With Chlorine, Chlorine Compounds, Oxygen, Ozone, Or Per-compounds Patents (Class 162/6)
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Patent number: 4865690Abstract: Process for improving the quality of deinked papermaking pulps obtained by ecycling waste printed papers, in which:the papers are converted into a slush pulp (1),most of the ink (12) is removed (11) from this slush pulp, especially by selective primary flotation of the ink, andthe deinked pulp is washed (5) to remove the residual ink before being conveyed into the circuit (14) for utilization of the pulp,wherein the waters (24) from this washing (5) are first of all subjected to a selective secondary flotation (16) to remove (17) only the residual ink therefrom, the suspension of the remaining matter (fibers and fillers) (18-23) being subsequently mixed with the pulp (15) originating from the washing (5).The invention also relates to a plant for making use of this process.Type: GrantFiled: March 8, 1988Date of Patent: September 12, 1989Assignees: Centre Technique De L'Industrie Des Papiers, Cartons Et Cellulose, Societe de Pate A Papier Savoie DauphineInventors: Emile Bernard, Gerard Galland, Yves Vernac, Charles Doublier
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Patent number: 4820379Abstract: The present invention relates to a method of removing ink from secondary fiber by contacting a pulp of said secondary fiber with an aqueous medium in the presence of a polymeric material having a glass transition temperature in the range of from about 20.degree. C. to about 70.degree. C. and a substituted polyethylene oxide to agglomerate the ink into discrete masses and separating the agglomerated ink from the pulp-containing aqueous medium.Type: GrantFiled: May 2, 1988Date of Patent: April 11, 1989Assignee: PPG Industries, Inc.Inventor: William B. Darlington
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Patent number: 4737238Abstract: Processes for treating waste paper containing aluminum and having a high lignin content are disclosed, including producing an aqueous pulp suspension of the waste paper, screening the pulp suspension, dewatering the pulp so as to produce a first white water stream including most of the aluminum, delignifying the pulp suspension with oxygen, separating a portion of the aqueous liquid from the delignified pulp to produce a separated pulp stream and a second white water stream which is substantially free of aluminum, transferring the separated pulp to a paper mill, diluting the separated pulp stream with a dilution liquid stream in the paper mill, evaporating the second white water stream, and transferring at least a major part of the first white water stream to the paper mill for use as the dilution liquid therein.Type: GrantFiled: April 23, 1987Date of Patent: April 12, 1988Assignee: Sunds Defibrator AktiebolagInventor: Alf R. de Ruvo
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Patent number: 4618400Abstract: A method for the deinking of wastepaper which comprises converting the wastepaper to a pulp, contacting the pulp with an aqueous medium of alkaline pH containing between about 0.2 and 2 percent by weight, calculated on dry weight of the pulp, of a deinking agent which is one or a mixture of certain thiol ethoxylate compounds, and treating the resulting pulp-containing medium to remove suspended or dispersed ink. The use of a thiol ethoxylate deinking agent offers a high level of performance in such a deinking process, both from the standpoint of the overall brightness and dirt count of paper prepared from the deinked pulp. In certain specific embodiments, the invention further comprises a step for treating thiol ethoxylate containing process streams and effluents to convert the surface active deinking agent to low-foaming sulfonyl derivatives, or to degrade the deinking agent to non-surface-active matter.Type: GrantFiled: January 10, 1986Date of Patent: October 21, 1986Assignee: Shell Oil CompanyInventors: Donald L. Wood, Herbert E. Fried
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Patent number: 4586982Abstract: There is disclosed an improvement to the process for the de-inking of printed waste paper which comprises (1) treating the waste paper in a pulper at an alkaline pH with alkali silicate, an oxidatively active bleaching agent, one or more acid components selected from the group consisting of fatty acids and resinic acids containing more than 10 carbon atoms, and mixtures thereof, and a dispersing agent, and (2) separating the detached printing ink particles from the fiber suspension by either flotation, washing, or a combination thereof. The improvement comprises employing the acid and the dispersing agent in the form of an oil-in-water emulsion.Type: GrantFiled: August 27, 1984Date of Patent: May 6, 1986Assignee: Akzona IncorporatedInventors: Gunter Poppel, Hasan Ulubay
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Patent number: 4548674Abstract: Waste paper containing polymeric contaminants is broken down in the presence of an acidic aqueous solution containing at least one peracid.Type: GrantFiled: August 2, 1984Date of Patent: October 22, 1985Assignee: Interox (Societe Anonyme)Inventors: Jacques Hageman, Liliane Meyers
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Patent number: 4540467Abstract: A method and apparatus for the removal of mold core material from metal castings and for fragmentation of municipal waste material, e.g., paper products, involves heating and hydrating the materials within a pressure vessel. Chemicals active on the material to be processed or the hydration water are added during hydration to soften the material to be removed or fragmented. Excess liquid in the vessel is drained and pressurized steam is added for a selected period of time. A suitable temperature and pressure are achieved such that the moisture or liquid carried by the processed material will rapidly turn to steam or vapor when the pressure in the vessel is rapidly reduced by quickly opening an unloading means at the bottom of the pressure vessel. The sudden release of the pressure in the vessel causes the moisture to change to steam and a certain portion of the liquid in the material to flash to vapor in accordance with thermodynamic laws.Type: GrantFiled: March 21, 1984Date of Patent: September 10, 1985Inventors: Kenneth E. Grube, Vincent E. Harrington, James V. Harrington
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Patent number: 4487655Abstract: The novel, advantageous, and economical process of reclaiming printed waste paper comprises subjecting waste paper to a flotation de-inking process. The degree of whiteness of the reclaimed paper is considerably increased by the addition of specific phosphonic acid compounds to the de-inking bath. Hydroxy carboxylic acids, amino carboxylic acids, polycarboxylic acids as well as magnesium sulfate may also be added to the de-inking bath containing the phosphonic acids.Type: GrantFiled: April 6, 1984Date of Patent: December 11, 1984Assignee: Benckiser-Knapsack GmbHInventors: Siegfried N/o/ etzel, Margarete Scholl, Heinz Ballreich
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Patent number: 4416727Abstract: A process is set forth for the recovery of fiber from paper waste and paper broke which paper has been treated with wet-strength resins. The process involves shredding the paper to be recovered and then subjecting the shredded paper to an alkaline solution and an oxygen containing atmosphere to liberate the paper fiber from the resin with retention of the paper fiber brightness. The liberated fiber can then be recycled through the paper web forming process. The process is particularly appropriate to the removal of thermoplastic resins from paper.Type: GrantFiled: January 11, 1982Date of Patent: November 22, 1983Assignee: Air Products and Chemicals, Inc.Inventors: Edward F. Elton, Vincent L. Magnotta
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Patent number: 4404107Abstract: Disclosed is a fine particle size hydrophobic organophilic water wettable cotton and its use as a seepage control additive in well-working fluids. Also disclosed is a process of preparing this additive which comprises reacting raw cotton, which contains its natural oils and waxes, with dry hydrochloric acid gas.Type: GrantFiled: June 1, 1981Date of Patent: September 13, 1983Assignee: Venture Chemicals, Inc.Inventors: Jack C. Cowan, Tommy Thrash, Jerry R. Rayborn
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Patent number: 4390395Abstract: The dry waste paper is directly fed in a disintegrator, functioning with a pulp consistency, at the disintegrator outlet, of between 20 and 50%, where it is disintegrated in the presence of an aqueous phase and at least one bleaching agent.Type: GrantFiled: June 23, 1981Date of Patent: June 28, 1983Assignee: InteroxInventors: Jean De Ceuster, Georges Papageorges
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Patent number: 4381969Abstract: Waste paper containing encapsulated constituents such as inks is bleached by pulping it in the presence of an aqueous alkaline solution which contains a peroxide compound such as hydrogen peroxide.Type: GrantFiled: May 22, 1981Date of Patent: May 3, 1983Assignee: InteroxInventors: Jean De Ceuster, Paul Duprez
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Patent number: 4356058Abstract: Papers containing dye substances in microencapsulated form are reprocessed by dissolving the papers in a pulper in the presence of chemical collectors and/or dispersing agents and in a neutral pH range and then feeding the dissolved pulp to the flotation or washing zone for the addition of a bleaching agent.Type: GrantFiled: April 2, 1979Date of Patent: October 26, 1982Assignee: J. M. Voith GmbHInventors: Siegbert Fischer, Lothar Pfalzer
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Patent number: 4347099Abstract: A process for the reclamation of waste paper in the presence of an aqueous alkaline solution comprises having the solution contain at least a carboxylated polymer.Type: GrantFiled: November 17, 1980Date of Patent: August 31, 1982Assignee: Solvay & Cie.Inventors: Jean De Ceuster, Paul Essemaeker
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Patent number: 4343679Abstract: Process for reclaiming waste paper without deinking which involves pulping the waste paper in the presence of soft water and then adding to the pulp thus obtained a compound capable of liberating, in aqueous solution, ions with a positive charge equal to or greater than 2.Type: GrantFiled: October 23, 1980Date of Patent: August 10, 1982Assignee: Interox (Societe Anonyme)Inventors: Jean De Ceuster, Paul Duprez
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Patent number: 4332638Abstract: The disclosure concerns a process and an apparatus for recovering fiber suspension from a mixture of different types of waste paper. The waste paper is disintegrated in a pulper to form a fiber suspension comprised of individual fibers. After perhaps passing a presorting device, the fiber suspension passes through a sorting device which separates the fibers into a long-fiber fraction and a short-fiber fraction. The two fractions are subsequently treated in different ways, generally for the purpose of cleaning the fiber fractions. Various treatment techniques are disclosed, including separating impurities from the long-fiber fraction by flotation and/or bleaching the long-fiber fraction and washing the short-fiber fraction and/or treating it by flotation for de-inking the short-fiber fraction and perhaps thereafter sorting the short-fiber fraction to remove impurities.Type: GrantFiled: March 3, 1980Date of Patent: June 1, 1982Assignee: J. M. Voith GmbHInventors: Eberhard Mauer, Siegbert Fischer, Lothar Pfalzer
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Patent number: 4283287Abstract: A flowable, non-caking aqueous slurry of sodium chlorate and sodium chloride having a weight ratio of sodium chloride to sodium chlorate between about 0.55 and 0.65, and, more preferably, about 0.59, is described. The slurry contains a solid phase essentially entirely of sodium chloride. The slurries contain from about 28 to about 33% by weight sodium chlorate, from about 15 to about 21% by weight sodium chloride, and from about 45 to about 58% by weight water.The slurries are produced by forming an initial aqueous solution of sodium chlorate and sodium chloride containing from about 28 to about 50% by weight sodium chlorate and from about 0 to about 14% by weight sodium chloride and subsequently adding sufficient sodium chloride to obtain a slurry containing from about 28 to about 33% by weight sodium chlorate, from about 15 to about 21% by weight sodium chloride, and from about 45 to about 58% by weight water.Type: GrantFiled: December 13, 1979Date of Patent: August 11, 1981Assignee: Hooker Chemicals & Plastics Corp.Inventors: Theodore H. Dexter, Willard A. Fuller
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Patent number: 4264412Abstract: Fibre recovery process for pressure-sensitive carbonless copying paper which comprises defibrating the wastage in aqueous media, preferably in the presence of a cationic quaternary ammonium surface active agent, treating the wastage with acid to destroy the microcapsules, and bleaching the defibrated wastage with a bleaching agent.Type: GrantFiled: May 22, 1979Date of Patent: April 28, 1981Assignee: The Wiggins Teape Group LimitedInventors: David J. Hasler, Peter Sinclair, Eileen H. Burns
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Patent number: 4244777Abstract: Chlorine dioxide is a specific bleaching agent for stilbene yellow dye which has been used to dye paper stock. Chlorine dioxide may be used in amounts as low as 0.25% based on the oven dry weight of the pulp fiber.Type: GrantFiled: November 7, 1979Date of Patent: January 13, 1981Assignee: Weyerhaeuser CompanyInventor: Maharaj K. Gupta
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Patent number: 4243478Abstract: Water used in the treatment of waste paper is now commonly re-cycled. Hard water is required for such processes. For maintaining the hardness of the water, the re-cycled water is hardened by dissolving calcium carbonate and carbon dioxide in it, thereby forming calcium bicarbonate. An apparatus for hardening the water comprises a mixing container with inlets for waste water, carbon dioxide, and calcium carbonate, and with outlets for foam, hardened water and undissolved calcium carbonate.Type: GrantFiled: November 24, 1978Date of Patent: January 6, 1981Assignee: J. M. Voith GmbHInventors: Lothar Pfalzer, Siegbert Fischer
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Patent number: 4231841Abstract: A de-inking composition is disclosed consisting substantially of:(A) a salt of a fatty acid of the formula: R--COO--M wherein R represents one or more hydrocarbon chains selected from the class consisting of saturated and/or unsaturated hydrocarbons; and M represents a metal selected from the class consisting of Na and K; said fatty acid salt being present in an amount between 5% and 32% with respect to the weight of the entire composition;(B) a non-ionic ethoxylated and/or propoxylated surfactant of the formula: ##STR1## wherein: Y is either H or CH.sub.3 ;R.sup.1 O represents the hydrophobic moiety of the molecule and is derived from a compound selected from the class consisting of alkylphenols of formula ##STR2## saturated primary fatty alcohols of formula R"--CH.sub.2 OH; saturated secondary fatty alcohols of formula R"' ##STR3## fatty acids of the formula R.sup.v --COOH; and mixtures thereof, wherein R', R", R"', R.sup.iv and R.sup.Type: GrantFiled: October 17, 1978Date of Patent: November 4, 1980Assignee: Montedison S.p.A.Inventors: Giulio Calmanti, Salvatore Gafa, Giovanni M. Dadea, Alfonso Gatti, Fulvio Burzio
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Patent number: 4204906Abstract: Equipment and method for treating solid waste in which a substantially nonoxidizing atmosphere is provided through which the shredded solid waste falls under gravity, unsupported and non-contacted, to prevent fusion of the plastics with each other, with other materials in the solid waste, or with the walls or components in the treating equipment. The unique atmosphere also allows a high treatment temperature to accelerate the debonding of fibrous combustible matter and fusion of the plastics into dense particles for substantially complete separation and recovery of plastics from the lighter fibrous but non-fusible combustible matter through gas classification during the fall. This same atmosphere also produces a clean, substantially, homogeneous, storageable and highly combustible fuel derived from the fibrous combustible matter.Type: GrantFiled: August 25, 1977Date of Patent: May 27, 1980Inventor: Hsin Liu
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Patent number: 4191549Abstract: A solar chemical process for converting sewer sludge from a gelatinous mass into a manageable product suitable for fertilizer includes the manufacture of a carbonaceous product by treating cellulose waste such as newspaper with sulfuric acid and heating the mixture until the cellulose product becomes substantially black. The black product is mixed with sludge in a ratio to produce a grainy product that can be chlorinated for sterility and spread as fertilizer. In a modified version of the process, coal ash is added to the sludge with the carbonaceous product for its nutrient value, and sand may be added with the coal ash to aid in aeration of the soil.Type: GrantFiled: August 22, 1978Date of Patent: March 4, 1980Inventor: Michael Boyko
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Patent number: 4108812Abstract: Disclosed are aqueous printing inks comprising an anionic dyestuff, a cationic fixing agent and ammonia or a volatile amine, and the use thereof in flexographic printing, particularly of tissue papers.Type: GrantFiled: December 1, 1975Date of Patent: August 22, 1978Assignee: Sandoz Ltd.Inventor: Erwin Grueninger
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Patent number: 4076578Abstract: Waste paper, particularly newsprint, is treated to release adhering ink particles (e.g. pigment carbon) from the paper fibers, and the ink solids (and organic contaminants) are then preferentially collected on the surface of inserted non-soap solids which have an affinity for, and are of larger size than, the ink solids. The ink-coated solids can be removed from the system by suitable physical means such as hydrocyclones, screens or decantation.Type: GrantFiled: August 2, 1976Date of Patent: February 28, 1978Assignees: Canadian Patents and Development Limited, The Ontario Paper Company Ltd.Inventors: Ira E. Puddington, Bryan D. Sparks, Ernest A. Sexton
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Patent number: 4056400Abstract: A composition which consists essentially of a mixture of oligomeric and polymeric oxidation products of cellulose, hemicellulose and lignin containing carboxy, ether and hydroxy groups as obtained by the direct oxidation of a woody plant material, preferably in an aqueous suspension thereof, using alkali hypohalite in a one stage oxidation procedure or nitrogen dioxide, alkali periodate or lead tetraacetate followed by alkali chlorite or alkali hypochlorite in a two stage oxidation procedure. The resulting oxidation products as obtained by one of these specific processes are especially valuable as additives to a surface active detergent or cleaning agent.Type: GrantFiled: July 28, 1975Date of Patent: November 1, 1977Assignees: Michael Diamantoglou, Helmut Magerlein, Rainer ZielkeInventors: Michael Diamantoglou, Helmut Magerlein, Rainer Zielke, Emery George Philomena Cornelissens
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Patent number: 3994770Abstract: Waste paper is treated to recover the fiber content thereof in a clean condition and without damaging the fibers by shredding the paper, admixing the paper with a treatment agent, retaining the paper and admixed treatment agent in a treatment zone for a period of time during which the paper is substantially completely disintegrated in the treatment agent, diluting the mixture, and processing the mixture through further treatment stations to a final flotation stage wherein the now clean fibers are separated from the liquid whereby the fibers can then be used in a further papermaking operation.Type: GrantFiled: July 25, 1974Date of Patent: November 30, 1976Assignee: J. M. Voith GmbHInventor: Heinz Lausch
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Patent number: 3951731Abstract: In a process for the production of fiber substances from waste which contains aerobically unstable components, the waste is subjected to aerobic decomposition at a temperature of at least 50.degree.C in the presence of oxygen to form a fibrous mass and then the mass is treated with solvents which dissolve these components. This eliminates the odor characteristic of fiber substances produced from waste. An arrangement for carrying out the process is also disclosed.Type: GrantFiled: November 29, 1973Date of Patent: April 20, 1976Assignee: Jetzer Engineering AGInventor: Raimund Jetzer