidizing centrifugal pump capable of pumping medium consistency pulp. The pump typically has a vacuum system associated with it for effecting degassing of the pulp. As the pulp is pumped out of the pump outlet, oxygen gas is added to the pulp. This is accomplished utilizing a shear plate having a central opening and one or more radial bores, oxygen being introduced under pressure into the bores to pass into the pulp flowing through the plate central opening. A tube may be disposed in the bore(s) and have an oxygen permeable portion (such as a porous stone or sintered metal) extending into the central opening in the plate, the oxygen being introduced in the form of very small bubbles by the oxygen permeable portion.

Abstract: A chemical pulping process is disclosed wherein wood chips are partially defiberized such that the fibers in the chips are substantially separated from one another but sufficient interfiber bonding is maintained to preserve chip integrity and thereby provide chips having an open porous fibrous network; and the chips are subjected to chemical pulping at an elevated temperature to remove a majority of the lignin in the chips.

Abstract: Bamboo can be formed into a suitable pulp if prior to digestion it undergoes a process of shredding, washing and wet depithing. The fibers are then chemically digested preferably by a process which uses rapid pressure drops to open the fibers using the energy contained in the wet superheated fibers.

Abstract: A method for controlling an oxygen-bleaching process of lignocellulosic pulp to a desired degree of delignification.The pulp is passed at a substantially constant temperature into a bleaching reactor wherein the pulp has a substantially constant level at its outlet. The hydrostatic pressure is measured and the quantity of oxygen fed into the reactor is adjusted to reach a desired degree of delignification.

Abstract: Method and apparatus for delignifying chemical pulp by means of oxygen, in which an aqueous slurry of chemical pulp is formed, then mixed with a caustic agent, followed by contact with a delignifying fluid. Water is drained off the slurry without reduction of pressure and while maintaining temperature following which the resulting slurry is maintained under these temperature and pressure conditions for a discrete period of time. The thus-obtained treated slurry is then washed.

Abstract: A process is disclosed for the pretreatment of lignocellulosic fibrous materials prior to delingification. The process in one of its embodiments is comprised of the following steps:1. Contacting the pulp material with treated filtrate and alkali for a short reaction period of about 1 to 2 minutes at 40.degree. C.,2. Withdrawing part of the liquid phase by filtration,3. Displacing substantially all of the remaining liquid phase with treated filtrate, and4. Allowing the pulp to react under conditions normally used for alkaline extraction or oxygen delignification.The treated filtrate is obtained by subjecting the liquor removed from the pulp at steps 2 and 3 to temperature of 5.degree. to 60.degree. C. for periods of about 5 to 10 minutes. Alternatively, step 3 can be eleminated.

Abstract: A process of manufacturing cellulose pulp from wood by digesting the wood with sulphite cooking liquor containing additions of sulphide and in the presence of a quinone or hydroquinone compound. According to the invention, the mole ratio between sulphide and sulphite shall amount to 0.01-0.2, preferably 0.05.0.15, suitably 0.08-0.12.

Abstract: Lignocellulosic material is pulped by a process comprising the steps of: introducing a molecular oxygen-containing gas, such as air, into an alkaline sulfide solution containing NaOH, Na.sub.2 S and at least one cyclic organic compound selected from quinone, hydroquinone, 9,10-diketohydroanthracene and 9,10-dihydroxyhydroanthracene compounds, to oxidize at least a portion of Na.sub.2 S; delignifying the lignocellulosic material with an alkaline sulfide cooking liquor containing the oxidized alkaline sulfide solution at an elevated temperature and; then, recovering the resultant pulp from the delignification mixture.

Abstract: Mechanical pulp is bleached by a treatment with hydrogen peroxide wherein prior to or simultaneously with said treatment the mechanical pulp is subject to an oxygen pressure.

Abstract: A method of producing salts of monoperoxysulfuric acid comprising reacting together, in the presence of a catalyst consisting of cupric ions in a concentration of at least 0.01 part per milion, (a) a solution of aerated water having a pH of from about 8 to about 14, and (b) a sulfur-containing reactant, wherein said reactant comprises sulfur dioxide or a sulfite. If a pulp is added to the reaction mixture and the cupric ion concentration is increased, the monoperoxysulfuric acid salts that are genrated in situ in the reaction mixture will simultaneously bleach the pulp.

Abstract: A process is provided for reducing carbohydrate losses in the sulphate pulping of wood using sodium hydroxide and sodium sulfide, by pretreating the wood in the presence of water with oxygen gas and nitrogen oxide such as NO.sub.2 and/or NO and/or polymeric oxides and double molecules thereof, for example, N.sub.2 O.sub.4 or N.sub.2 O.sub.3, for from about 3 to about 110 minutes at a temperature within the range from about 25.degree. to about 100.degree. C., the amount of nitrogen oxide charged, calculated as monomers, being within the range from about 0.05 to about 1 kilomole per 1000 kg bone-dry wood, resulting in one or several of the following advantages: an improved yield of pulp, an improved viscosity, and a reduced requirement for bleaching chemicals in any subsequent bleaching stages.

Abstract: The extent of delignification of chemical pulps by oxygen-containing chemicals, preferably hydrogen peroxide, is enhanced by demethylating the pulp prior to such oxidative delignification, to a degree of demethylation of at least about 30%, preferably at least about 50%. Demethylation may be achieved by chemical treatment of the already-formed pulp or by modification to the pulping process to result in demethylated pulp.

Abstract: Apparatus for the mixing of gas bubbles into fiber suspensions in order to remove impurities from the fiber suspension by means of flotation is disclosed, including an inlet, an outlet including diverging upper and lower walls, an intermediate mixing section including upper and lower wall surfaces and a wing suspended between them in order to create upper and lower passages in the intermediate mixing section, the wing including an initial diverging portion, a central portion and a subsequent converging portion so that the central portion has a maximum thickness corresponding to the minimum transverse dimension for the upper and lower passages, the converging portion of the wing corresponding with the diverging upper and lower wall portions of the outlet so that the upper and lower passages diverge substantially symmetrically in the direction of flow, and an aperture for injecting a gas such as air at a location corresponding to the central portion of the wing.

Abstract: The brightness of a thermomechanical pulp can be improved if a serial multiple blowdown technique is used and a bleachant is present at an effective concentration throughout the thermomechanical pulping process.

Abstract: A small deaeration tank which may be either at atmospheric pressure on under low pressure or vacuum and a system of operating this tank which allows pulp which has been treated with oxygen to be deaerated before being washed. A closed tank would allow steam or oxygen to be recovered. Preferably it would be the same diameter as an oxygen reactor so that it could be placed on top of the reactor and be supported by the reactor. It would have no moving parts, so there would be no need for motors to be mounted on or near the tank. The deaerator is a small open tank having an inlet pipe, an outlet pipe, and a tangential swirl inducing inlet pipe. The locations and sizes of these pipes provide optimum deaeration. The swirl inducing fluid is the filtrate from the washer after the oxygen bleach.

Abstract: A gas injector element for use in a mixing apparatus having a plurality of mixing elements, where the injector element is airfoil-shaped and is installed adjacent to the first of the plurality of mixing elements. The airfoil-shaped injector is fabricated from a metal or other suitable material having a porosity within a range of 0.5 to 100 or more microns, such that fluid injected into the mixing conduit through the injector will be released from the injector and will immediately contact material flowing through the conduit without the undesirable result of bubbles of the fluid or gas flowing from the injector coalescing with larger bubbles resulting in ineffective mixing of the gas with the material in the mixer.

Abstract: An improved process for bleaching and delignifying cellulose pulp. The process comprises subjecting the pulp to a bleaching stage followed by washing, and thereafter extracting the bleached pulp as received from the bleaching stage in a caustic extraction stage in the presence of oxygen and hypochlorite. The preferred embodiment is a sequential treatment of the bleached pulp with oxygen and hypochlorite without a pulp washing step between chemical additions. The process is characterized by enhanced delignification with high brightness and high viscosity. The process is further characterized by extraction stage filtrates of improved environmental characteristics.

Abstract: A process for the delignification and bleaching of cellulose with oxygen and hydrogen peroxide, in which in a given case the delignification is carried out with oxygen in the presence of MgO, and the cellulose subsequently is bleached simultaneously with hydrogen peroxide and oxygen at a pH<5.

Abstract: The use of primary and secondary amines and certain other compounds in ferricyanide assisted oxygen delignifying bleaching of lignocellulosic pulps permits more rapid removal of a desired amount of lignin from the pulp and, hence, the retention of higher pulp viscosity.

Abstract: Delignifying bleaching of lignocellulosic materials, particularly wood pulps already partly delignified by conventional alkaline pulping processes by electrochemically generated ferricyanide in the presence of an effective amount of molecular oxygen is disclosed.Attainment of low kappa numbers employing milder temperature and pressure conditions than are employed in conventional oxygen bleaching is made possible and the process may be substituted for at least a portion of the conventional chlorine based bleaching processes which are current industry standard practice for bleaching kraft pulps.

Abstract: A pollution free pulping process wherein a lignocellulosic material is subjected to various pulping and bleaching steps without the use of sulphur and chlorine. The system is a closed one thus minimizing energy and chemical requirements while permitting one to obtain a product having excellent physical properties.

Abstract: The present invention provides a reactor adapted to simultaneously accomplish chemical reactions and operations of size reduction of the solid materials in suspension and particularly for treatment in the cellulose and/or paper pulp industry. The reactor provides an essentially closed working environment and is provided in the lower part with a rotor which creates turbulence with flows over essentially the whole volume of the closed environment and is adapted to realize said conditions of the size reduction of solid materials with intimate mixing of same with the suspending liquid.

Abstract: A process is provided for delignifying bleaching lignin-containing cellulose pulp which comprises:(1) activating cellulose pulp by reacting the pulp at a pulp consistency within the range from about 20% to about 60% and at a temperature within the range from about 20.degree. to about 130.degree. C. with a gas comprising NO.sub.2 and oxygen in the presence of water, sodium nitrate in an amount of at least 0.15 g mole per kg of water, and optionally nitric acid;(2) washing the activated pulp with water or an aqueous solution; and(3) treating the activated washed pulp with an aqueous alkaline solution at a temperature within the range from about 70.degree. to about 170.degree. C., optionally in the presence of oxygen gas until the lignin content of the pulp is so reduced that the Kappa number of the pulp is within the range from about 10 to about 60% of the Kappa number of the pulp entering the activating stage (1).

Abstract: A process is provided for pretreating particulate lignocellulosic material to remove heavy metals and resin without any delignification or defibration, which comprises washing particulate lignocellulosic material; compressing the washed material to a solids content of at least 40% to remove absorbed and excess liquid; impregnating the compressed material with an alkaline aqueous solution comprising alkali and at least one of a heavy metal ion complexing agent and a heavy metal ion reducing agent; heating the impregnated material at a temperature within the range from abut 50.degree. to 100.degree. C. for up to approximately 0.75 hour; compressing the pretreated material to a solids content of at least 40%; and separating undiluted liquor squeezed out during the compression, while maintaining conditions during the pretreating such that the pH of the squeezed-out liquor is within the range from about 4 to about 9.

Abstract: A method for batch pulp digestion with hydroxide-bearing cooking liquors in combination with continuous alkaline oxygen delignification is described. The brown stock washing plant and the connected oxygen stage are freed from oxygen-consuming black liquid by withdrawing black liquor from a pre-cook wherein cooking liquor is reacted with a surplus of hydroxide-consuming chips. Moreover, spent cooking liquor in the brown stock washing plant is displaced with spent liquor from the oxygen delignification stage (oxy-liquor) and/or alkalization spent liquor (bleaching spent liquor worth recovering because of its sodium content). A mixture of said liquors is prepared in a pressurized cooking liquor accumulator and charged to the digestion plant liquor circulation system.

Abstract: An exothermic reaction of a gas with a gas permeable material is performed in a retention vessel. Temperature control of the exothermic reaction is obtained by recirculating the gas from the top of the vessel downwardly through and co-current to the gas permeable material and removing the downwardly flowing gas at a point above the bottom of the reactor and simultaneously recirculating gas which has been cooled into the bottom of the reactor, upwardly through and counter-current to the gas permeable material and removing the gas at a point above the bottom of the reactor.

Abstract: A multi-stage process for the delignification and bleaching of lignocellulosic pulp is disclosed wherein the first alkaline extraction stage comprises extracting the pulp with caustic in the presence of oxygen and either a hypochlorite or a peroxide.

Abstract: In the delignification of chemical wood pulp with oxygen and alkali a larger reduction of the kappa number may be obtained without an increase in the charge of oxygen or alkali, provided the pulp is pretreated with a solution of sulphite or bisulphite in order to introduce hydrophilic groups in the sulphate lignin in the chemical wood pulp.

Abstract: Wood pulp is bleached in a process which includes passing pulp slurry from a chlorine tower through a washer to a downflow extraction tower which is open to the ambient atmosphere. Caustic and steam are supplied to the extraction tower as is dilution water which is introduced into the lower portion thereof. Oxygen is dissolved in the dilution water which may be at least partially comprised of recycled washer filtrate. This addition of oxygen to the dilution zone of an extraction stage enables the consumption of chemicals such as hypochlorite and/or chlorine dioxide to be reduced while still meeting required levels of pulp brightness and strength. Oxygen may be added to the extraction or other alkaline stages of a bleaching process.

Abstract: A method for producing pulp in high yield in order to achieve strength improvement and increased absorption of liquid in the end-product, the paper, whereby a lignocellulosic material is treated in liquid or gas phase in alkalic media, the treatment thereby being performed in the presence of oxygen gas. The material is then mechanically defibrated in the presence of oxygen. It is possible to perform the treatment on the material when in the form of logs, chips, shavings as well as on completely or partly separated fibres. The treatment is performed in such a combination of treatment time, temperature, charge of chemicals, oxygen gas pressure and pulp consistency that pulp yield, i.e. the ratio between the produced amount of fibre and the charged amount material, is higher than 80%, preferably within the range of 80-95%.

Abstract: This invention is a process for maintaining pulp viscosity while enhancing brightness during the oxygen bleaching stage or stages of pulp preparation in the manufacture of paper comprising adding an effective amount of melamine to paper pulp prior to the oxygen bleaching stage.

Abstract: A method provides for the continuous treatment of a porous, fibrous material such as paper pulp, with a gas, such as ozone. The material is entrained with gas and passed in a first path. The material and gas move in a path defined by a downwardly curved upper wall and an open bottom, with a baffle disposed adjacent the bottom termination of the downwardly curved wall, so that the material is separated from the gas, the material flowing in a second path and the gas in a third path, distinct from the second path. The material in the second path is moved so that it intersects the flow of gas in the third path at least once, with the gas passing through the material while remaining in the third path, until the desired treatment of the material has been achieved. Preferably the second path is a serpentine path including horizontal portions, and the third path is a substantially straight downward path. After treatment, the material is discharged in a fourth path, and the gas passes along a fifth path.