Reversible Chemical Reaction Patents (Class 165/104.12)
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Publication number: 20110226447Abstract: A chemical heat accumulator includes first- to Mth-stage heat storage units and a condensing part. Each heat storage unit includes a reaction vessel housing first reactant, a container housing second reactant, and a connection passage connecting the reaction vessel and the container for guiding the second reactant from the container to the reaction vessel. The connection passage is provided with an opening/closing member for opening and closing the connection passage. The reaction vessel of the Mth-stage heat storage unit is thermally connected with an object to be heated. The reaction vessel of a (N?1)th-stage heat storage unit is thermally connected with the container of an Nth-stage heat storage unit. M is an integer equal to or greater than 2, and N is an integer equal to or greater than 2 and equal to or less than M.Type: ApplicationFiled: March 17, 2011Publication date: September 22, 2011Applicant: DENSO CORPORATIONInventor: Hiroshi Mieda
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Patent number: 7988926Abstract: In a hydrogen consuming system and a method for the operation thereof wherein the system comprises a hydrogen-consuming unit and a hydrogen storage arrangement comprising a compressed gas storage part and a solid material storage part and a cooling circuit with a radiator extending through the solid material storage part and the consuming unit, hydrogen bypass lines are provided for the solid material storage part and for the hydrogen consuming unit together with control valves for selectively by-passing the solid material storage part and the hydrogen consuming unit.Type: GrantFiled: October 27, 2008Date of Patent: August 2, 2011Assignee: Daimler AGInventors: Eberhard Schmidt-Ihn, David Wenger
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Publication number: 20110067839Abstract: A system for rejecting heat from equipment using endothermic isomerization. includes a heat exchanger configured to receive an elevated-temperature process fluid and an isomerization compound capable of endothermic isomerization. When the system is in operation, heat from the elevated temperature process fluid is transferred to the isomerization compound and the isomerization compound endothermically isomerizes to a higher energy state form. A vehicle includes an engine and a body. The body houses a catalytic heat exchanger having an output in fluid communication with the engine, a pump for urging an isomerization compound into the heat exchanger, and a heat sink controller for controlling the pump. A method for rejecting heat from equipment using endothermic isomerization includes providing a compound capable of endothermic isomerization and transferring heat from a process fluid to the compound, such that the compound endothermically isomerizes to a higher energy level isomer.Type: ApplicationFiled: September 22, 2009Publication date: March 24, 2011Applicant: LOCKHEED MARTIN CORPORATIONInventors: Daniel G. Norton, Robert J. Perry, Edward H. Allen, Paul B. Glaser
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Publication number: 20100263832Abstract: A system is described for the thermochemical capture of heat energy and the transfer of this energy to a point of use using a cycle decomposing SO3 to SO2 and O2 and the subsequent oxidation of SO2 and O2 to SO3. This system can store this energy in the form of chemical energy by storing liquid SO2. Embodiments are described wherein oxygen is stored by a solid oxygen storage material or removed and added to the process by selective membranes or by electrochemical pumping. In addition, an alternative embodiment uses an electrochemical generator for the direct conversion of SO2 to electrical energy.Type: ApplicationFiled: April 16, 2009Publication date: October 21, 2010Inventor: Ralph A. Dalla Betta
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Patent number: 7780713Abstract: A pouch includes a mixture of a crystalline substance and liquid that is solid at room temperature (e.g., 70° F.) and melts when in contact with a human body, therein cooling the body.Type: GrantFiled: January 4, 2006Date of Patent: August 24, 2010Inventor: John B. Roberts
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Patent number: 7727492Abstract: An onboard hydrogen storage unit for a hydrogen powered vehicle including one or more hydrogen storage vessels at least partially filled with a hydrogen storage material which stores hydrogen in metal hydride form. During operation of the hydrogen powered vehicle heat is provided to the hydrogen storage material within the one or more hydrogen storage vessels to aid in desorption of hydrogen from the hydrogen storage material. During hydrogen refueling, heat of hydride formation is removed from the hydrogen storage material within the one or more hydrogen storage vessels to aid in absorption of hydrogen into the hydrogen storage material. The heat of hydride formation is removed from the one or more hydrogen storage vessels via a heat transfer fluid circulated and/or cooled by a stream of compressed air.Type: GrantFiled: June 14, 2006Date of Patent: June 1, 2010Assignee: Ovonic Hydrogen Systems LLCInventors: Vitaliy Myasnikov, Stanford R. Ovshinsky
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Patent number: 7712605Abstract: An elongate gas distributing tube, which extends in a longitudinal direction of a container, is accommodated within the container that constitutes a gas storage container. Discharge ports, through which the gas is discharged, are provided only on a side circumferential wall of the gas distributing tube. Therefore, the discharged gas advances while being directed toward the inner side wall of the container. The gas distributing tube is surrounded by a gas absorbing/adsorbing material. On the other hand, the gas absorbing/adsorbing material is surrounded by a mixture, which is prepared by mixing the gas absorbing/adsorbing material with a heat storage material, such that heat is absorbed by the heat storage material contained therein.Type: GrantFiled: December 18, 2007Date of Patent: May 11, 2010Assignee: Honda Motor Co., Ltd.Inventors: Takanori Suzuki, Yusuke Sogawa, Terumi Furuta
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Patent number: 7581698Abstract: A transportation vehicle includes a fluid tempering arrangement to supply a gaseous and/or liquid, heated and/or cooled, fluid such as water. At least one thermochemical reservoir is in heat exchange relation with a conduit system, having at least one valve and a controller that controls the transfer of heat between the fluid and the thermochemical reservoir to adjust the temperature of the fluid provided to an outlet. Preferably two interconnected thermochemical reservoirs respectively contain hydride-forming metals having different hydrogen sorption-desorption temperatures. By sorption and desorption of hydrogen in the two reservoirs, heat energy produced electrically during low electrical demand can be chemically stored and later released for heating the fluid during high electrical demand.Type: GrantFiled: April 25, 2005Date of Patent: September 1, 2009Assignee: Airbus Deutschland GmbHInventors: Merle Hoehne, Joachim Hoehne, Hans-Juergen Heinrich
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Patent number: 7559356Abstract: A heat transfer system comprising a primary heat exchanger for receiving heat from a heat source; a secondary heat exchanger for exhausting heat to a heat sink; a conduit connecting the primary heat exchanger and the secondary heat exchanger; and an electrokinetic pump for pumping a heat exchange fluid between the primary heat exchanger and the secondary heat exchanger through the conduit.Type: GrantFiled: April 19, 2004Date of Patent: July 14, 2009Assignee: Eksident Technologies, Inc.Inventors: Phillip H. Paul, Deon S. Anex, Don W. Arnold
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Patent number: 7531084Abstract: A reactor for the thermal cleavage of monofunctional and/or polyfunctional carbamic esters into the corresponding isocyanate and hydroxyl components in the liquid phase having devices for introduction of heat into the reactor, where the devices are heat exchanger plates through which a heat transfer medium flows and have a geometry defined by the ratio of the degassing area to the volume and arrangement of the heating surfaces which makes it possible for the cleavage to be carried out in a two-phase mixture which has a gas content of over 50% by volume.Type: GrantFiled: April 9, 2003Date of Patent: May 12, 2009Assignee: BASF AktiengesellschaftInventors: Dieter Starosta, Peter Pfab, Volker Krase, Andreas Schmidt, Matthias Kloetzer, Andreas Otterbach
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Publication number: 20090020264Abstract: A thermal storage method according to the present invention includes the steps of: (A) putting a first composition A, including an n-hydrate (where n is a hydration number) of an inorganic salt in solid phase and having a phase change temperature Tm of 100° C.Type: ApplicationFiled: February 28, 2007Publication date: January 22, 2009Inventors: Yoshio Morita, Motohiro Suzuki
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Publication number: 20080314035Abstract: A reverse flow heat exchanger is combined with an energy source to generate a temperature ladder. This system is used to create temperatures at which particles within a gas flow are combusted. Applications described include cleaning of particle laden gas, raising the temperature of a catalyst, exhaust cleaning and room air cleaning.Type: ApplicationFiled: August 29, 2008Publication date: December 25, 2008Inventor: Lincoln Evan-Beauchamp
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Patent number: 7468167Abstract: A method for quickly starting up a reactor and a reactor system therefor are provided. A shell-and-tube reactor in the system is adapted to circulate a heat medium having a solid point in the range of 50-250° C. to the outside of the reaction tubes and characterized by initiating temperature elevation of the reactor by introducing a gas of a temperature in the range of 100-400° C. to the reaction tubes' side and then circulating the heat medium in a heated state to the outside of the reaction tubes. By introducing a gas of an elevated temperature preparatorily to the reaction tubes, it is made possible to prevent the heat medium after circulation from being solidified again and enable the reactor to be quickly started up.Type: GrantFiled: September 7, 2005Date of Patent: December 23, 2008Assignee: Nippon Shokubai Co., Ltd.Inventors: Yukihiro Matsumoto, Takeshi Nishimura, Hideki Sogabe, Kazuhiko Sakamoto, Osamu Dodo
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Patent number: 7363965Abstract: An onboard hydrogen storage unit with heat transfer system for a hydrogen powered vehicle. The system includes a hydrogen storage vessel containing a hydrogen storage alloy configured to receive a stream of hydrogen and provide hydrogen for use in powering a vehicle. During refueling a cooling/heating loop is used to remove the heat of hydride formation from the hydrogen storage alloy and during operation of the vehicle the heating/cooling loop is used to supply heat to the hydrogen storage alloy to aid in hydrogen desorption.Type: GrantFiled: February 18, 2005Date of Patent: April 29, 2008Assignee: Ovonic Hydrogen Systems LLCInventors: Vitaliy Myasnikov, Rosa Young, Yang Li, Stanford R. Ovshinsky
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Patent number: 7318520Abstract: A container for use in hydrogen transfer includes structural tubular members and perforations for fluid communication with a central passage covered with a film that is selectively permeable to hydrogen, but not to other gases. The tubular member walls comprise a sturdy material to fix the hydride powder, preventing it from shifting within the container. The hydrogen flow, when being absorbed or desorbed by the metal hydride, will pass through the film both as it is absorbed in the hydride material and also after it is desorbed to pass into the central passage. Simultaneously, the tubular member material, acting as a flexible cover or support for the film, retains contaminant gases within the conduit passage, but permits hydrogen to flow therethrough. Alternatively, a flexible conduit may be interspersed within selected ones of the longitudinal structural members, and hydride material may be packed within the springs, which provide for expansion protection.Type: GrantFiled: September 27, 2004Date of Patent: January 15, 2008Assignee: Ergenics Corp.Inventor: P. Mark Golben
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Patent number: 7306750Abstract: The application of carboxylate salts for storing thermal energy is disclosed. The invention is directed to methods for the storage and use of thermal energy comprising contacting mixtures of alkali metal salts or alkali earth metal salts of carboxylic acids, storing the thermal energy in the mixture, containing the mixture in a suitable heat exchange system and using the stored thermal energy in the heat exchange system.Type: GrantFiled: May 17, 2001Date of Patent: December 11, 2007Assignee: Texaco Inc.Inventors: Jean-Pierre Maes, Serge Lievens, Peter Roose
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Patent number: 7241331Abstract: The present invention provides a metal hydride canister apparatus having structures capable of discharging hydrogen gas uniformly and exchanging heat effectively, comprising: a shell having a joint arranged in a central hole located on top of the shell, and two via holes arranged respectively at a side of the central hole; a filtering rod connecting to the joint; a pipe having a first end, a second end and a middle section between the first end and the second end; and a metal hydride stored inside the shell; wherein, the first end and the second end of the pipe pass the corresponding via hole in respective, and the middle section of the pipe forms a twin spiral structure wrapping around the filtering rod, the middle section having a first loop interconnecting to a second loop.Type: GrantFiled: March 22, 2004Date of Patent: July 10, 2007Assignee: Industrial Technology Research InstituteInventors: Chou-Zong Wu, Chi-Tang Hsu
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Patent number: 7065981Abstract: A sorption unit for air-conditioning technology apparatus with sheets for heat emission, past which water vapor is passed. The sheets are provided with zeolite bodies which are designed to have surface contact with the sheets. Channels for vapor passage are defined between bodies arranged one beside the other. Lateral grooves are formed on the top and bottom surfaces of the zeolite bodies for communicating water vapor from the surface of the zeolite bodies to the channels. A buffer section and a condenser/evaporator unit complete the sorption unit to form an air-conditioning system.Type: GrantFiled: November 8, 2004Date of Patent: June 27, 2006Assignee: Dometic AGInventor: Bengt Ebbeson
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Patent number: 6997242Abstract: An HM reservoir for storing hydrogen includes a housing and a plurality of storage units. The storage units are stacked in the interior of the housing. Each storage unit includes a pair of plate-like molded bodies and a flat heat exchanger. The plate-like molded bodies are formed by compressing powder of hydrogen storage material. The heat exchanger is provided between the molded bodies. Each molded body includes a first side and a second side, which is opposite to the first side. The first side contacts the heat exchanger. A plurality of flat hydrogen passages are formed in the interior of the housing to face the second sides of the associated molded bodies. The structure of the HM reservoir is thus simple. Further, the molded bodies of the HM reservoir smoothly absorb hydrogen and smoothly release the same.Type: GrantFiled: March 6, 2001Date of Patent: February 14, 2006Assignee: Kabushiki Kaisha Toyoda Jidoshokki SeisakushoInventors: Katsuyoshi Fujita, Hidehito Kubo, Keiji Toh, Hiroyuki Mitsui, Sinichi Towata, Kazuhiko Itoh
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Patent number: 6973963Abstract: This invention provides a compact heat exchanger that has an effective geometry for heat transfer operations regardless of the heat conductivity of the material chosen for the fin materials. It has further been found that the use of adsorbent coated anodized aluminum for fin materials provides for a very efficient heat exchanger.Type: GrantFiled: November 15, 2004Date of Patent: December 13, 2005Assignee: UOP LLCInventors: Stephen R. Dunne, Steven A. Bradley
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Patent number: 6918430Abstract: An onboard hydrogen storage unit with heat transfer system for a hydrogen powered vehicle. The system includes a hydrogen storage vessel containing a hydrogen storage alloy configured to receive a stream of hydrogen and provide hydrogen for use in powering a vehicle. During refueling a cooling/heating loop is used to remove the heat of hydride formation from the hydrogen storage alloy and during operation of the vehicle the heating/cooling loop is used to supply heat to the hydrogen storage alloy to aid in hydrogen desorption.Type: GrantFiled: August 14, 2002Date of Patent: July 19, 2005Assignee: Texaco Ovonic Hydrogen Systems LLCInventors: Vitaliy Myasnikov, Rosa Young, Yang Li, Stanford R. Ovshinsky
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Patent number: 6895779Abstract: An adsorption refrigeration device having an evaporator containing a refrigerant liquid that evaporates under the effect of a depression and an adsorbent capable of fixing the vapors (V) of the refrigerant liquid. The adsorbent is in contact with a heat exchanger containing a cooling liquid that evaporates when the adsorbent (205) is heated, and the heat exchanger includes at least one aperture to the outside atmosphere constituted by at least one hole that limits the flow rate of the vapor of the cooling liquid.Type: GrantFiled: November 9, 2001Date of Patent: May 24, 2005Assignee: ThermagenInventor: Pierre Jeuch
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Patent number: 6892798Abstract: A heat exchanger for storing or releasing heat including a channel unit in which a heat medium flows; and a heat exchange unit contacted-combined with the channel unit and containing a porous heat transfer member which conducts heat exchange with a thermal storage material.Type: GrantFiled: December 30, 2002Date of Patent: May 17, 2005Assignee: Korea Institute of Science and TechnologyInventors: Dae-Young Lee, Seo-Young Kim
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Patent number: 6823931Abstract: A hydrogen gas cooled hydrogen storage element which includes a hydrogen storage alloy material in which hydrogen flow channels are provided. The flow channels provide pathways through the hydrogen storage material to allow for high speed hydrogen gas flow. A portion of the high speed hydrogen flow is stored within the storage material which releases its heat of hydride formation. The remainder of the hydrogen flows through the hydrogen storage material at a sufficient mass flow rate to remove the heat of hydride formation. The unit also includes an encapsulant to prevent any loose particles of the storage material from becoming entrained in the high flow rate hydrogen.Type: GrantFiled: December 17, 1999Date of Patent: November 30, 2004Assignee: Energy Conversion Devices, Inc.Inventors: Ned T. Stetson, Arthur Holland, Trevor Stephenson
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Publication number: 20040231828Abstract: This invention provides a compact heat exchanger that has an effective geometry for heat transfer operations regardless of the heat conductivity of the material chosen for the fin materials. It has further been found that the use of adsorbent coated anodized aluminum for fin materials provides for a very efficient heat exchanger.Type: ApplicationFiled: May 22, 2003Publication date: November 25, 2004Inventors: Stephen R. Dunne, Steven A. Bradley
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Publication number: 20040231829Abstract: There are provided heat storage means 5 which have heat storage material 52 sealed therein and exchange heat with stored fuel F in a tank 11. AS the characteristics of saturated vapor pressure of the stored fuel F are such that rate of change of the saturated vapor pressure with respect to temperature change thereof is large in high temperature range and rate of change of the saturated vapor pressure with respect to the temperature change is small in low temperature range, the effect of the heat storage material 52 for suppressing temperature rise of the stored fuel F to thereby suppress rise of the saturated vapor pressure is larger than the effect of the heat storage material 52 for suppressing temperature drop of the stored fuel F to thereby suppress a drop of the saturated vapor pressure, so that overall effect is to suppress fuel evaporation.Type: ApplicationFiled: April 16, 2004Publication date: November 25, 2004Applicants: NIPPON SOKEN, INC., DENSO CORPORATIONInventors: Noriyasu Amano, Naoya Kato, Nobuhiko Koyama
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Patent number: 6736194Abstract: A sorber heat exchanger is provided with a substrate material incorporating a sorbent for reacting with a polar gas refrigerant or hydrogen. A preferred sorbent is a metal salt capable of reacting with the polar gas refrigerant to form a complex compound. The sorbent incorporating substrate is loaded into the reactor space between the heat transfer surfaces. Incorporating the sorbent into the substrate reduces sorbent migration thereby improving performance and life expectancy of the heat exchanger.Type: GrantFiled: December 7, 2000Date of Patent: May 18, 2004Assignee: Rocky ResearchInventors: Uwe Rockenfeller, Lance D. Kirol, Kaveh Khalili, James W. Langeliers, William T. Dooley
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Publication number: 20040031591Abstract: An onboard hydrogen storage unit with heat transfer system for a hydrogen powered vehicle. The system includes a hydrogen storage vessel containing a hydrogen storage alloy configured to receive a stream of hydrogen and provide hydrogen for use in powering a vehicle. During refueling a cooling/heating loop is used to remove the heat of hydride formation from the hydrogen storage alloy and during operation of the vehicle the heating/cooling loop is used to supply heat to the hydrogen storage alloy to aid in hydrogen desorption.Type: ApplicationFiled: August 14, 2002Publication date: February 19, 2004Inventors: Vitaliy Myasnikov, Rosa Young, Yang Li, Stanford R. Ovshinsky
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Patent number: 6672372Abstract: A hydrogen storage device for avoiding powder dispersion, having a magnetic hydrogen-absorbing material, prevents powder, generated as the hydrogen-absorbing material releases and absorbs hydrogen, from clogging pipelines, a design that can increase the gas flux and work efficiency, thus extending the device lifetime; a magnetic component having a strong magnetic field is further included to keep the magnetic property of the hydrogen-absorbing material, thus the magnetic strength of the hydrogen-absorbing material will not reduce due to the repeated residual stress actions.Type: GrantFiled: November 15, 2002Date of Patent: January 6, 2004Assignee: Industrial Technology Research InstituteInventors: Yu-Chu Li, Shih-Ming Lee, Jenn-Chen Tang
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Patent number: 6652771Abstract: The present invention relates to a powdered mix of a phase change material blend. The blend includes a polar phase change material bound substantially to at least one surface of a clay matrix having a surface charge, wherein the blend is present in a powdered form at temperatures above and below the phase change temperature of the polar phase change material. The present invention also relates to a method of making the powdered mix of a phase change material blend and a therapy pack including the powdered mix of a phase change material blend.Type: GrantFiled: February 12, 2002Date of Patent: November 25, 2003Inventor: Ronald M. Carn
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Patent number: 6530233Abstract: A hydrogen storage device prevents localization of hydrogen occlusion alloy and ensures rapid discharge of hydrogen. The hydrogen storage device has a plurality of porous molded pieces arranged longitudinally at predetermined intervals. Conductive cushioning materials are inserted between the molded pieces and between the molded pieces and an adiabatic insulation material. The conductive cushioning materials include first conductive cushioning materials inserted between the adiabatic insulation material and upper and lower end surfaces of the molded pieces and second conductive cushioning materials inserted between left and right end surfaces of the adiabatic insulation material. Disposed at opposed ends of a row of the molded pieces are movable urging electrodes which can move in response to dimensional changes of the molded pieces resulting from their volume changes and which urge the molded pieces to constantly maintain physical contact between the molded pieces and lids.Type: GrantFiled: August 22, 2000Date of Patent: March 11, 2003Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kenji Nakamura, Taketoshi Minohara
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Publication number: 20030042008Abstract: A method for storing hydrogen which combines the advantages of at least two known methods for storing hydrogen, selected amongst the methods for storing hydrogen in a gaseous form, in a liquid form and in a solid form.Type: ApplicationFiled: June 29, 2001Publication date: March 6, 2003Inventors: Robert Schulz, Guoxian Liang, Jacques Huot, Patrick Larochelle
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Patent number: 6520249Abstract: High-temperature-side hydrogen storage alloy containers each containing a hydrogen storage alloy are disposed as a heat exchanging portion in high-temperature-side heat exchangers. Low-temperature waste-heat gas generated in a micro gas turbine is imported into the heat exchangers so that direct heat exchange is performed between the waste-heat gas and each of the alloy containers. On the other hand, low-temperature-side hydrogen storage alloy containers each containing a hydrogen storage alloy are disposed as a heat exchanging portion in low-temperature-side heat exchangers. The high-temperature-side alloy containers and the low-temperature-side alloy containers are connected to each other by hydrogen-travelling pipes. Cold heat generated in the low-temperature-side heat exchangers is supplied to a refrigeration output portion.Type: GrantFiled: June 8, 2001Date of Patent: February 18, 2003Assignee: The Japan Steel Works, Ltd.Inventors: Takashi Iwamoto, Hiroyuki Togo, Masamitsu Murai, Ritsu Miura, Koji Hattori, Harunobu Takeda
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Patent number: 6478077Abstract: The present invention provides an improved internal heat exchange element arranged so as to traverse the inside diameter of a container vessel such that it makes good mechanical contact with the interior wall of that vessel. The mechanical element is fabricated from a material having a coefficient of thermal conductivity above about 0.8 W cm−1° K−1 and is designed to function as a simple spring member when that member has been cooled to reduce its diameter to just below that of a cylindrical container or vessel into which it is placed and then allowed to warm to room temperature. A particularly important application of this invention is directed to a providing a simple compartmented storage container for accommodating a hydrogen absorbing alloy.Type: GrantFiled: May 15, 2001Date of Patent: November 12, 2002Assignee: Sandia National LaboratoriesInventors: Grosvenor Cook Story, Ray Orico Baldonado
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Publication number: 20020112848Abstract: A reciprocal design for an electrochemical heat exchanger comprised of a gas-based driving system, a liquid-based cooling system, and a non-permeable flexible diaphragm to physically separate the contents of the driving system from the contents of the cooling system while maintaining a pressure based communication between the contents of the two systems. The gas-based driving system utilizes a hydrogen electrochemical pump to induce circulation of a liquid coolant through the cooling system. Said liquid coolant exchanges heat with the object to be cooled and transfers heat out of the heat exchange system by way of matched banks of radiator tubes.Type: ApplicationFiled: February 5, 2002Publication date: August 22, 2002Inventors: Boris Tsenter, Alexei Petrov
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Patent number: 6425440Abstract: A reciprocal design for an electrochemical heat exchanger comprised of a gas-based driving system, a liquid-based cooling system, and a non-permeable flexible diaphragm to physically separate the contents of the driving system from the contents of the cooling system while maintaining a pressure based communication between the contents of the two systems. The gas-based driving system utilizes a hydrogen electrochemical pump to induce circulation of a liquid coolant through the cooling system. Said liquid coolant exchanges heat with the object to be cooled and transfers heat out of the heat exchange system by way of matched banks of radiator tubes.Type: GrantFiled: July 6, 2000Date of Patent: July 30, 2002Assignee: Borst, Inc.Inventors: Boris Tsenter, Alexei Petrov
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Patent number: 6412295Abstract: A sorption device for heating and cooling gas streams, with a sorbent container which contains a sorbent that takes up a working fluid which evaporates in an evaporator that contains a quantity of working fluid in correspondence with the quantity of sorbent, with a sorbent heat exchanger which exchanges the heat between a sorbent and a sorbent gas stream, with a working fluid heat exchanger which exchanges the heat between working fluid, and with a working fluid gas stream, and a closable valve between the sorbent container and the evaporator, which valve is able to interrupt the flow of the working fluid vapor, with both the sorbent heat exchanger and the working fluid heat exchanger having at their inlets and outlets connecting elements which can be readily attached to, detached from, and exchanged for one another on the gas flow channels for supplying and discharging gas streams that are to be heated or cooled.Type: GrantFiled: June 7, 2001Date of Patent: July 2, 2002Assignee: Zeo-Tech Zeolith Technologie, GmbHInventors: Rüdiger Weiss, Jürgen Just, Hartmut Gehse, Peter Maier-Laxhuber, Reiner Worz, Andreas Becky, Leo Totschnig, Christoph Grupp
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Patent number: 6379582Abstract: The invention is a composition for thermal energy storage in heating or cooling items. The composition includes a crosslinked alkali metal polyacrylamide or polyacrylate/polyacrylamide copolymer. The alkali metal may be potassium or sodium, preferably potassium. The copolymer has a particle size of at least 1500 microns, preferably 2000-4000 microns. The composition includes water with its pH adjusted to 6.0 to 7.0. The composition also includes propylene glycol. An antimicrobial agent is included to prevent degradation due to microbial growth. A coloring agent may also be added. The composition has the appearance of crushed ice.Type: GrantFiled: March 28, 2000Date of Patent: April 30, 2002Assignee: Magic Ice, Inc.Inventor: Jimmy W. Putman
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Patent number: 6378601Abstract: A hydrogen cooled hydrogen storage unit. The unit employs excess hydrogen flow between hydrogen storage alloy rods in the hydrogen storage unit in order to provide convective cooling thereof. The unit provides for high packing density of the storage materials. The unit also allows for efficient thermal transfer of heat energy from a central source of heat through the rods thereof during discharge of the stored hydrogen. The hydrogen storage rods of the unit are encased in an encapsulant layer which prevents entrainment of the hydrogen storage material in the high flow rate hydrogen.Type: GrantFiled: May 12, 2000Date of Patent: April 30, 2002Assignee: Energy Conversion Devices, Inc.Inventors: Stanford R. Ovshinsky, Rosa T. Young
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Patent number: 6370903Abstract: A heat pump type heating and air conditioning system is provided. The heat pump comprises a series of heat exchange relationships between an internal refrigeration circuit and at least one external coolant circuit. In a preferred embodiment, a fuel cell coolant circuit and an electronics coolant circuit are in heat exchange relationship with the refrigeration circuit. A method of selectively heating and/or cooling air within a passenger compartment of a fuel cell vehicle is also provided.Type: GrantFiled: March 14, 2001Date of Patent: April 16, 2002Assignee: Visteon Global Technologies, Inc.Inventor: Dick Philip Wlech
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Patent number: 6360811Abstract: A case for a hydrogen absorption indirect heat exchanger of the present invention includes a square cylindrical portion 11 having each portion thereof formed integrally by die-casting or extrusion molding. The corners 11a of this square cylindrical portion 11 and the center portion of its side 11b are shaped to a greater thickness than that of other portions. The weight of the case can be reduced while the case powder capacity is secured.Type: GrantFiled: September 6, 2000Date of Patent: March 26, 2002Assignees: Kabushiki Kaisha Toyoda Jidoshokki Seisakusho, Toyota Jidosha Kabushiki KaishaInventors: Keiji Toh, Hidehito Kubo, Nobuo Fujita, Hiroyuki Mitsui
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Publication number: 20020017380Abstract: In a chemical heat pump a substance is used which in an efficient way interacts with a volatile liquid such as water. The substance is selected considering among other things the magnitude of its &Dgr;T and its energy content so that the heat pump becomes suited for converting low grade heat energy such as solar energy to cooling for airconditioning and also for a simultaneous production of heat for example for use as hot tap water in houses. The heat pump can also be used in a refrigerating box. Suitable substances comprise barium hydroxide, lithium hydroxide, strontium bromide and cobalt chloride. The substance is applied as a layer (23) on the surface of a heat conducting wall (22) by applying a slurry-like mixture of the substance with the liquid when being vibrated to the wall between heat conducting flanges 25). The mixture is dried under a vacuum and is heated and is simultaneously compressed by applying an exterior pressing force.Type: ApplicationFiled: May 24, 2001Publication date: February 14, 2002Inventors: Staffan Jonsson, Ray Olsson, Mona Karebring-Olsson
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Publication number: 20020006365Abstract: A hydrogen storage tank has an outer cylinder and a cylindrical hydrogen storage module within the outer cylinder spaced apart from an inner peripheral surface of the outer cylinder to provide a hydrogen passage therebetween. The cylindrical hydrogen storage module includes a lamination having a plurality of hydrogen storage units filled with powdery hydrogen absorption material and a hydrogen absorption and desorption surface on an entire outer peripheral surface, while interposing a heating/cooling element between ones of adjacent units. First and second main passages penetrate the lamination in a lamination direction of the units, and permit heating fluid and cooling fluid to flow therethrough. Sub passages branch from the main passages and extend over within each of the heating/cooling elements.Type: ApplicationFiled: April 11, 2001Publication date: January 17, 2002Inventors: Takanori Suzuki, Izuru Kanoya, Mitsuya Hosoe
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Publication number: 20010050163Abstract: High-temperature-side hydrogen storage alloy containers each containing a hydrogen storage alloy are disposed as a heat exchanging portion in high-temperature-side heat exchangers. Low-temperature waste-heat gas generated in a micro gas turbine is imported into the heat exchangers so that direct heat exchange is performed between the waste-heat gas and each of the alloy containers. On the other hand, low-temperature-side hydrogen storage alloy containers each containing a hydrogen storage alloy are disposed as a heat exchanging portion in low-temperature-side heat exchangers. The high-temperature-side alloy containers and the low-temperature-side alloy containers are connected to each other by hydrogen-travelling pipes. Cold heat generated in the low-temperature-side heat exchangers is supplied to a refrigeration output portion.Type: ApplicationFiled: June 8, 2001Publication date: December 13, 2001Applicant: JAPAN STEEL WORKS, LTD.Inventors: Takashi Iwamoto, Hiroyuki Togo, Masamitsu Murai, Ritsu Miura, Koji Hattori, Harunobu Takeda
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Patent number: 6318453Abstract: A hydrogen cooled hydrogen storage unit which employs excess hydrogen flow through flow channels between hydrogen storage alloy plates in order to provide convective cooling of the plates. The unit provides for high packing density of the storage materials and ease of expansion of storage capacity by merely adding more storage material plates. Since the hydrogen flows transversely between the plates and does not flow along the entire length of the stack, the cooling flow path of the hydrogen is short, and the temperature differential between any point of the stack and the hydrogen coolant is maximized, which maximizes the cooling efficiency of the unit.Type: GrantFiled: April 26, 2000Date of Patent: November 20, 2001Assignee: Energy Conversion Devices, Inc.Inventors: Stanford R. Ovshinsky, Rosa T. Young
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Publication number: 20010035281Abstract: An HM reservoir for storing hydrogen includes a housing and a plurality of storage units. The storage units are stacked in the interior of the housing. Each storage unit includes a pair of plate-like molded bodies and a flat heat exchanger. The plate-like molded bodies are formed by compressing powder of hydrogenstorage material. The heat exchanger is provided between the molded bodies. Each molded body includes a first side and a second side, which is opposite to the first side. The first side contacts the heat exchanger. A plurality of flat hydrogen passages are formed in the interior of the housing to face the second sides of the associated molded bodies. The structure of the HM reservoir is thus simple. Further, the molded bodies of the HM reservoir smoothly absorb hydrogen and smoothly release the same.Type: ApplicationFiled: March 6, 2001Publication date: November 1, 2001Inventors: Katsuyoshi Fujita, Hidehito Kubo, Keiji Toh, Hiroyuki Mitsui, Sinichi Towata, Kazuhiko Itoh
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Patent number: 6305186Abstract: The invention concerns a method for controlling a thermochemical reaction or a solid-gas adsorption being carried out in a reactor (10) containing an active agent capable of reversibly reacting with a gas, the reactor (10) being connected to an evaporator/condenser assembly (14) for the gas by a connection (12) without control valve, the reactor (10) and the evaporator/condenser assembly (14) each provided with means for selectively exchanging calories with their surroundings.Type: GrantFiled: August 29, 2000Date of Patent: October 23, 2001Assignee: Centre National de la Recherche ScientifiqueInventors: Xavier Py, Francis Kindbeiter
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Patent number: 6257322Abstract: In a heat-exchange unit 1a constituting a chief portion of an indirect heat exchanger 1, the streams of hot medium that flow through many small flow passages 20 in the flat tubes 2 in the upstream heat-exchange set 5, meet together in the tubular headers 4 for each of the flat tubes 2 and, then, flow again into many small flow passages 20 in the flat tubes 2 in the downstream heat-exchange set 6. Even in case some of the small flow passages 20 are clogged or constricted, all the small flow passages 20 from the upstream common header 71 to the downstream common header 72 do not become incapable of exchanging heat and do not lose the function for exchanging heat, and most of the area of the upstream side and of the downstream side can be normally used.Type: GrantFiled: July 25, 2000Date of Patent: July 10, 2001Assignee: Kabushiki Kaisha Toyoda Jidoshokki SeisakushoInventors: Keiji Toh, Hidehito Kubo
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Patent number: 6213197Abstract: A sorption unit for air-conditioning technology apparatus with sheets for heat emission, past which water vapor is passed. The sheets are provided with zeolite, that forms string-shaped profiled bodies which are designed to have surface contact with the sheets. Channels for vapor passage are defined between bodies arranged one beside the other. A buffer section and a condenser/evaporator unit complete the sorption unit to form an air-conditioning system.Type: GrantFiled: July 10, 1998Date of Patent: April 10, 2001Assignee: Electrolux Leisure Appliances AGInventor: Bengt Ebbeson
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Patent number: 6183855Abstract: A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material.Type: GrantFiled: December 20, 1999Date of Patent: February 6, 2001Inventor: Theresa M. Buckley