Abstract: The present invention relates to a demulsification additive composition for demulsification of water-in-oil emulsion caused due to wash water in the crude oil, wherein the composition comprises: (a) one or more demulsifiers (the component (a)); and (b) a compound selected from the group comprising glyoxal, neutralized glyoxal, glyoxal derivative and a mixture thereof (the component (b)), and (c) further comprises phosphoric acid (the component (c)). The present invention also relates to a method of using the present demulsification additive composition for demulsification of water-in-oil emulsion caused due to wash water in the crude oil. The present invention also relates to a method for demulsification of water-in-oil emulsion caused due to wash water in the crude oil by employing the present demulsification additive composition.

Abstract: The invention concerns an electrostatic coalescing device that includes a vessel or a pipe through which a mixture of fluids flows. At least one metal electrode plate and transformer are arranged inside the pipe/vessel. The electrode plate and transformer are fully enclosed by insulation, and the transformer is energized from an external alternating low voltage source/power supply located outside the vessel/pipe. The transformer includes a first end of a high voltage winding connected electrically to the metal plate within the insulation.

Abstract: A system for improving oil-water separator performance wherein an electrostatic coalescer (15) is located upstream of a cyclonic oil-water separator (16). Preferably, the electrostatic coalescer is able to be bypassed and/or is located in parallel with a mechanical coalescer (17). In the case of parallel arrangement, selection of the flow path route between the electrostatic coalescer (15) and mechanical coalescer (17) is determined by use of an upstream phase detector (18).

Abstract: An active method for decanting the dispersed phase in the continuous phase of an emulsion. According to the method, repulsive forces created by an electric field are used on the drops constituting the dispersed phase. The electric field scans the reservoir containing the emulsion, enabling the dispersed phase to be concentrated in a determined region of the reservoir, for the recovery and/or analysis of the emulsion. A device implements the method.

Abstract: Embodiments discussed herein relate to systems and methods for separating two or more phases of an emulsion or other mixture. The methods include providing the mixture with a net and unipolar charge (e.g., such that adjacent droplets therein acquire net and unipolar charges), thereby enhancing coalescence of like-phase droplets therein and producing, or enhancing the production of, two or more consolidated phases; and collecting the two or more consolidated phases.

Abstract: The invention relates to a device for electrostatic coalescence of liquid particles in a flowing fluid mixture, comprising: a tube having an feed opening located at the front side of the tube and a discharge opening located on the opposite side of the tube and a least one arrangement with flow guide vanes arranged in the tube, positioned in between the opened infeed side and an opposite opened outfeed side, for reducing the turbulence or for imparting a rotating movement to the fluid mixture flowing through the tube. The invention also relates to a method for electrostatic coalescence of liquid particles in a flowing fluid mixture.

Abstract: Methods are provided for concentrating particles on the surface of a drop or bubble in a continuous phase, for separating different types of particles, and for removing particles from the surface of the drop or bubble. The methods also facilitate separation of two types of particles on a drop or bubble, optionally followed by solidification of the drop and/or the continuous phase, for example to produce a particle for which the surface properties vary, such as a Janus particle. The methods can be also used to destabilize emulsions and foams by re-distributing or removing particles on the surface of the drop or bubble, facilitating coalescence of the particle-free drops or bubbles.

Abstract: An electrically energized compact coalescer (50) comprising an elongated, closed shell (53) having a fluid inlet (52) and a fluid outlet (59); at least one electrode (55) mounted in an internal chamber formed in the closed shell and forming at least one narrow gap (58) between the electrode means and a wall in the closed shell. An external power supply (64) is electrically connected to the electrode and the energized electrode (55) is fully encapsulated with insulation to enable an intense electrostatic field to be applied to an electrically conductive emulsion whereby the flow of emulsion through said at least one narrow gap (58) will be non-laminar. One or more helical vanes (57) are disposed in the narrow gap at an angle with respect to the electrode longitudinal axis and extending for at least a portion of the length (L) of the electrode, whereby the fluid flowing through said narrow gap will follow a spiraling pattern at least partially around the electrode (55).

Abstract: An apparatus and method for separating water from an oil-and-water mixture includes at least two elongated separator vessels oriented at an incline and connected to one another so that an upwardly flowing oil predominant fluid passes from the first separator vessel to the second separator vessel where further electrostatic separation of water from the oil predominant fluid occurs. Each vessel has an electrode at its upper end preferably connected to a different voltage source. The inlet to each vessel is located relative to the electrode to provide an up flow or a down flow vessel. Additionally, the first vessel may be at a different elevation than the second vessel. An additional vessel may be included with output from the first vessel bypassing the additional vessel, the second vessel, or both. Baffles may be added in the water collection portion of each vessel to reduce turbulence and settling distance.

Abstract: An apparatus for separating water from a water-in-oil mixture having an elongated inlet vessel with a lower outlet end and an upper inlet end, the length thereof being a multiple of the largest vessel cross-sectional dimension. A separation vessel having an oil outlet and a divergent water outlet has an inlet passageway in communication with the inlet vessel lower outlet end. At least one electrode is positioned within the inlet vessel by which a mixture flowing therethrough is subjected to an electric field.

Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Abstract: The present invention is generally directed to an apparatus for harvesting algae using a two-stage approach. The two-stage approach includes a flocculation stage and a dewatering stage. The flocculation stage is implemented within a first-stage flocculation tank in which algae suspended within a growth medium is flocculated. The flocculated algae is then fed to a second-stage flotation tank in which electrodes are used to produce hydrogen and oxygen bubbles which attach to the flocculated algae causing the flocculated algae to float to the surface. The mat of floating algae can then be skimmed off the surface of the growth medium.

Abstract: Nanoparticles in a colloid are purified, with the colloid including a fluid, unwanted matter, and the nanoparticles to be purified. An electric field is applied that is substantially spatially uniform over a distance that is at least equal to a characteristic dimension of the nanoparticles, so that at least some of the nanoparticles move towards at least one collection surface as a result of the force arising between their electrical charge and the electric field, whereupon nanoparticles are collected on said at least one collection surface. The collection surface(s) may be one or more electrodes to which a voltage potential is applied. The collected nanoparticles are then removed from the collection surface, e.g., by dispersing them into another fluid.

Abstract: A method of removing entrained salt containing water from an inlet crude oil stream includes the steps of applying an electrical energy to at least one electrode of a plurality of horizontally oriented, spaced-apart electrodes (12, 14, 16) housed within an elongated desalting vessel (10) and distributing an inlet crude oil stream between the electrodes. Each electrode in the plurality of electrodes is housed in an upper portion of the desalting vessel and may be in communication with a first, second and third transformer (42, 44, 46), respectively. The electrical energy may be at a single frequency and voltage or at a modulated voltage. Or, the electrical energy may be a modulated frequency at a single or modulated voltage. Fresh water may be mixed with the inlet crude oil stream either exteriorly or interiorly of the vessel.

Abstract: Disclosed is a process for the reduction of the electrical conductivity of a product mixture containing the oil and water phases resulting from the conversion of biomass to liquid products, including the at least partial breaking of any oil/water emulsion, which aids in the separation of the oil and water phases.

Abstract: A method for fabricating a sheet-shaped electrode for an electrostatic coalescing device. A layered material structure including an electrically conductive layer for forming a conductive member of the electrode and two electrically non-conductive insulation layers are arranged in an envelope. The insulation layers include thermoplastic or thermoset material for forming the insulation of the electrode. The conductive layer is arranged between the insulation layers. The envelope is sealed. Gas is evacuated from the envelope. The material structure is heated to a temperature above the melting temperature of the thermoplastic material or above the curing temperature of the thermoset material so as to consolidate the material structure while keeping the material structure inside the evacuated envelope. The material structure is cooled and removed from the envelope.

Abstract: A method for recovering for a material such as an absorbed solute from an ionic liquid is described. In the method, an electric field is applied to the ionic liquid to release the absorbed solute.

Abstract: A method of separating gaseous components, heavier liquid components and lighter liquid components of a stream including the steps of conducting the stream between spaced apart electrodes in a treatment vessel, supplying from a voltage source an AC voltage of at least one base frequency F1 to at least one of the electrodes to establish an electric field within the vessel through which the stream passes, modulating the frequency F1 of the AC voltage at a modulation frequency F2, and withdrawing separated gaseous components from an upper portion of the vessel, heavier stream components from a lower portion of the vessel, and lighter liquid components from an intermediate portion of said vessel.

Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.

Abstract: A method of augmenting the separation of immiscible heavier and lighter components of an emulsion including the steps of conducting the emulsion into a treatment vessel, providing an AC voltage source, employing from the source an AC voltage of at least one selected frequency F1 to establish at least one electric filed within the vessel through which the emulsion passes, and cyclically modulating the AC voltage with a method of modulation selected from: (a) amplitude modulation; (b) frequency modulation; and (c) combined amplitude and frequency modulation.

Abstract: A method and apparatus for the high-pressure electrocoagulative treatment of aqueous and viscous fluids and sludge is provided. The apparatus includes a plate and frame design utilizing mechanical closure on a plurality of recessed, gasketed, non-electrically conductive electrocoagulation spacer plates that completely enclose and isolate all fluids, electrical contacts, and electrodes within the confines of the apparatus. The spacer plates include intergral supports that position and support said plates with enclosed electrodes on top of the side rails of the supporting frame of the apparatus allowing said plates to be separated for electrode replacement and maintenance and conversly closed, pressured and put into service. The apparatus includes a baffled influent and effluent chamber at both ends for the addition and flash mixing of chemical reagents and/or flocculants and to provide a means of fluid communication between fluid conduits and chambers formed within the apparatus.

Abstract: A method of augmenting the separation of immiscible heavier and lighter components of an emulsion including the steps of passing the emulsion into a treatment vessel, establishing at least one dual frequency electric field within the vessel and selectably varying the electric field at a frequency F1 modulated in intensity at a frequency F2 where F1 is greater than F2.

Abstract: The present invention is an apparatus and a process for separation and resolution of particles suspended in, or molecules dissolved in, a sample mixture or solution using electrical field flow fractionation (EFFF). Fractionation of individual components in the mixture/solution is obtained by the interaction of particles/molecules with an electric field applied perpendicular to the flow direction, and externally to the fractionation channel. The plate electrodes are electrically isolated from the sample and carrier within a thin, non-permeable, insulating coating on the inside surfaces electrodes. This coating forms a barrier between the solution phase and the electric circuit used to generate the working electric field. The flow channel is formed by sandwiching a shaped insulating gasket between the two parallel plate electrodes. The side walls of the channel are defined then by the inside walls of the shaped, insulating gasket.

Abstract: The present invention is an apparatus and a process for separation and resolution of particles suspended in, or molecules dissolved in, a sample mixture or solution using electrical field flow fractionation (EFFF). Fractionation of individual components in the mixture/solution is obtained by the interaction of particles/molecules with an electric field applied perpendicular to the flow direction, and externally to the fractionation channel. The plate electrodes are electrically isolated from the sample and carrier within a thin, non-permeable, insulating coating on the inside surfaces electrodes. This coating forms a barrier between the solution phase and the electric circuit used to generate the working electric field. The flow channel is formed by sandwiching a shaped insulating gasket between the two parallel plate electrodes. The side walls of the channel are defined then by the inside walls of the shaped, insulating gasket.

Abstract: In order to improve the efficiency of the separation of an insulating liquid from a dispersum, in particular of water dispersed in oil, the electric conductivity of a dispersion having the dispersion constituents is measured continuously or discontinuously. An optimum frequency is calculated as a function of this conductivity. Pulsations of at least one pulsating electric field are thereby prescribed, this dispersion being led through said field. This frequency is preferably in the frequency range of >60 Hz-1 kHz. An electric field with a separating AC voltage can be arranged downstream of an electric field of a pulsating separating voltage of adjustable frequency in the flow direction of the dispersion, and an electric field of a pulsating charging DC voltage can be arranged upstream.

Abstract: Method for separating the constituents of a dispersion In order to improve the efficiency of the separation of an insulating liquid (3) from a dispersum (4), in particular of water dispersed in oil, the electric conductivity (&sgr;s) of a dispersion (S) having the dispersion constituents (3, 4) is measured continuously or discontinuously. An optimum frequency (f) is calculated as a function of this conductivity. Pulsations of at least one pulsating electric field are thereby prescribed, this dispersion (S) being led through said field. This frequency (f) is preferably in the frequency range of >60 Hz-1 kHz. An electric field with a separating AC voltage (U3) can be arranged downstream of an electric field of a pulsating separating voltage (U2) of adjustable frequency (f) in the flow direction of the dispersion (S), and an electric field of a pulsating charging DC voltage (U1) can be arranged upstream.

Abstract: Wastewater containing a surfactant and an oil content that has been emulsified by the action of the surfactant can be freed of the oil content by a method including feeding the wastewater into the anode compartment, for electrolysis, of a diaphragm electrolyzer having an anode and a cathode provided in the anode compartment and a cathode compartment, respectively, which are spaced apart by a porous diaphragm and which are supplied with a dc voltage between the anode and the cathode, passing part of the electrolyzed wastewater through the diaphragm so that it enters the cathode compartment, discharging the influent from the cathode compartment, discharging the remainder of the electrolyzed wastewater from the anode compartment and introducing the same into the intermediate portion of a gas-liquid separator, withdrawing part of the influent from the top of the gas-liquid separator and introducing the same into a layer packed with an adhering material, where it is brought into contact with the adhering material,

Abstract: A method and a reactor for electrochemical conversion of a material (21) being insoluble in a fluid into a material being soluble in the fluid, which method comprises that a flow of the fluid is passed to a reaction zone which comprises an internal circuit consisting of: one or more working electrodes (12), one or more counter-electrodes (13), and one or more ion-selective electrolytes (11), and which internal circuit is applied with an electrical voltage difference sufficient for the electrochemical processes; and use thereof for removal of soot particles from flue gasses and removal of oil in waste water.

Abstract: Small particles, of macromolecular size or the like, are separated in a liquid by size by applying electric fields of predetermined distributions in time and space to enhance the Brownian motion of the particles so as to favor motion of particles of a particular size. When the particles are separated by size they can be removed from the region in which they have accumulated and they can be collected by size.

Abstract: A process for separating an emulsion into separate and easily recoverable phases. The process comprises exposing an emulsion comprising a discontinuous phase and a non-conducting continuous phase to an electric field thereby effecting coalescence of the discontinuous phase into droplets of a size for effective gravitation from the continuous phase, where the discontinuous phase and the continuous phase have different dielectric constants and densities and at least one of the phases comprise a silicon containing compound or a silicon containing polymer. The present process is especially useful for separating emulsions where the discontinuous phase is an aqueous acid solution and the continuous phase is diorganopolysiloxane.

Abstract: An apparatus for separating an aqueous colloidal solution into water and agglomerate of colloidal particles by applying a high frequency voltage to the aqueous colloidal solution comprises a tank accommodating the aqueous colloidal solution, and at least one pair of electrodes disposed in the tank. The electrodes is configured such that lines of electric force are locally concentrated when the voltage is applied to said solution.

Abstract: Device for separating a mixture consisting of at least a continuous phase (I) and of at least a conducting disperse phase (II) in the form of particles such as drops in the continuous phase, the two phases having different densities. The device includes at least two substantially cylindrical parts (1, 3) fitted into each other which delimit an annular zone (5), introducing means (6, 7) for introducing the mixture to be separated at the periphery of the outer tubular part (1), arranged so as to communicate a rotational motion to the mixture, means for applying between the two parts (1, 3) a potential difference capable of causing the particles of the disperse phase (II) to coalesce, receiving and decanting means (4), means (8, 9) for discharging the two phases (I) and (II) at least partly separated on account of the differentiated motion of the particles which have coalesced and means for establishing a circulation of the mixture.

Abstract: Certain base catalyzed oxyalkylated-cardanol-alkylphenol-aldehyde resins may be utilized in refinery demulsification operations. These materials find particular utility in breaking water-in-oil emulsions resulting from the water wash of crude oils. The materials may also be employed to break other water-in-oil refinery emulsions.