Compositions Patents (Class 174/137B)
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Patent number: 6140590Abstract: A stator winding insulation for improving the dielectric and thermal properties of a main insulation of a conductor bar of an electric machine. The stator winding insulation includes a mica band having at least one layer-like carrier composed of longitudinal threads and transverse threads and a mica-containing layer fixed to at least one face of the carrier with the aid of a binder. In the layer-like carrier, the volume ratio of the longitudinal threads to the transverse threads is greater than or equal to 2.5:1 and a weight ratio of the mica in the mica-containing layer to the layer-like carrier in the mica band is greater than or equal to 6:1.Type: GrantFiled: April 15, 1998Date of Patent: October 31, 2000Assignee: ABB Research Ltd.Inventors: Thomas Baumann, Jorg Oesterheld, Roland Schuler
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Patent number: 6118079Abstract: A polymer insulator having a core member, an insulation overcoat member arranged on an outer surface of the core member, and a securing metal fitting fixed to an end portion of the core member in such a manner that the end portion is contacted with the insulation overcoat member is disclosed. The disclosed polymer insulator further includes a seal portion arranged at a boundary between the insulation overcoat member and the securing metal fitting, which is made of a sealing agent in which 80-250 parts by weight of ATH (Alumina trihydrate, Al.sub.2 O.sub.3.3H.sub.2 O) is included with respect to 100 parts by weight of a polymer component. Therefore, the polymer insulator according to the invention has an improved tracking-erosion resistance performance.Type: GrantFiled: June 11, 1998Date of Patent: September 12, 2000Assignee: NGK Insulators, Ltd.Inventors: Yukihiro Koshino, Takanori Kondou
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Patent number: 6106954Abstract: A silicone rubber composition is obtained by blending (A) 100 parts by weight of an organopolysiloxane composition of the addition reaction curing type with (B) about 30-400 parts by weight of aluminum hydroxide which has been surface treated with an organosilane or organosilazane substantially free of an aliphatic unsaturated group or a partial hydrolyzate thereof so that the aluminum hydroxide has 0.01-2% by weight of carbon affixed thereto. The composition maintains silicone rubber properties even though it is loaded with large amounts of aluminum hydroxide. It cures into a silicone rubber having improved high-voltage electrical insulating properties and thus suited for use as high-voltage electrical insulators.Type: GrantFiled: December 30, 1998Date of Patent: August 22, 2000Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Noriyuki Meguriya, Syuuichi Azechi, Susumu Sekiguchi, Takeo Yoshida
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Patent number: 6040528Abstract: An electrically insulating supporting structure for a high voltage electric apparatus having a high voltage charging part and a ground potential part, the structure being adapted to be disposed between the high voltage charging part apparatus and the ground potential part. The structure includes an organic insulating structure formed in a predetermined shape, and an inorganic insulating layer formed on a surface of the organic insulating structure and an intermediate layer consisting essentially of an organic and an inorganic powder.Type: GrantFiled: October 17, 1994Date of Patent: March 21, 2000Assignee: Fuji Electric Co., Ltd.Inventors: Tadao Kitamura, Hisaji Shinohara
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Patent number: 5990610Abstract: This invention secures the breakdown voltage between stem pins or the like for high voltage service in a cathode ray tube. This insulator is formed of a clay-like silicone compound having a tip-throughhole and pin-throughholes or a stem base with the electric insulator mounted to the stem base. An inter-stem electric insulation device is structured by mounting either one of the electric insulator or the stem base with the electric insulator to the stem of a cathode ray tube and by pressing to fix together. This structure does not allow bubble generation caused by the electric insulator, and makes the handling easy, and furthermore, allows an automatic mounting of the electric insulator to a stem.Type: GrantFiled: September 12, 1994Date of Patent: November 23, 1999Assignee: Sony CorporationInventors: Shigeo Matsumoto, Takashi Setsuda, Haruo Ito, Kazuyuki Ota
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Patent number: 5977487Abstract: The invention relates to a high voltage insulator of ceramic material, which includes a longitudinal shank having molded sheds and to whose ends of the shank metal caps are shrink-fitted. The ends of the longitudinal shank are enlarged so that the diameter of the enlarged ends is at least 1.05 times the diameter of the longitudinal shank. The cylindrical surface, and the end face of the enlarged ends of the longitudinal shank are machined.Type: GrantFiled: December 23, 1997Date of Patent: November 2, 1999Assignee: Hoechst CeramTec AktiengesellschaftInventor: Martin Kuhl
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Patent number: 5977280Abstract: A method of thickening solvents involves reacting (A) an .ident.Si--H containing polysiloxane with (B) an alkene such as an alpha, omega-diene; conducting the reaction in the presence of a platinum catalyst and (C) a solvent; continuing the reaction until a gel is formed by crosslinking and addition of .ident.Si--H across double bonds in the alpha, omega-diene; adding additional solvent and a post cure terminating agent to the gel; and subjecting the solvent, the post cure terminating agent, and the gel to shear force until a paste is formed. The post cure terminating agent is an amino acid ester, preferably a sulfur containing amino acid ester, such as methionine methyl ester, methionine ethyl ester, cysteine methyl ester, cysteine ethyl ester, and cystine dimethyl ester.Type: GrantFiled: November 5, 1997Date of Patent: November 2, 1999Assignee: Dow Corning CorporationInventors: Donald Anthony Kadlec, William James Schulz, Jr., Shizhong Zhang
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Patent number: 5962569Abstract: A non-tacky electrical stress control material comprisinga) about 100 parts of a resin component containing1) from about 20% to about 80% of an epihalohydrin polymer, and2) correspondingly, from about 80% to about 20% of an insulating silicone polymer having a tan .delta. of less than one,b) from about 10 to about 200 parts of a filler, said filler being nonconductive at room temperature, selected from the group consisting of barium titanate and hydrated aluminum silicate, andc) from 0 to 30 parts of a plasticizer.Type: GrantFiled: June 23, 1998Date of Patent: October 5, 1999Assignee: 3M Innovative Properties CompanyInventors: Thomas J. D. Heyer, Robert A. Wandmacher
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Patent number: 5804630Abstract: A non-tacky electrical stress control material comprisinga) about 100 parts of a resin component containing1) from about 20% to about 80% of an epihalohydrin polymer, and2) correspondingly, from about 80% to about 20% of an insulating silicone polymer having a tan .delta. of less than one,b) from about 10 to about 200 parts of a filler, said filler being nonconductive at room temperature, selected from the group consisting of barium titanate and hydrated aluminum silicate, andc) from 0 to 30 parts of a plasticizer.Type: GrantFiled: August 8, 1996Date of Patent: September 8, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Thomas J. D. Heyer, Robert A. Wandmacher
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Patent number: 5723813Abstract: The present invention provides an insulating spacer for a high-voltage conductor constructed with a plastic made of an epoxy resin composition so that the volumetric specific resistance of the shield electrode increases toward the median point between a container and the conductor and a method for manufacturing shield electrode used therein. The insulating spacer according to the present invention can lessen the concentration of electric fields in the boundary areas between the shield electrode and the insulating member with the result that reliability is improved and service life is lengthened.Type: GrantFiled: June 14, 1996Date of Patent: March 3, 1998Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Hiromi Ito, Kenji Mimura, Hirofumi Fujioka, Etsuro Tomonaga, Hiroshi Aoki, Hiroyuki Hama
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Patent number: 5677052Abstract: Aluminium nitride ceramics improved in heat radiation property used as a substrate for integrated circuits and package material, comprising a sintered article consisting mainly of aluminium nitride and having a thermal conductivity higher than 100.multidot.W/m.multidot.K at room temperature and a surface layer consisting mainly of aluminium nitride or oxide glass deposited on the sintered article.A paste of aluminium nitride powder or oxide glass powder is coated on a surface of the sintered article of aluminium nitride and then is sintered to prepare a dense smooth surface layer.Type: GrantFiled: August 15, 1996Date of Patent: October 14, 1997Assignee: Sumitomo Electric Industries, Ltd.Inventors: Kouhei Shimoda, Kazuya Kamitake, Hirohiko Nakata, Kazutaka Sasaki, Masuhiro Natsuhara, Harutoshi Ukegawa
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Patent number: 5654047Abstract: An explosion-proof porcelain housing for use in a gas-filled insulating apparatus, comprising a porcelain housing body, and a first and second films. The first film is made of a first insulating material having low hardness and high elasticity, and is bonded to an inner surface of the porcelain housing body. The second film is made of a second insulating material having high hardness and high mechanical strength, and is bonded to an inner surface of the first film. A process for producing such an explosion-proof porcelain housing is also disclosed.Type: GrantFiled: December 2, 1991Date of Patent: August 5, 1997Assignee: NGK Instulators, Ltd.Inventors: Akihiro Watanabe, Keiichi Asai, Yasunori Matsuura, Nagahiro Kawano, Masafumi Sugi
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Patent number: 5496619Abstract: Conductive paste for via connection of a multilayer ceramic substrate, comprising: an inorganic component which consists of 30.0 to 70.0% by weight of powder of conductive material and the remainder being one of glass powder having a softening point higher than a starting point of sintering of insulating material and crystalline glass ceramic powder having a glass transition point higher than the starting point of sintering of the insulating material; and an organics vehicle component which consists of at least organic binder and solvent.Type: GrantFiled: June 6, 1994Date of Patent: March 5, 1996Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Minehiro Itagaki, Kazuyuki Okano, Suzushi Kimura, Seiichi Nakatani, Yoshihiro Bessho, Satoru Yuhaku, Yasuhiko Hakotani, Kazuhiro Miura
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Patent number: 5374780Abstract: A composite link and insulator, and method of construction, includes a fiberglass body. The body is formed by coating glass fibers with a liquid resin and winding the fibers around a plurality of tubular fittings or bushings in two layers, a first extending longitudinally of the body and the second transversely and around the first. A polymer shield layer and weathersheds are injection molded over the fiberglass body to create an insulator.Type: GrantFiled: September 2, 1992Date of Patent: December 20, 1994Assignee: MacLean Fogg CompanyInventor: Jiri Pazdirek
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Patent number: 5330809Abstract: An electrical cable having a wire bundle core surrounded by a thermal protection sleeve, the thermal protection sleeve consisting of a sandwich structure of outer acrylic adhesive layer and a silicone foam core.Type: GrantFiled: December 12, 1990Date of Patent: July 19, 1994Assignee: The Boeing CompanyInventor: Mickey A. Williamson
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Patent number: 5236973Abstract: An electrical insulator including a thermosetting matrix and a filler composed primarily of powdered material embedded in the thermosetting matrix. The insulator has a high service life in spite of severe mechanical stressing at temperatures of up to 105.degree. C. This is achieved as a result of the thermosetting matrix having a glass transition temperature exceeding 140.degree. C. and the inclusion of a powdered filler, which has a reduced rigidity compared with the thermosetting matrix, embedded in the thermosetting matrix.Type: GrantFiled: April 2, 1992Date of Patent: August 17, 1993Assignee: Asea Brown Boveri Ltd.Inventors: Anton Demarmels, Leopold Ritzer
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Patent number: 5011717Abstract: A hollow porcelain insulator including an elastic insulating layer having a tensile strength of at least 150 kg/cm.sup.2 and a thickness of at least 2 mm for improving an explosion preventing property.Type: GrantFiled: July 5, 1989Date of Patent: April 30, 1991Assignee: NGK Insulators, Ltd.Inventors: Tsutomu Moriya, Yasunori Matsuura, Takao Nakamura
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Patent number: 4931515Abstract: An epoxy resin composition comprising a novolak type epoxy resin which is produced from a substituted-phenol novolak and epihalohydrin, and is 0.15 or less in a maximum absorbance of a 3% (W/V) dichloromethane solution of the epoxy resin, the absorbance being measured at a wave number of between 3570 and 3600 cm.sup.-1 with an infrared spectrophotometer having a cell of 2 mm length, which is useful particularly in encapsulating and laminating applications in electronic fields.Type: GrantFiled: December 8, 1988Date of Patent: June 5, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Hisao Takagishi, Shuichi Kanagawa, Kunimasa Kamio, Kazuo Sumiyoshi
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Patent number: 4757162Abstract: Rigid electrical insulator including a soda-lime glass dielectric with an average thickness of 10 to 15 mm, exhibiting a substantially parabolic stress curve, wherein the maximum value of the surface compression stresses at any point in the part falls within the range of 30 to 80 MPa, while the maximum value of the internal tensile stresses at any point in the part falls within the range of 15 to 40 MPa.Type: GrantFiled: July 16, 1987Date of Patent: July 12, 1988Assignee: CeraverInventors: Denis Dumora, Jean-Paul Parant, Laurent Pargamin
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Patent number: 4748209Abstract: The present invention provides a method for improving impulse destructive strength of an electrical insulating material which is characterized by employing, as the electrical insulating material, a random copolymer of a styrene series monomer and ethylene or a combination of ethylene and another ethylenic unsaturated monomer, or a composition in which the copolymer is blended with an ethylene series polymer, the copolymer being prepared by introducing, into a reaction system, the styrene series monomer selected from the group of styrene and single-ring substituted styrenes, ethylene or the combination of ethylene and the ethylenic unsaturated monomer and a polymerization initiator, the latter being introduced thereinto separately from at least the styrene series monomer, and subjecting these monomers to a high-pressure radical copolymerization under a polymerization pressure of 500 to 4,000 kg/cm.sup.2 at a polymerization temperature of 50.degree. to 400.degree. C.Type: GrantFiled: June 8, 1987Date of Patent: May 31, 1988Assignee: Nippon Petrochemicals Co., Ltd.Inventors: Yuichi Orikasa, Shinji Kojima, Takashi Inoue, Kaoru Yamamoto, Atsushi Sato, Shigenobu Kawakami
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Patent number: 4745457Abstract: An electronic substrate is provided in the form of a sintered body of polycrystalline alumina ceramic which further contains up to approximately 4% glass forming oxide selected from SiO.sub.2, MgO and ZrO.sub.2 along with about 0.4-2.0% refractory metal oxide to substantially reduce visible transmission in said substrate. In a preferred embodiment, said substrate comprises an elongated member of the ceramic material such as a flat layer which further includes a central cavity region housing an integrated circuit component such as a chip in which may be further provided with cover means for the central cavity in said member that can be formed with the same ceramic.Type: GrantFiled: July 30, 1984Date of Patent: May 17, 1988Assignee: General Electric CompanyInventor: Charles G. Morgan
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Patent number: 4576856Abstract: A reconstituted mica material produced by sheet forming a slurry containing mica flakes prepared by disintegrating unfired mica and comprising (i) mica flakes having a particle size of 1.7 mm or more and an aspect ratio of 150 or more, (ii) mica flakes having a particle size of 1.0 mm or more and less than 1.7 mm and an aspect ratio of 150 or more, (iii) mica flakes having a particle size of 0.25 mm or more and less than 1.0 mm and an aspect ratio of 100 or more, and (iv) mica flakes having a particle size of less than 0.25 mm and an aspect ratio of 100 or more, in definite ranges, gives reconstituted mica prepreg materials, reconstituted mica products and insulated coils having excellent mechanical and electrical properties.Type: GrantFiled: June 18, 1984Date of Patent: March 18, 1986Assignee: Hitachi Chemical Company, Ltd.Inventors: Hideji Kuwajima, Takeyoshi Watanabe
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Patent number: 4476155Abstract: A method of manufacturing an improved electrical high voltage coated insulator is described. The method involves applying and curing a one-part, room temperature curable silicone composition to the surface of an insulator, the insulator surface having a minimum designated arc resistance. The silicone composition is the product obtained by mixing in the substantial absence of moisture a specified polydimethylsiloxane fluid containing hydroxyl radicals, finely divided aluminum hydroxide filler, a silane of the formula R.sub.b Si(ON.dbd.X).sub.4-b and an optional condensation catalyst. The coating cures on exposure to atmospheric moisture to produce a surface adhered onto the insulator that resists the development of leakage currents and flashover failure upon exposure to electrical stress, moisture, contamination, and other outdoor weathering stresses.Type: GrantFiled: April 18, 1983Date of Patent: October 9, 1984Assignee: Dow Corning CorporationInventor: Randolph G. Niemi
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Patent number: 4471024Abstract: A tempered glass dielectric material for use as an electrical insulator is thermally tempered to produce surface compression between 200 MPa and 400 MPa. At least part of the material is then chemically tempered under conditions of temperature and duration such that the surface compression due to the thermal tempering is reduced by between 50% and 80%. The chemical tempering is effected by applying to the relevant part of the material, at ambient temperature, a solution containing alkaline salts. This solution is dried and the material then heated for several hours at a temperature between 300.degree. C. and 500.degree. C. The solution has the following composition (in percentage by weight):______________________________________ H.sub.2 O 70% to 90% Starch 2% to 10% KNO.sub.3 4% to 12% K.sub.2 HPO.sub.4 + KCl + K.sub.2 SO.sub.Type: GrantFiled: October 27, 1982Date of Patent: September 11, 1984Assignee: CeraverInventors: Laurent Pargamin, Jean-Paul Parant, Henri Sa/i/ sse, Michel Cornebois
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Patent number: 4431578Abstract: A particular dielectric fluid, having a composition with a specific gravity of at least 1.02 and consisting essentially of a silicone fluid and an additive, soluble in said silicone fluid, selected from the group consisting of trimethylsilyl treated (CH.sub.3).sub.3 SiO.sub.1/2 /SiO.sub.2 resin copolymer, dipropyleneglycoldibenzoate, dixylylethane, phenylxylylethane, and a mixture of [(CH.sub.3).sub.3 Si].sub.2 O treated silica and a silica aerogel, is employed to encapsulate and insulate an electrical cable splice. The same particular dielectric field composition is also used to fill an electrical cable's conductor interstices.Type: GrantFiled: November 27, 1981Date of Patent: February 14, 1984Assignee: Dow Corning CorporationInventor: Eugene D. Groenhof
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Patent number: 4431579Abstract: The anti-inflammability of dimethyl silicone oil for use in static electric apparatuses is improved by reacting the dimethyl silicone oil with a cerium chelate compound so as to bind thereto a predetermined amount of the cerium chelate compound. This binding suppresses the generation of the cyclic oligomer components to be produced by the decomposition of dimethyl silicone oil, thereby elevating the flash point of the dimethyl silicone oil.Type: GrantFiled: April 30, 1982Date of Patent: February 14, 1984Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventor: Sachio Yasufuku
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Patent number: 4426549Abstract: Track and erosion resistant electrical insulating materials are disclosed comprising (a) a base insulating material comprising a polymer of ethylene and additives necessary to allow the polymer to function as electrical insulation, and (b) hydrated zinc borate as an anti-tracking and anti-erosion additive. The hydrated zinc borate functions to increase the track and erosion resistance of the electrical insulating material in concentrations of as little as 1% by weight of the entire material with its maximum effect being achieved at concentrations of about 25% by weight of the entire material.Type: GrantFiled: July 9, 1982Date of Patent: January 17, 1984Assignee: High Voltage Engineering CorporationInventor: Gary S. Natwig
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Patent number: 4415674Abstract: Sheathed electrical heating elements containing MgO heat conductive, electrical insulating material having an additive of fine particles of spherically shaped fused ZrO.sub.2 to increase the electrical resistivity and maintain favorable tap density and flow properties. The spherically shaped ZrO.sub.2 particles are formed by gravitationally separating the ZrO.sub.2 particles from ground fused zircon (ZrO.sub.2.SiO.sub.2).Type: GrantFiled: April 12, 1982Date of Patent: November 15, 1983Assignee: Combustion Engineering, Inc.Inventor: Walter R. Johnson
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Patent number: 4377404Abstract: This invention relates to a manufacturing method and a hermetic glass-to-metal seal suitable for a component in an electric circuit such as a liquid tantalum electrolytic capacitor. The method comprises the steps of fusing a raw material glass in order to form a glass tube; setting a bead, obtained by cutting the glass tube across the axis, in the opening to be sealed, for example, the opening of a member which forms a circuit component; and heating the assembly of the members which composes the circuit component including the bead, above the melting temperature of the bead, with a longitudinal conductor piercing through the bead. This simplified method of manufacturing a hermetic glass-to-metal seal accomplishes a perfect sealing since the sealing glass includes no undesirable impurities such as binder, and since the thermal expansion coefficient of the sealing glass is close to that of the metals used to construct the circuit components, and the sealing glass is stable to electrolyte.Type: GrantFiled: July 10, 1981Date of Patent: March 22, 1983Assignees: Matsuo Electric Company Limited, Osaka CityInventors: Takeshi Hoshikawa, Iwao Takinami
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Patent number: 4301042Abstract: A resistance material comprising a mixture of a permanent binder, a temporary binder and a bismuth-strontium rhodate having a composition defined by the formula Bi.sub.x Sr.sub.1-x Rh.sub.2.5 O.sub.5-5.5 wherein 1/2>x>O as a resistance determining component. This component has a linear positive temperature coefficient of resistance (TCR). A resistor having a very low TCR may be made using a mixture of this resistance-determining material with a resistance-determining component having a negative TCR. The resistor is produced by firing this resistance material on a substrate.Type: GrantFiled: March 5, 1980Date of Patent: November 17, 1981Assignee: U.S. Philips CorporationInventors: Alexander H. Boonstra, Cornelis A. H. A. Mutsaers
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Patent number: 4223071Abstract: New high voltage insulating compositions are disclosed. The compositions comprise a polymer (e.g. a polysiloxane, epoxide resin or a polymer of one or more olefins or substituted olefins), an antitracking additive (e.g. an alumina hydrate), and certain phosphorus-containing compounds which have been found to provide the compositions with greatly improved resistance to erosion by high voltage stress. The phosphorus-containing compounds include phosphonates, phosphates, phosphites, phosphinates, phosphonites, phosphinites, phosphine oxides and sulfides, and phosphines, and salts and complexes thereof. The phosphorus-containing compound can react in situ with the polymer or other ingredients of the composition.Type: GrantFiled: January 13, 1978Date of Patent: September 16, 1980Assignee: Raychem CorporationInventors: Nicodemus E. Boyer, Travers K. Cammack, II, David D. Nyberg
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Patent number: 4219607Abstract: New high voltage insulating compositions are disclosed. The compositions comprise a polymer (e.g. a polysiloxane, epoxide resin or a polymer of one or more olefins or substituted olefins), an antitracking additive (e.g. an alumina hydrate), and certain phosphorus-containing compounds which have been found to provide the compositions with greatly improved resistance to erosion by high voltage stress. The phosphorus-containing compounds include phosphonates, phosphates, phosphites, phosphinates, phosphonites, phosphinites, phosphine oxides and sulfides, and phosphines, and salts and complexes thereof. The phosphorus-containing compound can react in situ with the polymer or other ingredients of the composition.Type: GrantFiled: January 13, 1978Date of Patent: August 26, 1980Assignee: Raychem CorporationInventors: Travers K. Cammack, II, David D. Nyberg
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Patent number: 4216406Abstract: An improved electric lamp of the type wherein a transparent bulb is sealed to a terminal socket cap and contains a foamed cap cement which substantially fills the interior of said terminal cap. The foamed cap cement contains a small amount of a halogen-containing material and functions to extinguish electric arcs generated in the cap.Type: GrantFiled: September 8, 1978Date of Patent: August 5, 1980Assignee: Lumalampan AktiebolagInventors: Karl A. G. Bjorkman, Gunther Jonsson
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Patent number: 4206066Abstract: An arc track resistant, high voltage, filled synthetic resin insulator is disclosed which exhibits a wide range of desirable qualities heretofore unobtainable with any single type of prior insulator. The insulator hereof unexpectedly gives excellent arc track and flame resistance, along with a flexibilized yet rugged construction having good weatherability properties. These qualities are achieved through use of a relatively critical selection of components and proportions which also facilitate cast construction of the insulators by giving a pourable, yet highly filled liquid casting composition during the fabrication stage. The insulators include critical quantities of hydrated alumina (from about 60 to 75% by weight) and a synthetic resin matrix having expoxidized castor oil (18 to 24% by weight) and a glycidyl rigidizer therein, along with a curing agent and accelerator.Type: GrantFiled: July 17, 1978Date of Patent: June 3, 1980Assignee: A. B. Chance CompanyInventor: William M. Rinehart
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Patent number: 4198310Abstract: New high voltage insulating compositions are disclosed. The compositions comprise a polymer (e.g. a polysiloxane, epoxide resin or a polymer of one or more olefins or substituted olefins), an antitracking additive (e.g. an alumina hydrate), and certain organic polymerizable phosphorus-containing compounds which have been found to provide the compositions with greatly improved resistance to erosion by high voltage stress. The phosphorus-containing compounds include phosphonates, phosphates, phosphites, phosphinates, phosphonites, phosphinites, phosphine oxides and sulfides, and phosphines, and salts and complexes thereof. The phosphorus-containing compound can react in situ with the polymer or other ingredients of the composition.Type: GrantFiled: January 13, 1978Date of Patent: April 15, 1980Assignee: Raychem CorporationInventors: Bernard J. Lyons, Travers K. Cammack, II, David D. Nyberg
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Patent number: 4189392Abstract: An electrical insulating material having anti-tracking properties has incorporated therein an erosion inhibiting fluorine-substituted compound. The electrical insulating material comprises a polymeric material having an anti-tracking filler and the fluorine-substituted compound is a hydrophobic, non-ionic compound having a fluorine-substituted aliphatic carbon chain linked to a group having an affinity for the polymeric material and/or the anti-tracking filler. The electrical insulating material may be used in high voltage applications where it is necessary to resist erosion and/or control leakage currents.Type: GrantFiled: July 26, 1977Date of Patent: February 19, 1980Inventors: Richard J. Penneck, John M. Senior
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Patent number: 4126597Abstract: Polyvinyl formal dissolved in a solvent comprising certain monoalkyl ethers of diethylene glycol and triethylene glycol or the monophenyl ether of ethylene glycol, diethylene glycol, triethylene glycol, tetraethylene glycol or propylene glycol. In some cases it is necessary to have a diluent such as an aromatic hydrocarbon present.Type: GrantFiled: March 21, 1977Date of Patent: November 21, 1978Assignee: Schenectady Chemicals, Inc.Inventors: George A. Walrath, John T. Keating
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Patent number: 4112193Abstract: The invention relates to an electrical insulator coated with a semi-conducting tin oxide system glaze layer wherein the glaze layer contains 0.05 to 10 percent by weight of at least one metal oxide selected from the group consisting of niobium oxide, tantalum oxide, titanium oxide, zirconium oxide, yttrium oxide and tungsten oxide. The additional metal oxide reduces the dependance of resistance on the environmental temperature.Type: GrantFiled: August 3, 1976Date of Patent: September 5, 1978Assignee: Nippon Gaishi Kabushiki KaishiInventors: Noboru Higuchi, Takayuki Ogasawara, Shoji Seike
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Patent number: 4100089Abstract: An improved high voltage insulating material comprising one or more polymers and an anti-tracking and erosion inhibiting composition comprising a hydrate of alumina and one or more compounds selected from the groups consisting of nickel phosphate, phosphinic acid or a derivative thereof, phosphonous acid or a derivative thereof, and phosphonic acid or a derivative thereof. The composition functions to prevent failure by tracking and to substantially retard failure by erosion.Type: GrantFiled: January 16, 1976Date of Patent: July 11, 1978Assignee: Raychem CorporationInventors: Travers Kregg Cammack, II, David Dolph Nyberg
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Patent number: 4091124Abstract: An improved electrical grade concrete insulator is prepared by immersing a self-supporting concrete body impregnated with an uncured polymer in a liquid curable resin bath, curing said polymer, separating said body from said resin bath whereby said body has a secondary impregnation filling the voids produced when the primary impregnation shrinks on curing. The residual resin on the outside also forms a thin sealant coating on the surface of said body.Type: GrantFiled: April 21, 1976Date of Patent: May 23, 1978Assignee: Gould Inc.Inventor: David H. Reighter
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Patent number: 4038491Abstract: A fluid, filled, resinous casting composition, having a viscosity below about 20,000 cp. at 100.degree. C, is made from liquid resin, resin curing agent, and as high as 85 weight percent of a glassy filler comprising about 50 to about 60 weight percent of SiO.sub.2, about 12 to about 22 weight percent of Al.sub.2 O.sub.3, about 5 to about 15 weight percent of B.sub.2 O.sub.3, about 4 to about 14 weight percent of MgO and about 2.5 to about 12.5 weight percent of CaO.Type: GrantFiled: March 30, 1976Date of Patent: July 26, 1977Assignee: Westinghouse Electric CorporationInventors: James R. Gamble, James W. Chapman
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Patent number: 4001128Abstract: A filler system for polymers is disclosed which provides high voltage insulation which is resistant to tracking. The filler system utilizes a combination of alumina trihydrate and a chemically treated silica filler. The silica-treated filler results from the exposure of an inorganic silicon-containing filler having a specific surface area of at least 40 square meters per gram to one or more silanes. Preferred silanes are substituted silanes having the formula R.sub.n Si X.sub.4.sub.-n where n is 1, 2 or 3, R is an organic radical bonded to the silicon atom by a Si--C bond and X is a radical bound to the silicon atom via an atom other than a carbon atom.Type: GrantFiled: July 21, 1972Date of Patent: January 4, 1977Assignee: Raychem CorporationInventor: Richard John Penneck
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Patent number: 3963632Abstract: An insulating coating composition is described which prevents deterioration of the insulating ability of newly fabricated material and when applied will also restore insulation characteristics to material presently in use. The composition comprises a mixture of1. a main resinous coating of a thermoplastic resin;2. a cation exchange resin which may be either strongly acidic, i.e., one containing sulfur type, sulphonic acid radicals or weakly acidic, i.e., one containing carboxyl groups or phenolic hydroxyl groups; and3. an anion exchange resin which may be either strongly basic, i.e., one containing quaternary ammonium radicals or weakly basic, i.e., one containing amine radicalsA method of arresting or preventing deterioration of insulating coatings is also disclosed by the use of the above materials which when applied will remove disassociated ions which, in turn, prevent formation of an electroconductive film on the surface of the coating.Type: GrantFiled: January 7, 1974Date of Patent: June 15, 1976Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventor: Koji Tanaka
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Patent number: 3950452Abstract: A weather-resistant high-voltage electrical insulator appliance, or at least a portion thereof which is exposed to the atmosphere, is formed of a solvent-free aliphatic polyurethane which is at least substantially free of aromatic groups.Type: GrantFiled: January 21, 1972Date of Patent: April 13, 1976Assignee: Dr. Beck & Co. AGInventors: Karl Schmidt, Gerhard Boockmann
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Patent number: 3941707Abstract: A method of producing an aluminum oxide and tungstate powder for insulating cathode heaters includes mixing a finely divided aluminum oxide powder with ammonium tungstate, rinsing out excess ammonium tungstate, drying the mixture and heating in a nitrogen-hydrogen atmosphere to about 700.degree.C.Type: GrantFiled: November 23, 1973Date of Patent: March 2, 1976Assignee: International Standard Electric CorporationInventor: Eberhard Weiss
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Patent number: 3935157Abstract: A polycarbonate plastic having improved electrical tracking resistance is provided by including in the polycarbonate a substance which is normally an oxidation or combustion catalyst such as a transition metal having a positive oxidation potential of >+0.2 volt.Type: GrantFiled: March 28, 1974Date of Patent: January 27, 1976Assignee: Bayer AktiengesellschaftInventors: Paul Schiller, Hugo Vernaleken