Abstract: A gas-separation membrane module assembly and a gas-separation process using the assembly. The assembly includes a set of tubes, each containing gas-separation membranes, arranged within a housing. The housing contains tube sheets that divide the space within the housing into three separate, gas-tight spaces, with the tubes mounted in the central space. Within this space, each tube has an aperture or hole in its wall that enables gas that has been retained on the feed side of the membranes to flow out of the tubes and into the space. The assembly can be used in various ways to carry out gas separation processes.

Abstract: A membrane has a permeate channel including a 3D spacer fabric having an upper and a lower fabric surface (2,3) spaced apart by monofilament thread (4) at a predefined distance, the permeate channel being interposed between two membrane layers (12, 13), wherein the membrane layers are linked at a multitude of points with the upper and lower fabric surfaces to form an integral structure with a high bonding strength suitable for backflush operations. A method provides an integrated permeate channel membrane, including the steps of:—Providing a 3D spacer fabric having an upper and lower surface fabric (2,3) spaced apart by monofilament thread (4) at a predefined distance; and—Applying a membrane layer to both the upper and the lower surface fabric.

Abstract: A polymetaphenylene isophthalamide porous hollow fiber membrane is produced by extruding a film-forming solution comprising polymetaphenylene isophthalamide, polyvinylpyrrolidone and an inorganic salt through a concentric double annular spinning nozzle while keeping the film-forming solution at 70° C. or higher, thereby conducting dry-and-wet spinning, followed by moisture retention treatment, where it is preferable to subject the resulting porous hollow fiber membrane obtained by dry-and-wet spinning to heat treatment in water at 80° C. or higher before the moisture retention treatment. The polymetaphenylene isophthalamide porous hollow fiber membrane resulting from wet heat treatment under wet heat conditions at the temperature of 100° C.

Abstract: Membranes for use in methods and apparatuses for hemodialysis and hemofiltration are composed of at least one polyarylethernitrile block copolymer having structural units of formula I wherein Z is a direct bond, O, S, CH2, SO, SO2, CO, RPO, CH2, alkenyl, alkynyl, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical or a combination thereof; R is a C6-12 aromatic radical or a C1-12aliphatic radical; R1 and R2 are independently H, halo, nitro, a C1-C12aliphatic radical, a C3-C12cycloaliphatic radical, a C3-C12aromatic radical, or a combination thereof; a is 0, 1, 2 or 3; b is 0, 1, 2, 3 or 4; and m and n are independently 0 or 1.

Abstract: In a hollow fiber membrane flat module according to the present invention, both ends of hollow fiber membrane bundle which are formed by bundling a plurality of hollow fiber membrane as a sheet are fixed to two housing separately by a fixing resin while maintaining an opening condition in an opening end section in the follow fiber membrane. Furthermore, a maximum width in an orthogonal direction to a longitudinal direction of the hollow fiber membrane is no longer than 25 mm in a cross section which is orthogonal to a longitudinal direction of the housings, and a maximum deflection in the housings which are measured according to a method for measuring the deflection according to the present invention is not more than 1% of a distance between the two housings.

Abstract: A method for hemodialysis and hemofiltration includes contacting blood with a porous membrane in a hollow fiber or flat sheet configuration. The membrane comprises a polyarylethernitrile sulfone having structural units of formula I wherein R1 and R2 are independently H, nitro, a C1-C12 aliphatic radical, a C3-C12 aromatic radical, or a combination thereof; a is 0, 1, 2 or 3; b is 0, 1, 2, 3 or 4; and m and n are independently 0 or 1.

Abstract: In accordance with the present invention, there are provided methods for improving performance of hollow fiber filtration membrane modules. Invention methods comprise a unique backwashing technique wherein the hollow fiber membranes within the module are pressurized with a gas on the feed side at specified times during the backwash. Periodic use of invention methods effectively removes fouling components from the hollow-fiber membranes, thereby providing stable permeability and low trans-membrane pressures, which results in an efficient and economic filtration process. In addition, there are provided methods for cleaning hollow fiber membranes and increasing filtrate flow rate through membranes.

Abstract: A hollow fiber membrane cartridge comprising a bundle of multiple hollow fiber membranes arranged so as to be vertical in an immersion vessel and comprising bond fixing layers capable of bond fixing of the hollow fiber membrane bundle at both ends thereof, wherein the morphology of each of the bond fixing layers is selected from the group consisting of a triangle, a rectangle and a hexagon, and wherein at least an edge of upper side bond fixing layer, the hollow of the hollow fiber membranes opens, and wherein the hollow fiber membrane bundle at a filtration zone side interface of the upper side bond fixing layer is in the form of multiple wisps.

Abstract: Polymer fibers having a novel cross-sectional geometry are used as stationary phase materials for liquid chromatography separations. Fibers of 20 to 50 micrometer diameters have surface-channel structures extending their entire lengths. Bundles of fibers having this novel cross-sectional geometry are packed in columns. Different polymer compositions permit the “chemical tuning” of the separation process. Channeled fibers composed of polystyrene and polypropylene have been used to separate mixtures of polyaromatic hydrocarbons (PAHs), Pb-containing compounds and fatty acids. Use of channeled fibers allows a wide range of liquid flow rates with very low backing pressures.

Abstract: A porous polyethylene hollow fiber membrane having a pore-size gradient across the inner and outer surfaces thereof is prepared by introducing, during the cooling step of a melt-spun polyethylene hollow fiber, a nitrogen flow and a solvent having a boiling point in the range of 30 to 80° C. to the inner and outer surfaces of the melt-spun hollow fiber, respectively.

Abstract: Separator apparatus for removing an impurity or contaminant, such as oil or heavy metals, from a fluid, such as a liquid or a gas, comprises a body member having a fluid inlet and a fluid outlet, a fluid flow channel for the flow of fluid through the body member from the fluid inlet to the fluid outlet, a plurality of perforated or fluid pervious hollow members, such as spheres or balls, located in the fluid flow channel, wherein at least some of the hollow members contain a fluid treatment medium capable of removing the impurity or contaminant from the fluid as the fluid flows through the fluid flow channel. A fluid pervious or perforated hollow member loaded with a fluid treatment medium is also provided. A method for removing an impurity from a fluid is further provided.

Abstract: The present invention provides a method for sterilizing a blood purifier, which method is effective to decrease the amounts of extracts from the blood purifier attributed to the deterioration of the selectively permeable separation membranes with time during and after exposure to a radioactive ray or an electron ray, and which method is highly reliable in safety when employed for hemocatharsis therapy. The present invention also provides a blood purifier package. The present invention relates to a method for sterilizing a blood purifier which comprises substantially dried selectively permeable separation membranes as a main component, by way of the exposure of the same blood purifier to a radioactive ray and/or an electron ray, and this method is characterized in that the blood purifier is sealed in a packaging bag, together with an oxygen scavenger and a humectant or together with an oxygen scavenger capable of releasing a moisture, and is then sterilized in such a sealed state by the above exposure.

Abstract: A concentrator is used for concentrating a fluid, particularly a plasma component out of blood, for treatment of a patient. The concentrator apparatus includes a main housing defining a centrifuge chamber, that also holds the filter. The concentrator allows viewing of the fluid after centrifuging, with an outlet port positionable at a height corresponding to the level of the fraction of the fluid to be further concentrated. Once the fluid is centrifuged, a portion of the fluid is drawn through the outlet, and then pressured past the filter to further concentrate the fluid using the same vessel as used for centrifuging. The same plunger is preferably used to draw centrifuged fluid from the centrifuge chamber as to pressure the centrifuged fluid past the filter.

Abstract: A porous membrane for water treatment of the present invention is made of a resin composition containing 100 parts by weight of a polyvinylidene fluoride based resin, and 5 to 13 parts by weight of a polyvinyl alcohol based polymer having a degree of saponification of 10 to 80 mol %. The porous membrane has a permeation wetting tension of 38 to 72 mN/m, and a tensile strength of 7 to 20 MPa, and thus is characterized by having the excellent mechanical strength and wettability. This is a porous membrane for water treatment essentially containing the polyvinylidene fluoride based resin, which allows water treatment to be highly efficiently performed on raw water (river water, industrial waste water, and the like), in particular.

Abstract: There is provided a porous membrane of vinylidene fluoride resin which has pores of appropriate size and distribution and also excellent mechanical strength represented by tensile strength and elongation at break and is useful as a microfiltration membrane or a separator for batteries. The porous membrane of vinylidene fluoride resin is characterized by the presence in mixture of a crystalline oriented portion and a crystalline non-oriented portion as confirmed by X-ray diffraction, and is produced by subjecting a melt-extruded composition obtained by mixing a vinylidene fluoride resin having a molecular weight distribution which is appropriately broad and high as a whole with a plasticizer and a good solvent for vinylidene fluoride resin, to cooling for solidification from one surface, extraction of the plasticizer and stretching.

Abstract: A method and apparatus for reducing the effect of integrity loss in a hollow fiber membrane module, said module including a plurality of hollow fiber membranes (5), at least one end of the fiber membranes (5) being supported in a pot (6), the method including the step of increasing flow resistance of the liquid through the lumen (8) of the fiber membrane (5) in the region of the pot (6).

Abstract: A membrane composition comprising an inorganic substrate which has a coating of an associating polymer. The membrane composition includes an inorganic substrate selected from the group consisting of a porous silica hollow tube, an alumina hollow tube and a ceramic monolith.

Abstract: A method and apparatus for ultrafiltration of blood operating by removing blood from a peripheral blood vessel at a rate of less than two percent of total cardiac output of a patient, extracting fluid at a rate of 0.1 liter to 1.0 liters per hour while retaining cells and proteins in the blood, and returning the concentrated blood to a secondary blood vessel is disclosed. Blood is removed and returned using small gage needles. As a pump circulates blood from the patient, a filter removes ultrafiltrate from the blood using duty cycle or pump control, and a transparent container collects the removed fluid.

Abstract: A filtering apparatus having a vessel and a filter made from fluororesin and treated before filtering operation by at least one of adding thermal treatment in gas or liquid and penetrating with fluid composed of hot water or steam at a temperature of less than melting point of the fluororesin.

Abstract: There is provided a high efficient gas separation membrane of two or more layers, which comprises a separating layer of 3-dimensional nanostructure and a supporting layer, wherein the 3-dimensional nanostructure can maximize a surface area per unit permeation area.

Abstract: The invention relates to a membrane that consists of a polymer or a polymer mixture. The aim of the invention is to produce membranes, especially planar membranes or hollow fiber membranes that have an as high a separation efficiency as possible while simultaneously having a high membrane efficiency. To this end, the membrane has a gas- or liquid-permeable bicontinuous foam structure with orifices in the interior whose diameters do not exceed 500 nm.

Abstract: A membrane contactor includes a housing, a stack of membrane mats, and a cap. The housing has a closed end and an open end. The closed end includes an outlet port. The cap is united to the open end and includes an inlet port. A stack of membrane mats is within the housing stacked substantially perpendicular to the longitudinal axis of the housing. Each membrane mat has a plurality of hollow fiber members. A potting material bonds the membrane mats to each other and simultaneously bonds one end of the stack to the closed end and bonds the other end of the stack to the cap. The potting material forms an internal chamber and at least one external chamber within the housing. The hollow fiber members extend through the potting material from the internal chamber into the external chambers. The inlet port and the outlet port are in communication with the internal chamber. At least one side port is in communication with the external chambers.

Abstract: A process for the manufacture of a polyimide hollow fibre comprising: (i) providing a dope solution comprising one or more polyimides dissolved in a solvent comprising 60-100 wt % N-methylpyrollidone and 0-40 wt % ethanol, (ii) providing a bore fluid, (iii) generating a tube of the dope solution filled with the bore fluid, (iv) bringing the product of step (iii) into contact with a coagulation solvent to form a hollow fiber.

Abstract: An apparatus for filtering a liquid in a tank has a plurality of elements and a frame for holding the elements while they are immersed in the liquid. The elements have a plurality of hollow fibre membranes attached to and suspended between an upper header and a lower header. The membranes are in fluid communication with one or more permeate channels in one or more of the headers. Releasable attachments between the headers and the frame allow the frame to releasably hold the elements by their headers. The size and configuration of the frame determines the positions of the upper and lower headers of each element relative to each other. Connections between the permeate channels and one or more permeate collection tubes attached to the frame are releasable and resealable connections which are made or broken automatically by the movements involved in inserting or removing an element into or out of the frame.

Abstract: A filter for an extracorporeal blood circuit including a bundle of hollow fibers having an end section encased in a potting material, wherein the end section of potting material has an end surface with open ends of the fibers distributed throughout the end surface, and a filter header cap having an inlet connectable to a blood line and an open end sealed around a side surface of the end section of the bundle of hollow fibers.

Abstract: An air dehydration membrane is made of a hydrophilic polymer having a permeability for water vapor which is greater than its permeability for air, and having low selectivity between oxygen and nitrogen. The membrane has a hydrophilic coating, which itself may be a polymer. The coating does not affect the selectivity of the coated membrane with respect to oxygen and nitrogen, but does increase selectivity of the membrane with respect to water vapor. A preferred material for the membrane is polysulfone. Preferred materials for the coating are poly vinyl alcohol and Triton X-100. The membrane is selected such that the dominant mechanism for gas flow through the membrane is Knudsen flow. The membranes are made at low cost, and can outperform existing commercial membranes in either volumetric productivity or product recovery.

Abstract: A hollow fiber membrane module using a sheet-form hollow fiber membrane having excellent cleaning properties in which the pressure resistance of a hollow fiber membrane anchor section does not deteriorate, even when the membrane area increases; a hollow fiber membrane module unit using the module; a membrane filtration device using the unit; and an operation method therefor are provided. The hollow fiber membrane module comprises sheet-form hollow fiber membranes and an anchoring member which anchors the sheet-form hollow fiber membranes in a roughly parallel manner while maintaining in an open state at least one end portion of the sheet-form hollow fiber membranes. The shape of an end face of a side of the anchoring member from which the hollow fiber membranes are exposed is roughly rectangular, and the shape of an end face of a side of the anchoring member toward which the hollow fiber membranes open is roughly circular.

Abstract: A microfluidic sieve having a substrate with a microfluidic channel, and a carbon nanotube mesh. The carbon nanotube mesh is formed from a plurality of intertwined free-standing carbon nanotubes which are fixedly attached within the channel for separating, concentrating, and/or filtering molecules flowed through the channel. In one embodiment, the microfluidic sieve is fabricated by providing a substrate having a microfluidic channel, and growing the intertwined free-standing carbon nanotubes from within the channel to produce the carbon nanotube mesh attached within the channel.

Abstract: A separation membrane module having hollow fibers, wherein a plurality of hollow fibers are heated and melted to bond and thermally fuse the external surfaces of the hollow fibers with each other; and a method of manufacturing a separation membrane module having hollow fibers whereby the ends of a plurality of hollow fibers are inserted into a sheath, the sheath and the hollow fibers are tightly bonded together to form spaces, and the sheath portion into which hollow fibers have been inserted is heated up to the temperature at which the surfaces of the hollow fibers melt, with the spaces thus formed kept in a decompressed state, so that the exterior surfaces of the hollow fibers are thermally fused and integrated together.

Abstract: A curved hollow fiber membrane comprises a support and a film. The support is curved before being coated with the film. The membrane may be used, for example, in a filtration module.

Abstract: A membrane filtration manifold for connecting a filter submodule including one or more elongate bundles of semipermeable polymeric fibers is provided. The manifold includes a housing and connecting collar connected with said housing. The collar is adapted to receive and locate the submodule, where the submodule has a connecting sleeve with a locking formation. The submodule can be secured at one end to the collar by a clip adapted to engage both the collar and the locking formation to prevent axial withdrawal of the submodule from the collar. Also disclosed is a membrane filtration apparatus including a filter submodule including one or more elongate bundles of semipermeable polymeric fibers. The apparatus further includes a membrane filtration manifold removably connected at one end of said filter submodule and a basepiece removably connected to the other end of said filter submodule.

Abstract: The instant invention is a hollow fiber membrane contactor, and method of making same. The hollow fiber membrane contactor includes (1) a shell, said shell having a internal bonding surface, an interlocking geometry ring being provided on said internal bonding surface; (2) a unitized structure; (3) a potting material joining said unitized structure to said shell at said interlocking geometry ring thereby forming an interlocking seal therebetween; and (4) end caps, said end caps being adjoined to lateral ends of said shell. The method of making a hollow fiber membrane contactor includes (1) providing a shell, said shell having a internal bonding surface; (2) providing an interlocking geometry ring on said internal bonding surface; (3) forming a unitized structure; (4) placing the unitized structure into said shell (5) potting said unitized structure to said shell at said interlocking geometry ring thereby forming an interlocking seal therebetween; and (6) adjoining end caps to lateral ends of said shell.

Abstract: The object of the present invention is to provide a porous membrane having a high strength and excellent water permeability and rejection properties. The porous membrane of the present invention has both a three-dimensional network structure and a spherical structure. The porous membrane of the present invention is suitably used for water treatment membranes, battery separators, charged membranes, fuel cells, blood purification membranes, and the like.

Abstract: The invention pertains to a device for the condensation of water from an aqueous liquid by using a temperature gradient, which device includes: (a) a vapor chamber that can be brought in contact with a condensation compartment wherein at least part of the water vapor from the aqueous liquid condenses, and wherein inside of said vapor chamber is located (b) an evaporation compartment having a least a wall with an outer surface and which includes a closed, hollow and water permeable membrane wherein the vapor chamber has an outer surface that includes a substantially water-impermeable insulation skirt with an inner and an outer surface, such that there is a gap between the inner surface of the insulation skirt and the outer surface of the evaporation compartment, and wherein the vapor chamber has a lower surface of an active width (w) which is at least 10% of the effective diameter (d) of the evaporation compartment.

Abstract: A catchment header allowing a plurality of membrane modules to be connected thereto, having a tubular catchment part with a Young's modulus of 4.0 GPa or less for collecting and taking out filtrated liquid from the membrane modules, wherein at least a part of the tubular catchment part is covered with a reinforcement member with a Young's modulus of 4.0 to 250 GPa, the tubular catchment part of the catchment header is preferably formed of a synthetic resin, and the cross sectional area thereof perpendicular to the longitudinal direction of the tubular catchment part is preferably 4 to 36 cm2.

Abstract: A method is provided for measuring the local hydraulic permeability, Lpi, of a sub-group of hollow fibres of a bundle of hollow fibres mounted in a tubular casing. The method comprises a step of placing the casing containing the bundle in a vertical position, the lateral opening of the casing being disposed toward the bottom, and sealing the lower end of the casing. A graduated, calibrated tube is applied in a vertical position over a portion of the upper cut surface of the bundle to form a sealed connection there between. A liquid is passed through the lateral opening of the casing at a defined flow rate, and the time required for the liquid to pass from a first graduation to a second graduation of the tube is measured.

Abstract: A hollow fiber membrane module comprising a large number of hollow fiber membranes contained in a cylindrical case, wherein one end of each hollow fiber membrane, which is left open, is fixed to the cylindrical case, while the other ends of the hollow fiber membranes are divided into more than one small bundles, with the ends, contained in separate small bundles, being kept together and plugged.

Abstract: The preparation and use of novel porous poly(aryl ether) articles is disclosed. The porous articles are prepared from blends of poly(aryl ether) polymers with polyimides by selectively decomposing the polyimide phase. The preferred reagents used to decompose the polyimide phase include monoethanolamine and tetramethylammonium hydroxide. The porous articles can be configured as a single layer or as a multilayer article. The porous articles of the present invention are unique that at least one of the layers exhibits a narrow pore size distribution. The articles of the present invention can be used as a porous media for a broad range of applications, including porous membranes for fluid separations, such as microfiltration, ultrafiltration, and gas separation, as a battery separators, and as a sorption media.

Abstract: The invention relates to a terpolymer of tetrafluoroethylene (TFE) monomer, polyvinylidene fluoride (PVDF) monomer and hexafluoropropylene (HFP) monomer for forming an ultrafiltration or microfiltration membrane, method of forming said membranes, and to the ultrafiltration or microfiltration membranes themselves. The invention also relates to a method of forming a polymeric ultrafiltration or microfiltration membrane including preparing a leachant resistant membrane dope which incorporates a leachable pore forming agent, casting a membrane from the dope and leaching the pore forming agent from the membrane. The invention also relates to a method of preparing a polymeric ultrafiltration or microfiltration membrane of improved structure including the step of adding a nucleating agent to the membrane dope before casting.

Abstract: This invention provides an inexpensive hollow-fiber membrane module that can prevent diaphragms from peeling or coming off from the cylindrical casing. The invention includes a hollow-fiber membrane module, comprising a cylindrical casing having an inlet port for the treating liquid at one end and an outlet port for the treating liquid at the other end, a hollow-fiber membrane bundle contained in the cylindrical casing, potting layers for fixing the hollow-fiber membrane bundle to the inner wall of the cylindrical casing at both the ends of the hollow-fiber membrane bundle, a header having an outlet port for the liquid undergoing treatment provided at one end of the cylindrical casing, and a header having an inlet port for the liquid undergoing treatment provided at the other end of the cylindrical casing, wherein baffle cylinders having slits extending in the direction at an angle to the axis of the cylindrical casing are fitted in the potting layers.

Abstract: A filter device has a housing in the shape of a tubular section, with at least two chambers separated from one another by membranes, and with at least one connection for each flow chamber. The device has two filter caps, with one of each of the filter caps being located on each of the two end regions of the housing, and connected directly or indirectly thereto. All connections for the flow chambers are positioned on the tubular section in order to avoid tolerance variations that frequently occur during installation of the filter device.

Abstract: A separation column for chromatography or a medium for solid phase extraction, which comprises a hollow capillary and a collected body packed in the hollow capillary and serving as a stationary phase, the collected body comprising long fibers having an adsorbing ability selective towards a target solute and arranged in the axial direction of the capillary, and a sample injection system which comprises the foregoing hollow capillary incorporated into a loop of a valve or a passage connecting two valves, the valve(s) being used as an injector for the chromatography. The use of the polymeric long fibers, which have chemical structures specially designed so that they can specifically interact with a target substance (a solute or an analyte) to be analyzed, permits the selective or preferential extraction and/or concentration of the solute.

Abstract: The invention relates to a method for producing a hydrolytically stable polyamide membrane having an open-pored, microporous and sponge-like support-layer structure, using a process involving thermally induced liquid-liquid phase separation. A solution of an aliphatic polyamide in a solvent system, comprising preferably a solvent and a non-solvent for the polyamide, is extruded to form a shaped object. After leaving the die, the shaped object is cooled by means of a cooling medium until phase separation occurs and the polymer-rich phase solidifies to form the membrane structure. The solution of the polyamide in the solvent system contains an antioxidant agent as a stabiliser for the polyamide which, together with the solvent system, is selected in a way that the antioxidant agent is essentially insoluble in the solvent system at the phase separation temperature.

Abstract: An in-vivo plasmapheresis and/or in-vivo ultrafiltration membrane comprises elongated hollow fibers each fiber having an interior lumen extending along the fiber length, the fiber wall having a plurality of zones between the inner and outer wall surfaces, each of the zones having a mass density different than the mass density of an adjacent zone. The fiber wall is characterized by having a lower mass density zone at the inner wall surface and a higher mass density zone at the outer wall surface. The fiber is further characterized by having an average elongation breaking force strength of at least about 0.2 lbs. and an average elongation of at least about 45%.

Abstract: The invention relates to a hollow membrane (11) comprising two support layers arranged one above the other forming a space between them and a plurality of capillary tubes arranged between the support layers forming capillary channels for the flow of a first fluid, the space between the capillary tubes forming an internal cavity for the circulation of a second fluid around the capillary tubes, and the whole assembly being made of an organic polymer. These membranes (11) can be assembled into modules for the treatment of a fluid with intermediate porous panels (13).

Abstract: A method of producing a hollow fiber membrane includes discharging a polyvinylidene fluoride solution comprising a polyvinylidene fluoride resin and a poor solvent at a temperature above a phase separation temperature into a cooling bath at a temperature below the phase separation temperature to coagulate the polyvinylidene fluoride resin. The hollow fiber membrane comprises a polyvinylidene fluoride resin having spherical structures that have an average diameter in the range of 0.3 to 30 ?m.

Abstract: The invention discloses a method for synthesizing hollow structured freestanding membrane having pore size of 2 to 200 nm which provides long-term stability that makes it viable for many practical applications such as protein separation and drug delivery.

Abstract: Functionalized porous poly(aryl ether ketone) articles are prepared by reacting ketone groups in the backbone of poly(aryl ether ketone) polymer with a primary amine reagent. Preferred functional primary amines are primary aliphatic amines or substituted hydrazines containing one or more target functional groups including polar groups, such as hydroxyl groups, ˜OH, amino groups, ˜NH2, ˜NHR, ˜NRR?, and ethylene oxide groups, ˜OCH2CH2—, negatively or positively charged ionic groups, such as ˜SO3?, ˜COO?, and ˜NH4+ groups, hydrophobic groups such as siloxane or perfluorcarbone groups, and non-polar groups, such as linear or branched hydrocarbon groups. The functionalized porous poly(aryl ether ketone) article can be prepared by reacting primary amine with a pre-formed, shaped porous poly(aryl ether ketone) article or by functionalizing the surface of a non-porous precursor article that is subsequently converted into a porous article.

Abstract: A defect free semipermeable composite membrane having outstanding integrity and high water permeability is provided. Said composite membrane comprises an inside support layer to provide sufficient mechanical strength, an outside barrier layer to provide selective separation and a middle layer to provide both chemical and physical binding between the support and the barrier layer. Two different methods for making said defect free composite membrane are discovered. These methods have been successfully used to produce high quality coatings and defect free composite membranes, which are independent of chemical composition and physical structure of said support. In the present invention, the ultrasonic sonication is utilized to speed up the phase inversion process of a membrane casting solution, and to produce a composite membrane at a speed higher than that disclosed in the prior art.

Abstract: A multicapillary column especially useful for liquid chromatography and sample preparation comprising a plurality of uniform capillaries coated with an insoluble stationary phase, wherein the thickness of the stationary phase is correlated with the radius of the individual capillaries for high efficiency.