Abstract: A method for preparing hydrogen sulfide from sulfur dioxide by electrochemical reduction includes electrochemically reducing sulfur dioxide absorbed in an aqueous solution into gaseous hydrogen sulfide with a membrane electrode, resulting in efficient and selective conversion of the sulfur dioxide absorbed in the aqueous solution into the hydrogen sulfide to avoid a deactivation of a cathode due to colloidal sulfur produced on the cathode and adhesion onto a surface of the cathode, wherein the method is carried out at ambient temperature and normal pressure without addition of a reducing agent, having no waste salts produced, and is simple in operation, and is convenient for large-scale application.

Abstract: A system for controlling an electrochemical production process includes a variable controllable power circuit and an electrolytic cell. The cell includes two electrodes and operates in different states dependent on the potential difference across the electrodes. The system includes a power circuit controller that causes the power circuit to apply a given potential difference across the electrodes to initiate operation of the cell in the one of multiple possible states associated with the given potential difference. The possible states include a production state associated with a first non-zero potential difference in which a product of interest is produced, and an idle state associated with a second non-zero potential difference in which the product of interest is not produced. A monitoring and control subsystem maintains a predefined set of production process conditions, including a predefined operating temperature range, while the cell operates in both the production state and the idle state.

Abstract: An automotive battery system including a first battery that couples to an electrical system. Additionally, the first battery includes a first battery chemistry. Further, the automotive battery system includes a second battery coupled in parallel with the first battery and couples to the electrical system. Furthermore, the automotive battery system includes a first switch coupled to a positive terminal of the second battery, which electrically couples or decouples the second battery to or from the electrical system. Moreover, the automotive battery system includes a battery control unit that detects a short circuit condition of the first battery, the second battery, or both and decouples the second battery from the electrical system by opening the first switch upon detecting the short circuit condition.

Abstract: Compounds for use in a rechargeable battery are provided, including a compound according to the formula: wherein R1 and R9 are independently selected from the group consisting of H, alkyl, aryl, perfluoroaryl, perfluoroalkyl, alkylaryl, alkoxyaryl, alkylcarboxyl, aryl carbonyl, haloalkyl, perfluoroalkyl, glycols, haloaryl, a negative electrolyte, and a polymer, so long as when R1 is H, R9 is not H; and R10 is selected from the group consisting of methyl, alkyl, aryl, alkylaryl, alkoxyaryl, alkylcarboxyl, aryl carbonyl, haloalkyl, perfluoroalkyl, perfluoroaryl, glycols, haloaryl, an oligomer, and a polymer.

Abstract: An ion conductive intercalation membrane is useful to separate anode and cathode compartments in an electrochemical cell and provide ion transport between the anode and cathode compartments. The intercalation membrane does not receive and release electrons during operation of the electrochemical cell. An electric potential and current source is connected to an anode and a cathode disposed in respective anode and cathode compartments to cause oxidation and reduction reactions to occur at the anode and cathode, to cause electrons to flow through an external circuit coupled to the anode and cathode, and to cause ions to transport through the intercalation membrane to maintain charge neutrality within the electrochemical cell. The electrochemical cell operates at a current density greater than 25 mA/cm2 across the intercalation membrane.

Abstract: A fuel cell module has a hydrogen recirculation pump and a controller. The controller receives a signal indicating the response of the pump to changes in the density or humidity of gasses in the hydrogen recirculation loop. The controller is programmed to consider the signal in controlling one or more balance of plant elements that effect the removal of water from the stack. In a process for operating the fuel cell module, the signal is considered when controlling one or more balance of plant elements that effect the removal of water from the stack. For example, an increase in current drawn from a constant speed or voltage recirculation pump indicates an increase in humidity and suggests that water should be removed from the stack, for example by increasing a coolant temperature set point.

Abstract: A fuel cell system of the present invention can suppress an excessively wet or dry state of a fuel cell stack so as to thereby ensure the durability of the fuel cell stack. The fuel cell system supplies an oxidant gas with a reduced flow rate per unit time and for a long time period if the rate of voltage decrease of the stack becomes faster than a threshold rate, and supplies the oxidant gas with an increased flow rate per unit time and for a short time period if the rate of voltage decrease becomes slower than a threshold rate.

Abstract: A membrane-electrode assembly for use in a reversible fuel cell comprises an ion conductive membrane having first and second surfaces; a first electrocatalyst layer in contact with the first surface of the membrane, such first electrocatalyst layer comprising at least one discrete electrolysis-active area (ELE1i) and at least one discrete energy generation-active area (EG1i). A second electrocatalyst layer is placed in contact with the second surface of the membrane, such second electrocatalyst layer comprising at least one discrete electrolysis-active area (ELE2i) and at least one discrete energy generation-active area (EG2i).

Abstract: A circuit applies an electric field to a reforming chamber housing a hydrocarbon-water mixture to cause molecular breakdown and create a feed of hydrogen and carbon and dioxide that can be supplied to fuel cells. The circuit includes a DC-to-DC converter, a DC-to-AC inverter and a transformer to transform available input voltage to a control voltage that can be used to apply the electric field to the mixture in the reforming chamber. The signal supplied to the DC-to-AC inverter is monitored to determine whether enough voltage is supplied to create an electrical discharge in the reforming chamber. If an electrical discharge exists, the variables to the circuit is left alone or decreased until the signal indicates the electrical discharge is no longer present. If no electrical discharge exists, the variable input voltage is increased until an electrical discharge is detected.

Abstract: A water electrolysis system includes a high-pressure hydrogen production unit for electrolyzing water to generate oxygen and high-pressure hydrogen (the pressure of the high-pressure hydrogen being higher than that of the oxygen), and a gas-liquid separation unit for removing water contained in the high-pressure hydrogen. The gas-liquid separation unit is placed on a hydrogen pipe for discharging the high-pressure hydrogen from the high-pressure hydrogen production unit. In addition, the water electrolysis system includes a high-pressure hydrogen supply pipe for transferring dewatered high-pressure hydrogen from the gas-liquid separation unit, a cooling unit, which is placed on the high-pressure hydrogen supply pipe and is capable of variably controlling the temperature of the high-pressure hydrogen to adjust the humidity of the high-pressure hydrogen, and a control unit.

Abstract: The present disclosure is directed to a method for tuning the performance of at least one electrochemical cell of an electrochemical cell stack. The method includes supplying power to an electrochemical cell stack. The electrochemical cell stack includes a plurality of electrochemical cells. The method further includes monitoring a parameter of at least one electrochemical cell and determining if an electrochemical cell becomes impaired. The method also includes diverting a fraction of the current flow from the impaired electrochemical cell during operation of the electrochemical cell stack.

Abstract: Method and system for monitoring the functionality of electrolysis cells for use in chlor-alkali electrolysis.

Abstract: A system is disclosed for controlling an electrochemical process. The system has a power source that is coupled to a power amplifier. The power amplifier is configured to provide an electromotive force (emf) signal, and a plurality of electrodes apply the emf signal to an electrochemical solution. A control element is configured to control the power amplifier such that the emf signal exhibits a predetermined frequency, amplitude, and duty cycle for reducing a thickness of the Nernst diffusion layer such that an operational parameter is set to a predetermined value.

Abstract: The present disclosure is directed towards a method and a system for monitoring the performance of an electrochemical cell stack. Monitoring can be performed remotely by measuring the voltage across the stack, and comparing the measured values to predetermined reference values to determine the condition of the stack. Monitoring of the stack voltage enables detection of performance decay, which in turn enables preemptive repair of the stack prior to catastrophic failure.

Abstract: A system (10) for generating a chlorine-containing compound includes an anodic chamber (12), a cathodic chamber (20), and a brine chamber (30). The anodic chamber (12) includes an anodic electrode (14) and the cathodic chamber (20) includes a cathodic electrode (22). A membrane (28) separates the anodic and cathodic chambers (12), (20). The brine chamber (30) includes an anodic electrode (32) and a cathodic electrode (34). Concentration and type of the chlorine-containing compound can be selectively and consistently controlled by the system (10) in real time.

Abstract: Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean. For high current density cells, cleaning is preferably performed by reversing the polarity of the electrodes and applying a lower current density to the electrodes, preferably by adjusting the salinity or brine concentration of the electrolyte while keeping the voltage constant. Electrolyte flow preferably comprises water and brine flows which are preferably separately monitored and automatically adjusted. For bipolar cells, flow between modules arranged in parallel is preferably approximately equally distributed between modules and between intermediate electrodes within each module.

Abstract: A method for extracting noble and non-ferrous metals from refractory raw materials includes a first stage electric treatment of ground pulp in a chloride solution and a subsequent second stage of extracting commercial metals, carried out in one reactor using electrolysers with graphite anodes and steel cathodes. The reactor is fed with pulp having an S:L ratio of 1:(1-20) in a solution with a chlorine concentration of 60-180 g/L, being acidified to pH=0.2-1.0, it's agitated, the volume current density is set to 1000-10000 A/m3 and the electrolyser's voltage to 2-5 V, then maintained constant. The first stage terminates by a transition of electric current through a maximum and chaning pH to 1-2. At the second stage, the cathode current density is set to 50-200 A/m2., until pH reaches 3-7. Cathode deposits of both stages are combined and further processed by known methods.

Abstract: Described are devices and methods for detecting binding on an electrode surface. In addition, devices and methods for electrochemically synthesizing polymers and devices and methods for synthesizing and detecting binding to the polymer on a common integrated device surface are described.

Abstract: A system and method for generating hypochlorous acid, the system comprising an electrolysis cell, a first fluid line configured to direct a first salt solution to a cathode chamber of the electrolysis cell, and a second fluid line configured to direct a second salt solution to an anode chamber of the electrolysis cell, where the second salt solution has a greater salt concentration than the first salt solution.

Abstract: Described are quality control methods and devices for the reproducible manufacturing and integrity monitoring of polymers on electrochemical synthesis and detection chips. The devices and methods allow for simultaneous manufacturing and synthesis of polymers.

Abstract: Systems and methods for selectively removing hydrogen gas from a hydrogen-containing fluid volume are disclosed. An exemplary system includes a proton exchange membrane (PEM) selectively permeable to hydrogen by exclusively conducting hydrogen ions. The system also includes metal deposited as layers onto opposite sides or faces of the PEM to form a membrane-electrode assembly (MEA), each layer functioning as an electrode so that the MEA functions as an electrochemical cell in which the ionic conductors are hydrogen ions, and the MEA functioning as a hydrogen selective membrane (HSM) when located at the boundary between a hydrogen-containing fluid volume and a second fluid.

Abstract: An apparatus has a tank with an interior for containing water, a nozzle for directing ozonated water out of the spray apparatus, and an electrolytic cell located between the nozzle and the tank. The electrolytic cell is configured to ozonate water as the water flows from the tank to the nozzle. The apparatus also includes a power source for providing electric potential to the electrolytic cell. The tank, nozzle, and electrolytic cell all are part of a single spray bottle or dispenser (e.g., like a soap dispenser).

Abstract: An electrolytic cell is suitable for production of aluminium, and includes at least one collector bar made of first metal and at least one complementary bar made of a second metal having an electrical conductivity greater than the first metal and arranged adjacent to one of the side faces of the collector bar so that the external end of the complementary bar is at a specified distance from a specified end face of the block. The second end terminates so as to limit heat losses from said cell. The cell makes it possible to obtain significantly lower voltage drops while avoiding excessive heat losses through the collector bars.

Abstract: Described are devices and methods for detecting binding on an electrode surface. In addition, devices and methods for electrochemically synthesizing polymers and devices and methods for synthesizing and detecting binding to the polymer on a common integrated device surface are described.

Abstract: Described are quality control methods and devices for the reproducible manufacturing and integrity monitoring of polymers on electrochemical synthesis and detection chips. The devices and methods allow for simultaneous manufacturing and synthesis of polymers.

Abstract: Methods and apparatus for controlling a catalytic layer deposition process are provided. A feed stream comprising a carbon source is provided to a catalyst layer. An asymmetrical alternating current is applied to the catalyst layer. A polarization impedance of the catalyst layer is monitored. The polarization impedance can be controlled by varying the asymmetrical alternating current. The controlling of the polarization impedance provides control over the structure and amount of carbon particles deposited on the catalyst layer. The carbon particles may be in the form of nanotubes, fullerenes, and/or nanoparticles.

Abstract: A cleaning solution generator comprising a housing with an interior reservoir and a brine tank, the cleaning solution generator being configured to generate an alkaline solution from a mixed solution and to operably direct the generated alkaline solution to the interior reservoir of the housing.

Abstract: This is an electrolytic apparatus and process for the production of Hypochlorous Acid (HClO) and Sodium Hydroxide (NaOH) in a closed-loop arrangement. A brine solution in an electrolyzer cell is subjected to an electric current, causing HClO and/or NaOH to be produced in water circulated through the cell. The produced solution is recirculated through the cell as its chemical properties are monitored by a sensor, connected by a controller which controls a recirculating pump and the electric current, until the sensor indicates that the concentration of the solution has reached a desired value, and the controller stops the process.

Abstract: An electrolysis cell is controlled for operation under varying electrical power supply conditions. A flow of feed stock to the cell includes an electrolysis reactant at a controlled concentration. A varying amount of electrical power is supplied to the cell to produce an electrolysis reaction that generates a first reaction product at a first side of the cell and a second reaction product at a second side of the cell. The reactant concentration is adjusted as the electrical power varies to substantially maintain the cell at its thermal neutral voltage during cell operation. The cell may be used in an electrolysis system powered by a renewable energy source with varying power output (e.g., wind, solar, etc.).

Abstract: There is described a method for ensuring and monitoring electrolyzer safety and performances in a manufacturing process which uses at least one electrolyzing cell containing at least one cathode and at least one anode separated by a membrane, comprising the step of: determining a safe single voltage operation range depending of the current and corresponding to the normally working electrolyzing cell; determining a reference voltage deviation depending on the time derivation of the current; measuring the voltage over time at the terminals of the electrolyzing cell; determining the measured voltage deviation by calculating the time derivative of the measured voltage; comparing the measured voltage to the safe single voltage operation range and the measured voltage deviation to the reference voltage deviation over time; stopping the manufacturing process when the measured voltage is outside the safe single voltage operation range or the difference between the measured voltage deviation and the reference voltage

Abstract: Various apparatuses and methods for producing ammonia are provided. One embodiment has uses a plurality of environments and an electrode configured to be exposed to the plurality of environments. The electrode is configured to receive hydrogen while being exposed to one of the environments, reduce nitrogen while being exposed to another environment, and allow the hydrogen and nitrogen to react with each other to form ammonia. Other embodiments provide for simultaneous hydrogen oxidation and nitrogen reduction at the same electrode, which in turn react for formation of ammonia.

Abstract: Method and apparatus for a low maintenance, high reliability on-site electrolytic generator incorporating automatic cell monitoring for contaminant film buildup, as well as automatically removing or cleaning the contaminant film. This method and apparatus preferably does not require human intervention to clean. For high current density cells, cleaning is preferably performed by reversing the polarity of the electrodes and applying a lower current density to the electrodes, preferably by adjusting the salinity or brine concentration of the electrolyte while keeping the voltage constant. Electrolyte flow preferably comprises water and brine flows which are preferably separately monitored and automatically adjusted. For bipolar cells, flow between modules arranged in parallel is preferably approximately equally distributed between modules and between intermediate electrodes within each module.

Abstract: There is described a method and a system for evaluating damage of a plurality of cells in an electrolyser. The method comprises acquiring a voltage for each one of the cells; comparing the voltage to at least two threshold voltage levels; classifying the cells as one of: severely damaged cells, non-severely damaged cells and undamaged cells, based on the comparison of the voltage with the at least two threshold voltage levels; and deactivating the cells classified as severely damaged cells from the electrolyser.

Abstract: Systems and methods for selectively removing hydrogen gas from a hydrogen-containing fluid volume are disclosed. An exemplary system includes a proton exchange membrane (PEM) selectively permeable to hydrogen by exclusively conducting hydrogen ions. The system also includes metal deposited as layers onto opposite sides or faces of the PEM to form a membrane-electrode assembly (MEA), each layer functioning as an electrode so that the MEA functions as an electrochemical cell in which the ionic conductors are hydrogen ions, and the MEA functioning as a hydrogen selective membrane (HSM) when located at the boundary between a hydrogen-containing fluid volume and a second fluid.

Abstract: Described are quality control methods and devices for the reproducible manufacturing and integrity monitoring of polymers on electrochemical synthesis and detection chips. The devices and methods allow for simultaneous manufacturing and synthesis of polymers.

Abstract: A method and apparatus are provided for energizing an electrolysis cell receiving a liquid to be electrochemically activated and contacting the liquid with an exposed, conductive tip of a voltage detector. The voltage detector generates a humanly-perceptible indicator as a function of charge movement sensed by the voltage detector through the liquid.

Abstract: There is described a method for ensuring and monitoring electrolyzer safety and performances in a manufacturing process which uses at least one electrolyzing cell containing at least one cathode and at least one anode separated by a membrane, comprising the step of: determining a safe single voltage operation range depending of the current and corresponding to the normally working electrolyzing cell; determining a reference voltage deviation depending on the time derivation of the current; measuring the voltage over time at the terminals of the electrolyzing cell; determining the measured voltage deviation by calculating the time derivative of the measured voltage; comparing the measured voltage to the safe single voltage operation range and the measured voltage deviation to the reference voltage deviation over time; stopping the manufacturing process when the measured voltage is outside the safe single voltage operation range or the difference between the measured voltage deviation and the reference voltage

Abstract: Methods and systems for generating biocidal solution having a predetermined level of available free chlorine and pH, including an electrolytic cell that generates the biocidal solution by an electrolytic reaction, the electrolytic cell including an input pipe for receiving an input brine solution, an anode chamber including an anode and a cathode chamber including a cathode separated by a separator, electrical connections for application of voltage to the anode and cathode; temperature sensing means for detecting a temperature of a solution of the electrolytic cell and outputting a signal indicative of the detected temperature; and process control means for adjusting the voltage applied to the electrolytic cell by the process control means thereby maintaining the level of available free chlorine and pH at the predetermined level in response to the signal output from the temperature sensing means.

Abstract: A method of operating a hybrid sulfur electrolyzer to generate hydrogen is provided that includes the steps of providing an anolyte with a concentration of sulfur dioxide, and applying a current. During steady state generation of hydrogen a plot of applied current density versus concentration of sulfur dioxide is below a boundary line. The boundary line may be linear and extend through the origin of the graph with a slope of 0.001 in which the current density is measured in mA/cm2 and the concentration of sulfur dioxide is measured in moles of sulfur dioxide per liter of anolyte.

Abstract: The present invention relates to methods and apparatus for activation of a low reactivity, non-polar chemical compound. In one example embodiment, the method comprises introducing the low reactivity chemical compound to a catalyst. At least one of (a) an oxidizing agent or a reducing agent and (b) a polar compound is provided to the catalyst and the chemical compound. An alternating current is applied to the catalyst to produce an activation reaction in the chemical compound. This activation reaction produces a useful product.

Abstract: The present invention provides methods and apparatus for controlling catalytic processes, including catalyst regeneration and soot elimination. An alternating current is applied to a catalyst layer and a polarization impedance of the catalyst layer is monitored. The polarization impedance may be controlled by varying the asymmetrical alternating current. At least one of water, oxygen, steam and heat may be provided to the catalyst layer to enhance an oxidation reaction for soot elimination and/or to regenerate the catalyst.

Abstract: A method for optimizing the efficiency of a solar powered hydrogen generation system is disclosed. The system utilizes photovoltaic modules and a proton exchange membrane electrolyzer to split water into hydrogen and oxygen with an efficiency greater than 12%. This high efficiency for the solar powered electrolysis of water was obtained by matching the voltage generated by photovoltaic modules to the operating voltage of the electrolyzer. Optimizing PV-electrolysis systems makes solar generated hydrogen less expensive and more practical for use as an environmentally clean and renewable fuel.

Abstract: A hydrogen generating system includes an electrode plate assembly including a plurality of electrode plates, a first connector and a second connector, each connector connected to at least some of the plates, an amperage sensor, a temperature sensor, and a controller capable of receiving signals from the amperage sensor and temperature sensor to monitor an amperage and a temperature of the hydrogen generating system. The controller includes a processor programmed to receive a target amperage, select, based on the target amperage, certain of the plurality of conductive plates to receive voltage input during a predetermined duty cycle, determine an actual amperage and an actual temperature resulting from the voltage input, compare the actual amperage and the actual temperature to a respective amperage threshold and temperature threshold; and adjust the duty cycle for applying voltage based on the comparison.

Abstract: A method of dynamically adding or removing a quantity of active plates in a plate assembly of a hydrogen generating system, the plate assembly comprising a plurality of plates. The method includes receiving a minimum amperage threshold, a maximum amperage threshold, a maximum temperature threshold, a first actual amperage, and a first actual temperature of a hydrogen generating system, selecting a first plurality of plates from the plate assembly, wherein the selection is based on at least one of the following: the minimum amperage threshold, the maximum amperage threshold, the first actual amperage, and the first actual temperature, and applying a first voltage to the first plurality of plates.

Abstract: A hydrogen generating system includes a plurality of conductive plates, a first connector and a second connector, wherein each connector is connected to at least some of the plates, an amperage sensor configured to measure an actual amperage of the hydrogen generating system, and a temperature sensor configured to measure an actual temperature of the hydrogen generating system, and a controller. The controller includes a processor programmed to receive a target amperage, a maximum amperage threshold, a maximum temperature threshold, and an optimal temperature, select, based on the target amperage, certain of the plurality of conductive plates to receive an applied voltage, receive a measurement of an actual amperage and an actual temperature from the amperage sensor and the temperature sensor, respectively, compare the actual amperage and the actual temperature to the maximum amperage threshold and the optimum temperature, respectively, and adjust the applied voltage based on the comparison.

Abstract: In order to carry out a selective extraction of cations (Mn+) by an electrochemical transfer in a solution from a first electrolyte (E1) to a second electrolyte (E2), the method includes using as an electrolyte separation wall a transfer wall (2) made of chalcogenide with molybdenum clusters (MonXn+2 or MxMonXn+2) and ensuring the cation transfer through the transfer wall by generating a potential difference (?E) between the electrode A1 in the first electrolyte (E1) and the electrode C2 in the second electrolyte (E1) or the transfer wall (2) in order to induce an interleaving of the cations in the transfer wall on the side of the first electrolyte, a scattering of the cations therein, and the de-interleaving thereof in the second electrolyte.

Abstract: The method of process control is for a Hall-Héroult process of aluminum production from alumina ore in an industrial potline. The method includes measuring an array of sampled potline data including a plurality of cell voltages (V) and a plurality of line amperages (A) at a plurality of time points. The method also includes calculating a predicted voltage (PV) for each cell voltage and line amperage in the array. The method further includes controlling a plurality of alumina ore feed rates and a plurality of pot voltage settings based upon the predicted voltages. The method also includes calculating a plurality of bath temperatures based upon the predicted voltages. The PV variable is preferably used in an automated control environment. The PV variable is also preferably used to monitor cell noise levels, operating temperature, metal pad roll, and oscillatory electrical shorting events.

Abstract: A fuel cell system, control method and current measuring device for a power unit are disclosed. The fuel cell system includes a fuel cell having local areas, a current measuring device associated with at least one of the local areas to measure localized current related to a specified operating characteristic, and a control section for diagnosing an operating condition of the fuel cell in response to localized current to enable optimum control of the fuel cell depending upon a specified operating characteristic determined by localized current. The control method controls the operating condition of the fuel cell in response to localized current indicative of the specified operating characteristic of the fuel cell. The current measuring device includes an electrical conductor formed with a recessed portion, a localized current conductor received in the recessed portion, and a current sensor for detecting current flowing across the localized current conductor.

Abstract: An electrolytic cell includes an electrode in a chamber including an electrolyte and an electrical power supply arranged to supply electrical energy to the electrode. A current sensor detects electrical current in the cell. A reservoir of a metal salt solution is provided. A controller is arranged to supply metal salt solution from the reservoir to the chamber of the cell in dependence on the current detected at the sensor. This permits the conductivity of the electrolyte to be brought up to required levels quickly, independently of dynamic cell conditions. Previously, metal salt was added gradually to the electrolyte. This was time-consuming and produced inconsistent results.

Abstract: A method and apparatus are provided for energizing an electrolysis cell receiving a liquid to be electrochemically activated and contacting the liquid with an exposed, conductive tip of a voltage detector. The voltage detector generates a humanly-perceptible indicator as a function of charge movement sensed by the voltage detector through the liquid.