With Discrete Hydrogenation Of Recycle Stream Patents (Class 208/416)
  • Patent number: 10301549
    Abstract: A method of depolymerizing coal includes preparing a high temperature depolymerizing medium consisting of heavy hydrocarbon oils and mixing it with coal to form a mixture, performing an optional first distillation at a temperature below 250° C. to recover naphthalene, heating the mixture to a temperature between 350° C. and 450° C. to create a digested coal, centrifuging the digested coal to remove ash and obtain a centrate, and distillation of the centrate into separate fractions. The high temperature depolymerizing medium may be a heavy hydrocarbon with a hydrogen to carbon (H/C) ratio higher than 7.0% and may include liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils. The high temperature depolymerizing medium may be blended with an oil, preferably with H/C ratio higher than 10.
    Type: Grant
    Filed: November 14, 2017
    Date of Patent: May 28, 2019
    Assignee: QUANTEX RESEARCH CORPORATION
    Inventors: Elliot B. Kennel, Gilbert A. Chalifoux
  • Patent number: 9845431
    Abstract: A method of depolymerizing coal includes preparing a high temperature depolymerizing medium consisting of heavy hydrocarbon oils and mixing it with coal to form a mixture, performing an optional first distillation at a temperature below 250° C. to recover naphthalene, heating the mixture to a temperature between 350° C. and 450° C. to create a digested coal, centrifuging the digested coal to remove ash and obtain a centrate, and distillation of the centrate into separate fractions. The high temperature depolymerizing medium may be a heavy hydrocarbon with a hydrogen to carbon (H/C) ratio higher than 7.0% and may include liquids chosen from the group consisting of: coal tar distillate, decant oil, anthracene oil, and heavy aromatic oils. The high temperature depolymerizing medium may be blended with an oil, preferably with H/C ratio higher than 10.
    Type: Grant
    Filed: November 22, 2016
    Date of Patent: December 19, 2017
    Assignee: QUANTEX RESEARCH CORPORATION
    Inventors: Elliot B. Kennel, Gilbert A. Chalifoux
  • Patent number: 8894846
    Abstract: This is a method to reactively refine hydrocarbons, such as heavy oils with API gravities of less than 20° and bitumen-like hydrocarbons with viscosities greater than 1000 cp at standard temperature and pressure using a selected fluid at supercritical conditions. The reaction portion of the method delivers lighter weight, more volatile hydrocarbons to an attached contacting device that operates in mixed subcritical or supercritical modes. This separates the reaction products into portions that are viable for use or sale without further conventional refining and hydro-processing techniques. This method produces valuable products with fewer processing steps, lower costs, increased worker safety due to less processing and handling, allow greater opportunity for new oil field development and subsequent positive economic impact, reduce related carbon dioxide, and wastes typical with conventional refineries.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: November 25, 2014
    Inventor: Stephen Lee Yarbro
  • Patent number: 8063258
    Abstract: A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. and 300° C. to form particulated biomass having a mean average particle size from about 1 ?m to about 1000 ?m. The particulated biomass is mixed with a liquid to form a suspension, wherein the liquid comprises bio-oil, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a hydropyrolysis reactor; and at least a portion of the particulated biomass of the suspension is converted into fuel.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: November 22, 2011
    Assignee: Kior Inc.
    Inventors: Robert Bartek, Michael Brady, Dennis Stamires
  • Patent number: 7569121
    Abstract: The present development is a multistage process for converting solid hydrocarbon resources into synthetic oil. The process comprises a raw hydrocarbon material treatment stage, followed by a pyrolysis stage, and then a synthetic liquid upgrading stage. Throughout the process, heat is transferred to the hydrocarbon resources via recyclable ceramic spheres.
    Type: Grant
    Filed: March 31, 2005
    Date of Patent: August 4, 2009
    Inventor: Clyde Wesley Devore
  • Patent number: 6927260
    Abstract: A process for preparing polyethylene from “feed ethylene” comprises: a) a hydrogenation stage in which “feed ethylene” containing impurities or secondary components such as acetylene and ethane is reacted with hydrogen to remove the acetylene by catalytic hydrogenation to form ethylene and part of the ethylene is converted into ethane, and b) a polymerization stage in which the ethylene leaving stage a) is reacted in the gas phase in a fluidized-bed reactor to form polyethylene, where the fluidizing gas used comprises, on entering the reactor, ethene and from 20 to 70% by volume of ethane, based on the total volume of the fluidizing gas, possibly together with further components, where, in a), ethylene is converted in a targeted manner into ethane in addition to the ethane already present in the “feed ethylene” so that the concentration specified in b) results. An apparatus for carrying out the process is also provided.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: August 9, 2005
    Assignee: Basell Polyolefine GmbH
    Inventors: Klaus Berhalter, Walter Schicketanz, Gerard Duc
  • Patent number: 5122260
    Abstract: In the two stage liquefaction of a carbonaceous solid such as coal wherein coal is liquefied in a first stage in the presence of a liquefaction solvent and the first stage effluent is hydrogenated in the presence of a supported hydrogenation catalyst in a second stage, catalyst which has been previously employed in the second stage and comminuted to a particle size distribution equivalent to 100% passing through U.S. 100 Mesh, is passed to the first stage to improve the overall operation.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: June 16, 1992
    Assignee: ABB Lummus Crest Inc.
    Inventors: Avinash Gupta, Marvin I. Greene
  • Patent number: 5120429
    Abstract: In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater.Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.
    Type: Grant
    Filed: July 10, 1987
    Date of Patent: June 9, 1992
    Assignee: Lummus Crest Inc.
    Inventors: Avinash Gupta, Marvin I. Greene
  • Patent number: 4879021
    Abstract: A process for the hydrogenation of undissolved coal and subsequent liquefaction of the hydrogenated coal particles to provide useful hydrocarbon liquid products including naphtha, gasoline and diesel fuel. These low boiling hydrocarbon liquids are produced by the process comprising: (a) mixing solid coal particles with a coal derived solvent in a solvent/coal ratio ranging from about 8/1 to about 1.5/1 to provide a flowable coal/oil slurry of solid coal particles; (b) passing the coal/oil slurry and hydrogen upwardly through a first reaction zone containing a coal-derived liquid and bed of particulate catalyst maintained at a temperature ranging from about 400.degree. to about 700.degree. F.
    Type: Grant
    Filed: August 26, 1988
    Date of Patent: November 7, 1989
    Assignee: HRI, Inc.
    Inventors: Edwin J. Hippo, Alfred G. Comolli, Robert O'Brien
  • Patent number: 4846963
    Abstract: A coal liquefaction process using ionic liquefaction techniques with polar solvent solubilizing agents and water soluble inorganic compounds, produces a carbonaceous liquefaction product which is separated from the process stream by the use of methanol as a partitioning agent and the methanol and solubilizing agent are recovered separately for reuse.
    Type: Grant
    Filed: April 18, 1986
    Date of Patent: July 11, 1989
    Inventors: Curtis L. Knudson, John R. Rindt, Sylvia A. Farnum
  • Patent number: 4629554
    Abstract: A method of liquefying coal in which coal is mixed with a process solvent comprising at least partially hydrogenated coal tar material to produce a coal-solvent slurry. This slurry is treated under coal-liquefying conditions, preferably including a hydrogen atmosphere and elevated temperatures, to produce a solution containing coal liquefaction products. These products are recovered from the solution. Recovered, process-derived solvent material may be recycled in order to supplement the at least partially hydrogenated coal tar material as an ingredient of the process solvent.
    Type: Grant
    Filed: September 19, 1985
    Date of Patent: December 16, 1986
    Assignee: Kerr-McGee Corporation
    Inventors: Srikant Gir, Donald E. Rhodes
  • Patent number: 4605486
    Abstract: An improved process for liquefying solid carbonaceous materials wherein the solid carbonaceous material is slurried with a suitable solvent and then subjected to liquefaction at elevated temperature and pressure to produce a normally gaseous product, a normally liquid product and a normally solid product. The normally liquid product is further separated into a naphtha boiling range product, a solvent boiling range product and a vacuum gas-oil boiling range product. At least a portion of the solvent boiling-range product and the vacuum gas-oil boiling range product are then combined and passed to a hydrotreater where the mixture is hydrotreated at relatively severe hydrotreating conditions and the liquid product from the hydrotreater then passed to a catalytic cracker. In the catalytic cracker, the hydrotreater effluent is converted partially to a naphtha boiling range product and to a solvent boiling range product.
    Type: Grant
    Filed: April 26, 1985
    Date of Patent: August 12, 1986
    Assignee: Exxon Research and Engineering Co.
    Inventor: Daniel F. Ryan