Abstract: A process for the manufacture of recycled paper having improved strength properties is achieved by replacing refiners by agitators, modifying extractor, applying effective amount of dispersion aids, and applying appropriate amount of dry strength additives.

Abstract: Process for repulping paper comprising providing paper comprising thermosetting resin which is the reaction product of epihalohydrin and polyamide made from polyalkylene polyamine, succinic acid and optionally another dicarboxylic acid and repulping the paper to obtain recycled pulp fibers.

Abstract: According to the present invention there is provided a method of treating reject from a plant for de-inking waste paper which reject comprises in an aqueous medium a mixture of suspended solids comprising at least ink particles, inorganic particles and fibers, which method includes the steps of (i) chemically treating an aqueous suspension comprising said reject by adding to the aqueous suspension a source of alkaline earth metal ions and a source of carbonate ions to react with the alkaline earth metal ions to form therein a composite particulate material comprising a substantially white insoluble alkaline earth metal carbonate compound precipitated by the said reaction which compound bonds to and entrains material comprising ink particles, inorganic particles and fibers contained in said reject, whereby the darkness of the reject is reduced by formation of the precipitate of the carbonate compound; and (ii) recovering the composite particulate material and delivering the composite particulate material for r

Abstract: Methods for controlling wax and other contaminants by improving the dispersion of these materials through the addition of treatment agents such as plasticizers, dispersants or wetting agents to the process of recycling paper and paperboard are disclosed. Preferred treatment agents include polymeric wetting agents, dispersants, plasticizers and combinations thereof.

Abstract: A method wherein waste cellulosic material is used as an alternative fiber source during chemical pulping to replace a fraction of the wood chips. The waste cellulosic material is fed to the digester along with wood chips. The waste cellulosic material need not be repulped or slurried prior to digestion. The wood chips may be any species of hardwood or softwood. Normal chemical pulping charges, temperatures and cooking times applied in the case of 100% wood chip pulping may be used for the co-pulping of waste cellulosic material and wood chips. Thereafter, the pulp is processed as usual for chemical pulping, including the steps of blowing the digester, washing and thickening the brown stock, and bleaching the brown stock under the normal conditions used for the component co-pulped with the waste cellulosic material. Further screening or cleaning steps may be required to remove debris from waste cellulosic material.

Abstract: A process for dissolving a binder off a fiber web bonded therewith includes treating the fiber web, which is bonded with a polymeric binder having carboxylate groups crosslinked via alkaline earth metal cations, with an aqueous solution of an alkali metal salt to form a sparingly soluble salt or complex between the anion of the alkali metal salt and the alkaline earth metal cations, and then removing the fiber freed of the binder.

Abstract: The invention relates to a process for sanitizing post-consumer wastepaper fibers for liquid packages and containers, a paper product for food packaging and a liquid food container. The process comprises providing paper fibers from a wastepaper recycle process, adding water to the paper fibers to achieve a slurry, de-watering the slurry to obtain a paper fiber stream and passing the fiber stream through a mixing device while heating the fiber stream and supplying hydrogen peroxide in the mixing device.

Abstract: A waste paper treatment process for the recycle and re-use of waste paper, which process comprises treating the waste paper, in a repulper, with a surfactant, in the absence of traditional repulper chemicals such as silicate, caustic and peroxide. The surfactant is preferably a copolymer of ethylene oxide and propylene oxide, and is used in a sufficient concentration to form ink agglomerates. The ink agglomerates are retained on the paper, rather than being removed as in waste paper deinking. The process permits the elimination of normal repulper chemicals, and reduces the amount of ink sludge generated, while providing acceptable brightness levels for the recycled pulp.

Abstract: The present invention is directed to a deinking agent with which a high-quality pulp sheet having a low Eric number can be obtained.The deinking agent for wastepaper reclamation comprises (a) an alkylene oxide adduct of an ester prepared from a dimer acid and/or polymer acid obtained from an unsaturated fatty acid having a specific number of carbon atoms, and an alcohol having a specific number of carbon atoms at a specific molar ratio, and (b) a higher fatty acid and/or higher fatty acid soap having a specific number of carbon atoms, provided that the (a)/(b) weight ratio is 95/5 to 60/40.

Abstract: Deinking of impact and nonimpact printed paper is accomplished by repulping the printed paper in an alkali aqueous medium containing a deinking composition comprising one or more nonionic surfactants and/or alkanols. The presence of the deinking composition causes ink particles to agglomerate, which are removed from the aqueous medium by size and density separation. The invention provides an agglomeration method with high ink removal from all types of impact and nonimpact printed paper.

Abstract: Repulping and/or decolorizing formulations and mixtures which include a catalytic amount of a salt of a metal such as copper, iron, silver, or nickel; a persulfate; and from 0-10% saccharide. Formulations containing a carbonate, sesquicarbonate or bicarbonate for adjusting pH are preferred. A method of repulping and/or decolorizing broke, whether containing wet strength resin or not, using the formulations or mixtures of the ingredients in the formulations.

Abstract: A process is provided for the preparation of valuable products from vinasse which contains potassium salts. The process comprises concentrating the vinasse to a dry matter content of 50-80% dry solids and separating the formed crystals in a concentration step to form a supernatant which is free of potassium salts. Ammonium sulphate is added to the vinasse before or during concentrating the vinasse.Furthermore, clarification of the supernatant is carried out to provide for the separation of betaine, PCA, succinic acid or citric acid. Filtration, or microfiltration is used for the clarification and a chromatographic separation is used for the separation of betaine as well as the other products. Potassium salts are obtained from the crystals to provide for a fertilizer.

Abstract: This invention provides an integrated system for recovering fibers from mixed grades of waste paper and simultaneously cleaning (deinking) waste fibers. The system comprises a mild alkaline pulping process with oxygen and hydrogen peroxide followed by rapid decompression of fibers and then by hot washing.

Abstract: The invention relates to aqueous dispersions containing A. C.sub.6-22 carboxylic acids and/or resinic acids and B. C.sub.6-22 oxoalcohols alkoxylated with 2 to less than 6 mol C.sub.2-4 alkylene oxides for deinking printed wastepaper.

Abstract: Hot melt wax compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline aqueous medium. The compositions comprise from about 20% to 97.5% by weight of a water-repellent wax that is a solid at 20.degree. C.; from about 2.

Abstract: Paper and paperboard can be effectively repulped by a composition of nonchlorinated oxidizing agent (persulfates) and a buffer (carbonates) yielding a pH of 7-12. The repulping composition of the present invention is particularly useful in repulping paper containing wet strength resins.

Abstract: The present invention discloses a process for treating filter rods comprising cellulose acetate tow waste comprising the steps of:a. cutting said filter rods so that fiber of said cellulose acetate have a fiber length of less than about 4 inches; andb. treating said cut filter rods with an aqueous base until at least 5% of acetyl groups on said cellulose acetate has been hydrolyzed.Filter rods treated in this manner are suitable for use in various paper products. The process of the present invention may further include a step for repulping the cut filter rods to repulp any included plugwrap.Modified fiber comprising cellulose acetate wherein at least 5% of acetyl groups on said cellulose acetate have been hydrolyzed, said fiber having a length of less than about 4 inches, are also disclosed.Paper products comprising between about 5 and about 90% of the fiber of claim 21 and paper pulp are also disclosed.

Abstract: A process of de-inking waste paper can be operated under conditions using a simple combination of chemicals to result in a waste liquor that is substantially environmentally friendly. The process comprises forming a pulp from the waste paper in a aqueous medium that has a pH of between 6 and 9 and that is substantially free of dissolved phosphate and that includes an ink-dispersing amount of polycarboxylic acid dispersing agent, and separating the ink from the pulp. The use of a cationic surfactant for promoting flotation is particularly desirable.

Abstract: A flotation process for removing toner particles from photocopied paper which utilizes the following compound as a collector: ##STR1## wherein R is an alkyl, aryl, alkylaryl or allyl group having from 4-28 carbon atoms and, preferably from 6-10 carbon atoms, and M represents an alkali metal, or alkaline earth metal radical or a hydrogen atom.

Abstract: A bleaching composition for cellulosic materials such as paper pulp, cotton and cotton blends. The chemical system of the present invention includes a mixture of sodium hydroxide, optical brighteners and an enhanced hydrogen peroxide composition including a silicate-free stabilizer. In the preferred embodiment, the silicate-free stabilizer includes a magnesium salt; an aminoalkylphosphonic acid; dipicolinic acid; and the balance water. The resulting textile goods are soft, absorbent, silicate-free with a Hunter Scale whiteness of greater than about 85. Because a silicate-free stabilizer is used, low levels of extractable solids are obtained.

Abstract: Wastepaper containing printing ink is refined in the presence of the reaction products of epoxidized derivatives of C.sub.10 -C.sub.22 carboxylic acids with alkoxylated carbohydrate-derived polyols and the detached printing ink particles are subsequently removed from the paper stock suspensions by flotation or washing.

Abstract: A process for removing a xerographic image from a substrate which comprises contacting the image with an aqueous solution comprised of water, a surfactant, ionic salts and caustic reagent.

Abstract: A method is disclosed for producing, in a continuous throughput, high quality paper from recycled waste paper utilizing high consistency, low shear pulping, followed by a series of cleaning steps to produce a wet, friable pulp which is digested and optionally bleached. The resulting pulp can be run on a paper machine alone or blended with virgin pulp to produce a paper containing at least 5 by weight recycled paper with less than 20 ppm per unit area solid non-fibrous contaminants larger than 0.3 mm.sup.2, and which may be blade coated on a high speed paper machine. A blade coated paper produced by the method is disclosed.

Abstract: Process for repulping wet strength paper containing at least one wet strength resin in which initial breakdown of the paper is conducted at a first pH and the substantial completion of the conversion to fibers is conducted at a second pH which is higher than the first pH.

Abstract: This invention relates generally to a method for extracting lignosulfonate for the manufacture of vanillin and other specialty chemicals. Specifically, the invention relates to a method for recovering lignosulfonates from newsprint comprising the steps of:a) converting newsprint to a crumb pulp comprising of from about 20% to about 50% crumb pulp fiber solids by weight on an oven dry basis and the remainder water;b) cooking the crumb pulp in a medium comprising crumb pulp and cooking acid solution selected from the group consisting of sodium bisulfite, magnesium bisulfite, ammonium bisulfite, calcium bisulfite or mixtures thereof wherein the weight ratio of cooking acid solution to the crumb pulp fiber is from about 3 to about 6 for sufficient time and sufficient temperature and pressure for lignosulfonate removal;c) separating the crumb pulp fiber from the spent sulfite liquor; andd) recovering the lignosulfonates from the spent sulfite liquor.

Abstract: A method is disclosed for producing, in a continuous throughput, high quality paper from recycled waste paper utilizing high consistency, low shear pulping, followed by a series of cleaning steps to produce a wet, friable pulp which is digested and optionally bleached. The resulting pulp can be run on a paper machine alone or blended with virgin pulp to produce a paper containing at least 5% by weight recycled paper with less than 20 ppm per unit area solid non-fibrous contaminants larger than 0.3 mm.sup.2, and which may be blade coated on a high speed paper machine. The pulp and paper produced by the methods are also disclosed.

Abstract: Hot melt polymer/fatty acid compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline pH aqueous medium.

Abstract: A method for brightening fiber from colored waste paper comprising bleaching pulp from colored waste paper with sodium hydrosulfite, formamidine sulfinic acid, or hydrogen peroxide in the presence of a selected quaternary compound.

Abstract: A composition of paper comprising 99 to 10 weight percent cellulose fibers and 1 to 90 weight percent cored cellulose fibers that are uniformly dispersed within the paper. The cored cellulose fibers are composed of a cellulose sheath that is 4 to 15 weight percent of the weight of the fiber and a cellulose acetate core. The cored cellulose fibers contain no substantial crimp and have an average length of 1 to 7 mm, a density of 1.20 to about 1.35 gm/cc, a denier 1 to 30 grams per 9,000 meters and a uniform dispersion index of less than 0.15.

Abstract: Paper pulp, especially recycled paper pulp which has been deinked, is bleached in a synergistic two-stage process first with sodium bisulfite and then with sodium borohydride. The borohydride is preferably added in an aqueous mixture with sodium hydroxide. A weak acid such as acetic acid may be added to the pulp to advance further the brightness gain.

Abstract: Methods for reducing stickies and removing ink from wastepaper fiber wherein a cationic kaolin is added to a wastepaper fiber furnish under conditions such that the kaolin attaches to the stickies or the ink and the stickies or ink are removed from the furnish using a centrifugal cleaner.

Abstract: A method is disclosed for producing, in a continuous throughput, high quality paper from recycled waste paper utilizing high consistency, low shear pulping, followed by a series of cleaning steps to produce a wet, friable pulp which is digested and optionally bleached. The resulting pulp can be run on a paper machine alone or blended with virgin pulp to produce a paper containing at least 10% by weight recycled paper with less than 20 ppm per unit area solid non-fibrous contaminants larger than 0.3 mm.sup.2, and which may be blade coated on a high speed paper machine.

Abstract: The invention is directed to a method for deinking and uncoating printed paper which comprises using a monocomponent cellulase during recycling.

Abstract: A process for removing printing inks from printed wastepaper in the presence of a deinking chemical is provided. In this process printed wastepaper is disintegrated to form a paper stock suspension and the detached printing ink particles are removed in known manner by flotation or washing in another stage. In this process, alkoxylates of blown oils are used as the deinking chemical. The deinking chemical is added during disintegration and/or before the flotation or washing step. Preferably, the printed wastepaper is disintegrated in the presence of 0.02 to 2% by weight and preferably 0.1 to 0.8% by weight, based on air-dry paper stock, of alkoxylates of blown oils. This deinking chemical also removed printing inks from paper circuit waters.

Abstract: Wastepaper containing printing ink is refined in the presence of the reaction products of castor oil with an alkoxylated fatty acid, alcohol, amine, amide, phosphate ester, polyhydroxy alcohol, or sorbitan, and the detached printing ink particles are subsequently removed from the paper stock suspensions by flotation or washing.

Abstract: Waste lignocellulosic material, for example brown kraft grocery bag and corrugated paperboard, is treated in a multi-step process to produce a recycle brownstock pulp having a sufficiently low kappa number that it may be bleached according to conventional means such that its final optical and strength properties are comparable to that of virgin pulps bleached according to similar means; biological enzymes are used in conjunction with medium consistency pulping to separate fibers and loosen contaminants, such as wax and adhesives; low temperature soaking of waste lignocellulosic material in an alkaline peroxide liquid using long reaction times is used to minimize energy consumption, degrade contaminants, and to selectively remove lignin; loosened contaminants and poorly bonding lignocellulose debris are removed by screening and cleaning methods; high consistency peroxygen cooking is used to substantially delignify the pulp and to destroy contaminants in an energy efficient manner; liquid streams are treated an

Abstract: Waste cellulosic paper products, for example, old corrugated containers are recycled employing oxygen delingnification in the presence of an alkaline material to produce a recycled pulp of lower kappa number, while maintaining adequate strength in the pulp. The recycling process preferably employs an acid pretreatment in combination with the oxygen delignification, and exposure of the waste product to the alkaline material is preferably controlled so that at any point in the delignification the waste product is exposed to not more than 50%, by dry weight, of the alkaline material based on the weight of residual lignin in the waste paper product.

Abstract: A bleaching composition for cellulosic materials such as paper pulp, cotton and cotton blends. The chemical system of the present invention includes a mixture of sodium hydroxide, optical brighteners and an enhanced hydrogen peroxide including a silicate-free stabilizer. In the preferred embodiment, the silicate-free stabilizer includes; magnesium acetate; phosphonic acid derivative or substituted phosphonic acids; dipicolinic acid; and the balance water. The resulting textile goods are soft, absorbent, silicate-free with a Hunter Scale whiteness of greater than about 85. Because a silicate-free stabilizer is used, low levels of extractable solids are obtained.

Abstract: The invention relates to a method of bleaching waste paper pulp. The pulp is first treated to a reductive chemical followed by acidification and washing or dewatering. The pulp is then subjected to ozone and then to hydrogen peroxide. The reductive chemical used is either formamidine sulphinic acid or sodium hydrosulfite.

Abstract: A method of deinking waste paper for reclamation thereof, which comprises disintegrating waste paper with an alkali in water in the presence of a polyoxyalkylene ether compound having the formulaR-O(PO)x(AO)y(PO)z-Hwherein R is an alkyl or alkenyl of 8-22 carbons, or an alkylphenyl wherein the alkyl has 4-12 carbons; PO is an oxypropylene group; and AO is an oxyethylene group, or a mixed oxyalkylene group composed of an oxyethylene group and at least one oxyalkylene group selected from the group consisting of an oxypropylene group and an oxybutylene group: and x is a numeral of 3-15, y is a numeral of 20-40, and z is a numeral of 5-20, in an amount effective as a deinking agent.

Abstract: This invention relates to a method for producing packaging materials containing reclaimed/recycled fiber by chemically hydrolyzing the fiber, treating the fiber at elevated temperature greater than 100.degree. C., adding a reduced sulfur agent to the fiber to reduce the sulfur content of the fiber by forming insoluble heavy metal sulfide compounds which precipitate from the hydrolyzed fiber, oxidizing and then washing the fiber to produce a paper pulp. Such methods of this type, generally, produce reclaimed/recycled fiber that is sufficiently hygienic for food grade and medical device packaging applications.

Abstract: A method for controlling, inhibiting the deposition of and/or for removing stickies from the surfaces of pulping and papermaking machinery in secondary fiber operations by adding an effective amount of a melamine formaldehyde-type polymer to a pulp slurry or furnish containing secondary fiber that is in contact with said machinery. Improved paper end products resulting from this method are also disclosed.

Abstract: Recycled paper pulp is de-inked by pulping it at neutral or alkaline pH with an aqueous deinking composition comprising one or more reducing agents. The preferred reducing agents are sodium bisulfite and sodium borohydride. Sodium hydroxide is preferably used to give the desired pH.

Abstract: The removal of inks, particularly hydrophilic flexographic inks, from a pulp fiber slurry is accomplished by use of a combination of (a) a non-ionic surfactant; (b) a fatty acid or salt thereof; and (c) a water-soluble cationic polymer having a molecular weight less than about 1,000,000 daltons, particularly a polymer derived from the reaction of epichlorohydrin and at least one diamine or the polymerization of aziridine.

Abstract: The invention relates to the use of compounds containing polyether chains prepared by reaction of epoxidized C.sub.10-22 carboxylic acid derivatives with polyalkylene glycols having average molecular weights of 100 to 2,000 and/or certain alkoxylated aliphatic compounds for the removal of printing inks from printed wastepaper and/or paper circuit waters.

Abstract: A two phase method for deinking printed waste paper having a mixture of printing inks is shown. The first phase is carried out in a neutral or slightly acid medium and the second phase in an alkaline medium. The first phase has disintegration, ink removal, and thickening steps. The second phase includes mixing and treating the thickened output from phase one with alkaline reagents, removal of any residual ink, and a second thickening. A third treatment of the removed ink and recycling of the media is also indicated.

Abstract: Deinked paper pulp is subjected to bleaching with sulfite or bisulfite ions and a reducing agent, preferably sodium bisulfite and sodium borohydride in aqueous alkaline solution. To assist the removal of ink particles, steam is bubbled through the pulp causing the ink particles to rise to the surface as a black foam which can be continuously removed.

Abstract: A process for treating wastepaper to remove oily waste and inorganic components, which comprises: (a) forming an organoclay treating composition in a wastepaper aqueous system; (b) contacting the wastepaper aqueous system with an amount of the organoclay effective to remove from the wastepaper oily waste and inorganic components; and (c) recovering paper pulp from the aqueous system. The process is effective in wastepaper treatment systems using both air flotation removal as well as systems utilizing water-washing processes.

Abstract: A process is disclosed for deinking pulp which has been made from paper printed with oil based ink. The process uses a surfactant component with and at least one alkoxylated diamine selected from Formula I: ##STR1## where X, Y, W and Z may be alike or different and are each independently selected from the group consisting of(i) --(CH.sub.2 --CH(CH.sub.3)--O).sub.a (CH.sub.2 --CH.sub.2 --O).sub.b --;(ii) --(CH.sub.2 --CH.sub.2)--O).sub.c (CH.sub.2 --CH(CH.sub.3)--O).sub.d --; and(iii) random copolymers of ethylene oxide and propylene oxide,wherein a, b, c and d are each selected independently to be a number between 1 and 30 so as to give an HLB value between 5-15.

Abstract: A waste paper recycling process relates to the treatment of a mixture of waste paper containing non-cellulosic contraries and printing inks, in order to release the contraries from the fibers and further to separate them from the stock in order to produce re-usable pulp for the production of paper and board.The invention has to do with new and useful improvements in methods for first removing the non-ink contraries from the fibrous mass and second releasing and then removing the ink particles from the said fibrous mass.The invention is directed to the treatment of the fiber slurry produced during the ink separation stage, after the ink releasing stage has been applied. One aim of the process is to allow both the use of the fibers and the mineral fillers contained in that slurry, for pulp and board making, and the use the solids-free water contained in the same slurry as the washing liquid in the previous ink-separation treatment, thus closing the fibers and the water circuits.