Abstract: A vibrating bed pyrolysis system has a vibrating bed which is supplied with hot solid particles. Dry coal particles are rapidly heated by the hot solid particles to drive off hydrocarbon vapors. The vapors are condensed in a jet condenser, and products are flowed to a header tank. A portion of the liquid product is stored at room temperature for later use. A small portion of the liquid product is pumped from the header tank and cooled to ambient temperature and is sprayed in the jet condenser, which is positioned above the vibrating pyrolysis bed. A dryer bed vibrated by the same vibrating machine which vibrates the pyrolysis bed is supplied with hot solid particles and the crushed coal. Moisture in the coal particles is evaporated, and water vapors entrain coal fines before the coal particles are passed to the pyrolysis bed. The hot solid particles are taken from a fluidized bed combustor and are returned to the combustor with the coal char particles by entrainment into the gas lift system.

Abstract: Middlings from the primary separation vessel ("PSV") are recycled through a line to the PSV. The middlings are aerated with fine air bubbles using in line eductor/aerator assemblies. The aerated middlings are mixed as they are pumped through a line back to the PSV. Bitumen recovery from the PSV is increased as a result.

Abstract: A method and apparatus for recycling asphalt based roofing material which typically comprises a body of asphalt and fiber, with aggregate on and adhered to the asphalt. The asphalt bodies, with aggregate, are subjected to action to separate or disengage the aggregate from the asphalt body without substantially reducing the size of the aggregate. Disengagement is effected by causing asphalt bodies with aggregate to impact on each other. Disengagement may be effected by placing asphalt bodies with aggregate in water to form in a slurry, which is agitated, as by an impeller. The asphalt bodies float to the top of the liquid, which is a non-solvent for asphalt, and are removed and dewatered; the aggregate of undiminished size is separately recovered.

Abstract: A process is disclosed for the removal of hydrocarbons such as bitumen or heavy fuel oil from hydrocarbon contaminated sludge, or particulate solid material or the like non-homogenous material after appropriate conditioning, such as by ball milling, with the conditioned material being aerated and then fed substantially tangentially into a substantially vertical cyclonic separator vessel to cause the hydrocarbons to which air bubbles have become attached to tend to float as a froth to the top of the vessel, with the remaining solids sinking to the bottom of the vessel. The hydrocarbon containing froth is then removed from the top of the vessel, and the remaining solids removed from the bottom of the vessel. This pneumatic flotation process obviates the need to add chemicals such as wetting agents or promoters.

Abstract: A process and an apparatus are described for separation of water and solids from oil sands froth in which heated froth is fed into a gravity settling vessel at a level below a bitumen-water interface established between a bitumen froth layer floating on a quiescent body of water whereby water and solids contained in the froth separate from the froth stream, the oil rises to accumulate in the bitumen froth layer, and the solids fall by gravity to the bottom of the gravity settling vessel. The apparatus comprises an injector manifold suspended horizontally within the vessel below the bitumen-water interface, said injector manifold having a plurality of equispaced, inwardly facing openings for the inward discharge of oil sands froth into the body of water. The injector ring manifold may also have a plurality of outwardly facing openings for both inward and outward discharge of froth.

Abstract: An apparatus and a process for separating particles in a slurry based on different physical, magnetic and/or chemical properties of the particles, the slurry including a mixture of solid particles and/or liqid particles which are immiscible in the slurry.

Abstract: A stream containing kerogen-rich and mineral-rich oil shale particles flow in a downward helical course such that the stream is confined in a manner to give the stream an outer and upper side having a first depth and comprising a substantial amount of said kerogen-rich particles, and an inner and lower side having a second depth and comprising a substantial amount of said mineral-rich particles, the first depth being greater than the second depth. The kerogen-rich and mineral-rich particles are subsequently separated in order to recover the kerogen-rich particles. The mineral-rich particles are further processed using froth flotation.

Abstract: A process for separating bitumen from tar sands, which comprises: a) agitating a mixture of tar sand with substantially coarse clean sand at ambient or below ambient temperature in the presence of water, so as to mechanically shear bitumen and enhance the detachment of bitumen particles from mineral matter in said tar sand, b) eluting the detached bitumen and fine mineral matter from the coarse sand by an upward flow of water while stirring gently, c) returning the coarse sand to step a) for reuse, and d) subjecting the eluted bitumen and fine mineral matter to froth flotation to separate the bitumen from said fine mineral matter, wherein the flotation is effected without using any reagents.

Abstract: The recovery of bitumen from tar sands by flotation is improved by the use of alkanol amines as flotation promoters. Monoethanolamine and diethanolamine are particularly useful for this purpose.

Abstract: A method and apparatus for producing oil, bitumen, precious metals, and hydrocarbon gases from mined oil-bearing rock material, such as tar sands and soil shale. The rock is ground, preconditioned in a heated and pressurized atmosphere devoid of oxygen, and subsequently centrifuged in the presence of an oil-replacement gas to produce oil, and also any precious metal particles that are present in the oil-bearing rock material. The produced oil and precious metals are subsequently separated from each other by centrifuging.

Abstract: An aperature is formed in the bottom wall of the launder. A downwardly extending container communicates with the aperture. A weir is positioned immediately downstream of the aperture. The container and weir combine to form a separator. In the launder, free water and solids contaminants settle and form a bottom layer of dirty water. The layer is diverted into the container through the aperture and the weir temporarily retains a small head of it. Temporary retention in the separator therefore generates a vertical fluid column comprising an upper layer of relatively clean froth and a lower layer of dirty water, said layers having an ascertainable interface. The elevation of the interface is monitored and contaminated fluid is withdrawn from the container as underflow at a rate controlled to keep the interface elevation substantially constant. The froth overflowing the weir is reduced in water and solids relative to the original froth issuing from the flotation vessel.

Abstract: A soil reclamation system that separates the contaminant from all soil particles greater than one micron in diameter and generates resuable soil and contaminant products. The process is based on a novel application of gas-sparged centrifugal separation under operating conditions and equipment specifications tailored to optimize the separation of the particular contaminant. The apparatus is mounted on a front-end loader for mobility and self-contained on site operation.

Abstract: An improved process for the hydroconversion of coal comprising pretreating coal in an aqeuous carbon monoxide-containing environment, followed by extracting a soluble hydrocarbon material from the coal, and subsequently hydroconverting the extracted material in a hydroconversion reactor with a high catalyst loading to obtain a nearly finished product with low heteroatom levels. The extracted material consists of a relatively hydrogen-rich material which is readily converted to valuable liquid products in high yield. The residue from the extraction stage is relatively hydrogen deficient material which can be gasified to produce hydrogen and carbon monoxide for the hydroconversion and pretreatment stages, respectively.

Abstract: Process and apparatus for disengaging organic, bituminous material from pulverized bituminous ores and for recovering a concentrated mixture of the bituminous material and water. Wherein the apparatus comprises a pulverizer to pulverize the ores to be processed to particles not larger than 1/4 inch in size and inner and outer process vessels which are preferably combined into a unitary assembly and wherein the process comprises a combination of mechanical and hot water disengagement of the organic, bituminous materials from the mineral ore solids, i.e.

Abstract: A method is provided for separating an inert solid substantially inorganic fraction comprising sand or soil from a tarry or oily organic matter in a feedstock. The feedstock may be contaminated soil or tarry waste. The feedstock is combined with pulverized coal and water. The ratio (oil or tar to dry weight of coal) of about 1.0:10 to about 4.0:10 at a temperature in the range of 60.degree.-95.degree. C. The mixture is agitated, the coarse particles are removed, and up to about 0.10% by weight (based on weight of coal) of a frothing agent is added. The mixture is then subjected to flotation, and the froth is removed from the mixture.

Abstract: A method for dedusting synthetic oil is disclosed. A feed of dust-laden synthetic oil is dissolved in a non-polar solvent of at least one alkane containing from 4 to 7 carbon atoms and aggregates of dust material are formed. The dissolved dust-laden synthetic oil is then gravitationally separated into a substantially dedusted stream in a dust-enriched stream including aggregates formed in the dissolution step. The dissolution and gravitational separation steps are conducted at a temperature and pressure greater than about 150.degree. F. and about ambient pressure and less than about the critical point temperature and pressure of the solvent and the aggregates provide acceptable settling and sludge compression rates. Methods for producing and dedusting oil from synthetic fuel stock are also disclosed.

Abstract: Bitumen froth is treated in a circuit comprising a plurality of serially connected mixer and inclined plate settler units. A light hydrocarbon diluent moves countercurrently through the circuit. Thus, as the bitumen content of the stream being settled diminishes, the concentration of diluent in that stream increases.

Abstract: The invention provides a process for extracting bitumen from oil sands. The process includes the step of conditioning the oil sands by adding hot water and steam to the oil sands. The conditioned oil sands are then introduced into a separation zone. Separation of the oil sands into a bitumen froth phase, a middlings phase and a tailings phase occurs in the separation zone. Water with air dissolved therein is continuously injected under pressure upwardly through the separation zone. The water is at a low temperature relative to the oil sands. At least two of the phases are then separately withdrawn from the separation zone.

Abstract: When low-quality iron ore is used as a coal liquefaction catalyst, in order to improve its catalytic activity it is subjected to one or a combination of reduction, heat-treatment, or washing with or immersion in water for a long period of time so as to remove catalyst poisons before it is used as a catalyst. When high-quality iron ore is used, it is first reduced with carbon monoxide and then used as a catalyst.

Abstract: Oil containing sludges are treated for the recovery of oil therefrom to render the resultant sludge disposable, by a process of conditioning the sludge to destabilize the emulsified phase thereof, centrifuging the destabilized sludge to obtain a solids-rich material which is largely hydrocarbon free and disposable, and a supernatant, hydrocarbon-containing liquid, and then subjecting the supernatant so formed to liquid/liquid phase separation. The conditioning is conducted so as to prepare a conditioned sludge characterized by a solids content of less than 50% by weight, a water content of less than 90% by weight, an oil phase with an API gravity of less than 12.degree., a continuous aqueous phase, and the solids in the sludge being primarily water wetted, this conditioned sludge being ready for centrifugation.

Abstract: An improvement is provided to the known hot water process for extracting bitumen from mined oil sand. More particularly, a methodology is provided for the production of microbubbles of air, and it has been found that the so-produced microbubbles can be used in the primary flotation/settling step of the hot water process to yield increased bitumen recovery. More particularly, a steam stream and an air stream in admixture are injected via a submerged nozzle into a flowing aqueous stream. A plurality of finely dispersed microbubbles are formed. These microbubbles have a diameter less than about 100 microns. The stream of microbubbles is injected into the diluted aqueous tar sand slurry formed in the hot water process. The injection is practiced following the conditioning step and prior to the introduction of the slurry into the flotation/settling step.

Abstract: A starting slurry composed of raw brown coal and a solvent is heated and pressurized, subjected to gas-liquid separation and dehydration and then to hydrogenation/liquefaction. The CO.sub.2 -containing gas produced in the preheating/dehydration step and/or a CO.sub.2 -containing gas supplied from outside the system is blown into the slurry in the above-mentioned preheating/dehydration step, whereby carbonate-forming metal components in the brown coal are converted to the carbonates thereof in advance. In this manner, the hydrogenation/liquefaction efficiency is improved, and stabilized long-term continuous operation is attained.

Abstract: A process for treating a fuel oil feedstock that is contaminated with water and a large amount of small particles is provided. Centrifugal separators, mixing tanks and filter presses are used in accordance with a two step separation scheme that permits recovery of a final reject that can be directly disposed of and a treated oil that can be utilized directly as a fuel or that can undergo further treatment is obtained.

Abstract: A liquefaction process for coal or lignite is set forth. In the preferred and illustrated embodiment, coal or lignite is ground to a suitable particle size and placed in a reactor vessel. The reactor vessel is located within a pressure vessel. Pressure in the vessel is reduced to about 10.sup.-2 torr.Heat is applied. One procedure is to convert the carbon (in the coal or lignite) at an elevated temperature (600.degree.-900.degree. F.) in the presence of hydrogen (at pressures as high as 2,000 psi) into a hydrocarbon mix; depressurization avoids making various oxides and nitrides, and also can be optionally carried out in the presence of iron or iron ore in particulate form acting as a catalyst.

Abstract: A process for the conversion of high boiling saturated organic materials is described. The method comprises contacting said high boiling organic materials at a temperature of at least about 300.degree. C. and at a reaction pressure of at least about 2000 psi with an aqueous acidic medium containing at least one olefin, and a halogen-containing compound selected from the group consisting of a halogen, a hydrogen halide, a compound which can form a halide or a hydrogen halide in the aqueous acidic medium under the process conditions, or mixtures thereof whereby the high boiling organic material and aqueous acidic medium form a substantially single phase system. Optionally the process can be conducted in a reducing atmosphere. The process of the invention is useful for producing and recovering fuel range liquids from petroleum, coal, oil shale, shale oil, tar sand solids, bitumen and heavy hydrocarbon oils such as crude oil distillation residues which contain little or no carbon-carbon unsaturation.