Abstract: A system for gasifying a carbonaceous feedstock, such as municipal waste, to generate power includes a devolatilization reactor that creates char from the feedstock and a gasifier that creates a product gas from both the char and from volatiles released when devolatilizing the feedstock. The product gas is reacted in a fuel cell to create electrical energy and process heat. The process heat is used to heat the devolatilization reactor and the gasifier. The gasifier comprises a plurality of configurable circuits that can each be tuned to meet the individual needs of the char material being gasified.

Abstract: Method for preparing coal for coke making includes controlling particles size of coal or caking additive before arriving at the plant so particles content having diameter of 6 mm or more in the coal or caking additive reaches 30% by mass or less when the coal or caking additive has permeation distance of 15 mm or more. In another method, the relationship between a critical permeation distance and Gieseler maximum fluidity is obtained using permeation distances and Gieseler maximum fluidity values of one or more brands of coal or caking additive, particles size of coal or caking additive is controlled before arriving at the plant so particles content having diameter of 6 mm or more in coal or caking additive reaches 30% by mass or less when permeation distance of coal or caking additive is larger or equal to a critical permeation distance calculated from the Gieseler maximum fluidity.

Abstract: A method for reducing the coking time in the oven area near the door or end wall and for improving coke quality and situation of emissions by compensating for radiation losses through coke oven chamber doors and end walls is described. This compensation is accomplished by varying the height of the coal cake in the environment of the frontal coke oven chamber doors. The variation is achieved both by increasing or decreasing the coal cake over part of the length or over the entire length of the coke oven chamber door. The reduction in the height of the coal cake can be generated by omission of coal or coal compacts, the increase in height can be accomplished by stacking of coal and pressing or adding of coal compacts, with it also being envisaged to omit the pressing cycle so as to obtain a recess with a lower coal cake density which also has less heat radiation.

Abstract: A method of treating untreated low calorific coal containing moisture and organic volatiles includes feeding untreated coal to a dryer, and drying the coal. The dried coal is subjected to a pyrolyzing step where oxygen-deficient gases are brought into contact with the coal, thereby lowering the volatile content of the coal and producing a stream of pyrolysis effluent gases. The pyrolysis effluent gases are subjected to a separation process to separate lean fuel gases from liquids and tars, wherein the separation process removes less than about 20 percent of the pyrolysis effluent gases as the liquids and tars, with the remainder being the lean fuel gases. The lean fuel gases are returned to the dryer combustor, the pyrolyzer combustor, or the pyrolyzer.

Abstract: A method for producing individual compacts made of coke and suitable for coke oven chambers by dividing a coal cake in a non-mechanical manner, wherein the coal cake is produced by a compression method according to the prior art and the coal cake is divided by non-mechanical, energy-supplying media, and the non-mechanical media supplying shearing energy are, for example, a laser beam, a high-pressure water jet, an abrasive-solid jet, an ultrasonic beam, a compressed-air jet, or a gas jet. By using the method, coal compacts can be produced from coal cakes without forming dust, without wearing out cutting tools, and with high precision.

Abstract: A method for compacting coal in a manner suitable for coke oven chambers is described. The coal is initially compressed by means of a suitable compressing device into one or more coal cakes, and the obtained coal cakes are divided into compacted products by a cutting device. The compacted products are stacked on top of the each other such that they can be loaded into a coke oven chamber for coking. The compacted products enable the coke oven chambers to be loaded in a precise and a coal loss-free manner. The coal compacted products are easy to store.

Abstract: Apparatus and a process are described for compressing superheated steam into porous coal batches in chambers, and, after a time interval, expanding this steam out of the chambers, and repeating this steam cycle of compression followed by expansion. Thusly heated by the steam, volatile matter separates from the solid coke portion of the coal and separate volatile matter and coke products can be produced from coal or biomass fuels. These volatile matter liquids and tars can be used as fuel components in slurry fuels, for internal combustion engines used in our surface transportation industries. These solid coke products can be used as boiler fuel in steam electric plants. In this way our large domestic reserves of coal can be used as a fuel source, not only for electric power generation, but also for our surface transportation needs.

Abstract: A new approach to the production of coke. In this process multiple optimized value streams are produced from a coke facility located at mine mouth or locally at an existing plant. As part of the process, lower cost Indiana/Illinois Basin-type coals are blended with conventional metallurgical coals. The blending process is optimized to meet coke quality requirements and simultaneously to obtain a pyrolysis gas composition suitable for production of ancillary products including liquid transportation fuels, fertilizer, hydrogen, and electricity. By using lower cost Indiana/Illinois Basin coal it is possible to reduce net coal costs. This process provides a new direction and approach for the production of coke in the future that optimizes value over multiple product streams while reducing both business and technological risk.

Abstract: A new approach to the production of coke. In this process multiple optimized value streams are produced from a coke facility located at mine mouth or locally at an existing plant. As part of the process, lower cost Indiana/Illinois Basin-type coals are blended with conventional metallurgical coals. The blending process is optimized to meet coke quality requirements and simultaneously to obtain a pyrolysis gas composition suitable for production of ancillary products including liquid transportation fuels, fertilizer, hydrogen, and electricity. By using lower cost Indiana/Illinois Basin coal it is possible to reduce net coal costs. This process provides a new direction and approach for the production of coke in the future that optimizes value over multiple product streams while reducing both business and technological risk.

Abstract: A method and apparatus for continuously carbonizing materials while co-producing gases in a coking chamber closed to the atmosphere, having a charger at one end comprising a pushing ram surrounding a mandrel that surrounds an air or oxygen injection lance. The other end of the coking chamber collects and separates coke from gases, with coke directed to a closed quenching chamber and gases directed to a cleanup. Thermal energy for converting coal into coke derives from combusting some metallurgical coal by said lance.

Abstract: Heat from a concentrated solar power source is applied to the conversion of carbonaceous materials such as heavy petroleum crude oils, coals and biomass to liquid hydrocarbons. The solar heat is applied to provide at least a portion of the process heat used in the high temperature, short contact time hydropyrolysis of the carbonaceous material which is supplied with hydrogen generated by a high temperature process such as high temperature steam electrolysis, the sulfur-iodine cycle, the hybrid sulfur cycle, the zinc-zinc oxide cycle or by methane steam cracking. The heat from the solar source may be used to generate electricity to operate high temperature steam electrolysis used in generation of the hydrogen. By the use of solar thermal energy sources, hydrocarbon resource utilization for process heat is eliminated along with carbon dioxide evolution associated with burning of the hydrocarbon resource to generate process heat.

Abstract: A method of production of blast furnace coke comprising drying mixed coal, then, or simultaneously with the drying, classifying it to fine-grained coal and coarse-grained coal, then adding to the fine-grained coal at a temperature of 80 to 350° C. a caking additive comprised of one or more of a heavy distillate of tar, soft pitch, and petroleum pitch, agglomerating it by hot pressing, then mixing the clumps of coal and the coarse-grained coal and charging and carbonizing the mixture in a coke oven.

Abstract: A new approach to the production of coke. In this process multiple optimized value streams are produced from a coke facility located at mine mouth or locally at an existing plant. As part of the process, lower cost Indiana/Illinois Basin-type coals are blended with conventional metallurgical coals. The blending process is optimized to meet coke quality requirements and simultaneously to obtain a pyrolysis gas composition suitable for production of ancillary products including liquid transportation fuels, fertilizer, hydrogen, and electricity. By using lower cost Indiana/Illinois Basin coal it is possible to reduce net coal costs. This process provides a new direction and approach for the production of coke in the future that optimizes value over multiple product streams while reducing both business and technological risk.

Abstract: The present invent provides improved rapid thermal conversion processes for efficiently converting wood, other biomass materials, and other carbonaceous feedstock (including hydrocarbons) into high yields of valuable liquid product, e.g., bio-oil, on a large scale production. In an embodiment, biomass material, e.g., wood, is feed to a conversion system where the biomass material is mixed with an upward stream of hot heat carriers, e.g., sand, that thermally convert the biomass into a hot vapor stream. The hot vapor stream is rapidly quenched with quench media in one or more condensing chambers located downstream of the conversion system. The rapid quenching condenses the vapor stream into liquid product, which is collected from the condensing chambers as a valuable liquid product. In one embodiment, the liquid product itself is used as the quench media.

Abstract: The present invention relates to a system and a process for obtaining phenanthrene of about 95% purity from coal tar distilled fraction containing crude phenanthrene by performing fractional distillation at a reduced pressure of 50 mm mercury and at a temperature range of 160-180° C. to obtain first distilled fraction containing acenaphthene and fluorene; a second distillate fraction at a temperature range of 200-230° C. containing phenanthrene, anthracene and traces of carbazole; followed by re-distilling the second distillate fraction at a temperature range of 210-224° C. to finally obtain pure phenanthrene and a residue which is again used for the recovery of residual phenanthrene by re-distillation at a temperature range of 210-224° C.

Abstract: In a method of producing coke for metallurgy by carbonizing a coal blend obtained by blending plural raw coals in an coke oven, a coal blend containing not less than 60 wt % of a medium coking coal of middle coalification degree and low fluidity having an inert component content of not less than 30% is used as a coal charged into the coke oven, whereby a great amount of raw coal of a brand being cheap and easily available can be blended in a great amount and hence coke for metallurgy having an excellent quality such as strength or the like can be produced by blending few brands of coals as compared with a coal blend of many brands.

Abstract: The invention provides a process for the production of charcoal, fuel gas, and potassium from a biomass gassifier.

Abstract: A method is provided for converting coal to coke by the steps of blending pulverized coal with water and a binder to a kneadable dough; and baking said dough in a reducing environment.

Abstract: The present invention relates to a system and a process for obtaining phenanthrene of about 95% purity from coal tar distilled fraction containing crude phenanthrene by performing fractional distillation at a reduced pressure of 50 mm mercury and at a temperature range of 160-180° C. to obtain first distilled fraction containing acenaphthene and fluorene; a second distillate fraction at a temperature range of 200-230° C. containing phenanthrene, anthracene and traces of carbazole; followed by re-distilling the second distillate fraction at a temperature range of 210-224° C. to finally obtain pure phenanthrene and a residue which is again used for the recovery of residual phenanthrene by re-distillation at a temperature range of 210-224° C.

Abstract: A blast furnace coal is produced by rapidly heating a coal blend having 10 to 30% by weight of a non-slightly-caking coal having softening initiation temperature T with the balance including a caking coal having softening initiation temperature T.sub.0 (T.sub.0 .ltoreq.T +40.degree. C.) at a rate of 1.times.10.sup.3 to 1.times.10.sup.6 .degree. C./min to a temperature region from (T -60.degree. C.) to (T +10.degree. C.) wherein T represents the softening initiation temperature of the non-slightly-caking coal; or rapidly heating a non-slightly-caking coal having softening initiation temperature T and a caking coal having softening initiation temperature T.sub.1 separately at a rate of 1.times.10.sup.3 to 1.times.10.sup.6 .degree. C./min to a temperature region from (T -100.degree. C.) to (T +10.degree. C.), wherein T represents the softening initiation temperature of the non-slightly-caking coal, or a temperature region from (T.sub.1 -100.degree. C.) to (T.sub.1 +10.degree. C.), wherein T.sub.

Abstract: This invention generally relates to a new method and apparatus for the fast pyrolysis of carbonaceous materials involving rapid mixing, high heat transfer rates, precisely controlled short uniform residence times and rapid primary product quench in an upflow, entrained-bed, transport reactor with heat carrier solids recirculation. A carbonaceous feedstock, a non-oxidative transport gas and inorganic particulate heat supplying material are rapidly mixed in a reactor base section, then transported upward through an entrained-bed tubular reactor. A cyclonic hot solids recirculation system separates the solids from the non-condensible gases and primary product vapors and returns them to the mixer. Product vapors are rapidly quenched to provide maximum yields of liquids, petrochemicals, high value gases and selected valuable chemicals.

Abstract: This invention generally relates to a new method and apparatus for the fast pyrolysis of carbonaceous materials involving rapid mixing, high heat transfer rates, precisely controlled short uniform residence times and rapid primary product quench in an upflow, entrained-bed, transport reactor with heat carrier solids recirculation. A carbonaceous feedstock, a non-oxidative transport gas and inorganic particulate heat supplying material are rapidly mixed in a reactor base section, then transported upward through an entrained-bed tubular reactor. A cyclonic hot solids recirculation system separates the solids from the non-condensible gases and primary product vapors and returns them to the mixer. Product vapors are rapidly quenched to provide maximum yields of liquids, petrochemicals, high value gases and selected valuable chemicals.

Abstract: The invention concerns a process for recovering synthetic raw materials and fluid fuel components from used or waste plastics in accordance with patent application P 43 11 034,7. At least a partial flow of the depolymer produced according to this process is subjected, together with coal, to a coking process, fed to a thermal utilization system or introduced as a reducing agent into a blast furnace process. The depolymer can be used as an additive for bitumen and bituminous products.

Abstract: Pieces of coke of high density and strength are made continuously from fine particles of bituminous or subbituminous or lignite coals or of mixtures thereof. The particles are generally oxygenated, mixed with water, compressed to squeeze out some of the water to obtain single bodies which are heat processed lying on a traveling grate on which they undergo drying, pyrolyzing, carbonizing and cooling.Modifications include mixing in with the coal material(s) listed above, coke fines or char or anthracite coal; or limestone; or carbon-reducible oxides such as oxidic ores of Fe, Mn, Cr and quartzite in recited important proportions. Such formed coke bodies are useable in a submerged arc furnace or in a blast furnace or in an open hearth to produce desired intermediate or end metallic products. The pieces of coke with incorporated fine limestone burn without developing SO.sub.2.

Abstract: High purity coke particularly suited to the production of anodes for aluminium smelting is produced by an integrated process that includes flash pryolysis and delayed coking. In the integrated process, flash pyrolysis of carbonaceous materials such as coal, oil shale or tar sand is operated under conditions that maximize the production of tar suitable for coking, and the delayed coking is operated under conditions that maximize the coke yield, and intermediate products may be recycled to enhance overall efficiency.

Abstract: Green coal is charred in pre- and post- treatment carbonizers, then crushed, mixed with pitch, briquetted, tempered in a tempering oven, recirculated with succeeding green coal to char in a reducing atmosphere through only the latter part of the pre-treatment carbonizer and through the post-treatment carbonizer, cooled, and separated from the as yet unbriquetted char. The pre-treatment carbonization is characterized by having air updrafted through all the airbox zones under the travelling grate.

Abstract: The strength and density of a metallurgical coke produced in a slot coke oven are both increased by replacing at least a part of the normal loose charge in the oven with compacted materials and fragments thereof made from a mixture of particularly sized particulate fusible bituminous coal particles, non-fusible particles of a material compatible with the burden of a blast furnace, and water. During compacting the pressure and the moisture content of the mix are such that at least some water is squeezed out of the mix. The non-fusible materials that are useful include non-coking coals, poorly coking coals, other carbonaceous materials, such as coke breeze, char, anthracite, lignite, and iron oxide-bearing materials, such as iron ores and waste materials from steel plants. At least a major proportion of the fusible particles and at least a substantial proportion of the non-fusible particles are smaller than about 0.15 mm.

Abstract: Production of coke from coal is improved by mixing self-feeding coal with compacted non self-feeding coal prior to carrying out the coking process. Preferably, there is about 10% to about 60% by weight of the non self-feeding coal based on the total charge. Binders may be used and it is preferred that the non self-feeding coal be preheated to approximately 150.degree. C. to 250.degree. C. prior to mixing. In the event that an aqueous emulsion is used as the binder, the preheating step may be omitted. Coke of superior abrasion resistance is obtained by the foregoing method.

Abstract: A process is described for maintaining the proportions of each coal in a coal blend at a desired level. The process involves(1) making a spectral analysis, preferably by infrared spectrometry, of at least one sample of the coal blend, the sample having known desired proportions of each coal,(2) making a spectral analysis of the coal blend sample of unknown proportions of each coal,(3) comparing the spectral analyses of steps (1) and (2), and(4) upon noting a significant difference between the spectral analyses of steps (1) and (2), making adjustments to achieve a final coal blend having proportions of each coal closer to those of the blend of known desired proportions of each coal. The relationship of the aromatic to aliphatic groupings is preferably determined by spectral analysis of each coal sample.This process is particularly useful on-line in the production of blast furnace coke of high strength and high stability.

Abstract: Blast furnace coke containing low grade coal in a high blending ratio is manufactured by a method which comprises blending not less than 60% of a blended coal having an adjusted total moisture content of not more than 4% with not more than 40% of briquettes and carbonizing the resultant mixture.The blended coal consists essentially of not less than 80% of coking coal and not more than 20% of low grade coal. When coking coal of a kind which has its coking property segregated according to its grain size distribution is pulverized and classified by sifting and the portion of fine particles is used as mixed with the coking coal, the blending ratio of the low grade coal in the blended coal can be increased to up to 35%. The briquettes consist essentially of not less than 10% of coking coal and not more than 90% of low grade coal.

Abstract: A three step process is provided for producing high strength metallurgical coke from high volatile caking coals. Firstly, the caking coal is oxidized by heating the coal in an oxygen-containing atmosphere for a period of time. Secondly, the oxidized caking coal is blended with fresh or relatively non-oxidized caking coal. Thirdly, the blend is carbonized to yield metallurgical grade coke.

Abstract: A method of preparing coals for coking in a conventional coke oven includes agglomerating the loose coal, in combination with a binder, into flakes, mixing the flakes with non-agglomerated coal, and charging the mixture into the coke oven in the conventional manner. The method provides for the utilization in a conventional coke oven, of coals that are marginal in coking quality, greater bulk densities of the coal as charged into a conventional coke oven, acceptable shatter resistance and physical stability of the coke produced, and acceptable carbonization pressure on the coke oven walls.

Abstract: An improved method for producing calcined coke agglomerates having good stability including adjusting the fluidity of coals or blends of coals to within a range of 1300 DDPM and 3000 DDPM, mixing the coals or blends of coals with char and optionally topped tar in a rotating agglomerating drum and agglomerating the mixture at a temperature between 750.degree. F. and 875.degree. F. (399.degree. C.and 468.degree. C.) for a time to form partially coked green coal agglomerates generally spherical in shape and calcining the partially coked green coal agglomerates at a temperature between 1500.degree. F. and 2000.degree. F. (815.degree. C. and 1093.degree. C). The calcined coke agglomerates are characterized by having a stability of not less than 60%.

Abstract: Adjacent alternating rows of relatively coarse and fine coal are deposited onto a horizontal moving grate running through a coking furnace.

Abstract: The method of producing blast furnace coke by (1) compacting a finely divided coal wherein at least about 60% by weight of the coal has a diameter of less than about 1/8 inch to form a coal compact, which compact immediately after removal from the compacting means comprises at least about 20% by weight of particles having a particle size of less than 1/4 inch in diameter; (2) breaking the thus formed compact such that the bulk density is sufficiently increased to be capable of conversion into coke suitable for use in large blast furnaces upon carbonization thereof; and (3) carbonizing the broken compact to thereby produce blast furnace coke having a minimum hardness of about 68 and a minimum stability of about 55. The compacting is preferably performed at a pressure equivalent to that achieved by passing the finely divided coal between rolls at a pressure applied to the coal of between about 20 and about 60 tons per lineal inch.

Abstract: A process for producing formcoke composed of char and selected binders comprising process steps in which non-oxidative thermal carbonization is employed.

Abstract: A horizontal circulating carbonizer comprising an annular horizontally rotatable circulating hearth disposed rotatably, a carbonizer body covering said hearth, a coal feeder equipped on the carbonizer body, a preheating zone disposed in the vicinity of said feed coal supply opening, a carbonizing zone connected to said preheating zone, a cooling zone connected to the carbonizing zone, and a discharger of cooled coke, and a process for the preparation of coke using this horizontal circulating carbonizer.

Abstract: Process for manufacturing an isotropic carbonaceous material having a high density and a high crushing strength which comprises the steps of (a) extracting a reformed coal from at least one component selected from the group consisting of brown coal, lignite and grass peat in the presence of hydrogen gas; (b) heating the reformed coal to produce a green coke; and (c) coking the green coke.

Abstract: A plurality of different types of raw material coal fines are sieved to a size not exceeding 1.5 mm; said sieved raw material coal fines are blended so as to satisfy the following conditions:(a) AP index: 75 at the minimum,(b) Mean maximum reflectance: 1.20% at the minimum, and(c) A [dilatation] - [contraction] value of from -2 to +5% when carbonized under conventional conditions in a horizontal type coke oven battery at a heating rate of 5.degree. C/min. (350.degree. - 600.degree. C);said blended raw material coal fines thus obtained are mixed with a binder and formed to produce a formed coal; and then, said formed coal thus obtained is charged into a horizontal type coke oven battery and carbonized, whereby a high-strength formed coke for blast furnace is a slight mutual agglomeration is manufactured.

Abstract: With the use of low-fluidity blended raw material coal fines having a maximum fluidity of up to 20 d.d.p.m. as an inner core material, and coal fines having a maximum fluidity of at least 30 d.d.p.m. or a bituminous material having a C/H ratio of from 0.7 to 1.9 as an outer envelope material, green composite briquettes are formed by covering said inner core material with said outer envelope material. Said green composite briquettes thus formed are charged into a conventional coke oven battery and carbonized by an ordinary process, whereby a high-strength metallurgical formed coke in a slight mutual agglomeration is produced.

Abstract: Process for producing formed coke for metallurgical use from coal powder by continuously heating with a high temperature gas as heating medium for carbonizing agglomerated coal which are made of coal powder and a binder such as coal tar, pitch and petroleum asphalt, comprising providing tuyeres for introducing gas at the middle and the lower parts of an upright type carbonization oven, adjusting temperature of the gas to be supplied to the tuyere at the middle part at 600.degree. to 800.degree. C, adjusting the supply rate of the gas so as to maintain the temperature of the gas on the agglomerated coal at 300.degree. to 500.degree. C, and further adjusting the supplied heat to the lower part of the carbonization oven including the lower tuyere to amount less than 50% of the total supplied heat.

Abstract: A process for preparing blast furnace cokes which contain large amounts of low-grade coal which comprises the steps of adding a binder to a coal for making briquettes which comprises a substantially low-grade coal such as non- and/or poorly-coking coal; either alone or when blended in an amount of up to about 40% or more with a charging coal; mixing the binder and the coal briquetting the mixture in a roll press to form briquettes of two or more types; blending the resulting briquettes of different types with a charging coal in a total amount of about 35% or more of the briquettes based on the charging coal and, to prepare a blended charging coal; and carbonizing the blended charging coal in a coke oven.

Abstract: A method of producing form coke that is coke having pieces of substantially identical form using a heated shaft furnace comprises mixing fine coke with a caking coal and pressing the mixture at temperatures at which the mixture is plastic in order to form briquettes. The briquettes are permitted to harden and degasify and thereafter they are exposed to a high temperature after hardening for example to a temperature of from 400.degree. to 900.degree. C from 60 to 120 minutes. Thereafter the briquettes are cooled. A first mixing substance is prepared by permitting a fine coal to fall in a non-compressed stream in the shaft furnace while heat is transferred thereto substantially by radiation.

Abstract: A substance to be treated for the production therefrom of useful products (usually decomposition products) is formed into a bed on a perforate support, the bed having a thickness of up to about one inch. An inert atmosphere is maintained above and in contact with the bed in a substantially closed space of constant volume. The bed is heated to progressively increasing temperatures by means of a radiant heat source located in the closed space at a distance of up to one and one-half inches above the upper surface of the bed. As the bed is heated, liquid products are educted from the substance and are removed by the force of gravity from the bottom of the bed through the perforate support.

Abstract: Raw coal is charred in pre- and post-treatment carbonizers, then pulverized, mixed with pitch, briquetted, re-circulated through the pre- and post-treatment carbonizers with succeeding green coal, cooled, and finally separated from the as yet un-briquetted char.