Abstract: A controlled kiln and manufacturing system for biochar production includes control systems and subsystems. An example controlled kiln (100) includes a drum (200), a lid (120) and a floor (250) together forming a combustion chamber configured to contain feedstock for conversion into biochar. A catalytic converter (700) may be operatively coupled with an outlet of the kiln (100). A monitor and control subsystem may be operative to issue notifications or automatically end biochar conversion. A ventilation and exhaust system including independently controllable air inlet ports (240), a chimney (300) and smoke inlet pipes (330) enables regulation of smoke flow from a combustion chamber of the kiln while a heat exchanger (1000) enables providing exhaust heat to one or more secondary applications.

Abstract: The inventions are related to industrial processing of combustible carbon- and hydrocarbon products. A method of processing combustible carbon- and hydrocarbon products is implemented using a reactor equipped with temperature sensors. The reactors comprise the phases of heating the charge (13), pyrolysis of combustible components and coking (12), combustion (11), and formation of a solid residue (4). At the phases of heating the charge (13) and coking and pyrolysis (12), an aerosol (i.e. dust particles and condensed liquid droplets carried away from the combustion zone (11) sorption zone (21) is formed by flushing the upper part of the charge by liquid hydrocarbonaceous products through the dispenser (22) and/or by adding to the batch the solid hydrocarbonaceous products having a softening point above 60° C. and the end boiling point above 300° C.

Abstract: A method of gasification using a downdraft gasifier having a plurality of vertically positioned tubes to create a pyrolysis zone, an oxidation zone beneath the pyrolysis zone and a reduction zone beneath the oxidation zone. The shape of the tubes eliminates the need for a restriction (hearth) in the gasifier, which limits the maximum achievable throughput. A rotating and vertically adjustable grate is located beneath, but not attached to, the reduction zone of the gasifier.

Abstract: A coke oven of horizontal construction (non-recovery/heat recovery type) includes at least one coking chamber, laterally arranged vertical downcomers as well as bottom flues arranged horizontally and extending underneath the coking chamber for indirect reheating of said coking chamber. One or more gas space dividing walls are arranged in the oven free space which in the intended operation of the coke oven is not destined for being filled with solid matter so that the gas routing is improved and a homogenisation of radiation in the coking chamber is achieved.

Abstract: The invention provides an apparatus for gasifying a fuel to form synthesis gas wherein also a slag is formed. The apparatus comprises: a pressure shell; a slag bath; a gasifier wall; a free-fall trajectory for slag; and a heat shield. The gasifier wall is arranged inside the pressure shell defining a gasification chamber. It comprises a converging wall part that is provided with a slag discharge opening, located above the quench fluid in the slag bath. The heat shield is arranged above the slag bath between the free-fall trajectory and the pressure shell. The heat shield has a wall structure for allowing passage of a cooling fluid, the wall structure comprising an upper wall part and a lower wall part. The lower wall part of the heat shield is essentially refractory free.

Abstract: A pyrolysis process is provided. The process includes the steps of: depositing a quantity of waste into a porous container, the porous container adapted to allow a convective stream of substantially anaerobic gas to flow therethrough; inserting the porous container into a pyrolysis thermal processor; sealing the thermal processor; circulating the convective stream of gas through the pyrolysis thermal processor; heating the waste according to a first time-temperature profile to pyrolyze the waste and form a carbonaceous char; and cooling the carbonaceous char by circulating the convective stream of gas through a cooler. An oil product and a gaseous hydrocarbon product are produced during the pyrolysis. The carbonaceous char is further processed to form a carbon black product and a recyclable metal product.

Abstract: A method of collecting hydrocarbons from comminuted hydrocarbonaceous material within a vertical retort infrastructure having an outer boundary substantially comprised of igneous cementations materials, an inlet, a substantially horizontal suspended grate, an outlet, and an auger disposed proximate the outlet. In the method comminuted hydrocarbonaceous material in introduced proximate an upper end of the vertical retort. The comminuted hydrocarbonaceous material is passed through the substantially horizontal suspended grate and heated while passing through the grate. The heat causes organic material within the comminuted hydrocarbonaceous material to pyrolize. The comminuted hydrocarbonaceous material is then discharged through the outlet with the assistance of the auger disposed proximate the outlet.

Abstract: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, said apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of no less than 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10?22 bar and oxygen partial pressure of 10?10 bar, at a temperature of 1200° C.; wherein said refractory material has no less than 4 vol % formed porosity, measured at 20° C., based upon the bulk volume of said refractory material. In another embodiment, the refractory material has total porosity in the range of from 4 to 60 vol %.

Abstract: In one aspect, the invention includes a reactor apparatus for pyrolyzing a hydrocarbon feedstock, the apparatus including: a reactor component comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C. and which remains in oxide form when exposed to a gas having carbon partial pressure of 10?22 bar, an oxygen partial pressure of 10?10 bar, at a temperature of 1200° C. In some embodiments, the reactor comprises a regenerative pyrolysis reactor apparatus and in other embodiments it includes a reverse flow regenerative reactor apparatus. In other aspects, this invention includes a method for pyrolyzing a hydrocarbon feedstock using a pyrolysis reactor system comprising the step of providing in a heated region of a pyrolysis reactor system for pyrolyzing a hydrocarbon feedstock, apparatus comprising a refractory material in oxide form, the refractory material having a melting point of at least 2060° C.

Abstract: A catalytically activated vacuum distillation system, several novel component parts of said system, a process for producing carbon based products and novel carbon black that is produced from such a system and process.

Abstract: In the operation of smoking/burning type volume reduction treatment apparatus (1), referring to view (A), charcoal carbonized layer (T2) is spread over powdery ceramic layer (T1) in the state of having negative ion air fed through air supply inlet (H). Further, sawdust layer (T3) is spread thereover, and thereafter treatment subject layer (V) is piled thereon. In a temporary burning region of the carbonized layer (T2), the powdery ceramic layer (T1) exerts not only heat storing action but also heat radiation action. Referring to view (B), the interior of the sawdust layer (T3) is altered into temporary carbonized layer (T3 1) and temporary dried layer (T3 2). As the temporary burning region slowly moves upward, an under side of the treatment subject layer (V) is altered into dried layer (V1) and further, carbonized layer (V2) shown in view (C) is formed. Thereafter, this carbonized layer (V2) catches fire, so that burning region (V3) is formed in layered form in the treatment subject layer (V).

Abstract: A chamber for treating waste material includes a substantially closed chamber which is horizontally elongate with a conveyor provided within the chamber oriented generally horizontally and defining an upper portion and a lower portion with a series of paddles arranged to move material along the upper portion of the conveyor. A material supporting surface formed of ceramic material is provided between the upper portion and the lower portion of the conveyor. The material supporting surface is generally U-shaped and forms a channel through which the paddles move along the upper portion of the conveyor. The material supporting surface is carried by a plurality of metal horizontal support members which are cooled by a fluid. The paddles are asymmetrically oriented with respect to the conveyor.

Abstract: A lubricating base oil composition is provided comprising (a) at least one Fischer-Tropsch derived lubricating base oil characterized as having a kinematic viscosity of about 2 to about 5 centistoke (cSt) at 100° C.; and (b) at least one polyol ester. Methods for improving the fuel economy of an internal combustion engine are also provided.

Abstract: A pure steam-related apparatus, which is one of apparatus in the group of pure steam generators generating pure steam from purified water, pipelines for pure steam and sterilizers using pure steam, is protected from discoloration, so-called "fouling", to red or black caused by contact with the pure steam. The apparatus is manufactured by using an austenitic stainless steel sheet as the material, by taking the blanks from the material which received no mechanical surface polishing, by deforming and welding, without electrolytic polishing customarily done, and by passivating the surface to contact pure water to increase Cr-content in the passivation film to such extent as 45 atomic % or higher, preferably 55 atomic % or higher. Better results will be obtained by ensuring Cr/Fe ratio in the passivation film at the level of 1.45 or higher, preferably, 1.70 or higher.

Abstract: Method for the gas sealing manufacture of a door frame of a coke oven battery which battery comprises a refractory structure with an armor plate connected to it onto which the door frame is fitted characterized by the following steps:measuring the profile of the surface of the armor plate at the position where it faces the door frame in its mounted state;fitting a profile to one side of the door frame which in its mounted state faces the armor plate, corresponding to the profile of the surface of that armor plate measured in the previous step, in such a way that in its mounted state the door frame rests essentially against the armor plate;placing the door frame thus adapted against the armor plate.

Abstract: The present disclosure is directed to methods and compositions for boronizing metal and in particular ferrous surfaces. It has been discovered that if hydrocarbons are processed in metallic equipment which have been previously boronized, that coke formation and deposition which is commonly experienced at high temperatures can be minimized if not totally eliminated. The compositions utilized for this purpose are comprised of boron or boron compounds contained in an organic solvent or carrier together with specific activating materials.

Abstract: An offset expansion joint and method of installing the same in a repaired or rebuilt furnace, such as a coke oven or the like, comprises at least two segments of ceramic fiber spaced laterally from one another and separated by silica bricks and a barrier of silica mortar which extends along an edge of each segment and along an edge of each of the bricks by which the segments are spaced, the silica mortar having the ability to set up when exposed to about 2200.degree. F. to prevent passage of gas through the expansion joint in the area of the horizontal flue of the coke oven.

Abstract: A spalled and deteriorated portion of a refractory brick heating wall of a coke oven heating chamber is dismantled. The deteriorated brick is removed with the undamaged brick remaining in place. Individual thermally destructable forms forming the gas flow passageways are vertically erected surrounding ports in the floor through which preheated gas and preheated air are separately supplied into the heating chamber. A second set of destructable forms having passageways forming the heating flues for receiving the products of combustion are positioned between the forms for the gas flow passageways. Horizontal forms, also forming gas flow passageways, connect adjacent vertical forms for the flow of air and gas from the ports into the heating flues where combustion of the air and gas takes place. When the thermally destructable forms are in place, a refractory material is sprayed onto the outer surfaces of the forms.

Abstract: Flue gas discharged from a recuperator or regenerator of a coke oven battery has the steam thereof removed by means of a direct or indirect cooling and condensation operation. After the steam is removed from the flue gas it is then passed through a coke dry cooling plant in direct contact with hot coke therein to form dry cooled coke while simultaneously increasing the temperature of the flue gas. The flue gas is then passed through a coal preheating plant to directly contact and dry and preheat moist coking coal contained therein. The entire system is open, such that a given quantity of the flue gas passes only once through the system. When the temperature of the flue gas as received from a coke oven battery is extremely high, then the flue gas may be subjected to a partial cooling operation prior to the cooling and condensation operation.

Abstract: A dry thermal processor for recovering hydrocarbons from oil sand solids comprises concentric, radially spaced, horizontal inner and outer tubular members connected for rotation together. The inner member provides a substantially open preheat zone and vaporization zone while the outer member provides, in the annular space between the tubular members, a substantially open combustion zone and heat transfer zone. The ends of the outer member are sealed by stationary feed end and product end structures. Advance means move the oil sand solids from the feed end structure through the preheat and vaporization zones to the product end structure and back through the combustion and heat transfer zones. Rotation of the inner member causes size reduction of the oil sand feed in the preheat zone, and oversize is discharged directly into the annular space at the second end of the preheat zone.

Abstract: This invention relates to a method and apparatus for the separation of bitumen crude petroleum from oil bearing solid materials and the collection of all the vapors produced, as multiple fractionated hydrocarbons.

Abstract: Continuous production of coke by pyrolysis of a hydrocarbon mixture containing petroleum tar, coal tar pitch or pyrolysis tars in which the hyrocarbon mixture and recycled condensate is heated in a preheater at a rate to increase the mesophase content of the mixture up to 30 to 60%; the preheated mixture is then heated in a coking zone at a rate to form a raw coke having a mesophase content of 70 to 100%; continuously removing the raw coke from the coking zone and heating it in a calciner. The coke produced is more uniform and the process more efficient.

Abstract: Method for charging a coke oven chamber. Where the chamber is charged through a single charging hole with a stream of flowable preheated particulate coal at a flow rate of between substantially 8-20 tons per minute. The coal flows sufficiently in the chamber to assure filling of the chamber to substantially 100% of the volumetric capacity of the same. Due to the flowability of the preheated coal the charge is self-leveling.

Abstract: A method for sealing a by-product coke oven in which a silicone material is caused to foam to form a foaming silicone composition preferably by mixing a first mixture of organohydrogensiloxane and hydroxylated organosiloxane with a second mixture of organohydrogensiloxane most desirably with a platinum catalyst, and heating the mixture to provide a volumetrically expandable foam. The volumetrically expandable foam is sprayed around the periphery of coke oven doors, slip-joints and similar points of gaseous emissions where it undergoes a foaming acting in the presence of the heat of the oven such that the foam volumetrically expands to provide a seal that prevents the emission of gas, dust, and smoke during the coking cycle.

Abstract: A method of manufacturing blast furnace coke wherein said coke is obtained by a process in which coal to be used for making briquettes is mixed with a caking substance having a softening point of 40.degree.-250.degree. C. with or without a solvent having fluidity at the mixing temperature and dissolvable to said caking substance, the resultant mixture being mixed by means of a powerful mixer capable of applying mixing energy of 0.01KW/Kg or more at a temperature of 40.degree.-250.degree. C. for 1-10 minutes, while a heating medium such as steam is passed therethrough and is then subjected to briquetting with a roll press. The briquette obtained is either carbonized directly or after blending with coal ready for coke oven charging.

Abstract: A method for mixing a stream of particulate carbonaceous material with another stream of particulate material in a reaction zone maintained substantially free of free oxygen, which method is especially useful for mixing a stream of particulate agglomerative carbonaceous material with a stream of particulate heat-supplying material to produce valuable gaseous, liquid and solid products. This invention discloses a number of apparatuses useful for mixing streams of particulate material in a reactor maintained substantially free of free oxygen.