Abstract: A method of enhanced oil recovery for a crude oil production well includes the steps of pyrolyzing rubber materials including the steps of heating the rubber materials to form pyro-vapors, condensing the pyro-vapors to form pyro-gas and pyro-oil where the pyro-oil includes an inhibitor solution including non-polar hydrocarbons and polar hydrocarbons. The inhibitor solution is injected as an injection stream into the crude oil production well to facilitate production of crude oil from the crude oil production well.

Abstract: The present invention relates to an improvement over the invention previously submitted by the inventor relating to an apparatus for recovering heavy oil from oil shale and a method for recovery using same, the present invention relating to an apparatus for supplying continuous heat/pressure to continuously supply and discharge oil shale sludge, in which a plurality of unit extraction apparatuses, comprising a kerogen extraction apparatus and an intermediate storage tank, are installed to implement a continuous operation, which is an improvement over a semi-continuous operation of alternately operating the kerogen extraction apparatus and the intermediate storage tank.

Abstract: A process and system to separate crude from tar sands. A tar sand and crude oil mixture is created using ground tar sands. The tar sand and crude oil mixture is mixed under high pressure in a treatment vessel with either natural gas or exhaust gas from an internal combustion engine. The mixture is then moved through a entrainment vessel still under the high pressure. When the mixture is removed from the entrainment vessel excess gas is removed from the mixture. The crude oil is then separated from the sand typically through a cyclone separator. A portion of the crude oil may be used to mix with the ground tar sand on the front end of the process.

Abstract: A method for the pyrolytic extraction of hydrocarbons such as shale oil from kerogen. Oil shale containing kerogen which has been ground into particulate form, is cascaded downwardly between a plurality of rotating trays within a heated processing chamber. As the hydrocarbons are volatized within the chamber, the volatiles are collected and condensed within a condenser or other suitable recovery apparatus.

Abstract: The invention provides systems and methods for extracting and upgrading heavy hydrocarbons from substrates such as oil sands, oil shales, and tar sands in a unitary operation. The substrate bearing the hydrocarbon is brought into contact with a supercritical or near-supercritical fluid, a source of hydrogen such as hydrogen gas, and a catalyst. The materials are mixed and heated under elevated pressure. As a consequence of the elevated temperature and pressure, upgraded hydrocarbon-containing material is provided in a single or unitary operation. In some embodiments, sonication can be used to improve the upgrading process. Fluids suitable for use in the process include carbon dioxide, hexane, and water. It has been observed that upgrading can occur within periods of time of a few hours.

Abstract: A method for the pyrolytic extraction of hydrocarbons such as shale oil from kerogen. Oil shale containing kerogen which has been ground into particulate form, is cascaded downwardly between a plurality of rotating trays within a heated processing chamber. As the hydrocarbons are volatized within the chamber, the volatiles are collected and condensed within a condenser or other suitable recovery apparatus.

Abstract: A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed. In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.

Abstract: A method for the pyrolytic extraction of hydrocarbons such as shale oil from kerogen. Oil shale containing kerogen which has been ground into particulate form, is cascaded downwardly between a plurality of rotating trays within a heated processing chamber. As the hydrocarbons are volatized within the chamber, the volatiles are collected and condensed within a condenser or other suitable recovery apparatus.

Abstract: A method and apparatus for recovering oil from oil-containing sorbents, such as drill cuttings obtained from drilling with an oil-based mud. The method includes peptizing the substrate with an acid reagent and direct thermal desorption with combustion effluent gases at high temperature under turbulent mixing conditions. Another method disclosed includes upgrading the oil in the substrate to improve one or more of the properties of the recovered oil relative to the oil in the substrate, such as, lower aromatics content, lower sulfur content, lower functional group content, higher saturates, higher viscosity, higher viscosity index, and any combination thereof. The apparatus provides for efficient recovery of oil from the substrate with a short residence time, high throughput, low residual oil content in the treated solids and/or high percentage of oil recovery. The apparatus may be transported to a remote location for on-site treatment of drill cuttings or other oil-containing solids.

Abstract: An apparatus and method for achieving improved throughput capacity of indirectly heated rotary kilns used to produce pyrolysis products such as shale oils or coal oils that are susceptible to decomposition by high kiln wall temperatures is disclosed. High throughput is achieved by firing the kiln such that optimum wall temperatures are maintained beginning at the point where the materials enter the heating section of the kiln and extending to the point where the materials leave the heated section. Multiple high velocity burners are arranged such that combustion products directly impact on the area of the kiln wall covered internally by the solid material being heated. Firing rates for the burners are controlled to maintain optimum wall temperatures.

Abstract: A process is disclosed process for converting a solid or highly viscous carbon-based energy carrier material to liquid and gaseous reaction products, said process comprising the steps of: a) contacting the carbon-based energy carrier material with a particulate catalyst material b) converting the carbon-based energy carrier material at a reaction temperature between 200° C. and 450° C., preferably between 250° C. and 350° C., thereby forming reaction products in the vapor phase. In a preferred embodiment the process comprises the additional step of: c) separating the vapor phase reaction products from the particulate catalyst material within 10 seconds after said reaction products are formed; In a further preferred embodiment step c) is followed by: d) quenching the reaction products to a temperature below 200° C.

Abstract: A system for producing petroleum products (12) from oil shale (32) includes a kiln line (72,152) of plural series-connected, substantially horizontally-disposed kilns (90,94,104,170,180). Crushed oil shale (36) is advanced through kilns (90,94,104,170,180) in succession and exhausted from the kiln line (72,152) substantially freed of hydrocarbons. A heat extraction unit (80) recovers heat (82) from hot spent shale (78). Successive kilns (90,94,104,170,180) along the advancement of crushed oil shale (36) are maintained at successively higher temperatures (T94,T94,T104,T170,T180). Pyrolysis is indirectly-driven using kiln-surrounding roasting jackets (96,106,182), A fuel distinct from hydrocarbons in oil shale (32), such as natural gas (132), syngas (54) from a gasifier (48), or hydrogen gas (62) from a separator (60) provides heat. These combustible gasses are burned in roasting jackets (96,106,182) or converted by a burner (134) into hot flue gas (136) that passes through roasting jackets (96,106,182).

Abstract: An apparatus for separating carbon products from used tires includes a decomposing chamber into which used tires are charged, a nitrogen gas supply device that supplies nitrogen gas into the decomposing chamber, one or more magnetrons that generate microwave of predetermined frequency and one or more phase shifters that removes interference between microwaves generated by the magnetrons, a receiving plate that is adapted to receive carbon black and iron cores generated by the decomposing process, a tire support that is adapted to support used tires, an opening and closing device that opens or closes a door on which used tires are placed, conveyor belt that moves carbon black and iron cores to a desired location after decomposition is complete, and a cooling plate that is provided in an upper portion of the apparatus and cools down gaseous oil that is generated by decomposition by microwave into liquid oil.

Abstract: A system 100 is described for the treatment of multiphase residues having unlimited content of water, oil and solids to obtain hydrocarbons and other products, said system comprising multiphase residue feed system 10, inert gas system 20 and reduced pressure system 30, tubular reactor 40 provided with three heating zones Z-1, Z-2 and Z-3 with a temperature gradient and transportation helicoid 42 to displace the residue mass throughout the reaction zones, the hydrocarbon products and water being collected in a system 60 of condensers 61, 62 and 63 linked to a system 70 of bubbling vessels 71, 72 and 73, reactor 40 being operated in the sealed mode and being provided with a multiphase residue inlet 43 and exit 44 of solid product. The solid product is collected in a system 50 comprising upper valve 51 and lower valve 52, and intermediate silo 53 and then directed to post-treatment system 90 for activation aiming at industrial utilization. The process using the system 100 of the invention is also described.

Abstract: An apparatus for dry distillation of oil shale, has a vibration bed with multiple layers, a gas retort, a feeding system, a feeding hole, a screen plate, a water seal tank, a discharging system, and a gas outlet. The feeding system and the feeding hole are disposed at the top of the gas retort. The screen plate is disposed on the vibration bed. The layers of the vibration bed are obliquely disposed in the gas retort. The number of layers of the vibration bed is nine. Three hot recycle gas inlets are disposed on the wall of the gas retort and respectively below the fourth layer, the fifth layer and the sixth layer of the vibration bed. A cold recycle gas inlet is disposed below the ninth layer of the vibration bed. The water seal tank and the discharging system are disposed at the bottom of the gas retort. The gas outlet is disposed at the top of the gas retort. The apparatus features a simple structure, convenient operation, low cost, and a high oil recovery and resource unitization rate.

Abstract: An apparatus separates solids from gas in a vessel using cyclones. The cyclones have centers located at different distances from a center of the vessel, but the inlets to the cyclones are located at the same distance from the center to balance the proportions of catalyst fines entering each cyclone.

Abstract: A method and apparatus for the continuous recycling of hydrocarbon containing used and waste materials such as plastic and polymeric waste including, for example, polyurethane, rubber wastes and the like, and in particular scrap rubber tires, are disclosed. The process is carried out under moderate temperatures and atmospheric pressure in the presence of air and a feed of liquid(s) containing oxygen. The method is characterized by the low residence time.

Abstract: A retort heating apparatus includes a perimeter wall bounding a central compartment. A partition wall is disposed within the central compartment so as to separate the central compartment into at least a heating chamber and a vapor chamber. The partition wall has a plurality of spaced apart apertures formed thereon so as to provide fluid communication between the heating chamber and the collection chamber. A plurality of spaced apart baffles are disposed within the heating chamber between the perimeter wall and the partition wall. A collection plate is disposed within the vapor chamber at a downward curved or sloped orientation. The collection plate has lower end disposed at or adjacent to the partition wall and an opposing upper end disposed at or toward the perimeter wall.

Abstract: A process for recovering hydrocarbons from coal or oil shale is disclosed. The process involves the steps of forming a pulp of finely divided coal or oil shale in a first reaction bed, adding concentrated sulphuric acid to the first reaction bed, controlling the temperature of the first reaction bed to produce a hydrocarbon mixture, and deacidifying the hydrocarbon mixture.

Abstract: A process for the removal of petroleum contaminants from particulates is disclosed which involves (i) volatilization of the contaminated particulates in a toroidal dynamic bed (1) suspended in hot gases and/or (ii) extraction of the contaminated particulates in a toroidal dynamic bed (1) suspended in hot gases (such as hot combustion product gases, e.g., mixtures of CO.sub.2, CO, H.sub.2 O, unconsumed hydrocarbons, in a variety of proportions) optionally containing steam or a solvent for the petroleum contaminant. The separation of the petroleum contaminant is to obtain solids containing less than 1, preferably less than 0.5 and most preferably less than about 0.1 weight percent of the contaminant. The process allows sufficient petroleum removal so that the solids are suitable for direct dumping in a landfill, assuming that the solids are free of non-petroleum environmental contaminants.

Abstract: A process for heteroatom removal-enhancing hydrogenation of highly refractory aromatic ring structures that involves contacting a highly refractory structure having at least one aryl linkage connecting a first heteroaryl moiety and a moiety selected from the group consisting of an aryl moiety and a second heteroaryl moiety with supercritical water having a temperature of from about 400.degree. C. to about 600.degree. C. in the presence of from about 3.4 MPa to about 18.6 MPa of CO to produce lower molecular weight products having decreased aromatic and heteroatom content. The process has utility for producing more valuable lower molecular weight products having a reduced aromatic heteroatom content from starting materials that are highly refractory and widely considered to be difficult to upgrade such as coals and asphaltenes, and model compounds containing the biaryl linkages.

Abstract: Scrap rubber automobile tires, oil soluble plastics, as well as waste motor oil are disposed of by the process of the subject invention without polluting the nation's environment. Further, useful product synthesis gas, reducing gas, or fuel gas is produced. The rubber from the rubber tires and/or oil soluble plastics are dissolved in the waste motor oil to produce a homogeneous pumpable tire-oil which is separated from undissolved tire belt material containing undissolved rubber and/or oily material, solid residue, and off-gas comprising light hydrocarbons having a maximum atmospheric boiling point of 850.degree. F., and H.sub.2 S. The undissolved tire belt material is coked to produce off-gas, inorganic materials and carbon black. Off-gas form the liquefaction and coking reactors is cooled to produce organic condensate. The tire oil, carbon black, and condensate are mixed together and introduce into a partial oxidation gas generator for the production of synthesis gas, reducing gas, or fuel gas.

Abstract: A method of reducing the oil content of cuttings, in which the cuttings are introduced into a drum-shaped space, where an elevated temperature is predominant and subjected to a hammering treatment in that space and the drum-shaped space is permanently heated from without so that during the performance of the hammering treatment the temperature in the interior is maintained in the vicinity of, but below, the cracking temperature of the oil in the cuttings to be treated, while further the pressure in the spaces is maintained at a value of at least 0.3 bar gauge.

Abstract: As-mined, naturally water-wet oil sand is mixed at the mine site with hot water and NaOH to produce a slurry containing entrained air. The slurry is pumped through a pipeline and is fed directly to a conventional gravity separation vessel. The pipeline is of sufficient length so that, in the course of being pumped therethrough, sufficient coalescence and aeration of bitumen occurs so that, when subsequently retained in the gravity separation vessel under quiescent conditions, a viable amount of the bitumen floats, forms froth, and is recovered.

Abstract: A process for removing and recovering specific constituents from a waste stream at higher temperatures than the boiling point of the specific constituents. In the process, the waste is moved at a specified retention time, through a heat zone, thus increasing the temperature of the waste stream. There is further provided a means to separate certain components in that waste stream whereby the components are evaporated and are released in a gaseous state, either from a liquid or a solid within the waste stream. The gaseous components are then transferred in the gaseous state through a flow of an inert medium, such as nitrogen gas, to inhibit combustion of the components, or to prevent the combination of oxidation, or oxygen being used as a catalyst to form even more hazardous compounds.

Abstract: A system and process for educing hydrocarbons from shale. The system comprises a retort vessel which has an integral apparatus for mixing raw and recycle shale that embodies raw shale pulverizing and has an integral apparatus for finally pulverizing the raw shale particulates that have descended through a fluidized bed. The system further comprises: a burner which generates process heat; heat transfer apparatus which extracts heat for use in the process; and means for recovering such heat. The process involves recovery of significant amounts of process energy including: the recovery of heat from retort vapors; the recovery of heat from spent shale; recovery and utilization of the heat of combustion; and recycling of gases for the operation of mechanical pulverizing apparatus.

Abstract: A method and apparatus for producing oil, bitumen, precious metals, and hydrocarbon gases from mined oil-bearing rock material, such as tar sands and soil shale. The rock is ground, preconditioned in a heated and pressurized atmosphere devoid of oxygen, and subsequently centrifuged in the presence of an oil-replacement gas to produce oil, and also any precious metal particles that are present in the oil-bearing rock material. The produced oil and precious metals are subsequently separated from each other by centrifuging.

Abstract: Process and apparatus for near-zero discharge soil remediation, preferably in conjunction with an asphalt plant, comprising heating soil contaminated with up to about 30,000 ppm light hydrocarbons in an inclined, axially-fired rotating separator, and sampling the output soil to determine the remaining contaminants. If below 100 ppm (preferably 10 ppm) it may be reemplaced as clean fill. If it does meet D.O.T./CALTRANS standards and is below about 100 ppm it may be used as roadbed fill. If between about 1000 and 100 ppm and meets standards it may be used as aggregate, being mixed with hot oil to form asphalt. The separator offgases are condensed, the reclaimed liquid hydrocarbons separated and combined with the hot oil. The hot condenser offgases are supplied as secondary air to a main dryer, improving efficiency of operation. A dust/mud blow down system clears the heat exchange plenums with compressed air.

Abstract: A method for the recovery of oil from solid hydrocarbonaceous material and particularly from oil shale by retorting fresh feed shale and heat medium particles using a fluidized bed. The invention uses a self supporting dense phase fluidized bed in a retort without the need to use an external fluid for fluidization.Also described is a control system for the method whereby feed stock input rate is controlled as a function of flow rate of oil vapour products given off, and whereby heat medium particle input rate is controlled as a function of the temperature of either the retort bed or of the oil vapor product.

Abstract: A process for retorting oil shale in a vertical retort. Recycle gas containing steam and produced gas is separated from the retort off-gas and used to heat the oil shale. The steam is present in amount by volume of the recycle gas of at least 40% and preferably 70%. The minimum particle size of the oil shale is such that the particles are retained on a screen having 1/4 inch openings. The maximum particle size is such that the particles are capable of passing through a screen having 3 inch openings.

Abstract: A process and apparatus for the production of coke, asphalt and jet fuel m a feed of fossil fuels containing volatile carbon compounds therein is disclosed. The process includes the steps of pyrolyzing the feed in an entrained bed pyrolyzing means, separating the volatile pyrolysis products from the solid pyrolysis products removing at least one coke from the solid pyrolysis products, fractionating the volatile pyrolysis products to produce an overhead stream and a bottom stream which is useful as asphalt for road pavement, condensing the overhead stream to produce a condensed liquid fraction and a noncondensable, gaseous fraction, and removing water from the condensed liquid fraction to produce a jet fuel-containing product. The disclosed apparatus is useful for practicing the foregoing process. the process provides a useful method of mass producing and jet fuels from materials such as coal, oil shale and tar sands.

Abstract: A two step retorting process for pyrolyzing a solid feed selected from the group consisting of oil shale, tar sand, waste motor oil, and scrap tires to recover valuable products therefrom comprising retorting a mixture of the solid feed in heavy oil at a relatively low temperature, recycling the oil formed back to the first step, and completing the pyrolysis of the residue formed at a higher temperature in the absence of product oil recycling. Apparatus is provided including a means for feeding and soaking the solid feed, a HSPR, an IFBC, and means for handling product liquid and gas.

Abstract: This invention is a continuous retorting process for various high molecular weight organic materials, including oil shale, that yields an enhanced output of liquid product. The organic material, mineral matter, and an acidic catalyst, that appreciably adsorbs alkenes on surface sites at prescribed temperatures, are mixed and introduced into a pyrolyzer. A circulating stream of olefin enriched pyrolysis gas is continuously swept through the organic material and catalyst, whereupon, as the result of pyrolysis, the enhanced liquid product output is provided. Mixed spent organic material, mineral matter, and cool catalyst are continuously withdrawn from the pyrolyzer. Combustion of the spent organic material and mineral matter serves to reheat the catalyst. Olefin depleted pyrolysis gas, from the pyrolyzer, is enriched in olefins and recycled into the pyrolyzer.

Abstract: A process for the pyrolysis of carbonaceous materials at an elevated temperature or an elevated temperature and an elevated pressure in which a fuel is burned in the presence of a combustion supporting material, in an amount sufficient to supply at least the stoichiometric amount of oxygen for combustion of all of the fuel, to produce an effluent containing significant amounts of nitrogen and carbon dioxide and having an elected temperature, passing the effluent to a pyrolysis zone, wihtout removal of components therefrom, to thereby create an elevated temperature within the pyrolysis zone and pyrolyzing the carbonaceous material in the pyrolysis zone in the presence of the effluent from the burning step and at an elevated temperature. The burning step may additionally be carried out at a high flame velocity to produce an effluent having an elevated pressure and the carbonaceous material may thus additionally be pyrolyzed at an elevated pressure.

Abstract: A method of separating oil in water and other evaporable liquids from drilling mud, bleaching earth, sludge from oil tanks, oil shale or the like, the mud being evaporated at a lower temperature than with conventional evaporation due to the fact that the capillary forces binding the separate fractions in the pores of the mud are destroyed in a friction evaporator.

Abstract: In a first condensation stage (which is on the rising current end of the low-temperature carbonization drum and the equipment for which is integrated) quenching is done with a cooled low-temperature carbonization oil fraction containing solids. Simultaneously the whole discharge opening placed on the rising current end in the base region of the low-temperature carbonization drum for the volatile components of the low-temperature carbonization process is continuously scrubbed clean with the low-temperature carbonization oil fraction containing solids. Additionally, the volatile and liquid components are also drawn off simultaneously.

Abstract: An apparatus and method for extracting hydrocarbons from tar sands. Stationary heater plates have a central opening therethrough through which a horizontal axle extends. Rotors having a central hub and a number of arms are splined on the axle, one closely sandwiched between every two heater plates. A ring is provided between the heater plates closely outward of the rotor arms. Sand retaining pockets are defined between adjacent arms of each rotor, the rotor hub, the ring and adjacent heater plates. Sand is retained in the sand retaining pockets for about one revolution about the axis between feed and removal positions. While retained in the pockets, the sand is heated and hydrocarbons driven off are collected.

Abstract: Fine particles of solid fossil fuels are pyrolyzed by passage in a thin layer through a heating zone at successively higher temperatures in a non-oxidizing atmosphere while rapidly separating and removing volatile pyrolysis products. The resulting char may be first treated with mineral acid or employed directly in the hydroprocessing of additional solid fossil fuel to liquid fuels. Alternatively, the acid-washed char may be hydrotreated to afford an improved char product having a low sulfur and mineral content.

Abstract: An apparatus and method for gas treating a particle bed wherein a uniform temperature gradient is achieved. A support member, such as a grate, serves to support a bed of particles on a surface thereof. The support member is moved in a predetermined direction. Gas is released from a plurality of positions at different depths in the bed.

Abstract: A process for recovery of organic oils and residues in association with inorganic solids by solvent extraction and for the recovery of solvent used for the extraction. The organic solvent extracted inorganic solids having remaining associated organic solvent is fluidized in a bed with fluidizing gas comprising superheated vapor of the organic solvent vaporizing and removing a substantial portion of the associated organic solvent. Then the solids are countercurrently contacted with a combustion gas stream at a lower temperature than the solids physically stripping a substantial portion of the residual solvent from the solids, the combustion gas stream being enhanced for combustion by comprising stripped organic solvent and by being heated.

Abstract: A process for separating solids from hydrocarbons in a slurry of hydrocarbonaceous solids and solvent is disclosed comprising atomizing the slurry, introducing and mixing the atomized slurry and superheated steam in a stripping zone, vaporizing the hydrocarbons, and separately removing the vapors and the solids. The process is particularly useful in an oil shale recovery process.

Abstract: Oil-containing solids are dried and heated by contacting them in a drying zone with superheated steam admitted to the zone at a temperature in excess of 200.degree. C. The heated solids may be distilled to remove hydrocarbons therefrom and the resulting proceduce and/or combustion products of the distillation or other combustion products are used to heat a mixed vapor remainder, after separation of said carbon from the vapors formed during the drying, to the temperature of 1200.degree. C. for recirculation to the drying zone.

Abstract: A process for the destructive distillation of hydrocarbonaceous solids in a retort, wherein a viscous bridging zone comprising viscous liquids in intimate contact with solids, which tends to impede the flow of vaporized hydrocarbons and the flow of solid particles, is agitated by reciprocating mechanical means actuated by a rotatable crankshaft.

Abstract: Process for sump-phase hydrogenation with integrated gas-phase hydrogenation relevant parameters being adjusted so that an economical heat recovery for the entire system is achieved, despite increasing incrustation of the mash heat exchanger and the increasing deactivation of the gas-phase catalyst. The process-relevant temperatures of the intermediate precipitator and of the gas-phase reactor are precisely adjusted by the use of head coolers which follow the sump-phase hydrogenator, and by head coolers which precede the intermediate precipitator. The procedure is such that the waste heat from the sump-phase products is partially recovered by using it to heat the raw materials constituting the gas phase and by feeding it back again to the mash heater.

Abstract: A process for improving the upgrading/conversion of hydrocarbonaceous materials such as coals, petroleum residual oils, shale oils and tar sand bitumens. In the process, the free radicals formed from thermal cracking of the hydrocarbons are reacted with the free radicals formed by the thermal cracking of a free radical forming chemical reactant, such as dimethyl ether, to yield stable low molecular weight hydrocarbon distillate products. The hydrocarbonaceous feed material is preheated to a temperature of 600.degree.-700.degree. F. and the hydrocarbon and the free radicals forming chemical, such as dimethyl ether, are passed through a flow reactor at temperature of 750.degree.-900.degree. F., pressure of 200-1000 psi, and liquid hourly space velocity of 0.3 to 5.0 LHSV. Free radicals formed from the hydrocarbon feed material and from the ether material react together in the reactor to produce low molecular weight hydrocarbon liquid materials.