Planar Electrode Surface Patents (Class 204/426)
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Patent number: 12163913Abstract: An electrochemical cell for sensing gas has added mechanical support for the working electrode to prevent flexure of the working electrode due to pressure differentials. The added mechanical support includes: 1) affixing a larger area of the working electrode to the body of the cell; 2) a gas vent to a cavity of the body to equalize pressures; 3) a rigid electrolyte layer abutting a back surface of the working electrode; 4) infusing an adhesive deep into sides of the porous working electrode to enhance rigidity; 5) supporting opposing surfaces of the working electrode with the rigid package body; and 6) other techniques to make the working electrode more rigid. A bias circuit is also described that uses a controllable current source, an integrator of the varying current, and a feedback circuit for supplying a voltage to the counter electrode and a bias voltage to the reference electrode.Type: GrantFiled: June 24, 2020Date of Patent: December 10, 2024Assignee: QUALCOMM Technologies, Inc.Inventors: Jim Chih-Min Cheng, Eric Paul Lee, Jerome Chandra Bhat
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Patent number: 12007353Abstract: A method for producing a gas sensor element, for covering a detection portion (150) by an inner protection layer (21) and an outer protection layer (22), including: a first dipping step of dipping the gas sensor element into a first slurry S1 for the inner protection layer, to form a first coating film (700) on a front end surface (100c) and a peripheral surface (100d); a drying step of drying and solidifying the first coating film; a second dipping step of dipping, without removing the first coating film, the gas sensor element into a second slurry S2 for the outer protection layer, to form a second coating film (800) on a surface of the solidified first coating film; and a scraping-off step of performing scraping-off on the second coating film so as not to scrape-off the first coating film, to remove a part of the second coating film.Type: GrantFiled: August 3, 2021Date of Patent: June 11, 2024Assignee: NITERRA CO., LTD.Inventors: Yuki Hanaki, Suguru Kyomoto, Kaoru Osaki, Kotaro Ueda, Masaki Nakagawa
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Patent number: 12007352Abstract: A gas sensor includes a sensor element and one or more hollow columnar dense bodies. The sensor element includes an element main body having a side surface, a porous layer and a water-penetration reduction portion that cover at least a front end-side part of the side surface. The water-penetration reduction portion disposed on the side surface so as to divide the porous layer or to be located closer to the rear end than the porous layer, an overlap length W that is the length of a continuous overlap between a range in which the water-penetration reduction portion is present in a longitudinal direction and a range in which inner peripheral surfaces of the one or more dense bodies are present in the longitudinal direction being 0.5 mm or more, and having a dense layer covers the side surface, the water-penetration reduction portion reduces the capillarity of water.Type: GrantFiled: June 13, 2022Date of Patent: June 11, 2024Assignee: NGK INSULATORS, LTD.Inventors: Yuki Nakayama, Shota Kageyama, Yusuke Fujii, Kei Kosaka
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Patent number: 12000794Abstract: An illustrative example hydrogen concentration sensor includes a plurality of electrically conductive plates. A hydrogen evolving electrode assembly in a first location between two of the plates is configured to generate hydrogen. A detection electrode assembly in a second location between two of the plates is configured to provide an indication of a concentration of hydrogen in a fluid of interest. A plurality of isolating layers includes a first isolating layer at the first location between two of the plates and a second isolating layer at the second location between two of the plates. The first and second isolating layers each include a sealant that secures the two plates together and seals a perimeter around the electrode assembly at the corresponding location.Type: GrantFiled: December 8, 2020Date of Patent: June 4, 2024Assignee: HYAXIOM, INC.Inventors: Joshua Preston, Marc Soldini
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Patent number: 11977042Abstract: An oxygen sensor for detecting gas concentration based on either an electric current value or a resistance value measured when a voltage is applied to a sensor element includes gaps formed between electrodes arranged in an element main body and ridges where surfaces of an element touch each other. These gaps will be escaping parts for expansion and contraction of electrode material that accompany thermal expansion and contraction of a sensor main body, and concentration of thermal stress at edge parts of the element main body may thus be eliminated, thereby alleviating thermal stress on the oxygen sensor. This allows provision of a gas sensor that controls generation of cracks in the element and that is stably usable over a long period of time.Type: GrantFiled: March 20, 2019Date of Patent: May 7, 2024Assignee: KOA CorporationInventors: Chika Ito, Ken Takahashi, Tetsuro Tanaka, Kenichi Iguchi
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Patent number: 11940405Abstract: A sensor element (10) having a laminate structure, and extending in an axial direction AX, the sensor element including a first and second ceramic layers (118B, 115) disposed apart from each other in a laminating direction; a third ceramic layer (118) intervening between the first and second ceramic layers in the laminating direction and having a hollow space (10G) formed therein; and an internal space which is the hollow space surrounded by the first ceramic layer, the second ceramic layer, and the third ceramic layer, wherein, at a periphery (10f) of the internal space, a fourth ceramic layer (181) containing as a main component a ceramic material different from that contained as a main component in the first and third ceramic layers intervenes between the first ceramic layer and the third ceramic layer which are exposed to the internal space. Also disclosed is a method for manufacturing the gas sensor element.Type: GrantFiled: August 27, 2020Date of Patent: March 26, 2024Assignee: NITERRA CO., LTD.Inventors: Hitoshi Furuta, Akinori Kojima
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Patent number: 11940401Abstract: A sulfurization detection resistor makes it possible to detect a degree of sulfurization accurately and easily, and a manufacturing method for such sulfurization detection resistor. A sulfurization detection resistor includes an insulated substrate having a rectangular parallelepiped shape, a first front electrode and a second front electrode formed at both ends on a main surface of the insulated substrate, multiple sulfurization detecting conductors connected in parallel to the first front electrode, multiple resistive elements connected between the sulfurization detecting conductors and the second front electrode, and a protective film formed to partially cover the sulfurization detecting conductors and entirely cover the resistive elements.Type: GrantFiled: December 24, 2019Date of Patent: March 26, 2024Assignee: KOA CORPORATIONInventors: Junichi Otsuka, Yoji Kobayashi
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Patent number: 11933750Abstract: A ceramic member unit includes at least insertion members and a ceramic member having insertion sections into which the insertion members are inserted respectively. Each of the insertion sections has at least an insertion opening which opens on a deeper side of an introduction opening in the surface of the ceramic member while communicating with the introduction opening and into which the insertion member can be inserted. The insertion section further has taper hole portions becoming narrower toward the insertion opening in a communication region between the introduction opening and the insertion opening. The taper hole portions are connected to the insertion opening while increasing in a taper angle toward the insertion opening.Type: GrantFiled: February 8, 2019Date of Patent: March 19, 2024Assignee: NITERRA CO., LTD.Inventors: Masana Okai, Kouji Matsuo, Daisuke Tahira
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Patent number: 11936107Abstract: The dipole-resonator resistive absorber is a metamaterial absorber operating in the microwave regime. A single unit of the dipole-resonator resistive absorber includes a first rectangular conductive ring having a pair of first resistors mounted thereon and in electrical communication therewith, and a plurality of parallel linear arrays of second rectangular conductive rings, where each of the second rectangular conductive rings has a pair of second resistors mounted thereon and in electrical communication therewith. The first rectangular conductive ring is mounted above the plurality of parallel linear arrays of the second rectangular conductive rings, and this structure is backed by an electrically conductive layer. The single unit dipole-resonator resistive absorber may be expanded into an arrayed structure, forming a polarization-independent dipole-resonator resistive absorber.Type: GrantFiled: August 2, 2021Date of Patent: March 19, 2024Assignee: THE HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Ping Sheng, Sichao Qu, Yuxiao Hou
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Patent number: 11913930Abstract: A bismuth oxide material with a hierarchical structure in gas detection used for detecting the content of low-concentration ammonia in an environment. The bismuth oxide material with the hierarchical structure integrally presents a microsphere shape. The diameter of the microsphere is 1-3 ?m. The bismuth oxide material is formed by self-assembling lamellar structure units with the thickness of 10-80 nm. The bismuth oxide material is made into a gas sensor with high sensitivity and selectivity to ammonia gas at room temperature, which is suitable for detecting trace harmful gas in the environment. The gas sensor made of bismuth oxide does not need to be heated when in use, so that the heating step of the conventional gas sensor is omitted, and the gas sensor can be directly placed in a normal-temperature environment for operation. The method is simple, easy to operate, high in efficiency and wide in application prospect.Type: GrantFiled: April 8, 2022Date of Patent: February 27, 2024Assignee: QINGDAO UNIVERSITY, CHINAInventors: Kewei Zhang, Mingxin Zhang, Yanzhi Xia, Bin Hui, Anqin Zhou
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Patent number: 11898881Abstract: In a method for manufacturing a gas sensor, a casing for holding a sensor element and a protective cover are connected to each other so that a distal end portion of the sensor element is covered with the protective cover. A first gas chamber, a sensor element chamber, and a second gas chamber into which gas is introduced from the outside are formed between the protective cover and the casing. In the gas introduction portion including the first gas chamber, the sensor element chamber, and the second gas chamber, there is no joint portion formed by welding.Type: GrantFiled: September 7, 2022Date of Patent: February 13, 2024Assignee: NGK INSULATORS, LTD.Inventor: Toshiaki Kuno
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Patent number: 11898982Abstract: A liquid heater apparatus increases the temperature of an A/F sensor up to a target temperature by a target heating time. The liquid heating apparatus such as a gas water heater uses the A/F sensor for detecting an oxygen density in a heating tube. An MPU of a controller count a time from beginning by using a timer and decides whether a moisture on the A/F sensor is evaporated by using the change of a current for a heater portion of the A/F sensor. When the MPU decides the A/F sensor is dried out, the MPU counts the time from the beginning to such time t? as a drying time and setts a heating completing time by reducing the drying time from the predetermined target time. The MPU so controls the heating portion that the temperature of the sensor portion becomes the target temperature by the heating completing time.Type: GrantFiled: August 31, 2020Date of Patent: February 13, 2024Assignee: DENSO WAVE INCORPORATEDInventor: Katsuhiro Matsunami
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Patent number: 11885764Abstract: A gas sensor according to the present application includes a detecting device that detects a specific gas concentration of a measurement-object gas based on an electromotive force generated between a reference electrode and a measurement electrode; and a reference gas regulating device that flows an oxygen pumping current between the reference electrode and a measurement-object gas side electrode and pumps oxygen from around the measurement-object gas side electrode to around the reference electrode, wherein when the average value of the oxygen pumping current is P and the limiting current value of a reference gas introduction layer when oxygen is pumped from around the reference electrode to around the measurement-object gas side electrode is Q, the ratio Q/P is from 0.8 to 10.Type: GrantFiled: June 22, 2021Date of Patent: January 30, 2024Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Watanabe, Tetsuya Ishikawa
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Patent number: 11867659Abstract: A sensor element (10) including: a measurement chamber (150); a pump cell (110) including a solid electrolyte (111), an inner electrode (113) exposed to the measurement chamber, and an outer electrode (112), the pump cell being configured to adjust an oxygen concentration in the measurement chamber; a diffusion resistance portion (151); and a detection cell (120) configured to measure a concentration of a specific gas in the measurement target gas after the adjustment of the oxygen concentration. The outer electrode is covered by a porous layer (114) and is disposed in a hollow space (10G) surrounded by a gas non-permeable dense layer 115, 118. The hollow space is in communication with an air introduction hole (10h) that is open on a rear side relative to the diffusion resistance portion. The outer electrode is exposed via the porous layer to air introduced through the air introduction hole.Type: GrantFiled: April 20, 2020Date of Patent: January 9, 2024Assignee: NITERRA CO., LTD.Inventors: Hitoshi Furuta, Kentaro Kamada, Akinori Kojima, Satoshi Yamahara, Akihiro Hara
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Patent number: 11815485Abstract: A gas sensor includes: a sensor element; a plurality of element pads formed on a rear end portion of the sensor element; and a plurality of contact members holding the rear end portion of the sensor element and electrically connected respectively to the plurality of element pads. The plurality of contact members include contact members that each have an outer end surface protruding out from a corresponding one of end surfaces of the sensor element.Type: GrantFiled: September 16, 2020Date of Patent: November 14, 2023Assignee: NGK INSULATORS, LTD.Inventors: Shotaro Niizuma, Yusuke Watanabe, Toshihiro Hirakawa, Hayami Aota
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Patent number: 11796502Abstract: According to one embodiment, a gas sensor includes a fixed electrode, and a film structure which covers the fixed electrode, forms a cavity inside the film structure, and includes a sensitive layer formed of an amorphous material containing a metal element, and a cap layer provided on the sensitive layer. The film structure is allowed to be deformed when the sensitive layer absorbs a predetermined gas.Type: GrantFiled: June 14, 2021Date of Patent: October 24, 2023Assignee: Kabushiki Kaisha ToshibaInventor: Yumi Hayashi
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Patent number: 11772135Abstract: An air nozzle includes a main body having a compressed air passageway to allow a compressed air to flow therethrough and a compensation air passageway in communication with the compressed air passageway. An external air is sucked into the compressed air passageway through the compensation air passageway and ejected together with the compressed air when the compressed air flows through the compressed air passageway.Type: GrantFiled: June 2, 2021Date of Patent: October 3, 2023Assignee: Tyco Electronics (Shanghai) Co., Ltd.Inventors: Jialin Zhang, Jinlong Li, Dan Li, Zhongxi Huang, Jiankun Zhou, Daiqiong Zhang
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Patent number: 11754528Abstract: A gas detection device according to an embodiment of the present invention includes a casing and a plurality of sensor elements. The casing includes a gas introducing port, a first chamber that communicates with the introducing port, a second chamber that communicates with the first chamber, a flow limiter that limits a flow of gas from the first chamber to the second chamber, and a gas exhausting portion that communicates with the second chamber. The plurality of sensor elements are disposed within the second chamber and have different detection sensitivities depending on a gas type.Type: GrantFiled: August 22, 2022Date of Patent: September 12, 2023Assignee: TAIYO YUDEN CO., LTD.Inventor: Yasuhito Hagiwara
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Patent number: 11736037Abstract: A microelectromechanical system (MEMS) device includes a substrate and a movable element at least partially suspended above the substrate and having at least one degree of freedom. The MEMS device further includes a protrusion extending from the substrate and configured to contact the movable element when the movable element moves in the at least one degree of freedom, wherein the protrusion comprises a surface having a water contact angle of higher than about 15° measured in air.Type: GrantFiled: October 30, 2019Date of Patent: August 22, 2023Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Yi Heng Tsai, Chia-Hua Chu, Kuei-Sung Chang
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Patent number: 11680926Abstract: A gas sensor includes a sensor element including an element body, a first electrode, a second electrode, and a heater; a voltage acquisition section that acquires a voltage between the first electrode and the second electrode; a heater power supply; an external common lead that serves as both at least part of an electric circuit used to acquire the voltage by providing electrical continuity between the first electrode and the voltage acquisition section and at least part of an electric circuit used to supply an electric power from the heater power supply to the heater and that is disposed outside the sensor element; and a correction section that derives a value of a voltage drop in the external common lead in accordance with a heater current and that corrects the voltage acquired by the voltage acquisition section in accordance with the derived value of the voltage drop.Type: GrantFiled: February 9, 2021Date of Patent: June 20, 2023Assignee: NGK INSULATORS, LTD.Inventors: Taku Okamoto, Yuichiro Kondo, Osamu Nakasone
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Patent number: 11673375Abstract: A method for producing a heater with a co-sintered multilayer construction for a system for providing an inhalable aerosol, including providing at least one first substrate layer, arranging at least one first insulating layer at least in areas on the first substrate layer, arranging at least one heating element at least in areas on the first insulating layer, arranging at least one second substrate layer and at least one second insulating layer at least in areas on the heating element. The second insulating layer is arranged at least in areas on the second substrate layer, and the second insulating layer is in contact at least in areas with the heating element and/or with the first insulating layer. The method includes pressing the layers and the heating element, and firing the pressed layers in order to co-sinter the layers of the multilayer construction.Type: GrantFiled: May 3, 2018Date of Patent: June 13, 2023Assignee: Heraeus Nexensos GmbHInventors: Stefan Dietmann, Dieter Teusch, Tim Asmus, Karlheinz Wienand
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Gas-based method and device for diagnosing lung cancer using light-regulated electrochemical sensors
Patent number: 11624724Abstract: The present invention provides methods and devices for detecting and distinguishing various types of gas molecules or volatile organic compounds (VOCs), the methods and devices have enhanced sensing ability; namely response magnitude, sensitivity, detection limit and selectivity (i.e., classification capability). In one embodiment, the present invention provides methods and devices for diagnosing a disease in a subject or a health status of a subject through the detection of VOCs indicative of the disease or health status in question from breath of the subject. In one embodiment, the present invention provides methods and devices for detecting the existence of lung cancer or the stage of lung cancer in a subject through the detection of VOCs indicative of the existence of lung cancer from breath of the subject.Type: GrantFiled: August 31, 2018Date of Patent: April 11, 2023Assignee: QI DIAGNOSTICS LIMITEDInventor: Han Jin -
Patent number: 11604161Abstract: A gas sensor includes a sensor element, an elastic insulating member, a plurality of lead wires, a plurality of metal terminals, and a ceramic housing. The plurality of lead wires are inserted in the elastic insulating member. The plurality of metal terminals each have a first end electrically connected to the sensor element, and a second end electrically connected to a corresponding one of the plurality of lead wires. The ceramic housing includes a plurality of insertion portions each including a through hole in which a corresponding one of the plurality of metal terminals is inserted, and at least one of the plurality of insertion portions has a different height from other insertion portions.Type: GrantFiled: November 10, 2020Date of Patent: March 14, 2023Assignee: NGK INSULATORS, LTD.Inventors: Shotaro Niizuma, Yusuke Watanabe, Toshihiro Hirakawa, Hayami Aota
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Patent number: 11567032Abstract: The heater 72 of the heater portion includes the linear portions 78 and the bend portions 77. A resistance value per unit length of the bend portions 77 at least at a temperature within a temperature range of no less than 700° C. and no more than 900° C. is lower than a resistance value per unit length of the linear portions 78.Type: GrantFiled: May 20, 2020Date of Patent: January 31, 2023Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Watanabe, Takao Murase, Masashi Yasui, Rui Sakaguchi
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Patent number: 11567034Abstract: A first gas sensor having a first sensor element includes a first protective cover that protects the first sensor element, and a second gas sensor having a second sensor element includes a second protective cover that protects the second sensor element. The first protective cover is coated with an oxidation catalyst for one target component from among a plurality of target components, and the second protective cover is coated with an inert catalyst for the one target component.Type: GrantFiled: March 18, 2021Date of Patent: January 31, 2023Assignee: NGK INSULATORS, LTD.Inventors: Daichi Ichikawa, Yuichiro Kondo, Nobuhiko Mori
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Patent number: 11542848Abstract: The present invention is applied to an exhaust system provided with a three-way catalyst and a NOx catalyst which are provided in an exhaust passage of an engine and to which sulfur components in exhaust adhere and release the attached sulfur components by rich components in exhaust, and NOx sensors provided downstream of the catalysts. The NOx sensor is a limiting current type sensor. It is determined whether a sulfur release state is present in which a sulfur component is released from the three-way catalyst and the NOx catalyst. When it is determined that it is in the state of sulfur release, reaction suppression processing for suppressing the reaction between oxygen and sulfur components in the pump cell electrodes and the monitor cell electrodes of the NOx sensors is performed.Type: GrantFiled: July 7, 2021Date of Patent: January 3, 2023Assignee: DENSO CORPORATIONInventor: Marie Horikawa
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Patent number: 11531014Abstract: A controller of the gas sensor can perform diagnostic processing of diagnosing a situation of control to the gas sensor in a case that the gas sensor in an operation state is determined to satisfy a predetermined diagnostic condition and adjustment processing of adjusting a condition for controlling the gas sensor in accordance with a result of diagnosis. In the diagnostic processing, a main pump voltage and a diagnostic threshold as a value of a voltage not causing decomposition of NOx in the main pump cell are compared. In the adjustment processing, temperature adjustment processing to cause, in a case that the main pump voltage is diagnosed to be equal to the threshold or more, the main pump voltage to be less than the threshold, at least in a way that the heater part increases the element driving temperature in the operation state by a predetermined increase amount is performed.Type: GrantFiled: August 20, 2020Date of Patent: December 20, 2022Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Watanabe, Takayuki Sekiya, Daichi Ichikawa
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Patent number: 11505481Abstract: The invented bio-electrical system is a housing-electrode which allows insertion of another electrode for various electrochemical and bio-electrical applications. Together with other invented elements as well as standard components, the system is fully scalable, modular, and allows production and collection of gases under pressure. It can be built in many shapes, such as the embodied tubular shape. The design allows operation on unstable ground, for example on ships. Flow of electrolyte can be regulated and directed in cascaded reactions by opening and closing the compartments of the outer or the inner electrodes using the provided electrode holders. The redox conditions inside the system can be controlled using off-the-shelf power supplies which are controlled using the provided algorithm. Gas collection can be regulated based on the level of liquid inside the system using the provided float switches or conductivity probes even as the system is moving or operated under zero-gravity conditions.Type: GrantFiled: April 18, 2018Date of Patent: November 22, 2022Inventor: Michael Siegert
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Patent number: 11486852Abstract: A sensor element is used to detect the concentration of a predetermined component in a gas. The sensor element includes a sensor element body including a solid-state-electrolyte layer having oxygen-ion conductivity, an outer pump electrode that is disposed on an upper surface, which is one of the surfaces, of the sensor element body, and a porous protective layer that is provided so as to cover at least the outer pump electrode. A spatial layer is provided between the porous protective layer and the sensor element body. The spatial layer includes a first spatial layer between the porous protective layer and the outer pump electrode. The maximum-height roughness Rz of a region of the inner surface of the porous protective layer, the region facing the outer pump electrode, is 50 ?m or smaller.Type: GrantFiled: February 20, 2020Date of Patent: November 1, 2022Assignee: NGK INSULATORS, LTD.Inventors: Ryo Onishi, Yusuke Watanabe
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Patent number: 11486853Abstract: A gas sensor includes a sensor element, an inner protective cover including a first member and a second member, and an outer protective cover having outer inlets. The inner protective cover has a sensor element chamber inside. The outer protective cover and the inner protective cover form an inlet-side gas flow channel from an outside to the sensor element chamber. The inlet-side gas flow channel has a first flow channel extending in an upward direction from the outer inlets and a second flow channel extending in a downward direction. A ratio W2/W1 between a flow channel width W1 of the first flow channel and a flow channel width W2 of the second flow channel is less than one. A tip end portion of the outer protective cover has a tapered portion that reduces in diameter toward a bottom portion of the tip end portion.Type: GrantFiled: September 30, 2020Date of Patent: November 1, 2022Assignee: NGK INSULATORS, LTD.Inventors: Fumiya Takahashi, Takeshi Omori
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Patent number: 11448574Abstract: A sensor device is equipped with a housing having an element cover retaining a sensor element such that a detection section of the sensor element is positioned at the tip end of the sensor element. The element cover includes an inner cover provided with inner side holes and an inner tip face hole respectively provided therein, and an outer cover provided with outer side holes in a side thereof, with the tip position of the outer side holes located closer to the tip end than is the tip position of the inner cover. Between the outer surface of the inner cover and the inner surface of the outer cover there is a large clearance section at the tip end and a small clearance section at the base end, providing a flow path that is shaped for connecting the large clearance section and the small clearance section without a step.Type: GrantFiled: May 28, 2020Date of Patent: September 20, 2022Assignee: DENSO CORPORATIONInventors: Yuto Tamei, Hirofumi Noda, Takehito Kimata, Takashi Araki
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Patent number: 11415543Abstract: A sensor assembly is described. The sensor assembly includes a sensor body having an outwardly-extending flange, first and second spacers, and an integral two-part housing with first and second housing parts. The two-part housing includes an annular groove in which the outwardly-extending flange and the first and second spacers are received. Facing annular surfaces of the housing and the first and second spacers are in sliding contact with each other. Facing annular surfaces of the first and second spacers and the flange are in sliding contact with each other. The annular surfaces of the housing apply a compressive load to the flange by means of the first and second spacers to maintain a hermetic seal between the facing annular surfaces. The facing annular surfaces accommodate differential thermal expansion between the component parts of the sensor assembly if the sensor assembly is exposed to an environment with an elevated temperature.Type: GrantFiled: January 23, 2020Date of Patent: August 16, 2022Assignee: Future Technology (Sensors) Ltd.Inventor: Howard Elliott
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Patent number: 11391232Abstract: A particulate matter sensor includes a first sensing electrode and a second sensing electrode spaced away from the first sensing electrode such that an electrode gap is formed between the first sensing electrode and the second sensing electrode upon which particulate matter is collected, thereby changing conductance between the first sensing electrode and the second sensing electrode. An ionic conductive material is in electrical communication with the first sensing electrode and the second sensing electrode.Type: GrantFiled: October 23, 2019Date of Patent: July 19, 2022Assignee: DELPHI TECHNOLOGIES IP LIMITEDInventors: Daniel G. Gauthier, David D. Cabush, Alfredo Ibarra Covarrubias, David A. Goulette
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Patent number: 11385198Abstract: A sensor element includes: three electrode pads provided on the first main surface, and electrically connected to a connection terminal, the three electrode pads including; a pad group including two electrode pads which are arranged in a widthwise direction of the sensor element, and a single pad which is not overlapped with the pad group when viewed in a widthwise direction, the single pad including a main body portion which has a width greater than a clearance between the two electrode pads of the pad group, which is electrically connected to the connection terminal, and a connection portion which is connected to a conductor formed within a through hole extending within the sensor element in a thickness direction, and which is adjacent to a side surface of the main body portion.Type: GrantFiled: May 2, 2019Date of Patent: July 12, 2022Assignee: NGK SPARK PLUG CO., LTD.Inventors: Hitoshi Furuta, Akinori Kojima
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Patent number: 11307159Abstract: A resistor-assembly includes a substrate, a heater, a resistor-element, and conductive-leads. The substrate is formed of a ceramic-material. The heater heats the resistor-assembly. The resistor-element is formed of an ion-conducting material that overlies the substrate. The conductive-leads are formed of a catalytic-metal that are in communication with a gas and in electrical contact with the resistor-element. The resistor-element is characterized by a resistance-value influenced by an oxygen-presence in the gas when the resistor-element is heated by the heater such that a resistor-temperature is greater than a temperature-threshold.Type: GrantFiled: May 18, 2017Date of Patent: April 19, 2022Assignee: DELPHI TECHNOLOGIES IP LIMITEDInventors: Alfredo Ibarra Covarrubias, Kaius K. Polikarpus
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Patent number: 11274591Abstract: Nitrous oxide (NOx) sensors and related methods and systems for use with combustion processes. The NOx sensor uses metal oxide semiconductors. The NOx sensor may have two sensing circuits that share a common electrode. The sensing circuits are differentiated by having different porous catalytic filter coatings protecting the metal oxide semiconductors: one sensing circuit has a porous catalytic filter coating that contains a Noxcat material (rhodium, ruthenium, cobalt, palladium, or nickel), while the porous catalytic filter coating of the other sensing circuit is substantially free of Noxcat material. The two sensing circuits are simultaneously exposed to the exhaust gases at a common macro location. The NOx level may be determined based on a difference in resistance between the two sensing circuits and a temperature of the NOx sensor.Type: GrantFiled: July 16, 2020Date of Patent: March 15, 2022Assignee: Kerdea Technologies, Inc.Inventor: Ken Ervin Fosaaen
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Patent number: 11249045Abstract: A gas sensor, and a method for measuring the concentrations of a plurality of target components in a gas to be measured are disclosed. The gas sensor is provided with: a specific component measurement means which measures the concentration of a specific component in a measurement chamber; a preliminary oxygen concentration control means which controls the oxygen concentration in a preliminary adjustment chamber; a drive control means which controls the driving and stopping of the preliminary oxygen concentration control means; and a target component acquisition means which, on the basis of the difference between sensor outputs from the specific component measurement means when the preliminary oxygen concentration control means is being driven and when the preliminary oxygen concentration control means is stopped, and one of the respective sensor outputs, acquires the concentrations of a first target component and a second target component.Type: GrantFiled: December 20, 2018Date of Patent: February 15, 2022Assignee: NGK INSULATORS, LTD.Inventor: Kunihiko Nakagaki
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Patent number: 11209387Abstract: A gas sensor element including a solid electrolyte body, a sensor electrode, and a reference electrode is provided. The solid electrolyte body has oxygen ion conductivity and includes a measurement gas surface to be exposed to a measurement gas introduced from the exterior and a reference gas surface to be exposed to a reference gas introduced from the exterior. The sensor electrode is provided on the measurement gas surface of the solid electrolyte body. The reference electrode is provided on the reference gas surface of the solid electrolyte body. The sensor electrode includes a porous body containing a solid electrolyte having oxygen ion conductivity and a precious metal, the peak pore size of the sensor electrode being 0.03 ?m to 0.3 ?m.Type: GrantFiled: December 9, 2016Date of Patent: December 28, 2021Assignee: DENSO CORPORATIONInventors: Yusuke Todo, Mitsunobu Nakato, Hiroki Ichikawa
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Patent number: 11174807Abstract: In a method of performing active control between a lean operation state and a rich operation state on a vehicle engine including a three way catalyst in an exhaust path, on a downstream side with respect to the three way catalyst in the exhaust path, a limited current type NOx sensor having NH3 interference and also capable of detecting a change in an oxygen concentration on the downstream side is disposed, and an operation state of the vehicle engine is switched between a lean operation state and a rich operation state at a timing when a detection of a change in an oxygen concentration in an exhaust air flowing out from the three way catalyst or a detection of NOx or NH3 is performed first by the NOx sensor.Type: GrantFiled: August 6, 2020Date of Patent: November 16, 2021Assignee: NGK INSULATORS, LTD.Inventors: Taku Okamoto, Osamu Nakasone
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Patent number: 11085895Abstract: In a gas sensor element 1 capable of detecting a concentration of a specific gas contained in a measuring target gas, an electrode 12 formed on a solid electrolyte body 11 having an oxygen ion conductivity is made of noble metal and solid electrolyte. The electrode 12 has a noble metal part 121 made of the noble metal, a solid electrolyte part 122 made of the solid electrolyte, and a mixture part 123 made of the noble metal and the solid electrolyte when a cross-sectional surface of the electrode 12 is observed. The mixture part 123 is formed along an interface part 120 between the noble metal part 121 and the solid electrolyte part 122.Type: GrantFiled: November 18, 2013Date of Patent: August 10, 2021Assignee: DENSO CORPORATIONInventors: Norikazu Kajiyama, Tadashi Nakamura
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Patent number: 10996192Abstract: A gas sensor is equipped with a sensor element which detects a specific gas concentration within a gas that is being measured, a housing having the sensor element disposed in the interior thereof and retained therein, and an element cover disposed at an axial-direction tip end of the housing. The tip of the sensor element is provided with a gas introduction part. The element cover has an inner cover and an outer cover, with a space opened between the inner cover and outer cover. Inner side flow holes provided in the inner cover are disposed closer to an axial-direction base end than is a tapered-diameter step part. The distance between the tip of the sensor element and the inner-side flow holes of the inner cover, with respect to an axial direction, is less than or equal to 1.6 mm.Type: GrantFiled: September 9, 2016Date of Patent: May 4, 2021Assignee: DENSO CORPORATIONInventors: Takashi Araki, Takehito Kimata, Mitsunobu Nakatou
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Patent number: 10876991Abstract: Disclosed is a stacked-type plate-shaped sensor element for detecting the concentration of a specific gas component in a gas under measurement. The sensor element includes: a first ceramic layer; a pair of measurement and reference electrodes stacked on a front end part of the first ceramic layer; a through hole formed through at least the first ceramic layer in a rear end side of the sensor element; a through hole conductor disposed on an inner wall of the through hole; a porous reference lead extending between the reference electrode and the through hole conductor; a gas-impermeable second ceramic layer arranged on the first ceramic layer to cover at least the reference lead; and a ventilation portion provided, in the form of a hollow space or a porous substance, between the first and second ceramic layers at a position facing the through hole and communicating with the reference lead.Type: GrantFiled: February 8, 2019Date of Patent: December 29, 2020Assignee: NGK SPARK PLUG CO., LTD.Inventors: Yasumitsu Shimizu, Takayuki Kito
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Patent number: 10801389Abstract: A particulate matter sensor is provided. The particulate matter sensor includes: an insulating substrate; a first electrode unit, and a plurality of spaced electrodes; a second electrode unit and a heater unit. Wherein each of the spaced electrode includes a sensing unit, wherein the particulate matter is deposited on the sensing unit, and a capacitor unit is configured on the spaced electrode for measuring capacitance. The plurality of spaced electrodes and the rim electrode are electrically connected when particulate matter is deposited, and thereby the capacitance between the first electrode unit and the second electrode unit can be measured.Type: GrantFiled: June 8, 2016Date of Patent: October 13, 2020Assignee: AMOTECH CO., LTD.Inventors: Yeon-Soo Chung, Soo-Min Oh, Eun-Ji Kim, Sung-Jin Hong
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Patent number: 10760466Abstract: Nitrous oxide (NOx) sensors and related methods and systems for use with combustion processes. The NOx sensor uses metal oxide semiconductors. The NOx sensor may have two sensing circuits that share a common electrode. The sensing circuits are differentiated by having different porous catalytic filter coatings protecting the metal oxide semiconductors: one sensing circuit has a porous catalytic filter coating that contains a Noxcat material (rhodium, ruthenium, cobalt, palladium, or nickel), while the porous catalytic filter coating of the other sensing circuit is substantially free of Noxcat material. The two sensing circuits are simultaneously exposed to the exhaust gases at a common macro location. The NOx level may be determined based on a difference in resistance between the two sensing circuits and a temperature of the NOx sensor.Type: GrantFiled: March 8, 2017Date of Patent: September 1, 2020Assignee: Kerdea Technologies, Inc.Inventor: Ken Ervin Fosaaen
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Patent number: 10753844Abstract: A particulate matter sensor is provided that can include: an insulating substrate; a plurality of sensing electrodes which are disposed on one surface of the insulating substrate and spaced a predetermined interval from each other so as not to be electrically connected to each other; a connection electrode disposed to be coplanar with the plurality of sensing electrodes and connected to a connection terminal formed on the one surface of the insulating substrate to be connected to some or all of the plurality of sensing electrodes through deposited particulate matter; a plurality of terminals formed on the one surface of the insulating substrate and connected one-to-one with the plurality of sensing electrodes and the connection electrode; and a heater unit disposed inside the insulating substrate and configured to provide heat for removing the particulate matter deposited on the sensing electrodes.Type: GrantFiled: March 30, 2017Date of Patent: August 25, 2020Assignee: AMOTECH CO., LTD.Inventors: Soo Min Oh, Yeon Soo Chung, Sung Jin Hong, Eun Ji Kim
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Patent number: 10739300Abstract: A heater part of a planar sensor element includes: a Pt heater element; and an insulating layer including 90-99.9 wt % of an insulating material having a different coefficient of thermal expansion from a solid electrolyte forming a base part of the element. The heater part other than a heater electrode is buried in the base part. The heater element has a thickness of 10-50 ?m and is covered with the insulating layer. The insulating layer has a porosity of 4% or less and a thickness of 50-150 ?m. The distances of the insulating layer from an end portion of the element, from a main surface on which the heater electrode is located, and from a side surface of the element are respectively 0.25-0.75 mm, 0.20-0.60 mm, and 0.20-0.60 mm. The total length of the element is 80.0 mm or less.Type: GrantFiled: March 8, 2018Date of Patent: August 11, 2020Assignee: NGK Insulators, Ltd.Inventors: Kosuke Ujihara, Toru Hayase, Kenji Morimoto
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Patent number: 10693185Abstract: An object of the present disclosure is to provide a solid electrolyte material with excellent fluoride ion conductivity. The present disclosure achieves the object by providing a solid electrolyte material to be used for a fluoride ion battery, the solid electrolyte material comprising: a composition of BixM1?xF2+x, in which 0.4?x?0.9, and M is at least one kind of Sn, Ca, Sr, Ba, and Pb; and a crystal phase that has a Tysonite structure.Type: GrantFiled: October 27, 2017Date of Patent: June 23, 2020Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Kazuto Ide
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Patent number: 10473049Abstract: This control device for an internal combustion engine is equipped with: an air/fuel ratio sensor; and an engine control device that controls the internal combustion engine according to the output of the air/fuel ratio sensor. The air/fuel ratio sensor is configured so that the applied voltage at which the output current reaches zero varies according to the exhaust air/fuel ratio, and the output current increases if the applied voltage is increased at the air/fuel ratio sensor when the exhaust air/fuel ratio is the stoichiometric air/fuel ratio.Type: GrantFiled: January 29, 2013Date of Patent: November 12, 2019Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Go Hayashita, Keiichiro Aoki
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Patent number: 10473573Abstract: A particulate matter sensor and an exhaust gas purification system using the same are provided. A particular matter sensor according to some embodiments of the present invention includes a first insulation layer including a first electrode unit exposed on a first side thereof, which includes a plurality of first electrodes not electrically connected to each other, a second insulation layer arranged in parallel to the first insulation layer with a space therebetween, including a second electrode unit on a first side thereof, which includes a plurality of second electrodes electrically connected to each other, a temperature sensing unit formed on a first side of a third insulation layer located on a second side of the second insulation layer, and a heater unit formed on a first side of a fourth insulation layer located on a second side of the third insulation layer, the heater unit configured to heat the first and second electrode units.Type: GrantFiled: April 27, 2016Date of Patent: November 12, 2019Assignee: AMOTECH CO., LTD.Inventors: Yeon-Soo Chung, Soo-Min Oh, Eun-Ji Kim, Sung-Eun Jo, Yang-Joo Ko, Jung-Taek Kim, Heon-Joon Park, Tae-Kwan Yi
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Patent number: 10429339Abstract: A gas sensor includes a solid electrolyte body provided with a measured gas side electrode and a reference gas side electrode, a heater in the solid electrolyte body, a housing for holding the solid electrolyte body therein, and a cover for covering the solid electrolyte body. The cover has a large-diameter cover portion positioned on an outer circumferential side of the solid electrolyte body, a small-diameter cover portion positioned adjacent to a tip side of the large-diameter cover portion and formed smaller than the large-diameter cover portion, and a stepped portion connecting the small-diameter cover portion and the large-diameter cover portion. A first through hole is formed at a tip of the small-diameter cover portion. A second through hole is formed at a plurality of positions in a circumferential direction of the stepped portion.Type: GrantFiled: July 9, 2015Date of Patent: October 1, 2019Assignee: DENSO CORPORATIONInventors: Kengo Toguchi, Masatake Nakamura