Nonelemental Material From Ferrous Metal Patents (Class 205/712)
  • Patent number: 10597741
    Abstract: A high-strength steel sheet and a method for manufacturing a high-strength steel sheet having excellent phosphatability and excellent corrosion resistance after electrodeposition coating has been performed, even in the case where the contents of Si and Mn are high. The method may comprise annealing a steal sheet by using a continuous annealing method, performing a heating process, controlling the maximum end-point temperature of a steel sheet in the annealing furnace, controlling the traveling time of the steel sheet, and controlling the dew point of the atmosphere.
    Type: Grant
    Filed: November 13, 2014
    Date of Patent: March 24, 2020
    Assignee: JFE STEEL CORPORATION
    Inventors: Yusuke Fushiwaki, Yoshiyasu Kawasaki
  • Patent number: 10400350
    Abstract: An apparatus for removing paint from a metallic component. The apparatus includes an electrolytic cell in which the metallic component is an anode, and a DC power supply capable of producing a plasma causing the paint from the metallic component to disintegrate. A method of depainting a metallic component includes providing an electrolytic cell with the metallic component to be depainted acting as an anode. A DC power supply connected to the cathode and anode is activated to produce a plasma causing the paint from the metallic component to disintegrate. Another method of method of depainting a metallic component includes providing an aqueous solution of sodium hydrogen carbonate, sodium citrate, and potassium oxalate as an electrolyte, a cathode and a pained metallic component as an anode. A DC power supply connected to the cathode and anode produces a plasma causing the paint from the painted metallic component to disintegrate.
    Type: Grant
    Filed: April 18, 2017
    Date of Patent: September 3, 2019
    Assignee: IBC Materials & Technologies, Inc.
    Inventors: Solomon Berman, Daesung Chong, Ashok Ramaswamy
  • Patent number: 9334579
    Abstract: This invention relates to compositions and methods for the at least partial dissolution, disruption and/or removal of deposit, such as scale and other deposit, from heat exchanger components. The heat exchanger components can include pressurized water reactor steam generators. In accordance with the invention, elemental metal is added locally to the surface of the deposit and/or anodic or cathodic current is applied locally to the deposit surface to destabilize or weaken the deposit. Subsequently, mechanical stress is applied to the weakened deposit to disrupt and remove the deposit from the surface of the heat exchanger component.
    Type: Grant
    Filed: October 29, 2013
    Date of Patent: May 10, 2016
    Assignee: Westinghouse Electric Company LLC
    Inventors: Kurtis R. Crytzer, David W. Selfridge, Jr., Martin Legoff, Lauren R. Ikeda
  • Patent number: 8734633
    Abstract: Proposed is a method of recovering valuable metal from scrap containing conductive oxide including the steps of using an insoluble electrode as either an anode or a cathode, using a scrap containing conductive oxide as the counter cathode or anode, performing electrolysis while periodically inverting the polarity, and recovering the scrap as hydroxide. With the foregoing method of recovering valuable metal from scrap containing conductive oxide, oxide system scrap is conductive oxide and a substance that can be reduced to metal or suboxide with hydrogen. This method enables the efficient recovery of valuable metal from sputtering target scrap containing conductive oxide or scrap such as mill ends of conductive oxide that arise during the production of such a sputtering target.
    Type: Grant
    Filed: February 8, 2008
    Date of Patent: May 27, 2014
    Assignee: JX Nippon Mining & Metals Corporation
    Inventors: Yuichiro Shindo, Kouichi Takemoto
  • Patent number: 8636887
    Abstract: The invention relates to a method for electrokinetic decontamination of a porous solid medium, which comprises: a) extracting the contaminating species present in the solid medium in an electrolyte appearing as an essentially inorganic gel, this extraction being obtained by applying an electric current between two electrodes positioned at the surface and/or in the interior of the solid medium, the contact of at least one of these electrodes with said solid medium being ensured by a layer of said gel, b) drying the gel containing the thereby extracted contaminating species until a dry residue is obtained which fractures, and c) removing the thereby obtained dry residue from said solid residue.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: January 28, 2014
    Assignee: Commissariat a l'Energie Atomique et aux Energies Alternatives
    Inventors: Frédéric Cuer, Axel De Nadaï
  • Patent number: 8313637
    Abstract: A wear of an electrode is prevented as much as possible, thereby efficiently electrolyzing a sulfuric acid solution and the like. An electrolysis method includes: passing an electrolytic solution through an electrolysis cell including at least a pair of an anode and a cathode; and supplying the electrodes with an electric power, so as to electrolyze the electrolytic solution, wherein a viscosity of the electrolytic solution is set in a range in response to a current density upon the electric power supply to carry out the electrolysis. The viscosity of a sulfuric acid solution as the electrolytic solution is equal to or less than 10 cP when the current density is equal to or less than 50 A/dm2, the viscosity of the sulfuric acid solution is equal to or less than 8 cP when the current density is from more than 50 to 75 A/dm2, and the viscosity of the sulfuric acid solution is equal to or less than 6 cP when the current density is from more than 75 to 100 A/dm2.
    Type: Grant
    Filed: December 26, 2008
    Date of Patent: November 20, 2012
    Assignee: Kurita Water Industries Ltd.
    Inventors: Minoru Uchida, Tatsuo Nagai, Shunichi Kanamori
  • Patent number: 7045053
    Abstract: An apparatus for the superficial electrolytic treatment of metal strips, comprising several separate and non-communicating tanks, or containers, located along the path of metal strip (13). A series of electrodes in pairs (14?, 15?, 14?, 15?, 14??, 15??), arranged as tunnels, is situated along the path. Each pair is associated with a container (2?, 2?, 2??), in which an electrod 14?, 14?, 14??) of each pair is located above the strip and the other (15?, 15?, 15??) is located below said strip, in a reciprocally opposits position and at an appropriate distance. The electrode pairs alternately have opposite polarity and each of them is respectively associated with a container. Rollers (3, 3?, 3?, 3??) in pairs for strip pressing are situated at the common border of adjacent containes for the galvanic separation of the strip surface areas facing the electrode pairs of opposite polarity.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: May 16, 2006
    Assignee: Danieli & C.Officine Meccaniche S.p.A.
    Inventors: Ralf Matzka, Dieter Gruchot
  • Patent number: 6726830
    Abstract: This invention relates to an improved apparatus and method for electrolytic descaling of steel strips. The apparatus comprises electrodes integrated with nozzles having jet openings for dispensing electrolyte onto the surface of the steel strips. By jetting the electrolyte to the steel strip in the air and applying a voltage to the electrode, the scale on the surface of the steel strip is removed. This jetting of electrolyte reduces the size requirement of the electrolyte tank storing the electrolyte because the required quantity of electrolyte decreases. The present invention does not require immersion of the electrodes in the electrolyte and thus avoids the problem of short-circuiting that occurs with submerged electrodes. This results in a significant improvement in electric power efficiency.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: April 27, 2004
    Assignee: Hitachi, Ltd.
    Inventors: Katsumi Mabuchi, Tomoko Kikuchi, Yasunobu Kani, Tsuneo Nakamura, Shinichi Yokosuka
  • Publication number: 20040011667
    Abstract: This invention relates to a process for the derusting or removal of corrosion products form ferrous metal substrates by electrochemical treatment.
    Type: Application
    Filed: June 17, 2003
    Publication date: January 22, 2004
    Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESEARCH
    Inventors: Nerur Sankaranayan Rengaswamy, Sironmani Palraj, Gopalan Subramanian, Thirupathisaram Muthukrishna Balasubramanian
  • Patent number: 6506294
    Abstract: A process for regeneration of electrolytes, in particular Na2SO4, from waste pickles created during picking of stainless steel, in particular stainless steel strips. The electrolytes are regenerated by adding NaxHySzOv in an acid solution whereby Cr6+ is reduced to Cr3+. Variables x, y, z and v having the following values: x=0 to 2, y=0 to 2, z=1 to 6, v=2 to 6.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: January 14, 2003
    Assignee: Andritz-Patentverwaltungs-Gesselschaft m.b.H.
    Inventors: Jovan Starcevic, Edgar Braun
  • Publication number: 20020033344
    Abstract: The electrodes have jet openings which jet the electrolyte to the steel strip, that is to say, the electrode is integrated with the nozzle which jets an electrolyte.
    Type: Application
    Filed: October 18, 2001
    Publication date: March 21, 2002
    Applicant: Hitachi, Ltd.
    Inventors: Katsumi Mabuchi, Tomoko Kikuchi, Yasunobu Kani, Tsuneo Nakamura, Shinichi Yokosuka
  • Patent number: 6203691
    Abstract: A method and apparatus for cleaning conductive bodies using a basic aqueous disodium phosphate and sodium bicarbonate electrolyte. The outside surfaces of a metallic body is cleaned by placing the body in contact with the electrolyte and flowing DC current from an anode to the body, which forms a cathode. The body may be immersed in the electrolyte or the electrolyte may be sprayed onto the body.
    Type: Grant
    Filed: September 18, 1998
    Date of Patent: March 20, 2001
    Assignee: Hoffman Industries International, Ltd.
    Inventors: John E. Hoffman, Jr., Richard A. Hoffman, Sr.
  • Patent number: 6045686
    Abstract: A process for the delacquering and detinning of a metal substrate is presented comprising the fully electrochemical removal of both an outer polymeric coating and an inner tin coating from a metal substrate. The disclosed method provides a clean metal substrate, and results in wastes which are easily disposed of with minimal cost and minimal environmental impact. In one embodiment, the present invention comprises a one-stage process for removing an outer polymeric coating and an inner tin coating from a metal substrate in a single electrolyte bath through electrolytic removal of both the polymeric and tin layers from the metal substrate. An electrically conductive container having the electrolyte bath therein acts as an anode in the process, and the removed tin is plated out on the cathode. In another embodiment, the present invention comprises a two-stage process for removing an outer polymeric coating and an inner tin coating from a metal substrate.
    Type: Grant
    Filed: December 15, 1997
    Date of Patent: April 4, 2000
    Assignee: The University of Connecticut
    Inventors: James M. Fenton, John E. Dresty, Jr., Richard Bodensteiner, Chunzhi He, Ramakrishnan Venkataraman, Jung-Chou Lin, Antonio J. Aldykiewicz, Jr.
  • Patent number: 6042713
    Abstract: A device and method for removing metal or mineral deposits from surfaces (eg. surfaces of oil drilling equipment) by creating an electrochemical cell of which the contaminated surface is a part.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: March 28, 2000
    Inventor: Richard Keatch
  • Patent number: 6030519
    Abstract: A method of electrolytically separating a paint coating from a metal surface comprising the steps of providing a metal member having a surface having a paint coating thereon and contacting the member with an essentially neutral electrolytic solution. The metal member is made cathodic in an electrolytic cell and current is passed from an anode electrode pad through the electrolytic solution to the metal member for a time sufficient to cause the paint coating to separate from the metal member. The pad is comprised of a first blanket for contacting the paint coating, a second blanket to cover the first blanket and an electrode mesh positioned between the first and second blankets.
    Type: Grant
    Filed: July 6, 1998
    Date of Patent: February 29, 2000
    Inventors: Rudolf Keller, Brian J. Barca, Daniel M. Hydock
  • Patent number: 5981084
    Abstract: An electrolytic process for cleaning the surface of a workpiece of an electrically conducting material, which process comprises:i) providing an electrolytic cell with a cathode comprising the surface of the workpiece and an inert anode;ii) introducing an electrolyte into the zone created between the anode and the cathode by causing it to flow under pressure through at least one opening in the anode and thereby impinge on the surface of the cathode, the surface of the cathode not otherwise being immersed in the electrolyte; andiii) applying a voltage between the anode and the cathode and operating in a regime in which the electrical current decreases or remains substantially constant with increase in the voltage applied between the anode and the cathode, and in a regime in which gas bubbles are present on the surface of the workpiece during treatment.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: November 9, 1999
    Assignee: Metal Technology, Inc.
    Inventors: Vitalij M. Riabkov, Valerij L. Steblianko
  • Patent number: 5938913
    Abstract: Process for electrolytic treatment of continuous running material in which the material runs through an electrolytic liquid and electric potential is applied to the material. In order to guarantee freedom from differential potential in the material to be treated in any form of electrolytic treatment, the differential potential in the treated material is measured after electrolytic treatment and at least the same degree of inverse compensating potential is applied to the material.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: August 17, 1999
    Assignee: Andritz-Patentverwaltungs-Gesellschaft m.b.H.
    Inventors: Jovan Starcevic, Karl Siegmund
  • Patent number: 5916431
    Abstract: During filtration, periodic application of a potential difference between an electrically conducting filter medium and counter electrode (as anode) generates a gaseous product at the filter and cleans the filter. To minimise corrosion the counter electrode is of low chromium stainless steel, for example 9% chromium.
    Type: Grant
    Filed: November 10, 1994
    Date of Patent: June 29, 1999
    Assignee: AEA Technology plc
    Inventors: Andrew Derek Turner, Ronald Keith Dawson
  • Patent number: 5814204
    Abstract: The invention relates to processes of decontaminating by electrochemical attack, a metal workpiece or solution contaminated with one or more metal oxides. A metal workpiece or solution contaminated with one or metal oxides is mixed or exposed to a solution including hydrazide ions to complex metal ions of the metal oxides with hydrazide ions. The metal workpiece or an anode is connected to a positive terminal of means for providing direct current. A cathode is disposed away from the metal workpiece in the solution including metal ions complexed with hydrazide ions and connecting the cathode to a negative terminal of means for providing direct current. DC current is conducted from the metal workpiece through the solution including metal ions complexed with hydrazide ions to the cathode. The solution or workpiece is decontaminated by plating out the metal ion as a metal at the cathode thereby removing the metal oxides from the metal workpiece or solution.
    Type: Grant
    Filed: October 11, 1996
    Date of Patent: September 29, 1998
    Assignee: Corpex Technologies, Inc.
    Inventor: Thomas F. D'Muhala
  • Patent number: 5800694
    Abstract: The invention concerns a process for pickling material strips made of steel, in particular stainless steel, where the strip passes through at last one pickling bath with at least one pickling acid. It is above all characterized by the fact that the acid concentration and/or the acid composition is controlled as a function of the material quality, of the pre-treatment and of the operating parameters of the pickling plant. Furthermore, the invention concerns a plant for carrying out the process, where at least two circulation tanks having different acid concentrations and/or acid compositions are provided.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: September 1, 1998
    Assignee: Andritz-Patentverwaltungs-Gesellschaft m.b.H.
    Inventors: Jovan Starcevic, Erich Mahr
  • Patent number: 5786556
    Abstract: A method and a device for performing the method of electrolytic pickling of a metal strip. The metal strip continuously passes through an electrolyte bath which has an electrolyte circulating through a closed system. Crevices are formed on both sides of the metal with electrodes which are located above the top crevice and below the bottom crevice. The electrodes are of opposite polarity and are chemically resistant to the electrolyte. An electrical current is passed from one electrode, through one crevice, through the metal, through the other crevice and to the other electrode which results in the electrolytic pickling of the metal.
    Type: Grant
    Filed: November 9, 1995
    Date of Patent: July 28, 1998
    Assignee: Swedish Pickling AB
    Inventors: Conny Gronlund, Kaj Gronlund
  • Patent number: 5670041
    Abstract: A method for minimizing localized corrosion of fluid containers that occurs as a consequence of most non-chemical procedures for removing scale deposits is described. It counteracts the unavoidable side-effect of the lowering of the local pH in the vicinity of the bubbles of CO.sub.2 that are generated during an electromagnetically-induced controlled precipitation procedure. The method is a simple and facile procedure for curbing the localized corrosion occurring as a result of most non-chemical procedures for removing scales. The method is desirably performed by an induction coil wrapped around a fluid container such as a pipe encrusted with scale through which hard water is flowing. A pulsing electrical current is successively applied through the coil and halted, preferably for 3 to 10 minutes each. When the current is applied, a transitory induced magnetic field is generated in the solution, and scale encrusted on the fluid container dissolves in the solution.
    Type: Grant
    Filed: October 17, 1995
    Date of Patent: September 23, 1997
    Assignees: Electronic De-Scaling 2000,Inc., Drexel University
    Inventors: Young I. Cho, Karl M. Kyriss
  • Patent number: 5545311
    Abstract: An electrically conducting filter medium (20) is cleaned in situ by applying, at intervals, a brief voltage pulse between the medium (20) and a counter electrode (18) so the process liquid undergoes electrolysis. The cleaning process is significantly improved by occasionally applying a voltage of reverse polarity. For example a 5 second cleaning pulse making the filter medium (20) cathodic might be applied every quarter of an hour, and a reverse polarity pulse of similar duration applied every two hours. This process can significantly increase permeation rates.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: August 13, 1996
    Assignee: United Kingdom Atomic Energy Authority
    Inventor: Mark D. Neville
  • Patent number: 5507926
    Abstract: Disclosed is a method of electrolytically separating a paint coating front a metal surface comprising the steps of providing a metal member having a surface having a paint coating thereon and contacting the member with an essentially neutral electrolytic solution. The metal member is made cathodic in an electrolytic cell and current is passed from an anode through the electrolytic solution to the metal member for a time sufficient to cause the paint coating to separate from the metal member.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: April 16, 1996
    Assignee: EMEC Consultants
    Inventors: Rudolf Keller, T. David Burleigh, Daniel M. Hydock
  • Patent number: 5490908
    Abstract: A method for processing stainless steel strip or sheet provides for cleaning the surface of the stainless steel with a solution selected from the group consisting of water and alkaline-based and acid-based compounds to reduce oxide scale formation and to provide more uniform oxide scale during subsequent annealing by transverse-flux induction heating up to an annealing temperature of about 2300 degrees Fahrenheit and then electrolytically descaling by immersing in an aqueous solution electrolyte of one neutral salt, preferably, sodium sulfate maintained at a temperature in excess of 150 degrees Fahrenheit and with the use of low current density of 0.1 to 1.0 amperes per square inch to descale the steel substantially entirely, and thereafter applying a water rinse combined with wet wiping to the electrolytically-descaled stainless steel.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: February 13, 1996
    Assignee: Allegheny Ludlum Corporation
    Inventors: Yeong-U Kim, Donald R. Zaremski, Carol S. Hertzler