Silicon Or Aluminum Containing Patents (Class 205/364)
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Patent number: 9099582Abstract: The present disclosure includes a texture formulation that includes an aliphatic diol, an alkaline compound and water which provides a consistent textured region across a silicon surface suitable for solar cell applications. The current invention describes silicon texturing formulations that include at least one high boiling point additive. The high boiling point additive may be a derivative compound of propylene glycol or a derivative compound of ethylene glycol. Processes for texturing a crystalline silicon substrate using these formulations are also described. Additionally, a combinatorial method of optimizing the textured surface of a crystalline silicon substrate is described.Type: GrantFiled: April 25, 2014Date of Patent: August 4, 2015Assignee: Intermolecular, Inc.Inventors: Zhi-Wen Sun, Nikhil Kalyankar, Nitin Kumar, Minh Anh Nguyen, Sagar Vijay
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Patent number: 8961773Abstract: The invention relates to a method of producing aluminum in an electrolysis cell, which includes setting up a succession of control periods of duration T, identifying perturbative tending operations on the cell that can introduce superfluous alumina in the electrolytic bath, noting the performance of the perturbative tending operations, determining a regulation feed rate B(k?) for each control period k? and setting a specified feed rate SR(k?) equal to M(k?)×B(k?), where M(k?) is a predetermined modulation factor that modulates the regulation feed rate B(k?) so as to take into account a reduction of the needs of the cell induced by the superfluous alumina. The method of the invention makes it possible to significantly reduce the rate of occurrence of anode effects.Type: GrantFiled: June 5, 2009Date of Patent: February 24, 2015Assignee: Rio Tinto Alcan International LimitedInventors: Sylvain Fardeau, Benoît Sulmont
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Patent number: 8734889Abstract: The invention relates to a ceramic implant, especially a dental implant, comprising a structured or porous surface for at least partially inserting into a bone. An especially advantageous surface is obtained when it is at least partially modified by a salt melt. These excellent osteointegration properties can be obtained by a method whereby the surface is modified in a salt melt at least in the regions exposed to the bones and/or soft tissue, optionally following a previous modification of the surface whereby material has been removed.Type: GrantFiled: June 1, 2006Date of Patent: May 27, 2014Assignee: Thommen Medical AGInventors: Falko Schlottig, Thomas Hefti
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Publication number: 20130220823Abstract: A series of inventions leading to the production of specific aluminum alloys (especially aluminum beverage can sheet product) through novel approach of introducing, selectively partitioning and managing alloying elements. This invention also enables manufacturing practices to enhance the performance characteristics of aluminum alloys produced. The selected elements can be derived from carbon anodes made from calcined petroleum coke with high metallic contents (such as nickel and vanadium). Alloying elements can also be introduced and managed from other raw material such as alumina and bath constituents added during aluminum smelting process. Additionally, cell operating parameters, such as cell temperature, off gas flow rate, aluminum tapping rate and impurity partition characteristics can also be manipulated to produce low cost aluminum alloys and facilitate utilization of high metallic content calcined petroleum coke.Type: ApplicationFiled: August 27, 2012Publication date: August 29, 2013Inventors: Gyan Jha, Frank R. Cannova, Subodh K. Das, Barry A. Sadler
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Patent number: 7790014Abstract: The present invention pertains to a method for removing a substance (X) from a solid metal or semi-metal compound (M1X) by electrolysis in a melt of M2Y, which comprises conducting the electrolysis under conditions such that reaction of X rather than M2 deposition occurs at a electrode surface, and that X dissolves in the electrolyte M2Y. The substance X is either removed from the surface (i.e., M1X) or by means of diffusion extracted from the case material. The temperature of the fused salt is chosen below the melting temperature of the metal M1. The potential is chosen below the decomposition potential of the electrolyte.Type: GrantFiled: February 12, 2004Date of Patent: September 7, 2010Assignee: Metalysis LimitedInventors: Derek John Fray, Thomas William Farthing, Zheng Chen
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Publication number: 20100000875Abstract: A process for preparing silicon comprising the following steps a) fused salt electrolysis of an SiO2-containing starting material together with antimony, mercury and sulfur to obtain a decomposed material; b) washing to remove elemental sulfur; c) acid treatment to eliminate foreign ions; d) reduction treatment to reduce mercury and/or antimony salts; e) density separation to separate the silicon from the residual components.Type: ApplicationFiled: May 13, 2006Publication date: January 7, 2010Inventor: Wulf Naegel
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Patent number: 7101470Abstract: A process for preparing highly purified silicon and aluminum and silumin (aluminum silicon alloy) in the same electrolysis furnace, by subjecting silicate and/or quartz containing rocks to electrolysis in a salt melt containing fluoride, whereby silicon and aluminum are formed in an electrolysis bath, and the aluminum formed, which may be low alloyed, flows to the bottom and is drawn off; transferring cathode with deposit to a Si-melting furnace, whereby the deposit with Si on the cathode flows down to the bottom of the melting furnace, and the cathode is removed before melting Si in said furnace, or during the electrolysis, shuffling the deposit formed on the cathode(s) down into the molten electrolysis bath, and transferring the molten or frozen bath containing Si from the cathode deposit to a Si-melting furnace after Al has flowed down to the bottom of the electrolysis furnace and been drawn off; melting the cathode deposit and/or molten or frozen bath, which contain silicon and slag, in the Si-melting furType: GrantFiled: February 21, 2002Date of Patent: September 5, 2006Assignee: Norwegian Silicon Refinery ASInventor: Jan Reidar Stubergh
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Patent number: 6974534Abstract: Process for preparing highly purified silicon and optionally aluminum and silumin (aluminum silicon alloy) in the same cell, wherein silicate and/or quartz containing rocks are subjected to electrolysis in a salt melt containing fluoride, whereby silicon and aluminum are formed in the same bath, and aluminum formed, which may be low alloyed, flow to the bottom and is optionally drawn off, and deposit formed on the cathode is removed from the cathode and crushed, optionally together with the remaining electrolysis bath, concentrated sulfuric acid and then hydrochloric acid and water are added to the crushed material, liberated Si-grains float to the surface and are taken out and treated further as desired.Type: GrantFiled: February 21, 2002Date of Patent: December 13, 2005Assignee: Norwegian Silicon Refinery ASInventor: Jan Reidar Stubergh
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Patent number: 6921473Abstract: A method of removing oxygen from a solid metal, metal compound or semi-metal M1O by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface and that oxygen dissolves in the electrolyte M2Y and wherein, M1O is in the form of (sintered) granules or is in the form of a powder which is continuously fed into the fused salt. Also disclosed is a method of producing a metal foam comprising the steps of fabricating a foam-like metal oxide preform, removing oxygen from said foam structured metal oxide preform by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface. The method is advantageously applied for the production of titanium from Ti-dioxide.Type: GrantFiled: February 20, 2001Date of Patent: July 26, 2005Assignee: Qinetiq LimitedInventors: Charles M Ward-Close, Alistair B Godfrey
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Publication number: 20040108218Abstract: Process for preparing highly purified silicon and optionally aluminum and silumin (aluminum silicon alloy) in the same cell, wherein silicate and/or quartz containing rocks are subjected to electrolysis in a salt melt containing fluoride, whereby silicon and aluminum are formed in the same bath, and aluminum formed, which may be low alloyed, flow to the bottom and is optionally drawn off, and deposit formed on the cathode is removed from the cathode and crushed, optionally together with the remaining electrolysis bath concentrated sulfuric acid and then hydrochloric acid and water are added to the crushed material, liberated Si-grains float to the surface and are taken out and treated further as desired.Type: ApplicationFiled: November 5, 2003Publication date: June 10, 2004Inventor: Jan Reidar Stubergh
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Publication number: 20040094428Abstract: Process for preparing highly purified silicon and optionally aluminum and silumin (aluminum silicon alloy) in the same cell. wherein silicate and/or quartz containing rocks are subjected to electrolysis in a salt melt containing fluoride. whereby silicon and aluminum are formed in the same bath.Type: ApplicationFiled: November 5, 2003Publication date: May 20, 2004Inventor: Jan Reidar Stubergh
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Patent number: 6712952Abstract: The present invention pertains to a method for removing a substance (X) from a solid metal or semi-metal compound (M1X) by electrolysis in a melt of M2Y, which comprises conducting the electrolysis under conditions such that reaction of X rather than M2 deposition occurs at a electrode surface, and that X dissolves in the electrolyte M2Y. The substance X is either removed from the surface (i.e., M1X) or by means of diffusion extracted from the case material. The temperature of the fused salt is chosen below the melting temperature of the metal M1. The potential is chosen below the decomposition potential of the electrolyte.Type: GrantFiled: January 22, 2001Date of Patent: March 30, 2004Assignee: Cambridge Univ. Technical Services, Ltd.Inventors: Derek John Fray, Thomas William Farthing, Zheng Chen
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Publication number: 20020092774Abstract: A cermet anode of an electrolytic cell is protected from thermal shock during cell start-up by coating an outer surface portion of the anode with a coating composition comprising carbon or aluminum or a mixture thereof. A particularly preferred coating composition includes an aluminum underlayer adjacent the outer surface portion of the anode, and a carbon overlayer overlying the underlayer. A support structure assembly supporting the cermet anode includes a high alumina ceramic material. In a preferred embodiment, the high alumina ceramic material is protected from thermal shock and corrosion by the coating composition of the invention.Type: ApplicationFiled: January 18, 2001Publication date: July 18, 2002Inventors: Calvin Bates, Patricia A. Stewart, Larry F. Wieserman
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Patent number: 6022396Abstract: The residues arising from industrial processes and from waste disposal which are polluted with heavy metals and/or heavy metal compounds, are subjected to a two-stage reduction process with formation of re-usable metal-containing and silicon-containing alloys. In a first reduction stage, using carbon or carbon-generating means as the reduction means, the compounds of silicon and metals are reduced, which have a standard potential which is greater than that of silicon. Following separation of the reduced metals, the residue obtained, which contains aluminum in oxidized form, is subsequently converted to a salt melt and this salt melt is subjected to a second reduction stage of a fused salt electrolysis, yielding an aluminum and silicon melt. The process is particularly suitable for filter residues from waste incineration plants.Type: GrantFiled: October 14, 1997Date of Patent: February 8, 2000Assignee: Refista Recycling AGInventor: Markus Grauwiller
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Patent number: 5873993Abstract: The present invention concerns a procedure for continuous or batch production in one or possibly more steps in one or more furnaces of silicon metal (Si), possibly silumin (AlSi alloys) and/or aluminium metal (Al) in the required conditions in a melting bath, preferably using feldspar or feldspar containing rocks dissolved in a fluoride and process equipment for implementing the procedure. Highly pure silicon is produced by electrolysis (step I) in a first furnace comprising a replaceable carbon anode (3) located at the bottom of the furnace and a carbon cathode (1) located at the top of the furnace. For the production of silumin the Si-poor residual electrolyte from step I is transferred to a second furnace and aluminium metal is added (step II). Aluminium metal is produced in a third furnace (step III) by electrolysis after Si has been removed in step I and possibly in step II.Type: GrantFiled: February 25, 1997Date of Patent: February 23, 1999Inventor: Jan Stubergh
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Patent number: 5573574Abstract: A process for obtaining aluminum of purity above 99.998%. A liquid aluminum raw material is subjected to a fractional crystallization to obtain prepurified aluminum crystals in a yield of between 50 and 80% and a liquid aluminum portion of lesser purity. The prepurified aluminum crystals are subjected to a three-layer electrolysis process in which the uppermost layer comprises a cathodic purified aluminum layer. The aluminum of purity above 99.998% is removed from the uppermost layer at a yield of above 90%, the aluminum having a total rare earth content of less than 100 ppb and a total content of U+Th of less than 20 ppb.Type: GrantFiled: June 13, 1995Date of Patent: November 12, 1996Assignee: Aluminium PechineyInventor: Michel Leroy