Abstract: The present invention relates to a system and a process for obtaining phenanthrene of about 95% purity from coal tar distilled fraction containing crude phenanthrene by performing fractional distillation at a reduced pressure of 50 mm mercury and at a temperature range of 160-180° C. to obtain first distilled fraction containing acenaphthene and fluorene; a second distillate fraction at a temperature range of 200-230° C. containing phenanthrene, anthracene and traces of carbazole; followed by re-distilling the second distillate fraction at a temperature range of 210-224° C. to finally obtain pure phenanthrene and a residue which is again used for the recovery of residual phenanthrene by re-distillation at a temperature range of 210-224° C.

Abstract: Tire pyrolysis systems and processes are provided which include feeding tire shreds to a pyrolysis vessel (40) and pyrolyzing the shreds in a pyrolysis vessel (40) to produce a pyrolysis gas and carbon black mixture. The pyrolysis gas processed by centrifugally separating entrained particles therefrom, separating the pyrolysis gas into a hydrocarbon condensate and a light vapor, removing entrained hydrocarbon condensate from the light vapor, and purifying and refining the hydrocarbon condensate. The carbon black mixture is processed by pulverizing the mixture to break up all strands and clumps of inorganic solids, cooling the carbon black mixture, separating the gross contaminants from the carbon mixture, and purifying and refining the carbon black. The hydrocarbon condensate is purified and refined by removing all remaining contaminants, removing any polycyclic aromatics to produce a clear, colorless plasticizer oil.

Abstract: A film-type vaporizer in a vaporization enclosure, for example the upper column of a double air-distillation column, is associated with a measurement and analysis box where a polished surface and a spillway reconstruct the flow of liquid in the vaporizer in order to check for the absence of the deposition of impurities in the liquid that is to be evaporated. If deposition occurs, the impurities involved are quantified and analyzed and appropriate action taken on the settings of the machine.

Abstract: This invention concerns a database computer system and method for making applications recoverable from system crashes. The application state (i.e., address space) is treated as a single object which can be atomically flushed in a manner akin to flushing individual pages in database recovery techniques. To enable this monolithic treatment of the application, executions performed by the application are mapped to logical loggable operations which can be posted to the stable log. Any modifications to the application state are accumulated and the application state is periodically flushed to stable storage using an atomic procedure. The application recovery integrates with database recovery, and effectively eliminates or at least substantially reduces the need for check pointing applications. In addition, optimization techniques are described to make the read, write, and recovery phases more efficient.

Abstract: The invention provide a process for energy recovering through waste classification and calcination and an apparatus therefor, comprises crushing and sorting various types of wastes and by means of a series of classification, calcination and recovering treatments, recovering and reusing efficiently fuel oil, fuel gas and residues as well as electric power and heat required for the apparatus in the self-supplying feedback system of the invention, and additionally, lowering successfully the possibility of secondary pollution from wastes disposal.

Abstract: A purge chamber for purging oxygen from interlocking, solid material, such as shredded tire pieces, prior to further processing of the material in a liquefaction apparatus. The purge chamber includes a chamber for holding interlocking, solid material An entrance port is connected to the chamber for passing the interlocking, solid material into the chamber. A purge device communicates with the chamber for providing a purging gas to the chamber. An exit port of the chamber passes the interlocking, solid material from the chamber. An auger screw mounted in the chamber, when rotated, moves the interlocking, solid material from within the chamber into the exit port.

Abstract: A discharge system is used with a tire liquefaction process using a reactor. The system includes a receiver receiving unreacted components, including oil coated metal from the reactor. The unreacted components are moved through a pyrolysis reactor where they are heated to a temperature sufficient to convert the unreacted hydrocarbon components to a liquid and to a gas by way of pyrolysis. The liquid and the majority of gas are drawn off from the pyrolysis reactor. Discharge apparatus connected to the pyrolysis reactor converts the remaining gas to a condensate and discharges the metal. The condensate is also removed for further use.

Abstract: Apparatus for the thermal conversion of solids containing hydrocarbons. In one embodiment for solids which can be converted entirely to vapour, pieces of the solids are continually fed into a molten lead bath in an oxygen free atmosphere in an elongated conversion chamber. An auger partially immersed in the lead bath carries the floating pieces along in the molten lead bath until they are gradually converted to hydrocarbon vapour which rises upwardly to a condenser. In another embodiment for solids which can be converted to a vapour, particulate matter and residual solids, the lead bath extends further into a separation chamber with an inclined retaining skirt extending between the conversion chamber and the separation chamber, The auger forces the particulate matter and residual solids remaining after vaporization down under the inclined skirt, but the hydrocarbon vapour is prevented from escaping into the separation chamber.

Abstract: Used batteries and other material for reclamation and recovery or environmentally safe disposal are transferred from a feed bin by an auger into a crusher and then into a pyrolysis chamber. The feed system excludes air or oxygen from passing through the auger and crusher into the pyrolysis chamber. The material from the crusher is transferred by an auger through the pyrolysis chamber which is heated to a decomposition temperature between 350.degree. and 650.degree. F. and is decomposed. The pyrolysis chamber includes a vapor recovery system for removing the vapors and maintaining a vacuum in the pyrolysis chamber. The vapors are withdrawn through a heat exchanger and into the liquid/gas separator where the condensed liquids are removed and the gas is further processed. The residue from the pyrolysis chamber is discharged into a residue recovery system which includes a closed auger for transferring the residue from the pyrolysis chamber into a bin.

Abstract: A method for producing a solid fuel from combustible waste includes sorting and grinding the waste, treating the waste by heating in the absence of oxygen in a first pyrolysis reactor and then collecting the waste so treated. Polluting elements in the gases emerging from the pyrolysis are removed while the gases are hot before being directly reused to heat a first pyrolysis reactor so that solids leaving the pyrolysis operation provide a fuel without the pollutants initially contained in the waste. The device for carrying out this method includes a pyrolysis reactor and a unit for supplying an absorbent to a zone wherein the gases generated by pyrolysis are contacted by the absorbent to remove the polluting elements; the absorbent and the decontaminated solids are separated from each other.

Abstract: Heating of polyvinyl chloride, in particular plasticizer-containing polyvinyl chloride, to a temperature of from 250.degree. to 500.degree. C. in the absence of oxygen gives a low-chlorine, carbon-containing residue, plasticizer and hydrogen chloride.

Abstract: A discharge system is used with a tire liquefaction process using a reactor. The system includes a receiver receiving unreacted components, including oil coated metal, from the reactor. The unreacted components are moved through a pyrolysis reactor where they are heated to a temperature sufficient to convert the unreacted hydrocarbon components to a liquid and to gas by way of pyrolysis. The liquid and the majority of gas are drawn off from the pyrolysis reactor. Discharge apparatus connected to the pyrolysis reactor converts the remaining gas to a condensate and discharges the metal. The condensate is also removed for further use.

Abstract: The reactor forms a chamber which contains the reaction process. There are accesses to the chamber for receiving shredded tires and oil. There are egresses from the chamber for discharging the tire oil and for discharging unreacted elements. Apparatus is located within the chamber which separates the unreacted components of the shredded tires from the tire oil. The apparatus also provides for the removal of the unreacted elements from the chamber means. The reactor also includes a heater which heats the inside of the chamber to a temperature sufficient to cause a reaction between the shredded tires and the oil.

Abstract: An apparatus for the thermal conversion and recovery of organic waste materials includes an oxygen-free chamber filled with molten lead and a method of use of the apparatus. The chamber is elongate and inclined so that organic material introduced in a lower portion of the chamber migrates through the molten lead to a higher portion of the chamber due to the organic material having a specific gravity less than that of lead. As the organic material migrates through the molten lead, the material is thermally converted to gaseous and vapor hydrocarbons that are captured in a condenser. The gaseous hydrocarbons are utilized to heat the lead in the chamber and the vapor is condensed to liquid hydrocarbons in the condenser. Residual solids flow to a reservoir connected to the chamber. Light carbon black is drawn into a receiver by a vacuum line located near the top of the reservoir and all other residual solids flow over a reservoir wall.

Abstract: The invention concerns a process for removing dust from coke cooled by a dry method after the coke has left the cooling zone of a cooling chamber, and a device for carrying out the process. A dust-free flushing gas is injected below the cooling zone, preferably parallel to the direction in which the coke moves when it has been cooled to below 200.degree. C., to draw the gas off above the discharge lock together with the stirred-up coke dust, and to recirculate the gas after the dust is removed from it. As an alternative, compressed air is blown through the coke after it has left the lock and while it is being transported through a vibrating machine. The coke is cooled in a dry cooling unit to below 200.degree. C. and preferably 130.degree. to 180.degree. C. The coke is then cooled outside the dry cooling unit by means of air at about 50.degree. to 90.degree. C. and preferably 70.degree. to 80.degree. C.

Abstract: A method of cooling and dedusting coke after leaving the coke dry cooling system comprises directing the coke at a temperature of approximately 150.degree. to 200.degree. C. into an immersion tank which has a liquid temperature of approximately 100.degree. C., thereafter conveying the coke out of the immersion tank at a selected variable speed so as to free it of fine dust. The water content of the coke after leaving the immersion tank and after an adequate evaporation time is controlled by the speed of the conveyor which is located in the immersion tank and the water content is advantageously kept below 5%, preferably from 0 to 3%. The immersion tank comprises a closed housing overlying a box-shaped tank with a continuously revolving chain conveyor located so as to extend through the tank at its upper reach for conveying the coke into the tank and which has a lower return reach which is directed outside of the tank below the tank itself.

Abstract: A polymeric material containing solids in the form of metal and/or cord lumps is partially thermally decomposed to produce a suspension of the polymeric material containing solids in the form of metal and/or cord lumps. Then, the suspension with the solids is directed to a separator, which may be an inclined conveyor, where the solids and the suspension are separated. The separated polymeric material then is thermally decomposed completely. In the separator, the separated solids may be treated by flushing the solids on the conveyor with a preheated solvent, followed by applying steam to the solids and finally drying the solids on the conveyor. Thermal decomposition of the separated polymeric material is completed in a vertical distillation column having a lower liquid phase and an upper vapor-gas phase.

Abstract: A device for and method of working up etching and pickling liquids consisting of a vertical furnace having one or more vertical reaction spaces through which balls move at a maximum packing density.The furnace has a temperature gradient from the bottom (high) to the top (low). The reaction space and the balls consist of a material which is inert with respect to the liquid to be worked up. The liquid is introduced into the upper side of the furnace so that a film is formed in the heated surface of the balls. The salt dissolved in the liquid decomposes pyrolytically. The metal oxide is deposited on the surface of the balls and is removed therefrom after leaving the reaction space. The acid residue vapours are drained at the top and recovered in a separate absorber to the original pickling or etching acid.

Abstract: In an oil shale retorting process, hot heat-carrying spherically-shaped solids are cycled to a retort zone to mix with and retort crushed oil shale, thereby producing gas and oil products and a mixture of irregularly-shaped, laminar spent shale and spherically-shaped solids. The spherically-shaped solids are separated and recovered from the spent shale for recycle through the process. In one stage of the separation procedure, a mixture of spent shale and spherically-shaped solids is fed to a continuously restored inclined surface whereon the spherically-shaped solids roll from the surface while the irregularly-shaped spent shale solids are separately removed from the inclined surface. Continuous restoration of the inclined surface is achieved through movement of the feed and the impingement area of the inclined surface relative to each other. The separation system may be used for separating other types of spherically-shaped solids which will roll from nonspherical, irregularly-shaped solids which do not roll.

Abstract: There is provided a system for segregating through comminution and classification solid waste into ferrous metal, inorganic, and organic fractions. The inorganic fraction is further classified into aluminum and glass fractions. The organic fraction is further comminuted, dried and fed to a pyrolysis system where it is converted to gas for use in drying the organic material for feed to the pyrolysis system, pyrolytic oils and char. The principal saleable products recovered are char, pyrolytic oils, glass, aluminum, and ferrous metal.

Abstract: A method of cooling a hot particulate material, such as calcined petroleum coke, is described.The stream of hot particulate material is split as it leaves the device or calciner in which it has been heated. A major portion of it, such as about 80-90%, is dropped directly into a tank of hot water. This material is then separated from the hot water while simultaneously being transferred to a cooling device (such as a rotary cooler) by a suitable conveyor system. The minor portion of hot material is transferred directly from the calciner to the cooling device. In the cooling device, the residual heat content in this hot, minor portion of particulate material is used to drive off the remaining water or moisture contained in the quenched major portion of material.