Utilizing Halogen Containing Material Patents (Class 205/570)
  • Patent number: 8617377
    Abstract: An electrowinning method of metals through electrolysis of a metal chloride solution uses an anode comprising a substrate comprising titanium or titanium alloy, and a coating layer comprising a plurality of a unit layer, provided on the surface of the substrate. The unit layer comprises the first coating layer comprising a mixture of iridium oxide, ruthenium oxide and titanium oxide and the second coating layer comprising a mixture of platinum and iridium oxide. The first coating layer contacts with the surface of said substrate and an outer coating layer of the unit layer formed on the outermost layer of said coating layer is the second coating layer. The coating layer is formed by thermal decomposition baking, which followed by post-baking at a higher baking temperature.
    Type: Grant
    Filed: October 14, 2011
    Date of Patent: December 31, 2013
    Assignee: Permelec Electrode Ltd.
    Inventor: Toshikazu Hayashida
  • Patent number: 8505730
    Abstract: Compositions, kits and regimens for treatment of damaged skin, especially décolletage, include application of a retinoid, hydroquinone or hydroquinone derivatives, and a composition containing a multi-metal complex.
    Type: Grant
    Filed: August 23, 2012
    Date of Patent: August 13, 2013
    Assignee: JR Chem, LLC
    Inventors: Jose E. Ramirez, Joseph R. Faryniarz
  • Patent number: 8025859
    Abstract: A process for the extraction of a precious metal, such as gold or silver, from a sulphide ore or concentrate or other source material comprises subjecting the source material to pressure oxidation to produce a pressure oxidation slurry. The pressure oxidation slurry is flashed down to a lower temperature and pressure and is then subjected to a liquid/solid separation to obtain a pressure oxidation solution and a solid residue containing the precious metal. The solid residue is then subjected to cyanidation to extract the precious metal. The formation of thiocyanide during cyanidation is minimized or counteracted by effecting the cyanidation at an elevated oxygen pressure and a reduced retention time, such as 30 to 90 minutes. A method for the reduction of copper cyanide formation during cyanidation leaching is also provided.
    Type: Grant
    Filed: May 18, 2007
    Date of Patent: September 27, 2011
    Assignee: CESL Limited
    Inventor: David L. Jones
  • Patent number: 7858056
    Abstract: A process for recovering a precious metal from a sulfidic material comprises the steps of preparing an acidic aqueous halide solution having an oxidation potential sufficient to oxidize the sulfidic material and render the precious metal soluble in the solution, adding the material to the acidic aqueous halide solution so that the sulfidic material is oxidized and the precious metal is solubilized and separating the precious metal from the oxidized sulfidic material. In addition, a process for removing a contaminant from a contaminated sulfidic material comprises the steps of mixing the material in an aqueous solution wherein a multi-valent species of a relatively high oxidation state oxidizes the contaminant to render it soluble in the solution, produces a contaminant refined material, and is reduced to a relatively lower oxidation state; and removing the contaminant from the solution while regenerating the multi-valent species to its relatively high oxidation state.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: December 28, 2010
    Assignee: INTEC, Ltd.
    Inventors: John Moyes, Frank Houllis
  • Patent number: 7785395
    Abstract: The invention relates to a method for recovering gold from a sulphidic concentrate, particularly one containing arsenopyrite and/or pyrite, hydro-metallurgically. The concentrate is first subjected to leaching with a concentrated solution of alkali chloride and copper (II) chloride, by means of which the copper minerals and some of the gold in the concentrate are made to dissolve. Elemental sulphur and precipitated iron and arsenic compounds are separated from the leaching residue using physical separation methods, whereby the first intermediate is obtained, which contains gold-bearing sulphide minerals and gangue minerals as well as the gold that remains undissolved. The free gold that remains undissolved is separated by means of gravity separation methods. After gravity separation, additional comminution is carried out, after which the sulphide minerals are decomposed and the gold-containing solution or residue is routed to the concentrate leaching circuit.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: August 31, 2010
    Assignee: OUTOTEC OYJ
    Inventors: Jaakko Leppinen, Olli Hyvärinen, Seppo Heimala, Veikko Palosaari, Matti Hämäläinen, Tuula Hämäläinen, legal representative
  • Patent number: 6156186
    Abstract: The present invention is directed to a process for removing various contaminants (e.g., organic collectors, contaminant metals or spectator ions, and/or suspended and colloidal solids) from process streams in leaching processes. The contaminant removal is performed by one or more membrane filtration systems (e.g., nanofilters, ultrafilters, and/or microfilters) treating process streams including, the pregnant leaching solution, the barren raffinate, and the lean and rich electrolytes.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: December 5, 2000
    Assignee: HW Process Technologies, Inc.
    Inventors: Jeff Mueller, Dennis H. Green
  • Patent number: 5876589
    Abstract: Wastewater containing a surfactant and an oil content that has been emulsified by the action of the surfactant can be freed of the oil content by a method including feeding the wastewater into the anode compartment, for electrolysis, of a diaphragm electrolyzer having an anode and a cathode provided in the anode compartment and a cathode compartment, respectively, which are spaced apart by a porous diaphragm and which are supplied with a dc voltage between the anode and the cathode, passing part of the electrolyzed wastewater through the diaphragm so that it enters the cathode compartment, discharging the influent from the cathode compartment, discharging the remainder of the electrolyzed wastewater from the anode compartment and introducing the same into the intermediate portion of a gas-liquid separator, withdrawing part of the influent from the top of the gas-liquid separator and introducing the same into a layer packed with an adhering material, where it is brought into contact with the adhering material,
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: March 2, 1999
    Assignee: Ebara Corporation
    Inventors: Qingquan Su, Hiroaki Sato, Michihiro Noda
  • Patent number: 5874055
    Abstract: A process for the extraction of a metal from an ore or concentrate comprises subjecting the ore or concentrate to pressure oxidation in the presence of oxygen and an acidic solution containing halogen ions and a source of bisulphate or sulphate ions, such as H.sub.2 SO.sub.4. The metals which can be extracted by the process comprises copper, as well as non-cuprous metals, such as zinc, and precious metals, such as gold and silver.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: February 23, 1999
    Assignee: Cominco Engineering Services Ltd.
    Inventor: David L. Jones
  • Patent number: 5869012
    Abstract: A process for the extraction of zinc from a sulphide ore or concentrate containing copper and zinc includes subjecting the concentrate to pressure oxidation in the presence of oxygen and an acidic halide solution to obtain a resulting pressure oxidation slurry and subjecting the slurry to a liquid/solid separation step to produce a liquor containing copper and zinc in solution. The liquor containing the copper and zinc is subjected to a first solvent extraction with a copper extractant to remove copper from the solution and to produce a copper depleted raffinate. The copper depleted raffinate is subjected to a second solid extraction with a zinc extractant to produce a zinc depleted raffinate and the zinc depleted raffinate is recycled to the pressure oxidation step.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: February 9, 1999
    Assignee: Cominco Engineering Services Ltd.
    Inventor: David L. Jones
  • Patent number: 5542957
    Abstract: Platinum group metals and rhenium are extracted from their elemental state, complex ores, and other materials such as catalysts by leaching them with a solution containing ammonium halogen salts--iodide and bromide in the presence oxygen and/or sulfuric acid. The invented process is particularly effective for spent catalysts containing precious metals and rhenium in an autoclave at a temperature of 50.degree. C.-300.degree. C.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: August 6, 1996
    Assignee: South Dakota School of Mines and Technology
    Inventors: Kenneth N. Han, Xinghui Meng
  • Patent number: 5487819
    Abstract: A process for producing one or more metals from a mineral feedstock (12) is defined. The mineral is fed to a leaching apparatus (10) wherein it is contacted with electrolyte (14). The leaching apparatus has zones of decreasing oxidation potential (17, 18, 19, 20) respectively. A stream of electrolyte (14A) is removed from zone (20) and is treated to remove impurities and unwanted metals in treatment unit (25A), prior to metal recovery by electrolysis. The electrolyte after electrolysis is then returned to the leaching unit (10). A second electrolyte stream (14B) may be removed from zone (19) for recovery of additional metals. The electrolyte (14B) is treated to remove impurities and any unwanted metals in treatment unit (25B), prior to metal recovery by electrolysis. The electrolyte after electrolysis is returned to leaching unit (10). The process enables the leaching of difficult to leach minerals, including gold, and can produce one or more metals of high purity.
    Type: Grant
    Filed: December 23, 1994
    Date of Patent: January 30, 1996
    Inventor: Peter K. Everett