Cyclic Patents (Class 210/500.28)
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Patent number: 12138599Abstract: The present invention provides highly permeable and porous polybenzimidazole membranes, methods of making them, and their application as a high-performance membrane support for gas separation composite membranes. The polybenzimidazole membranes are bonded to a fabric substrate.Type: GrantFiled: July 16, 2021Date of Patent: November 12, 2024Assignee: Battelle Memorial InstituteInventors: David Philip Hopkinson, Lingxiang Zhu
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Patent number: 12091625Abstract: This disclosure relates to CO2-philic crosslinked polyethylene glycol membranes useful for natural gas purification processes. Also provided are methods of using the membranes to remove CO2 and H2S from natural gas.Type: GrantFiled: June 13, 2023Date of Patent: September 17, 2024Assignee: Saudi Arabian Oil CompanyInventors: Benjamin James Sundell, John Alden Lawrence, III, Seth A. Sharber, Sibo Lin, Daniel J. Harrigan
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Patent number: 11986772Abstract: The present invention provides compact spiral-wound filter elements having cassette-like performance. The invention further provides filtration systems (e.g., TFF systems) and processes (e.g., SPTFF processes) employing compact spiral-wound filter elements having cassette-like performance.Type: GrantFiled: March 24, 2022Date of Patent: May 21, 2024Assignee: EMD Millipore CorporationInventor: Jonathan Steen
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Patent number: 11806654Abstract: Disclosed is an air filter and a method of manufacture for an air filter which is much more cost effective and provides greater operational effectiveness than state-of-the-art air filters. The air filter includes an outer metallic shell which may be used to attach the filter in line to ducting of a heating, ventilation, and air conditioning (HVAC) system. The filter may further include a filter unit made of activated carbon material. The filter unit may have one or more sections and may have a honeycomb cross section.Type: GrantFiled: October 14, 2022Date of Patent: November 7, 2023Assignee: Focus Universal Inc.Inventor: Desheng Wang
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Patent number: 11679995Abstract: Synthesis, fabrication, and application of nanocomposite polymers in different form (as membrane/filter coatings, as beads, or as porous sponges) for the removal of microorganisms, heavy metals, organic, and inorganic chemicals from different contaminated water sources.Type: GrantFiled: May 30, 2019Date of Patent: June 20, 2023Assignee: UNIVERSITY OF HOUSTON SYSTEMInventor: Debora F. Rodrigues
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Patent number: 11565217Abstract: The invention pertains to a polyaryl ether sulfone polymer solution [solution (SP)] comprising: —at least one sulfone polymer [polymer (PSI)] having recurring units, wherein more than 50% moles, with respect to all the recurring units of polymer (PSI), are recurring units (RPSI) selected from the group consisting of those of formulae (RPSI-1) and (RPSI-2) herein below: (RPSI-1) (RPSI-2) wherein: —each of E?, equal to or different from each other and at each occurrence, is selected from the group consisting of those of formulae (E?-1) to (E?-3): (E?-I) (E?-II) (E?-III) —each R? is independently selected from the group consisting of halogen, alkyl, alkenyl, alkynyl, aryl, ether, thioether, carboxylic acid, ester, amide, imide, alkali or alkaline earth metal sulfonate, alkyl sulfonate, alkali or alkaline earth metal phosphonate, alkyl phosphonate, amine and quaternary ammonium; and —j? is zero or an integer of 1 to 4; is a bond or a divalent group optionally comprising one or more than one heteroatom; preferablyType: GrantFiled: March 14, 2017Date of Patent: January 31, 2023Assignee: SOLVAY SPECIALTY POLYMERS ITALY S.p.A.Inventors: Emanuele Di Nicolo′, Pasquale Campanelli, Narmandakh Taylor
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Patent number: 11420916Abstract: The present disclosure pertains to methods and systems for separating olefins from a mixture that includes olefins and non-olefins. The methods include associating the mixture with a support that is embedded with an ionic liquid and a metal ion. The ionic liquid prevents the substantial reduction of the metal ion by reducing agents while the metal ion mediates the transport of the olefin through the support by selectively and reversibly coupling with the olefin. In some embodiments, the support may be in the form of supported ionic liquid porous membranes, and the ionic liquid may be held within the pores of the support by capillary forces. In some embodiments, the support may be in the form of a composite, and the ionic liquid may be dispersed throughout the composite. In some embodiments, the metal ion may be dissolved in the ionic liquid and dispersed throughout the support.Type: GrantFiled: June 10, 2019Date of Patent: August 23, 2022Assignee: Board of Regents, The University of Texas SystemInventors: Joan F. Brennecke, Benny D. Freeman, Constanza Miguel Sanchez
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Patent number: 11208611Abstract: A lubricating oil composition comprising at least 50 percent by mass, based on the mass of the composition of an oil of lubricating viscosity and 0.01 to 25 percent by mass, based on the mass of the composition of a polymer comprising units (a) and one or both units (b) and (c): —N(COR1)(CH2)x—??(a) —NH(CH2)y—??(b) —N(CH2CH2-k(CH3)kCOOR2)(CH2)z ??(c) where the total number (n) of units (a), (b) and (c) is an integer between 4 and 500; wherein x, y and z are independently 2 or 3; wherein k is zero or 1. The polymer shows good solubility in the lubricating oil and provides friction modification. A method of synthesising a polymer is also disclosed.Type: GrantFiled: May 26, 2020Date of Patent: December 28, 2021Assignee: Infineum International LimitedInventors: Anthony J. Strong, Beatrice N. Cattoz, Andrew D. Schwarz, Remzi Becer, Ben Drain
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Patent number: 11167249Abstract: An object of the present invention is to provide a separation membrane having high permeability and selective removability of divalent/monovalent ions. The separation membrane of the present invention includes a supporting membrane and a separation functional layer formed on the supporting membrane, in which the separation functional layer contains a polymerized product of a polyfunctional amine with a polyfunctional acid halide, the polyfunctional amine contains a polyfunctional aliphatic amine as a main component, the separation functional layer has a hollow protuberant structure, and the separation functional layer has a relative surface area of 1.1-10.0.Type: GrantFiled: July 29, 2016Date of Patent: November 9, 2021Assignee: TORAY INDUSTRIES, INC.Inventors: Masakazu Koiwa, Ryoma Miyamoto, Hiroaki Tanaka, Koji Nakatsuji, Kentaro Takagi
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Patent number: 10851241Abstract: Multicomponent copolymers including two or more types of repeat units is presented. In one example, the multicomponent copolymer includes at least one repeat unit AC having a structure (I), at least one repeat unit DC having a structure (II), and at least one repeat unit BC having a structure (III) or (V). The multicomponent copolymer may be cross-linked via a cross-linking agent. A polymer blend including the multicomponent copolymer or a cross-linked copolymer and a second polymer is also provided. The multicomponent copolymer may be a random or a block copolymer. The structural units of the multicomponent copolymers provide improved, tunable properties, such as improved biocompatibility and hydrophilicity, protein fouling, and mechanical properties, to the copolymers and/or the membranes fabricated from the copolymers.Type: GrantFiled: May 15, 2018Date of Patent: December 1, 2020Assignee: Cytiva Sweden ABInventors: David Moore, Matthew Jeremiah Misner, Hongyi Zhou, Patrick McCloskey, Matthew Rainka
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Patent number: 10434479Abstract: The present invention relates to a composite membrane for gas separation and/or nanofiltration of a feed stream solution comprising a solvent and dissolved solutes and showing preferential rejection of the solutes. The composite membrane comprises a separating layer with intrinsic microporosity. The separating layer is suitably formed by interfacial polymerization on a support membrane. Suitably, at least one of the monomers used in the interfacial polymerization reaction should possess concavity, resulting in a network polymer with interconnected nanopores and a membrane with enhanced permeability. The support membrane may be optionally impregnated with a conditioning agent and may be optionally stable in organic solvents, particularly in polar aprotic solvents. The top layer of the composite membrane is optionally capped with functional groups to change the surface chemistry. The composite membrane may be cured in the oven to enhance rejection.Type: GrantFiled: October 18, 2012Date of Patent: October 8, 2019Assignee: IP2IPO Innovations LimitedInventors: Andrew Guy Livingston, Maria Fernanda Jimenez Solomon
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Patent number: 10357747Abstract: A method for producing a spiral wound separation membrane element includes preparing a composite semipermeable membrane having a skin layer on the surface of a porous support. The method further includes forming on the skin layer a protective layer containing 35 mg/m2 or more of an anionic polyvinyl alcohol to prepare a protective layer-equipped composite semipermeable membrane, preparing an unwashed spiral wound separation membrane element from the protective layer-equipped composite semipermeable membrane, and passing wash water through the unwashed spiral wound separation membrane element to remove the protective layer on the skin layer.Type: GrantFiled: September 30, 2016Date of Patent: July 23, 2019Assignee: NITTO DENKO CORPORATIONInventors: Shinya Nishiyama, Taisuke Yamaguchi, Takahisa Konishi, Hiroki Fujioka, Takashi Kamada, Shinichi Inoue
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Patent number: 10352833Abstract: A microextraction capsule holding a sol-gel coating or monolithic bed with an affinity for one or more target analytes infused in a porous tube that can be placed in a sample matrix containing the target analytes. The microextraction capsule can include a magnetic wire to allow the capsule to be spun in the presence of the matrix to increase the rate of absorption of the target analytes. The microextraction capsule can be formed by infusing a sol solution into the porous tube and forming a metal oxide or hybrid inorganic-organic sorbent comprising gel from the sol within the pores of the porous tube or by forming a gel by sol-gel condensation with water followed by grinding the gel to a particulate gel and infusing the particles into a porous tube.Type: GrantFiled: July 22, 2015Date of Patent: July 16, 2019Assignee: THE FLORIDA INTERNATIONAL UNIVERSITY BOARD OF TRUSTEESInventors: Abuzar Kabir, Kenneth G. Furton
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Patent number: 10124297Abstract: A thin film nanocomposite nanofiltration membrane or TFC-NF membrane includes an ultrafiltration support membrane coated with a trimesic acid coating layer. The trimesic acid coating layer is formed or self-assembled on the ultrafiltration support membrane by pouring an aqueous solution of a water soluble tertiary amine on the support membrane to form a first coating layer and then applying a solution of trimesolychloride on the first coating layer. In other words, the trimesic acid coating layer can be formed as a result of the liquid-liquid interface of the water soluble tertiary amine and the trimesolychloride. A total thickness of the TFC-NF membrane can be about 150 ?m. The thin film nanocomposite nanofiltration membrane can be free from MPD monomers.Type: GrantFiled: March 6, 2018Date of Patent: November 13, 2018Assignee: KUWAIT INSTITUTE FOR SCIENTIFIC RESEARCHInventors: Rajesha Kumar, Mansour Ahmed, Bhadrachari Garudachari, Jibu P. Thomas
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Patent number: 9675941Abstract: The present invention relates to the synthesis of linear aromatic polyimides and the production of membranes for the separation of gases. Specifically, polyimides featuring in their chemical structure, in the part derived from a diamine, 4-fluoro-4?,4?-diaminotriphenylmethane, and an aromatic dianhydride derived from tetracarboxylic acid. Polyimides are soluble in amidic solvents such as N,N?-dimethylformamide, N,N?-dimethylacetamide, N-methyl-2-pyrrolidone, etc., which are processed as dense membranes by controlled evaporation of the solvent. The resulting membranes are capable of separating at least a gaseous mixture constituted by two components such as H2/CH4, He/N2, H2/CO2, O2/N2, CO2/CH4 and CO2/N2.Type: GrantFiled: April 29, 2015Date of Patent: June 13, 2017Assignee: INSTITUTO MEXICANO DEL PETROLEOInventors: Diego Javier Guzman Lucero, Javier Guzman Pantoja, Jorge Froylan Palomeque Santiago
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Patent number: 9647259Abstract: Methods of making a battery component are provided. The method comprises gas phase depositing a composition onto an electrode, the composition comprising a first component and a second component, and removing at least a portion of the second component to form a separator comprising a porous polymer film on the electrode. The first component is selected from the group consisting of polymers, dimers and monomers. In some embodiments, the second component is selected from the group consisting of polymers, dimers and monomers and is different from the first component. The first component and the second component each form separate polymer phases and together form a layer. In some embodiments, the second component is selected from the group consisting of by-products and remaining portions of the first component from the forming the first polymer.Type: GrantFiled: October 31, 2013Date of Patent: May 9, 2017Assignee: Enevate CorporationInventors: Benjamin Yong Park, Alexander Gorkovenko, Rabih Bachir Zaouk, William Hubert Schank, Jr.
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Patent number: 9598598Abstract: Disclosed are methods of preparing antifouling coatings on reverse osmosis membranes with initiated chemical vapor deposition. The coatings enhance the stability and lifetime of membranes without sacrificing performance characteristics, such as permeability or salt retention.Type: GrantFiled: July 7, 2014Date of Patent: March 21, 2017Assignees: Massachusetts Institute of Technology, King Fahd University of Petroleum and MIneralsInventors: Karen K. Gleason, Zafarullah Khan, Hafiz Zahid Shafi, Rong Yang
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Patent number: 9513042Abstract: The heat exchangerless membrane system optimizes heat transfer between a set of two immiscible fluids such that the second of the two immiscible fluids having an additive, notably an additive that makes the second fluid corrosive, is infrequently in contact any heat exchangers that would make the heat exchanger subject to corrosion. This membrane system is capable of separating the two immiscible fluids downstream of the heat transfer process, such that heat transfer can repeat the cycle again in an energy efficient manner.Type: GrantFiled: September 7, 2014Date of Patent: December 6, 2016Inventor: Michael Gurin
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Patent number: 9172075Abstract: A porous polymer battery separator is provided that includes variable porosity along its length. Such battery separators can increase the uniformity of the current density within electrochemical battery cells that may normally experience higher current density and higher temperatures near their terminal ends than they do near their opposite ends. By disposing a variable porosity separator between the electrodes of an electrochemical cell such that its terminal end has a lower porosity than its opposite end, the transport of ions, such as lithium ions, through the separator can be more restricted in normally high current regions and less restricted in normally low current regions, thereby increasing the overall uniformity of current density within the battery cell. Variable porosity battery separators may be produced by a modified solvent exchange process.Type: GrantFiled: December 21, 2010Date of Patent: October 27, 2015Assignee: GM Global Technology Operations LLCInventors: Hamid G. Kia, Xiaosong Huang, Mark W. Verbrugge
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Patent number: 9156933Abstract: The application describes a method of preparing a polymer that includes: mixing in an aqueous solution comprising water and a water-soluble alcohol: a vinyl-based monomer having a sulfonic acid functional group, a bifunctional vinyl-based cross-linking agent, and a polymerization initiator, to form a reaction solution, where the monomer and the cross-linking agent are soluble in the reaction solution; and polymerizing the monomer and cross-linking agent to form the polymer. The application further describes a polymer that includes a polymer backbone comprising sulfonic acid functional groups; and crosslinks comprising alcohol functional groups.Type: GrantFiled: September 13, 2011Date of Patent: October 13, 2015Assignee: General Electric CompanyInventors: Chakravarthy S. Gudipati, Russell James MacDonald
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Publication number: 20150053610Abstract: Described herein are mixed matrix filtration membranes and related, compositions, methods and systems and in particular mixed matrix filtration membranes with an embedded polymer network and/or embedded polymeric micro/nanoparticles functionalized with a functionalization polymer covalently and/or non covalently linked to the micro/nanoparticles and related compositions, methods, and systems.Type: ApplicationFiled: July 30, 2014Publication date: February 26, 2015Inventors: Mamadou S. DIALLO, Madhusudhana Rao KOTTE
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Publication number: 20150021262Abstract: A polymeric membrane on a support, wherein the polymeric membrane includes a crosslinked polymer covalently bound to a molecular cage compound. An interfacial polymerization method for making the polymeric membrane is also disclosed.Type: ApplicationFiled: October 1, 2014Publication date: January 22, 2015Inventors: Jacquana T. Diep, Young-Hye Na, Ratnam Sooriyakumaran, Ankit Vora
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Patent number: 8887927Abstract: A method of preparation for polyimine self-supported dynamic polymeric membranes (called “dynameric” membranes) is provided along with their use in separation processes, especially for separating gaseous species.Type: GrantFiled: March 11, 2010Date of Patent: November 18, 2014Assignee: Centre National de la Recherche ScientifiqueInventors: Gihane Nasr, Mihail-Dumitru Barboiu, Christophe Charmette, José Gregorio Sanchez Marcano
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Publication number: 20140319047Abstract: The disclosure provides a filtration material and a method for fabricating the same. The filtration material includes a supporting layer, and a composite layer, wherein the composite layer includes an ionic polymer and an interfacial polymer. Particularly, the ionic polymer and the interfacial polymer are intertwined with each other, resulting from ionic bonds formed between the ionic polymer and the interfacial polymer.Type: ApplicationFiled: April 23, 2014Publication date: October 30, 2014Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Shu-Hui CHENG, Wei-Cheng TSAI, Shan-Shan LIN, Yu-Chuan HSU, Yin-Ju YANG
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Publication number: 20140299538Abstract: Disclosed are methods of preparing antifouling and chlorine-resistant coatings on reverse osmosis membranes with initiated chemical vapor deposition. The coatings enhance the stability and lifetime of membranes without sacrificing performance characteristics, such as permeability or salt retention.Type: ApplicationFiled: April 7, 2014Publication date: October 9, 2014Applicant: Massachusetts Institute of TechnologyInventors: Karen K. Gleason, Rong Yang
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Publication number: 20140284269Abstract: The present invention relates to a porous ABPBI (phosphoric acid doped poly (2, 5-benzimidazole)) membrane and process of preparing the same. A stable porous ABPBI (Phosphoric Acid Doped Poly (2, 5-benzimidazole)) membrane stable to acids, bases, solvents and autoclaving is disclosed. The membrane finds use for separation of solutes in solution in acids, bases and solvents.Type: ApplicationFiled: March 24, 2014Publication date: September 25, 2014Applicant: Council of Scientific and Industrial ResearchInventors: Ulhas KHARUL, Harshada LOHOKARE
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Publication number: 20140284270Abstract: Synthetic RNA molecules having a pore, compositions including RNA molecules having a pore, where the compositions are capable of filtering metal ions, filtering molecular ions, performing size exclusion chromatography, performing ion specific chromatography, reversible metal ion and molecular ion binding, ion selective membranes, ion selective channels, ion selective/specific sensors, electrical conduits, battery components, etc., and devices and methods for making and using same. The RNAs used may be modified to improve stability. For example, by for example, a methyl group may be attached to the 2? OH of the ribose.Type: ApplicationFiled: September 23, 2013Publication date: September 25, 2014Inventors: George Fox, Quyen Tran, Mario Rivas-Medrano
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Publication number: 20140284267Abstract: A filtration membrane (1) is provided that includes a porous support (4) and a membrane layer having a first and a second zone (2, 3). The first zone (2) has a thickness of 5 to 15 ?m and an average pore opening size of smaller/equal 0.4 and the second zone (3) has a thickness of 5 to 40 ?m and an average pore opening size of 0.5 to 5.0 ?m. The filtration membrane (1) is produced by forming a single- or -double-layer coating on the porous support (4).Type: ApplicationFiled: October 2, 2012Publication date: September 25, 2014Inventors: Gisela Jung, Andreas Bareth, Ulrich Meyer-Blumenroth
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Publication number: 20140263024Abstract: A halogen resistant polyamide is formed from the reaction product of an amine monomer and an acid chloride monomer wherein the amino group of the starting amine monomer is separated from the aromatic amine ring system by an alkyl group and (i) minimizes halogenation on the amine and (ii) minimizes N-halogenation at a pH range of approximately 7 to approximately 10.5. A membrane is made from the polyamide for use, for example, in a reverse osmosis desalination unit.Type: ApplicationFiled: March 14, 2013Publication date: September 18, 2014Inventors: Andrew Patrick Murphy, Robert Lee Riley, Yuliana Elvira Porras Mendoza
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Publication number: 20140238939Abstract: The present invention discloses antimicrobial water treatment membranes, comprising a water treatment membrane, covalently attached to one or more antimicrobial polymers or derivatives thereof, either directly or via one or more tether molecules. There are also provided a process for preparing these antimicrobial membranes, and uses thereof in water treatment applications.Type: ApplicationFiled: June 14, 2012Publication date: August 28, 2014Applicants: WISCONSIN ALUMNI RESEARCH FOUNDATION, BENIGURION UNIVERSITY OF THE NEGEV RESEARCH AND DEVELOPMENT AUTHORITYInventors: Ron Kasher, Shani Avneri, Marina Yamit Lutsky, Jihua Zhang, Samuel Helmer Gellman, Shannon Stahl
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Publication number: 20140224728Abstract: The present disclosure relates to a method of manufacturing a water treatment membrane having high chlorine resistance and high permeability, the method including: forming an aqueous amine solution layer on a porous support, using an aqueous amine solution including a fluorine compound having an epoxy group in a terminal thereof and an amine compound; and forming a polyamide layer containing the fluorine compound by bringing an organic solution containing acyl halide into contact with the aqueous amine solution layer, and a water treatment membrane manufactured using the same.Type: ApplicationFiled: April 18, 2014Publication date: August 14, 2014Applicant: LG CHEM, LTD.Inventors: Jae-Hong KIM, Young-Hoon KO, Chong-Kyu SHIN
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Patent number: 8778186Abstract: The invention provides a method of contacting a membrane having a highly cross-linked polydicyclopentadiene matrix with a feed solution having a) a first component with a molecular weight in the range of from about 100 g mol?1 to about 600 g mol?1 and a cross-sectional area of less than about 0.40 nm2 and b) a second component with a molecular weight in the range of from about 100 to about 600 grams g mol?1 and a cross-sectional area of greater than about 0.50 nm2 so that the feed solution is fractionated into a permeate comprising the first component and a retentate enriched in the second component.Type: GrantFiled: July 11, 2012Date of Patent: July 15, 2014Assignee: University of Iowa Research FoundationInventors: Ned B. Bowden, Abhinaba Gupta, Tyler R. Long
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Patent number: 8739977Abstract: Disclosed herein are a composite semipermerable membrane and a method for producing the same. The composite semipermeable membrane comprises a microporous support membrane and a separation functional layer provided on the microporous support membrane, wherein the separation functional layer contains a condensation product produced by condensation of at least one selected from the group consisting of ions of trialkoxysilanes each having an imidazolium group and a conjugated base of a polymer having at least one acidic group. The composite semipermeable membrane achieves excellent selective separation of divalent ions over monovalent ions, and is suitable for use in various water treatment fields such as seawater desalination and drinking water production.Type: GrantFiled: March 18, 2010Date of Patent: June 3, 2014Assignee: Toray Industries, Inc.Inventors: Hiroki Minehara, Koji Nakatsuji
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Publication number: 20140144833Abstract: The Invention relates to a membrane formed from a blend of high molecular weight polyvinylidene fluoride (PVDF) (>580,000 Mw) with low molecular weight PVDF (<580,000 Mw). Porous membranes of average pore size from 5 nm to 100 microns made from the blend show improved water permeability compared to membranes formed from a single Mw PVDF.Type: ApplicationFiled: August 1, 2012Publication date: May 29, 2014Applicant: Arkema Inc.Inventor: Walter Kosar
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Publication number: 20140110328Abstract: The forward osmosis membrane flow system (1) includes a high osmotic pressure fluid flow section (2) to which a high osmotic pressure fluid is supplied, a low osmotic pressure fluid flow section (3) to which a low osmotic pressure fluid with a lower osmotic pressure than that of the high osmotic pressure fluid is supplied, and a semipermeable membrane (4) that separates the high osmotic pressure fluid flow section and the low osmotic pressure fluid flow section from each other. A flow rate in the high osmotic pressure fluid flow section (2) is increased by an occurrence of fluid migration from the low osmotic pressure fluid flow section (3) into the high osmotic pressure fluid flow section (2) through the semipermeable membrane (4). The semipermeable membrane (4) is a composite semipermeable membrane with a polyamide-based skin layer formed on a porous epoxy resin membrane.Type: ApplicationFiled: June 8, 2012Publication date: April 24, 2014Applicant: NITTO DENKO CORPORATIONInventors: Takao Doi, Osamu Hayashi, Masahiko Hirose, Makoto Kobuke, Yoshihide Kawaguchi, Noriaki Harada
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Patent number: 8678203Abstract: Embodiments in accordance with the present invention provide forming polynorbornenes useful for forming pervaporation membranes, the membranes themselves and methods of making such membranes.Type: GrantFiled: May 21, 2013Date of Patent: March 25, 2014Assignee: Promerus, LLCInventors: Brian Knapp, Edmund Elce, Brian Bedwell, Leah J. Langsdorf, Ryan Wilks
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Publication number: 20140069862Abstract: The present invention is directed to microfiltration and ultrafiltration membranes comprising a microporous material. The microporous material comprises: (a) a polyolefin matrix present in an amount of at least 2 percent by weight, (b) finely divided, particulate, substantially water-insoluble silica filler distributed throughout said matrix, said filler constituting from about 10 percent to about 90 percent by weight of said coated microporous material substrate, (c) at least 20 percent by volume of a network of interconnecting pores communicating throughout the coated microporous material, and (d) at least one coating composition applied to at least one surface of the membrane to adjust the surface energy of the membrane.Type: ApplicationFiled: November 12, 2013Publication date: March 13, 2014Inventors: Qunhui Guo, Carol Knox, Shawn P. Duffy, Luciano M. Parrinello, Nicholas J. Parise, Brian K. Rearick
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Publication number: 20140061121Abstract: A separation membrane includes a membrane comprising a polymer, characterized in that a functional layer is formed on the surface in one side of the membrane, the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface of the preceding functional layer is 0.1% (by atomic number) or more but not more than 10 (% by atomic number), and the peak area percentage of carbon derived from ester group measured by the electron spectroscopy for chemical analysis (ESCA) on the surface opposite to the functional layer is not more than 10 (% by atomic number). A separation membrane module suffering from little sticking of organic matters, proteins, platelets and so on is provided with the separation membrane as a built-in membrane.Type: ApplicationFiled: November 12, 2013Publication date: March 6, 2014Applicant: Toray Industries, Inc.Inventors: YOSHIYUKI UENO, Masaki Fujita, Hiroyuki Sugaya
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Publication number: 20140054227Abstract: The present invention provides a sugar-immobilized polymer substrate for removing a virus, the polymer substrate allowing efficient removal of a hepatitis virus or the like in a fluid, and a method for removing a virus. In particular, the present invention provides a sugar-immobilized polymer substrate for removing a hepatitis virus or the like, the polymer substrate allowing, in the case of an application to blood of a living body, reduction in the amount of blood taken out of the body, reduction in the removal amount of blood useful components, low invasiveness, and shortening of the operation cycle; and a method for removing a virus. A hollow fiber membrane according to the present invention can be used as a module having a function of effectively removing a virus and a function of not removing useful plasma components.Type: ApplicationFiled: February 29, 2012Publication date: February 27, 2014Applicant: DIC CORPORATIONInventors: Naoto Sakurai, Naoya Ikushima, Tetsuro Suzuki
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Publication number: 20140048478Abstract: A polymeric membrane for separating oil from water has a pore size of 0.005 ?m to 5 ?m, a thickness of 50 ?m to 1,000 ?m, a water contact angle of 0° to 60°, an oil contact angle of 40° to 100°. The membrane contains a hydrophobic matrix polymer and a functional polymer that contains a hydrophobic backbone and side chains. The side chains each have an oleophobic terminal segment and a hydrophilic internal segment. The weight ratio of the matrix polymer to the functional polymer is 99:1 to 1:9. Also disclosed is a method of making the above described membrane.Type: ApplicationFiled: April 27, 2012Publication date: February 20, 2014Inventors: Renbi Bai, Xiaoying Zhu
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Publication number: 20130334130Abstract: A conformal coating that resists fouling by waterborne contamination in aquatic environments, a method for fabricating the coating, and a filter having such a coating are disclosed. The coating comprises a hydrophilic polymer and a surfactant wherein the surfactant undergoes a phase change upon exposure to a saline solution. Also disclosed are in situ methods for regenerating anti-fouling filters having the fouling resistant coating.Type: ApplicationFiled: June 14, 2012Publication date: December 19, 2013Inventors: Rahul Ganguli, Vivek Mehrotra, Tony Ten-Luen Liao
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Patent number: 8602221Abstract: [Problems] To provide a novel hydrophilized separation membrane for use in the treatment of a liquid, which comprises an aromatic ether polymer, is less likely to be degraded by sterilization with a high energy ray and has a controlled pore size and a high water permeability. [Means for Solving Problems] A porous separation membrane for use in the treatment of a liquid which is produced by a wet film formation process using an aromatic ether polymer and a hydrophilizing agent. The separation membrane can be used for medical purposes or in a pharmaceutical of food.Type: GrantFiled: August 4, 2006Date of Patent: December 10, 2013Assignee: Asahi Kasei Kabuhiki KaishaInventors: Hitoshi Mizomoto, Junichi Shishido, Shinya Hamasaki, Hirofumi Miura
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Publication number: 20130306550Abstract: A reverse osmosis membrane includes a porous support, a polyamide active layer formed on the porous support, and a coating layer including a copolymer including an amphoteric ionic compound and glycidyl (meth)acrylate. The coating layer makes a chemical bond with the polyamide active layer. A method of manufacturing the reverse osmosis membrane also is disclosed.Type: ApplicationFiled: July 25, 2013Publication date: November 21, 2013Applicant: LG Chem, Ltd.Inventors: Seung-Pyo JEONG, Chong-Kyu Shin
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Patent number: 8550256Abstract: A method of photo-grafting onto a separation membrane a copolymer includes at least one of: and; For example, in Structure 1A, x1?2 and y1?1; R1 and R2 are independently selected from the group consisting of CH3 and H; R3 is independently selected from the group consisting of poly(oxyalkylene), quaternary ammonium salts, pyridinium salts, sulfonium salts, sulfobetaines, carboxybetaines, alcohols, phenols, tertiary amines, aryl groups; linear, branched and cyclic alkylenes; linear, branched and cyclic heteroalkylenes; linear, branched and cyclic fluoroalkylenes; and siloxyl; R4 is independently selected from the group consisting of linear, branched, and cyclic alkylenes; linear, branched and cyclic hetroalkylenes; linear, branched and cyclic fluoroalkylenes; phenyl; and siloxyl; and Z1 is 0 or 1.Type: GrantFiled: July 27, 2012Date of Patent: October 8, 2013Assignee: International Business Machines CorporationInventors: Jacquana T. Diep, Young-Hye Na, Ankit Vora
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Publication number: 20130240437Abstract: The disclosed subject matter provides a filter that is modified by a polymer-carbon based nanomaterial nanocomposite intended to significantly enhance the performance of filtration, separation, and remediation of a broad variety of chemicals, heavy metal ions, organic matters, and living organisms. Polymeric materials, such as but not limited to poly-N-vinyl carbazole (PVK), are combined with (1) graphene (G) and/or graphene-like materials based nanomaterials and (2) graphene oxide (GO) chemically modified with a chelating agent such as but not limited to EDTA. The nanocomposite is homogenously deposited on the surface of the membrane.Type: ApplicationFiled: September 10, 2012Publication date: September 19, 2013Inventors: Debora F. Rodrigues, Rigoberto C Advincula, Fritz Claydon, Catherine M. Santos, Maria Celeste R. Tria
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Publication number: 20130233791Abstract: The present invention relates to a separation membrane for water treatment having high water flux and membrane contamination preventing characteristics, and a manufacturing method thereof. The separation membrane for water treatment according to the present invention includes a nanofiber wherein the separation membrane has a surface electric charge. According to the present invention, a separation membrane for water treatment having high water flux and membrane contamination preventing characteristics, and a manufacturing method thereof may be implemented.Type: ApplicationFiled: October 9, 2012Publication date: September 12, 2013Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGYInventors: Chong Min KOO, Kyung Youl BAEK, Seung Sang HWANG, Soon Man HONG, Ho Bum PARK, Ji Young JUNG, Jang Woo LEE, Young Hoon CHO, Seung Gun YU, Sang Hee PARK
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Publication number: 20130213881Abstract: Described herein are filtration membranes and related, compositions, methods and systems and in particular filtration membranes with embedded polymeric micro/nanoparticles and related compositions, methods, and systems.Type: ApplicationFiled: January 30, 2013Publication date: August 22, 2013Applicants: Korea Advanced Institute of Science and Technology, California Institute of TechnologyInventors: California Institute of Technology, Korea Advanced Institute of Science and Technology
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Publication number: 20130213880Abstract: A separation membrane is provided containing hydrophilic molecules and having, as formed on at least one surface of a feed side and a permeate side thereof, a height difference of from 80 ?m to 2000 ?m, in which a weight of the hydrophilic molecules in a bone-dry separation membrane is from 0.1% to 40% based on a weight of the bone-dry separation membrane from which the weight of the hydrophilic molecules has been subtracted.Type: ApplicationFiled: October 21, 2011Publication date: August 22, 2013Applicant: TORAY INDUSTRIES, INC.Inventors: Hiroho Hirozawa, Masakazu Koiwa, Kentaro Takagi, Yutaro Suzuki, Katsufumi Oto, Masahiro Fimura
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Publication number: 20130206694Abstract: A porous membrane can include a polyazole.Type: ApplicationFiled: February 12, 2013Publication date: August 15, 2013Applicant: KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGYInventor: King Abdullah University of Science and Technology
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Patent number: 8506815Abstract: A method of removing water from fluid mixtures of the water with other compounds uses selective vapor permeation or pervaporation of the water, as the case may be, from the mixture through a membrane having an amorphous perfluoropolymer selectively permeable layer. The novel process can be applied in such exemplary embodiments as (a) removing water from mixtures of compounds that have relative volatility of about 1-1.1 or that form azeotropic mixtures with water, (b) the dehydration of hydrocarbon oil such as hydraulic fluid to concentrations of water less than about 50 ppm, (c) removing water byproduct of reversible chemical equilibrium reactions to favor high conversion of reactants to desirable products, (d) drying ethanol to less than 0.5 wt. % water as can be used in fuel for internal combustion engines, and (e) controlling the water content to optimum concentration in enzyme-catalyzed chemical reactions carried out in organic media.Type: GrantFiled: July 19, 2012Date of Patent: August 13, 2013Assignee: CMS Technologies Holdings Inc.Inventors: Stuart M. Nemser, Sudipto Majumdar, Kenneth J. Pennisi