Lead, Zinc, Titanium, Zirconium, Or Hafnium Containing Patents (Class 205/366)
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Patent number: 11149356Abstract: A method of forming an elemental metal (e.g., a rare-earth element) includes forming a multicomponent solution comprising an ionic liquid, a secondary component, and a metal-containing compound. The multicomponent solution is contacted with at least a first electrode and a second electrode. A current is passed between the first electrode to the second electrode through the multicomponent solution. The metal-containing compound is reduced to deposit the elemental metal therefrom on the first electrode.Type: GrantFiled: December 19, 2017Date of Patent: October 19, 2021Assignee: Battelle Energy Alliance, LLCInventors: Donna L. Baek, Robert V. Fox, Tedd E. Lister
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Patent number: 10563315Abstract: A process for preparing lead by electroreduction with an ammonium chloride and an ammonia is disclosed. In the process, an ammonium chloride aqueous solution is used as an electrolyte, a lead compound is used as a raw material, titanium is used as an anode, stainless steel or lead is used as a cathode, and a direct-current electric field is applied in an electrolytic bath; the lead compound is reduced to metal lead after obtaining electrons at the cathode; and at the anode, ammonia is oxidized to nitrogen for escaping, and H+ ions are generated simultaneously; sulfate radical ions and chloride ions in the lead compound enter the solution to form ammonium sulfate and ammonium chloride; and the lead monoxide and lead dioxide in the lead compound are reduced to a metal lead and OH? ions are simultaneously released to combine with the H+ ions to form water.Type: GrantFiled: July 10, 2017Date of Patent: February 18, 2020Assignee: XIANGYUN TENGLONG INVESTMENT CO., LTD.Inventors: Yuzhang Shu, Long Yang, Rongxiang Liu
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Patent number: 10326155Abstract: Method of combining industrial processes having inherent carbon capture and conversion capabilities offering maximum flexibility, efficiency, and economics while enabling environmentally and sustainably sound practices. Maximum chemical energy is retained throughout feedstock processing. A hybrid thermochemical cycle couples staged reforming with hydrogen production and chlorination. Hydrogen generated is used to upgrade feedstocks including bitumen, shale, coal, and biomass. Residues of upgrading are chlorinated, metals of interest are removed, and the remainder is reacted with ammonia solution and carbon dioxide to form carbonate minerals. The combination provides emissions free production of synthetic crude oil and derivatives, as well as various metals and fertilizers. Sand and carbonate minerals are potentially the only waste streams. Through this novel processing, major carbon dioxide reduction is afforded by minimizing direct oxidation.Type: GrantFiled: September 11, 2015Date of Patent: June 18, 2019Inventor: Justin Langley
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Patent number: 9611558Abstract: A method of producing metallic powder comprises steps of arranging a volume of feedstock comprising a plurality of non-metallic particles within an electrolysis cell, causing a molten salt to flow through the volume of feedstock, and applying a potential between a cathode and an anode such that the feedstock is reduced to metal. In preferred embodiments the feedstock is a plurality of discrete powder particles and these particles are reduced to a corresponding plurality of discrete metallic particles. In advantageous embodiments, the feedstock may be sand.Type: GrantFiled: October 4, 2012Date of Patent: April 4, 2017Assignee: METALYSIS LIMITEDInventors: Kartik Rao, James Deane, Lucy Grainger, John Clifford, Melchiorre Conti, James Collins
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Patent number: 8303793Abstract: The invention relates to a method of providing an electric current taker made from silver and having a highly electroconductive contact surface into an aluminium support bar to be used in electrolysis.Type: GrantFiled: June 25, 2009Date of Patent: November 6, 2012Assignee: Valvas OyInventor: Niko Hagner
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Publication number: 20120006690Abstract: The present invention provides a process for preparing lithium alloy or lithium metal from lithium carbonate or its equivalent lithium ion source such as spudomene ore without creating toxic byproducts such as halogen gases and a system adopted for such a process.Type: ApplicationFiled: June 29, 2011Publication date: January 12, 2012Inventors: Steven C. Amendola, Lawrence Swonger, Stefanie Goldman
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Patent number: 7879219Abstract: The subject invention pertains to methods for processing a solid material (M1X) comprising a solid solution of a non-metal species (X) in a metal or semi-metal (M1) or a compound between the non-metal species and the metal or semi-metal is immersed in a molten salt (M2Y). A cathodic potential is applied to the material to remove a portion of the non-metal species by electro-deoxidation. To remove the non-metal species at lower concentrations, a source of a reactive metal (M3) is immersed in the molten salt and is electronically connected to the material. Reactions occur at the material, where the non-metal species dissolves in the salt, and at the reactive metal, which reacts with the non-metal species dissolved in the salt to form a reaction product more stable than a compound between the non-metal species and the metal or semi-metal (M1). The non-metal species is thus removed from the solid material.Type: GrantFiled: December 2, 2002Date of Patent: February 1, 2011Assignee: Metalysis LimitedInventors: Derek John Fray, Robert Charles Copcutt
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Patent number: 7790014Abstract: The present invention pertains to a method for removing a substance (X) from a solid metal or semi-metal compound (M1X) by electrolysis in a melt of M2Y, which comprises conducting the electrolysis under conditions such that reaction of X rather than M2 deposition occurs at a electrode surface, and that X dissolves in the electrolyte M2Y. The substance X is either removed from the surface (i.e., M1X) or by means of diffusion extracted from the case material. The temperature of the fused salt is chosen below the melting temperature of the metal M1. The potential is chosen below the decomposition potential of the electrolyte.Type: GrantFiled: February 12, 2004Date of Patent: September 7, 2010Assignee: Metalysis LimitedInventors: Derek John Fray, Thomas William Farthing, Zheng Chen
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Publication number: 20090114546Abstract: The present invention provides a method by which a metal-fog-forming metal dissolved in one portion of “a molten salt mixture consisted of one or more of metal-fog-forming metal containing molten salts” (generally, a molten salt) can be removed and transferred to another portion of the molten salt to increase the concentration thereof. The method can hence be utilized as one of means for treating molten salts in various industrial fields in which metal-fog-forming metal-containing molten salts such as Ca or Na are handled. In particular, when the method is utilized in producing Ti by Ca reduction, the Ca dissolved in the molten salt to be fed to an electrolytic cell can be rapidly removed (recovered) and the Ca formation efficiency during the electrolysis of the molten salt can be enhanced. Consequently, Ca formation and TiCl4 reduction in the electrolysis of the molten salt can be efficiently carried out and a stable operation on a commercial scale is possible.Type: ApplicationFiled: March 9, 2007Publication date: May 7, 2009Inventors: Tadashi Ogasawara, Makoto Yamaguchi
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Patent number: 7504009Abstract: The invention relates to a method for achieving a good contact surface on an aluminium electrode support bar used in electrolysis. In the method the support bar is fabricated as a continuous bar and a highly electroconductive layer is formed on its end. The highly electroconductive layer forms a metallic bond with the support bar and can be achieved for example with thermal spray coating. The invention also relates to an electrode support bar, the end of which is coated with a highly electroconductive material.Type: GrantFiled: November 6, 2003Date of Patent: March 17, 2009Assignee: Outotec OyjInventors: Karri Osara, Veikko Polvi
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Patent number: 7425257Abstract: The disclosure relates to a method of obtaining a good current contact on the support bar of a cathode used in electrolysis. In this method a highly electroconductive layer is formed on the contact piece on the end of the support bar of the cathode, especially at the point that comes into contact with the electrolysis cell busbar. The electroconductive layer forms a metallic bond with the contact piece of the support bar. The disclosure also relates to the cathode support bar, wherein a highly electroconductive layer is formed to the contact piece on the end of said bar, in particular the area that touches the electrolysis cell busbar.Type: GrantFiled: November 6, 2003Date of Patent: September 16, 2008Assignee: Outotec OyjInventors: Karri Osara, Veikko Polvi
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Patent number: 7252751Abstract: The invention includes a method of forming a material which comprises at least two elements. More specifically, the method comprises providing an electrolytic cell comprising a cathode, an anode, and an electrolytic solution extending between the cathode and anode. A metallic product is electrolytically formed within the electrolytic cell. The forming of the metallic product comprises primarily electrorefining of a first element of the at least two elements and primarily electrowinning of a second element of the at least two elements. The invention also includes a mixed metal product comprising at least two elements, such as a product comprising tantalum and titanium.Type: GrantFiled: March 5, 2004Date of Patent: August 7, 2007Assignee: Honeywell International Inc.Inventor: Guangxin Wang
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Patent number: 6921473Abstract: A method of removing oxygen from a solid metal, metal compound or semi-metal M1O by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface and that oxygen dissolves in the electrolyte M2Y and wherein, M1O is in the form of (sintered) granules or is in the form of a powder which is continuously fed into the fused salt. Also disclosed is a method of producing a metal foam comprising the steps of fabricating a foam-like metal oxide preform, removing oxygen from said foam structured metal oxide preform by electrolysis in a fused salt of M2Y or a mixture of salts, which comprises conducting electrolysis under conditions such that reaction of oxygen rather than M2 deposition occurs at an electrode surface. The method is advantageously applied for the production of titanium from Ti-dioxide.Type: GrantFiled: February 20, 2001Date of Patent: July 26, 2005Assignee: Qinetiq LimitedInventors: Charles M Ward-Close, Alistair B Godfrey
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Patent number: 6848157Abstract: A disposable syringe device auxiliary unit of the present invention for preventing iatrogenic infection through a needle includes a cap holding section for disposing and holding therein a cap which covers, when a medical treatment is performed, a needle positioned at the extreme end of a syringe barrel constituting a disposable syringe device; and a needle separating section for separating the needle, which is covered with the cap and fitted on an end of the syringe barrel, therefrom.Type: GrantFiled: December 10, 2001Date of Patent: February 1, 2005Inventor: Koichiro Abe
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Publication number: 20030047462Abstract: A method for the production of a master alloy including the steps of; introducing mixed ores comprising the metals of the alloy; introducing the mixed ores into an electrochemical cell, the cell containing a liquid electrolyte comprising a fused salt or mixture of salts generally designated as M2Y in which contaminants X contained in the mixed ores are soluble, and a relatively inert anode; conducting electrolysis under conditions favourable to the selective dissolution of contaminants contained in the mixed ores in preference to the deposition of the M2 cation; and following electrolysis, reclaiming the purified mixed ore form the cathode.Type: ApplicationFiled: September 10, 2002Publication date: March 13, 2003Inventors: Charles M Ward-Close, Alastair B Godfrey