Abstract: An apparatus and method for effecting liquid-liquid contact between an aqueous liquid medium and an organic liquid medium comprises a chamber for holding a body of each of the media having an agitator therein. One or both of the media are supplied to a mixing zone around the agitator. By means of the agitator a dispersion band is formed with a free space above and/or below it which is devoid of baffles. A layer of disengaged lighter medium forms above the dispersion band and a layer of disengaged heavier medium below it, at least one of these layers extending into the or a corresponding free space. Disengaged lighter and/or heavier medium is recovered from the corresponding layer thereof at the same rate that it is supplied to the mixing zone.

Abstract: There is disclosed a manifold assembly for a rotary solvent extractor formed of an elongated fluid distribution trough or conduit divided into a plurality of fluid distribution subsections by intermediate gate members wherein each fluid distribution subsection is in fluid communication with a fluid supply conduit. A deflector plate is disposed therebelow beneath a manifold assembly to permit for the adjustment of the angle of fluid discharge.

Abstract: Process and apparatus for extracting an organic liquid from an organic liquid solute/solvent mixture. The mixture is contacted with a fluid extractant which is at a temperature and pressure to render the extractant a solvent for the solute but not for the solvent. The resulting fluid extract of the solute is then depressurized to give a still feed which is distilled to form still overhead vapors and liquid still bottoms. The enthalpy required to effect this distillation is provided by compressing the still overhead vapors to heat them and indirectly to heat the still feed. The process is particularly suitable for separating mixtures which form azeotropes, e.g., oxygenated hydrocarbon/water mixtures. The energy required in this process is much less than that required to separate such mixtures by conventional distillation techniques.

Abstract: A centrifugal counter-flow liquid container contactor in which a light liquid and a heavy liquid are introduced into a rotary body fixed to a rotary shaft from the outer peripheral portion and the inner peripheral portion of the rotary body, respectively, so that the light liquid and heavy liquid make counter-flow contact with each other and, after the contact, the light liquid and heavy liquid are discharged from the inner peripheral portion and outer peripheral portion of the rotary body. Disc-shaped partition plates are disposed at both sides of radially extending pipes within the rotary body such as a light liquid introduction pipe, heavy liquid discharging pipe and so forth inserted into the rotary body, so as to separate these radial pipes from the region where the light and heavy liquids are mixed with each other.

Abstract: Mixing of two liquid phases can be advantageously conducted when the two phases are supplied at steady flow rates. Variations in the rates of supply of the phases are compensated for by pumping each liquid at a constant flow rate higher than the maximum flow rate provided by the supply, and permitting recirculation of disengaged phase in the amount necessary to meet the demand of the system.

Abstract: A method and apparatus for removing organic contaminants from an aqueous metal-cleaning solution. The apparatus includes a first conduit, or pipe, for removing portions of the contaminated aqueous solution from its tank. The solution enters an extractor which permits intimate contact between the contaminated solution and an organic solvent. A second tube, or conduit, returns the aqueous solution, purified by this contact, to the original tank. A third conduit removes the organic solvent from the extractor after its contact with the aqueous solution, by which time it will contain organic components from the aqueous solution. This solvent, with the contaminants, enters a separator, such as a still, which removes the contaminants from it. The purified organic solvent then returns to the extractor along a fourth conduit. The cleansing operation proceeds intermittently or, preferably, continuously.

Abstract: A multiple stage extractor column for the countercurrent contact of an upwardly moving hydrocarbon phase and a downwardly moving solvent phase is disclosed. The column is particularly useful for the solvent extraction of aromatics from a hydrocarbon feedstock containing C.sub.9 aromatics. The contactor column embodies an upper extraction section comprising a first plurality of perforated extraction trays and a backwash section comprising a second plurality of perforated extraction trays, said second plurality of trays being vertically spaced apart a greater distance than the trays of said first plurality whereby the solvent/hydrocarbon interface at the bottom of the column is more readily controlled.

Abstract: A multiple stage extractor column for the countercurrent contact of an upwardly moving hydrocarbon phase and a downwardly moving solvent phase is disclosed. The column is particularly useful for the solvent extraction of aromatics from a hydrocarbon feedstock containing C.sub.9 aromatics. The contactor column embodies an upper extraction section comprising a first plurality of perforated extraction trays and a backwash section comprising a second plurality of perforated extraction trays, the upcomer means of said second plurality being of larger cross-sectional area whereby the solvent/hydrocarbon interface at the bottom of the column is more readily controlled.

Abstract: A liquid-liquid extraction apparatus, which apparatus comprises a liquid-liquid extraction column with timing controls for sequentially pulsing the light and heavy phases and controlling the operation of the valves which introduce into the withdraw from the column the liquid phases, based on the percent of phase-volume changes occurring in the liquid-liquid extraction in the column.

Abstract: A multiple stage contactor column for the countercurrent contact of an upwardly moving hydrocarbon phase and a downwardly moving solvent phase is disclosed. The column is particularly useful for the solvent extraction of aromatics from a hydrocarbon feedstock containing C.sub.9 aromatics. The contactor column embodies an upper extraction section comprising a first plurality of perforated extraction trays and a backwash section comprising a second plurality of perforated extraction trays, the perforations of said second plurality being of larger cross-sectional area whereby the solvent/hydrocarbon interface at the bottom of the column is more readily controlled.

Abstract: A compact, multi-stage, co- or counter-current liquid-liquid extraction apparatus includes first and second mixer-settlers which share a common wall. Each of the first and second mixer-settlers comprises a mixing chamber having an agitator mounted therein, upper and lower settling chambers, and upper and lower baffles between the mixing chamber and the upper and lower settling chambers respectively. The liquid media to be contacted in each mixer-settler are supplied to the mixing chamber from which dispersion flows upwardly and downwardly into the upper and lower baffles. Disengaged lighter medium flows out from the upper settling chamber to the mixer-settler, over a weir whose length exceeds half the length of the common wall, while disengaged heavier medium flows out of the lower settling chamber of one mixer-settler to the corresponding mixing chamber of the next mixer-settler. In one form the disengaged heavier medium also overflows a corresponding outlet weir to pass on to the next mixer-settler.

Abstract: Method and apparatus for making separations from aqueous solutions, particularly for removing water from aqueous solutions of electrolytes or other substantially non-volatile solutes, such as saline water. According to the invention, a solvent extraction process is employed which produces streams of lower and higher solute concentration in composition from an aqueous solution by contacting the aqueous solution with a solvent to produce an extract stream and a residual raffinate stream, the solvent having the property of dissolving water at a first lower temperature and substantially releasing it at a second higher temperature without substantially extracting the solute from the aqueous solution. The extract stream is contacted with a hotter aqueous reflux and thereby simultaneously heated and caused to have its content of undesired solute diminished.

Abstract: A process and apparatus for separating tar from a tar sand mixture. The separating step is by a novel mechanical process avoiding the complication of heating, freezing and the use of solvents. In the process a suitable suspension liquid is added to a tar sand mixture which is then struck with a plurality of striker arms to separate tar from said particles and agglomerate tar into droplets. After the striking step, the sand particles are allowed to settle to the bottom and tar droplets rise and float, the tar droplets are skimmed off the mixture, and the tar droplets are also scraped off the striker arms. The resulting tar droplets are washed at least once to remove remaining sand particles.

Abstract: An apparatus for countercurrent chromatography consisting of a coiled separation column which is rotated about the axis about which is it wound and the axis is also rotated about a main axis. The embodiments of the invention are based on the fact that the pattern of the centrifugal force field greatly changes with the ratio of the two radii of rotation and depending on the particular effect desired, the apparatus is configured to achieve the most effective force field to gain the effect. The separation column is a tube helix wound around a flexible core member which can be wound onto the coil holder in various orientations to further effect the desired results.

Abstract: A method for the recovery of a color developing agent of the N,N-disubstituted paraphenylene diamine type is provided. The used color developing solution is placed in a cell member which is separated from a second cell member, which contains an aqueous acid solution by a semipermeable nonporous membrane.The semi-permeable non-porous membrane has imbibed in it an organic solvent of low water miscibility in which the color developing agent is soluble. The color developing agent diffuses through the semi-permeable non-porous membrane and forms a salt with the aqueous acid, and is then used as such.

Abstract: A continuous extraction system wherein two immiscible solvents move in opposite directions through a rotating helical column. Elution of a desired phase takes place by use of a separation device at the head end which selects either the heavier or the lighter phase. This may consist of a suitably weighted suspended outlet tube in a rotating cylindrical outlet chamber or may consist of a shunt and settling chamber located outside the rotating part; the heavier phase may be removed from the bottom and the lighter phase may be removed from the top.

Abstract: A process for the purification of waste water containing grease and soil, especially the effluent from wool-soaking and wool-washing, which comprises mixing the waste water with a heavy solvent; separating the emulsion formed to obtain degreased water, a small quantity of water-solvent emulsion, and solvent charged with greasy matter and soil; clarifying this solvent to separate the soil; subjecting the clarified solvent to an azeotropic distillation in the presence of water, to form an emulsion from which the greasy matter can be recovered, and a head product from which the solvent can be regenerated, and apparatus therefor.

Abstract: Method for separating foreign solid particles from a liquid having the steps of disposing the contaminated liquid in the position of an upper layer on the flushing liquid and permitting the contamination particles to sink into the flushing liquid which is removed from the tank while the processed contaminated liquid is also removed from the tank.

Abstract: A rotatable drum having an interior which tapers in a horizontal direction has a first port at the smaller end for receiving particulate Tar Sands or coal, and an agglomerating liquid, e.g. water, and a second port at the larger end for receiving an organic material separating liquid, e.g. Varsol, with which the agglomerating liquid is immiscible. The first port is, for example, larger than the second port so that the separating liquid will drain from the drum through the first port. A conveying means delivers the particulate material and agglomerating liquid into the drum interior, and the separating liquid forms a slurry therewith so that inorganic residue from the particulate material is formed into ball agglomerates as it tumbles along the drum and the ball agglomerates overflow through the second port while the separating liquid fed into the second port separates organic material from the particulate material (Tar Sands) in the drum and overflows therewith through the first port.