Sugar Cane, Bagasse Or Cornstalks Patents (Class 162/96)
  • Publication number: 20150041085
    Abstract: One aspect of the invention relates to a pulp composition made from agricultural renewable fibers (ARF) having low Kappa number with unexpected quality sufficient for papermaking (e.g., high strength parameters and high freeness). Another aspect of the invention relates to an ARF pulp having ISO brightness of 60% or higher, and unexpected quality sufficient for papermaking (e.g. high strength parameters and high freeness). Another aspect of the invention relates to a pulp composition made from a pulping process comprising using a high concentration of anthraquinone (AQ). The pulping process can use wood or nonwood fibers (e.g., bagasse and corn stover) to provide pulp having good paper-making quality.
    Type: Application
    Filed: October 23, 2014
    Publication date: February 12, 2015
    Inventors: Brent A. Hawkins, Fred Martin
  • Patent number: 8529731
    Abstract: Sugarcane bagasse consists of mainly three polymeric components, namely cellulose (40-45%), hemicellulose (xylan) (28-30%), and lignin (19-21%). A process is herein disclosed for fractionating sugarcane bagasse into cellulose, hemicellulose and lignin with high purity ?-cellulose, which is a useful raw material for preparing cellulose esters like cellulose triacetate and other high value-added cellulose plastics. Co-production and recovery of hemicellulose (xylan) and lignin in high yields and high purities, along with ?-cellulose, is another important feature of this process. Sugarcane bagasse consists of a material known as pith which constitutes 30-35% by weight of bagasse. Pith contains cellulose, hemicellulose, and lignin, in addition to various other ingredients and cell mass. The process described herein discloses the use of partially depithed bagasse as a preferred raw material for fractionation.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: September 10, 2013
    Assignee: Council of Scientific & Industrial Research
    Inventor: Anjanikumar Jyotiprasad Varma
  • Patent number: 8157955
    Abstract: A system for collecting ligno-cellulosic biomass over a large area to enable the commercial refining of biomass from 2,500 to in excess of 50,000 tons of biomass per day to produce ethanol or other products. The biomass is collected at a series of collection points and then transported through a network of conduit “loops” interconnecting each of the collection points and the central refining plant. The water used to transport the biomass, as a slurry, is recovered and sequentially recycled in the same pipeline system to push the biomass slurry around the system in a “loop.” The outgoing and return legs of each loop optionally are located adjacent each other.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: April 17, 2012
    Assignee: Iogen Energy Corporation
    Inventor: Patrick J. Foody, Sr.
  • Publication number: 20120047600
    Abstract: The invention provides methods for increasing lignin content in plants by expression of a cinnamoyl CoA reductase 2 (CCR2) coding sequence in the plant. Also provided are methods for reducing lignin content in a plant by down-regulation of CCR2 expression in the plant. Nucleic acid molecules for modulation of CCR2 expression and transgenic plants the same are also provided. Plants described herein may be used, for example, as improved biofuel feedstock and as highly digestible forage crops. Methods for processing plant tissue and for producing biofuels by utilizing such plants are also provided.
    Type: Application
    Filed: July 12, 2011
    Publication date: February 23, 2012
    Inventors: Rui ZHOU, Richard A. DIXON, Fang CHEN
  • Patent number: 8057635
    Abstract: A system for collecting ligno-cellulosic biomass over a large area to enable the commercial refining of biomass from 2,500 to in excess of 50,000 tons of biomass per day to produce ethanol or other products. The biomass is collected at a series of collection points and then transported through a network of conduit “loops” interconnecting each of the collection points and the central refining plant. The water used to transport the biomass, as a slurry, is recovered and sequentially recycled in the same pipeline system to push the biomass slurry around the system in a “loop”.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: November 15, 2011
    Assignee: Iogen Energy Corporation
    Inventor: Patrick Foody, Sr.
  • Patent number: 8012308
    Abstract: The present invention relates to a manufacturing method of mechanical pulp from stalks of corn, an annual plant, by adding a digesting agent and, prior to, during or following addition of the digesting agent, completely separating fibrous material from the cornstalks by mechanical refining. The method of the present invention comprises: (1) a first digesting process of adding 0.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: September 6, 2011
    Inventor: Hai-il Ryu
  • Patent number: 7988822
    Abstract: A method to chemically treat light weight, bulky cellulosic material including: introducing the material to an upper inlet of a substantially vertical treatment vessel; maintaining the material in the vessel at a pressure of at least 20 bar and at a temperature of at least 200° C.; treating the material with a cooking liquor in the vessel; moving the material past at least one anti-compression ring on an inside surface of the vessel, as the material moves downward through the vessel; agitating the material in the vessel, and discharging the treated material from a lower discharge port of the vessel.
    Type: Grant
    Filed: September 8, 2008
    Date of Patent: August 2, 2011
    Assignee: Andritz Inc.
    Inventor: C. Bertil Stromberg
  • Patent number: 7892397
    Abstract: A process for producing dissolving pulp includes a degumming step using a degumming liquor which includes hydrogen peroxide and ammonia.
    Type: Grant
    Filed: May 23, 2008
    Date of Patent: February 22, 2011
    Assignee: Alberta Innovates - Technology Futures
    Inventors: Keith Luo, Wade Chute
  • Patent number: 7887672
    Abstract: A method for extracting such natural cellulosic fiber bundles from natural cellulose sources selected from the group consisting of cornhusk, cornstalk, switchgrass leaves, switchgrass stems, rice straw, sorghum leaves, sorghum stems, soybean straw, wheat straw, cotton stems, barley straw, and combinations thereof, the method comprising performing an alkali treatment to partially delignify the cellulose source material and an enzyme treatment to depolymerize hemicellulose, break covalent links between lignin and carbohydrates, and decompose cellulose chains in the natural cellulosic source material, or a combination thereof thereby yielding extracted natural cellulosic fiber bundles having a length that is greater than that of individual cells and a fineness of at least about 1 denier and no greater than about 300 denier.
    Type: Grant
    Filed: February 16, 2007
    Date of Patent: February 15, 2011
    Assignee: University of Nebraska-Lincoln
    Inventors: Yiqi Yang, Narenda Reddy
  • Publication number: 20090020246
    Abstract: The present invention relates to a manufacturing method of mechanical pulp from stalks of corn, an annual plant, by adding a digesting agent and, prior to, during or following addition of the digesting agent, completely separating fibrous material from the cornstalks by mechanical refining. The method of the present invention comprises: (1) a first digesting process of adding 0.
    Type: Application
    Filed: November 22, 2005
    Publication date: January 22, 2009
    Inventors: Hai-Il Ryu, Hook Hong
  • Patent number: 7186316
    Abstract: Disclosed is a method for preparing paper pulp from cornstalks comprising the steps of cooking, washing, screening, thickening, bleaching, beating and drying performed under moderate conditions which have little noxious effects on the environment. By using cornstalks as raw materials for paper pulp, it becomes possible to replace import of wood raw materials, to save foreign currency, to increase rural income, and to make high quality paper.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: March 6, 2007
    Assignee: CP & P Co., Ltd.
    Inventors: Haiil Ryu, Chul Kap Kim, Jong-Myoung Won
  • Patent number: 7074300
    Abstract: The present invention comprises an improved method for refining cellulose that produces a highly refined cellulosic material. The method comprises soaking raw material in a mild NaOH using reduced temperatures and pressures, and refining the material with a plate refiner so that a waste water stream is reduced in volume and has a pH within a range of 8 to 9. The present invention also comprises a HRC gel having a lignin concentration of at least about one (1)% by weight, and a water retention capacity of about 25 to at least about 56 g H2O/g dry HRC.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: July 11, 2006
    Assignees: Regents of the University of Minnesota, Agricultural Utilization Research Institute
    Inventors: Brock Lundberg, Lin Gu, Rongsheng Roger Ruan, Ling Chen, Paul Bradley Addis, Jack Edgar Johnson
  • Publication number: 20040256065
    Abstract: A new method for making pulp out of agricultural residue includes harvesting certain portion of plant stalk. The harvested plant stalk is bailed, transported and stored. At the mill, the plant stalk is chopped and goes through pulping process. The pulp is used to make varieties of papers with or without blending other wood based pulp.
    Type: Application
    Filed: June 18, 2003
    Publication date: December 23, 2004
    Inventors: Aziz Ahmed, Jong-Myoung Won, Haiil Ryu
  • Publication number: 20040188044
    Abstract: The invention relates to a process for the preparation of lignocellulosic substrates having a high digestibility. This process consists in bringing said lignocellulosic substrates, which have been ground beforehand and optionally moistened in the case of dry substrates, in a stirred reactor, into contact with ozone produced from a carrier gas, the ozone being present in the carrier gas in a concentration of between 80 and 200 g/m3 NTP, with a residence time of between 8 and 40 min in said reactor.
    Type: Application
    Filed: December 19, 2003
    Publication date: September 30, 2004
    Inventors: Alain Bailli, Christian Coste, Michel Dubois
  • Publication number: 20040163782
    Abstract: Through-air dried (“TAD”) fibrous structures, especially TAD fibrous structures incorporated into sanitary tissue products, that comprise a short fiber furnish having a length of from about 0.4 mm to about 1.2 mm and a coarseness of from about 3.0 mg/100 m to about 7.5 mg/100 m, and processes for making such TAD fibrous structures are provided.
    Type: Application
    Filed: February 25, 2003
    Publication date: August 26, 2004
    Inventors: Diego Antonio Hernandez-Munoa, Kenneth Douglas Vinson, Dale Gary Kavalew, Patrick Kip Edwards, John Allen Manifold
  • Publication number: 20040163781
    Abstract: Fibrous structures, especially fibrous structures incorporated into facial tissue, toilet tissue and paper towel and napkin products, that comprise a fiber having a length of from about 0.4 mm to about 1.2 mm and a coarseness of from about 3.0 mg/100 m to about 7.5 mg/100 m, wherein the fibrous structures exhibit a lint value of greater than about 3.5 to about 15, and processes for making such fibrous structures are provided.
    Type: Application
    Filed: February 25, 2003
    Publication date: August 26, 2004
    Applicant: The procter & Gamble Company
    Inventors: Diego Antonio Hernandez-Munoa, Kenneth Douglas Vinson, Dale Gary Kavalew, Patrick Kip Edwards, John Allen Manifold
  • Publication number: 20040079499
    Abstract: Discrete particles of cellulosic material are flowable and meterable. They are easily dispersible in an aqueous or a dry medium. The particles comprise singulated cellulose fibers that have been densified. The particles have a density of at least 0.3 g/cc.
    Type: Application
    Filed: October 25, 2002
    Publication date: April 29, 2004
    Inventors: Ramon C. Dezutter, Michael R. Hansen
  • Publication number: 20040040680
    Abstract: A papermaking process, and a paper product made from the process, wherein a biodegradable plastic is used with papermaking material. The biodegradeable plastic may be provided as a substrate, with the papermaking material being applied to the substrate. The papermaking material may include recycled paper fibers and/or agricultural crop material. Recycled wood fibers may be applied in a fibrous state or agricultural plant material may be powdered and applied to the substrate. The surface material is affixed to the substrate by the application of heat and pressure or by the use of vegetable slime juice as an adhesive.
    Type: Application
    Filed: September 2, 2003
    Publication date: March 4, 2004
    Inventor: Sachiko Iwasaki
  • Patent number: 6666951
    Abstract: An improvement in the process for the production of articles from lignocellulosic material and a formaldehyde based resin binder comprising the step of treating the lignocellulosic material prior to combining it with the binder by exposing the lignocellulosic material to an acidic environment.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: December 23, 2003
    Inventor: Darren J. Kostiw
  • Publication number: 20030196771
    Abstract: The use of corn starch and corn cobs and husks as the main materials in the producton of paper is very inportant at this time.
    Type: Application
    Filed: April 22, 2002
    Publication date: October 23, 2003
    Inventor: Judith Kay Shaull
  • Patent number: 6562191
    Abstract: A process based on formic acid cooking for producing pulp from herbaceous plants and deciduous trees by using acetic acid as an additional cooking chemical. The obtained pulp can be used in fine paper and board production as short-fibered material, for instance. The invention also relates to a process for adjusting the hemicellulose content of the pulp in connection with the formic acid cooking by using acetic acid as an additional cooking chemical.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: May 13, 2003
    Assignee: Chempolis Oy
    Inventors: Pasi Rousu, Päivi Rousu, Esa Rousu
  • Patent number: 6548659
    Abstract: Process for enriching the organic nitrogen content of commercial scale quantities of cellulosic materials which includes the steps of: a) placing substantially dry or unwetted cellulosic material in a pressurizable reactor; b) injecting an ammonia or ammonia-forming nitrogen solution into the reactor until the cellulosic material is approximately submerged; c) setting the temperature in the reactor to maintain a liquid temperature between about 80 and 200° C.; d) pressurizing the reactor to at least 750 psi; e) maintaining the temperature and pressure in the reactor for a period of time sufficient for the organically bound nitrogen content of the cellulosic material to exceed about 1.5%; and f) drying the cellulosic material to a moisture content sufficiently low to arrest microbial activity.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: April 15, 2003
    Assignee: The Board of Supervisors of Louisiana State University & Agricultural & Mechanical College
    Inventors: Gary Breitenbeck, Keith Kember
  • Patent number: 6506435
    Abstract: An improved method for refining cellulose that produces a highly refined cellulosic material comprising soaking raw material in a mild NaOH using reduced temperatures and pressures, and refining the material with a plate refiner so that a waste water stream is reduced in volume and has a pH within a range of 8 to 9. Also, a HRC gel having a lignin concentration of at least about one (1)% by weight, and a water retention capacity of about 25 to at least about 56 g H2O/g dry HRC is provided.
    Type: Grant
    Filed: November 3, 1999
    Date of Patent: January 14, 2003
    Assignees: Regents of the University of Minnesota, Agricultural Utilization Research Institute
    Inventors: Brock Lundberg, Lin Gu, Rongsheng Roger Ruan, Ling Chen, Paul Bradley Addis, Jack Edgar Johnson
  • Patent number: 6379495
    Abstract: Process for the production of cellulose paper pulps from vegetable masses, comprising the steps of mixing and conditioning a vegetative mass suitable to form a culture medium with an inoculum constituted of edible ligninolythic mushrooms, such as Lentinus edodes, Pleurotis Peryngii, Psajor-caju, and the like; extracting the so-obtained enzyme and adding it to the vegetative material for the production of paper pulp, mainly constituted of cultivated annual plants such as kenaf, hemp, flax, cotton and various stems and/or agricultural-industrial residues, such as cereal straws, maize stalks, and the like; conditioning and causing the mass to react; and lastly washing the mass after the biological attack, obtaining in this way a cellulose pulp to be submitted to possible mild final cooking and bleaching treatment. Apparatus for the realiztion of the process, and cellulose pulps obtained by biodelignification of cultivated annual plants and/or agricultural-industrial residues.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: April 30, 2002
    Assignees: Consiglio Nazionale Delle Ricerche, Universita' Studi Della Tuscia
    Inventors: Giovanni Giovannozzi Sermanni, Pier Luigi Cappellletto, Ruggero Baldo, Antonio Porri, Alessandro D'Annibale, Claudio Perani
  • Patent number: 6372086
    Abstract: Processes are disclosed for extracting sugar rich liquor from sugar cane. The sugar cane is first treated by pulping it in two tub type pulpers having a rotating impeller. The contents of the first pulper are extracted through the bedplate of the extractor and are forwarded onto the second pulper. The contents of the second pulper are extracted through the bedplate of the extractor and are forwarded to form a mat on a moving belt countercurrent extractor of the type having a foraminous belt. Negative pressure is applied below the belt to assist the extraction of a sugar rich liquid component through the belt. The material passes through several separation zones as it travels on the belt with liquid applied to the mat from a region above the belt. The extracted liquid component is collected for further processing.
    Type: Grant
    Filed: October 9, 2000
    Date of Patent: April 16, 2002
    Assignee: Kadant Black Clawson Inc.
    Inventors: Michael A. Sieron, Kirk A. King, Steven T. Haywood
  • Patent number: 6348127
    Abstract: A process for production of chemical fibrous pulp for making paper, paperboard and other fibrous products from herbaceous plants, such as kenaf. Pulp from the herbaceous plant is made by a process which involves densification of pieces of all or part of the plants; i.e., both the core and the stalk or just the core portion, into cubes or pellets having a density ranging from about 15 to about 70 lbs/ft3, preferably from about 25 to about 50 lbs/ft3, which are then chemically digested to produce a fibrous pulp. The densified cubes or pellets may be digested alone or together with conventional wood chips. A principal advantage of the invention is that the densified cubes or pellets exhibit significantly better yield and strength after treatment by conventional chemical pulping methods as compared with the undensified material, enabling more efficient and economical use of this material to supplement limited supplies of conventional hardwood and softwood pulp sources.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: February 19, 2002
    Assignee: International Paper Company
    Inventors: Hugh P. Gallagher, Nelson F. Hill, Curtis P. Koster, Robert F. Cassidy
  • Patent number: 6302997
    Abstract: A process for producing a pulp suitable for papermaking from a nonwood fiber source material. Representative nonwood fiber source materials include corn stover and wheat straw. The process includes the steps of providing a nonwood fiber source material; digesting the nonwood fiber source material with an alkaline pulping solution at at least about atmospheric pressure; reducing the pH of the nonwood fiber source material to an acidic pH with an acid solution; treating the nonwood fiber source material having an acidic pH with ozone; and treating the nonwood fiber source material with a bleaching solution to form a papermaking pulp.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: October 16, 2001
    Assignees: North Carolina State University, HurterConsult Incorporated
    Inventors: Robert W. Hurter, Medwick V. Byrd, Jr.
  • Publication number: 20010023749
    Abstract: A method for processing straw pulp that includes caustic treatment is provided. The caustic treated straw pulp can be incorporated into a papermaking furnish to provide a paper product. The caustic treated pulp imparts strength to papers incorporating the pulp.
    Type: Application
    Filed: November 4, 1998
    Publication date: September 27, 2001
    Applicant: WEYERHAEUSER COMPANY
    Inventors: WAYNE H. NAY, WILLIAM S. FULLER
  • Patent number: 6258207
    Abstract: High-yield chemimechanical lignocellulosic pulp is produced from non-woody species by cutting and screening the non-woody species, soaking them in an acidic aqueous solution preferably containing a chelating agent, treating the washed non-woody species with an alkaline peroxide solution containing a second chelating agent, and mechanical refining. To further increase the bleaching efficiency the non-woody species are impregnated with ozone or peracetic acid. The resulting pulp has a relatively high brightness while the consumption of peroxide is reduced compared to prior art processes.
    Type: Grant
    Filed: April 19, 1999
    Date of Patent: July 10, 2001
    Assignee: Alberta Research Council Inc.
    Inventor: George X. Pan
  • Patent number: 6251221
    Abstract: The method of the invention involves treating cellulosic vegetable matter (the “Feed Stocks”) for the selective recovery of lignin (when present in the feed-stock), cellulose and hemi-celluloses by: (1) reducing the material to be processed to an appropriate size; (2) adjusting the moisture content of the ligno-cellulosic feed stock to 15 percent to 30 percent water; (3) impregnating the ligno-cellulosic feed stock with an extraction liquor containing a glycol and an organic or Lewis acid; (4) rapid heating of said impregnated feed stock to a temperature of about 118° C. to about 145° C.; (5) maintaining the desired temperature for about 1 minute to about 6 minutes to solubilize the lignin therefrom (a period of about 2 minutes to about 5 minutes is preferred); (6) stopping the reaction immediately by lowering the temperature to <100° C.
    Type: Grant
    Filed: January 11, 1999
    Date of Patent: June 26, 2001
    Inventor: Leonard Burkart
  • Patent number: 6187136
    Abstract: A process for production of a lignocellulosic material modified by conjugation thereto of a phenolic substance comprising a substituent which, in the conjugated form of the phenolic substance, is, or may become, negatively or positively charged, respectively, comprises: reacting a lignocellulosic fibre material and the phenolic substance with an oxidizing agent in the presence of an enzyme capable of catalyzing the oxidation of phenolic groups by the oxidizing agent; and reacting together the products of the reactions; with the proviso that the phenolic substance is not a phenolic polysaccharide. A strengthened lignocellulose-based product (e.g. a paper product) may be prepared by a procedure wherein a product produced in accordance with the latter process is treated with a strengthening agent having an ionic charge of sign opposite to that which is conferred on the modified lignocellulosic material by the charge-conferring substituent.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: February 13, 2001
    Assignee: Novo Nordisk A/S
    Inventors: Lars Saaby Pedersen, Claus Felby, Niels Munk
  • Patent number: 6179959
    Abstract: A method of making kenaf pulp of the present invention is formed of a first process of cutting at least one of core, rind, root and stalk of kenaf into chips with a predetermined length; a second process of crushing the chips of kenaf by mixing the chips with water in a crushing device; and a third process of boiling the crushed chips with water, so that fibers of kenaf are separated into make the kenaf pulp. Accordingly, the kenaf pulp can be formed without chemical processing.
    Type: Grant
    Filed: November 4, 1999
    Date of Patent: January 30, 2001
    Inventors: Yoshiaki Kamano, Kunio Hiraga
  • Patent number: 6110323
    Abstract: A method of creating a number of separate product streams from an agricultural waste material, comprising: providing a starting material consisting of an agricultural waste material; hydrolyzing the starting material with an acid solution at atmospheric pressure, and temperatures not exceeding about 100.degree. C., to create an absorbent, hydrolyzed solid residue and a xylose-containing liquor; reserving the xylose-containing liquor; and delignifying the hydrolyzed solid residue with a basic solution, to create a fiber solid residue suitable for use as an absorbent material, and a dissolved lignin-containing solution.
    Type: Grant
    Filed: August 3, 1999
    Date of Patent: August 29, 2000
    Assignee: Betafoods Corporation
    Inventor: Charles Marsland
  • Patent number: 5958186
    Abstract: Nonwoven material produced by hydroentanglement of a wet-laid or foam-formed fibre web. The material comprises a mixture of short plant fibres, in particular pulp fibres, and long hydrophillic plant fibres, where the major portion of the fibres presents a fibre length which is at least 10 mm, whereby the portion of long fibres is at least 1 weight-% of the fibre weight. The fibres were mixed with each other in the presence of a dispersing agent which allows a uniform fibre formation, in a wet-laid or foam-formed fibre web which has been hydroentangled with sufficient energy to form a compact absorbing material.
    Type: Grant
    Filed: March 19, 1997
    Date of Patent: September 28, 1999
    Assignee: SCA Hygiene Products Aktiebolag
    Inventors: Ulf Holm, Ebbe Milding
  • Patent number: 5944953
    Abstract: A corn stalk and straw chip pulping method to greatly improve the yield of pulp by 1) preconditioning the corn stalk with propionic acid when harvesting or by impregnating the straw with HNO.sub.2 in the mill after chip washing, and 2) by pulping the stalk or straw chips in a high-consistency pulper with a KOH liquor, with or without K.sub.2 SO.sub.3, at a 12 to 15 percent consistency at 90.degree. C. for a predetermined time period (30 to 60 minutes). The pulping improvement step increases the yield of corn stalk and straw pulp from approximately 40 percent to 70 to 75 percent.
    Type: Grant
    Filed: March 12, 1996
    Date of Patent: August 31, 1999
    Assignee: Le Centre Specialise en Pates et Papiers (CSPP) du College D'Enseignement General et Professionnel de Trois-Riveres
    Inventors: Pierre Lavoie, Dennis Mondor, Jean Paradis, Daniel Thibautot, Isabelle Gagne, Marco Pelletier
  • Patent number: 5718802
    Abstract: Novel fiber bundles may be produced as a by-product of sugar cane or other plants. These fiber bundles may be spun into a yarn, or formed into a non-woven mat. The non-woven mat is useful, for example, as a biodegradable geotextile for inhibiting erosion while allowing plants to become established on roadsides, or in other applications. Sugar cane fiber bundles were extracted from the Tilby-separated rind of cane stalks using alkaline treatments. The amount of lignin removed was dependent on alkaline concentration and time, pressure of treatment, and steam explosion conditions if employed. Agitation and vigorous boiling affected the lignin removal. Alkali concentration significantly affected the mechanical properties of the fiber bundles. Tenacity, toughness, and linear density were higher for the fibers extracted at lower alkali concentration. Bending rigidity and hysteresis of these fibers were also higher. This process is also expected to work with other plant stalks having a high lignin content.
    Type: Grant
    Filed: January 9, 1995
    Date of Patent: February 17, 1998
    Assignee: Board of Supervisors of Louisiana State University and Agricultural and Mechanical College
    Inventors: John R. Collier, Billie J. Collier
  • Patent number: 5705216
    Abstract: A woody or non-woody biomass is delignified through continuous extrusion technology, utilizing high-pressure steam to break down complex biomass materials. The process is useful to form a hydrophobic fiber material for use as an extrusion filler, a plastics modifier, and in the papermaking arts. Alternatively, the process is useful for preparing dietary feeds for ruminant animals, as well as to produce a broad range of alcohols or polymers from lignocellulosic substrates.
    Type: Grant
    Filed: August 11, 1995
    Date of Patent: January 6, 1998
    Inventor: George J. Tyson
  • Patent number: 5266161
    Abstract: A method and apparatus for depithing bagasse fibers wherein a horizontal perforate surface such as a screen is provided with means for delivering bagasse onto a delivery end and the screen is given sudden vertical accelerations to accelerate the bagasse upwardly separating the pith from the fibers and driving the pith down through the perforations with the accelerations repeated at sequential localized areas along the screen.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: November 30, 1993
    Assignee: Beloit Technologies, Inc.
    Inventor: Gary Kroeker
  • Patent number: 4997488
    Abstract: A synergistic combination of high-shear mechanical disruption and alkali pretreatment in a high solids reaction mixture constitutes a significant improvement in the alkaline peroxide treatment of lignocellulosic materials. The simultaneous application of these conditions greatly reduces the amounts of reagents otherwise required, and also eliminates the waste stream of liquid byproducts. Suitable sources of substrate treatable by this process include nonwoody plant parts, crop residues, and agricultural byproducts. The products of this treatment are nontoxic and characterized by high cellulose availability. These products are thereby useful as carbohydrate sources in ruminant feeds, as microbial feedstocks, and as sources of dietary fiber for humans and other monogastrics.
    Type: Grant
    Filed: November 14, 1989
    Date of Patent: March 5, 1991
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventors: John M. Gould, Brian K. Jasberg
  • Patent number: 4968385
    Abstract: A method of preparing a pulp for digestion in a continuous process from a fiber-containing cellulose material is described.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: November 6, 1990
    Assignee: Kamyr AB
    Inventors: Julio Amador, Eurico de Faria Amaro, Hans T. Haukerud, Ake Backlund
  • Patent number: 4859282
    Abstract: An improved process of purifying the product from an alkaline peroxide treatment process for delignifying and bleaching nonwoody lignocellulosic agricultural residues comprising, optionally washing with water, then lowering and maintaining the pH of the substrate at less than about pH 3.0, then washing sufficiently to remove residual chemicals, separating the product from the wash liquid and, optionally, drying the product.
    Type: Grant
    Filed: April 15, 1988
    Date of Patent: August 22, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Yu-Chia T. Chou, David F. Garrison, William I. Lewis
  • Patent number: 4859283
    Abstract: An improved process for delignifying and bleaching nonwoody, lignocellulosic material into products digestible by ruminants and ingestible by humans. The process comprises treating the substrate in an alkaline solution for a period of time and adding magnesium ions prior to adding peroxide or, alternatively, adding the magnesium to the peroxide prior to adding the peroxide to the alkaline slurry.
    Type: Grant
    Filed: April 15, 1988
    Date of Patent: August 22, 1989
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Madhusudan D. Jayawant
  • Patent number: 4857145
    Abstract: Bamboo can be formed into a suitable pulp if prior to digestion it undergoes a process of shredding, washing and wet depithing. The fibers are then chemically digested preferably by a process which uses rapid pressure drops to open the fibers using the energy contained in the wet superheated fibers.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: August 15, 1989
    Assignee: Process Evaluation and Development Corporation
    Inventor: Eduardo J. Villavicencio
  • Patent number: 4699691
    Abstract: A process for thermomechanical digestion using a multiple blowdown technique. The digestion chemical is added just prior to blowdown which results in a concentration of digesting chemicals on the fiber. The process can be carried out with a digester having multiple chambers, each at a lower pressure has many advantages in forming pulps suitable for newsprint or fine papers from wood and vegetable fiber sources. The digester should be of a kind where the fiber will have a greater residence time in subsequent chambers.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: October 13, 1987
    Assignee: W. R. Grace & Co.
    Inventor: Eduardo J. Villavicencio
  • Patent number: 4689117
    Abstract: The brightness of a thermomechanical pulp can be improved if a serial multiple blowdown technique is used and a bleachant is present at an effective concentration throughout the thermomechanical pulping process.
    Type: Grant
    Filed: September 4, 1985
    Date of Patent: August 25, 1987
    Assignee: Process Evaluation and Development Corporation
    Inventor: Eduardo J. Villavicencio
  • Patent number: 4649113
    Abstract: By treating agricultural crop residues and other nonwoody lignocellulosic plant substrates with H.sub.2 O.sub.2 at a controlled pH within the range of about 11.2 to 11.8, the substrates are partially delignified and unprecedented levels of the cellulose and hemicellulose as insoluble fractions are made available for subsequent use. The products of this treatment are nontoxic and are characterized by low crystallinity and near quantitative cellulase digestibility. They are useful as carbohydrate sources in ruminant feeds and as microbial feedstocks for commercial process such as the production of alcohol and generation of single-cell protein.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: March 10, 1987
    Assignee: The United States of America as represented by the Secretary of Agriculture
    Inventor: John M. Gould
  • Patent number: 4644060
    Abstract: The bioavailability of polysaccharide components of lignocellulosic materials can be increased substantially by treatment with ammonia in a supercritical or near-supercritical fluid state.
    Type: Grant
    Filed: May 21, 1985
    Date of Patent: February 17, 1987
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Yu-Chia T. Chou
  • Patent number: 4622100
    Abstract: The use of primary and secondary amines and certain other compounds in ferricyanide assisted oxygen delignifying bleaching of lignocellulosic pulps permits more rapid removal of a desired amount of lignin from the pulp and, hence, the retention of higher pulp viscosity.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: November 11, 1986
    Assignee: International Paper Company
    Inventors: Madhu P. Godsay, Michael N. Hull, Vacheslav M. Yasnovsky
  • Patent number: 4462865
    Abstract: Lignocellulosic materials are separated into usable lignin and cellulose fractions by contacting said materials with a 2-oxazolidinone (or a 2-imidazolidinone) in weight ratios of at least 1:0.1, respectively, at a temperature between 200.degree. C. and 250.degree. C.
    Type: Grant
    Filed: September 30, 1981
    Date of Patent: July 31, 1984
    Assignee: The Dow Chemical Company
    Inventor: Wilhelm E. Walles
  • Patent number: 4347101
    Abstract: A high quality newsprint pulp can be produced from wood or vegetable fibers by thermomechanically pulping one portion of these fibers and thermochemically pulping the remaining portion. After combining these pulps the result is a pulp which has a GE brightness of 55 to 60, an opacity of 93 to 96 percent, and a relatively high tear strength. A pulp useful for making low strength papers can be produced by solely thermomechanically pulping fiber and directly using this pulp to make such products.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: August 31, 1982
    Assignee: W. R. Grace & Co.
    Inventor: Eduardo J. Villavicencio