With Acid Or Alkali Patents (Class 208/183)
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Patent number: 11260439Abstract: The invention relates to an aluminum alloy strip with improved surface optics, which is fabricated via hot and/or cold rolling, and consists of a type AA 3xxx, AA 5xxx, AA 6xxx or AA 8xxx aluminum alloy. The object of proposing an aluminum alloy strip that is suitable for attractive and precious surface optics despite the elevated percentage of alloy constituents is achieved in that, after degreasing, the finish-rolled aluminum alloy strip exhibits an increase in the luminance value L*(?L) in relation to the rolled-greasy state of more than 5 while measuring the color of the surface in the CIE L*a*b* color space using a standard illuminant D65 and a normal observation angle of 10°, excluding direct reflection in 45°/0° geometry.Type: GrantFiled: July 31, 2014Date of Patent: March 1, 2022Assignee: Hydro Aluminium Rolled Products GmbHInventors: Dieter Bögershausen, Jochen Schwarz, Bernhard Kernig, Kathrin Eckhard, Axel Blecher, Olaf Güßgen
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Patent number: 9006504Abstract: Methods for converting petroleum based oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to petroleum based oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.Type: GrantFiled: July 10, 2013Date of Patent: April 14, 2015Assignee: OTG Research, LLCInventor: Philip Allen Boe
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Patent number: 8859833Abstract: Methods and system for obtaining long chain carbons that generally include forming a conversion mixture of an alcohol and a base, adding the conversion mixture to oil (such as petroleum based oil, crude oil, used oil, used motor oil, and new motor oil) to form a reaction mixture, adding a high nitrate compound the reaction mixture, and separating out the long chain carbons for use as an input by other processing such as pharmaceutical and/or additional petro-chemical processing. Additional cooling and/or filtering processes may be utilized to complete and/or optimize oil conversion.Type: GrantFiled: April 12, 2013Date of Patent: October 14, 2014Inventor: Philip Allen Boe
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Patent number: 8492601Abstract: Methods for converting used oil into fuel generally include forming a conversion mixture of an alcohol and a base, and adding the conversion mixture to used oil, such as used motor oil, to form a reaction mixture. The methods can also include adding a high nitrate compound and an amino acid to the reaction mixture and ozonizing the reaction mixture. The result of the methods can include a three phase system in which the bottom phase is asphalt oil, the middle phase is diesel fuel or jet fuel, and the top phase is sulfuric acid. The three phases can be separated to obtain the final diesel fuel or jet fuel product.Type: GrantFiled: April 12, 2012Date of Patent: July 23, 2013Assignee: OTG Research, LLCInventor: Philip Allen Boe
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Patent number: 8193111Abstract: One exemplary embodiment can be a process for desorbing an adsorbent bed. The process can include passing a desorbent stream through the adsorbent bed to remove at least one of a nitrile compound and an oxygenate compound. Generally, the desorbent stream after desorbing is combined with a feed stream for an alkylation zone after a selective hydrogenation zone.Type: GrantFiled: July 24, 2009Date of Patent: June 5, 2012Assignee: UOP LLCInventors: Gavin P. Towler, Charles P. Luebke, David N. Myers, Steven L. Krupa
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Patent number: 7381309Abstract: Disclosed is an apparatus for extracting sulfur compounds from a hydrocarbon stream. A prewash section for converting hydrogen sulfide to sodium sulfide by reaction with an alkali such as caustic prepares the hydrocarbon stream for extraction. Spent alkali is continuously withdrawn and regenerated alkali is continuously added to the prewash section.Type: GrantFiled: December 17, 2003Date of Patent: June 3, 2008Assignee: UOP LLCInventors: Luigi Laricchia, Jonathan A. Tertel
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Publication number: 20080073249Abstract: A method of and system for reducing engine environmental atmospheric pollution emissions from a vehicle having a combustion engine utilizing hydrocarbon fuel for at least one of propulsion and auxiliary electrical power is disclosed. The method basically includes providing an unprocessed bulk fuel storage container and a clean processed fuel tank on the vehicle, supplying the engine for propulsion with fuel from the unprocessed fuel storage container when the vehicle is beyond a predetermined distance from an area having environmental restrictions passing a portion of unprocessed fuel through a desulphurization process to fill a clean fuel storage container while the vehicle is in motion and supplying the combustion engine for one of propulsion and auxiliary electrical power from clean fuel in the processed fuel storage container when the vehicle is within an area having environmental restrictions.Type: ApplicationFiled: April 10, 2007Publication date: March 27, 2008Applicant: INTELLIGENT ENERGY, INC.Inventors: Kandswamy Duraiswamy, Anand Chellappa
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Patent number: 7267760Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.Type: GrantFiled: January 2, 2001Date of Patent: September 11, 2007Inventors: Jeffrey H. Sherman, Richard T. Taylor
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Patent number: 7208079Abstract: A process for the treatment of waste oil comprises the steps of (a) supplying a stream of the waste oil to a dehydrator to dehydrate the waste oil and obtain a stream of dehydrated waste oil; (b) supplying the stream of dehydrated waste oil to a fractionated distillation column having a lower tray, an upper tray and a middle tray therebetween, wherein the lower tray is operated at a temperature of 370 to 390° C. under a sub-atmospheric pressure of 50 to 100 mmHg, the middle tray is operated at a temperature of 265 to 280° C. under a sub-atmospheric pressure of 35 to 45 mmHg and the upper tray is operated at a temperature of 100 to 110° C. under a sub-atmospheric pressure of 30 to 40 mmHg; (c) withdrawing from the distillation column a bottom product comprising a bituminous material; (d) withdrawing a first side stream from the distillation column between the first and second trays, the first side stream comprising a heavy oil having a viscosity of 130 to 180 cSt at 40° C.Type: GrantFiled: March 3, 2003Date of Patent: April 24, 2007Inventor: Nouredine Fakhri
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Patent number: 6929737Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.Type: GrantFiled: January 2, 2001Date of Patent: August 16, 2005Assignee: Miami UniversityInventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
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Patent number: 6398948Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.Type: GrantFiled: September 18, 2000Date of Patent: June 4, 2002Assignee: Miami UniversityInventors: Jeffrey H. Sherman, Richard T. Taylor
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Patent number: 6372122Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is coalesced to remove any remaining solvent therefrom, with the recovered solvent being reused.Type: GrantFiled: August 1, 2000Date of Patent: April 16, 2002Assignee: Avista Resources, Inc.Inventor: William A. Gorman
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Patent number: 6338792Abstract: A novel liquid collector assembly has been developed for a reactor used in the sweetening of sour hydrocarbons (e.g. sour gasoline). This refinery process normally involves contacting a reaction liquid, comprising both aqueous (caustic solution) and organic (hydrocarbon) phases, with a fixed bed of oxidation catalyst. The collector assembly design, comprising a piping manifold and a plurality of dependent, vertically aligned, and perforated conduits, allows for improved separation of the reaction products into essentially pure treated hydrocarbon and spent alkaline reagent streams. If sodium hydroxide is used as caustic solution, for example, the treated hydrocarbon product will normally contain less than 1 ppm by weight of sodium.Type: GrantFiled: April 24, 2000Date of Patent: January 15, 2002Assignee: UOP LLCInventor: Luigi Laricchia
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Publication number: 20010022281Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.Type: ApplicationFiled: January 2, 2001Publication date: September 20, 2001Inventors: Jeffrey H. Sherman, Richard T. Taylor
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Patent number: 6270678Abstract: The present invention relates to a method of treating alkaline waste water originating from washing spent oil which has undergone an alkaline treatment with water and which contains organic material. This method can produce water which can be discharged into conventional industrial water treatment facilities or which can be used directly as a base for preparing fertilizers or for preparing an agent for preventing ice formation on road surfaces.Type: GrantFiled: March 21, 2000Date of Patent: August 7, 2001Inventor: Bernard Chavet
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Patent number: 6238551Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.Type: GrantFiled: December 17, 1999Date of Patent: May 29, 2001Assignee: Miami UniversityInventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
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Publication number: 20010001198Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from petroleum distillates, phase transfer catalyst is employed to facilitate the transfer of inorganic or organic bases to the substrate of the distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation. A solvent is then mixed with the resulting distillate to extract contaminants therefrom. The solvent is recovered and distilled to separate the contaminants therefrom, and is then reused. The petroleum distillate having the contaminants separated therefrom is also distilled to remove any remaining solvent therefrom, with the recovered solvent being reused.Type: ApplicationFiled: January 4, 2001Publication date: May 17, 2001Applicant: Miami UniversityInventors: Jeffrey H. Sherman, Richard T. Taylor, Amanda L. Hofacker, James W. Hershberger, Garrett M. Conn, William A. Gorman
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Patent number: 6179999Abstract: In a method of removing acidic compounds, color, and polynuclear aromatic hydrocarbons, and for removing or converting hydrocarbons containing heteroatoms from used oil distillate, phase transfer catalysts are employed to facilitate the transfer of inorganic or organic bases to the substrate of the oil distillate. An inorganic or organic base, a phase transfer catalyst selected from the group including quaternary ammonium salts, polyol ethers and crown ethers, and used oil distillate are mixed and heated. Thereafter, contaminants are removed from the used oil distillate through distillation.Type: GrantFiled: October 15, 1999Date of Patent: January 30, 2001Assignee: Miami UniversityInventors: Jeffrey H. Sherman, Richard T. Taylor
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Patent number: 6174431Abstract: A method for pretreating and re-refining used oil that requires only moderate heat and only one re-refining step. The pretreatment involves mixing the used oil with a basic solution and optionally a phase transfer catalyst. The phase transfer catalyst aids the chemical reaction which allows removal of impurities in used oil. The basic solution preferably includes more than one base. The used oil, basic solution and phase transfer catalyst are mixed under low heat. The pretreated oil is then mixed with liquid propane in a non-turbulent manner, such as by use of a globe valve or orbit valve. The mixture of used oil and liquid propane are then placed into an extraction vessel and impurities are allowed to settle out of the oil and propane mixture. Heavy fraction may be removed from the extraction vessel. Preferably, a second vessel called a settling vessel will be used to cause further settling of impurities out of the used oil. Light fraction is produced which may be re-refined to produce base oil.Type: GrantFiled: May 26, 1999Date of Patent: January 16, 2001Assignee: Interline Hydrocarbon, Inc.Inventors: Michael R. Williams, Jan Krzykawski
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Patent number: 6059976Abstract: The present invention is a process for reclaiming and recycling oil/water mixtures. These mixtures are preferably hot or cold rolling oils for aluminum manufacturing operations. When used, the rolling oils contain organometallic particles and have less constituents than the unused oils. The present process enables the valuable portion of the oil to be reused by passing through an acid wash and a reconstitution process.Type: GrantFiled: June 22, 1998Date of Patent: May 9, 2000Assignee: Kaiser Aluminum & Chemical CorporationInventors: Al J. Kovolick, Robert A. Dickinson, Michael A. Green
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Patent number: 5573656Abstract: A process for significantly decreasing the acid sludge settling time in waste oil recovery processes comprising the steps of heating used oil to a high temperature above 725 degrees Fahrenheit, cooling the heated oil, adding an oxidizing agent to the oil, allowing the acid sludge to settle within a period of approximately 24 to 72 hours, separating the acid-sludge-free oil from the acid sludge which settles out of solution as a result of addition of the oxidizing agent, and adding a polishing agent and separating the re-refined oil from the spent polishing agent. The spent polishing agent is recycled, and the acid sludge which settles out after oxidation is converted to either hard, oxidized asphalt or soft asphalt or asphalt products such as emulsions etc. The process produces a high quality re-refined oil rapidly and economically with no acid sludge disposal problem.Type: GrantFiled: February 16, 1994Date of Patent: November 12, 1996Inventor: Benjamin Santos
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Patent number: 5470455Abstract: A process for converting the acid sludge produced by waste oil refineries into an intermediate sludge which can be used in the production of either soft, un-oxidized asphalt or hard, oxidized asphalt, and a process for converting the intermediate sludge into soft, un-oxidized asphalt. The process comprises contacting the entire surface area of acid sludge with a pH altering agent such as water or a solid base such as lime, caustic soda, or soda ash, to convert the acid sludge into a layer of liquid and a layer of intermediate sludge. Then the liquid layer is separated from the intermediate sludge layer, thereby producing an intermediate sludge having properties which make it suitable for use in asphalt production. To produce soft, un-oxidized asphalt, the intermediate sludge is heated to a temperature above the boiling point of water and held at that temperature long enough to remove all the aqueous components to create un-oxidized asphalt.Type: GrantFiled: February 17, 1994Date of Patent: November 28, 1995Inventor: Benjamin S. Santos
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Patent number: 5288392Abstract: A process for converting the acid sludge produced by waste oil refineries into an acid sludge intermediary which can be used in the production of asphaltic mixtures. The process includes contacting the entire surface area of acid sludge with a pH altering agent such as an aqueous inorganic liquid, and separating the liquid layer from the sludge layer, thereby producing an intermediate sludge having properties which make it suitable for use in asphalt production.Type: GrantFiled: May 7, 1992Date of Patent: February 22, 1994Inventor: Benjamin S. Santos
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Patent number: 5225081Abstract: Used lubricating oils can be rejuvenated by passing the oil through a filter system comprising a hollow solid composite that contains a thermoplastic binder and an active filter media of a chemically active filter media, a physically active filter media, or mixtures thereof. In a preferred embodiment, the composite is formed by forcing a substantially uniform mixture of thermoplastic binder particles, active filter media particles, solvent 600 Neutral base oil, and sodium stearate through an extrusion die of substantially uniform cross-section, wherein the mixture is subjected to heat, pressure, and cooling to consolidate the mixture so that it emerges from the die as a hollow solid composite. Most preferably, the composite will surround an inactive filter media located within the filter system.Type: GrantFiled: June 25, 1991Date of Patent: July 6, 1993Assignee: Exxon Research and Engineering Co.Inventor: Darrell W. Brownawell
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Patent number: 5209839Abstract: NaOH can be used to remove hydroperoxides from a lubricating oil provided the oil contains a metal thiophosphate. This extends the useful life of the oil and the equipment being lubricated. In a preferred embodiment, the NaOH is immobilized within the lubrication system of an internal combustion engine.Type: GrantFiled: March 5, 1992Date of Patent: May 11, 1993Assignee: Exxon Research and Engineering Co.Inventors: Harold Shaub, Darrell W. Brownawell, Arthur DiBenedetto
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Patent number: 5075044Abstract: According to the invention, the oil is passed through a pulverulent material, such as an earth or clay, in the presence of an acid. The pulverulent material can be placed beforehand on a filter or can be mixed with the oil before filtration. If necessary, the oil is recycled through the filter up to complete decontamination.Application to the radioactive decontamination of oils used in the nuclear industry.Type: GrantFiled: June 30, 1987Date of Patent: December 24, 1991Assignee: Electricite de France Service InternationalInventor: Jean-Michel Augem
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Patent number: 5069799Abstract: A filter system containing, in series, a first filter media having a chemically active filter media, a physically active filter media, or mixtures thereof and a second filter media having an inactive filter media can effectively rejuvenate used lubricating oils. In a preferred embodiment, the chemically or physically active filter media will be within a cannister that is separate from a container having both active and inactive filter media.Type: GrantFiled: September 7, 1989Date of Patent: December 3, 1991Assignee: Exxon Research & Engineering CompanyInventors: Darrell W. Brownawell, Paul K. Ladwig
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Patent number: 4997546Abstract: Hydroperoxides can be removed from a lubricating oil by contacting the oil with a heterogenous hydroperoxide decomposer. This extends the useful life of the oil and the equipment being lubricated. In a preferred embodiment, the hydroperoxide decomposer is incorporated on a substrate immobilized within the lubrication system of an internal combustion engine.Type: GrantFiled: September 7, 1989Date of Patent: March 5, 1991Assignee: Exxon Research and Engineering CompanyInventors: Harold Shaub, Darrell W. Brownawell, Arthur DiBenedetto
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Patent number: 4925597Abstract: In a process for decontaminating radioactively polluted lubricant oil, (a) the lubricant oil to be decontaminated is mechanically filtered, (b) an acid solution of the salts of the elements, the radionuclides of which are to be removed, is added, and (c) a dose of a precipitating agent that cooperates with the elements, the radionuclides of which are to be removed, producing a salt of low solubility, is added, (d) the acid salt solution is intimately mixed with the lubricant oil after step (b), (e) the depositing aqueous phase is discharged after step (b), before step (c), (f) additional intimate mixing is carried out after the dosed admixture of step (c), and (g) finally the precipitation products are separated by centrifugation from the lubricant oil.Type: GrantFiled: October 12, 1988Date of Patent: May 15, 1990Inventor: Martin Ganter
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Patent number: 4808299Abstract: A process for removing copper and/or iron impurities from a liquid hydrocarbon-containing feed comprises contacting the feed with an aqueous treating agent comprising water-soluble alkali metal silicate (in particular sodium silicate) and/or a surfactant, in particular an anionic surfactant.Type: GrantFiled: April 14, 1988Date of Patent: February 28, 1989Assignee: Phillips Petroleum CompanyInventors: Edward G. Latimer, Richard W. Jones
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Patent number: 4615794Abstract: A method of removing radioactive waste from oil in which all particulates, radioactive contaminants, and moisture are removed from the oil. Particulate matter is removed from the oil by a combination of filtering and heating. Radioactive contaminants are reacted with chlorine to form salts which are removed by filtration. Moisture is removed by use of a flash tank.Type: GrantFiled: August 20, 1984Date of Patent: October 7, 1986Inventor: Roger L. Belanger
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Patent number: 4614597Abstract: A process for recovering oil containing dissolved alkaline earth metal sulfonate from siliceous filter cakes containing such oils by mixing the filter cake with sufficient 0.5 to 16N sulfuric acid or phosphoric acid to bring the pH of the mixture to a level in the range about 2 to 7, settling the acid-filter cake mixture to separate an upper oil-sulfonate phase and recovering the upper phase.Type: GrantFiled: December 17, 1984Date of Patent: September 30, 1986Assignee: Claypro U.S.A.Inventors: Frank A. Stuart, William H. Tyson, Jr.
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Patent number: 4544491Abstract: A process for recovering hydrocarbon oils and hydrocarbon oils containing dissolved additives from filter cakes produced by filtering such oils using a siliceous filter aid.A small amount of a release agent, up to 2 cc per gram of filter cake, is slowly added to the filter cake with agitation to prevent formation of a release agent phase and then a further quantity of release agent is added to the resultant mixture with gentle stirring and the final mixture is then held quiescent at elevated temperature until an oil phase separates. The oil phase is removed and the remainder of the mixture is filtered to separate a release agent filtrate and a filter cake consisting mainly of filter aid.Type: GrantFiled: August 24, 1983Date of Patent: October 1, 1985Assignee: Claypro AssociatesInventors: William H. Tyson, Frank A. Stuart
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Patent number: 4502948Abstract: A method for purifying used oil without the use of hydrogen comprising contacting a demetallized used oil with an acid such as sulfuric acid and an adsorbent such as clay.Type: GrantFiled: March 30, 1984Date of Patent: March 5, 1985Assignee: Phillips Petroleum CompanyInventor: Donald C. Tabler
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Patent number: 4432865Abstract: A process for treating used motor oil or synthetic crude oil comprising: (i) contacting said used motor oil or synthetic crude oil with an effective amount of (A) a polyfunctional mineral acid and/or the anhydride of said acid and (B) a polyhydroxy compound to react undesired contaminants contained in said used motor oil or synthetic crude oil with components (A) and/or (B) to form one or more reaction products; and (ii) separating said reaction products from said used motor oil or synthetic crude oil. A process for reclaiming used motor oil is also disclosed.Type: GrantFiled: December 8, 1982Date of Patent: February 21, 1984Inventor: George R. Norman
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Patent number: 4431524Abstract: A process for rerefining used industrial oil comprising the steps of: (i) contacting said oil with an aqueous solution of the basic salt of an alkali metal to precipitate metal contaminants, polar compounds or particulates from said oil and to neutralize acid that may be present in said oil; (ii) separating bulk water and solid contaminants from said oil; (iii) separating fine particulates and remaining suspended water from said oil; (iv) vacuum drying said oil at a temperature in the range of about 250.degree. F. to about 400.degree. F. and a pressure in the range of about 2 to about 50 torr to remove dissolved water and light hydrocarbons from said oil; (v) contacting said oil with (A) from about 0.1 to about 3% by weight based on the weight of said oil of a polyfunctional mineral acid or the anhydride of said acid and (B) from about 0.Type: GrantFiled: January 26, 1983Date of Patent: February 14, 1984Inventor: George R. Norman
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Patent number: 4383915Abstract: A process is provided for removing contaminants from waste lubricating oil. The previously untreated waste oil is contacted with decolorizing clay and the mixture is heated to and retained for a period of time at a temperature in the range of about 650.degree.-725.degree. F., to render the mixture filterable. The product clay-oil mixture is cooled and filtered to produce an oil filtrate reduced in contaminants. The clay contacting step may optionally be performed in a hydrogen atmosphere. The oil product can be used for non-critical uses or further upgraded by conventional methods.Type: GrantFiled: January 15, 1982Date of Patent: May 17, 1983Assignee: Turbo Resources Ltd.Inventor: Conrad B. Johnson
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Patent number: 4256578Abstract: Oil, used as a lubricant and coolant in an industrial process, may become contaminated by foreign materials, for example, water and solid particulate. Because of its cost, continued use of the oil is desirous but impossible if the foreign materials are not removed when the concentration of such becomes excessive. By heating the contaminated oil and adding a chemical agent such as an alkaline solution of sodium metasilicate, the oil may be selectively separated from its contaminants allowing its further use.Type: GrantFiled: November 29, 1979Date of Patent: March 17, 1981Assignee: AMSTED Industries IncorporatedInventor: Robert S. Kozar
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Patent number: 4252637Abstract: A process for the reprocessing of used lubricating oil wherein said oils are treated with a mixture of potassium hydroxide and sodium hydroxide.Type: GrantFiled: April 18, 1979Date of Patent: February 24, 1981Assignee: Deutsche Gold und Silber-Scheideanstalt vormals RoesslerInventors: Helmut Knorre, Manfred Langer, Axel Waniorek
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Patent number: 4144162Abstract: A method for the solidification and containment of sludge from an oil reclaiming process to permit environmentally safe storage disposal of the sludge and particularly electric transformer oil containing PCB's. In the process, the sludge or oil is mixed with fuller's earth in a weight ratio of at least 40:60 of fuller's earth to sludge or oil. The fuller's earth has a particle size not greater than -4 mesh to 0 mesh range and a moisture content of less than 12%. The mixture is allowed to harden to a paste like solid material and conveyed to a conventional land fill storage disposal site.Type: GrantFiled: September 1, 1977Date of Patent: March 13, 1979Assignee: Mid-Florida Mining Co.Inventors: Allen C. Edgar, George N. Smith
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Patent number: 4097369Abstract: A process for reclaiming used hydrocarbon oils through prepurification by means of coagulation, adsorption, filtration, distillation, and after-treatment, wherein said oils are prepurified and then dehalogenated, fractionally distilled and hydrogenated. It is preferred that for the prepurification, said coagulation and said adsorption are carried out by means of a hydroxide or hydroxide mixture, preferably aluminum and/or ferric hydroxide, in a proportion of 0.5 - 5.0% by weight, preferably 1-2% by weight, of hydroxide relative to said used oil at a reaction temperature of from 20.degree. - 200.degree. C, preferably from 50 to 150.degree. C, said hydroxide or hydroxides being produced directly in said used oil in the presence of water or being introduced into said used oil in the form of an aqueous slurry.Type: GrantFiled: February 27, 1976Date of Patent: June 27, 1978Assignee: Adolf Schmids Erben AktiengesellschaftInventors: Eckhard Ebel, Hans-Rudolf Kobel, Ernst Widmer
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Patent number: 3954602Abstract: A process for cleaning a used oil, in particular engine oil and industrial lubricating oil. The process comprises heat treating the used oil in a heat treatment zone at a temperature of 325.degree.-400.degree.C at a pressure of 1-6 bars for a period of at least 15 minutes, continuously withdrawing a first part of the treated oil from the heat treatment zone, re-heating said first part of the oil and recycling the re-heated first part of the oil through the heat treatment zone, subjecting the remainder of the heat treated oil from the heat treatment zone to a treatment for separating out the sedimentary residues from the heat treated oil. The sedimentary residues are incinerated in the re-heating furnace for re-heating said first part. A system is described for carrying out the process.Type: GrantFiled: February 20, 1974Date of Patent: May 4, 1976Assignee: Societe Parisienne des Lubrifiants Nationaux et des Entrepots d'HydrocarburesInventors: Andre Troesch, Fernand Cleron
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Patent number: RE31267Abstract: A method for the solidification and containment of sludge from an oil reclaiming process to permit environmentally safe storage disposal of the sludge and particularly electric transformer oil containing PCB's. In the process, the sludge or oil is mixed with fuller's earth in a weight ratio of at least 40:60 of fuller's earth to sludge or oil. The fuller's earth has a particle size not greater than -4 mesh to 0 mesh range and a moisture content of less than 12%. .[.The mixture is allowed to harden to a paste like solid material and conveyed to a conventional land fill storage disposal site..].Type: GrantFiled: March 12, 1981Date of Patent: June 7, 1983Assignee: Mid-Florida Mining CompanyInventors: Allen C. Edgar, George N. Smith