With Gas Reference Material Patents (Class 204/427)
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Patent number: 11867658Abstract: The present invention relates to an oxygen probe for a furnace. The oxygen probe includes an elongate outer conductor and an inner conductor within the outer conductor. An oxygen sensor is in electrical connection with the outer conductor and the inner conductor. The oxygen probe further includes a seal arrangement for receiving the inner conductor and maintaining a seal to a reference chamber during movement of the conductors owing to heat from the furnace.Type: GrantFiled: August 9, 2019Date of Patent: January 9, 2024Assignee: Ceramic Oxide Fabricators Pty LtdInventor: Peter Crowhurst
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Patent number: 11774398Abstract: A sensor element for detecting a specific gas concentration in a measurement-object gas includes: an element body including an oxygen-ion-conductive solid electrolyte layer, and having inside a measurement-object gas flow portion that introduces and flows a measurement-object gas and a reference gas chamber used to store a reference gas that is a reference for detecting a specific gas concentration; a reference electrode disposed in the reference gas chamber; and an electrically conductive portion which includes a reference electrode terminal and a reference electrode lead portion that provides electrical continuity between the reference electrode terminal and the reference electrode. The reference gas chamber is provided inside the sensor element in an isolated form, and at least part of the electrically conductive portion is densely formed so as to block movement of oxygen between the reference gas chamber and the outside of the sensor element via the electrically conductive portion.Type: GrantFiled: March 4, 2021Date of Patent: October 3, 2023Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Watanabe, Takayuki Sekiya
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Patent number: 11768168Abstract: A sensor (1) comprising: a sensor element (10); metal terminals; and a front side separator (90) and a rear side separator (95) to hold the metal terminals, the metal terminals each include a front side metal terminal (30) and a rear side metal terminal (40) respectively held by the front side separator and the rear side separator, a first connection portion (33) is provided on a rear side of the front side metal terminal, a second connection portion (43) is provided on a front side of the rear side metal terminal, and an axis P2 of one of the first and the second connection portion, in all of the plurality of metal terminals, is displaced toward a radially outer side of the sensor element relative to an axis P1 of a counterpart thereof, and the first connection portion and the second connection portion are in contact with each other.Type: GrantFiled: August 6, 2020Date of Patent: September 26, 2023Assignee: NGK SPARK PLUG CO., LTD.Inventors: Sunchao Liu, Takehiro Oba
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Patent number: 11609217Abstract: A method for sensing gas by a gas sensing device, the method may include generating, by a semiconductor temperature sensing element that is spaced apart from a gas reactive element and is thermally coupled to the gas reactive element, detection signals that are indicative of a temperature of the gas reactive element; wherein the gas reactive element and the semiconductor temperature sensing element are of microscopic scale; and processing, by a readout circuit of the gas sensing device, the detection signals to provide information about a gas that affected the temperature of the gas reactive element.Type: GrantFiled: September 4, 2020Date of Patent: March 21, 2023Assignees: Todos Technologies Ltd., TECHNION RESEARCH AND DEVELOPMENT FOUNDATION LTD.Inventors: Yael Nemirovsky, Amikam Nemirovsky, Shmuel Melman
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Patent number: 11442036Abstract: A sensor element includes an element main body in which a flow portion of a measurement-object gas is disposed, a measurement electrode disposed in the flow portion of a measurement-object gas, a measurement electrode lead having a first portion that is connected to the measurement electrode and that is disposed in the flow portion of a measurement-object gas and a second portion that is connected to the first portion and that is embedded in the element main body, a hermetic layer that is part of the element main body and that surrounds an end region of the second portion including the border with the first portion; and a lead insulating layer that is part of the element main body and that surrounds at least part of the second portion excluding the end region.Type: GrantFiled: January 9, 2019Date of Patent: September 13, 2022Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Fujii, Sang Jae Lee
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Patent number: 11255812Abstract: Disclosed is a gas sensor element having an electrode containing a first metal as a predominant component and a lead containing a second metal as a predominant component. The electrode and the lead are connected directly at a connection boundary thereof, or connected indirectly via a connection joint. The connection boundary or joint includes a component region where either one of the first and second metals lower in specific gravity than the other of the first and second metals is contained in an amount ranging between those in the electrode and the lead.Type: GrantFiled: March 26, 2019Date of Patent: February 22, 2022Assignee: NGK SPARK PLUG CO., LTD.Inventors: Hitoshi Furuta, Tetsuo Yamada, Yoshihiro Nakano
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Patent number: 11125715Abstract: A sensor element of a gas sensor includes a solid electrolyte body which has oxygen-ion conductivity, a measuring electrode that is exposed to a measured gas, a reference gas electrode that is exposed to a reference gas, and a porous protection layer. The measuring electrode is mounted on an outer surface of the solid electrolyte body. The reference electrode is mounted on an inner surface of the solid electrolyte body. The protection layer covers a surface of the measuring electrode. A plurality of open portions are formed to penetrate through the measuring electrode. A part of the protection layer is joined to the solid electrolyte body, via the plurality of open portions.Type: GrantFiled: May 15, 2017Date of Patent: September 21, 2021Assignee: DENSO CORPORATIONInventors: Akira Saito, Kiyomi Kobayashi
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Patent number: 10969372Abstract: A gas sensor includes a sensing element, a metal shell that is tubular and that surrounds the sensing element, and a protector made of a metal and fixed to the metal shell. A back end portion of the protector is joined to an outer surface of the metal shell to form a joined portion. A coefficient of thermal expansion of a material of the protector at 800 degrees Celsius is higher than a coefficient of thermal expansion of a material of the metal shell at 800 degrees Celsius. In a cross section of a portion of the gas sensor including the joined portion, a minimum distance t1 between the outer surface of the metal shell and an outer surface of the protector and a minimum distance t2 between the outer surface of the metal shell and an inner surface of the metal shell satisfy 0.6?(t1/t2)?2.0.Type: GrantFiled: December 10, 2018Date of Patent: April 6, 2021Assignee: NGK SPARK PLUG CO., LTD.Inventors: Yuji Shimazaki, Hironari Furuta, Kentaro Mori
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Patent number: 10943776Abstract: A mass spectrometer is disclosed comprising an ion mobility separator 4 for separating ions according to their ion mobility, one or more first devices or stages arranged upstream of the ion mobility separator and a control system. The control system is arranged and adapted to monitor directly or indirectly the operating environment within the ion mobility separator 4, and to control the operating environment within the ion mobility separator 4 based on the monitoring by controlling one or more gas flows to or within one or more of the one or more first devices or stages.Type: GrantFiled: August 16, 2019Date of Patent: March 9, 2021Assignee: MICROMASS UK LIMITEDInventors: Steven Derek Pringle, Farnoush Salarzaei, Nicholas Tomczyk, Jason Lee Wildgoose
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Patent number: 10921283Abstract: A gas sensor includes a solid electrolyte, a gas chamber, a reference gas chamber, a pump cell, a monitor cell, and a sensor cell. The gas chamber has a spatial width W0 constant in a width direction W orthogonal to the direction of flow of a gas in a position where the pump electrode, the monitor electrode, and the sensor electrode are provided on the solid electrolyte. An amount of shift ?X1 of a central position O2 of a gap S in the width direction W between the monitor electrode and the sensor electrode from a central position O1 in the width direction of the pump electrode has relationship of ?X1?¼ W1 where the pump electrode has a width W1. In addition, positions ?Y1 of a of a side surface of the monitor electrode and of a side surface of the sensor electrode from the central position O1 in the width direction W of the pump electrode have relationship of ?Y1?½ W1.Type: GrantFiled: December 16, 2014Date of Patent: February 16, 2021Assignee: DENSO CORPORATIONInventors: Mitsunobu Nakatou, Keigo Mizutani, Takashi Araki, Yuusuke Toudou
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Patent number: 10801988Abstract: A gas sensor includes a sensor element having a detection section at a distal end portion thereof, and an element cover that surrounds a periphery of the sensor element. The sensor element includes electrodes and formed on a surface of a solid electrolyte body, a heater, and a porous protective layer formed on an outside of the detection section. The element cover includes a cover member with gas flow holes on a side surface and a gas passage is formed between the cover member and the sensor element. A distance between the cover member and the side surface of the sensor element in a direction perpendicular to an axis of the sensor element is in a range of 0.2 mm to 0.8 mm in the entire region of the gas passage leading from the gas flow holes to the detecting section.Type: GrantFiled: November 16, 2016Date of Patent: October 13, 2020Assignee: DENSO CORPORATIONInventors: Yota Iwamoto, Yasufumi Suzuki
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Patent number: 10774707Abstract: A non-transitory computer-readable medium having a NOx sensor purification instructions for a NOx sensor causes: an on-vehicle electronic computer mounted in the vehicle, when it comes to a predetermined purification time, to execute a start procedure to send a start command to perform a purification control to the control unit; and control unit, in response to the start command, to execute a purification procedure to perform the purification control which causes the current flowing in the reference pump cell from the reference pump current to be a purification pump current, which is set to a current value larger than the reference pump current.Type: GrantFiled: November 6, 2015Date of Patent: September 15, 2020Assignee: ISUZU MOTORS LIMITEDInventor: Kouji Sakumoto
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Patent number: 10705045Abstract: A gas sensor element including a lead portion (79a) formed on a lower surface of an insulating member (76) and extending through a through hole (176) to an upper surface thereof, and a lead portion (79b) extending from the upper surface of the insulating member (76) through the through hole (176) to the lower surface of the insulating member (76) so as to cover the lead portion (79a) along the inner circumferential wall and a portion of the lower surface around the through hole. The lead portion (79a) has a section exposed to a space (230) on the lower surface side of the insulating member (76). The lead portion (79b) is disposed so as to face the insulating member (76) with the space (230) therebetween. The lead portion (79a) communicates with the outside through the space (230). Also disclosed is a method for producing the gas sensor element.Type: GrantFiled: August 1, 2017Date of Patent: July 7, 2020Assignee: NGK SPARK PLUG CO., LTD.Inventors: Akinori Kojima, Hitoshi Furuta
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Patent number: 10388505Abstract: A mass spectrometer is disclosed comprising an ion mobility separator for separating ions according to their ion mobility, one or more first devices or stages arranged upstream of the ion mobility separator and a control system. The control system is arranged and adapted to monitor directly or indirectly the operating environment within the ion mobility separator, and to control the operating environment within the ion mobility separator based on the monitoring by controlling one or more gas flows to or within one or more of the one or more first devices or stages.Type: GrantFiled: June 10, 2015Date of Patent: August 20, 2019Assignee: Micromass UK LimitedInventors: Steven Derek Pringle, Farnoush Salarzaei, Nicholas Tomczyk, Jason Lee Wildgoose
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Patent number: 10145816Abstract: A gas sensor element (10) includes a composite ceramic layer (111) having an insulation portion (112) and an electrolyte portion (131) disposed within a through hole (112h), and a first conductor layer (150) extending in a continuous manner on a first insulation main surface (113) as well as on a first electrolyte main surface (133). The electrolyte portion (131) is thinner than the insulation portion (112), and the first electrolyte main surface (133) is located on a thickness-direction inward side DTN. The insulation portion (112) has, on a first insulation main surface side, a protruding portion (122) overlying the first electrolyte main surface (133). The thickness of the protruding portion (122) reduces toward the inward side DR1 of the through hole (112h). The first conductor layer (150) extends in a continuous manner on a protrusion surface (122s) as well as on the first electrolyte main surface (133).Type: GrantFiled: September 24, 2015Date of Patent: December 4, 2018Assignee: NGK SPARK PLUG CO., LTD.Inventors: Takashi Konno, Satoshi Okazaki, Masaki Nakagawa, Haruhiko Shigeta
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Patent number: 10106767Abstract: A transfer device includes at least one pump unit provided for a defined gas transfer between a first, closed-off space of an installation, in particular a photobioreactor installation, and a second space which is separate from the first space. The at least one pump unit is embodied as a selective oxygen pump.Type: GrantFiled: March 8, 2017Date of Patent: October 23, 2018Assignee: Airbus DS GmbHInventors: Heinz Hartstein, Peter Kern
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Patent number: 10090146Abstract: A mass spectrometer is disclosed comprising an ion mobility separation device for separating ions according to their ion mobility, a first quadrupole mass filter downstream of the ion mobility separation device, a control system arranged and adapted to scan and/or step the set mass of the first quadrupole mass filter a plurality of times over a first mass to charge ratio range of <±2 amu during the elution time of an ion mobility peak from the ion mobility separation device, and an analyzer or ion detector downstream of the first quadrupole mass filter arranged and adapted to analyze or detect ions so as to acquire multi-dimensional ion mobility-mass to charge ratio data.Type: GrantFiled: June 10, 2015Date of Patent: October 2, 2018Assignee: MICROMASS UK LIMITEDInventors: Martin Raymond Green, Keith Richardson, Jason Lee Wildgoose
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Patent number: 10088446Abstract: A gas sensor device is equipped with a pump cell and a sensor cell. The pump cell works to regulate the concentration of oxygen in a measurement gas space. The sensor cell works to measure an oxygen ion current flowing between a sensor electrode and a reference electrode. The gas sensor device is designed to subtract the oxygen ion current value I2, as measured by the sensor cell a given period of time after spraying of fuel into the internal combustion engine is interrupted, from the oxygen ion current value I1, as measured by the sensor cell when the fuel is being sprayed into the internal combustion engine, to derive the concentration of a given gas component based on the corrected oxygen ion current value I. This results in improved accuracy in determining the concentration of the given gas component.Type: GrantFiled: June 4, 2015Date of Patent: October 2, 2018Assignee: DENSO CORPORATIONInventors: Takashi Araki, Keigo Mizutani
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Patent number: 10078033Abstract: The present description relates generally to methods and systems for detecting thermal aging and blackening in oxygen sensors. Thermal aging and blackening effects may be differentiated based on a monitored change in impedance in each of a pump cell and a Nernst cell of the oxygen sensor following application of an alternating voltage. In response to detection of thermal aging and/or blackening in the oxygen sensor corrective measures may be taken to ensure accurate oxygen estimation using the sensor.Type: GrantFiled: January 20, 2016Date of Patent: September 18, 2018Assignee: Ford Global Technologies, LLCInventors: Michael McQuillen, Gopichandra Surnilla, Richard E. Soltis, Daniel A. Makled, John Joseph Virga
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Patent number: 9989506Abstract: Provided is a gas sensor in which a protective cover has no looseness even by repetitive use. The gas sensor includes a sensor element for detecting a predetermined measurement target gas component in a measurement gas; a protective cover which protects a side of one end portion of the sensor element; and a housing which houses the sensor element. The protective cover includes a brim portion at one end portion of an outer surface of the protective cover. The brim portion is brought into contact with a contact surface provided in said housing, and is held between a swaging portion and the contact surface, the swaging portion extending from the contact surface while bending, so that the protective cover is fixed to the housing. The brim portion is tilted at a tilt angle of 5° or more and 15° or less relative to a plane vertical to a central axis of the gas sensor.Type: GrantFiled: August 19, 2016Date of Patent: June 5, 2018Assignee: NGK INSULATORS, LTD.Inventors: Yusuke Watanabe, Takao Murase, Masashi Yasui
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Patent number: 9823220Abstract: An apparatus and method for individually detecting NO and NO2 concentrations as NOX components of an object gas. An NO concentration corresponding value is obtained from a first detection element not having a reduction section. An NO concentration corresponding value is obtained from a second detection element having a reduction section, and having an NO2/NO sensitivity ratio greater than that of the first detection element. The difference ?C between the NO concentration corresponding values of the two detection elements is obtained, and divided by the difference ?S between the NO2/NO sensitivity ratios of the two detection elements, whereby an NO2 concentration corresponding value is obtained. A value obtained by multiplying the NO2 concentration corresponding value by the NO2/NO sensitivity ratio of the second detection element is subtracted from the NO concentration corresponding value of the second detection element, whereby an NO concentration corresponding value is obtained.Type: GrantFiled: February 16, 2012Date of Patent: November 21, 2017Assignee: NGK SPARK PLUG CO., LTD.Inventors: Kenji Kato, Kouji Shiotani, Takeshi Kawai, Satoshi Teramoto
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Patent number: 9466498Abstract: A CMOS gas sensor comprises a membrane (13) extending over an opening (12) of a silicon substrate (1). A patch (2) of sensing material is arranged on the membrane (13) and in contact with electrodes (3) of platinum. A heater (5) of tungsten is located in or on the membrane (13) at the location of the patch (2) of metal-oxide sensing material. Combining platinum electrodes (3) with a tungsten heater (5) on top of a CMOS structure provides a gas sensor of high reliability and stability.Type: GrantFiled: January 22, 2014Date of Patent: October 11, 2016Assignee: Sensirion AGInventors: Johannes Buhler, Cyrill Kuemin
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Patent number: 9028671Abstract: An apparatus and methods are provided for the accurate determination of hydrogen content in fluid media at elevated temperatures. The apparatus consists of a proton conducting solid electrolyte in contact with an internal metal/hydrogen reference standard, in which the electrolyte and the reference material are in a chemically stable contact. The electrical signal generated is a function of the hydrogen concentration on the measuring side.Type: GrantFiled: July 20, 2011Date of Patent: May 12, 2015Assignee: Cambridge Enterprise LimitedInventors: Derek John Fray, Carsten Schwandt
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Publication number: 20150041319Abstract: An O2 sensor has a sensor element, which includes a solid electrolyte layer and a pair of electrodes. The solid electrolyte layer is held between the electrodes, which includes an atmosphere side electrode and an exhaust side electrode. A constant current circuit is installed in an electric path, which connects between the atmosphere side electrode and a ground, to induce a flow of a predetermined constant electric current between the electrodes through the solid electrolyte layer. When the sensor element generates an electromotive force, the constant current circuit conducts an electric current, which is generated while using the electromotive force of the sensor element as an electric power source, to induce the flow of the predetermined constant electric current between the electrodes in an electromotive force range, which is equal to or larger than an electromotive force of the sensor element generated at a stoichiometric air-to-fuel ratio.Type: ApplicationFiled: August 8, 2014Publication date: February 12, 2015Inventors: Yuji YAMADA, Mikiyasu MATSUOKA, Kenichi ONO, Takamasa OGURI, Takao MISHIMA
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Publication number: 20150041320Abstract: An O2 sensor has a sensor element, which includes a solid electrolyte layer and a pair of electrodes. The solid electrolyte layer is held between the electrodes, which includes an atmosphere side electrode and an exhaust side electrode. A constant current circuit is installed in an electric path, which connects between the atmosphere side electrode and a ground, to induce a flow of a predetermined constant electric current between the electrodes through the solid electrolyte layer. A voltage circuit is installed in an electric path, which connects between the exhaust side electrode and a ground, to increase an electric potential of the exhaust side electrode by a predetermined amount relative to an electric potential at an output side of the constant current circuit, from which the electric current flows out of the constant current circuit.Type: ApplicationFiled: August 8, 2014Publication date: February 12, 2015Inventors: Yuji YAMADA, Mikiyasu MATSUOKA, Takamasa OGURI, Takao MISHIMA
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Publication number: 20150021181Abstract: Provided is a hydrogen measurement sensor capable of monitoring a content of hydrogen within molten metal in real-time using an aluminum or magnesium alloy casting method, and, more particularly, a hydrogen measurement sensor having a junction structure of a solid oxygen ion conductor and a solid hydrogen ion conductor in molten metal capable of measuring a content of hydrogen within aluminum-magnesium alloy-molten metal using a new method which generates a fixed concentration of oxygen gas from a solid reference material at a high temperature by replacing a reference material of a standard gas method which is difficult to handle with a solid reference material or external air which is easy to handle or has the same effect as that of the gas reference material by using a feature in which the external air contains a predetermined pressure (0.21 atm) of oxygen.Type: ApplicationFiled: December 6, 2012Publication date: January 22, 2015Inventors: Chong Ook Park, Byoung Hyo Jung
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Publication number: 20140353156Abstract: An electrochemical gas sensor having an electrode with a catalyst distributed on a porous surface is described. The porous surface can be a polytetrafluoroethylene tape. Alternate embodiments include layered or stacked electrodes.Type: ApplicationFiled: May 12, 2014Publication date: December 4, 2014Applicant: LIFE SAFETY DISTRIBUTION AGInventors: Keith Francis Edwin Pratt, John Chapples, Martin Geoffrey Jones
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Patent number: 8899014Abstract: An emission control system for an engine includes a catalyst and an exhaust-gas sensor provided downstream of the catalyst in a flow direction of exhaust gas. The exhaust-gas sensor includes a sensor element that includes a pair of electrodes and a solid electrolyte body located between the electrodes. The emission control system further includes a constant current supply portion that changes an output characteristic of the exhaust-gas sensor by applying a constant current between the electrodes, a rich direction control portion that performs a rich direction control after a fuelling-stop control, and a characteristic control portion that performs a rich responsiveness control during the rich direction control. In the rich direction control, an air-fuel ratio of the exhaust gas is made to be richer. In the rich responsiveness control, the constant current supply portion increases a detection responsiveness of the exhaust-gas sensor with respect to rich gas.Type: GrantFiled: January 29, 2013Date of Patent: December 2, 2014Assignee: Denso CorporationInventors: Kosuke Nakano, Shingo Nakata, Mikiyasu Matsuoka
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Patent number: 8900432Abstract: A sensor element, which may be used as Lambda probe and/or inside a Lambda probe, for example, is provided for determining at least one physical property of a gas mixture in at least one gas chamber. The sensor element has at least one first electrode, at least one second electrode and at least one solid state electrolyte, which connects the at least one first electrode and the at least one second electrode. The at least one first electrode and the at least one second electrode are situated inside the sensor element. The at least one second electrode is connected to at least one reference gas chamber via at least one discharge air channel.Type: GrantFiled: November 22, 2007Date of Patent: December 2, 2014Assignee: Robert Bosch GmbHInventors: Goetz Reinhardt, Henrico Runge, Holger Reinshagen, Lothar Diehl
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Patent number: 8852415Abstract: A sensor element for determining at least one physical property of a gas in a measuring gas chamber, particularly for determining an oxygen concentration in an exhaust gas. The sensor element includes at least one first electrode and at least one second electrode, and at least one solid electrolyte connecting the first electrode and the second electrode. The second electrode is situated on the inside of the sensor element and is able to have gas from the measuring gas chamber applied to it via at least one gas access hole and at least one diffusion barrier. At least partially gas-impermeable cover layer is provided on the diffusion barrier, at least from area to area. The gas access hole has at least one chamfer in the vicinity of the cover layer.Type: GrantFiled: July 24, 2009Date of Patent: October 7, 2014Assignee: Robert Bosch GmbHInventor: Henrico Runge
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Publication number: 20140262835Abstract: Various embodiments of a gas sensor device and method of fabricating a gas sensor device are provided. In one embodiment a gas sensor device includes a base substrate, an electrolyte layer disposed on the base substrate and a plurality of potentiometric sensor units electrically coupled to the base substrate. Each potentiometric sensor unit includes an electrolyte layer disposed on the base substrate, a sensing electrode comprising tungsten oxide (WO3) and platinum (Pt), a reference electrode comprising Pt, and a plurality of connectors coupled to the plurality of potentiometric sensors to connect the plurality of potentiometric sensors in series.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: THE CLEVELAND CLINIC FOUNDATIONInventors: Gary W. Hunter, Carl W. Chang, Prabir K. Dutta, Suvra P. Mondal, Azlin M. Biaggi-Labiosa
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Publication number: 20140251834Abstract: A membrane electrode assembly for a gas sensor is described that includes a membrane disposed between a sensing electrode and a counter electrode. The membrane is a polymer membrane, such as an ionomer, having an ionic liquid retained therein.Type: ApplicationFiled: October 5, 2011Publication date: September 11, 2014Applicant: UTC FIRE & SECURITY CORPORATIONInventors: Lei Chen, Zhiwei Yang, Jean Yamanis, Georgios S. Zafiris, Joseph J. Sangiovanni
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Patent number: 8828206Abstract: In a gas sensor element, a measurement gas is introduced to a measurement electrode through a porous diffusion-resistant layer. A catalyst layer is formed on an outer surface of the diffusion-resistant layer via which the measurement gas flows into the diffusion-resistant layer. In the catalyst layer, the percentage content of Pt is in the range of 2.5 to 12 mass %, the percentage content of Pd is in the range of 0.4 to 2 mass %, and the percentage content of Rh is in the range of 0.06 to 1.5 mass %. The catalyst layer includes catalytic noble metal particles each of which is made of an alloy that contains at least Pt. For each of the catalytic noble metal particles, the percentage content of Pt at an outer peripheral portion of the catalytic noble metal particle is lower than that at a core portion of the catalytic noble metal particle.Type: GrantFiled: June 1, 2012Date of Patent: September 9, 2014Assignee: Denso CorporationInventor: Hirokatsu Imagawa
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Patent number: 8795491Abstract: A method of processing a sensor element includes the steps of: (a) preparing a gas atmosphere containing hydrocarbon, having an air-fuel ratio of 0.80 to 0.9999, and having a small amount of oxidizing gas added thereto; and (b) subjecting a sensor element to a heat treatment in the gas atmosphere at a temperature of 500° C. or higher for 15 minutes or longer. The sensor element includes an electrochemical pumping cell constituted of an oxygen-ion conductive solid electrolyte and an electrode having a NOx reduction ability. A NOx gas in a measurement gas is reduced or decomposed in the electrode. A NOx concentration in the measurement gas is obtained based on a current which flows in the electrochemical pumping cell at a time of the reduction or decomposition.Type: GrantFiled: March 4, 2011Date of Patent: August 5, 2014Assignees: NGK Insulators, Ltd., NGK Ceramic Device Co., Ltd.Inventors: Tetsuya Ishikawa, Sumiko Horisaka, Yuji Okuda
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Patent number: 8783019Abstract: An exhaust treatment system is disclosed that can diagnose the performance of an exhaust treatment oxidation catalyst in converting NO to NO2. The exhaust treatment system is fluidly coupled to an internal combustion engine, and includes an oxidation catalyst disposed in an engine exhaust stream; a reductant source for injecting a reductant into the exhaust stream downstream of the oxidation catalyst; an SCR catalyst disposed in the exhaust stream downstream of the reductant source; and a gas sensor, disposed in the exhaust stream downstream of the oxidation catalyst and upstream of the reductant source, comprising a plurality of sensing or pumping cells that measures NO concentration in the exhaust gas and NO2 concentration in the exhaust gas.Type: GrantFiled: September 5, 2012Date of Patent: July 22, 2014Assignee: GM Global Technology Operations LLCInventors: Joshua Clifford Bedford, Julian C. Tan, Janean E Kowalkowski
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Publication number: 20140190828Abstract: A first electrode (133) has an exposure portion (133b) exposed to a second measuring chamber (160), and a connection portion (133d) which is disposed at a position not exposed to the second measuring chamber (160) and is connected to the first lead (137) and which is a portion of the first electrode (133) located most distant from the second measuring chamber (160). The entire connection portion (133d) is located in a region A1 which extends from the second measuring chamber (160) over a distance of 1.0 mm or less.Type: ApplicationFiled: January 3, 2014Publication date: July 10, 2014Applicant: NGK SPARK PLUG CO., LTD.Inventors: Kentaro KAMADA, Masaki NAKAGAWA, Koji SHIOTANI
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Patent number: 8771488Abstract: A gas sensor (100) includes an oxygen pump cell (135) and an oxygen-concentration detection cell (150) laminated together with a spacer (145) interposed therebetween. The spacer (145) has a gas detection chamber (145c) which faces electrodes (137, 152) of the cells (135, 150). The oxygen-concentration detection cell (150) produces an output voltage corresponding to the concentration of oxygen in the gas detection chamber (145c). The oxygen pump cell (135) pumps oxygen into and out of the measurement chamber (145c) such that the output voltage of the oxygen-concentration detection cell (150) becomes equal to a predetermined target voltage. A leakage portion mainly formed of zirconia is disposed between which electrically connects the oxygen-concentration detection cell (150) and the oxygen pump cell (135).Type: GrantFiled: August 2, 2012Date of Patent: July 8, 2014Assignee: NGK Spark Plug Co., Ltd.Inventors: Tetsuya Ito, Satoshi Teramoto, Kentaro Mori
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Patent number: 8764955Abstract: A gas sensor (200) includes a gas sensor element (10) extending in the direction of an axis O, and a housing (50) made of metal, radially surrounding the gas sensor element, and adapted for inserting at least partially into a sensor-mounting hole (350) of a mounting body (300). The gas sensor (200) further includes a resin member (60, 61) which radially surrounds the housing at least partially and having a contact portion (C) in contact with the housing that is at least partially disposed axially frontward with respect to the outer surface of the mounting body (300) around the sensor-mounting hole, and a heat sink member (80) that is in contact with the housing at an axial position the same as or located frontward of the axial position of the front end of the contact portion.Type: GrantFiled: July 21, 2011Date of Patent: July 1, 2014Assignee: NGK Spark Plug Co., Ltd.Inventors: Takaya Yoshikawa, Tomohiro Tajima, Hisaharu Nishio, Masao Tsuzuki, Kunihiko Yonezu
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Patent number: 8747635Abstract: A gas sensor is provided with a multilayer body of solid electrolyte layers, a measurement electrode, a reference electrode, a reference gas introduction layer, a detection unit and a heater. The reference electrode and the measurement electrode are formed directly on the same first solid electrolyte layer. Thus, heat from the heater is transferred from a third substrate layer to the first solid electrolyte layer, and also to the reference electrode and the measurement electrode through the same first solid electrolyte layer. The reference electrode is covered with a reference gas introduction layer, formed of a porous body. The transference of heat from the heater to the reference electrode through the reference gas introduction layer is smaller than the transference of heat from the heater to the reference electrode through the first solid electrolyte layer on which the reference electrode is formed directly.Type: GrantFiled: March 7, 2012Date of Patent: June 10, 2014Assignee: NGK Insulators, Ltd.Inventors: Mika Murakami, Naoya Saito, Tomoya Seimori
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Patent number: 8721855Abstract: A crimp contact, a gas sensor including the crimp contact for outputting a signal from a sensing portion of a sensor element to an external device, and a method for manufacturing the crimp contact. The crimp contact includes a barrel portion crimped so as to fix a plurality of lead core wires (16) of an electrical lead connected to the external device. A hold portion constituting the barrel portion is formed such that the lead core wires 16 of the electrical lead are disposed in an U-shaped hold portion 77 so as to be crimped between an anvil 120 and a crimper 121. An outer surface of the U-shaped hold portion 77 has a plating layer 85 thereon to thereby constantly secure slidability between a sliding face of the crimper 121 and the outer surface of the U-shaped hold portion 77.Type: GrantFiled: November 29, 2006Date of Patent: May 13, 2014Assignee: NGK Spark Plug Co. Ltd.Inventors: Hisaharu Nishio, Masahiro Asai, Makoto Hishiki
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Patent number: 8721856Abstract: A gas sensor control system for a gas sensor having a first, a second, and a third cell. The second cell produces a second cell electric current indicating the concentration of oxygen in gas in which the amount of oxygen has already been controlled by the first cell. The third cell produces a third cell electric current indicating the concentration of a preselected component of the gas in which the amount of oxygen has already been controlled by the first cell. A second cell circuit converts the second cell electric current into a voltage as a second cell current-measured value. A current adjuster produces a flow of an adjustment current as a function of the second cell current-measured value so that a third cell circuit converts the third cell electric current minus the adjustment current into a voltage as representing the concentration of the preselected component of the gas.Type: GrantFiled: March 20, 2009Date of Patent: May 13, 2014Assignees: Denso Corporation, Nippon Soken, Inc.Inventors: Satoshi Hada, Takayuki Ishikawa, Katsuhide Akimoto
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Patent number: 8715474Abstract: A gas sensor element has a first cell, a second cell, and a solid electrolyte layer having proton conductivity commonly used by the first cell and the second cell. The first cell has a first cathode and a first anode exposed to the target detection gas containing hydrogen atoms. The second cell has a second anode, a second cathode, and a shield layer with which the second anode is covered. A voltage is supplied to the first and second cells. A gas concentration of the target detection gas is calculated on the basis of a difference between a current of the first cell and a current of the second cell because the current in the first cell is a sum of proton conductivity current and an electron conductivity current. The current in the second cell is an electron conductive current only.Type: GrantFiled: March 5, 2012Date of Patent: May 6, 2014Assignee: Denso CorporationInventors: Keigo Mizutani, Takehiro Watarai, Norikazu Kajiyama
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Patent number: 8679312Abstract: A gas sensor system including a gas sensor; a current control unit; a constant control unit; and a temperature acquisition unit. The gas sensor includes a measurement chamber, a pump cell and an electromotive force cell. The current control unit performs feedback control on current flowing through the pump cell in response to the voltage of the electromotive force cell and in accordance with a control constant which characterizes the feedback control. Further, the constant control unit changes the control constant of the feedback control in accordance with a value (for example, a resistance value of the electromotive force cell) corresponding to the temperature of the gas sensor.Type: GrantFiled: November 16, 2009Date of Patent: March 25, 2014Assignee: NGK Spark Plug Co., Ltd.Inventors: Yoshinori Inoue, Norikazu Ieda
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Publication number: 20140076725Abstract: A gas sensor including a sensor element constituted by an oxygen-ion conductive solid electrolyte as a main component and detecting a predetermined gas component in a measurement gas includes: an external communication part having an opening opened to the outside, and introducing the measurement gas from the outside under a predetermined diffusion resistance; an internal space communicating with the external communication part; a first electrode formed on a surface of the internal space; a second electrode formed in a space different from the internal space; and a pumping cell operable to pump out oxygen existing in the internal space when a predetermined voltage is applied between the first electrode and the second electrode. The thickness of the external communication part is 50% or more and 100% or less of the thickness of the internal space.Type: ApplicationFiled: November 19, 2013Publication date: March 20, 2014Applicant: NGK Insulators, Ltd.Inventors: Sumiko HORISAKA, Hiroki FUJITA, Mika MURAKAMI, Takashi ITO
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Patent number: 8673128Abstract: A gas sensor element includes an insulating ceramic base, a solid electrolyte body, and a heating element. The solid electrolyte body is disposed in an opening of the insulating ceramic base and has a measuring electrode affixed to one of major surfaces thereof and a reference electrode affixed to the other major surface. The measuring electrode is exposed to gas to be measured. The reference electrode is exposed to a reference gas. The heating element works to activate the solid electrolyte body and is mounted on one of opposed surfaces of the insulating ceramic base on the same side as the major surface of the solid electrolyte body on which the reference electrode is disposed. Specifically, the insulating ceramic base is located between the solid electrolyte body and the heating element, thereby ensuring a desired degree of electric insulation between the heating element and the reference electrode.Type: GrantFiled: September 27, 2012Date of Patent: March 18, 2014Assignee: Denso CorporationInventors: Masami Saitou, Namitsugu Fujii, Norikazu Kajiyama
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Publication number: 20140042025Abstract: A gas sensor (1) which can be an air-fuel ratio sensor includes a detection element (71) including a pair of electrodes, one of the paired electrodes being a sensing electrode (87) which is exposed to a gas-to-be-measured, and the other electrode being a reference electrode (95) which functions as an oxygen reference electrode. In the gas sensor (1), the reference electrode (95) is connected to a porous reference electrode lead (97) extending along the surface of a solid electrolyte body (77); the reference electrode lead (97) contains a noble metal as a main component and also contains a ceramic material; and the reference electrode lead (97) has a specific resistance lower than that of the reference electrode (95). The ceramic material has, in a sintered state, a mean primary grain size greater than that of the noble metal.Type: ApplicationFiled: August 8, 2013Publication date: February 13, 2014Applicant: NGK Spark Plug Co., Ltd.Inventor: Hitoshi FURUTA
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Patent number: 8632668Abstract: A deterioration signal generation device for an oxygen sensor having a power supply different than a power supply connected to an external device, including a connection unit for electrically connecting the ground lines of the respective power supplies; a first acquisition unit for electrically connecting to a first output line at a reference potential side and to a second output line at a sensor potential side of the oxygen sensor, to obtain first and second potentials, respectively; an operation unit that calculates a first differential value between the first and second potentials; a processing unit that performs an operation on the first differential value; a second acquisition unit that acquires a third potential of a first input line at a reference potential side of the external device; and an output unit that generates the deterioration signal by superposing the second differential value on the third potential.Type: GrantFiled: November 19, 2012Date of Patent: January 21, 2014Assignee: NGK Spark Plug Co., Ltd.Inventor: Seiji Maeda
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Patent number: 8632667Abstract: A deterioration signal generation device for an oxygen sensor having a power supply different than a power supply connected to an external device, including a connection unit for electrically connecting the ground lines of the respective power supplies; a first acquisition unit for electrically connecting to a first output line at a reference potential side and to a second output line at a sensor potential side of the oxygen sensor, to obtain first and second potentials, respectively; an operation unit that calculates a first differential value between the first and second potentials; a processing unit that performs an operation on the first differential value; a second acquisition unit that acquires a third potential of a first input line at a reference potential side of the external device; and an output unit that generates the deterioration signal by superposing the second differential value on the third potential.Type: GrantFiled: January 19, 2011Date of Patent: January 21, 2014Assignee: NGK Spark Plug Co., Ltd.Inventor: Seiji Maeda
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Patent number: 8623188Abstract: A gas sensor including a plate-shaped laminate disposed in a housing and fixed thereto via an element passage member and formed by laminating a gas sensor element and a heating element. The gas sensor element includes a plate-shaped solid electrolyte member, and a pair of detection electrodes formed on front and back surfaces thereof and constituting, in cooperation with the solid electrolyte member, a detection section for detecting the concentration of a specific gas. Insulating substrates mainly composed of alumina are provided on opposite sides of the laminate in the laminating direction. Coating layers mainly composed of a first material higher in toughness than alumina are formed on at least portions of outer surfaces of the insulating substrates in the laminating direction, the portions facing the element passage member. The coating layers are not formed on surfaces of the laminate parallel to the laminating direction.Type: GrantFiled: October 25, 2011Date of Patent: January 7, 2014Assignee: NGK Spark Plug Co., Ltd.Inventors: Ai Igarashi, Noboru Furuta
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Patent number: 8623187Abstract: A gas sensor including a sensor element constituted by an oxygen-ion conductive solid electrolyte as a main component and detecting a predetermined gas component in a measurement gas includes: an external communication part having an opening opened to the outside, and introducing the measurement gas from the outside under a predetermined diffusion resistance; an internal space communicating with the external communication part; a first electrode formed on a surface of the internal space; a second electrode formed in a space different from the internal space; and a pumping cell operable to pump out oxygen existing in the internal space when a predetermined voltage is applied between the first electrode and the second electrode. The thickness of the external communication part is 50% or more and 100% or less of the thickness of the internal space.Type: GrantFiled: March 22, 2011Date of Patent: January 7, 2014Assignee: NGK Insulators, Ltd.Inventors: Sumiko Horisaka, Hiroki Fujita, Mika Murakami, Takashi Ito