Aromatic Patents (Class 208/335)
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Patent number: 6303021Abstract: The improved process and apparatus of the present invention for extracting high purity aromatics from gasoline using a glycol solvent based extraction process decrease liquid-vapor flashing, reduce reflux flow rate, and use heat of enthalpy produces at one point as a source of energy used at another point, decreasing energy consumption while significantly increasing purity and amount of product obtained.Type: GrantFiled: December 12, 2000Date of Patent: October 16, 2001Assignee: Denim Engineering, Inc.Inventors: George Winter, Zvi Merchav
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Patent number: 6146520Abstract: A process for reducing the Mutagenicity Index and/or the PCA content of a lubricating oil extract by re-extracting a lubricating oil extract with a second extraction solvent, different from the first extraction solvent, to form a secondary raffinate and a secondary extract mix; separating the secondary raffinate from the secondary extract mix; and separating the secondary raffinate and the secondary extract from said second extraction solvent.Type: GrantFiled: April 2, 1997Date of Patent: November 14, 2000Assignee: Mobil Oil CorporationInventors: Anagha Avinash Gupte, David O. Marler
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Patent number: 5616238Abstract: The present invention is directed to an improved selective solvent extraction process wherein a hydrocarbon feed stream containing a mixture of aromatics and non-aromatics is contacted with an aromatics selective solvent in an extraction zone to produce an aromatics rich extract phase and an aromatics lean raffinate phase, water in a carefully controlled amount is added to the recovered extract phase resulting in the separation of the extract phase into a hydrocarbon rich pseudo-raffinate which is recycled to the extraction zone for processing with fresh feed and an increased yield of raffinate of higher quality than is obtained without pseudo-raffinate recycle.Type: GrantFiled: December 5, 1995Date of Patent: April 1, 1997Assignee: Exxon Research and Engineering CompanyInventors: Joseph P. Boyle, Adrianus Welmers
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Patent number: 5120900Abstract: Raffinate yield from solvent extraction is improved when the extract phase recovered from the solvent extraction process is subjected to a membrane separation step wherein a saturates/1-ring aromatics rich retentate is produced and a 2+ ring aromatics rich permeate are produced and the saturates/1-ring aromatic rich retentate phase is recycled to the solvent extraction process.Type: GrantFiled: December 5, 1990Date of Patent: June 9, 1992Assignee: Exxon Research and Engineering CompanyInventors: Tan-Jen Chen, James R. Sweet
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Patent number: 5095170Abstract: The yield, raffinate product quality, and throughput of the selective solvent extraction of hydrocarbon feeds is improved by subjecting the hydrocarbon feeds from which aromatic hydrocarbons are to be selectively solvent extracted to a membrane separation process which selectively permeates aromatics through the membranes to produce a permeate rich in aromatics and a retentate rich in saturates and 1-ring aromatics and subjecting this retentate to the selective solvent extraction process.Type: GrantFiled: December 5, 1990Date of Patent: March 10, 1992Assignee: Exxon and Research and Engineering CompanyInventors: Tan-Jen Chen, James R. Sweet
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Patent number: 5039399Abstract: A lubricating oil stock is extracted with N-methyl-2-pyrrolidone to yield a primary raffinate useful as a high VI lubricating base oil and a primary extract. The primary extract is mixed with antisolvent and chilled to yield a secondary raffinate. This secondary raffinate is sufficiently reduced in aromatics that it is solvent extracted to yield medium to high VI lubricating base oil.Type: GrantFiled: November 20, 1989Date of Patent: August 13, 1991Assignee: Texaco Inc.Inventor: Avilino Sequeira, Jr.
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Patent number: 4982049Abstract: A process for recovering diamondoid compounds from hydrocarbonaceous minerals and/or from deposits left by such minerals in equipment or otherwise, which comprises dissolving diamondoid compounds in an aromatic distillate fuel oil; extracting aromatics from the solution; and separating diamondoid compounds from the raffinate of the extraction.Type: GrantFiled: May 26, 1989Date of Patent: January 1, 1991Assignee: Mobil Oil Corp.Inventors: Richard A. Alexander, Charles E. Knight, Darrell D. Whitehurst
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Patent number: 4952749Abstract: A process for recovering diamondoid compounds from a fluid mixture thereof with other hydrocarbonaceous compounds which comprises contacting said mixture with a porous solid, for example, a zeolite, having pore opening large enough to admit said diamondoid compounds thereinto and small enough so that at least 50% of the external atoms of said diamondoid compounds are capable of simultaneously contacting the internal walls of the pores of said solid under conditions conducive to absorption of diamondoid compounds by said solid; and then desorbing the absorbate comprising diamondoid compounds from said solid absorbant.Type: GrantFiled: May 26, 1989Date of Patent: August 28, 1990Assignee: Mobil Oil Corp.Inventors: Richard A. Alexander, Charles E. Knight, Darrell D. Whitehurst
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Patent number: 4952748Abstract: A process is disclosed for extracting diamondoid compounds from a hydrocarbon gas stream. The process includes two stages, each of which alone is effective to remove diamondoids from a hydrocarbon gas stream. The first stage comprises contacting the diamondoid-laden hydrocarbon gas with a suitable solvent to preferentially dissolve the diamondoids into the solvent. Diesel fuel is the preferred solvent for this first stage. The second stage comprises sorbing diamondoids from the diamonoid-laden hydrocarbon gas with silica gel. The most preferred embodiment of the invention is a serial process in which a diamondoid-laden gas is first treated in the solvation stage and the partially purified gas is further resolved in the silica gel sorption stage. The invention still further includes a process for segregating adamantane and diamantane when both are separated from a hydrocarbon gas stream.Type: GrantFiled: September 7, 1989Date of Patent: August 28, 1990Assignee: Mobil Oil Corp.Inventors: Richard A. Alexander, Charles E. Knight
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Patent number: 4952747Abstract: According to this invention, substantially hydrocarbonaceous fractions comprising diamondoid compounds are peculiarly suitable for separation by a thermal gradient diffusion process. Applicability of this process to this service is dependent upon the fact that the diamondoid compounds exhibit a large change in viscosity relative to temperature, that is, their viscosity goes down significantly per degree of increase in temperature.Type: GrantFiled: May 26, 1989Date of Patent: August 28, 1990Assignee: Mobil Oil Corp.Inventors: Richard A. Alexander, Charles E. Knight, Darrell D. Whitehurst
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Patent number: 4381234Abstract: An improved solvent extraction process is described for the preparation of lube oil products, the improvement whereby the solvent contains an additive which facilitates phase separation and increases the yield of raffinate.Type: GrantFiled: November 21, 1980Date of Patent: April 26, 1983Assignee: Mobil Oil CorporationInventors: Costandi A. Audeh, Israel J. Heilweil, James R. White, Tsoung Y. Yan
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Patent number: 4304660Abstract: Lubricating oils suitable for use in refrigeration equipment in admixture with fluorinated hydrocarbon refrigerants are produced by solvent extraction of naphthenic lubricating oil base stocks, cooling the resulting extract mixture, optionally with the addition of a solvent modifier, to form a secondary raffinate and a secondary extract, and recovering a dewaxed oil fraction of lowered pour point from the secondary raffinate as a refrigeration oil product.The process of the invention obviates the need for a separate dewaxing operation, such as dewaxing with urea, as conventionally employed for the production of refrigeration oils.Type: GrantFiled: April 14, 1980Date of Patent: December 8, 1981Assignee: Texaco Inc.Inventors: Avilino Sequeira, Jr., Ralph P. Chesluk, Howard J. Platte
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Patent number: 4297206Abstract: An improvement in the solvent extraction of nonhydrocarbons from a synfuel liquid, e.g., shale oil, involves that the extract from the extractor, rather than being recycled directly back to the extractor, is first hydrotreated. A further improvement involves that a portion of the hydrotreated extract is fractionated and a light fraction is returned to the extractor. Use of the hydrotreated extract as recycle increases the efficiency of the extractor. A still further improvement involves the use as a selective solvent of one of the following: dialkylformamide, aldehydomorpholine, keto-morpholine, morpholine or an aliphatic aromatic ketone. These preferred solvents have the advantage of providing a clear interface between the extract and raffinate in the extractor. Removal of the nonhydrocarbons permits production of more hydrocarbons having enhanced utility as a jet fuel from a synfuel liquid than otherwise would be possible.Type: GrantFiled: February 1, 1980Date of Patent: October 27, 1981Assignee: Suntech, Inc.Inventor: Edward G. Scheibel