Abstract: The present invention relates to a process for co-gasification of two or more carbonaceous feedstock, said process comprising combusting a first carbonaceous feedstock having high calorific value with low ash and high hydrogen content, to produce a heated effluent; carrying the heated effluent to second reactor where the heated effluent reacts with a second carbonaceous feedstock, having low calorific value with high ash and low hydrogen content, to produce synthesis gas.

Abstract: A method for producing high levels of methane based on a combination of steam hydrogasification and a shift reactor is provided using carbonaceous material. Hydrogen produced by the shift reactor can be recycled back into the steam hydrogasifier.

Abstract: A catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, comprises a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape. The catalyst is prepared by a specific order of steps: crushing, calcining, acidic autoclaving, drying, further calcining and impregnation with catalytic metals.

Abstract: Integrated process, in which pure carbonyl iron powder (CIP) is prepared by decomposition of pure iron pentacarbonyl (IPC) in a plant A, carbon monoxide (CO) liberated in the decomposition of the IPC is used in plant A for the preparation of further CIP from iron or is fed to an associated plant B for the preparation of synthesis gas or is fed to an associated plant C for the preparation of hydrocarbons from synthesis gas, and the CIP prepared in plant A is used as catalyst or catalyst component in an associated plant C for the preparation of hydrocarbons from synthesis gas from plant B.

Abstract: Disclosed herein is a sorbent composition including an adsorbent support; and a metal component comprising a transition metal, wherein the metal component is impregnated on a surface of the adsorbent support; and wherein the metal component effects the removal of sulfur and vanadium from a hydrocarbon fuel. Also disclosed herein is a sorbent composition comprising an adsorbent support, wherein a surface of the adsorbent support has been chemically modified to comprise functional groups; and wherein the adsorbent support effects the removal of sulfur and vanadium from a hydrocarbon fuel.

Abstract: A multi-stage catalytic process for the direct liquefaction of coal is utilized with a hydrotreater to first liquefy and subsequently treat the product in one integrated process. A fresh hydrogenation catalyst is used to reduce heteroatoms (S, N) from coal liquids in the downstream hydrotreater. This catalyst is then cascaded and re-used in the direct coal liquefaction process, first in the low temperature Stage 1, and then re-used in the high temperature Stage 2. Coal liquid products have very low contaminants and can be readily used to produce gasoline and diesel fuel. Catalyst requirements are substantially lowered utilizing this novel process.

Abstract: A method for heating materials by application of radio frequency (“RF”) energy is disclosed. For example, the disclosure concerns a method and apparatus for RF heating of petroleum ore, such as bitumen, oil sands, oil shale, tar sands, or heavy oil. Petroleum ore is mixed with a substance comprising mini-dipole susceptors such as carbon strands. A source is provided which applies RF energy to the mixture of a power and frequency sufficient to heat the mini-dipole susceptors. The RF energy is applied for a sufficient time to allow the mini-dipole susceptors to heat the mixture to an average temperature greater than about 212° F. (100° C.). Optionally, the mini-dipole susceptors can be removed after the desired average temperature has been achieved. The susceptors may provide advantages for the RF heating of hydrocarbons, such as higher temperatures (sufficient for distillation or pyrolysis), anhydrous processing, and greater speed or efficiency.

Abstract: A method and apparatus for catalytic hydroconversion processing of less volatile carbonaceous material to volatile liquid products is disclosed. The process is carried out in a plug-flow reactor system using nanosize metallic catalyst particles dispersed in the reactant slurry with compressed hydrogen/hydrogen-sulfide at a temperature between about 275° C. and 525° C. at a pressure of between about 800 psi and 6000 psi and a residence time in the reactors between about 1 minute and 4 hours.

Abstract: A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. and 300° C. to form particulated biomass having a mean average particle size from about 1 ?m to about 1000 ?m. The particulated biomass is mixed with a liquid to form a suspension, wherein the liquid comprises bio-oil, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a hydropyrolysis reactor; and at least a portion of the particulated biomass of the suspension is converted into fuel.

Abstract: This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of zinc at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.

Abstract: This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of nickel and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.

Abstract: This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of cobalt and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.

Abstract: This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of copper and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.

Abstract: This invention encompasses systems and methods for converting solid carbonaceous material to a liquid product, comprising maintaining a solid carbonaceous material in the presence of at least one active source of titanium and at least one active source of a second metal at a reaction temperature of greater than 350° C. and at a pressure in the range of 300 to 5000 psig for a time sufficient to form a liquid product.

Abstract: A multi-stage catalytic process for the direct liquefaction of coal is utilized with a hydrotreater to first liquefy and subsequently treat the product in one integrated process. A fresh hydrogenation catalyst is used to reduce heteroatoms (S, N) from coal liquids in the downstream hydrotreater. This catalyst is then cascaded and re-used in the direct coal liquefaction process, first in the low temperature Stage 1, and then re-used in the high temperature Stage 2. Coal liquid products have very low contaminants and can be readily used to produce gasoline and diesel fuel. Catalyst requirements are substantially lowered utilizing this novel process.

Abstract: A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil, products and hydrogen to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor. In the next reactor, a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, products, hydrogen and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. The slurry reactor system is, in this invention, preceded by an in-line pretreating step, such as hydrotreating or deasphalting.

Abstract: A method of extracting hydrocarbon fuel from oil sand or shale. The oil sand or shale is admixed with a sensitizer and subjected to exposure to microwave energy. This acts to remove the hydrocarbon fuel from the oil sand or shale and can also crack the hydrocarbon, lower sulfur content as well as water content.

Abstract: The invention provides an iron sulfide characterized in that it comprises FeS2, Fe1−XS, Fe3O4 and FeSO4, and that the secondary particles thereof, have a 50% volume-cumulative particle diameter of from 20 to 300 &mgr;m. The invention also provides a process for producing an iron sulfide comprising the steps of introducing (a) ferrous sulfate monohydrate having a d50 of from 20 to 300 &mgr;m and (b) not less than stoichiometric amount of at least one sulfur compound selected from elemental sulfur and hydrogen sulfide into the fluidized bed of a furnace and then fluidizing, burning, and reacting the ingredients at a temperature of from 350 to less than 630° C., a superficial velocity of 0.1 m/sec or higher, and a pressure of 1 atm or higher using air as a fluidizing gas. The present invention is useful, for example, in a process of coal liquefaction or heavy-oil hydrocracking.

Abstract: A multi-stage catalytic hydrogenation and hydroconversion process for heavy hydrocarbon feed materials such as coal, heavy petroleum fractions, and plastic waste materials. In the process, the feedstock is reacted in a first-stage, back-mixed catalytic reactor with a highly dispersed iron-based catalyst having a powder, gel or liquid form. The reactor effluent is pressure-reduced, vapors and light distillate fractions are removed overhead, and the heavier liquid fraction is fed to a second stage back-mixed catalytic reactor. The first and second stage catalytic reactors are operated at 700-850° F. temperature, 1000-3500 psig hydrogen partial pressure and 20-80 lb./hr per ft3 reactor space velocity. The vapor and light distillates liquid fractions removed from both the first and second stage reactor effluent streams are combined and passed to an in-line, fixed-bed catalytic hydrotreater for heteroatom removal and for producing high quality naphtha and mid-distillate or a full-range distillate product.

Abstract: A rigid, hollow, bottomless container for transporting and displaying a seed ball which includes a sleeve extending about the container that allows printed indicia to be located on the exterior of the container. The container is comprised of a number of side walls integrally or separately formed and connected to form the container. Each side wall contains an upper and lower ridge on opposite ends of a central panel which define a channel extending around the exterior of the container. The sleeve is formed of a resilient material and is positioned about the container within the channel and allows an individual to display printed material on the exterior of the container, by printing directly on the sleeve, or by placing preprinted cards between the sleeve and the side wall that rest on the lower ridge of the side walls of the container.

Abstract: A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen are reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 250 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

Abstract: A method for converting solid carbonaceous materials to liquid products. The solid carbonaceous material is first treated with a aqueous composition of a metal carbonate or bicarbonate. This results in the metal being atomically dispersed in the carbonaceous material. The treated solid carbonaceous material is then subjected to liquefaction conditions. The preferred metal is iron.

Abstract: This invention relates to a catalytic process for converting a carbonaceous material to a liquid product. More specifically, this invention relates to a process for hydroconverting coal in a hydroconverting zone to liquid hydrocarbon products in the presence of a catalyst prepared in situ, with the catalyst being added to a mixture of coal and solvent as an oil soluble metal compound. An increased quantity of liquid product is achieved by incorporating a hydrocracking zone into the process.

Abstract: The present invention relates to a catalytic process for converting a solid carbonaceous material, such as coal, to a liquid product in the presence of hydrogen. More particularly, this invention relates to a coal liquefaction process wherein a mixture of coal, bottoms, solvent and a sulfiding agent is subjected to liquefaction conditions in the presence of a catalyst precursor. This catalyst or catalyst precursor is comprised of a thermally decomposable compound of Groups IIB, IVB, VB, VIB, VIIB, and VIII of the Periodic Table of the Elements such as molybdenum.

Abstract: A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

Abstract: This invention is directed to a staged process for producing liquids from coal or similar carbonaceous feeds combining a pretreatment stage and a liquefaction stage. In the process, the feed is dispersed in an organic solvent and reacted with carbon monoxide at an elevated temperature and pressure. The so pretreated coal is sent to a liquefaction reactor, wherein the coal is reacted in the presence of hydrogen and catalyst to produce valuable liquid fuels or feedstocks.

Abstract: A process for producing a liquefied coal oil by a two step hydrogenation reaction of coal, which comprises subjecting coal to a first hydrogenation and subjecting at least a part of the reaction product of the first hydrogenation to a second hydrogenation, wherein the second hydrogenation is conducted in the presence of an alkali metal compound and/or an alkaline earth metal compound and a catalyst carrying a metal of Group VI-A and a metal of Group VIII of the Periodic Table.

Abstract: In a process for producing distillates from coal by a first stage thermal liquefaction followed by a catalytic hydrogenation, liquefaction solvent is added at points spaced over the length of the thermal liquefaction heater.Coal may be co-processed with petroleum oil by adding pre-hydrogenated oil to the first stage or unhydrogenated oil to the second stage.

Abstract: This invention generally relates to a catalyzed short residence time decomposition and volatilization of coal to produce liquid co-products while minimizing production of char and gas without utilization of external hydrogen, that is, hydrogen other than that contained in the coal feedstock. The invention more particularly relates to an improved method of economically producing uniform, fluidic, oil-type transportable fuel systems and fuel compositions and a slate of "value-added" co-products by a catalyzed coal refining process employing short residence time hydrodisproportionation (SRT-HDP). The preferred catalysts are oxides and salts of iron.

Abstract: Disclosed is a method for catalytically hydropyrolyzing carbonaceous material to produce liquid products boiling under about 550.degree. C. with reduced amounts of methane being formed. The process comprises (a) treating the carbonaceous material with as hydrogenation catalyst; (b) contacting the so-treated carbonaceous material with an effective amount of hydrogen, at an effective residence time, at a temperature below the critical temperature of rapid methane formation; (c) recovering the resulting liquids, gases, and char; and (d) recycling the char.

Abstract: A method for dispersing finely divided catalyst precursors onto the surface of coal or other particulate material includes the steps of forming a wet paste mixture of the particulate material and a liquid solution containing a dissolved transition metal salt, for instance a solution of ferric nitrate. The wet paste mixture is in a state of incipient wetness with all of this solution adsorbed onto the surfaces of the particulate material without the presence of free moisture. On adding a precipitating agent such as ammonia, a catalyst precursor such as hydrated iron oxide is deposited on the surfaces of the coal. The catalyst is activated by converting it to the sulfide form for the hydrogenation or direct liquefaction of the coal.

Abstract: An improved process for the hydroconversion of coal comprising pretreating coal in an aqeuous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor with a high catalyst loading to obtain a nearly finished product with low heteroatom levels. The extracted material consists of a relatively hydrogen-rich material which is readily converted to valuable liquid products in high yield. The residue from the extraction stage is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.

Abstract: An improved hydroconversion process for carbonaceous materials wherein a dihydrocarbyl substituted dithiocarbamate of a metal selected from any one of Groups IV-B, V-A, VI-A, VII-B, and VIII-A of the Periodic Table of Elements or a mixture thereof is used as a catalyst precursor. The improved process is effective for both normally solid and normally liquid carbonaceous materials and for carbonaceous materials which are either solid or liquid at the conversion conditions. The hydroconversion will be accomplished at a temperature within the range from about 500.degree. to about 900.degree. F., at a total pressure within the range from about 500 to 7000 psig and at a hydrogen partial pressure within the range from about 400 to about 5000 psig.

Abstract: In a process for the co-processing of waste rubber and carbonaceous material to form a useful liquid product, the rubber and the carbonaceous material are combined and heated to the depolymerization temperature of the rubber in the presence of a source of hydrogen. The depolymerized rubber acts as a liquefying solvent for the carbonaceous material while a beneficial catalytic effect is obtained from the carbon black released on depolymerization the reinforced rubber. The reaction is carried out at liquefaction conditions of 380.degree.-600.degree. C. and 70-280 atmospheres hydrogen pressure. The resulting liquid is separated from residual solids and further processed such as by distillation or solvent extraction to provide a carbonaceous liquid useful for fuels and other purposes.

Abstract: At least one decomposable molybdenum compound selected from the group consisting of molybdenum dithiophosphates and molybdenum dithiocarbamates is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum compound is then contacted in a hydrovisbreaking process with hydrogen under suitable hydrovisbreaking conditions.

Abstract: Disclosed is a process for obtaining liquids and gases from carbonaceous material, such as coal. The carbonaceous material is first treated with a gasification catalyst, and optionally a hydrogenation catalyst, and hydropyrolyzed for an effective residence time, below the critical temperature at which methane begins to rapidly form, to make liquid products. The resulting char is gasified in the presence of steam at a temperature from about 500.degree. C. to about 900.degree. C.

Abstract: A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and iron-coal catalyst is described in which the iron-coal catalyst is prepared by grinding coal particles and particles of an iron compound in oil to form an additive slurry or paste and mixing the coal-iron oil slurry or paste with the heavy hydrocarbon oil to form a feedstock to a hydroconverter.

Abstract: A process for two-stage catalytic co-processing of coal and heavy petroleum hydrocarbon liquid fractions to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a petroleum residuum and optionally with a process-derived hydrocarbon liquid solvent and fed into a first stage catalytic reaction zone operated at relatively mild conditions which promote controlled rate liquefaction of the coal while simultaneously hydrogenating the petroleum and hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure and 10-100 lb/hr/ft.sup.3 space velocity for the total coal and oil feed. From the first stage reaction zone, the partially hydrogenated effluent material is passed directly to the close-coupled second stage catalytic reaction zone maintained at more severe conditions of 750.degree.-900.degree. F.

Abstract: A process for the hydrogenation of heavy oils, residual oils, waste oils, used oils, shell oils, and tar sand oils by hydrogenating a slurry of the oil at a partial hydrogen pressure of 50-300 bar, a temperature of 250.degree.-500.degree. C., a space velocity of 0.1-5 T/m.sup.3 h, and a gas/liquid ratio of 100-10000 Nm.sup.3/ T, wherein the additive comprises two different grain size portions, a fine grain portion having a grain size of 90 microns or less and a coarse grain portion having a grain size of 100-1000 microns.

Abstract: A process for two-stage catalytic hydrogenation and liquefaction of coal to produce increased yields of low-boiling hydrocarbon liquid and gas products. In the process, the particulate coal is slurried with a process-derived liquid solvent and fed at temperature below about 650.degree. F. into a first stage catalytic reaction zone operated at conditions which promote controlled rate liquefaction of the coal, while simultaneously hydrogenating the hydrocarbon recycle oils at conditions favoring hydrogenation reactions. The first stage reactor is maintained at 650.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and 10-60 lb coal/hr/ft.sup.3 reactor space velocity. The partially hydrogenated material from the first stage reaction zone is passed directly to the close-coupled second stage catalytic reaction zone maintained at a temperature at least about 25.degree. F. higher than for the first stage reactor and within a range of 750.degree.-875.degree. F.

Abstract: When low-quality iron ore is used as a coal liquefaction catalyst, in order to improve its catalytic activity it is subjected to one or a combination of reduction, heat-treatment, or washing with or immersion in water for a long period of time so as to remove catalyst poisons before it is used as a catalyst. When high-quality iron ore is used, it is first reduced with carbon monoxide and then used as a catalyst.

Abstract: A multi-stage catalytic process for hydrogenation and liquefaction of coal using ebullated-bed catalytic reactors to produce low-boiling hydrocarbon liquid products, in which used catalyst is removed from a lower temperature first stage reactor operating at temperature not exceeding about 800.degree. F. and cascaded forward to a higher temperature second stage reactor for further use therein. Reaction conditions in the first stage reactor are preferably 700.degree.-800.degree. F. temperature, 1000-4000 psig hydrogen partial pressure, and a coal feed rate of 10-90 lb coal/hr per ft.sup.3 catalyst settled volume in the reactor. Useful higher temperature or second stage reaction conditions are 750.degree.-850.degree. F. temperature, and 1000-4000 psig hydrogen partial pressure.

Abstract: A method for hydrogenating a solvent-refined coal, comprising:(a) hydrogenating coal in the presence of a hydrocarbon solvent and an iron catalyst;(b) obtaining a solvent-refined coal material therefrom, which has a boiling point of at least 400.degree. under atmospheric pressure conditions;(c) removing preasphaltenes from said solvent-refined coal material to obtain a substantially preasphaltene free solvent-refined coal; and(d) hydrogenating the solvent-refined coal in a fixed bed under hydrogen pressure.

Abstract: A method for sequentially co-processing heavy hydrocarbon materials and carbonaceous materials comprising first subjecting the heavy hydrocarbon material in the presence of a disposable metal catalyst to produce and separate therefrom a first distillate stream and a first non-distillable effluent stream containing the disposable metal catalyst. The first non-distillable effluent stream then is mixed with the carbonaceous material and the mixture subjected to liquefaction conditions in the presence of said disposable metal catalyst. The liquefaction product then is subjected through the use of sequential fractionation and critical solvent extraction processing steps to separate and recover various heavy hydrocarbon and carbonaceous-derived light hydrocarbon liquid products therefrom.

Abstract: A method for hydrogenating a solvent-refined coal by heating it under hydrogen pressure in a fixed bed, characterized in that a solvent-refined coal fraction containing no substantial amount of preasphaltene is used as the solvent-refined coal.

Abstract: A process for thermally cracking carbonaceous substances, such as coal, is described, comprising: rapidly heating the carbonaceous substance to 500.degree. to 950.degree. C. in an atmosphere consisting essentially of hydrogen gas at a pressure of 35 to 250 kg/cm.sup.2 (gauge pressure) in the presence of at least one compound selected from the group consisting of halides, sulfates, nitrates, phosphates, carbonates, hydroxides, and oxides of Group VIII metal elements of the Periodic Table. The process increases the cracking of the carbonaceous substances and accelerates the conversion of the carbonaceous substances into gas and liquid products, greatly increasing the yields of the gasoline fraction and light oils.

Abstract: Improved catalysts for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a hydrogen donor solvent comprise a combination of zinc or copper, or a compound thereof, and a Group VI or non-ferrous Group VIII metal, or a compound thereof.

Abstract: A liquefaction process for coal or lignite is set forth. In the preferred and illustrated embodiment, coal or lignite is ground to a suitable particle size and placed in a reactor vessel. The reactor vessel is located within a pressure vessel. Pressure in the vessel is reduced to about 10.sup.-2 torr.Heat is applied. One procedure is to convert the carbon (in the coal or lignite) at an elevated temperature (600.degree.-900.degree. F.) in the presence of hydrogen (at pressures as high as 2,000 psi) into a hydrocarbon mix; depressurization avoids making various oxides and nitrides, and also can be optionally carried out in the presence of iron or iron ore in particulate form acting as a catalyst.