Abstract: Described herein are systems and methods for the depolymerization of polyethylene-based plastics. In one embodiment, a method is disclosed that comprises combining a polyethylene-based plastic with a solvent in a reactor to generate a plastic solvent mixture, heating the plastic solvent mixture in the reactor, and fractionating the plastic solvent mixture into a gas phase product, a solid phase product, and a liquid phase product. In another embodiment, a system is disclosed that comprises a solvent, and a reactor configured to receive the polyethylene-based plastic and the solvent and convert the polyethylene-based plastic into a gas phase product, a solid phase product, and a liquid phase product, the reactor being configured to operate at a temperature greater than 275° C. and at a pressure greater than 2 megapascals.

Abstract: The present technology describes methods and systems for an improved quench tower. Some embodiments improve the quench towers ability to recover particulate matter, steam, and emissions that escape from the base of the quench tower. Some embodiments improve the draft and draft distribution of the quench tower. Some embodiments include one or more sheds to enlarge the physical or effective perimeter of the quench tower to reduce the amount of particulate matter, emissions, and steam loss during the quenching process. Some embodiments include an improved quench baffle formed of a plurality of single-turn or multi-turn chevrons adapted to prevent particulate matter from escaping the quench tower. Some embodiments include an improved quench baffle spray nozzle used to wet the baffles, suppress dust, and/or clean baffles. Some embodiments include a quench nozzle that can fire in discrete stages during the quenching process.

Abstract: A pyrolysis furnace having a heating chamber which surrounds a cylindrical pyrolysis chamber. The heating chamber is assembled from an upper part and a lower part, which can be joined. Each part of the heating chamber is provided with two rows of heating elements, which are arranged along the length of the housing of the heating chamber symmetrically relative to a vertical plane passing through the axis of the pyrolysis chamber. The heating elements are in the form of units, containing at least one flameless gas burner. The heating elements in the upper part of the heating chamber are arranged in a checkerboard fashion relative to the heating elements in the lower part. The furnace relates to power generation and the environment and is intended for the thermal processing of solid and free-flowing materials, particularly in processes for the pyrolysis of solid carbon-containing materials, including municipal and domestic waste.

Abstract: Efficient coal pre-processing systems (69) integrated with gasification, oxy-combustion, and power plant systems include a drying chamber (28), a volatile metal removal chamber (30), recirculated gases, including recycled carbon dioxide (21), nitrogen (6), and gaseous exhaust (60) for increasing the efficiencies and lowering emissions in various coal processing systems.

Abstract: A gasifier comprises an internal chamber, a slag collection region, a slag passageway, a slag breaker, and an actuator. The internal chamber comprises a main combustion region that is configured and adapted to gasify fuel. The slag collection region is located beneath the main combustion region. The slag passageway operatively connects the main combustion region to the slag collection region. The slag breaker comprises a face that is movable relative to the internal chamber. The face is configured and adapted to move within the slag passageway in a manner such that the face contacts and mechanically breaks solidified slag into chunks of solidified slag that then fall into the slag collection region. The actuator is connected to the slag breaker and is configured and adapted to move the face of the slag breaker.

Abstract: A method for reducing the coking time in the oven area near the door or end wall and for improving coke quality and situation of emissions by compensating for radiation losses through coke oven chamber doors and end walls is described. This compensation is accomplished by varying the height of the coal cake in the environment of the frontal coke oven chamber doors. The variation is achieved both by increasing or decreasing the coal cake over part of the length or over the entire length of the coke oven chamber door. The reduction in the height of the coal cake can be generated by omission of coal or coal compacts, the increase in height can be accomplished by stacking of coal and pressing or adding of coal compacts, with it also being envisaged to omit the pressing cycle so as to obtain a recess with a lower coal cake density which also has less heat radiation.

Abstract: A process for heat treatment of a solid, with a coolant solid, in which a stage for mixing the solid with the pre-heated coolant solid is carried out, with the coolant solid being a solid hydrocarbon. The solid hydrocarbon is ground, before the mixing stage with the solid, to obtain a solid hydrocarbon powder with a grain size of between 20 ?m and 300 ?m. The solid is ground, before the mixing stage with the coolant solid, to obtain solid pellets with a thickness of between 1 mm and 30 mm, a width of between 1 mm and 40 mm, and a length of between 1 mm and 100 mm. The mixing is carried out at a temperature of between 80° C. and 700° C.

Abstract: A process for treating a human remains comprises the steps of subjecting the remains to pyrolysis in a pyrolysis chamber under conditions that convert the particulate material to biochar remains.

Abstract: A disposal method for entirely recycling solid refuse includes the following steps: sorting, crushing, drying, pressing with high pressure to shaped articles, producing charcoal from combustible refuse in high temperature and firing incombustible refuse in high temperature, at last cooling high temperature articles to obtain solid fuel with various shapes and bricks or board used for building. The method achieves entirely recycling house refuse, especial solid refuse. The method recycles solid refuse to obtain fuel and building material with economic value. The method is simple and its processing cost is low.

Abstract: The method produces a hydrocarbonaceous fluid (a liquid mixture of hydrocarbons, or in other words a mixture of hydrocarbons which is liquid at ambient room temperature and atmospheric pressure), which functionally is a liquid hydrocarbon fuel, from a feed of waste plastic. The method can comprise the steps of: (step 1) melting a feed of substantially solid waste plastic in an aerobic atmosphere (for instance, air) whereby a waste-plastic melt is produced; (step 2) distilling at least a portion of the waste-plastic melt whereby a hydrocarbonaceous distillate is produced; and (step 3) collecting the hydrocarbonaceous distillate. That distillate is generally referred to above as a condensate. The method can include the step of comminuting the feed of substantially solid waste plastic into pieces substantially no greater than about 1.5 cm2 prior to step 1. The method can also include the step of adding an effective amount of a cracking catalyst to the waste plastic prior to step 2.

Abstract: A method for producing individual compacts made of coke and suitable for coke oven chambers by dividing a coal cake in a non-mechanical manner, wherein the coal cake is produced by a compression method according to the prior art and the coal cake is divided by non-mechanical, energy-supplying media, and the non-mechanical media supplying shearing energy are, for example, a laser beam, a high-pressure water jet, an abrasive-solid jet, an ultrasonic beam, a compressed-air jet, or a gas jet. By using the method, coal compacts can be produced from coal cakes without forming dust, without wearing out cutting tools, and with high precision.

Abstract: A process and a unit for fluidized bed torrefaction and grinding of particles of a biomass with a largest dimension of 2 cm to 5 cm, and which unit contains an envelope having a general shape of a sector having a) two substantially vertical walls delimiting that sector; and b) at least one inclined wall defining three zones, from bottom to top: a lower zone provided with a fluidization means, and provided with a grinder placed at the bottom of that zone; an intermediate zone (2) provided with a fluidization means; and an upper zone (3) provided with a fluidization means; and a pipe (11) for introducing the particles reaching into the unit to the level of the intermediate zone.

Abstract: A method for compacting coal in a manner suitable for coke oven chambers is described. The coal is initially compressed by means of a suitable compressing device into one or more coal cakes, and the obtained coal cakes are divided into compacted products by a cutting device. The compacted products are stacked on top of the each other such that they can be loaded into a coke oven chamber for coking. The compacted products enable the coke oven chambers to be loaded in a precise and a coal loss-free manner. The coal compacted products are easy to store.

Abstract: Method for fast pyrolysis of lignocellulose including: mechanically comminuting the lignocellulose to lignocellulose particles; at least one of completely drying and preheating the lignocellulose particles; mixing the lignocellulose particles with heat transfer particles so as to provide a mixture; heating the heat transfer particles, prior to the mixing, to a temperature between 500° C. and 650° C.; and heating, in a pyrolysis reactor with oxygen excluded, the lignocellulose particles using the heat transfer particles so as to establish a temperature between 400° C. and 600° C. for 1 to 50 seconds and so as to react the lignocellulose particles so as to provide pyrolysis coke, pyrolysis condensate, and pyrolysis gas.

Abstract: A process for obtaining petrochemical products from a carbonaceous feedstock is provided. The carbonaceous feedstock may be coal, coke, lignite, biomass, bitumen and the like. The carbonaceous feedstock is pulverized and fed to a pyrolysis reactor where the feedstock is pyrolyzed at 700-1000° C. at a pressure of 2-25 bar for 2-10 seconds, wherein the feedstock is entrained in hot syngas during the pyrolysis process.

Abstract: The invention provides an apparatus and method for thermolysis of waste plastic in which reaction residue and carbonization products are continuously removed. The apparatus includes a feeding system, an extruder, a reactor for thermolysis, a dual agitator housed within the reactor, a trigger system in operative connection with the reactor, a flux heater, and a collecting system in operative connection with the reactor. The reactor for thermolysis has a height at least 1.5 times bigger than a diameter. The trigger system includes a circulation pump and the collecting system has a three-way valve in an external circulation loop. The apparatus is arranged such that the extruder follows the feeding system, the reactor follows the extruder, the trigger system is at a bottom of the reactor, and the flux heater and collecting system follow the reactor.

Abstract: The invention provides an apparatus for thermolysis of waste plastics, particularly polyolefins. The apparatus includes a feeding system, an extruder, a main thermolysis reactor, a dual propeller/mixer housed within the reactor, and a discharging system. The height of the thermolysis reactor is at least 1.5 times bigger than the diameter. The apparatus is arranged such that the extruder follows the plastic feeding system, the thermolysis reactor follows the extruder, and the discharge system follows the thermolysis reactor. The invention also provides a method for using the apparatus for thermolysis of waste plastics. In this method, reaction feedstock, reaction residuals, and reaction products are removed continuously.

Abstract: Provided herein is a method, device and installation for devolatizing a solid feedstock, comprising carbon-based waste selected from the group consisting of hazardous material, biomass, animal manure, tires, municipal solid waste and refuse derived fuel. The method comprises treating the solid feedstock to a produce a particle size laying between about 1 cm3 and about 100 cm3. The solid feedstock is passed into a jacketed system. The solid feedstock is contacted with a heated gas, comprising hydrogen, inside the jacketed system at a temperature of about 500° C. to about 1000° C. for a time of about 60 seconds to about 120 seconds, whereby the solid feedstock is converted into a gas stream and a solid stream.

Abstract: A system for recycling carbon-containing material is provided. The system includes a reactor for heating the carbon-containing material to produce carbon-containing gases. The system further includes a condenser operably connected to the reactor for condensing a portion of the carbon-containing gases to provide condensed gas and non-condensed gas. The system further includes a conduit arrangement operably connected to the reactor and the condenser wherein the non-condensed gas from the condenser is returned to the reactor.

Abstract: A process for obtaining petrochemical products from a carbonaceous feedstock is provided. The carbonaceous feedstock may be coal, coke, lignite, biomass, bitumen and the like. The carbonaceous feedstock is pulverized and fed to a pyrolysis reactor where the feedstock is pyrolyzed at 700-1000° C. at a pressure of 2-25 bar for 2-10 seconds, wherein the feedstock is entrained in hot syngas during the pyrolysis process.

Abstract: A biocoke producing apparatus has a reaction vessel that has a preset temperature range and pressure range for, without carbonizing of the pulverized biomass, inducing a pyrolytic or thermal curing reaction of lignin and hemicellulose thereof. The reaction vessel has a pressurization device for pressurizing to the pressure range, a heating device for heating to the temperature range in the state of the pressurization and a cooling device for cooling after maintaining of the above state. Multiple reaction vessels are provided. A pulverization delivery conveyor is provided superior to these reaction vessels, and each of the multiple reaction vessels is connected via a connection tube to the conveyor. The connection tube is provided with a pulverizate charging device for charging a given amount of pulverized biomass in accordance with a timing of pulverizate charging to the reaction vessels.

Abstract: A method for producing a vapor stream from waste plastic comprises providing a waste plastic feedstock into a reactor containing one or more residues produced from a previously heated source of waste plastic, and heating the waste plastic feedstock in the reactor to a temperature from about 125° C. to 500° C. to generate a vapor containing one or more hydrocarbons. The waste plastic feedstock can be heated in the reactor without any added external catalyst. The waste plastic feedstock can have a calcium to sodium mass ratio from about 0.0001 to 400 as measured by inductively-coupled plasma (ICP) spectrometry. The catalytic activity in the reactor may be provided through one or more constituent elements in the waste plastic feedstock or the one or more residues produced from the previously heated source of waste plastic.

Abstract: A carbonization process of rubber products, such as shredded waste tires, in a sealed carbonizing vessel whose operating pressure is below atmospheric pressure and under controlled high temperature environment while continuously being moved in a defined path at a controlled speed thus enabling the shredded tires to be fed constantly into the vessel while the by-products of the carbonization process are continually discharged.

Abstract: According to various embodiments, systems and methods are provided for converting sewage, sludge, wet feedstock, animal waste, municipal trash, and/or other biomasses into combustible fuels. According to various embodiments, sewage is dewatered, pulverized, desiccated, pelletized, and/or subjected to pyrolysis in order to produce bio-fuels, combustible gases, and/or chars. Bio-fuels, gases and/or chars may be collected during and/or after pyrolysis for use as combustible fuels. According to various embodiments, the collected bio-fuels, gases and/or chars may be transported for later use as a fuel. The collected gases may be liquefied and transported for later use as a fuel.

Abstract: A process for treating bituminous coal includes providing dried, pulverized coal, and treating the pulverized coal in a vessel with a gas stream having an oxygen content sufficient to form oxides on surface of coal particles. The treated coal is transferred into a pyrolyzing chamber and passed into contact with an oxygen deficient sweep gas, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to the coal indirectly by heating the chamber, wherein the heating of coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. Some of the oxides are converted into paramagnetic mineral components, which are removed from coal to form a coal char having reduced ash and sulfur.

Abstract: A process for treating agglomerating coal includes providing dried, pulverized, agglomerating coal, and treating the coal in a vessel with a gas stream having an oxygen content sufficient to form at least some oxides on surface of coal particles, wherein the oxides are sufficient to convert coal into substantially non-agglomerating coal. The treated coal is transferred into a pyrolyzing chamber and passed into contact with an oxygen deficient sweep gas, the sweep gas being at a higher temperature than the temperature of the coal so that heat is supplied to the coal. The process further includes providing additional heat to coal indirectly by heating the chamber, wherein the heating of coal by the sweep gas and by the indirect heating from the chamber causes condensable volatile components to be released into the sweep gas. The sweep gas is removed from the chamber and treated to remove condensable components of coal.

Abstract: To provide a method for catalytically cracking waste plastics wherein the efficiency in decomposition is high; even polyethylene composed of linear chain molecules difficult in decomposition is decomposable at a low temperature and decomposed residue is hardly produced; the process is simple since dechlorination can be achieved at the same time with catalytically cracking waste plastics in one reaction vessel; and oil fractions can be recovered at 50% or more on a net yield basis. The method for catalytically cracking waste plastics of the present invention has a constitution in which waste plastics are loaded as a raw material into a granular FCC catalyst heated to a temperature range from 350° C. to 500° C. inside a reaction vessel, thereby decomposing and gasifying the waste plastics in contact with the FCC catalyst.

Abstract: This invention relates to biomass pyrolysis through the use of a hot liquid refinery feedstock as a heat transfer medium, preferably a vacuum gas oil feedstock.

Abstract: A biomass fractionator and method are described for inputting ground biomass and outputting several vapor streams of bio-intermediate compounds along with syngas and biochar. In one embodiment, a method for biomass fractioning, comprises dispensing biomass into thin sheets of ground biomass; subjecting the thin sheets to ramps of temperature; and selectively collecting various groups of compounds as they are released from the thin sheets.

Abstract: A solidified biomass consisting of semi-carbonized or pre-semi-carbonized solid matter is pressure-formed from raw biomass material while being heated and has a maximum compressive strength of 60-200 MPa and calorific value of 18-23 MJ/kg. A method for producing the solidified biomass: includes crushing raw biomass material; loading a barrel with the crushed raw biomass material; inserting a pressure applying piston into a hollow of the barrel; pressure-forming the crushed raw biomass materials by applying pressure with the pressure applying piston while heating the material; obtaining semi-carbonized or pre-semi-carbonized solid matter by retaining constant time of the heating and the pressurizing; cooling the semi-carbonized or pre-semi-carbonized solid matter while maintaining pressure to obtain a cooled solid; and taking out and drying the cooled solid, wherein the pressure applying piston and the hollow of the barrel have very small clearance between their outer and inner peripheries.

Abstract: A biochar generator to be carried by a vehicle may comprise a pyrolysis chamber, an auger, a heater, and a vapor condenser each connected to the pyrolysis chamber. The biochar generator may also include a synthesis gas collection chamber to collect synthesis gas, and a bio oil collection chamber to collect bio oil, each in communication with the vapor condenser. A biochar collection chamber may be included to collect biochar dispensed from the pyrolysis chamber.

Abstract: A method and apparatus for transporting and quenching coke, useful in quenching a batch of coke produced in one of a plurality of coke ovens forming a coke oven battery, is disclosed. A hot car defining a substantially planar receiving surface is positioned adjacent a coke oven of the coke oven battery, and a unitary cake of unquenched coke is placed onto the hot car receiving surface. The hot car and unquenched coke are transported to a transfer station having a dust collection system. A quenching car is positioned at the transfer station adjacent the hot car, under the dust collection system. The unitary cake of unquenched coke is dumped into the quenching car receptacle, thereby separating the unitary cake. At least a portion of the dust generated by separation is collected. The quench car is then transported to a quenching station, where the separated coke is quenched.

Abstract: To provide a method for catalytically cracking waste plastics wherein the efficiency in decomposition is high; even polyethylene composed of linear chain molecules difficult in decomposition is decomposable at a low temperature and decomposed residue is hardly produced; the process is simple since dechlorination can be achieved at the same time with catalytically cracking waste plastics in one reaction vessel; and oil fractions can be recovered at 50% or more on a net yield basis. The method for catalytically cracking waste plastics of the present invention has a constitution in which waste plastics are loaded as a raw material into a granular FCC catalyst heated to a temperature range from 350° C. to 500° C. inside a reaction vessel, thereby decomposing and gasifying the waste plastics in contact with the FCC catalyst.

Abstract: A process for treating solid organic materials, especially for recycling treated wood, uses energy provided by hot gases at the bottom of a reactor column to perform a distillation operation which ensures splitting of organic bonds in the material and uses, as the distillation operation progresses, constant control between a first temperature of the hot gases before they are introduced into the lower part of the reactor column and a second temperature of a layer of the material located in an area immediately above the grid of the reactor column. When the first temperature and the second temperature are identical or virtually identical, corresponding to removal of all the organic bonds of the material by evaporation and transport by the hot gases from the bottom to the top of the column, the layer of material at the second temperature is removed in order to collect a material that largely consists of carbon and constitutes a secondary raw material.

Abstract: The invention relates to waste processing and to producing hydrocarbons from domestic and industrial organic waste by pyrolysis. The inventive waste processing method involves carrying out the first and second pyrolysis stages, fractionating pyrolysis products and processing each fraction for producing useful products. The second pyrolysis stage is carried out simultaneously with the electromagnetic action produced on the pyrolysis products. The device for carrying out said method comprises a two-sectional pyrolysis reactor. An electromagnetic source is arranged on the second section of the reactor. The output of the second section is connected to a system for dividing the vaporous pyrolysis products. The technical result consists in increasing the waste processing effectiveness and producing solid, liquid and vaporous fuel components.

Abstract: The invention described herein generally pertains to utilization of high power density microwave energy to reduce organic compounds to carbon and their constituents, primarily in a gaseous state. The process includes, but is not limited to, scrap tires, plastics, asphalt roofing shingles, computer waste, medical waste, municipal solid waste, construction waste, shale oil, and PCB/PAH/HCB-laden materials. The process includes the steps of feeding organic material into a microwave applicator and exposing the material to microwave energy fed from at least two linear polarized sources in non-parallel alignment to each other, and collecting the material. The at least two sources of microwave energy are from a bifurcated waveguide assembly, whose outputs are perpendicular to each other and fed through waveguide of proper impedance, such that the microwave sources are physically and electrically 90° out of phase to each other. The microwave frequency is between 894 and 1000 MHz, preferably approximately 915 MHz.

Abstract: A method of production of blast furnace coke comprising drying mixed coal, then, or simultaneously with the drying, classifying it to fine-grained coal and coarse-grained coal, then adding to the fine-grained coal at a temperature of 80 to 350° C. a caking additive comprised of one or more of a heavy distillate of tar, soft pitch, and petroleum pitch, agglomerating it by hot pressing, then mixing the clumps of coal and the coarse-grained coal and charging and carbonizing the mixture in a coke oven.

Abstract: A system and process for the production of combustible substances by means of depolymerisation of rubber products, comprising a depressurized depolymerising device (1), inside which it takes place the depolymerisation of a predetermined quantity of products introduced at its inner, characterized in that it comprises a divider or phases separator (2) disposed downstream said depolymerising device (1), which consists of a substantially cylindrical body, with an upper base (20) and a lower base (21), and is connected with the depolymerising device (1) by means of a pipe (3): said phases separator (2) being apt to carry out the separation of at least a part of the liquid phase of the products exiting the depolymerising device (1), and having an outlet (23) for the thus separated liquid phase and an outlet (24) for the remaining part of the products in mostly gaseous phase.

Abstract: The present invention provides a method of recycling a plastic thereby forming a narrow spectrum of hydrocarbons having from 4 to 14 carbon atoms that can be directly used as gasoline without additional processing or refining. The method includes the step of feeding the plastic, selected from the group of polyethylene, polypropylene, polystyrene, and combinations thereof, into a heated vessel for melting. The method also includes the step of decomposing the plastic at a temperature of from 400° C. to 500° C. in the presence of a metallocene catalyst and a zeolitic catalyst thereby forming the hydrocarbons having from 4 to 14 carbon atoms. The metallocene catalyst includes dichlorobis(2-methylindenyl)zirconium (IV). The zeolitic catalyst includes ammonium Y zeolite and has a pore size of from 1 to 4 Angstroms.

Abstract: The invention relates to coke production in general and specifically to methods and devices for the production of metallurgical coke from noncaking coals. The method comprises metering, crushing and mixing of coal, an adhesion agent, and an organic waste component to produce uniform feedstock and subsequent heating of the feedstock, wherein as the adhesion agent are used high boiling point products of plastic waste pyrolysis, which are added to the feedstock in an amount of 15% to 20% of the total feedstock volume and wherein the feedstock is heated in the temperature range 250° C. to 1100° C. The device comprises a fire-resistant coking chamber; heating ducts; burners; means for charging the material to be coked; a coke discharging means, wherein the device comprises a heating tank provided with a charging hole for charging plastic waste, organic waste, and catalysts; and with a flight conveyor for removing undissolved residues from said tank.

Abstract: A pyrolyzer and method is provided for devolatizing coal and other volatile materials. The pyrolyzer has a pyrolyzer furnace housing having at least two screws laterally positioned adjacent and overlapping rotatably mounted within the furnace for moving volatile material through the pyrolyzer furnace housing. The screws have hollow drive shafts with a diverter inside for converging heated fluid to heat the volatile material moving through the pyrolyzer furnace housing. A combustion chamber combusts fuel to create heated exhaust gas for directing through the hollow drive shafts to heat the volatile material. The pyrolyzer furnace housing may have a double wall with a cavity between, capable of receiving heated fluid for further heating of volatile material moving through the pyrolyzer furnace housing.

Abstract: Relatively high speed methods for increasing the bulk density of coal particles, apparatus for increasing the bulk density of coal particles and methods for making metallurgical coke. Once such method includes depositing coal particles onto a charging plate external to a coking oven to provide an elongate bed of dry, uncompacted coal having an upper surface of the charging plate. The charging plate has side walls, and at least one movable end wall An impact pressure is applied to the upper surface of the bed of dry, uncompacted coal while degassing the coal to provide a dry, compacted coal bed having a bulk density ranging from about 960 to about 1200 kilograms per cubic meter.

Abstract: A retort heating apparatus for processing a feed material includes a heating chamber bounded at least in part by a side wall. A plurality of baffles are at least partially disposed within the heating chamber. Each baffle includes an elongated body having a top surface, at least a portion of the top surface being arched. The plurality of baffles are vertically and horizontally spaced apart so that substantially all of the feed material that vertically passes through the heating chamber is horizontally displaced as the feed material passes by the baffles. Systems are also provided for heating the feed material within the heating chamber.

Abstract: A method is provided for converting coal to coke by the steps of blending pulverized coal with water and a binder to a kneadable dough; and baking said dough in a reducing environment.

Abstract: Closed apparatus and processes by which carbon feedstock, is composed of a mixture of non-coking coal fines and another carbonaceous material, such as waste coke fines are disclosed. The coal and coke fines are mixed together and may be formed into solid pieces. The mixture alone or as solid pieces is fired through pyrolyzation into solid pieces of coke, with solid and gaseous by-products of pyrolyzation being recycled for use within the coke-producing closed system, thereby reducing or eliminating release of undesirable substances to the environment. A char-forming binder may or may not be added to the carbon mixture prior to pyrolyzation.

Abstract: A process for producing a brightness stabilization mixture of water-soluble organic compounds from biomass pyrolysis oils comprising: a) size-reducing biomass material and pyrolyzing the size-reduced biomass material in a fluidized bed reactor; b) separating a char/ash component while maintaining char-pot temperatures to avoid condensation of pyrolysis vapors; c) condensing pyrolysis gases and vapors, and recovering pyrolysis oils by mixing the oils with acetone to obtain an oil-acetone mixture; d) evaporating acetone and recovering pyrolysis oils; e) extracting the pyrolysis oils with water to obtain a water extract; f) slurrying the water extract with carbon while stirring, and filtering the slurry to obtain a colorless filtrate; g) cooling the solution and stabilizing the solution against thermally-induced gelling and solidification by extraction with ethyl acetate to form an aqueous phase lower layer and an organic phase upper layer; h) discarding the upper organic layer and extracting the aqueous

Abstract: A blast furnace coal is produced by rapidly heating a coal blend having 10 to 30% by weight of a non-slightly-caking coal having softening initiation temperature T with the balance including a caking coal having softening initiation temperature T.sub.0 (T.sub.0 .ltoreq.T +40.degree. C.) at a rate of 1.times.10.sup.3 to 1.times.10.sup.6 .degree. C./min to a temperature region from (T -60.degree. C.) to (T +10.degree. C.) wherein T represents the softening initiation temperature of the non-slightly-caking coal; or rapidly heating a non-slightly-caking coal having softening initiation temperature T and a caking coal having softening initiation temperature T.sub.1 separately at a rate of 1.times.10.sup.3 to 1.times.10.sup.6 .degree. C./min to a temperature region from (T -100.degree. C.) to (T +10.degree. C.), wherein T represents the softening initiation temperature of the non-slightly-caking coal, or a temperature region from (T.sub.1 -100.degree. C.) to (T.sub.1 +10.degree. C.), wherein T.sub.

Abstract: A method of forming liquid hydrocarbons from solid coal. The coal is pulverized to provide a particulate coal feed, which is then extruded to provide a hollow tube of compressed coal supported inside of a support tube. A clay feed is extruded to provide a hollow tube of compressed clay supported inside of the coal tube and a combustible fuel is burned inside of the clay tube. The temperature of combustion is sufficient to fire the extruded clay and pyrolyze the extruded coal to produce hydrocarbon gases and coal char. The support tube has holes for releasing the hydrocarbon gases, which contain suspended particles formed during combustion. The suspended particles are removed from the hydrocarbon gases to provide clean gases, which are passed through an ionizing chamber to ionize at least a portion thereof. The ionized gases are then passed through a magnetic field to separate them from each other according to their molecular weight.

Abstract: A thermolysis process for the production of volatiles for an external combustor or liquefaction of biomass solids in which specific and previously unrecognized conditions are employed. The thermolysis is carried out in a single fluidized bed of inert material operating at near atmospheric pressure, relatively low temperature, long solids and gas residence times and moderate heating rates. The distribution of the thermolysis products among, solid (char) and gases under these conditions is unique. The product effluent can be either quenched to produce a high liquid yield in addition to a low char yield or the volatile effluent can be used in either the same combustor or a second combustor to produce heat energy a particularly high efficiency system. In using a quencher, the quenched liquid is of similar composition to those obtained by so called fast pyrolysis processes of the prior art. The specified conditions are such as to allow production of liquids in high yields in an energy efficient manner.

Abstract: A thermolysis process for liquefaction of biomass solids in which specific and previously unrecognized conditions are employed. The thermolysis is carried out in a single fluidized bed of inert material operating at near atmospheric pressure, relatively low temperature, long solids and gas residence times and moderate heating rates. The distribution of the thermolysis products among liquid (bio-oil), solid (char) and gases under these conditions is unique. In particular, contrary to the prior art, both high liquid and low char yields are obtained. Furthermore the liquid is of similar composition to those obtained by so called fast pyrolysis processes of the prior art. The specified conditions are such as to allow production of liquids in high yields in an energy efficient manner. The low severity of the conditions in comparison with previous approaches allows simplified process design and scaleup leading to lower capital and operating costs as well as easier control.