Using Electrical, Magnetic Or Wave Energy Patents (Class 208/402)
  • Patent number: 11926794
    Abstract: A continuous operation method is employed for the microwave high-temperature pyrolysis of a solid material containing an organic matter. The method includes the steps of mixing a solid material containing an organic matter with a liquid organic medium; transferring the obtained mixture to a microwave field; and in the microwave field, continuously contacting the mixture with a strong wave absorption material in an inert atmosphere or in vacuum. The strong wave absorption material continuously generates a high temperature under a microwave such that the solid material containing an organic matter and the liquid organic medium are continuously pyrolyzed to implement a continuous operation.
    Type: Grant
    Filed: September 27, 2019
    Date of Patent: March 12, 2024
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Haibin Jiang, Jinliang Qiao, Xiaohong Zhang, Wenlu Liu, Jianming Gao, Guicun Qi, Zhihai Song, Jinmei Lai, Chuanlun Cai, Binghai Li, Xiang Wang, Yue Ru, Hongbin Zhang, Peng Han, Jiangru Zhang, Chao Jiang, Zhaoyan Guo
  • Patent number: 11612872
    Abstract: Soot removal process at or inside a synthesis gas- and/or CO-containing gas production apparatus using as feed gases carbon dioxide, steam, hydrogen and/or a hydrocarbon-containing residual gas and using electrical energy in RWGS processes, electrolyses for electrochemical decomposition of carbon dioxide and/or steam, reforming operations and/or synthesis gas production processes with at least one gas production unit, an electrolysis stack and/or a heater-reactor combination for performing an RWGS reaction and at least one cooling sector/recuperator for CO-containing gas and/or synthesis gas, and also a soot removal assembly. Formation of soot can be suppressed or prevented during gas cooling and soot that is nevertheless deposited can be removed again from the heat exchanger surface.
    Type: Grant
    Filed: June 11, 2018
    Date of Patent: March 28, 2023
    Assignee: SunFire GmbH
    Inventors: Dietmar Rueger, Carl Berninghausen, Christian Klahn, Sebastian Becker, Robert Blumentritt
  • Patent number: 11412586
    Abstract: A radio frequency (RF) heating system and process for rapidly and uniformly heating a plurality of articles on a convey line.
    Type: Grant
    Filed: May 31, 2019
    Date of Patent: August 9, 2022
    Inventor: Harold Dail Kimrey, Jr.
  • Patent number: 11162031
    Abstract: A method for the pyrolysis of raw materials, especially raw materials deriving from tires or bitumen, includes the steps of feeding the material to be subjected to the pyrolysis process to a reactor; heating the material in the reactor at a temperature needed to establish the pyrolysis process; collecting the final products of the pyrolysis reaction; separating the gaseous, liquid and solid phases of the reaction products; and storing, for further treatment, the reaction products separate one from another. The heating in the pyrolysis process to the activation temperature is obtained by irradiating the raw material with laser radiation, concentrated or focused on a localized area of a pre-established surface area on the mass of raw material of the focusing area, and progressively moved along the entire surface of the mass of raw material to activate the pyrolytic reaction on all the mass of raw material.
    Type: Grant
    Filed: February 14, 2019
    Date of Patent: November 2, 2021
    Inventors: Paolo Peri, Davide Russo, Christian Spreafico, Riccardo Degl'Innocenti
  • Patent number: 11021661
    Abstract: Conversion of heavy fossil hydrocarbons (HFH) to a variety of value-added chemicals and/or fuels can be enhanced using microwave (MW) and/or radio-frequency (RF) energy. Variations of reactants, process parameters, and reactor design can significantly influence the relative distribution of chemicals and fuels generated as the product. In one example, a system for flash microwave conversion of HFH includes a source concentrating microwave or RF energy in a reaction zone having a pressure greater than 0.9 atm, a continuous feed having HFH and a process gas passing through the reaction zone, a HFH-to-liquids catalyst contacting the HFH in at least the reaction zone, and dielectric discharges within the reaction zone. The HFH and the catalyst have a residence time in the reaction zone of less than 30 seconds. In some instances, a plasma can form in or near the reaction zone.
    Type: Grant
    Filed: February 21, 2012
    Date of Patent: June 1, 2021
    Assignee: Battelle Memorial Institute
    Inventors: James J. Strohm, John C. Linehan, Benjamin Q. Roberts, Douglas L. McMakin, David M. Sheen, Jeffrey W. Griffin, James A. Franz, Charlene Franz
  • Patent number: 10517147
    Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising susceptor particles that absorb RF energy. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the susceptor particles. The RF energy is applied for a sufficient time to allow the susceptor particles to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the susceptor particles can be removed from the mixture after the desired average temperature has been achieved. The susceptor particles may provide for anhydrous processing, and temperatures sufficient for cracking, distillation, or pyrolysis.
    Type: Grant
    Filed: September 26, 2017
    Date of Patent: December 24, 2019
    Assignee: HARRIS CORPORATION
    Inventor: Francis Eugene Parsche
  • Patent number: 10472941
    Abstract: Methods, systems and apparatus for enhanced oil recovery utilizing enhanced sensitizers with chemical blowing agents (CBAs) includes irradiation of electromagnetically activated sensitizers with electromagnetic (EM) waves. The injected enhanced sensitizers absorb the energy from EM waves which increases the temperature. The elevated temperature then activates chemical blowing agents to aid in fluidity of heavy oil or bitumen extractions. The released gases from CBAs also aid in upgrading by releasing desired gases which in turn reduces long hydrocarbon chains at elevated temperature along with catalysts.
    Type: Grant
    Filed: February 25, 2016
    Date of Patent: November 12, 2019
    Assignee: ESPARK ENERGY INC.
    Inventors: Simon Park, Seonghwan Kim, Rushi Vyas
  • Patent number: 9034176
    Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising susceptor particles that absorb RF energy. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the susceptor particles. The RF energy is applied for a sufficient time to allow the susceptor particles to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the susceptor particles can be removed from the mixture after the desired average temperature has been achieved. The susceptor particles may provide for anhydrous processing, and temperatures sufficient for cracking, distillation, or pyrolysis.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: May 19, 2015
    Assignee: HARRIS CORPORATION
    Inventor: Francis Eugene Parsche
  • Patent number: 9011647
    Abstract: A process for the plasma-assisted treatment of coal in which coal is directly converted to heavy hydrocarbons. The first step in the process is direct conversion of coal to aliphatic hydrocarbons under plasma conditions in the presence of light hydrocarbons, such as natural gas. In the second process step, the aliphatic hydrocarbons are upgraded to a liquid fuel. The energy for the process can be provided by radio frequency energy, such as microwave energy, that is powered by a renewable energy source. The process has flexibility to adjust aromatic content in the fuel to match fuel specification requirements.
    Type: Grant
    Filed: June 5, 2009
    Date of Patent: April 21, 2015
    Assignee: General Electric Company
    Inventors: Vitali Victor Lissianski, Anthony Mark Thompson, Daniel Lawrence Derr, Gregg Anthony Deluga, Ramanathan Subramanian, Surinder Prabhjot Singh
  • Publication number: 20150053592
    Abstract: A method of operating a hydrocarbon material processing system includes feeding a hydrocarbon feedstock from a hydrocarbon feedstock source into a reaction tube positioned within an opening of a waveguide, feeding a process gas from a process gas source into the reaction tube, receiving microwaves in the waveguide from a microwave generator, energy from the waveguide in the reaction tube to cause the feedstock and process gas to react and form into a product stream comprising a fuel product. The method also includes periodically delivering a cleaning gas into the reaction tube, without stopping the propagation of the energy and without pausing the feeding of the hydrocarbon feedstock and the process gas into the reaction tube.
    Type: Application
    Filed: August 20, 2014
    Publication date: February 26, 2015
    Inventors: George L. Skoptsov, Alan A. Johnson
  • Publication number: 20150053591
    Abstract: A system for processing hydrocarbon materials includes a waveguide having a lateral portion comprising housing having a first end portion configured to be connected to an energy generator, a closed opposite end portion, a primary axis extending from the first end portion to the second end portion, and a central portion having a circular opening. A reaction tube structure comprising an outer wall made of a dielectric material is positioned in or connected to the opening of the waveguide. When hydrocarbon feedstock and process gas are fed into the reaction tube structure and energy is received in the waveguide, energy is propagated to the reaction tube structure to form a plasma within the reaction tube structure and cause the feedstock and process gas to react and form into a product stream.
    Type: Application
    Filed: August 20, 2014
    Publication date: February 26, 2015
    Inventors: George L. Skoptsov, Alan A. Johnson
  • Patent number: 8920638
    Abstract: A method of extracting hydrocarbon from oil containing rocks is herein disclosed. According to one embodiment a method includes mixing oil sandstone and a phosphonium based ionic liquid and subjecting the resulting mixture to microwave radiation of 2.54 Gigahertz. Within 1 minute the trapped hydrocarbon is extracted into the ionic liquid which can be subsequently processed to remove the hydrocarbons from the ionic liquid.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: December 30, 2014
    Inventor: Robert Petcavich
  • Patent number: 8911617
    Abstract: The present disclosure provides a simple and efficient method for the self-sustaining radiation cracking of hydrocarbons. The method disclosed provides for the deep destructive processing of hydrocarbon chains utilizing hydrocarbon chain decomposition utilizing self-sustaining radiation cracking of hydrocarbon chains under a wide variety of irradiation conditions and temperature ranges (from room temperature to 400° C.). Several embodiments of such method are disclosed herein, including; (i) a special case of radiation-thermal cracking referred to as high-temperature radiation cracking (HTRC); (ii) low temperature radiation cracking (LTRC); and (iii) cold radiation cracking (CRC). Such methods were not heretofore appreciated in the art. In one embodiment, a petroleum feedstock is subjected to irradiation to initiate and/or at least partially propagate a chain reaction between components of the petroleum feedstock.
    Type: Grant
    Filed: May 4, 2012
    Date of Patent: December 16, 2014
    Assignee: Petrobeam, Inc.
    Inventors: Yuriy A. Zaikin, Raissa F. Zaikina
  • Patent number: 8888995
    Abstract: High power RF energy supplied to a reaction chamber at a resonant frequency is used to break the covalent bonds of a hydrocarbon material without heat. An RF signal generator may be used to supply RF energy to a resonant ring through a four port coupler. The phase of the RF energy passing through the resonant ring may be adjusted to achieve an integral multiple of a resonant wavelength. Wavelength and intensity may be adjusted to sublimate or pyrolyze the hydrocarbon material to yield a useful gaseous product.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: November 18, 2014
    Assignee: Harris Corporation
    Inventors: Victor Hernandez, Lisa Patton
  • Patent number: 8871482
    Abstract: Functionalized substrate materials, for example inorganic particles and/or synthetic polymeric particles, are used to enhance bioprocesses such as saccharification and fermentation.
    Type: Grant
    Filed: May 9, 2013
    Date of Patent: October 28, 2014
    Assignee: Xyleco, Inc.
    Inventors: Marshall Medoff, Thomas Craig Masterman, Harrison Medoff
  • Publication number: 20140299514
    Abstract: Systems and methods for extracting recoverable materials from source materials are provided. Source materials are introduced into a furnace. A condition is created within the furnace in which a gaseous pressure within the furnace is less than an atmospheric pressure outside of the furnace by removing air from within the furnace with a vacuum pump. Hydrocarbons contained within the source material are separated from the source material without using a significant amount of water by heating the source material to a temperature sufficient to cause the hydrocarbons to liquefy or vaporize. The liquefied hydrocarbons or vaporized hydrocarbons are then captured.
    Type: Application
    Filed: May 13, 2014
    Publication date: October 9, 2014
    Applicant: GREEN TECHNOLOGY LLC
    Inventors: John Lee Horning, Jan H. Matthias, Nigel Moriarty, John Stuart Lehde
  • Patent number: 8807220
    Abstract: The present invention provides a method of producing upgraded hydrocarbons in-situ from a production well. The method begins by operating a subsurface recovery of hydrocarbons with a production well. An RF absorbent material is heated by at least one RF emitter and used as a heated RF absorbent material, which in turn heats the hydrocarbons to be produced. Hydrocarbons are upgraded in-situ and then produced from the production well.
    Type: Grant
    Filed: September 15, 2011
    Date of Patent: August 19, 2014
    Assignee: ConocoPhillips Company
    Inventors: Maxine Jones Madison, Dwijen Kumar Banerjee, Francis Eugene Parsche, Mark Alan Trautman
  • Publication number: 20140208638
    Abstract: A pyrolysis oil composition by an oxygen-starved microwave process from an organic-carbon-containing feedstock is described. Feedstock is introduced into a substantially microwave-transparent reaction chamber. A microwave source emits microwaves which are directed through the microwave-transparent wall of the reaction chamber to impinge on the feedstock within the reaction chamber. The microwave source may be rotated relative to the reaction chamber. The feedstock is subjected to microwaves until the desired reaction occurs to produce a fuel. A catalyst can be mixed with the feedstock to enhance the reaction process.
    Type: Application
    Filed: November 9, 2013
    Publication date: July 31, 2014
    Inventors: Douglas M. Van Thorre, Michael L. Catto
  • Patent number: 8779013
    Abstract: Embodiments of the present invention are directed to apparatus and methods for converting carbon dioxide and/or methane into higher alkanes and hydrogen gas in a single reaction chamber using a catalyst and microwave radiation.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: July 15, 2014
    Assignee: Amiren LLC
    Inventor: Ben Zion Livneh
  • Patent number: 8771503
    Abstract: A process for recovering an oil from a tar sand, including the steps of drying the tar sand to produce a dried tar sand, mixing the dried tar sand with a microwave absorbent to produce a mixed sand, and cracking the mixed sand with microwaves to produce an oil vapor product containing the oil.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: July 8, 2014
    Assignee: C-Micro Systems Inc.
    Inventors: Chang Yul Cha, Paul Gil Vergnani
  • Publication number: 20140121425
    Abstract: A composition comprising at least one graphene-supported assembly, which comprises a three-dimensional network of graphene sheets crosslinked by covalent carbon bonds, and at least one metal chalcogenide compound disposed on said graphene sheets, wherein the chalcogen of said metal chalcogenide compound is selected from S, Se and Te. Also disclosed are methods for making and using the graphene-supported assembly, including graphene-supported MoS2. Monoliths with high surface area and conductivity can be achieved. Lower operating temperatures in some applications can be achieved. Pore size and volume can be tuned. Electrochemical methods can be used to make the materials.
    Type: Application
    Filed: March 15, 2013
    Publication date: May 1, 2014
    Applicant: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
    Inventors: Marcus A. Worsley, Joshua Kuntz, Christine A. Orme
  • Publication number: 20140114097
    Abstract: A method and apparatus is provided for the continuous microwave depolymerization of high molecular weight organic feedstock material, such as waste plastics and includes intermittent or continuous feeding of the processing material on the surface or into the bulk of the sensitized hot bed located under microwave irradiation. As a result of the interaction of electromagnetic field with processed materials, sensitizer is heated by microwave energy and feedstock material undergoes the depolymerization reactions. The reaction zone can be localized on the surface of the hot bed or distributed in the bulk of the reaction mass depending on the agitation conditions of the reaction mass, such as stirring, or other agitation means, for example by re-circulated gas. Products of the reactions are vaporized and transported to the collection system, which may include a combination of a scrubber, a condenser and a settler.
    Type: Application
    Filed: May 16, 2013
    Publication date: April 24, 2014
    Applicant: CLIMAX GLOBAL ENERGY
    Inventors: John Hemmings, Thomas Pinto, Viktor Sharivker
  • Patent number: 8691084
    Abstract: The invention provides systems and methods for extracting and upgrading heavy hydrocarbons from substrates such as oil sands, oil shales, and tar sands in a unitary operation. The substrate bearing the hydrocarbon is brought into contact with a supercritical or near-supercritical fluid, a source of hydrogen such as hydrogen gas, and a catalyst. The materials are mixed and heated under elevated pressure. As a consequence of the elevated temperature and pressure, upgraded hydrocarbon-containing material is provided in a single or unitary operation. In some embodiments, sonication can be used to improve the upgrading process. Fluids suitable for use in the process include carbon dioxide, hexane, and water. It has been observed that upgrading can occur within periods of time of a few hours.
    Type: Grant
    Filed: June 11, 2008
    Date of Patent: April 8, 2014
    Assignee: University of New Brunswick
    Inventors: Gerard Sean McGrady, Sarah Ann Brough, Christopher Willson
  • Publication number: 20140065684
    Abstract: Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems are described that can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy materials, to produce ethanol and/or butanol, e.g., by fermentation. Hydrocarbon-containing materials are also used as feedstocks.
    Type: Application
    Filed: November 7, 2013
    Publication date: March 6, 2014
    Inventor: Marshall Medoff
  • Patent number: 8665437
    Abstract: A method for controlling a transformation process in which the conversion of charge materials to a product takes place along a transformation interface from the crystal and/or grain and/or phase and/or pore surface into the charge material, wherein one or more chemical elements in the charge materials is released and/or incorporated and/or rearranged and wherein the conversion of the charge materials takes place along advancing transformation interfaces. The charge materials are identified on the basis of at least one optical, in particular microscopic, analysis with respect to their phases and/or phase components and/or their phase morphology, structure, texture and/or their chemical composition. On the basis of these variables, reference functions for the charge materials, which describe the conversion of the charge materials in the process, are assigned and used for establishing the process parameters of the transformation process.
    Type: Grant
    Filed: May 7, 2009
    Date of Patent: March 4, 2014
    Assignee: Siemens Vai Metals Technologies GmbH
    Inventors: Harald Fischer, Heinrich Rochus Mali, Johannes Leopold Schenk, Stefan Schuster, Bernhard Hailu Spuida, Kurt Wieder, Franz Winter
  • Publication number: 20140048452
    Abstract: Systems and methods for coal liquefaction are provided. According to one embodiment, coal is introduced into a plasma furnace. A plasma energy field is generated within the plasma furnace by causing an electrical discharge between a pair of arc rods located within the plasma furnace and positioned above the coal. Hydrocarbons contained within the coal are separated from the coal by causing the plasma energy field to penetrate the coal and heat the coal to a temperature sufficient to liquefy the hydrocarbons by focusing and drawing the plasma energy field through the coal with a magnetic field created proximate to the coal. The liquefied hydrocarbons are then captured.
    Type: Application
    Filed: October 29, 2013
    Publication date: February 20, 2014
    Applicant: GREEN TECHNOLOGY LLC
    Inventors: John Lee Horning, Jan H. Matthias, Nigel Moriarty, John Stuart Lehde
  • Patent number: 8470166
    Abstract: The present invention is drawn to a method of processing heavy paraffinic oils or heavy aromatic oils using radiation chemistry of polyethylene under oxidizing conditions. The process of the invention will result in a chain reaction for oxidative scission as the basis for a radiation processing for heavy paraffinic or aromatic oils. The method of the invention will allow for the cost-efficient and environmentally-friendly processing of heavy oils into lighter petroleum products.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: June 25, 2013
    Assignee: PetroRadiant, Inc.
    Inventors: Mohamad Al-Sheikhly, Joseph Silverman
  • Publication number: 20130056987
    Abstract: The invention pertains to utilization of high power density microwave energy to reduce organic compounds to carbon and their constituents, primarily in a gaseous state. The process includes, but is not limited to, scrap tires, plastics, asphalt roofing shingles, computer waste, medical waste, municipal solid waste, construction waste, shale oil, and PCB/PAH/HCB-laden materials. The process includes the steps of feeding organic material into a microwave applicator and exposing the material to microwave energy fed from at least two linear polarized sources in non-parallel alignment to each other, and collecting the material. The at least two sources of microwave energy are from a bifurcated waveguide assembly, whose outputs are perpendicular to each other and fed through waveguide of proper impedance, such that the microwave sources are physically and electrically 90° out of phase to each other. The microwave frequency is between 894 and 1000 MHz, preferably approximately 915 MHz.
    Type: Application
    Filed: September 14, 2012
    Publication date: March 7, 2013
    Inventor: John F. Novak
  • Publication number: 20120312723
    Abstract: A method of extracting bitumen from oil sands having a transition temperature at which the oil sands solidify includes forming formable oil sands into pellets and cooling at least a surface of the pellets sufficiently to prevent the pellets from aggregating; cooling the pellets to below the transition temperature; fracturing the pellets to release the bitumen from the oil sands while maintaining the temperature of the pellets below the transition temperature; and separating the bitumen from the oil sands in a separator.
    Type: Application
    Filed: February 14, 2011
    Publication date: December 13, 2012
    Applicant: CRYOEX OIL LTD.
    Inventor: Thomas Duma
  • Patent number: 8323458
    Abstract: A process is disclosed for making a biomass susceptible to depolymerization or liquefaction under mild conditions. The process comprises introducing into the biomass a material susceptible to the absorption of electro-magnetic radiation to form a radiation absorbent biomass. The radiation absorbent biomass is subjected to electro-magnetic radiation to form an activated biomass.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: December 4, 2012
    Assignee: KiOR, Inc.
    Inventors: Paul O'Connor, Dennis Stamires
  • Patent number: 8273244
    Abstract: Systems and methods for extracting recoverable materials (e.g., petroleum and/or other hydrocarbons) from source materials (e.g., tar sands) are provided. According to one embodiment a method is provided for extracting bitumen from tar sand. Tar sands are introduced into a batch or continuous processing plasma furnace. The bitumen contained within the tar sand is then vaporized by exposing the tar sands to a plasma energy field that penetrates the tar sands. The vaporized bitumen is captured for subsequent processing.
    Type: Grant
    Filed: December 9, 2010
    Date of Patent: September 25, 2012
    Assignee: Green Technology LLC
    Inventors: John Lee Horning, Nigel W. Moriarty, Jan H. Matthias, John Stuart Lehde
  • Publication number: 20120160744
    Abstract: Embodiments of a method are described for modifying pitches, oils, tars, and binders by using these materials as solvents to extract organic chemicals from coal.
    Type: Application
    Filed: March 5, 2012
    Publication date: June 28, 2012
    Applicant: WEST VIRGINIA UNIVERSITY
    Inventors: Elliot B. Kennel, Peter G. Stansberry, Alfred H. Stiller, John W. Zondlo
  • Patent number: 8192591
    Abstract: The present disclosure provides a simple and efficient method for the self-sustaining radiation cracking of hydrocarbons. The method disclosed provides for the deep destructive processing of hydrocarbon chains utilizing hydrocarbon chain decomposition utilizing self-sustaining radiation cracking of hydrocarbon chains under a wide variety of irradiation conditions and temperature ranges (from room temperature to 400° C.). Several embodiments of such method are disclosed herein, including; (i) a special case of radiation-thermal cracking referred to as high-temperature radiation cracking (HTRC); (ii) low temperature radiation cracking (LTRC); and (iii) cold radiation cracking (CRC). Such methods were not heretofore appreciated in the art. In one embodiment, a petroleum feedstock is subjected to irradiation to initiate and/or at least partially propagate a chain reaction between components of the petroleum feedstock.
    Type: Grant
    Filed: December 15, 2006
    Date of Patent: June 5, 2012
    Assignee: Petrobeam, Inc.
    Inventors: Yuriy A. Zaikin, Raissa F. Zaikina
  • Patent number: 8133384
    Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method and apparatus for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising mini-dipole susceptors such as carbon strands. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the mini-dipole susceptors. The RF energy is applied for a sufficient time to allow the mini-dipole susceptors to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the mini-dipole susceptors can be removed after the desired average temperature has been achieved. The susceptors may provide advantages for the RF heating of hydrocarbons, such as higher temperatures (sufficient for distillation or pyrolysis), anhydrous processing, and greater speed or efficiency.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: March 13, 2012
    Assignee: Harris Corporation
    Inventor: Francis Eugene Parsche
  • Publication number: 20120055851
    Abstract: A method of converting coal into a liquid hydrocarbon fuel utilizes a high pressure, high temperature reactor which operates upon a blend of micronized coal, a catalyst, and steam. Microwave power is directed into the reactor. The catalyst, preferably magnetite, will act as a heating media for the microwave power and the temperature of the reactor will rise to a level to efficiently convert the coal and steam into hydrogen and carbon monoxide.
    Type: Application
    Filed: July 19, 2011
    Publication date: March 8, 2012
    Inventor: Ronald Kyle
  • Publication number: 20120055850
    Abstract: A method for producing hydrocarbons is provided, which comprises (a) subjecting a coal feedstock to mechanical activation (203) in a liquid medium, thereby obtaining a mixture of solubilized asphaltenes; and (b) at least partial cracking (207) the resulting mixture in a supersonic nozzle reactor, thereby obtaining hydrocarbon products derived from the asphaltenes.
    Type: Application
    Filed: September 2, 2010
    Publication date: March 8, 2012
    Inventor: Willem P.C. Duyvesteyn
  • Publication number: 20110315605
    Abstract: Carbon nanostructures such as multiwalled carbon nanotubes are formed from electrolyzed coal char. The electrolyzed coal char is formed by forming a slurry of coal particles, metal catalyst and water and subjecting this to electrolysis, which generates carbon dioxide and hydrogen. This forms a coating on the particles which includes metal catalysts. These particles can be used as is for formation of multi-walled carbon nanotubes using a pyrolysis method or other method without the addition of any catalyst. The gelatinous coating can be separated from the char and used as a fuel or as a carbon source to form carbon nanostructures.
    Type: Application
    Filed: September 8, 2011
    Publication date: December 29, 2011
    Inventor: Gerardine G. Botte
  • Patent number: 8002972
    Abstract: A system for producing petroleum products from oil shale includes one or plural kiln lines made up of plural series-connected, indirect-fired, inclined rotary kilns. Plural kiln lines are operated for parallel processing. Oil shale is advanced through kilns in succession and exhausted from each kiln line substantially free of hydrocarbons. Successive kilns along the advancement of oil shale are maintained at successively higher temperatures. A fuel distinct from hydrocarbons in oil shale, such as syngas from a gasifier or hydrogen gas from a separator, drives pyrolysis to extract hydrocarbons. A refining unit located proximate to the kiln lines upgrades extracted hydrocarbons into petroleum products and separates the petroleum products by criteria. A heat extraction unit recovers heat from exhausted oil shale for reuse in kilns. A method involves drying oil shale followed by heating dry oil shale in successively hotter pyrolysis environments.
    Type: Grant
    Filed: October 12, 2007
    Date of Patent: August 23, 2011
    Assignee: EnShale, Inc.
    Inventors: Robert D. Morris, Jr., Robert D. Morris, III
  • Publication number: 20110132809
    Abstract: Systems and methods for extracting recoverable materials (e.g., petroleum and/or other hydrocarbons) from source materials (e.g., tar sands) are provided. According to one embodiment a method is provided for extracting bitumen from tar sand. Tar sands are introduced into a batch or continuous processing plasma furnace. The bitumen contained within the tar sand is then vaporized by exposing the tar sands to a plasma energy field that penetrates the tar sands. The vaporized bitumen is captured for subsequent processing.
    Type: Application
    Filed: December 9, 2010
    Publication date: June 9, 2011
    Inventor: John Lee Horning
  • Publication number: 20110108466
    Abstract: A method of extracting hydrocarbon from oil containing rocks is herein disclosed. According to one embodiment a method includes mixing oil sandstone and a phosphonium based ionic liquid and subjecting the resulting mixture to microwave radiation of 2.54 Gigahertz. Within 1 minute the trapped hydrocarbon is extracted into the ionic liquid which can be subsequently processed to remove the hydrocarbons from the ionic liquid.
    Type: Application
    Filed: November 8, 2010
    Publication date: May 12, 2011
    Inventor: Robert Petcavich
  • Publication number: 20110049016
    Abstract: The invention provides systems and methods for extracting and upgrading heavy hydrocarbons from substrates such as oil sands, oil shales, and tar sands in a unitary operation. The substrate bearing the hydrocarbon is brought into contact with a supercritical or near-supercritical fluid, a source of hydrogen such as hydrogen gas, and a catalyst. The materials are mixed and heated under elevated pressure. As a consequence of the elevated temperature and pressure, upgraded hydrocarbon-containing material is provided in a single or unitary operation. In some embodiments, sonication can be used to improve the upgrading process. Fluids suitable for use in the process include carbon dioxide, hexane, and water. It has been observed that upgrading can occur within periods of time of a few hours.
    Type: Application
    Filed: June 11, 2008
    Publication date: March 3, 2011
    Applicants: HSM SYSTEMS, INC., University of New Brunswick
    Inventors: Gerard Sean McGrady, Sarah Ann Brough, Christopher Willson
  • Publication number: 20100307960
    Abstract: A process for the plasma-assisted treatment of coal in which coal is directly converted to heavy hydrocarbons. The first step in the process is direct conversion of coal to aliphatic hydrocarbons under plasma conditions in the presence of light hydrocarbons, such as natural gas. In the second process step, the aliphatic hydrocarbons are upgraded to a liquid fuel. The energy for the process can be provided by radio frequency energy, such as microwave energy, that is powered by a renewable energy source. The process has flexibility to adjust aromatic content in the fuel to match fuel specification requirements.
    Type: Application
    Filed: June 5, 2009
    Publication date: December 9, 2010
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Vitali Victor Lissianski, Anthony Mark Thompson, Daniel Lawrence Derr, Gregg Anthony Deluga, Ramanathan Subramanian, Surinder Prabhjot Singh
  • Publication number: 20100219108
    Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method and apparatus for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising mini-dipole susceptors such as carbon strands. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the mini-dipole susceptors. The RF energy is applied for a sufficient time to allow the mini-dipole susceptors to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the mini-dipole susceptors can be removed after the desired average temperature has been achieved. The susceptors may provide advantages for the RF heating of hydrocarbons, such as higher temperatures (sufficient for distillation or pyrolysis), anhydrous processing, and greater speed or efficiency.
    Type: Application
    Filed: March 2, 2009
    Publication date: September 2, 2010
    Applicant: HARRIS CORPORATION
    Inventor: Francis Eugene Parsche
  • Publication number: 20100219107
    Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising susceptor particles that absorb RF energy. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the susceptor particles. The RF energy is applied for a sufficient time to allow the susceptor particles to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the susceptor particles can be removed from the mixture after the desired average temperature has been achieved. The susceptor particles may provide for anhydrous processing, and temperatures sufficient for cracking, distillation, or pyrolysis.
    Type: Application
    Filed: March 2, 2009
    Publication date: September 2, 2010
    Applicant: Harris Corporation
    Inventor: Francis Eugene Parsche
  • Publication number: 20100051511
    Abstract: Method for release of organic materials from shale oil and like solid substances, by treating shale oil powder in a liquid medium, with vortical movements, wave movements, acoustic turbulent streams, or combinations thereof. The treatment causes foaming of the liquid medium followed by separation of the foam from the liquid medium, whereby the foam is enriched with organic materials released from the shale oil powder. The foam can be placed in a liquid organic solvent and treated with vortical movements, wave movements, acoustic turbulent streams, or combinations thereof. The treatment causes the extraction of hydrocarbons into the solvent, and the inorganic shale material to precipitate. The remaining inorganic sold material can be utilized in the manufacture of construction materials. The obtained solution of the extracted hydrocarbons into the solvent represents a synthetic fuel, which could be used after slight reforming as motor fuel, jet fuel, or the like.
    Type: Application
    Filed: June 28, 2007
    Publication date: March 4, 2010
    Applicant: OSAT, LLC.
    Inventor: Vladimir Faerman
  • Publication number: 20100025304
    Abstract: The present invention provides methods for decomposing and extracting compositions for the recovery of petroleum-based materials from composites comprising those petroleum-based materials, comprising subjecting the compositions and/or composites to microwave radiation, wherein the microwave radiation is in the range of from about 4 GHz to about 18 GHz. The present invention also provides for products produced by the methods of the present invention and for apparatuses used to perform the methods of the present invention.
    Type: Application
    Filed: October 12, 2009
    Publication date: February 4, 2010
    Applicant: GLOBAL RESOURCES CORPORATION
    Inventors: Carl Everleigh, Julian Forthe, Frank G. Pringle
  • Publication number: 20090308793
    Abstract: The invention provides the activation, refining and stabilization of oil shale. The stabilization may be performed by recirculative extraction, the activation by electromagnetic irradiation, steam, or by an inorganic base, and the refining by ion beam irradiation. The thus processed oil shale may be used to adsorb organic and inorganic contaminants from a variety of materials include materials of vegetable origin.
    Type: Application
    Filed: July 19, 2007
    Publication date: December 17, 2009
    Applicant: NANOTECH INVESTMENT 2 (PTY) LTD Suite 8, Panorama Office Estate
    Inventors: Pieter Gideo Van Der Merwe, Hassan Hannache, Omar Bekri
  • Patent number: 7629497
    Abstract: The present invention provides methods for decomposing and extracting compositions for the recovery of petroleum-based materials from composites comprising those petroleum-based materials, comprising subjecting the compositions and/or composites to microwave radiation, wherein the microwave radiation is in the range of from about 4 GHz to about 18 GHz. The present invention also provides for products produced by the methods of the present invention and for apparatuses used to perform the methods of the present invention.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: December 8, 2009
    Assignee: Global Resource Corporation
    Inventor: Frank G. Pringle
  • Publication number: 20090120845
    Abstract: Methods for liberating organic carbonaceous products from mineral matrices such as oil shale and the products liberated by the present methods inter alia, the invention in a preferred embodiment subjects oil shale to resonance disintegration including inter alia rapid pressure and directional changes to essentially instantaneously vary forces acting thereon. Oil shale processed by non-impact processing according to the invention liberates kerogen from the mineral matrix to permit subsequent conversion to shale oil or other utilization.
    Type: Application
    Filed: April 10, 2006
    Publication date: May 14, 2009
    Inventor: James P. Yates
  • Patent number: 7378012
    Abstract: A method for reforming a lubricating oil which includes holding stably a container (6) containing a lubricating oil (5) on a stand (4) being insulated from the earth with four high-voltage insulators (3), and applying an electrostatic potential of 30 to 50 volts by the use of an electrostatic charge generating device (7), to thereby charge electrons to the lubricating oil (5). The charge of electrons converts an unsaturated hydrocarbon (1a) and an aromatic hydrocarbon (2a) in the lubricating oil (5) to a saturated hydrocarbon (1b) or (2b) and a naphthenic hydrocarbon (2c), which reduces the viscosity of the lubricating oil. Accordingly, the use of the lubricating oil (5) in an internal combustion engine lowers the friction resistance therein, which leads to a decrease in the fuel consumption of the engine. The method allows, therefore, the enhancement of fuel economy, in combination with the suppression of oxidation of the lubricating oil itself.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: May 27, 2008
    Inventor: Naoto Yokoo